[go: up one dir, main page]

WO2015068158A1 - Composition fongicide synergique - Google Patents

Composition fongicide synergique Download PDF

Info

Publication number
WO2015068158A1
WO2015068158A1 PCT/IL2014/050961 IL2014050961W WO2015068158A1 WO 2015068158 A1 WO2015068158 A1 WO 2015068158A1 IL 2014050961 W IL2014050961 W IL 2014050961W WO 2015068158 A1 WO2015068158 A1 WO 2015068158A1
Authority
WO
WIPO (PCT)
Prior art keywords
fungicide
composition
fluazinam
tubers
dimethomorph
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IL2014/050961
Other languages
English (en)
Inventor
Ofer SZYPER
Daphna BLACHINSKY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adama Makhteshim Ltd
Original Assignee
Adama Makhteshim Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Adama Makhteshim Ltd filed Critical Adama Makhteshim Ltd
Publication of WO2015068158A1 publication Critical patent/WO2015068158A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system

Definitions

  • the present subject matter relates to a method for controlling Spongospora subterranean (Powdery scab) in seeds, tubers, a plant grown from the seed or a plant grown from the tubers.
  • Dimethomorph is a systemic fungicide which protects plants from fungi in the water mold family (Oomycetes), such as late blight and downy mildew. Dimethomorph moves up the treated plant stem and into growing leaves. It also has anti-sporulant activity which helps to prevent the spread of blight between plants.
  • the mode of action of dimethomorph is that it affects cell wall production in fungi by inhibition of sterol synthesis.
  • Fluazinam is a broad spectrum contact fungicide that can be applied as a foliar spray or soil treatment. It is effective against a number of pathogenic fungi that cause the following diseases: foliar blight, tuber blight and sclerotinia rot in potatoes caused by the fungus Phytophthora infestans. Fluazinam is effective against both spore germination and spore growth, thereby giving it protective action with a good residual effect. The mode of action of fluazinam is due to the disruption of energy production in the fungus at multiple sites, therefore preventing resistance.
  • EP 0956769 teaches a liquid concentrated fungicidal composition
  • a fungicidally acceptable carrier and/or surface active agent and synergistically effective amounts of an acrylic acid morpholide and a at least one fungicidal N-pyridylaniline compound.
  • the composition is to be used for controlling diseases caused by oomycetes, e.g. Phytophthora infestans.
  • Powdery scab is a disease of potato tubers. It is caused by the cercozoan Spongospora subterranea f. sp. subterranea and is widespread in potato growing countries. Symptoms of powdery scab include small lesions in the early stages of the disease, progressing to raised pustules containing a powdery mass. Powdery scab has a cosmetic effect on tubers, which can result in rejection of potatoes. The powdery pustules contain resting spores, which release zoospores which can infect the root hairs of potatoes or tomatoes. Powdery scab is both seed and soil borne.
  • Incidence and severity of powdery scab symptoms can vary widely depending on a range of factors, including inoculum level and climatic conditions. Sporadic occurrences can have a big effect on crop value. It can result in total rejection of fresh crop if severe for example, and can have big consequences for peeling before processing.
  • Clubroot of cabbage and related crucifers is caused by the soilborne protist Plasmodiophora brassicae. Plasmodiophora brassicae forms no mycelia and can develop and multiply only in living host cells. The disease causes the formation of large galls on the roots which look like clubs. These formations impede nutrient and water uptake and can cause plant death. The pathogen can survive in a field for years as resting spores without a host present and will infect the next crop planted if it is a susceptible host.
  • agricultural fungicides are chemical compounds used to kill or inhibit fungi or fungal spores.
  • Agricultural fungicides can be used to protect seed grain during storage, shipment and germination and to protect mature crops, berries, seedlings, flowers and grasses in the field, in storage and during shipment. They can be applied to the soil to control fungi that are resident there, to the seed or foliage of the plant to be protected, or to harvested produce to prevent storage losses.
