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WO2020235789A1 - Lip cosmetic composition with improved longevity and dryness - Google Patents

Lip cosmetic composition with improved longevity and dryness Download PDF

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Publication number
WO2020235789A1
WO2020235789A1 PCT/KR2020/003261 KR2020003261W WO2020235789A1 WO 2020235789 A1 WO2020235789 A1 WO 2020235789A1 KR 2020003261 W KR2020003261 W KR 2020003261W WO 2020235789 A1 WO2020235789 A1 WO 2020235789A1
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WO
WIPO (PCT)
Prior art keywords
fluorine
oil
weight
cosmetic composition
composition
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2020/003261
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French (fr)
Korean (ko)
Inventor
정선아
김정아
윤성원
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LG H&H Co Ltd
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LG Household and Health Care Ltd
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Application filed by LG Household and Health Care Ltd filed Critical LG Household and Health Care Ltd
Publication of WO2020235789A1 publication Critical patent/WO2020235789A1/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A61K8/70Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine containing perfluoro groups, e.g. perfluoroethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/897Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing halogen, e.g. fluorosilicones
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips

Definitions

  • the present invention relates to a cosmetic composition for lips that contains a large amount of volatile oil and has improved durability and dryness.
  • a lip fluid formulation that seeks a long lasting effect, it is manufactured in a water-in-oil type W/O emulsion type or a small amount of non-volatile oil is prescribed in the oil formulation to improve dryness, but in this case, it causes bleeding and bleeding, resulting in persistence. There is a problem of dropping.
  • Korean Patent Application Publication No. 10-2018-0129694 is a water-in-oil type emulsifier containing an acrylic film forming agent, a volatile oil, purified water, a thickener, and an emulsifier, and it is about improved water resistance by including a coating agent in the water-in-oil type formulation. If it contains an aqueous phase, it gives a moist and soft feeling of use rather than an oil-dispersion formulation made of an emulsion, but there is a problem in that it is vulnerable to smearing and bleeding, that is, lasting power of the lip makeup. In addition, when the water is dry, dryness is induced and dead skin cells are highlighted, as in oil dispersion, and there is a problem that the dryness is not fundamentally resolved.
  • the prior art for improving the dryness in the oil dispersion formulation is disclosed in Korean Patent Application Publication No. 10-2014-0122582.
  • This relates to a cosmetic composition for lips and is characterized by containing distearyl maleate, which is a non-volatile oil.
  • distearylmalate slows the evaporation rate of moisture on the lips, reduces dryness of the lips, and has the effect of sustaining the color of the lips, but the raw material has an alkyl group having 18 carbon atoms formed at both ends, so it has a hydrophobic property. It is strong, and there is a problem that the feeling of use is heavy and stuffy when applied to the lips.
  • the raw material has a long chain structure with an alkyl group having 18 carbon atoms and has a lipophilic property, and viscosity increases due to the long chain structure and lipophilic properties, resulting in a problem of stickiness and greasy lips. Accordingly, there is a problem in that the color of the lips is not maintained for a long time because the lips must be frequently wiped with a cotton pad or tissue in order to eliminate the stickiness and greasyness of the lips.
  • the problem to be solved by the present invention is to provide a cosmetic composition for lips that does not contain an aqueous phase or non-volatile oil in order to solve the problems of the prior art, does not deteriorate persistence, and has improved dryness and tight feeling.
  • the inventors of the present invention when including a fluorine-based oil and a fluorine-based silicone wax together in the oil dispersion formulation containing a large amount of volatile oil and a coating agent of the present invention, formulation stability and A surprising discovery that not only the durability but also the dry feeling and the feeling of use are remarkably improved, the present invention has been completed.
  • the present invention provides a cosmetic composition for lips comprising a fluorine-based oil and a fluorine-based silicone wax.
  • the inventors of the present invention when including a fluorine-based oil having excellent oil resistance and water resistance in a volatile oil solvent in which the coating agent is dissolved, provides a moist and soft feeling to the cosmetic formulation for lips, unlike non-volatile oils that reduce the persistence, while adding to water or oil. It was found that the lip makeup was not easily removed and the persistence was strengthened.
  • fluorine-based oils are poor in compatibility with both handmade and emulsions, and separation occurs even when a small amount of less than 1% by weight is prescribed in an oil dispersion formulation, and formulation stability is poor when prescribed alone.
  • the inventors of the present invention have applied various stabilizers or thickeners to solve the problem that the fluorine-based oil deteriorates the formulation stability.
  • the formulation stability is remarkably improved with the increase in viscosity, and water resistance.
  • a lip fluid formulation with improved dryness and lasting power was realized by imparting oil resistance.
  • the fluorine-based oil may be a compound that can be used in a conventional cosmetic composition for lips, polyperfluoromethylisopropyl ether, polyperfluoroethoxymethoxy difluoroethyl PEG phosphate, poly Perfluoroethoxymethoxy difluorohydroxyethyl ether, polyoxyperfluoroalkane, perfluoropolymethylether, perfluorinated polyether, perfluorodecalin, perfluorodimethylcyclohexane, and purple Luoromethylcyclopentane It may include any one or more selected from the group consisting of, but is not limited thereto.
  • the fluorine-based oil may include polyperfluoromethylisopropyl ether, which may be represented by the following formula (1).
  • polyperfluoromethyl isopropyl ether When the polyperfluoromethyl isopropyl ether is included, a moist and soft feeling of use is imparted to the cosmetic formulation for lips, and the lasting power is remarkably improved.
  • n and m are each independently an integer of 1 to 100, and n/m may be 5 to 50, preferably 10 to 45, more preferably 20 to 40.
  • the molecular weight of the polyperfluoromethylisopropyl ether may be 800 to 8000, preferably 1000 to 7000, more preferably 1500 to 6250.
  • the polyperfluoromethylisopropyl ether may be a product of the brand name Fomblin HC-04.
  • the fluorine-based oil may be included in an amount of 0.1 to 5% by weight, preferably 0.3 to 4% by weight, and more preferably 0.5 to 3% by weight, based on the total weight of the composition. If the fluorine-based oil is less than 0.1% by weight, the effect of increasing the persistence and feeling of use of the cosmetic may not be sufficiently exhibited, and if it is more than 5% by weight, the formulation stability may be deteriorated.
  • the fluorine-based silicone wax has excellent compatibility with the fluorine-based oil in the fluorine portion of the compound, and a compound having excellent compatibility with an organic material by a long-chain alkyl group in the compound may be used.
  • a compound having excellent compatibility with an organic material by a long-chain alkyl group in the compound may be used.
  • perfluorononylethylstearyldimethicone may be used as the fluorine-based silicone wax.
  • the perfluorononylethylstearyldimethicone may be represented by the following formula (2).
  • l, m, and n may each independently be an integer of 1 to 100.
  • the n/m may be 1 to 20, preferably 1 to 10, more preferably 1 to 7.
  • the perfluorononylethylstearyldimethicone may be in the form of a solid wax at room temperature, which n/m is 2 to 20, preferably 2 to 4, and m is any one of 20 to 25 It can be an integer.
  • the cosmetic composition containing the solid wax form of perfluorononylethylstearyldimethicone significantly improves not only formulation stability, but also durability and feeling of use.
  • the viscosity (cPs) of the perfluorononylethylstearyldimethicone may be 400 to 1000, and the viscosity may be measured under the conditions of Spindle RV-7, 5 rpm, and 40°C using Brookfield RVT.
  • the volatility (%) of the perfluorononylethylstearyldimethicone may be up to 4.0 at 150°C and 1 hour, and the refractive index may be 1.400 to 1.423 at 20°C.
  • the perfluorononylethylstearyldimethicone may be a product such as Basel's SF-30W or Siltech's Fluorosil L118.
  • the fluorine-based silicone wax may be included in an amount of 0.5 to 10% by weight, preferably 0.7 to 8% by weight, and more preferably 1 to 5% by weight, based on the total weight of the composition.
  • the amount of the fluorine-based silicone wax is less than 0.5% by weight, the effect of improving the persistence and feeling of use of the cosmetic is not sufficiently exhibited, and when it is more than 10% by weight, the viscosity is excessively increased.
  • non-volatile oil may mean an oil having a vapor pressure of about 0.2 mmHg or less at 25°C at 1 atmosphere and/or an oil having a boiling point of about 300°C or more at 1 atmosphere.
  • Volatile oil may mean an oil exhibiting a vapor pressure of about 0.2 mmHg or more at 25°C.
  • the cosmetic composition for lips of the present invention may contain a large amount of volatile oil, the volatile oil is isododecane, isohexadecane, C7-8 isoparaffin, C8-9 isoparaffin, C10-11 Isoparaffin, C10-13 isoparaffin, C11-12 isoparaffin, C11-13 isoparaffin, C13-14 isoparaffin, methyltrimethicone, caprylylmethicone, cyclomethicone, cyclotetrasiloxane, cyclopentasiloxane and cyclo It may include any one or more selected from the group consisting of hexasiloxane, etc., but is not limited thereto.
  • the volatile oil may act to smoothly form a film of the coating agent while being volatilized when the lips are applied.
  • the volatile oil may be included in 50 to 90% by weight, preferably 60 to 80% by weight, based on the total weight of the composition. If the volatile oil is less than 50% by weight, other ingredients in the formulation may not be sufficiently dispersed, and if it is more than 90% by weight, the feeling of use of the cosmetic may be impaired.
