WO2020141735A1 - Solid oily component-stabilized, low-viscosity cosmetic composition - Google Patents
Solid oily component-stabilized, low-viscosity cosmetic composition Download PDFInfo
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- WO2020141735A1 WO2020141735A1 PCT/KR2019/016911 KR2019016911W WO2020141735A1 WO 2020141735 A1 WO2020141735 A1 WO 2020141735A1 KR 2019016911 W KR2019016911 W KR 2019016911W WO 2020141735 A1 WO2020141735 A1 WO 2020141735A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/553—Phospholipids, e.g. lecithin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/007—Preparations for dry skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/49—Solubiliser, Solubilising system
Definitions
- the present disclosure relates to a low-viscosity cosmetic composition that stabilizes a solid oily component.
- Basic cosmetics are classified into various formulations such as skin, essence, lotion, and cream. It is well known that the higher the content of oily ingredients such as oil, the higher the moisturizing effect of the skin.
- a transparent or translucent solubilizing formulation that contains mostly water-soluble components such as skin and does not contain oil or is added in a small amount to stabilize it, it has the advantage of being light and refreshing, but it has the disadvantage of not showing a high moisturizing power or a flexible feeling as an emulsifying formulation.
- solubilizing formulation it is important to increase the skin moisturizing power and realize a differentiated feeling of use while maintaining a merit of light and refreshing application by containing a large amount of oily ingredients.
- a large amount of a surfactant or thickener for solubilizing it must be used, and the excessive use of the surfactant or thickener is sticky or heavy feeling Or cause skin irritation.
- Patent Document 1 Republic of Korea Patent Publication No. 10-2018-0120388
- the present disclosure unlike conventional formulations containing a large amount of the oily component in a liquid form, transparently or translucently stabilizes the oily component present in a solid state at room temperature in a low viscosity solubilizing formulation. It is possible to provide a low-viscosity cosmetic composition that exhibits both a light and refreshing feeling of the solubilizing formulation and excellent skin moisturizing effect by oily ingredients.
- the present disclosure is an embodiment, a solid oily component; Thickener; And a polyol, wherein the solid oily component is included in an amount of 1 to 10% by weight based on the total weight of the composition, and the solid oily component is a mixture of two or more types, and the viscosity of the composition is 10,000 cps or less. to provide.
- the low-viscosity cosmetic composition according to an embodiment of the present disclosure can stabilize the oily component in a solid state at room temperature into a transparent or translucent low-viscosity solubilizing formulation.
- the formulation has excellent transparency and aging stability, and exhibits excellent skin moisturizing power by oily components, and can realize a refreshing feeling of use according to a low-viscosity solubilizing formulation.
- hydrophile-lipophile balance is a ratio of the hydrophilicity-hydrophobicity of a general surfactant, and means a relative value of hydrophilicity and hydrophobicity suitable for stable dispersion of each raw material.
- the HLB may be represented by a value of 0 to 20, and the lower the value, the more hydrophobic the characteristic, whereas the higher the value, the more hydrophilic the characteristic.
- “solubilization formulation” is a transparent or translucent oil-in-water formulation in which an oily component is stabilized in a large amount of water phase, and is distinguished from a “emulsifying formulation” having a milky white appearance, The solubilizing formulation has a transparent or translucent appearance.
- “translucent formulation” means that light is scattered by an oily component stabilized in a small particle state to give a white or slightly blue glow.
- the present invention in one aspect, a solid oily component; Thickener; And a polyol, wherein the solid oily component is contained in an amount of 1 to 10% by weight based on the total weight of the composition, and the solid oily component is a mixture of two or more, and the viscosity of the composition is less than or equal to 10,000 cps. It may be about
- the content of the solid oil component is 1% by weight or more, 2% by weight or more, 2.5% by weight or more, 2.7% by weight or more, 3% by weight or more, 3.3% by weight or more, 3.5% by weight or more based on the total weight of the composition , 4% or more, 4.5% or more, 5% or more, 5.5% or more, 5.7% or more, 6% or more, 6.2% or more, 6.5% or more, 7% or more, 8% or more Or 9% by weight or more, and the content of the solid oily component is 10% by weight or less, 9% by weight or less, 8% by weight or less, 7% by weight or less, 6.5% by weight or less, 6.2% by weight or less based on the total weight of the composition , 6% or less, 5.7% or less, 5.5% or less, 5% or less, 4.5% or less, 4% or less, 3.5% or less, 3.3% or less, 3% or less, 2.7% or less , 2.5% by weight or less or 2% by weight or less.
- the solid oily component is a solid oily component at room temperature, and may have a hydrophile-lipophile balance (HLB) of 8 to 13.
- HLB hydrophile-lipophile balance
- the HLB of the solid oily component may be 8 or more, 9 or more, 10 or more, 11 or more, or 12 or more, and may also be 13 or less, 12 or less, 11 or less, 10 or less, or 9 or less.
- the HLB of the solid oily component may be 10 to 11.
- the solid oily component is lecithin; C16-18 alcohol; And C16-18 fatty acids, salts or derivatives thereof; It may be two or more selected from.
- the derivative may be one in which the C16-18 fatty acid is synthesized with at least one of polyethylene glycol, glycerin, sugar, and phosphoric acid groups.
- the C16-18 fatty acid, a salt thereof, or a derivative thereof polyglyceryl-3 methylglucose distearate, cetearyl oleate/sorbitan oleate (cetearyl olivate/ sorbitan olivate), and glyceryl stearate citrate.
- the solid oily component comprises lecithin; And polyglyceryl-3 methylglucose distearate, cetearyl olivate/sorbitan olivate, and glyceryl stearate citrate. It may include at least one selected.
- the lecithin may be hydrogenated lecithin.
- each of the two or more solid oily components may be included in an amount of 5% by weight or less based on the total weight of the composition.
- each of the two or more solid oily components may be included in an amount of 5% by weight or less, 4% by weight or less, 3% by weight or less, or 2% by weight or less based on the total weight of the composition. , 2% by weight or more, 3% by weight or more, or 4% by weight or more. That is, two or more solid oily components included in an amount of 5 wt% or less may be mixed to include the solid oily component in an amount of 10 wt% or less based on the total weight of the composition.
- the thickener is xanthan gum (xanthan gum), cellulose gum (cellulose gum), hydroxyethylcellulose (hydroxyethylcellulose), carob gum (Ceratonia Siliqua Gum), carbomer (carbomer), acrylate /C10- 30 acrylates/c10-30 alkyl acrylate crosspolymer, Ammonium Acryloyldimethyltaurate/VP Copolymer, and hydroxyethyl acrylate/sodium acryloyl dimethyltau It may be at least one selected from hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer.
- the thickener may be included in an amount of 0.01 to 1% by weight based on the total weight of the composition.
- the content of the thickener is 0.01 wt% or more, 0.03 wt% or more, 0.05 wt% or more, 0.07 wt% or more, 0.09 wt% or more, 0.1 wt% or more, 0.15 wt% or more, based on the total weight of the composition, 0.2% or more, 0.25% or more, 0.3% or more, 0.35% or more, 0.4% or more, 0.45% or more, 0.5% or more, 0.6% or more, 0.7% or more, 0.8% or more, or It may be 0.9% by weight or more, and the content of the thickener is 1% by weight or less, 0.9% by weight or less, 0.8% by weight or less, 0.7% by weight or less, 0.6% by weight or less, 0.5% by weight or less, 0.45 based on the total weight of the composition Weight% or less, 0.4% or
- the polyol is 1,3-butylene glycol (1,3-butylene glycol), dipropylene glycol (dipropylene glycol), propylene glycol (propylene glycol), 1,3-propanediol (1,3- Propanediol, glycerin, diglycerin, methylpropanediol, ethylhexanediol, 1,2-hexanediol, and pentylene glycol It may be one or more selected from the group consisting of.
- the polyol may be included in an amount of 1 to 30% by weight based on the total weight of the composition.
- the content of the polyol is 1 wt% or more, 5 wt% or more, 7 wt% or more, 10 wt% or more, 12 wt% or more, 15 wt% or more, 18 wt% or more, 20 based on the total weight of the composition It may be at least 25% by weight, at least 25% by weight, or at least 27% by weight, and the content of the polyol is 30% by weight or less, 27% by weight or less, 25% by weight or less, 20% by weight or less, 18% by weight based on the total weight of the composition Or less, 15 wt% or less, 12 wt% or less, 10 wt% or less, 7 wt% or less, or 5 wt% or less.
- the polyol may be included in an amount of 5 to 30% by weight based on the total weight of the composition.
- the composition may have a viscosity of 10,000 cps or less.