  • Combinations of agricultural fungicides are typically used to broaden the spectrum of control, to minimize the doses of chemicals used and to reduce the cost of the treatment through additive effect. Combinations of agricultural fungicides can be also used to avoid or delay the risk of resistance development.
  • Synergism has been defined as the simultaneous action of two or more compounds in which the total response of an organism to the pesticide combination is greater than the sum of the individual components. Although many combinations of fungicides have been studied, a synergistic effect is rarely revealed and the global use of fungicide combinations with synergistically enhanced activity is rather limited.
  • the subject matter relates to a method of controlling growth of a protist from the class Phytomyxea in seeds, tubers, a plant grown from the seed, or a plant grown from the tubers by contacting the seeds, the plants or soil in which the seeds or tubers are planted with a synergistically effective amount of a combination of a morpholine fungicide and a pyridine fungicide.
  • Another embodiment relates to a use of a composition comprising a synergistic combination of a morpholine fungicide and a pyridine fungicide for controlling growth of a protist from the class Phytomyxea in seeds, tubers, a plant grown from the seed, or a plant grown from the tubers.
  • compositions comprising a synergistic combination of a morpholine fungicide and a pyridine fungicide for use in controlling growth of a protist from the class Phytomyxea in seeds, tubers, a plant grown from the seed, or a plant grown from the tubers.
  • the composition may further comprise an agriculturally acceptable carrier.
  • the composition may further comprise at least one surfactant, solid diluent, liquid diluent, or a combination thereof.
  • the protist may be at least one of Spongospora subterranean and Plasmodiophora brassicae.
  • the morpholine fungicide may be dimethomorph and the pyridine fungicide may be fluazinam.
  • the ratio by weight of the morpholine fungicide to the pyridine fungicide may be from approximately 1: 10 to approximately 10: 1. In some further embodiments, the ratio by weight of the morpholine fungicide to the pyridine fungicide may be 1: 1.
  • the application rates of the combination of the combination may be from approximately 1000 g/ha to approximately 2500 g/ha. In a further embodiment, the combination may be from approximately 1500 g/ha to approximately 2000 g/ha.
  • adjuvant refers to a substance, which can increase the biological activity of an active ingredient, but is not itself significantly biologically active.
  • contacting refers to applying the compounds and compositions described herein to the plant, to a site of infestation by protists, to a potential site of infestation by protists, which may require protection from infestation, or the environment around the habitat or potential habitat of protists.
  • the application may be by methods according to the present subject matter, such as by spraying, dipping, etc.
  • plant refers to whole plants, plant organs (e.g. leaves, stems, twigs, roots, trunks, limbs, shoots, fruits etc.), or plant cells. This term also encompasses plant crops such as fruits.
  • the term "plant” may include the propagation material thereof, which may include seeds and spores, vegetative structures such as bulbs, corms, tubers, rhizomes, roots stems, basal shoots, stolons, and buds.
  • the plants include vegetables, such as potatoes and tomatoes.
  • plants that tolerate the action of herbicides, fungicides or insecticides as a result of breeding, mutagenesis or genetic engineering methods are also included.
  • surfactant refers to an agriculturally acceptable material which imparts emulsifiability, stability, spreading, wetting, dispersibility or other surface-modifying properties.
  • the combination of a morpholine fungicide such as dimethomorph and a pyridine fungicide such as fluazinam results in a synergistic fungicidal activity against the growth of protists from the class Phytomyxea.
  • the protists may include Spongospora subterranean and Plasmodiophora brassicae.
  • the combination provides a higher fungicidal activity than that envisaged on the basis of the sum of activities of each of the fungicides found therein. Such a combination allows the reduced dosages of the individual fungicides which can damage agriculturally important plants.
  • the morpholine fungicides include compounds such as aldimorph, benzamorf, carbamorph, dimethomorph, dodemorph and salts thereof, fenpropimorph, flumorph, and tridemorph or a combination comprising at least one of the foregoing.