  • the cosmetic composition for lips of the present invention may include a coating agent, and the coating agent is an acrylate/polytrimethylsiloxymethacrylate copolymer, trimethylsiloxysilicate, polypropylsilsesquioxane, poly Methylsilsesquioxane, dimethicone/vinyltrimethylsiloxysilicate crosspolymer, trimethylsiloxysilicate/dimethiconol crosspolymer, trimethylsiloxysilylcarbamoyl pullulan polyvinyl alcohol, polyvinylpyrrolidone, acrylate-based copolymer It may include any one or more selected from the group consisting of coalescence and vinylpyrrolidone-based copolymer, but is not limited thereto.
  • the coating agent is an acrylate/polytrimethylsiloxymethacrylate copolymer, trimethylsiloxysilicate, polypropylsilsesquioxane, poly Methyls
  • the coating agent may be included in an amount of 5 to 40% by weight, preferably 10 to 30% by weight, and more preferably 15 to 25% by weight, based on the total weight of the composition. If the coating agent is less than 5% by weight, the film formation on the lips may be insufficient and the persistence may be reduced, and when it is more than 40% by weight, the stability of the formulation may be impaired.
  • the cosmetic composition for lips of the present invention may substantially contain no non-volatile oil.
  • the composition substantially free of non-volatile oil may contain 5% by weight or less, preferably 3% by weight or less, more preferably 1% by weight or less, based on the total weight of the composition, and most preferably May not be included at all. Since the cosmetic composition for lips of the present invention substantially does not contain non-volatile oil, it is not easily removed by water or oil, so that the durability is improved, and a moist and soft feeling of use is provided.
  • the non-volatile oil is caprylic/capric triglyceride, triethylhexanoin, diisostearylmalate, tridecyltrimelitate, pentaerythrityl tetraisostearate, triisostearin, di Glyceryl sebacate/isopalmitate, phytosteryl/isostearyl/cetyl/stearyl/behenyldimerdilinoleate, dipentaerythritylhexahydroxystearate/hexastearate/hexaloginate, phytosteryl /Isostearyl/cetyl/stearyl/behenyldimerdilinoleate, hydrogenated castor oil isostearate, dimethicone crosspolymer, dimethicone/vinyldimethicone crosspolymer, PEG-12dimethicone/PP -20 may be any one or more selected from the group consisting of crosspolymers
  • the cosmetic composition for lips of the present invention comprises a fluorine-based oil and a fluorine-based silicone wax of 1:0.1 to 10, preferably 1:0.5 to 7, more preferably 1:1 to 5, and most preferably 1:2 to It may be included in a weight ratio of 4 (fluorine-based oil: fluorine-based silicone wax).
  • fluorine-based oil fluorine-based silicone wax
  • the composition of the present invention contains a fluorine-based oil and a fluorine-based silicone wax in the weight ratio, formulation stability, makeup persistence, and feeling of use are remarkably increased.
  • the viscosity (cPs) of the cosmetic composition for lips of the present invention may be 8000 to 25000, preferably 10000 to 20000, more preferably 12000 to 18000.
  • the viscosity can be measured under Spindle Number 4, 30 rpm, and room temperature conditions. When the viscosity is less than 8000, separation of the formulation may occur, and when the viscosity is more than 25000, the viscosity is excessively high, and the feeling of use may be inhibited.
  • the cosmetic composition for lips of the present invention may include a pigment to impart a vivid color
  • the pigment may be used without limitation as long as it is commonly used in the art.
  • the pigment is Yellow No. 203, Yellow No. 4, Yellow No. 5, Yellow No. 201, Yellow No. 204, Red No. 103, Red No. 104, Red No. 201, Red No. 202, Red No. 218, Red No. 220 , Red No. 223, Red No. 226, Red No. 227, Red No. 203, Red Iron Oxide, Blue No. 1, Blue No. 2, Titanium Dioxide, and the like may be included, but are not limited thereto.
  • the pigment may be included in an amount of 0.1 to 30% by weight, preferably 0.1 to 20% by weight, and more preferably 1 to 15% by weight, based on the total weight of the composition. If the pigment is less than 0.1% by weight, the color development power may be insufficient, and if it is more than 30% by weight, the formulation stability may be deteriorated.
  • the cosmetic composition for lips of the present invention may be prepared in an oil dispersion formulation, and may be prepared in a liquid formulation such as lip gloss or lip cream that may be applied to the skin.
  • the cosmetic composition for lips according to the present invention is a group consisting of antifoam, wax, thickener, powder thickener, antioxidant, emollient, moisturizer, soothing agent, lubricant, preservative, moisturizer, ultraviolet absorber, and fragrance. It may further include one or more additives selected from.
  • the present invention is a lip cosmetic comprising 0.1 to 5% by weight of fluorine-based oil, 0.5 to 10% by weight of fluorine-based silicone wax, 50 to 90% by weight of volatile oil, and 5 to 40% by weight of a coating agent based on the total weight of the composition
  • the composition is provided.
  • the composition containing each of the above ingredients in a specific amount does not contain non-volatile oils, but gives a moist and soft feeling of use to the lip cosmetic formulation, and is not easily erased by water or oil, so it has excellent durability and stability of the formulation. Remarkably excellent.
  • the cosmetic composition for lips of the present invention has a moist and soft feeling of use, which improves dryness, is not easily erased by water or oil, has excellent persistence, and has a high viscosity, so that the formulation stability is remarkably excellent.
  • FIG. 2 is a schematic diagram of film formation showing a bonding structure of a film agent and a thickener after volatilization of volatile oil.
  • FIG. 3 is a schematic diagram of a lip formed with a film after use of a cosmetic composition for lips.
  • the cosmetic compositions of Examples and Comparative Examples 1 to 3 were prepared with the ingredients disclosed in Table 1 below. First, an acrylate/polytrimethylsiloxymethacrylate copolymer was dispersed and dissolved in isododecane with a disper mixer at room temperature. Thereafter, disteadimonium hectorite and propylene carbonate were added, followed by heating and dispersing at 80 to 85° C. for 10 minutes or more. Thereafter, the cosmetic compositions of Examples and Comparative Examples were prepared by mixing the raw materials according to the composition of Table 1 below, and dispersing, degassing, and cooling at room temperature at 80 to 85°C.
  • a suitable viscosity at which the formulation does not separate is at least 8,000 cPs at Spindle Number 4, 30 rpm, and room temperature conditions.
  • Table 2 below shows the formulation stability evaluation results of Examples and Comparative Examples 1 to 3.
  • Comparative Example 2 in which non-volatile oil was prescribed, had a significantly reduced viscosity compared to Comparative Example 3, which was not prescribed, and thus formulation separation occurred.
  • the viscosity of Comparative Example 1 is 8,000 cPs or more, it was confirmed that the fluorine-based oil was not stabilized and thus a separation phenomenon occurred.
  • the examples in which the fluorine-based silicone wax was prescribed had excellent formulation stability because oil separation did not occur. That is, it was confirmed that the fluorine-based oil could not be stabilized with the conventional wax or thickener, but formulation stability could be remarkably increased by prescribing a fluorine-based silicone wax.
  • Persistence was evaluated for burying, smearing, and oil resistance.
  • the formulation was uniformly applied to a thickness of 60 micrometers using an SI 1107 80mmm 4 side applicator and dried for 15 minutes.
  • a white paper was placed on the artificial leather of which the formulation was dried and pressed with a weight of 4.5 kg for 10 seconds, and the degree of burying on the paper was measured with a colorimeter.
  • a white paper was placed on the artificial leather of which the formulation was dried, and the white paper was pulled out under conditions of pressing with a weight of 1.5 kg, and the degree of smearing on the paper was measured with a colorimeter.
  • oil resistance to edible oil was evaluated in order to confirm that the oil is erased when eating.
  • Apply 10 microliters of canola oil using a micropipette on the dried artificial leather apply evenly, and after 1 minute, rotate the M1 grade 1kg round weight 10 times against the rough side of the paper filter. The shear force of was implemented, and the degree of burying on the paper filter was then measured with a colorimeter.
  • the model of the color difference meter used is KONICA MINOLTA CHROMA METER CR-400.
  • the average value of smearing or smearing was calculated by randomly measuring clean white paper three times with BLANK (L1, a1, b1), and the average value of smearing or smearing was calculated by randomly measuring the paper measured in the above conditions three times.
  • the measured values are expressed as L(Lightness), a(red-green chromaticity), and b(yellow blue chromaticity), and the degree of difference between the color immediately after application and the color on the paper is quantified by calculating the ⁇ E value as shown below. I did.
  • Comparative Example 2 corresponds to a case in which 3% by weight of diisostearylmaleate, which is a nonvolatile oil, is added compared to Comparative Example 3, in which case smearing, smearing and oil It was confirmed that the oil resistance value increased significantly, that is, the persistence decreased significantly. On the other hand, in Comparative Example 1 where fluorine-based oil was prescribed, the level of staining and bleeding ⁇ E was less than 1, which was unidentifiable, and the oil resistance ⁇ E value was also smaller than that of Comparative Example 2, confirming that the oil resistance was further increased.
  • FIG. 1 is a result of confirming the degree of burying of each formulation on the filter paper after measuring the oil and oil resistance, and when looking at the difference shown in FIG. 1, it can be confirmed that the persistence of the embodiment is the best.
  • Comparative Example 2 in which non-volatile oil was prescribed, the dryness was very excellent compared to Comparative Example 3, but the lasting power was significantly decreased.
  • Comparative Example 1 in which a fluorine-based oil was prescribed, spreadability, dryness, and durability were all increased compared to Comparative Example 3. It can be seen that the example in which the fluorine-based silicone wax was prescribed in addition to Comparative Example 1 improved the spreadability due to the use of the wax, and was significantly superior to Comparative Examples 1 and 3 in both dryness and lasting power.