- the viscosity of the composition is 10,000 cps or less, 9,000 cps or less, 8,000 cps or less, 7,000 cps or less, 6,900 cps or less, 6,700 cps or less, 6,500 cps or less, 6,300 cps or less, 6,000 cps or less, 5,600 cps or less, 5,300 cps or less Below, 5,000 cps or less, 4,500 cps or less, 4,000 cps or less, 3,500 cps or less, and the viscosity of the composition is 20 cps or more, 100 cps or more, 500 cps or more, 1,000 cps or more, 2,000 cps or more, 3,000 cps or more , 3,500 cps or more, 4,000 cps or more, or 4,500 cps or less,
- the solid oil component 100 parts by weight, the thickener may be included in 1 to 10 parts by weight, the polyol may be included in 200 to 600 parts by weight.
- the thickener is 1 part by weight or more, 2 parts by weight or more, 3 parts by weight or more, 4 parts by weight or more, 5 parts by weight or more, 6 parts by weight or more, 7 More than 8 parts by weight, or more than 9 parts by weight, or more, 10 parts by weight or less, 9 parts by weight or less, 8 parts by weight or less, 7 parts by weight or less, 6 parts by weight or less, 5 parts by weight or less, 4 parts by weight or less, 3 parts by weight or less, or 2 parts by weight or less.
- the polyol is 200 parts by weight or more, 250 parts by weight or more, 300 parts by weight or more, 350 parts by weight or more, 400 parts by weight or more, 450 parts by weight or more, 500 parts by weight or more, or It may be included in more than 550 parts by weight, in addition, 600 parts by weight or less, 550 parts by weight or less, 500 parts by weight or less, 450 parts by weight or less, 400 parts by weight or less, 350 parts by weight or less, 300 parts by weight or less or 250 parts by weight or less It can be included as
- the composition may further include a liquid oily component of 0.0001 to 5% by weight based on the total weight of the composition.
- the content of the liquid oil component is 0.0001 wt% or more, 0.001 wt% or more, 0.01 wt% or more, 0.1 wt% or more, 0.5 wt% or more, 1 wt% or more, 1.5 wt% based on the total weight of the composition Or more, 2 wt% or more, 2.5 wt% or more, 3 wt% or more, 3.5 wt% or more, 4 wt% or more, or 4.5 wt% or more, and the content of the liquid oily component is 5 wt% based on the total weight of the composition Or less, 4.5% or less, 4% or less, 3.5% or less, 3% or less, 2.5% or less, 2% or less, 1.5% or less, 1% or less, 0.5% or less, 0.1% or less
- it may be 0.01%
- the cosmetic composition may be a skin moisturizing composition.
- the present invention provides a solid oily component; Thickener; And administering an effective amount of a low-viscosity cosmetic composition comprising polyol to a subject in need thereof.
- the present invention provides a solid oily component for preparing a skin moisturizing composition; Thickener; And combinations of polyols.
- the present invention provides a solid oily component for use in moisturizing skin; Thickener; And combinations of polyols.
- the present invention provides a solid oily component for moisturizing the skin; Thickener; And combinations of polyols.
- the cosmetic composition according to an aspect of the present invention may be blended with components contained in a general cosmetic composition as necessary.
- Other ingredients included include moisturizers, organic and inorganic pigments, ultraviolet absorbers, preservatives, fungicides, antioxidants, blockers, plant extracts, pH adjusters, pigments, flavors, coolants, and purified water.
- Low-viscosity cosmetic compositions of Examples 1 to 3 and Comparative Examples 1 to 3 having the composition of Table 1 below were prepared. Specifically, the raw materials of Table 1 were stirred at 80°C for 10 minutes using a homomixer, and then cooled and defoamed to 30°C to prepare a low-viscosity cosmetic composition of the essence formulation.
- Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 Disodium ID 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 glycerin 2.00 2.00 2.00 2.00 2.00 Propanediol 9.00 9.00 9.00 9.00 9.00 Alcohol 3.00 3.00 3.00 3.00 3.00 Cetiaryl Olivet*Sorbitan Olivet 2.00 4.00 - 5.00 - - Polyglyceryl-3 methyl glucose distearate - - 2.00 - - - Hydrogenated lecithin 1.00 2.00 1.00 - - - Shea butter - - - - 5.00 - Jojoba ester - - - - - 5.00 Acrylate/C10-30 alkyl acrylate cross polymer 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Hydroxyethyl acrylate/sodium acryloyl di
- the viscosity becomes too high, so that the formulation is immediately separated or the viscosity gradually increases over time, whereas when it is included by mixing two or more types, the viscosity is low over time. It was confirmed that the degree was maintained.
- the long-term stability was evaluated through a temperature stability test, which is a general preservation test. Specifically, the state change was measured until the 4th week by observing the change in the state of the sample over time by leaving the cosmetic at constant temperature conditions (room temperature, 45°C, 4°C, -15°C, cycle). Physically, it was confirmed that there were no changes such as separation, precipitation, aggregation, solidification, softening, and chemically there was no discoloration, fading, odor, crystal precipitation, and the like. The results are shown in Table 3 and Figure 1 below.
- Cosmetic composition of o/w (oil-in-water) formulation according to the composition of Example 1 and Table 4 according to the present invention (Comparative Example 4) and w/s (water-in- according to the composition of Table 5) The usability of the cosmetic composition of silicon) (Comparative Example 5) was evaluated. Specifically, for 9 women in their 30s and 40s, after using the cosmetic composition of Example 1, a sensory evaluation for spreadability and moisture was conducted, and satisfaction evaluation for spreadability and moisture was 1 respectively. It was evaluated as a high score as the point to 19-point scale method was applied lightly or neatly, and the spreadability was good or the moisture was excellent. The results are shown in Table 6 below.
- Example 1 by stably dispersing the solid oily component without the oil in a low-viscosity solubilizing formulation, it was confirmed that it exhibits excellent moisture feeling while being light or refreshed.
- the present invention can provide the following embodiments as an embodiment.
- the first embodiment includes a solid oily component; Thickener; And a polyol, wherein the solid oily component is included in an amount of 1 to 10% by weight based on the total weight of the composition, and the solid oily component is a mixture of two or more, and the composition has a viscosity of 10,000 cps or less, a low viscosity cosmetic composition. Can provide.
- the second embodiment can provide a low-viscosity cosmetic composition, characterized in that in the first embodiment, the solid oily component has a hydrophile-lipophile balance (HLB) of 8 to 13.
- HLB hydrophile-lipophile balance
- the solid oily component is lecithin; C16-18 alcohol; And C16-18 fatty acids, salts or derivatives thereof; It can provide a low-viscosity cosmetic composition, characterized in that two or more selected from.
- the derivative in one or more of the first to third embodiments, is a low-viscosity cosmetic composition, characterized in that the C16-18 fatty acid is synthesized with at least one of sugars and alcohols. Can provide.
- the C16-18 fatty acid, a salt thereof, or a derivative thereof is polyglyceryl-3 methylglucose distearate.
- the solid oily component is lecithin; And polyglyceryl-3 methylglucose distearate, cetearyl olivate/sorbitan olivate, and glyceryl stearate citrate. It characterized in that it comprises at least one selected; may provide a low-viscosity cosmetic composition.
- the seventh embodiment is characterized in that, in one or more of the first to sixth embodiments, each of the two or more solid oily ingredients is contained in an amount of 5% by weight or less based on the total weight of the composition. It is also possible to provide a cosmetic composition.
- the thickener is xanthan gum, cellulose gum, hydroxyethylcellulose, carob gum ( Ceratonia Siliqua Gum, Carbomer, Acrylate/C10-30 alkyl acrylate crosspolymer, Ammonium Acryloyldimethyltaurate/VP Copolymer ), and one or more selected from hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer, it is possible to provide a low-viscosity cosmetic composition.
- the ninth embodiment provides a low-viscosity cosmetic composition according to one or more of the first to eighth embodiments, wherein the thickener is included in an amount of 0.01 to 1% by weight based on the total weight of the composition. can do.
- the polyol is 1,3-butylene glycol, dipropylene glycol, propylene glycol (propylene glycol), 1,3-propanediol, glycerin, diglycerin, methylpropanediol, ethylhexanediol, 1,2-hexanediol It can provide a low-viscosity cosmetic composition, characterized in that at least one selected from (1,2-hexanediol) and pentylene glycol.
- the eleventh embodiment provides a low-viscosity cosmetic composition according to one or more of the first to tenth embodiments, wherein the polyol is included in an amount of 1 to 30% by weight based on the total weight of the composition.
- the polyol is included in an amount of 1 to 30% by weight based on the total weight of the composition.
- the twelfth embodiment can provide a low-viscosity cosmetic composition, wherein at least one of the first to eleventh embodiments has a viscosity of 5,000 cps or less.
- the thickener in at least one of the first to twelfth embodiments, with respect to 100 parts by weight of the solid oily component, the thickener is contained in 1 to 10 parts by weight, and the polyol is 200 to 600 parts by weight. It is possible to provide a low-viscosity cosmetic composition, which is characterized by being included as a part.
- the 14th embodiment provides a low-viscosity cosmetic composition according to at least one of the first to 13th embodiments, further comprising 0.0001 to 5% by weight of a liquid oily component based on the total weight of the composition.
- a liquid oily component based on the total weight of the composition.