  • the morpholine fungicide is dimethomorph.
  • the pyridine fungicides include compounds such as boscalid, buthiobate, dipyrithione, fluazinam, fluopicolide, fluopyram, parinol, picarbutrazox, pyribencarb, pyridinitril, pyrifenox, pyrisoxazole, pyroxychlor, pyroxyfur, triclopyricarb or a combination comprising at least one of the foregoing.
  • the pyridine fungicide is fluazinam.
  • the ratio (by weight) of the morpholine fungicide to the pyridine fungicide is from 1: 100 to 100: 1. In another embodiment the ratio is from 1:25 to 25: 1. In a further embodiment the ratio is from 1: 10 to 10: 1. In a specific embodiment, the ratio (by weight) of the morpholine fungicide to the pyridine fungicide is 1: 1.
  • a method for controlling and/or preventing the growth of protists from the class Phytomyxea in seeds, tubers, a plant grown from the seed, or a plant grown from the tubers which comprises contacting the seeds, the plants or soil in which the seeds or tubers are planted with a synergistically effective amount of a combination of a morpholine fungicide and a pyridine fungicide, is provided.
  • a method for controlling and/or preventing a disease caused by Spongospora subterranea f.sp. Subterranea in seeds, tubers, a plant grown from the seed, or a plant grown from the tubers by contacting the seeds, tubers, the plants grown from the seeds or tuber or the soil in which the seeds or tubers are planted, with a synergistically effective amount of dimethomorph and fluazinam, is provided.
  • composition comprising a synergistic combination of a morpholine fungicide and a pyridine fungicide for controlling and/or preventing growth of a protist from the class Phytomyxea in seeds, tubers, a plant grown from the seed, or a plant grown from the tubers, is provided.
  • composition comprising a synergistically effective amount of dimethomorph and fluazinam for controlling and/or preventing a disease caused by Spongospora subterranea f.sp. Subterranea in seeds, tubers, a plant grown from the seed, or a plant grown from the tubers, is provided.
  • the protists may be one or more of the class phytomyxea.
  • this may include Spongospora subterranea f.sp. Subterranea (which causes Powdery scab in potatoes) and Plasmodiophora brassicae (which causes Clubroot in cabbage and other brassicaceous crops).
  • the application rates of the combination may vary, depending on the desired effect.
  • the application rates of the mixtures according to the present subject matter may be from approximately 1000 g/ha to 2500 g/ha, particularly from approximately 1500 to 2000 g/ha.
  • the application rates of the mixtures may be from approximately 1 g/ha to 1000 g/ha, particularly from approximately 100 to 500 g/ha, more particularly from approximately 200 to 400 g/ha.
  • the application rate of the morpholine fungicide (e.g. dimethomorph) in the mixture may be from approximately 600 g/ha to 1000 g/ha, and the amount of the pyridine fungicide (e.g. fluazinam) in the mixture may be from approximately 600 g/ha to 1000 g/ha.
  • the optimal rate for a specific application of the formulation will depend on the crop and may be readily determined by established biological tests known to those skilled in the art.
  • the application rates of the combination when used for treating seeds may be from approximately 0.1 to 50 g a.i./kg, and particularly from approximately 1 to 15 g a.i./kg.
  • a fungicidal composition comprising a synergistic combination of a morpholine fungicide and a pyridine fungicide for use in controlling/preventing growth of a protist from the class Phytomyxea in seeds, tubers, a plant grown from the seed, or a plant grown from the tubers, is provided.
  • a formulation may be obtained by combining a synergistic amount of the active ingredients with an agriculturally acceptable carrier, a surfactant or other application-promoting adjuvant customarily employed in formulation technology.
  • the present composition may be employed or prepared in any conventional form, for example, in the form of a twin pack, or for example, as wettable powders (WP), emulsion concentrates (EC), microemulsion concentrates (MEC), water-soluble powders (SP), water-soluble concentrates (SL), suspoemulsion (SE), oil dispersions (OD), concentrated emulsions (BW) such as oil-in-water and water-in-oil emulsions, sprayable solutions or emulsions, capsule suspensions (CS), suspension concentrates (SC), suspension concentrates, dusts (DP), oil-miscible solutions (OL), seed-dressing products, granules (GR) in the form of microgranules, spray granules, coated granules and absorption granules, granules for soil application or broadcasting, water-soluble granules (SG), water-dispersible granules (WDG), ULV formulations, microcapsules or wax