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Abstract

The present invention relates to a lip cosmetic composition comprising fluorine-based oil and fluorine-based silicone wax in a large amount of volatile oil. The lip cosmetic composition of the present invention has improved dryness due to a moist and soft feeling, is not easily removed by water or oil and thus has excellent longevity, and also has high viscosity such that formulation stability is significantly excellent.

Description

지속력 및 건조감을 개선한 입술용 화장료 조성물Cosmetic composition for lips with improved durability and dryness

본 출원은 2019년 5월 21일 출원된 대한민국출원 제10-2019-0059640호에 기초한 우선권을 주장하며, 해당 출원의 명세서 및 도면에 개시된 모든 내용은 본 출원에 원용된다.This application claims priority based on Korean Application No. 10-2019-0059640 filed on May 21, 2019, and all contents disclosed in the specification and drawings of the application are incorporated in this application.

본 발명은 휘발성 오일을 다량 포함하면서 지속력 및 건조감이 개선된 입술용 화장료 조성물에 관한 것이다.The present invention relates to a cosmetic composition for lips that contains a large amount of volatile oil and has improved durability and dryness.

파운데이션, 마스카라, 또는 립 등의 메이크업 제품군에 있어서, 지속성('롱래스팅'으로 지칭)은 소비자들이 끊임없이 요구하는 매우 중요한 품질 속성 중 하나이다. 지속성이 우수한 메이크업 제형을 개발하기 위해 화장품 개발자들의 많은 노력들이 이루어지고 있고, 립 메이크업 시장에서도 컵, 냅킨, 또는 의류에 화장료가 묻어나지 않도록 지속력을 강화시킨 제품들이 출시되어 왔다.In makeup products such as foundation, mascara, or lip, persistence (referred to as'long lasting') is one of the very important quality attributes that consumers constantly demand. A lot of efforts are being made by cosmetic developers to develop makeup formulations with excellent persistence, and in the lip makeup market, products that strengthen the persistence so that cosmetics do not get on cups, napkins, or clothing have been released.

종래에는 립 메이크업 제품의 지속성을 높이기 위해, 제형 내 다량의 휘발성 오일과 함께 다량의 유용성 실리콘계 필름 형성제를 포함시킴으로써, 오일이 휘발된 후 얇은 필름이 입술 위에 부착되어 입술 화장이 잘 지워지거나 번지지 않고 컵 등에 묻어나지 않는 효과를 얻을 수 있었다. 하지만 휘발성 오일이 휘발되어 피막이 형성될 때 입술의 조임을 유발하고 입술의 답답함과 건조감을 강하게 일으키며, 필름 형성제의 유연성이 떨어지는 특성 때문에 입술 주름 및 각질이 부각되어 사용에 부담을 주는 단점이 있었다. 따라서 롱래스팅 효과를 소구하는 립플루이드 제형의 경우, 건조감을 개선하기 위해 유중수형 W/O 유화타입으로 제조되거나 유상제형에 소량의 비휘발성 오일이 처방되나, 이 경우 묻어남과 번짐을 유발하여 지속성을 떨어뜨리는 문제가 있다.Conventionally, in order to increase the persistence of lip makeup products, by including a large amount of oil-soluble silicone-based film forming agent together with a large amount of volatile oil in the formulation, a thin film is adhered to the lips after the oil is volatilized, so that the lip makeup is not easily removed or smeared. It was possible to obtain an effect that did not get on the cup. However, when the volatile oil is volatilized and the film is formed, it causes tightness of the lips, increases the tightness and dryness of the lips, and there is a disadvantage that lip wrinkles and dead skin cells are highlighted due to the low flexibility of the film forming agent, which puts a burden on the use. Therefore, in the case of a lip fluid formulation that seeks a long lasting effect, it is manufactured in a water-in-oil type W/O emulsion type or a small amount of non-volatile oil is prescribed in the oil formulation to improve dryness, but in this case, it causes bleeding and bleeding, resulting in persistence. There is a problem of dropping.

일 예로, 입술용 유화 화장료 조성물에 관한 종래 기술로는 대한민국 공개특허 제10-2018-0129694호에 개시되어 있다. 이는 아크릴계 필름형성제, 휘발성 오일, 정제수, 점증제, 및 유화제를 포함하는 유중수형 유화제형이며, 유중수형 제형에 피막제가 포함되어 개선된 내수성에 관한 내용이다. 수상을 포함하고 있으면 유제로 이루어진 유분산 제형보다는 촉촉하고 부드러운 사용감을 주지만, 입술 화장의 묻어남과 번짐, 즉 지속력에 취약한 문제가 있다. 또한, 물이 다 마르면 유분산과 마찬가지로 건조함이 유발되고 각질이 부각되며, 근본적으로 건조감이 해결되지 않는 문제가 있다.For example, as a prior art for an emulsified cosmetic composition for lips, it is disclosed in Korean Patent Application Publication No. 10-2018-0129694. This is a water-in-oil type emulsifier containing an acrylic film forming agent, a volatile oil, purified water, a thickener, and an emulsifier, and it is about improved water resistance by including a coating agent in the water-in-oil type formulation. If it contains an aqueous phase, it gives a moist and soft feeling of use rather than an oil-dispersion formulation made of an emulsion, but there is a problem in that it is vulnerable to smearing and bleeding, that is, lasting power of the lip makeup. In addition, when the water is dry, dryness is induced and dead skin cells are highlighted, as in oil dispersion, and there is a problem that the dryness is not fundamentally resolved.

유분산 제형 내에서 건조감을 개선하기 위한 종래 기술은 대한민국 공개특허공보 제10-2014-0122582호에 개시되어 있다. 이는 입술용 화장료 조성물에 관한 것으로, 비휘발성 오일인 디스테아릴말레이트를 함유하는 것을 특징으로 하는 것이다. 상기 종래 기술에서 디스테아릴말레이트는 입술의 수분 증발 속도를 느리게 하여 입술 건조함을 줄이며 입술의 색상 지속 효과를 가지고 있지만, 상기 원료는 탄소수 18개를 가지는 알킬기가 양 끝쪽에 형성하고 있어 소수성 성질이 강하며, 이로 인해 입술에 도포 시 사용감이 무겁고 답답한 느낌을 주는 문제가 있다. 또한, 상기 원료는 탄소수 18개를 가지는 알킬기가 있는 긴 사슬형 구조로 친유성 성질을 가지고 있으며, 긴 사슬형 구조와 친유성 성질 때문에 점도가 증가되어 끈적임이 발생되고 입술이 번들거리는 문제가 있다. 이에 따라, 입술의 끈적임과 번들거림을 해소하고자 입술을 화장솜이나 티슈로 자주 닦아내야 하기 때문에 입술의 색상 유지가 오래가지 못하는 문제도 있다.The prior art for improving the dryness in the oil dispersion formulation is disclosed in Korean Patent Application Publication No. 10-2014-0122582. This relates to a cosmetic composition for lips and is characterized by containing distearyl maleate, which is a non-volatile oil. In the prior art, distearylmalate slows the evaporation rate of moisture on the lips, reduces dryness of the lips, and has the effect of sustaining the color of the lips, but the raw material has an alkyl group having 18 carbon atoms formed at both ends, so it has a hydrophobic property. It is strong, and there is a problem that the feeling of use is heavy and stuffy when applied to the lips. In addition, the raw material has a long chain structure with an alkyl group having 18 carbon atoms and has a lipophilic property, and viscosity increases due to the long chain structure and lipophilic properties, resulting in a problem of stickiness and greasy lips. Accordingly, there is a problem in that the color of the lips is not maintained for a long time because the lips must be frequently wiped with a cotton pad or tissue in order to eliminate the stickiness and greasyness of the lips.

본 발명이 해결하고자 하는 과제는 상기 종래 기술의 문제점을 해결하기 위해 수상 또는 비휘발성 오일을 포함하지 않으면서, 지속력이 저하되지 않고, 건조감 및 답답한 사용감이 개선된 입술용 화장료 조성물을 제공하는 것이다.The problem to be solved by the present invention is to provide a cosmetic composition for lips that does not contain an aqueous phase or non-volatile oil in order to solve the problems of the prior art, does not deteriorate persistence, and has improved dryness and tight feeling.

본 발명의 발명자들은 상기 종래기술들의 문제점을 극복하기 위하여 예의 연구 노력한 결과, 본 발명의 다량의 휘발성 오일과 피막제를 포함하는 유분산 제형 내에 불소계 오일 및 불소계 실리콘 왁스를 함께 포함하는 경우, 제형 안정성 및 지속성 뿐만 아니라 건조감, 사용감이 현저하게 개선되는 놀라운 발견을 하여, 본 발명을 완성하게 되었다.As a result of intensive research efforts in order to overcome the problems of the prior art, the inventors of the present invention, when including a fluorine-based oil and a fluorine-based silicone wax together in the oil dispersion formulation containing a large amount of volatile oil and a coating agent of the present invention, formulation stability and A surprising discovery that not only the durability but also the dry feeling and the feeling of use are remarkably improved, the present invention has been completed.