- the 15th embodiment can provide a low-viscosity cosmetic composition, characterized in that the composition is for moisturizing the skin in one or more of the first to 14th embodiments.
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Abstract
Description
본 개시는 고체 유성 성분을 안정화한 저점도 화장료 조성물에 관한 것이다.The present disclosure relates to a low-viscosity cosmetic composition that stabilizes a solid oily component.
관련 출원에 대한 상호 참조Cross reference to related applications
본 출원은 2019년 1월 2일자로 출원된 대한민국 특허출원 제10-2019-0000201호에 대한 우선권을 주장하며, 그 출원 내용 전체가 본 출원에 참조로서 통합된다.This application claims priority to Korean Patent Application No. 10-2019-0000201 filed on January 2, 2019, the entire contents of which are incorporated herein by reference.
기초 화장품은 스킨, 에센스, 로션, 크림 등의 다양한 제형으로 분류가 되는데, 보통 오일과 같은 유성 성분의 함량이 높을수록 피부 보습 효과가 높아지는 것이 잘 알려져 있다. 스킨과 같이 수용성 성분이 대부분이고 오일은 들어가지 않거나 소량만 첨가하여 안정화시키는 투명 또는 반투명의 가용화 제형의 경우, 가볍고 산뜻한 사용감이 장점이지만 유화 제형만큼 보습력이 높거나 유연한 사용감이 나타나지 못하는 단점이 있다.Basic cosmetics are classified into various formulations such as skin, essence, lotion, and cream. It is well known that the higher the content of oily ingredients such as oil, the higher the moisturizing effect of the skin. In the case of a transparent or translucent solubilizing formulation that contains mostly water-soluble components such as skin and does not contain oil or is added in a small amount to stabilize it, it has the advantage of being light and refreshing, but it has the disadvantage of not showing a high moisturizing power or a flexible feeling as an emulsifying formulation.
따라서 이러한 가용화 제형에 있어서 유성 성분을 다량 함유시켜 가볍고 산뜻한 발림성의 장점은 유지하면서 피부 보습력을 높이고 차별화된 사용감을 구현하는 것이 중요하다. 그러나 이러한 투명 또는 반투명한 제형으로 제조되는 가용화 화장료 조성물에 유성 성분을 다량 안정화시키기 위해서는 이를 가용화시키기 위한 계면활성제 또는 점증제를 다량으로 사용해야 하고, 이러한 계면활성제 또는 점증제의 과다 사용은 끈적이거나 무거운 사용감을 초래하거나 피부 자극을 유발시키는 원인으로 작용할 수 있다.Therefore, in such a solubilizing formulation, it is important to increase the skin moisturizing power and realize a differentiated feeling of use while maintaining a merit of light and refreshing application by containing a large amount of oily ingredients. However, in order to stabilize a large amount of an oily component in a solubilized cosmetic composition prepared in such a transparent or translucent formulation, a large amount of a surfactant or thickener for solubilizing it must be used, and the excessive use of the surfactant or thickener is sticky or heavy feeling Or cause skin irritation.
[선행기술문헌][Advanced technical literature]
[특허문헌][Patent Document]
(특허문헌 1) 대한민국 공개특허공보 제10-2018-0120388호(Patent Document 1) Republic of Korea Patent Publication No. 10-2018-0120388
상기와 같은 문제점을 해결하기 위하여, 본 개시는 종래의 액상 형태의 유성 성분을 다량 함유시킨 제형과는 달리 실온에서 고체 상태로 존재하는 유성 성분을 저점도의 가용화 제형에 투명 또는 반투명하게 다량 안정화시킬 수 있고, 가용화 제형의 가볍고 산뜻한 사용감 및 유성 성분에 의한 우수한 피부 보습 효과를 모두 나타내는 저점도 화장료 조성물을 제공하고자 한다.In order to solve the above problems, the present disclosure, unlike conventional formulations containing a large amount of the oily component in a liquid form, transparently or translucently stabilizes the oily component present in a solid state at room temperature in a low viscosity solubilizing formulation. It is possible to provide a low-viscosity cosmetic composition that exhibits both a light and refreshing feeling of the solubilizing formulation and excellent skin moisturizing effect by oily ingredients.
상기한 목적을 달성하기 위하여, 본 개시는 일 실시예로서, 고체 유성 성분; 점증제; 및 폴리올을 포함하며, 상기 고체 유성 성분은 조성물 총 중량 대비 1 내지 10 중량%로 포함되고, 상기 고체 유성 성분은 2종 이상이 혼합된 것이며, 조성물의 점도가 10,000 cps 이하인, 저점도 화장료 조성물을 제공한다.In order to achieve the above object, the present disclosure is an embodiment, a solid oily component; Thickener; And a polyol, wherein the solid oily component is included in an amount of 1 to 10% by weight based on the total weight of the composition, and the solid oily component is a mixture of two or more types, and the viscosity of the composition is 10,000 cps or less. to provide.
본 개시의 일 실시예에 의한 저점도 화장료 조성물은, 실온에서 고체 상태인 유성 성분을 투명 또는 반투명한 저점도의 가용화 제형으로 안정화시킬 수 있다.The low-viscosity cosmetic composition according to an embodiment of the present disclosure can stabilize the oily component in a solid state at room temperature into a transparent or translucent low-viscosity solubilizing formulation.
또한, 본 개시의 일 실시예에 따르면, 제형의 투명성 및 경시 안정성이 우수하며, 유성 성분에 의한 우수한 피부 보습력을 나타내면서 저점도 가용화 제형에 따른 산뜻한 사용감을 구현할 수 있다.In addition, according to an embodiment of the present disclosure, the formulation has excellent transparency and aging stability, and exhibits excellent skin moisturizing power by oily components, and can realize a refreshing feeling of use according to a low-viscosity solubilizing formulation.
도 1은 본 개시의 일 실시예에 따른 실시예 1 및 3과 비교예 2 및 3의 외관을 나타낸 것이다.1 shows appearances of Examples 1 and 3 and Comparative Examples 2 and 3 according to an embodiment of the present disclosure.
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 명세서에서, "HLB(hydrophile-lipophile balance)"는 일반적인 계면활성제의 친수성-소수성의 비율로서, 각 원료가 안정하게 분산되기 위해 적합한 친수성과 소수성의 상대값을 의미한다. 상기 HLB는 0 내지 20의 수치를 통해 나타낼 수 있으며, 이의 수치가 낮을수록 소수성의 특징을 나타내며, 반대로 이의 수치가 높을수록 친수성의 특징을 나타낸다.As used herein, "hydrophile-lipophile balance" (HLB) is a ratio of the hydrophilicity-hydrophobicity of a general surfactant, and means a relative value of hydrophilicity and hydrophobicity suitable for stable dispersion of each raw material. The HLB may be represented by a value of 0 to 20, and the lower the value, the more hydrophobic the characteristic, whereas the higher the value, the more hydrophilic the characteristic.
본 명세서에서, "가용화(solubilization) 제형"은 다량의 수상에 유성 성분이 안정화된 투명 또는 반투명한 수중유(oil-in-water) 제형으로서, 유백색의 외관을 갖는 "유화 제형"과 구분되며, 가용화 제형은 투명 또는 반투명한 외관을 갖는다. 또한, "반투명 제형"은 빛이 작은 입자 상태로 안정화된 유성 성분에 의해 산란되어 흰색 또는 약간 푸른 빛을 띄는 것을 의미한다.In the present specification, "solubilization formulation" is a transparent or translucent oil-in-water formulation in which an oily component is stabilized in a large amount of water phase, and is distinguished from a "emulsifying formulation" having a milky white appearance, The solubilizing formulation has a transparent or translucent appearance. In addition, "translucent formulation" means that light is scattered by an oily component stabilized in a small particle state to give a white or slightly blue glow.