  • compositions can be formulated using agriculturally acceptable carriers, surfactants or other application-promoting adjuvants customarily employed in formulation technology and formulation techniques that are known in the art.
  • liquid carriers potentially useful in the present compositions include but are not limited to water; aromatic hydrocarbons such as alkylbenzenes and alkylnaphthalenes; alcohols such as methanol, cyclohexanol, and decanol; ethylene glycol; polypropylene glycol; dipropropylene glycol; N,N- dimethylformamide; dimethylsulfoxide; dimethylacetamide; N-alkylpyrrolidones such as N-methyl-2-pyrrolidone; paraffins; various oils such as olive, castor, linseed, tung, sesame, corn, peanut, cotton-seed, soybean, rape-seed, or coconut oil; fatty acid esters; ketones such as cyclohexanone, 2-heptanone, isophorone, and 4-hydroxy-4-methyl-2- pentanone; and the like.
  • aromatic hydrocarbons such as alkylbenzenes and alkylnaphthalenes
  • alcohols such
  • suitable solid carriers potentially useful in the present compositions include but are not limited to mineral earths such as silica gels, silicates, talc, kaolin, sericite, attaclay, limestone, bentonite, lime, chalk, bole, mirabilite, loess, clay, dolomite, zeolite, diatomaceous earth, calcium carbonate, calcium sulfate, magnesium sulfate, magnesium oxide, sodium carbonate and bicarbonate, and sodium sulfate; ground synthetic materials; fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal, and nutshell meal; cellulose powders; and other solid carriers.
  • mineral earths such as silica gels, silicates, talc, kaolin, sericite, attaclay, limestone, bentonite, lime, chalk, bole, mirabilite, lo
  • surfactants include, but are not limited to, non-ionic, anionic, cationic and ampholytic types such as alkoxylated fatty alcohols, ethoxylated polysorbate (e.g. tween 20), ethoxylated castor oil, lignin sulfonates, fatty acid sulfonates (e.g.
  • phosphate esters such as phosphate esters of alcohol alkoxylates, phosphate esters of alkylphenol alkoxylates and phosphate esters of styrylphenol ethoxylates, condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalene sulfonic acid with phenol and formaldehyde, alkylarylsulfonates, ethoxylated alkylphenols and aryl phenols, polyalkylene glycols, sorbitol esters, alkali metal, sodium salts of lignosulphonates, tristyrylphenol ethoxylate phosphate esters, aliphatic alcohol ethoxylates, alkylphenol ethoxylates, ethylene oxide/propylene oxide block copolymers, graft copolymers
  • the biological activity of the active ingredient can also be increased by including an adjuvant to the composition.
  • Other ingredients such as wetting agents, anti-foaming agents, adhesives, thickeners, binders, fertilizers, biocides, stabilizers, buffers, or anti-freeze agents, may also be added to the composition including the combination of the fungicides in order to increase the stability, density and viscosity of the composition.
  • the amount of the active ingredient or ingredients in the composition is about 0.1-99 wt. %, about 0.1-95 wt. %, or about 0.1-90 wt. %, based on the total weight of the composition.
  • the amount of the mixture of active ingredients in the composition is about 10-90 wt. %.
  • the amount of the mixture of active ingredients in the composition is about more specifically 10-80 wt. %, based on the total weight of the composition.
  • the herbicidal compositions and herbicidal mixtures discussed herein may be applied jointly or in a succession. That is, each of the morpholine fungicide and a pyridine fungicide may be applied jointly or in succession.
  • the morpholine fungicide and the pyridine fungicide are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
  • the morpholine fungicide and the pyridine fungicide are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
  • the morpholine fungicide and the pyridine fungicide are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
  • the fungicidal mixture may be applied via basal application, broadcast application, directed- spray application, foliar application, soil application, soil incorporation or soil injection.
  • the present composition may include additional crop protection agents, for example pesticides, or safeners.
  • additional crop protection agents for example pesticides, or safeners.
  • additional crop protection agents are unnecessary to achieve the desired control of undesired vegetation as achieved by the present combinations.