본 발명은 불소계 오일 및 불소계 실리콘 왁스를 포함하는 입술용 화장료 조성물을 제공한다. 본 발명의 발명자들은 피막제를 녹인 휘발성 오일 용제에 내유성 및 내수성이 우수한 불소계 오일을 포함시킬 때, 지속성을 저하시키는 비휘발성 오일과 달리 입술용 화장료 제형에 촉촉하고 부드러운 사용감을 부여하면서, 물 또는 오일에 입술 화장이 잘 지워지지 않아 지속성이 강화됨을 발견하였다. 단, 불소계 오일은 수제 및 유제 모두와 상용성이 떨어져, 유분산 제형 내에서 1 중량% 미만으로 소량 처방되어도 분리가 일어나, 단독 처방시 제형 안정성이 떨어지는 단점이 있었다. 본 발명의 발명자들은 불소계 오일이 제형 안정성을 떨어뜨리는 문제를 해결하기 위해 여러 안정화제 또는 점증제를 적용해본 결과, 불소계 실리콘 왁스를 적용할 때 점도의 증가와 함께 제형 안정성이 현저하게 개선되며, 내수성 및 내유성이 부여되어 건조감 및 지속력이 개선된 립 플루이드 제형이 구현됨을 발견하였다.The present invention provides a cosmetic composition for lips comprising a fluorine-based oil and a fluorine-based silicone wax. The inventors of the present invention, when including a fluorine-based oil having excellent oil resistance and water resistance in a volatile oil solvent in which the coating agent is dissolved, provides a moist and soft feeling to the cosmetic formulation for lips, unlike non-volatile oils that reduce the persistence, while adding to water or oil. It was found that the lip makeup was not easily removed and the persistence was strengthened. However, fluorine-based oils are poor in compatibility with both handmade and emulsions, and separation occurs even when a small amount of less than 1% by weight is prescribed in an oil dispersion formulation, and formulation stability is poor when prescribed alone. The inventors of the present invention have applied various stabilizers or thickeners to solve the problem that the fluorine-based oil deteriorates the formulation stability. As a result, when applying the fluorine-based silicone wax, the formulation stability is remarkably improved with the increase in viscosity, and water resistance. And it was found that a lip fluid formulation with improved dryness and lasting power was realized by imparting oil resistance.

일 실시예에서, 상기 불소계 오일은 통상적인 입술용 화장료 조성물에 사용될 수 있는 화합물이 사용될 수 있으며, 폴리퍼플루오로메틸이소프로필에테르, 폴리퍼플루오로에톡시메톡시 디플루오로에틸 PEG 포스페이트, 폴리퍼플루오로에톡시메톡시 디플루오로하이드록시에틸 에테르, 폴리옥시퍼플루오로알칸, 퍼플루오로폴리메칠에테르, 퍼플루오리네이티드폴리에테르, 퍼플루오로데칼린, 퍼플루오로디메틸사이클로헥산, 및 퍼플루오로메틸사이클로펜탄 등으로 이루어진 군에서 선택된 어느 하나 이상을 포함할 수 있으나, 이에 제한되는 것은 아니다. In one embodiment, the fluorine-based oil may be a compound that can be used in a conventional cosmetic composition for lips, polyperfluoromethylisopropyl ether, polyperfluoroethoxymethoxy difluoroethyl PEG phosphate, poly Perfluoroethoxymethoxy difluorohydroxyethyl ether, polyoxyperfluoroalkane, perfluoropolymethylether, perfluorinated polyether, perfluorodecalin, perfluorodimethylcyclohexane, and purple Luoromethylcyclopentane It may include any one or more selected from the group consisting of, but is not limited thereto.

바람직하게, 상기 불소계 오일은 폴리퍼플루오로메틸이소프로필에테르를 포함할 수 있으며, 이는 하기 화학식 1로 나타낼 수 있다. 상기 폴리퍼플루오로메틸이소프로필에테르를 포함하는 경우, 입술용 화장료 제형에 촉촉하고 부드러운 사용감이 부여되고, 지속력이 현저하게 개선된다.Preferably, the fluorine-based oil may include polyperfluoromethylisopropyl ether, which may be represented by the following formula (1). When the polyperfluoromethyl isopropyl ether is included, a moist and soft feeling of use is imparted to the cosmetic formulation for lips, and the lasting power is remarkably improved.

[화학식 1][Formula 1]

CF 3-O-(CF(CF 3)CF 2-O) n-(CF 2-O) m-CF 3 CF 3 -O-(CF(CF 3 )CF 2 -O) n -(CF 2 -O) m -CF 3

상기 화학식 1에서 n 및 m은 서로 독립적으로 1 내지 100 중 어느 하나의 정수이며, n/m은 5 내지 50, 바람직하게 10 내지 45, 더욱 바람직하게 20 내지 40일 수 있다. 상기 폴리퍼플루오로메틸이소프로필에테르의 분자량은 800 내지 8000, 바람직하게 1000 내지 7000, 더욱 바람직하게 1500 내지 6250일 수 있다. 상기 범위 내의 n, m 값 및 분자량을 갖는 폴리퍼플루오로메틸이소프로필에테르를 사용할 경우, 입술용 화장료 조성물의 지속력 및 건조감 개선 효과가 보다 우수하다. 일 실시예에서, 상기 폴리퍼플루오로메틸이소프로필에테르는 상품명 Fomblin HC-04의 제품이 사용될 수 있다. 또한, 상기 불소계 오일은 조성물 총 중량 대비 0.1~5 중량%, 바람직하게 0.3~4 중량%, 더욱 바람직하게 0.5~3 중량%로 포함될 수 있다. 상기 불소계 오일이 0.1 중량% 미만일 경우에는 화장료의 지속성 및 사용감 상승 효과가 충분히 발휘되지 않을 수 있으며, 5 중량% 초과일 경우에는 제형 안정성이 저하될 수 있다.In Formula 1, n and m are each independently an integer of 1 to 100, and n/m may be 5 to 50, preferably 10 to 45, more preferably 20 to 40. The molecular weight of the polyperfluoromethylisopropyl ether may be 800 to 8000, preferably 1000 to 7000, more preferably 1500 to 6250. When using polyperfluoromethylisopropyl ether having n, m values and molecular weight within the above range, the effect of improving the durability and dryness of the cosmetic composition for lips is more excellent. In one embodiment, the polyperfluoromethylisopropyl ether may be a product of the brand name Fomblin HC-04. In addition, the fluorine-based oil may be included in an amount of 0.1 to 5% by weight, preferably 0.3 to 4% by weight, and more preferably 0.5 to 3% by weight, based on the total weight of the composition. If the fluorine-based oil is less than 0.1% by weight, the effect of increasing the persistence and feeling of use of the cosmetic may not be sufficiently exhibited, and if it is more than 5% by weight, the formulation stability may be deteriorated.

일 실시예에서, 상기 불소계 실리콘 왁스는 화합물 내 불소 부분이 불소계 오일과 상용성이 우수하며, 화합물 내 장쇄 알킬기에 의해 유기계열 물질과의 상용성이 우수한 화합물이 사용될 수 있다. 바람직하게 상기 불소계 실리콘 왁스는 퍼플루오로노닐에틸스테아릴디메티콘이 사용될 수 있다. 상기 퍼플루오로노닐에틸스테아릴디메티콘을 불소계 오일과 함께 포함하는 경우, 입술용 화장료 조성물의 지속력 및 건조감이 현저하게 개선될 수 있다. 상기 퍼플루오로노닐에틸스테아릴디메티콘은 하기 화학식 2로 나타낼 수 있다.In one embodiment, the fluorine-based silicone wax has excellent compatibility with the fluorine-based oil in the fluorine portion of the compound, and a compound having excellent compatibility with an organic material by a long-chain alkyl group in the compound may be used. Preferably, as the fluorine-based silicone wax, perfluorononylethylstearyldimethicone may be used. When the perfluorononylethylstearyldimethicone is included together with a fluorine-based oil, the durability and dryness of the cosmetic composition for lips may be remarkably improved. The perfluorononylethylstearyldimethicone may be represented by the following formula (2).

[화학식 2] [Formula 2]

Figure PCTKR2020003261-appb-img-000001
Figure PCTKR2020003261-appb-img-000001

상기 화학식 2에서 l, m 및 n은 서로 독립적으로 1 내지 100 중 어느 하나의 정수일 수 있다. 상기 n/m은 1 내지 20, 바람직하게 1 내지 10, 더욱 바람직하게 1 내지 7일 수 있다. 바람직하게, 상기 퍼플루오로노닐에틸스테아릴디메티콘은 상온에서 고체 왁스 형태일 수 있으며, 이는 상기 n/m이 2 내지 20, 바람직하게 2 내지 4이며, 상기 m은 20 내지 25 중 어느 하나의 정수일 수 있다. 상기 고체 왁스 형태의 퍼플루오로노닐에틸스테아릴디메티콘을 포함하는 화장료 조성물은 제형 안정성뿐만 아니라 지속성 및 사용감이 현저하게 개선된다. 상기 퍼플루오로노닐에틸스테아릴디메티콘의 점도(cPs)는 400 내지 1000일 수 있으며, 상기 점도는 Brookfield RVT를 사용하여, Spindle RV-7, 5rpm, 및 40℃의 조건에서 측정할 수 있다. 상기 퍼플루오로노닐에틸스테아릴디메티콘의 휘발도(%)는 150℃ 및 1시간의 조건에서 최대 4.0일 수 있으며, 굴절률은 20℃에서 1.400~1.423일 수 있다. 일 실시예에서, 상기 퍼플루오로노닐에틸스테아릴디메티콘은 Basel사의 SF-30W 또는 Siltech사의 Fluorosil L118 등의 제품이 사용될 수 있다.In Formula 2, l, m, and n may each independently be an integer of 1 to 100. The n/m may be 1 to 20, preferably 1 to 10, more preferably 1 to 7. Preferably, the perfluorononylethylstearyldimethicone may be in the form of a solid wax at room temperature, which n/m is 2 to 20, preferably 2 to 4, and m is any one of 20 to 25 It can be an integer. The cosmetic composition containing the solid wax form of perfluorononylethylstearyldimethicone significantly improves not only formulation stability, but also durability and feeling of use. The viscosity (cPs) of the perfluorononylethylstearyldimethicone may be 400 to 1000, and the viscosity may be measured under the conditions of Spindle RV-7, 5 rpm, and 40°C using Brookfield RVT. The volatility (%) of the perfluorononylethylstearyldimethicone may be up to 4.0 at 150°C and 1 hour, and the refractive index may be 1.400 to 1.423 at 20°C. In one embodiment, the perfluorononylethylstearyldimethicone may be a product such as Basel's SF-30W or Siltech's Fluorosil L118.