본 발명은 일 측면에서, 고체 유성 성분; 점증제; 및 폴리올을 포함하며, 상기 고체 유성 성분은 조성물 총 중량 대비 1 내지 10 중량%로 포함되고, 상기 고체 유성 성분은 2종 이상이 혼합된 것이며, 조성물의 점도가 10,000 cps 이하인, 저점도 화장료 조성물에 관한 것일 수 있다.The present invention, in one aspect, a solid oily component; Thickener; And a polyol, wherein the solid oily component is contained in an amount of 1 to 10% by weight based on the total weight of the composition, and the solid oily component is a mixture of two or more, and the viscosity of the composition is less than or equal to 10,000 cps. It may be about
일 구현 예로서, 상기 고체 유성 성분의 함량은 조성물 총 중량 대비 1 중량% 이상, 2 중량% 이상, 2.5 중량% 이상, 2.7 중량% 이상, 3 중량% 이상, 3.3 중량% 이상, 3.5 중량% 이상, 4 중량% 이상, 4.5 중량% 이상, 5 중량% 이상, 5.5 중량% 이상, 5.7 중량% 이상, 6 중량% 이상, 6.2 중량% 이상, 6.5 중량% 이상, 7 중량% 이상, 8 중량% 이상 또는 9 중량% 이상일 수 있으며, 또한, 상기 고체 유성 성분의 함량은 조성물 총 중량 대비 10 중량% 이하, 9 중량% 이하, 8 중량% 이하, 7 중량% 이하, 6.5 중량% 이하, 6.2 중량% 이하, 6 중량% 이하, 5.7 중량% 이하, 5.5 중량% 이하, 5 중량% 이하, 4.5 중량% 이하, 4 중량% 이하, 3.5 중량% 이하, 3.3 중량% 이하, 3 중량% 이하, 2.7 중량% 이하, 2.5 중량% 이하 또는 2 중량% 이하일 수 있다.As one embodiment, the content of the solid oil component is 1% by weight or more, 2% by weight or more, 2.5% by weight or more, 2.7% by weight or more, 3% by weight or more, 3.3% by weight or more, 3.5% by weight or more based on the total weight of the composition , 4% or more, 4.5% or more, 5% or more, 5.5% or more, 5.7% or more, 6% or more, 6.2% or more, 6.5% or more, 7% or more, 8% or more Or 9% by weight or more, and the content of the solid oily component is 10% by weight or less, 9% by weight or less, 8% by weight or less, 7% by weight or less, 6.5% by weight or less, 6.2% by weight or less based on the total weight of the composition , 6% or less, 5.7% or less, 5.5% or less, 5% or less, 4.5% or less, 4% or less, 3.5% or less, 3.3% or less, 3% or less, 2.7% or less , 2.5% by weight or less or 2% by weight or less.
일 구현 예로서, 상기 고체 유성 성분은 실온에서 고체 상태인 유성 성분으로서, HLB(hydrophile-lipophile balance)가 8 내지 13일 수 있다. 다른 구현 예로서, 상기 고체 유성 성분의 HLB는 8 이상, 9 이상, 10 이상, 11 이상 또는 12 이상일 수 있고, 또한, 13 이하, 12 이하, 11 이하, 10 이하 또는 9 이하일 수 있다. 바람직하게는, 상기 고체 유성 성분의 HLB는 10 내지 11일 수 있다.As an exemplary embodiment, the solid oily component is a solid oily component at room temperature, and may have a hydrophile-lipophile balance (HLB) of 8 to 13. As another embodiment, the HLB of the solid oily component may be 8 or more, 9 or more, 10 or more, 11 or more, or 12 or more, and may also be 13 or less, 12 or less, 11 or less, 10 or less, or 9 or less. Preferably, the HLB of the solid oily component may be 10 to 11.
일 구현 예로서, 상기 고체 유성 성분은 레시틴(lecithin); C16-18 알코올; 및 C16-18 지방산, 이의 염 또는 이의 유도체; 중에서 선택된 2종 이상일 수 있다. 이때 상기 유도체는 상기 C16-18 지방산이 폴리에칠렌글라이콜(polyethylene glycol), 글리세린, 당 및 인산기 중 적어도 하나 이상과 합성된 것일 수 있다.In one embodiment, the solid oily component is lecithin; C16-18 alcohol; And C16-18 fatty acids, salts or derivatives thereof; It may be two or more selected from. In this case, the derivative may be one in which the C16-18 fatty acid is synthesized with at least one of polyethylene glycol, glycerin, sugar, and phosphoric acid groups.
일 구현 예로서, 상기 C16-18 지방산, 이의 염 또는 이의 유도체는, 폴리글리세릴-3 메틸글루코스 디스테아레이트(polyglyceryl-3 methylglucose distearate), 세테아릴 올리베이트/소르비탄 올리베이트(cetearyl olivate/sorbitan olivate), 및 글리세릴 스테아레이트 시트레이트(glyceryl stearate citrate)에서 선택되는 하나 이상일 수 있다.As an exemplary embodiment, the C16-18 fatty acid, a salt thereof, or a derivative thereof, polyglyceryl-3 methylglucose distearate, cetearyl oleate/sorbitan oleate (cetearyl olivate/ sorbitan olivate), and glyceryl stearate citrate.
다른 구현 예로서, 상기 고체 유성 성분은 레시틴; 및 폴리글리세릴-3 메틸글루코스 디스테아레이트(polyglyceryl-3 methylglucose distearate), 세테아릴 올리베이트/소르비탄 올리베이트(cetearyl olivate/sorbitan olivate), 및 글리세릴 스테아레이트 시트레이트(glyceryl stearate citrate) 중에서 선택된 적어도 하나 이상;을 포함할 수 있다. 또 다른 구현 예로서, 상기 레시틴은 하이드로제네이티드 레시틴(hydrogenated lecithin)일 수 있다.In another embodiment, the solid oily component comprises lecithin; And polyglyceryl-3 methylglucose distearate, cetearyl olivate/sorbitan olivate, and glyceryl stearate citrate. It may include at least one selected. As another exemplary embodiment, the lecithin may be hydrogenated lecithin.
다른 구현 예로서, 상기 2종 이상의 고체 유성 성분 각각은 조성물 전체 중량에 대하여 5 중량% 이하의 양으로 포함될 수 있다. 예를 들어, 상기 2 종 이상의 고체 유성 성분 각각은 조성물 전체 중량에 대하여 5 중량% 이하, 4 중량% 이하, 3 중량% 이하 또는 2 중량% 이하의 양으로 포함될 수 있으며, 또한, 1 중량% 이상, 2 중량% 이상, 3 중량% 이상 또는 4 중량% 이상의 양으로 포함될 수 있다. 즉, 각각 5 중량% 이하의 양으로 포함되는 고체 유성 성분 2종 이상을 혼합하여 고체 유성 성분을 조성물 전체 중량에 대하여 총 10 중량% 이하의 양으로 포함할 수 있다.As another embodiment, each of the two or more solid oily components may be included in an amount of 5% by weight or less based on the total weight of the composition. For example, each of the two or more solid oily components may be included in an amount of 5% by weight or less, 4% by weight or less, 3% by weight or less, or 2% by weight or less based on the total weight of the composition. , 2% by weight or more, 3% by weight or more, or 4% by weight or more. That is, two or more solid oily components included in an amount of 5 wt% or less may be mixed to include the solid oily component in an amount of 10 wt% or less based on the total weight of the composition.
일 구현 예로서, 상기 점증제는 잔탄검(xanthan gum), 셀룰로오스검(cellulose gum), 하이드록시에틸셀룰로오스(hydroxyethylcellulose), 캐롭검(Ceratonia Siliqua Gum), 카보머(carbomer), 아크릴레이트/C10-30알킬아크릴레이트크로스폴리머(acrylates/c10-30 alkyl acrylate crosspolymer), 암모늄아크릴로일디메틸타우레이트/브이피코폴리머(Ammonium Acryloyldimethyltaurate/VP Copolymer), 및 하이드록시에틸아크릴레이트/소듐아크릴로일다이메틸타우레이트코폴리머(hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer) 중에서 선택된 1종 이상일 수 있다.In one embodiment, the thickener is xanthan gum (xanthan gum), cellulose gum (cellulose gum), hydroxyethylcellulose (hydroxyethylcellulose), carob gum (Ceratonia Siliqua Gum), carbomer (carbomer), acrylate /C10- 30 acrylates/c10-30 alkyl acrylate crosspolymer, Ammonium Acryloyldimethyltaurate/VP Copolymer, and hydroxyethyl acrylate/sodium acryloyl dimethyltau It may be at least one selected from hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer.
일 구현 예로서, 목적하는 효과를 위하여, 상기 점증제는 조성물 총 중량 대비 0.01 내지 1 중량%의 양으로 포함될 수 있다. 다른 구현 예로서, 상기 점증제의 함량은 조성물 총 중량 대비 0.01 중량% 이상, 0.03 중량% 이상, 0.05 중량% 이상, 0.07 중량% 이상, 0.09 중량% 이상, 0.1 중량% 이상, 0.15 중량% 이상, 0.2 중량% 이상, 0.25 중량% 이상, 0.3 중량% 이상, 0.35 중량% 이상, 0.4 중량% 이상, 0.45 중량% 이상, 0.5 중량% 이상, 0.6 중량% 이상, 0.7 중량% 이상, 0.8 중량% 이상 또는 0.9 중량% 이상일 수 있으며, 또한, 상기 점증제의 함량은 조성물 총 중량 대비 1 중량% 이하, 0.9 중량% 이하, 0.8 중량% 이하, 0.7 중량% 이하, 0.6 중량% 이하, 0.5 중량% 이하, 0.45 중량% 이하, 0.4 중량% 이하, 0.35 중량% 이하, 0.3 중량% 이하, 0.25 중량% 이하, 0.2 중량% 이하, 0.15 중량% 이하, 0.1 중량% 이하, 0.09 중량% 이하, 0.07 중량% 이하, 0.05 중량% 이하 또는 0.03 중량% 이하일 수 있다.As an embodiment, for the desired effect, the thickener may be included in an amount of 0.01 to 1% by weight based on the total weight of the composition. As another embodiment, the content of the thickener is 0.01 wt% or more, 0.03 wt% or more, 0.05 wt% or more, 0.07 wt% or more, 0.09 wt% or more, 0.1 wt% or more, 0.15 wt% or more, based on the total weight of the composition, 0.2% or more, 0.25% or more, 0.3% or more, 0.35% or more, 0.4% or more, 0.45% or more, 0.5% or more, 0.6% or more, 0.7% or more, 0.8% or more, or It may be 0.9% by weight or more, and the content of the thickener is 1% by weight or less, 0.9% by weight or less, 0.8% by weight or less, 0.7% by weight or less, 0.6% by weight or less, 0.5% by weight or less, 0.45 based on the total weight of the composition Weight% or less, 0.4% or less, 0.35% or less, 0.3% or less, 0.25% or less, 0.2% or less, 0.15% or less, 0.1% or less, 0.09% or less, 0.07% or less, 0.05 It may be less than or equal to 0.03% by weight.