  • the present fungicidal compositions and fungicidal mixtures may be limited to containing the combination of a morpholine fungicide and a pyridine fungicide, as the only crop protection agents present.
  • kits comprising the fungicidal mixture as described herein, or components thereof.
  • kits may comprise, in addition to the aforementioned active ingredients, one or more additional active and/or inactive ingredients, either within the provided fungicidal composition or separately.
  • kits comprise a morpholine fungicide and a pyridine fungicide, each in a separate container, and each optionally combined with a carrier.
  • a synergistic effect exists wherever the action of a combination of active components is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount (or an effective amount of a synergistic composition or combination) of the present compositions is an amount that exhibits greater fungicidal activity than the sum of the fungicidal activities of the individual components.
  • synergistic effect exists wherever the action of a combination of active components is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount (or an effective amount of a synergistic composition or combination) is an amount that exhibits greater fungicidal activity than the sum of the fungicidal activities of the individual components.
  • E represents the expected percentage of fungicidal control for the combination of the two fungicides at defined doses (for example equal to x and y respectively)
  • X is the percentage of fungicidal control observed by dimethomorph at a defined dose (equal to x)
  • Y is the percentage of fungicidal control observed by fluazinam at a defined dose (equal to y).
  • compositions of dimethomorph (Athlete® 50% WG) and Fluazinam (OHAYO® 500 SC), as well as composition comprising a combination of dimethomorph, and fluazinam (mixed at a weight ratio of 1: 1) (Banjo® Forte Dimethomorph 20% and Fluazinam 20% SC) were compared.
  • Each of the tested compositions were sprayed broadcasting on the beds (i.e. the soil).
  • the soil was incorporated before the potato tubers were planted.
  • the trial was on potato tubers of the variety Nicola.
  • the formulations of dimethomorph and fluazinam were individually applied at a rate of 2 L/ha (equivalent to 100 g a.i./ha).
  • the formulation comprising both dimethomorph and fluazinam was applied at rate of 5 L/ha (equivalent to 100 g a.i./ha of each of dimethomorph and fluazinam).
  • the valuation of the potato tubers were carried out two months after application of the formulations.
  • the potatoes were given an index number based on the severity of the infection. A value of 0 was given to potatoes which were not infected. A value of 1 was given to potatoes which had the infection on less than 5% of its surface. A value of 3 was given to potatoes which had the infection on between 5% and 30% of its surface. A value of 5 was given to potatoes which had the infection on more than 30% of its surface.
  • Table 1 The results are presented in Table 1.
  • the percentages of potatoes in each category of Table 1 are multiplied by its associated index value.
  • the severity index can then be used to determine the percent control of each type of treatment.
  • the severity index and percent control of each type of treatment is indicated in Table 2.
  • the expected fungicidal control for the fluazinam/dimethomorph formulation is 39.06%. Therefore the Colby ratio of percent observed/percent expected is equal to 1.63, thereby showing synergism in the combination of dimethomorph and fluazinam against powdery scab.
  • the fungicidal composition comprising dimethomorph and fluazinam was found to exhibit a strong synergistic effect against Spongospora subterranea f. sp. Subterranean.
  • a synergistic combination of a morpholine fungicide (e.g. dimethomorph) and a pyridine fungicide (e.g. fluazinam) is suitable for controlling and/or preventing diseases in agriculturally important plants or propagation material thereof caused by Spongospora subterranea f. sp. Subterranean.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne un procédé de lutte/prévention contre Spongospora subterranea dans des graines et des tubercules, une plante cultivée à partir de ces graines ou une plante cultivée à partir de ces tubercules.
PCT/IL2014/050961 2013-11-07 2014-11-05 Composition fongicide synergique Ceased WO2015068158A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361901171P 2013-11-07 2013-11-07
US61/901,171 2013-11-07