또한, 상기 불소계 실리콘 왁스는 조성물 총 중량 대비 0.5~10 중량%, 바람직하게 0.7~8 중량%, 더욱 바람직하게 1 내지 5 중량%로 포함될 수 있다. 상기 불소계 실리콘 왁스가 0.5 중량% 미만일 경우에는 화장료의 지속성 및 사용감 개선 효과가 충분히 발휘되지 않으며, 10 중량% 초과일 경우에는 점도가 과도하게 상승되는 문제가 발생한다.In addition, the fluorine-based silicone wax may be included in an amount of 0.5 to 10% by weight, preferably 0.7 to 8% by weight, and more preferably 1 to 5% by weight, based on the total weight of the composition. When the amount of the fluorine-based silicone wax is less than 0.5% by weight, the effect of improving the persistence and feeling of use of the cosmetic is not sufficiently exhibited, and when it is more than 10% by weight, the viscosity is excessively increased.

본 발명에 있어서, "비휘발성 오일"은 1 기압에서 25℃에서 약 0.2 mmHg 이하의 증기압을 나타내는 오일 및/또는 비등점이 1 기압에서 약 300℃ 이상인 오일을 의미할 수 있다. "휘발성 오일"은 25℃에서 약 0.2 mmHg 이상의 증기압을 나타내는 오일을 의미할 수 있다.In the present invention, "non-volatile oil" may mean an oil having a vapor pressure of about 0.2 mmHg or less at 25°C at 1 atmosphere and/or an oil having a boiling point of about 300°C or more at 1 atmosphere. "Volatile oil" may mean an oil exhibiting a vapor pressure of about 0.2 mmHg or more at 25°C.

일 실시예에서, 본 발명의 입술용 화장료 조성물은 다량의 휘발성 오일을 포함할 수 있으며, 상기 휘발성 오일은 이소도데칸, 이소헥사데칸, C7-8이소파라핀, C8-9이소파라핀, C10-11이소파라핀, C10-13이소파라핀, C11-12이소파라핀, C11-13이소파라핀, C13-14이소파라핀, 메칠트리메치콘, 카프릴릴메치콘, 사이클로메치콘, 사이클로테트라실록산, 사이클로펜타실록산 및 사이클로헥사실록산 등으로 이루어진 군으로부터 선택된 어느 하나 이상을 포함할 수 있으나, 이에 제한되는 것은 아니다. 상기 휘발성 오일은 입술 도포시 휘발되면서 피막제의 피막 형성이 원활하게 이루어지도록 작용할 수 있다.In one embodiment, the cosmetic composition for lips of the present invention may contain a large amount of volatile oil, the volatile oil is isododecane, isohexadecane, C7-8 isoparaffin, C8-9 isoparaffin, C10-11 Isoparaffin, C10-13 isoparaffin, C11-12 isoparaffin, C11-13 isoparaffin, C13-14 isoparaffin, methyltrimethicone, caprylylmethicone, cyclomethicone, cyclotetrasiloxane, cyclopentasiloxane and cyclo It may include any one or more selected from the group consisting of hexasiloxane, etc., but is not limited thereto. The volatile oil may act to smoothly form a film of the coating agent while being volatilized when the lips are applied.

일 실시예에서, 상기 휘발성 오일은 조성물 총 중량 대비 50~90 중량%, 바람직하게 60~80 중량%로 포함될 수 있다. 상기 휘발성 오일이 50 중량% 미만일 경우에는 제형 내 다른 성분들이 충분히 분산되지 않을 수 있으며, 90 중량% 초과일 경우에는 화장료의 사용감이 저해될 수 있다.In an embodiment, the volatile oil may be included in 50 to 90% by weight, preferably 60 to 80% by weight, based on the total weight of the composition. If the volatile oil is less than 50% by weight, other ingredients in the formulation may not be sufficiently dispersed, and if it is more than 90% by weight, the feeling of use of the cosmetic may be impaired.

일 실시예에서, 본 발명의 입술용 화장료 조성물은 피막제를 포함할 수 있으며, 상기 피막제는 아크릴레이트/폴리트라이메틸실록시메타크릴레이트 코폴리머, 트리메틸실록시실리케이트, 폴리프로필실세스퀴옥산, 폴리메틸실세스퀴옥산, 디메티콘/비닐트리메틸실록시실리케이트 크로스폴리머, 트리메틸실록시실리케이트/디메티콘올 크로스폴리머, 트리메틸실록시실릴카바모일 풀루란 폴리비닐알콜, 폴리비닐피롤리돈, 아크릴레이트계 공중합체, 및 비닐피롤리돈계 공중합체 등으로 이루어진 군에서 선택된 어느 하나 이상을 포함할 수 있으나, 이에 제한되는 것은 아니다. 상기 피막제는 조성물 총 중량 대비 5~40 중량%, 바람직하게 10~30 중량%, 더욱 바람직하게 15~25 중량%로 포함될 수 있다. 상기 피막제가 5 중량% 미만일 경우에는 입술 위 피막 형성이 불충분하여 지속성이 감소될 수 있으며, 40 중량% 초과일 경우에는 제형 안정성이 저해될 수 있다.In one embodiment, the cosmetic composition for lips of the present invention may include a coating agent, and the coating agent is an acrylate/polytrimethylsiloxymethacrylate copolymer, trimethylsiloxysilicate, polypropylsilsesquioxane, poly Methylsilsesquioxane, dimethicone/vinyltrimethylsiloxysilicate crosspolymer, trimethylsiloxysilicate/dimethiconol crosspolymer, trimethylsiloxysilylcarbamoyl pullulan polyvinyl alcohol, polyvinylpyrrolidone, acrylate-based copolymer It may include any one or more selected from the group consisting of coalescence and vinylpyrrolidone-based copolymer, but is not limited thereto. The coating agent may be included in an amount of 5 to 40% by weight, preferably 10 to 30% by weight, and more preferably 15 to 25% by weight, based on the total weight of the composition. If the coating agent is less than 5% by weight, the film formation on the lips may be insufficient and the persistence may be reduced, and when it is more than 40% by weight, the stability of the formulation may be impaired.

일 실시예에서, 본 발명의 입술용 화장료 조성물은 비휘발성 오일을 실질적으로 포함하지 않을 수 있다. 구체적으로, 상기 비휘발성 오일을 실질적으로 포함하지 않는 조성물은 비휘발성 오일을 조성물 총 중량 대비 5 중량% 이하, 바람직하게 3 중량% 이하, 더욱 바람직하게 1 중량% 이하로 포함할 수 있으며, 가장 바람직하게 전혀 포함하지 않을 수 있다. 본 발명의 입술용 화장료 조성물은 비휘발성 오일을 실질적으로 포함하지 않음으로써, 물 또는 오일에 잘 지워지지 않아 지속성이 향상되고, 촉촉하고 부드러운 사용감이 부여된다.In one embodiment, the cosmetic composition for lips of the present invention may substantially contain no non-volatile oil. Specifically, the composition substantially free of non-volatile oil may contain 5% by weight or less, preferably 3% by weight or less, more preferably 1% by weight or less, based on the total weight of the composition, and most preferably May not be included at all. Since the cosmetic composition for lips of the present invention substantially does not contain non-volatile oil, it is not easily removed by water or oil, so that the durability is improved, and a moist and soft feeling of use is provided.

본 발명에 있어서, 비휘발성 오일은 카프릴릭/카프릭트리글리세라이드, 트리에칠헥사노인, 디이소스테아릴말레이트, 트리데실트리멜리테이트, 펜타에리스리틸테트라이소스테아레이트, 트리이소스테아린, 디글리세릴세바케이트/이소팔미테이트, 피토스테릴/이소스테아릴/세틸/스테아릴/베헤닐다이머디리놀리에이트, 디펜타에리스리틸헥사하이드록시스테아레이트/헥사스테아레이트/헥사로지네이트, 피토스테릴/이소스테아릴/세틸/스테아릴/베헤닐다이머디리놀리에이트, 하이드로제네이티드캐스터오일이소스테아레이트, 디메치콘크로스폴리머, 디메치콘/비닐디메치콘크로스폴리머, 피이지-12디메치콘/피피지-20크로스폴리머 등으로 이루어진 군으로부터 선택된 어느 하나 이상일 수 있으나, 이에 제한되는 것은 아니다.In the present invention, the non-volatile oil is caprylic/capric triglyceride, triethylhexanoin, diisostearylmalate, tridecyltrimelitate, pentaerythrityl tetraisostearate, triisostearin, di Glyceryl sebacate/isopalmitate, phytosteryl/isostearyl/cetyl/stearyl/behenyldimerdilinoleate, dipentaerythritylhexahydroxystearate/hexastearate/hexaloginate, phytosteryl /Isostearyl/cetyl/stearyl/behenyldimerdilinoleate, hydrogenated castor oil isostearate, dimethicone crosspolymer, dimethicone/vinyldimethicone crosspolymer, PEG-12dimethicone/PP -20 may be any one or more selected from the group consisting of crosspolymers, etc., but is not limited thereto.