일 구현 예로서, 상기 폴리올은 1,3-부틸렌글리콜(1,3-butylene glycol), 디프로필렌글리콜(dipropylene glycol), 프로필렌글리콜(propylene glycol), 1,3-프로판디올(1,3-propanediol), 글리세린(glycerin), 디글리세린(diglycerin), 메틸프로판디올(methylpropanediol), 에틸헥산디올(ethylhexanediol), 1,2-헥산디올(1,2-hexanediol) 및 펜틸렌글리콜(pentylene glycol)로 이루어진 군으로부터 선택되는 1종 이상 일 수 있다.In one embodiment, the polyol is 1,3-butylene glycol (1,3-butylene glycol), dipropylene glycol (dipropylene glycol), propylene glycol (propylene glycol), 1,3-propanediol (1,3- Propanediol, glycerin, diglycerin, methylpropanediol, ethylhexanediol, 1,2-hexanediol, and pentylene glycol It may be one or more selected from the group consisting of.
일 구현 예로서, 목적하는 효과를 위하여, 상기 폴리올은 조성물 총 중량 대비 1 내지 30 중량%의 양으로 포함될 수 있다. 다른 구현 예로서, 상기 폴리올의 함량은 조성물 총 중량 대비 1 중량% 이상, 5 중량% 이상, 7 중량% 이상, 10 중량% 이상, 12 중량% 이상, 15 중량% 이상, 18 중량% 이상, 20 중량% 이상, 25 중량% 이상 또는 27 중량% 이상일 수 있으며, 또한, 상기 폴리올의 함량은 조성물 총 중량 대비 30 중량% 이하, 27 중량% 이하, 25 중량% 이하, 20 중량% 이하, 18 중량% 이하, 15 중량% 이하, 12 중량% 이하, 10 중량% 이하, 7 중량% 이하 또는 5 중량% 이하일 수 있다. 바람직하게는 상기 폴리올은 조성물 총 중량 대비 5 내지 30 중량%의 양으로 포함될 수 있다.As an embodiment, for the desired effect, the polyol may be included in an amount of 1 to 30% by weight based on the total weight of the composition. As another embodiment, the content of the polyol is 1 wt% or more, 5 wt% or more, 7 wt% or more, 10 wt% or more, 12 wt% or more, 15 wt% or more, 18 wt% or more, 20 based on the total weight of the composition It may be at least 25% by weight, at least 25% by weight, or at least 27% by weight, and the content of the polyol is 30% by weight or less, 27% by weight or less, 25% by weight or less, 20% by weight or less, 18% by weight based on the total weight of the composition Or less, 15 wt% or less, 12 wt% or less, 10 wt% or less, 7 wt% or less, or 5 wt% or less. Preferably, the polyol may be included in an amount of 5 to 30% by weight based on the total weight of the composition.
일 구현 예로서, 상기 조성물은 점도가 10,000 cps 이하일 수 있다. 구체적으로, 상기 조성물의 점도는 10,000 cps 이하, 9,000 cps 이하, 8,000 cps 이하, 7,000 cps 이하, 6,900 cps 이하, 6,700 cps 이하, 6,500 cps 이하, 6,300 cps 이하, 6,000 cps 이하, 5,600 cps 이하, 5,300 cps 이하, 5,000 cps 이하, 4,500 cps 이하, 4,000 cps 이하, 3,500 cps 이하일 수 있으며, 또한, 상기 조성물의 점도는 20 cps 이상, 100 cps 이상, 500 cps 이상, 1,000 cps 이상, 2,000 cps 이상, 3,000 cps 이상, 3,500 cps 이상, 4,000 cps 이상 또는 4,500 cps 이상일 수 있다. 바람직하게는 상기 조성물은 점도가 5,000 cps 이하일 수 있다.As an example embodiment, the composition may have a viscosity of 10,000 cps or less. Specifically, the viscosity of the composition is 10,000 cps or less, 9,000 cps or less, 8,000 cps or less, 7,000 cps or less, 6,900 cps or less, 6,700 cps or less, 6,500 cps or less, 6,300 cps or less, 6,000 cps or less, 5,600 cps or less, 5,300 cps or less Below, 5,000 cps or less, 4,500 cps or less, 4,000 cps or less, 3,500 cps or less, and the viscosity of the composition is 20 cps or more, 100 cps or more, 500 cps or more, 1,000 cps or more, 2,000 cps or more, 3,000 cps or more , 3,500 cps or more, 4,000 cps or more, or 4,500 cps or more. Preferably, the composition may have a viscosity of 5,000 cps or less.
일 구현 예로서, 상기 고체 유성 성분 100 중량부에 대하여, 상기 점증제는 1 내지 10 중량부로 포함되고, 상기 폴리올은 200 내지 600 중량부로 포함될 수 있다. 다른 구현 예로서, 상기 고체 유성 성분 100 중량부에 대하여, 상기 점증제는 1 중량부 이상, 2 중량부 이상, 3 중량부 이상, 4 중량부 이상, 5 중량부 이상, 6 중량부 이상, 7 중량부 이상, 8 중량부 이상 또는 9 중량부 이상으로 포함될 수 있으며, 또한, 10 중량부 이하, 9 중량부 이하, 8 중량부 이하, 7 중량부 이하, 6 중량부 이하, 5 중량부 이하, 4 중량부 이하, 3 중량부 이하 또는 2 중량부 이하로 포함될 수 있다.As an embodiment, the solid oil component 100 parts by weight, the thickener may be included in 1 to 10 parts by weight, the polyol may be included in 200 to 600 parts by weight. As another embodiment, with respect to 100 parts by weight of the solid oil component, the thickener is 1 part by weight or more, 2 parts by weight or more, 3 parts by weight or more, 4 parts by weight or more, 5 parts by weight or more, 6 parts by weight or more, 7 More than 8 parts by weight, or more than 9 parts by weight, or more, 10 parts by weight or less, 9 parts by weight or less, 8 parts by weight or less, 7 parts by weight or less, 6 parts by weight or less, 5 parts by weight or less, 4 parts by weight or less, 3 parts by weight or less, or 2 parts by weight or less.
또한, 상기 고체 유성 성분 100 중량부에 대하여, 상기 폴리올은 200 중량부 이상, 250 중량부 이상, 300 중량부 이상, 350 중량부 이상, 400 중량부 이상, 450 중량부 이상, 500 중량부 이상 또는 550 중량부 이상으로 포함될 수 있으며, 또한, 600 중량부 이하, 550 중량부 이하, 500 중량부 이하, 450 중량부 이하, 400 중량부 이하, 350 중량부 이하, 300 중량부 이하 또는 250 중량부 이하로 포함될 수 있다.In addition, with respect to 100 parts by weight of the solid oil component, the polyol is 200 parts by weight or more, 250 parts by weight or more, 300 parts by weight or more, 350 parts by weight or more, 400 parts by weight or more, 450 parts by weight or more, 500 parts by weight or more, or It may be included in more than 550 parts by weight, in addition, 600 parts by weight or less, 550 parts by weight or less, 500 parts by weight or less, 450 parts by weight or less, 400 parts by weight or less, 350 parts by weight or less, 300 parts by weight or less or 250 parts by weight or less It can be included as
다른 구현 예로서, 상기 조성물은 조성물 총 중량 대비 0.0001 내지 5 중량%의 액상 유성 성분을 더 포함할 수 있다. 또 다른 구현 예로서, 상기 액상 유성 성분의 함량은 조성물 총 중량 대비 0.0001 중량% 이상, 0.001 중량% 이상, 0.01 중량% 이상, 0.1 중량% 이상, 0.5 중량% 이상, 1 중량% 이상, 1.5 중량% 이상, 2 중량% 이상, 2.5 중량% 이상, 3 중량% 이상, 3.5 중량% 이상, 4 중량% 이상 또는 4.5 중량% 이상일 수 있으며, 또한, 상기 액상 유성 성분의 함량은 조성물 총 중량 대비 5 중량% 이하, 4.5 중량% 이하, 4 중량% 이하, 3.5 중량% 이하, 3 중량% 이하, 2.5 중량% 이하, 2 중량% 이하, 1.5 중량% 이하, 1 중량% 이하, 0.5 중량% 이하, 0.1 중량% 이하, 0.01 중량% 이하 또는 0.001 중량% 이하일 수 있다.As another embodiment, the composition may further include a liquid oily component of 0.0001 to 5% by weight based on the total weight of the composition. As another embodiment, the content of the liquid oil component is 0.0001 wt% or more, 0.001 wt% or more, 0.01 wt% or more, 0.1 wt% or more, 0.5 wt% or more, 1 wt% or more, 1.5 wt% based on the total weight of the composition Or more, 2 wt% or more, 2.5 wt% or more, 3 wt% or more, 3.5 wt% or more, 4 wt% or more, or 4.5 wt% or more, and the content of the liquid oily component is 5 wt% based on the total weight of the composition Or less, 4.5% or less, 4% or less, 3.5% or less, 3% or less, 2.5% or less, 2% or less, 1.5% or less, 1% or less, 0.5% or less, 0.1% or less Hereinafter, it may be 0.01% by weight or less or 0.001% by weight or less.