Publications (1)

Publication Number Publication Date
WO2015068158A1 true WO2015068158A1 (fr) 2015-05-14

Family

ID=51982664

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IL2014/050961 Ceased WO2015068158A1 (fr) 2013-11-07 2014-11-05 Composition fongicide synergique

Country Status (1)

Country Link
WO (1) WO2015068158A1 (fr)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2771900A1 (fr) * 1997-12-01 1999-06-11 Ishihara Sangyo Kaisha Composition pour la lutte contre les organismes vivants nuisibles et son procede d'utilisation
EP0956769A1 (fr) 1998-05-13 1999-11-17 American Cyanamid Company Mélanges fongicides
CN101617678A (zh) * 2009-07-29 2010-01-06 深圳诺普信农化股份有限公司 一种农药组合物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2771900A1 (fr) * 1997-12-01 1999-06-11 Ishihara Sangyo Kaisha Composition pour la lutte contre les organismes vivants nuisibles et son procede d'utilisation
EP0956769A1 (fr) 1998-05-13 1999-11-17 American Cyanamid Company Mélanges fongicides
CN101617678A (zh) * 2009-07-29 2010-01-06 深圳诺普信农化股份有限公司 一种农药组合物

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
COLBY S. R.: "Calculation of the synergistic and antagonistic responses of herbicide combinations", JOURNAL WEEDS, vol. 15, 1967, pages 20 - 22
KAZUMI SUZUKI ET AL: "Biological Mode of Action of Fluazinam, a New Fungicide, for Chinese Cabbage Clubroot.", JAPANESE JOURNAL OF PHYTOPATHOLOGY, vol. 61, no. 4, 1 January 1995 (1995-01-01), pages 395 - 398, XP055161665, ISSN: 0031-9473, DOI: 10.3186/jjphytopath.61.395 *
M. BRAITHWAITE ET AL: "Control of powdery scab of potatoes with chemical seed tuber treatments", NEW ZEALAND JOURNAL OF CROP AND HORTICULTURAL SCIENCE, vol. 22, no. 2, 1 June 1994 (1994-06-01), pages 121 - 128, XP055161657, ISSN: 0114-0671, DOI: 10.1080/01140671.1994.9513815 *
OLAF VAN CAMPEN ET AL: "BANJO FORTE: A Unique Solution for Potato Late Blight", EUROPEAN ASSOCIATION OF POTATO RESEARCHERS CONFERENCE, 17 November 2013 (2013-11-17) - 21 November 2013 (2013-11-21), pages 1 - 21, XP055161450 *

Similar Documents

Publication Publication Date Title
US20230270113A1 (en) Fungicidal mixtures
EP4463001A1 (fr) Mélanges fongicides comprenant une combinaison contenant des fongicides de phtalimide
KR102334544B1 (ko) 활성 화합물의 배합물
TW201517798A (zh) 殺真菌組成物及其用途
EP3905883B1 (fr) Mélange fongicide
BR112016000998B1 (pt) mistura fungicida, método para controlar patógenos de planta e uso da mistura fungicida
TW201705863A (zh) 協同性殺昆蟲組合物
CN114223665B (zh) 一种杀菌组合物用于防治植物致病真菌的用途
CN104968202A (zh) 具有减少的植物毒性的苯醚甲环唑立体异构组合物
US20190104737A1 (en) Use of heterocyclic fluoroalkenyl sulfone compounds for repelling molluscs
CN112136825A (zh) 一种杀菌组合物
EP4616711A2 (fr) Utilisation comme fongicide
CN106922702A (zh) 一种杀菌组合物
WO2015068158A1 (fr) Composition fongicide synergique
EA039414B1 (ru) Гербицидная комбинация и способ контроля сорняков
CN106922701A (zh) 一种杀菌组合物
CN112244034A (zh) 一种杀菌组合物
KR20220075235A (ko) 농약 혼합물
EA048222B1 (ru) Фунгицидная смесь
CN112042658A (zh) 一种杀菌组合物
CN111109269A (zh) 一种杀菌组合物

Legal Events

Date Code Title Description
NENP Non-entry into the national phase

Ref country code: DE

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 14802951

Country of ref document: EP

Kind code of ref document: A1

122 Ep: pct application non-entry in european phase

Ref document number: 14802951

Country of ref document: EP

Kind code of ref document: A1