일 실시예에서, 본 발명의 입술용 화장료 조성물은 불소계 오일 및 불소계 실리콘 왁스를 1:0.1~10, 바람직하게 1:0.5~7, 더욱 바람직하게 1:1~5, 가장 바람직하게 1:2~4의 중량비(불소계 오일:불소계 실리콘 왁스)로 포함할 수 있다. 본 발명의 조성물이 불소계 오일 및 불소계 실리콘 왁스를 상기 중량비로 포함하는 경우 제형 안정성, 화장 지속성 및 사용감이 현저하게 상승한다.In one embodiment, the cosmetic composition for lips of the present invention comprises a fluorine-based oil and a fluorine-based silicone wax of 1:0.1 to 10, preferably 1:0.5 to 7, more preferably 1:1 to 5, and most preferably 1:2 to It may be included in a weight ratio of 4 (fluorine-based oil: fluorine-based silicone wax). When the composition of the present invention contains a fluorine-based oil and a fluorine-based silicone wax in the weight ratio, formulation stability, makeup persistence, and feeling of use are remarkably increased.

일 실시예에서, 본 발명의 입술용 화장료 조성물의 점도(cPs)는 8000 내지 25000, 바람직하게 10000 내지 20000, 더욱 바람직하게 12000 내지 18000일 수 있다. 상기 점도는 Spindle Number 4, 30 rpm, 상온 조건에서 측정될 수 있다. 상기 점도가 8000 미만일 경우에는 제형의 분리 현상이 일어날 수 있고, 25000 초과일 경우에는 점도가 과도하게 높아 사용감이 저해될 수 있다.In one embodiment, the viscosity (cPs) of the cosmetic composition for lips of the present invention may be 8000 to 25000, preferably 10000 to 20000, more preferably 12000 to 18000. The viscosity can be measured under Spindle Number 4, 30 rpm, and room temperature conditions. When the viscosity is less than 8000, separation of the formulation may occur, and when the viscosity is more than 25000, the viscosity is excessively high, and the feeling of use may be inhibited.

일 실시예에서, 본 발명의 입술용 화장료 조성물은 선명한 색상을 부여하기 위해 색소를 포함할 수 있으며, 상기 색소는 당업계에서 통상적으로 사용되는 것이라면 제한되지 않고 사용될 수 있다. 예를 들어, 상기 색소는 황색 203호, 황색 4호, 황색 5호, 황색 201호, 황색 204호, 적색 103호, 적색 104호, 적색 201호, 적색 202호, 적색 218호, 적색 220호, 적색 223호, 적색 226호, 적색 227호, 적색 203호, 적색 산화철, 청색1호, 청색 2호, 티타늄디옥사이드 등으로 이루어진 군에서 선택된 어느 하나 이상을 포함할 수 있으나, 이에 제한되지 않는다. 상기 색소는 조성물 총 중량 대비 0.1 내지 30 중량%, 바람직하게 0.1 내지 20 중량%, 더욱 바람직하게 1 내지 15 중량%로 포함될 수 있다. 상기 색소가 0.1 중량% 미만일 경우에는 발색력이 불충분할 수 있으며, 30 중량% 초과일 경우에는 제형 안정성이 떨어질 수 있다.In one embodiment, the cosmetic composition for lips of the present invention may include a pigment to impart a vivid color, and the pigment may be used without limitation as long as it is commonly used in the art. For example, the pigment is Yellow No. 203, Yellow No. 4, Yellow No. 5, Yellow No. 201, Yellow No. 204, Red No. 103, Red No. 104, Red No. 201, Red No. 202, Red No. 218, Red No. 220 , Red No. 223, Red No. 226, Red No. 227, Red No. 203, Red Iron Oxide, Blue No. 1, Blue No. 2, Titanium Dioxide, and the like may be included, but are not limited thereto. The pigment may be included in an amount of 0.1 to 30% by weight, preferably 0.1 to 20% by weight, and more preferably 1 to 15% by weight, based on the total weight of the composition. If the pigment is less than 0.1% by weight, the color development power may be insufficient, and if it is more than 30% by weight, the formulation stability may be deteriorated.

일 실시예에서, 본 발명의 입술용 화장료 조성물은 유분산 제형으로 제조될 수 있으며, 피부에 도포될 수 있는 립글로스 또는 립크림 등의 액상 제형으로 제조될 수 있다. 본 발명에 따른 입술용 화장료 조성물은 상기 성분들 외에 소포제, 왁스, 점증제, 분체계 점증제, 산화방지제, 피부연화제, 보습제, 진정제, 윤활제, 방부제, 보습제, 자외선흡수제, 및 향료 등으로 이루어진 군에서 선택된 하나 이상의 첨가제를 추가로 포함할 수 있다.In one embodiment, the cosmetic composition for lips of the present invention may be prepared in an oil dispersion formulation, and may be prepared in a liquid formulation such as lip gloss or lip cream that may be applied to the skin. In addition to the above ingredients, the cosmetic composition for lips according to the present invention is a group consisting of antifoam, wax, thickener, powder thickener, antioxidant, emollient, moisturizer, soothing agent, lubricant, preservative, moisturizer, ultraviolet absorber, and fragrance. It may further include one or more additives selected from.

일 실시예에서, 본 발명은 조성물 총 중량 대비 불소계 오일 0.1~5 중량%, 불소계 실리콘 왁스 0.5~10 중량%, 휘발성 오일 50~90 중량%, 및 피막제 5~40 중량%을 포함하는 입술용 화장료 조성물을 제공한다. 상기 각 성분을 특정한 함량으로 포함하는 조성물은 비휘발성 오일을 포함하지 않으면서도, 입술용 화장료 제형에 촉촉하고 부드러운 사용감을 부여하고, 물 또는 오일에 잘 지워지지 않아 지속성이 우수할뿐만 아니라, 제형 안정성이 현저하게 우수하다.In one embodiment, the present invention is a lip cosmetic comprising 0.1 to 5% by weight of fluorine-based oil, 0.5 to 10% by weight of fluorine-based silicone wax, 50 to 90% by weight of volatile oil, and 5 to 40% by weight of a coating agent based on the total weight of the composition The composition is provided. The composition containing each of the above ingredients in a specific amount does not contain non-volatile oils, but gives a moist and soft feeling of use to the lip cosmetic formulation, and is not easily erased by water or oil, so it has excellent durability and stability of the formulation. Remarkably excellent.

본 발명의 입술용 화장료 조성물은 사용감이 촉촉하고 부드러워 건조감이 개선되고, 물 또는 오일에 잘 지워지지 않아 지속성이 우수할뿐만 아니라, 높은 점도를 가져 제형 안정성이 현저하게 우수하다.The cosmetic composition for lips of the present invention has a moist and soft feeling of use, which improves dryness, is not easily erased by water or oil, has excellent persistence, and has a high viscosity, so that the formulation stability is remarkably excellent.

도 1은 실시예 및 비교예 1~3의 화장 지속성을 평가한 사진이다.1 is a photograph of evaluating the makeup persistence of Examples and Comparative Examples 1 to 3.

도 2는 휘발성 오일의 휘발 후 피막제 및 점증제의 결합 구조를 나타낸 피막 형성 모식도이다.2 is a schematic diagram of film formation showing a bonding structure of a film agent and a thickener after volatilization of volatile oil.

도 3은 입술용 화장료 조성물의 사용 후 피막이 형성된 입술의 모식도이다.3 is a schematic diagram of a lip formed with a film after use of a cosmetic composition for lips.

이하, 본 발명의 이해를 돕기 위하여 실시예 등을 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 하기 실시예들에 한정되는 것으로 해석되어서는 안 된다. 본 발명의 실시예들은 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해 제공되는 것이다.Hereinafter, examples, etc. will be described in detail to aid understanding of the present invention. However, the embodiments according to the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the following examples. The embodiments of the present invention are provided to more completely explain the present invention to those of ordinary skill in the art.

실시예 및 비교예 1 내지 3의 제조Preparation of Examples and Comparative Examples 1 to 3

하기 표 1에 개시된 성분으로 실시예 및 비교예 1 내지 3의 화장료 조성물을 제조하였다. 먼저, 이소도데칸에 아크릴레이트/폴리트라이메틸실록시메타크릴레이트 코폴리머를 상온에서 디스퍼 믹서로 분산 용해시켰다. 이후, 디스테아디모늄 헥토라이트와 프로필렌 카보네이트를 투입 후 80~85℃에서 10분 이상 가온 분산시켰다. 이후, 하기 표 1의 조성으로 원료들을 혼합하여 80~85℃ 조건에서 분산, 탈포 및 상온 냉각해줌으로써 실시예 및 비교예의 화장료 조성물을 제조하였다.The cosmetic compositions of Examples and Comparative Examples 1 to 3 were prepared with the ingredients disclosed in Table 1 below. First, an acrylate/polytrimethylsiloxymethacrylate copolymer was dispersed and dissolved in isododecane with a disper mixer at room temperature. Thereafter, disteadimonium hectorite and propylene carbonate were added, followed by heating and dispersing at 80 to 85° C. for 10 minutes or more. Thereafter, the cosmetic compositions of Examples and Comparative Examples were prepared by mixing the raw materials according to the composition of Table 1 below, and dispersing, degassing, and cooling at room temperature at 80 to 85°C.