일 구현 예로서, 상기 화장료 조성물은 피부 보습용 조성물일 수 있다.As an embodiment, the cosmetic composition may be a skin moisturizing composition.
본 발명은 다른 측면에서, 고체 유성 성분; 점증제; 및 폴리올을 포함하는 저점도 화장료 조성물의 유효량을 이를 필요로 하는 대상체에게 투여하는 단계를 포함하는, 피부 보습 방법에 관한 것일 수 있다.In another aspect, the present invention provides a solid oily component; Thickener; And administering an effective amount of a low-viscosity cosmetic composition comprising polyol to a subject in need thereof.
본 발명은 또 다른 측면에서, 피부 보습용 조성물을 제조하기 위한, 고체 유성 성분; 점증제; 및 폴리올의 조합의 용도에 관한 것일 수 있다.In another aspect, the present invention provides a solid oily component for preparing a skin moisturizing composition; Thickener; And combinations of polyols.
본 발명은 또 다른 측면에서, 피부 보습 용도로 사용하기 위한, 고체 유성 성분; 점증제; 및 폴리올의 조합에 관한 것일 수 있다.In another aspect, the present invention provides a solid oily component for use in moisturizing skin; Thickener; And combinations of polyols.
본 발명은 또 다른 측면에서, 피부 보습을 위한, 고체 유성 성분; 점증제; 및 폴리올의 조합의 용도에 관한 것일 수 있다.In another aspect, the present invention provides a solid oily component for moisturizing the skin; Thickener; And combinations of polyols.
본 발명의 일 측면에 따른 상기 화장료 조성물은 필요에 따라 일반적인 화장료 조성물에 포함되는 성분을 배합해도 된다. 이외에 포함되는 배합 성분으로는 보습제, 유기 및 무기 안료, 자외선 흡수제, 방부제, 살균제, 산화 방지제, 봉쇄제, 식물 추출물, pH 조절제, 색소, 향료, 냉감제, 정제수 등을 들 수 있다.The cosmetic composition according to an aspect of the present invention may be blended with components contained in a general cosmetic composition as necessary. Other ingredients included include moisturizers, organic and inorganic pigments, ultraviolet absorbers, preservatives, fungicides, antioxidants, blockers, plant extracts, pH adjusters, pigments, flavors, coolants, and purified water.
이하, 본 발명의 내용을 실시예 및 시험예를 통하여 보다 구체적으로 설명한다. 그러나, 이러한 실시예 및 시험예는 본 발명의 내용을 이해하기 위해 제시되는 것일 뿐, 본 발명의 권리범위가 이러한 실시예 및 시험예로 한정되는 것은 아니고, 당업계에서 통상적으로 주지된 변형, 치환 및 삽입 등을 수행할 수 있으며, 이에 대한 것도 본 발명의 범위에 포함된다.Hereinafter, the contents of the present invention will be described in more detail through examples and test examples. However, these examples and test examples are only presented to understand the contents of the present invention, the scope of the present invention is not limited to these examples and test examples, and modifications and substitutions commonly known in the art And insertion, and the like is also included in the scope of the present invention.
[실시예 및 비교예][Examples and Comparative Examples]
하기 표 1의 조성을 갖는 실시예 1 내지 3 및 비교예 1 내지 3의 저점도 화장료 조성물을 제조하였다. 구체적으로, 하기 표 1의 원료 물질들을 80℃에서 호모믹서를 이용하여 10분 동안 교반시킨 다음, 30℃로 냉각 및 탈포시켜 에센스 제형의 저점도 화장료 조성물을 제조하였다.Low-viscosity cosmetic compositions of Examples 1 to 3 and Comparative Examples 1 to 3 having the composition of Table 1 below were prepared. Specifically, the raw materials of Table 1 were stirred at 80°C for 10 minutes using a homomixer, and then cooled and defoamed to 30°C to prepare a low-viscosity cosmetic composition of the essence formulation.
[시험예 1] 점도 변화 평가[Test Example 1] Evaluation of viscosity change
상기 실시예 1 내지 3 및 비교예 1 내지 3에 대하여 경시적으로 점도의 변화가 없는지 평가하였다. 구체적으로, 1주일 간격으로 4주 동안 브룩필드 점도계(Brookfield LVDV-II+PRO)를 이용하여 스핀들 번호 3, 회전수 12 rpm의 조건에서 2분 동안 각 조성물의 점도를 측정하였다. 그 결과는 하기 표 2에 나타내었다.For Examples 1 to 3 and Comparative Examples 1 to 3, it was evaluated whether there was no change in viscosity over time. Specifically, the viscosity of each composition was measured for 2 minutes under conditions of spindle number 3 and rotation speed of 12 rpm using a Brookfield viscometer (Brookfield LVDV-II+PRO) for 4 weeks at intervals of 1 week. The results are shown in Table 2 below.
상기 표 2의 결과로부터, 본 발명에 따른 고체 유성 성분을 2종 혼합하여 포함하는 실시예 1 내지 3의 경우, 장기간 저점도가 유지되는 반면, 본 발명에 따른 고체 유성 성분을 1종만 단독으로 5 중량% 포함하는 비교예 1의 경우, 점도가 10,000 cps 이상으로서, 특히 4주 이후에는 15,000 cps 이상으로 증가하여 저점도 제형으로 구현되지 않는 것을 확인할 수 있었다. 또한, 비교예 2 및 3의 경우에는, 제조 직후 제형이 분리되어 점도 측정이 불가하였다.From the results of Table 2, in the case of Examples 1 to 3 comprising two types of solid oily components according to the present invention, long-term low viscosity is maintained, while only one solid oily component according to the present invention is 5 alone. In the case of Comparative Example 1 containing weight%, it was confirmed that the viscosity is 10,000 cps or more, particularly after 4 weeks, to 15,000 cps or more, and thus is not implemented as a low-viscosity formulation. In addition, in the case of Comparative Examples 2 and 3, the formulation was separated immediately after preparation, and viscosity measurement was impossible.
즉, 본 발명에 따른 고체 유성 성분을 1종만 포함할 경우에는 점도가 너무 높아져 제형이 곧바로 분리되거나, 경시적으로 점도가 점차 증가하게 되는 반면, 2종 이상 혼합하여 포함할 경우에는 경시적으로 저점도가 유지되는 것을 확인할 수 있었다.That is, when only one type of the solid oily component according to the present invention is included, the viscosity becomes too high, so that the formulation is immediately separated or the viscosity gradually increases over time, whereas when it is included by mixing two or more types, the viscosity is low over time. It was confirmed that the degree was maintained.
[시험예 2] 장기 안정도 평가[Test Example 2] Long-term stability evaluation
상기 실시예 1 내지 3 및 비교예 1 내지 3에 대하여 장기 안정도를 평가하였다. 장기안정도 평가는 일반적인 보존시험인 온도 안정성 시험을 통하여 평가하였다. 구체적으로, 화장품을 일정한 온도조건(실온, 45℃, 4℃, -15℃, cycle)에 방치하여 시간 경과에 따른 시료의 상태변화에 대하여 관찰하는 방법으로 4주차까지 상태변화를 측정하였다. 물리적으로는 분리, 침전, 응집, 고화, 연화 등의 변화가 없는지 확인하였으며, 화학적으로 변색, 퇴색, 변취, 결정 석출 등이 없는지 확인하였다. 그 결과는 하기 표 3 및 도 1에 나타내었다.Long-term stability was evaluated for Examples 1 to 3 and Comparative Examples 1 to 3. The long-term stability was evaluated through a temperature stability test, which is a general preservation test. Specifically, the state change was measured until the 4th week by observing the change in the state of the sample over time by leaving the cosmetic at constant temperature conditions (room temperature, 45°C, 4°C, -15°C, cycle). Physically, it was confirmed that there were no changes such as separation, precipitation, aggregation, solidification, softening, and chemically there was no discoloration, fading, odor, crystal precipitation, and the like. The results are shown in Table 3 and Figure 1 below.
상기 표 3 및 도 1의 결과로부터, 본 발명에 따른 고체 유성 성분을 2종 이상 혼합하여 특정 함량 범위로 포함하는 실시예 1 내지 3의 경우 경시적으로 안정도의 변화가 없이 불투명한 외관이 유지되는 반면, 유성 성분으로서 쉐어버터 또는 호호바 에스터를 포함하는 비교예 2 및 3의 경우, 제조 직후 하얗게 석출되어 분리되는 현상이 나타나는 것을 확인할 수 있었다. 한편, 비교예 1의 경우 장기 안정도는 문제가 없었으나, 상기 시험예 1의 결과로부터 점도가 너무 높아 저점도 제형으로 구현되지 않는 것을 확인하였다.From the results of Table 3 and Figure 1, in the case of Examples 1 to 3 containing a specific content range by mixing two or more solid oily components according to the present invention, the opaque appearance is maintained without a change in stability over time. On the other hand, in the case of Comparative Examples 2 and 3 containing a shea butter or jojoba ester as an oily component, it was confirmed that a phenomenon of white precipitation and separation immediately after production was observed. On the other hand, in the case of Comparative Example 1, long-term stability was not a problem, but it was confirmed from the results of Test Example 1 that the viscosity was too high to be implemented as a low-viscosity formulation.
[시험예 3] 사용감 평가[Test Example 3] Evaluation of usability
본 발명에 따른 상기 실시예 1과 하기 표 4의 조성에 따른 o/w(oil-in-water) 제형의 화장료 조성물(비교예 4) 및 표 5의 조성에 따른 w/s(water-in-silicon) 제형의 화장료 조성물(비교예 5)의 사용감을 평가하였다. 구체적으로, 30-40대의 여성 9명을 대상으로, 상기 실시예 1의 화장료 조성물을 사용하게 한 후, 펴발림성 및 수분감에 대한 관능평가를 실시하였으며, 펴발림성 및 수분감에 대한 만족도 평가는 각각 1 점 내지 19점 척도법으로 가볍거나 산뜻하게 발려 펴발림성이 좋거나 수분감이 뛰어날수록 높은 점수로 평가하도록 하였다. 그 결과는 하기 표 6에 나타내었다.Cosmetic composition of o/w (oil-in-water) formulation according to the composition of Example 1 and Table 4 according to the present invention (Comparative Example 4) and w/s (water-in- according to the composition of Table 5) The usability of the cosmetic composition of silicon) (Comparative Example 5) was evaluated. Specifically, for 9 women in their 30s and 40s, after using the cosmetic composition of Example 1, a sensory evaluation for spreadability and moisture was conducted, and satisfaction evaluation for spreadability and moisture was 1 respectively. It was evaluated as a high score as the point to 19-point scale method was applied lightly or neatly, and the spreadability was good or the moisture was excellent. The results are shown in Table 6 below.
상기 표 6의 결과로부터, 기존의 일반 유화 제형에 해당하는 비교예 4 및 비교예 5의 경우, 오일 종류의 액상 유성 성분을 다량 분산시킴으로써, 실시예 1에 비하여 펴발림성과 수분감이 떨어지는 것을 확인할 수 있었다.From the results of Table 6, in the case of Comparative Examples 4 and 5 corresponding to the conventional general emulsion formulation, by dispersing a large amount of the liquid oily component of the oil type, it can be confirmed that the spreadability and moisture drop compared to Example 1 there was.
반면, 본 발명에 따른 실시예 1의 경우, 오일을 포함하지 않고 고체 유성 성분을 저점도의 가용화 제형에 안정적으로 분산시킴으로써, 가볍거나 산뜻하게 발리면서 뛰어난 수분감을 나타내는 것을 확인할 수 있었다.On the other hand, in the case of Example 1 according to the present invention, by stably dispersing the solid oily component without the oil in a low-viscosity solubilizing formulation, it was confirmed that it exhibits excellent moisture feeling while being light or refreshed.
본 발명은 일 실시예로서 다음의 실시형태들을 제공할 수 있다.The present invention can provide the following embodiments as an embodiment.
제1 실시형태는, 고체 유성 성분; 점증제; 및 폴리올을 포함하며, 상기 고체 유성 성분은 조성물 총 중량 대비 1 내지 10 중량%로 포함되고, 상기 고체 유성 성분은 2종 이상이 혼합된 것이며, 조성물의 점도가 10,000 cps 이하인, 저점도 화장료 조성물을 제공할 수 있다.The first embodiment includes a solid oily component; Thickener; And a polyol, wherein the solid oily component is included in an amount of 1 to 10% by weight based on the total weight of the composition, and the solid oily component is a mixture of two or more, and the composition has a viscosity of 10,000 cps or less, a low viscosity cosmetic composition. Can provide.
제2 실시형태는, 제1 실시형태에 있어서, 상기 고체 유성 성분은 HLB(hydrophile-lipophile balance)가 8 내지 13인 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.The second embodiment can provide a low-viscosity cosmetic composition, characterized in that in the first embodiment, the solid oily component has a hydrophile-lipophile balance (HLB) of 8 to 13.
제3 실시형태는, 제1 실시형태 및 제2 실시형태 중 하나 이상에 있어서, 상기 고체 유성 성분은 레시틴(lecithin); C16-18 알코올; 및 C16-18 지방산, 이의 염 또는 이의 유도체; 중에서 선택된 2종 이상인 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.In a third embodiment, in at least one of the first embodiment and the second embodiment, the solid oily component is lecithin; C16-18 alcohol; And C16-18 fatty acids, salts or derivatives thereof; It can provide a low-viscosity cosmetic composition, characterized in that two or more selected from.
제4 실시형태는, 제1 실시형태 내지 제3 실시형태 중 하나 이상에 있어서, 상기 유도체는 상기 C16-18 지방산이 당 및 알코올 중 적어도 하나 이상과 합성된 것임을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.In a fourth embodiment, in one or more of the first to third embodiments, the derivative is a low-viscosity cosmetic composition, characterized in that the C16-18 fatty acid is synthesized with at least one of sugars and alcohols. Can provide.
제5 실시형태는, 제1 실시형태 내지 제4 실시형태 중 하나 이상에 있어서, 상기 C16-18 지방산, 이의 염 또는 이의 유도체는, 폴리글리세릴-3 메틸글루코스 디스테아레이트(polyglyceryl-3 methylglucose distearate), 세테아릴 올리베이트/소르비탄 올리베이트(cetearyl olivate/sorbitan olivate), 및 글리세릴 스테아레이트 시트레이트(glyceryl stearate citrate)에서 선택되는 하나 이상인 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.In the fifth embodiment, in at least one of the first to fourth embodiments, the C16-18 fatty acid, a salt thereof, or a derivative thereof is polyglyceryl-3 methylglucose distearate. ), one or more selected from cetearyl oleate/sorbitan olivate, and glyceryl stearate citrate, to provide a low-viscosity cosmetic composition. have.
제6 실시형태는, 제1 실시형태 내지 제5 실시형태 중 하나 이상에 있어서, 상기 고체 유성 성분은 레시틴; 및 폴리글리세릴-3 메틸글루코스 디스테아레이트(polyglyceryl-3 methylglucose distearate), 세테아릴 올리베이트/소르비탄 올리베이트(cetearyl olivate/sorbitan olivate), 및 글리세릴 스테아레이트 시트레이트(glyceryl stearate citrate) 중에서 선택된 적어도 하나 이상;을 포함하는 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.In the sixth embodiment, in at least one of the first to fifth embodiments, the solid oily component is lecithin; And polyglyceryl-3 methylglucose distearate, cetearyl olivate/sorbitan olivate, and glyceryl stearate citrate. It characterized in that it comprises at least one selected; may provide a low-viscosity cosmetic composition.
제7 실시형태는, 제1 실시형태 내지 제6 실시형태 중 하나 이상에 있어서, 상기 2종 이상의 고체 유성 성분 각각은 조성물 전체 중량에 대하여 5 중량% 이하의 양으로 포함되는 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.The seventh embodiment is characterized in that, in one or more of the first to sixth embodiments, each of the two or more solid oily ingredients is contained in an amount of 5% by weight or less based on the total weight of the composition. It is also possible to provide a cosmetic composition.