구분division 성분명Ingredient name 실시예Example 비교예1Comparative Example 1 비교예2Comparative Example 2 비교예3Comparative Example 3 휘발성 오일Volatile oil 이소도데칸Isododecane 잔량Balance 잔량Balance 잔량Balance 잔량Balance 소포제Antifoam 디메치콘Dimethicone 0.20.2 0.20.2 0.20.2 0.20.2 왁스Wax 글리세릴베헤네이트/에이코사디오에이트Glyceryl Behenate/Ecosadioate 33 33 33 33 피막제Coating agent 아크릴레이트/폴리트라이메틸실록시메타크릴레이트 코폴리머Acrylate/Polytrimethylsiloxymethacrylate Copolymer 2020 2020 2020 2020 분체계 점증제Split system thickener 디스테아디모늄 헥토라이트Disteadimonium hectorite 66 66 66 66 점증제Thickener 프로필렌 카보네이트Propylene carbonate 22 22 22 22 산화방지제Antioxidant 1,2-헥산디올1,2-hexanediol 1One 1One 1One 1One 불소계 오일Fluorine oil 폴리퍼플루오로메틸이소프로필 에테르Polyperfluoromethylisopropyl ether 1One 1One -- -- 불소계 실리콘 왁스Fluorine silicone wax 퍼플루오로 노닐에틸 스테아릴 디메티콘Perfluoro nonylethyl stearyl dimethicone 33 -- -- -- 비휘발성 오일Nonvolatile oil 디소스테아릴 말레이트Disostearyl malate -- -- 33 -- 색소Pigment 적색 201호Red No. 201 0.60.6 0.60.6 0.60.6 0.60.6 색소Pigment 적색 산화철Red iron oxide 22 22 22 22 색소Pigment 티타늄디옥사이드Titanium dioxide 33 33 33 33

(단위: 중량%)(Unit: wt%)

실험예 1: 제형 안정성Experimental Example 1: Formulation stability

제형의 분리 여부는 실온 조건에서 1주일차에 경시 안정성으로 확인하였다. 제형이 분리되지 않는 적당한 점도는 Spindle Number 4, 30 rpm, 및 상온 조건에서 최소 8,000 cPs 이상이다. 하기 표 2에 실시예 및 비교예 1~3의 제형 안정성 평가 결과를 나타내었다.Whether or not the formulation was separated was confirmed by stability over time at the first week at room temperature. A suitable viscosity at which the formulation does not separate is at least 8,000 cPs at Spindle Number 4, 30 rpm, and room temperature conditions. Table 2 below shows the formulation stability evaluation results of Examples and Comparative Examples 1 to 3.

구분division 실시예Example 비교예1Comparative Example 1 비교예2Comparative Example 2 비교예3Comparative Example 3 점도 cpsViscosity cps 15,70015,700 10,10010,100 7,0007,000 12,40012,400 분리여부Separation 안정stability 분리detach 분리detach 안정stability

비휘발성 오일이 처방된 비교예 2는 처방되지 않은 비교예 3보다 점도가 크게 감소하여 제형 분리가 발생하였다. 한편, 비교예 1의 점도는 8,000 cPs 이상이지만 불소계 오일이 안정화되지 않아 분리 현상이 발생된 것을 확인하였다. 반면, 불소계 실리콘 왁스가 처방된 실시예는 오일 분리가 일어나지 않아 제형 안정성이 우수함을 확인하였다. 즉, 기존의 처방되던 왁스 또는 점증제로는 불소계 오일을 안정화시킬 수 없으나, 불소계 실리콘 왁스를 처방함으로써 제형 안정성을 현저하게 상승시킬 수 있음을 확인하였다.Comparative Example 2, in which non-volatile oil was prescribed, had a significantly reduced viscosity compared to Comparative Example 3, which was not prescribed, and thus formulation separation occurred. On the other hand, although the viscosity of Comparative Example 1 is 8,000 cPs or more, it was confirmed that the fluorine-based oil was not stabilized and thus a separation phenomenon occurred. On the other hand, it was confirmed that the examples in which the fluorine-based silicone wax was prescribed had excellent formulation stability because oil separation did not occur. That is, it was confirmed that the fluorine-based oil could not be stabilized with the conventional wax or thickener, but formulation stability could be remarkably increased by prescribing a fluorine-based silicone wax.

또한, 상기 실시예의 불소계 실리콘 왁스 3 중량% 대신, INCI명이 동일하며 불소계 실리콘 오일인 액체 타입의 퍼플루오로 노닐에틸 스테아릴 디메티콘 3 중량%로 처방 시(비교예 4) 12,800 cPs의 점도가 형성되지만, 오일이 빠르게 분리되어 제형 안정성을 확보하기 어려움을 확인하였다.In addition, instead of 3% by weight of the fluorine-based silicone wax of the above embodiment, when prescribed with 3% by weight of liquid perfluoro nonylethyl stearyl dimethicone with the same INCI name and a fluorine-based silicone oil (Comparative Example 4), a viscosity of 12,800 cPs was formed. However, it was confirmed that it was difficult to secure the formulation stability due to the rapid separation of the oil.

실험예 2: 화장 지속성Experimental Example 2: Cosmetic persistence

지속성은 묻어남, 번짐, 및 내유성에 대한 평가로 진행하였다. 먼저 인조피혁에 실시예 또는 비교예 각각의 조성물을 도포 후, SI 1107 80mmm 4 side applicator를 이용하여 60 마이크로미터의 두께로 제형을 균일하게 도포하고 15분 건조하였다.Persistence was evaluated for burying, smearing, and oil resistance. First, after applying the composition of each of the examples or comparative examples to artificial leather, the formulation was uniformly applied to a thickness of 60 micrometers using an SI 1107 80mmm 4 side applicator and dried for 15 minutes.

묻어남을 측정하는 방법으로는 제형이 건조된 인조피혁 위에 흰 종이를 올려두고, 4.5 kg의 무게의 추로 10초간 눌러서 종이에 묻어나는 정도를 색차계로 측정하였다.As a method of measuring burying, a white paper was placed on the artificial leather of which the formulation was dried and pressed with a weight of 4.5 kg for 10 seconds, and the degree of burying on the paper was measured with a colorimeter.

또한, 번짐을 측정하는 실험 방법으로는 제형이 건조된 인조피혁 위에 흰 종이를 올려두고 1.5 kg의 무게의 추로 누르는 조건에서 흰 종이를 잡아당겨 빼내어 종이에 번져 묻어나는 정도를 색차계로 측정하였다.In addition, as an experimental method for measuring bleeding, a white paper was placed on the artificial leather of which the formulation was dried, and the white paper was pulled out under conditions of pressing with a weight of 1.5 kg, and the degree of smearing on the paper was measured with a colorimeter.

또한, 식사 시 오일에 대한 지워짐을 확인하기 위해 식용유에 대한 내유성을 평가하였다. 제형이 건조된 인조피혁 위에 마이크로피펫을 이용해 10 마이크로리터의 카놀라유를 떨어뜨린 후 골고루 도포하고, 1분 뒤 페이퍼필터의 거친면을 대고 M1급 1kg 원형 분동을 10회 회전하며 음식 섭취시에 위아래 입술의 전단력을 구현하였으며, 이후 페이퍼필터에 묻어나는 정도를 색차계로 측정하였다. In addition, oil resistance to edible oil was evaluated in order to confirm that the oil is erased when eating. Apply 10 microliters of canola oil using a micropipette on the dried artificial leather, apply evenly, and after 1 minute, rotate the M1 grade 1kg round weight 10 times against the rough side of the paper filter. The shear force of was implemented, and the degree of burying on the paper filter was then measured with a colorimeter.

사용한 색차계의 기종은 KONICA MINOLTA CHROMA METER CR-400이다. BLANK로 깨끗한 흰 종이를 랜덤하게 3회 측정하여 묻어남 또는 번짐의 평균값을 계산하였고(L1,a1,b1), 위 조건으로 측정한 종이를 랜덤하게 3회 측정하여 묻어남 또는 번짐의 평균값을 계산하였다(L2,a2,b2). 측정값은 L(Lightness), a(red-green chromaticity), b(yellow blue chromaticity)로 표기되며, 하기의 식과 같이 △E 값을 계산하여 도포 직후 색상과 종이에 묻어나는 색상의 차이 정도를 수치화하였다.The model of the color difference meter used is KONICA MINOLTA CHROMA METER CR-400. The average value of smearing or smearing was calculated by randomly measuring clean white paper three times with BLANK (L1, a1, b1), and the average value of smearing or smearing was calculated by randomly measuring the paper measured in the above conditions three times. Was (L2,a2,b2). The measured values are expressed as L(Lightness), a(red-green chromaticity), and b(yellow blue chromaticity), and the degree of difference between the color immediately after application and the color on the paper is quantified by calculating the △E value as shown below. I did.

△E= {(L1-L2) 2 +(a1-a2) 2+(b1-b2) 2} 1/2 △E= {(L1-L2) 2 +(a1-a2) 2 +(b1-b2) 2 } 1/2

△E가 1 이하일 경우, 육안으로 색상 확인이 불가능한 수준으로 묻어남과 번짐의 정도가 우수함을 나타낸다. 하기 표 3에 실시예 및 비교예 1~3의 화장 지속성 평가 결과를 나타내었다.If △E is less than 1, it indicates that the degree of burying and bleeding is excellent at a level that cannot be visually checked. Table 3 below shows the results of the cosmetic persistence evaluation of Examples and Comparative Examples 1 to 3.