제8 실시형태는, 제1 실시형태 내지 제7 실시형태 중 하나 이상에 있어서, 상기 점증제는 잔탄검(xanthan gum), 셀룰로오스검(cellulose gum), 하이드록시에틸셀룰로오스(hydroxyethylcellulose), 캐롭검(Ceratonia Siliqua Gum), 카보머(carbomer), 아크릴레이트/C10-30알킬아크릴레이트크로스폴리머(acrylates/c10-30 alkyl acrylate crosspolymer), 암모늄아크릴로일디메틸타우레이트/브이피코폴리머(Ammonium Acryloyldimethyltaurate/VP Copolymer), 및 하이드록시에틸아크릴레이트/소듐아크릴로일다이메틸타우레이트코폴리머(hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer) 중에서 선택된 1종 이상인 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.In the eighth embodiment, in one or more of the first to seventh embodiments, the thickener is xanthan gum, cellulose gum, hydroxyethylcellulose, carob gum ( Ceratonia Siliqua Gum, Carbomer, Acrylate/C10-30 alkyl acrylate crosspolymer, Ammonium Acryloyldimethyltaurate/VP Copolymer ), and one or more selected from hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer, it is possible to provide a low-viscosity cosmetic composition.
제9 실시형태는, 제1 실시형태 내지 제8 실시형태 중 하나 이상에 있어서, 상기 점증제는 조성물 총 중량 대비 0.01 내지 1 중량%의 양으로 포함되는 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.The ninth embodiment provides a low-viscosity cosmetic composition according to one or more of the first to eighth embodiments, wherein the thickener is included in an amount of 0.01 to 1% by weight based on the total weight of the composition. can do.
제10 실시형태는, 제1 실시형태 내지 제9 실시형태 중 하나 이상에 있어서, 상기 폴리올은 1,3-부틸렌글리콜(1,3-butylene glycol), 디프로필렌글리콜(dipropylene glycol), 프로필렌글리콜(propylene glycol), 1,3-프로판디올(1,3-propanediol), 글리세린(glycerin), 디글리세린(diglycerin), 메틸프로판디올(methylpropanediol), 에틸헥산디올(ethylhexanediol), 1,2-헥산디올(1,2-hexanediol) 및 펜틸렌글리콜(pentylene glycol) 중에서 선택된 1종 이상인 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.In the tenth embodiment, in one or more of the first to ninth embodiments, the polyol is 1,3-butylene glycol, dipropylene glycol, propylene glycol (propylene glycol), 1,3-propanediol, glycerin, diglycerin, methylpropanediol, ethylhexanediol, 1,2-hexanediol It can provide a low-viscosity cosmetic composition, characterized in that at least one selected from (1,2-hexanediol) and pentylene glycol.
제11 실시형태는, 제1 실시형태 내지 제10 실시형태 중 하나 이상에 있어서, 상기 폴리올은 조성물 총 중량 대비 1 내지 30 중량%의 양으로 포함되는 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.The eleventh embodiment provides a low-viscosity cosmetic composition according to one or more of the first to tenth embodiments, wherein the polyol is included in an amount of 1 to 30% by weight based on the total weight of the composition. Can.
제12 실시형태는, 제1 실시형태 내지 제11 실시형태 중 하나 이상에 있어서, 상기 조성물은 점도가 5,000 cps 이하인 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.The twelfth embodiment can provide a low-viscosity cosmetic composition, wherein at least one of the first to eleventh embodiments has a viscosity of 5,000 cps or less.
제13 실시형태는, 제1 실시형태 내지 제12 실시형태 중 하나 이상에 있어서, 상기 고체 유성 성분 100 중량부에 대하여, 상기 점증제는 1 내지 10 중량부로 포함되고, 상기 폴리올은 200 내지 600 중량부로 포함되는 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.In the thirteenth embodiment, in at least one of the first to twelfth embodiments, with respect to 100 parts by weight of the solid oily component, the thickener is contained in 1 to 10 parts by weight, and the polyol is 200 to 600 parts by weight. It is possible to provide a low-viscosity cosmetic composition, which is characterized by being included as a part.
제14 실시형태는, 제1 실시형태 내지 제13 실시형태 중 하나 이상에 있어서, 조성물 총 중량 대비 0.0001 내지 5 중량%의 액상 유성 성분을 더 포함하는 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.The 14th embodiment provides a low-viscosity cosmetic composition according to at least one of the first to 13th embodiments, further comprising 0.0001 to 5% by weight of a liquid oily component based on the total weight of the composition. Can.
제15 실시형태는, 제1 실시형태 내지 제14 실시형태 중 하나 이상에 있어서, 상기 조성물은 피부 보습용인 것을 특징으로 하는, 저점도 화장료 조성물을 제공할 수 있다.The 15th embodiment can provide a low-viscosity cosmetic composition, characterized in that the composition is for moisturizing the skin in one or more of the first to 14th embodiments.
Claims (15)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201980066415.XA CN112839629B (en) | 2019-01-02 | 2019-12-03 | Low-viscosity cosmetic composition that stabilizes solid oily components |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2019-0000201 | 2019-01-02 | ||
| KR1020190000201A KR102673707B1 (en) | 2019-01-02 | 2019-01-02 | Low viscosity cosmetic composition stabilizing solid oily components |
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| Publication Number | Publication Date |
|---|---|
| WO2020141735A1 true WO2020141735A1 (en) | 2020-07-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/KR2019/016911 Ceased WO2020141735A1 (en) | 2019-01-02 | 2019-12-03 | Solid oily component-stabilized, low-viscosity cosmetic composition |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR102673707B1 (en) |
| CN (1) | CN112839629B (en) |
| WO (1) | WO2020141735A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102223008B1 (en) * | 2020-09-22 | 2021-03-04 | 한국콜마주식회사 | Low viscosity cosmetic composition containing capsule |
| KR20220109259A (en) | 2021-01-28 | 2022-08-04 | 김경수 | The composition for sterilization comprising carvacrol as an active ingredient |
| KR102582409B1 (en) * | 2021-04-28 | 2023-09-25 | 주식회사 미스미네랄 | Method and Composition for Recovery of Exercise-induced Muscle Damage |
| KR102835382B1 (en) * | 2024-10-18 | 2025-07-18 | 한국콜마주식회사 | Cosmetic composition with excellent cooling sensation containing sodium carbomer |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100732728B1 (en) * | 2006-10-26 | 2007-06-27 | 주식회사 코스메카코리아 | Low Viscosity Emulsion Cosmetic Composition |
| KR101125922B1 (en) * | 2009-11-19 | 2012-03-21 | (주)아모레퍼시픽 | Cosmetic composition with low viscosity |
| KR20120070192A (en) * | 2010-12-21 | 2012-06-29 | (주)아모레퍼시픽 | Low viscous o/w cosmetic composition having improved cosmetics formulation stability and safety |
| JP2012250919A (en) * | 2011-06-01 | 2012-12-20 | Daicel Corp | Oily gel-like composition |
| KR20160012757A (en) * | 2014-07-25 | 2016-02-03 | 주식회사 엘지생활건강 | Cosmetic composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006035042A1 (en) * | 2006-07-28 | 2008-01-31 | Beiersdorf Ag | Oil-in-water cosmetic preparation, useful as make-up products and for moisturizing skin, comprises polyol, light-weight oils e.g. isodecyl neopentanoate, medium-weight oils e.g. polydecene, and wax e.g. myristyl myristate and shea butter |
| KR102014998B1 (en) * | 2012-10-12 | 2019-08-27 | (주)아모레퍼시픽 | Low viscous cosmetic composition using a natural emulsifying agent |
| TWI610687B (en) * | 2013-11-13 | 2018-01-11 | 愛茉莉太平洋股份有限公司 | Low viscous cosmetic composition using a natural emulsifying agent |
| CN104644532B (en) * | 2013-11-20 | 2019-08-09 | 株式会社爱茉莉太平洋 | Low viscosity cosmetic composition using natural emulsifier |
| KR102310520B1 (en) | 2017-04-27 | 2021-10-08 | (주)아모레퍼시픽 | Transparent solubilization cosmetic composition and method for preparing thereof |
-
2019
- 2019-01-02 KR KR1020190000201A patent/KR102673707B1/en active Active
- 2019-12-03 CN CN201980066415.XA patent/CN112839629B/en active Active
- 2019-12-03 WO PCT/KR2019/016911 patent/WO2020141735A1/en not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100732728B1 (en) * | 2006-10-26 | 2007-06-27 | 주식회사 코스메카코리아 | Low Viscosity Emulsion Cosmetic Composition |
| KR101125922B1 (en) * | 2009-11-19 | 2012-03-21 | (주)아모레퍼시픽 | Cosmetic composition with low viscosity |
| KR20120070192A (en) * | 2010-12-21 | 2012-06-29 | (주)아모레퍼시픽 | Low viscous o/w cosmetic composition having improved cosmetics formulation stability and safety |
| JP2012250919A (en) * | 2011-06-01 | 2012-12-20 | Daicel Corp | Oily gel-like composition |
| KR20160012757A (en) * | 2014-07-25 | 2016-02-03 | 주식회사 엘지생활건강 | Cosmetic composition |
Also Published As
| Publication number | Publication date |
|---|---|
| KR102673707B1 (en) | 2024-06-12 |
| TW202027723A (en) | 2020-08-01 |
| CN112839629A (en) | 2021-05-25 |
| CN112839629B (en) | 2025-02-25 |
| KR20200084153A (en) | 2020-07-10 |
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