구분division 실시예Example 비교예1Comparative Example 1 비교예2Comparative Example 2 비교예3Comparative Example 3 묻어남ΔEBuriedΔE 0.410.41 0.510.51 1.351.35 0.540.54 번짐ΔESmear ΔE 0.880.88 0.960.96 3.843.84 0.490.49 내유성ΔEOil resistanceΔE 2.132.13 3.963.96 9.119.11 5.045.04

상기 표 3에 나타난 결과를 볼 때, 비교예 2는 비교예 3과 비교하여 비휘발성 오일인 디이소스테아릴말레이트가 3 중량% 추가된 경우에 해당하는데, 이 경우에 묻어남, 번짐 및 오일 내유성 수치가 크게 증가하여 즉 지속성이 크게 감소했음을 확인할 수 있었다. 반면, 불소계 오일이 처방된 비교예 1에서 묻어남 및 번짐 △E 수치는 1 미만으로 식별 불가한 수준이고, 내유성 △E 수치도 비교예 2에 비해 작아 오일 내유성은 더 증가했음을 확인하였다.When looking at the results shown in Table 3, Comparative Example 2 corresponds to a case in which 3% by weight of diisostearylmaleate, which is a nonvolatile oil, is added compared to Comparative Example 3, in which case smearing, smearing and oil It was confirmed that the oil resistance value increased significantly, that is, the persistence decreased significantly. On the other hand, in Comparative Example 1 where fluorine-based oil was prescribed, the level of staining and bleeding ΔE was less than 1, which was unidentifiable, and the oil resistance ΔE value was also smaller than that of Comparative Example 2, confirming that the oil resistance was further increased.

불소계 오일 및 불소계 실리콘 왁스가 처방된 실시예는 묻어남과 번짐 △E 수치가 1 미만이었으며, 내유성 △E 수치도 가장 낮은 값을 보여 지속성이 가장 우수함을 확인할 수 있다.In the examples in which fluorine-based oil and fluorine-based silicone wax were prescribed, the staining and bleeding △E value was less than 1, and the oil resistance △E value was also the lowest, indicating that the persistence was the most excellent.

도 1은 오일 내유성 측정 후, 필터페이퍼에 각각의 제형의 묻어남 정도를 확인한 결과이며, 도 1에 나타난 차이를 볼 때 실시예의 지속성이 가장 우수함을 확인할 수 있다. FIG. 1 is a result of confirming the degree of burying of each formulation on the filter paper after measuring the oil and oil resistance, and when looking at the difference shown in FIG. 1, it can be confirmed that the persistence of the embodiment is the best.

실험예 3: 관능 평가Experimental Example 3: Sensory evaluation

20대에서 30대 여성 16명을 대상으로 발림성, 건조감, 식사 후 지속성 평가를 진행하였다. 항목별 5점 척도(1점: 아주 나쁨, 3점: 보통, 5점: 아주 좋음)으로 비교 평가하였고, 각 항목당 평균값으로 하기 표 4에 나타내었다.Applicability, dryness, and persistence after eating were evaluated on 16 women in their 20s to 30s. Each item was evaluated on a 5-point scale (1 point: very bad, 3 points: average, 5 points: very good), and the average values for each item are shown in Table 4 below.

구분division 실시예Example 비교예1Comparative Example 1 비교예2Comparative Example 2 비교예3Comparative Example 3 발림성Spreadability 4.24.2 4.04.0 3.83.8 2.62.6 건조감Dryness 4.44.4 3.63.6 4.34.3 2.02.0 지속력vitality 4.54.5 3.63.6 1.91.9 3.23.2

상기 평가 결과를 볼 때, 비휘발성 오일이 처방된 비교예 2에서는 비교예 3에 비해 건조감은 매우 우수하지만 지속력이 크게 떨어졌다. 불소계 오일이 처방된 비교예 1은 발림성, 건조감 및 지속력이 비교예 3에 비해 모두 증가했다. 비교예 1에 추가로 불소계 실리콘 왁스가 처방된 실시예는 왁스 사용으로 인한 발림성이 더 좋아졌고 건조감 및 지속력 모두 비교예 1과 3에 비해 현저하게 우수한 것을 확인할 수 있다.As a result of the evaluation, in Comparative Example 2, in which non-volatile oil was prescribed, the dryness was very excellent compared to Comparative Example 3, but the lasting power was significantly decreased. In Comparative Example 1, in which a fluorine-based oil was prescribed, spreadability, dryness, and durability were all increased compared to Comparative Example 3. It can be seen that the example in which the fluorine-based silicone wax was prescribed in addition to Comparative Example 1 improved the spreadability due to the use of the wax, and was significantly superior to Comparative Examples 1 and 3 in both dryness and lasting power.

Claims (14)

불소계 오일 및 불소계 실리콘 왁스를 포함하는 입술용 화장료 조성물.Lip cosmetic composition comprising a fluorine-based oil and a fluorine-based silicone wax. 제1항에 있어서, 상기 불소계 오일은 폴리퍼플루오로메틸이소프로필에테르, 폴리퍼플루오로에톡시메톡시 디플루오로에틸 PEG 포스페이트, 폴리퍼플루오로에톡시메톡시 디플루오로하이드록시에틸 에테르, 폴리옥시퍼플루오로알칸, 퍼플루오로폴리메칠에테르, 퍼플루오리네이티드폴리에테르, 퍼플루오로데칼린, 퍼플루오로디메틸사이클로헥산, 및 퍼플루오로메틸사이클로펜탄으로 이루어진 군으로부터 선택된 어느 하나 이상을 포함하는 입술용 화장료 조성물.The method of claim 1, wherein the fluorine-based oil is polyperfluoromethylisopropyl ether, polyperfluoroethoxymethoxy difluoroethyl PEG phosphate, polyperfluoroethoxymethoxy difluorohydroxyethyl ether, Including any one or more selected from the group consisting of polyoxyperfluoroalkane, perfluoropolymethylether, perfluorinated polyether, perfluorodecalin, perfluorodimethylcyclohexane, and perfluoromethylcyclopentane Cosmetic composition for lips. 제1항에 있어서, 상기 불소계 오일은 조성물 총 중량 대비 0.1~5 중량%인 입술용 화장료 조성물.The cosmetic composition for lips of claim 1, wherein the fluorine-based oil is 0.1 to 5% by weight based on the total weight of the composition. 제1항에 있어서, 상기 불소계 실리콘 왁스는 퍼플루오로노닐에틸스테아릴디메티콘인 입술용 화장료 조성물.The cosmetic composition for lips according to claim 1, wherein the fluorine-based silicone wax is perfluorononylethylstearyldimethicone. 제4항에 있어서, 상기 퍼플루오로노닐에틸스테아릴디메티콘은 하기 화학식 2로 표시되며 상온에서 고체인, 입술용 화장료 조성물The cosmetic composition for lips according to claim 4, wherein the perfluorononylethylstearyldimethicone is represented by the following formula (2) and is solid at room temperature. [화학식 2][Formula 2]
Figure PCTKR2020003261-appb-img-000002
Figure PCTKR2020003261-appb-img-000002
상기 l, m, n은 서로 독립적으로 1 내지 100중 어느 하나의 정수이며,The l, m, n are each independently an integer of 1 to 100, 상기 n/m은 1 내지 20임.The n/m is 1 to 20.
제1항에 있어서, 상기 불소계 실리콘 왁스는 조성물 총 중량 대비 0.5~10 중량%인 입술용 화장료 조성물.The cosmetic composition for lips according to claim 1, wherein the fluorine-based silicone wax is 0.5 to 10% by weight based on the total weight of the composition. 제1항에 있어서, 상기 조성물은 추가로 휘발성 오일을 포함하는 입술용 화장료 조성물.The cosmetic composition for lips according to claim 1, wherein the composition further comprises a volatile oil. 제7항에 있어서, 상기 휘발성 오일은 조성물 총 중량 대비 50~90 중량%인 입술용 화장료 조성물.The cosmetic composition for lips according to claim 7, wherein the volatile oil is 50 to 90% by weight based on the total weight of the composition. 제1항에 있어서, 상기 조성물은 추가로 피막제를 포함하는 입술용 화장료 조성물.The cosmetic composition for lips according to claim 1, wherein the composition further comprises a coating agent. 제9항에 있어서, 상기 피막제는 조성물 총 중량 대비 5~40 중량%인 입술용 화장료 조성물.The cosmetic composition for lips according to claim 9, wherein the coating agent is 5 to 40% by weight based on the total weight of the composition. 제1항에 있어서, 상기 조성물은 비휘발성 오일을 실질적으로 포함하지 않는 입술용 화장료 조성물.The cosmetic composition for lips according to claim 1, wherein the composition does not contain a nonvolatile oil substantially. 제1항에 있어서, 상기 조성물은 불소계 오일 및 불소계 실리콘 왁스를 1:0.1~10의 중량비(불소계 오일:불소계 실리콘 왁스)로 포함하는 입술용 화장료 조성물.The cosmetic composition for lips according to claim 1, wherein the composition comprises a fluorine-based oil and a fluorine-based silicone wax in a weight ratio of 1:0.1 to 10 (fluorine-based oil: fluorine-based silicone wax). 제1항에 있어서, 상기 조성물의 점도는 8000 내지 25000 cPs인 입술용 화장료 조성물.The cosmetic composition for lips according to claim 1, wherein the composition has a viscosity of 8000 to 25000 cPs. 조성물 총 중량 대비 불소계 오일 0.1~5 중량%, 불소계 실리콘 왁스 0.5~10 중량%, 휘발성 오일 50~90 중량%, 및 피막제 5~40 중량%을 포함하는 입술용 화장료 조성물.A cosmetic composition for lips comprising 0.1 to 5% by weight of fluorine-based oil, 0.5 to 10% by weight of fluorine-based silicone wax, 50 to 90% by weight of volatile oil, and 5 to 40% by weight of a coating agent based on the total weight of the composition.
PCT/KR2020/003261 2019-05-21 2020-03-09 Lip cosmetic composition with improved longevity and dryness Ceased WO2020235789A1 (en)

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