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WO2019038650A1 - Composition de biocarburant hydrocarboné et procédé de préparation associé - Google Patents

Composition de biocarburant hydrocarboné et procédé de préparation associé Download PDF

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Publication number
WO2019038650A1
WO2019038650A1 PCT/IB2018/056259 IB2018056259W WO2019038650A1 WO 2019038650 A1 WO2019038650 A1 WO 2019038650A1 IB 2018056259 W IB2018056259 W IB 2018056259W WO 2019038650 A1 WO2019038650 A1 WO 2019038650A1
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WO
WIPO (PCT)
Prior art keywords
range
alcohol
ethyl
formate
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2018/056259
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English (en)
Inventor
Ramar R.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyedatore M Mahadevaiah
Original Assignee
Kyedatore M Mahadevaiah
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Filing date
Publication date
Application filed by Kyedatore M Mahadevaiah filed Critical Kyedatore M Mahadevaiah
Publication of WO2019038650A1 publication Critical patent/WO2019038650A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only

Definitions

  • the present disclosure relates to the field of hydrocarbon fuels.
  • Bio-hydrocarbons are second generation biofuels and are derived from lignocellulosic biomass such as trees, grasses, waste, agricultural or forest residues, or algae. These fuels are not produced using agricultural commodities like corn, sugarcane, soybean, etc.
  • Bio-hydrocarbons do not require significant modification in either the existing fuel distribution infrastructure and also the vehicle engine.
  • Advanced bio-hydrocarbon fuels are also known as drop-in fuel.
  • the energy content of advanced bio-hydrocarbon fuels is equivalent to that of their petroleum-based counterparts.
  • Bio-hydrocarbon fuel can be obtained.
  • biomass is defined as organic matter obtained from agriculture or agriculture products.
  • Many side -products of foods are inefficiently used, leading to large amounts of organic waste.
  • Use of such waste as a fuel per se or as a blend compatible with existing petroleum based fuels could extend limited petroleum reserves, reduce organic waste and, depending on the processing of the organic waste, provide a less expensive alternate fuel or fuel blends.
  • biomass such as fermentation, gasification, pyrolysis and algal conversion.
  • Biomass sources have been explored as fuel source alternatives to petroleum.
  • Conventional bio-hydrocabon fuel contains various unsaturated hydrocarbons due to which large amount of carbon-monoxide is emitted and cause environment pollution.
  • the primary object of the present disclosure is to provide a composition for a bio- hydrocarbon fuel.
  • the present disclosure envisages a bio-hydrocarbon fuel composition.
  • the bio- hydrocarbon fuel composition comprises the following ingredients; limonene in the range of 2-60 wt.%, benzoyl peroxide in the range of 1-5 wt.%., isopropyl alcohol in the range of 1- 5wt.
  • % glycerine in the range of 5-25wt.%, tetrahydrofuran in the range of 10-40wt.%, tertiary butyl alcohol in the range of 10-20wt.%, ethyl formate in the range of 5-30wt.%, methyl formate in the range of 10-30wt.%, methyl alcohol in the range of 5-25wt.%, cyclopentane in the range of 2-10wt.%, ethyl alcohol in the range of 22-40 wt.%, and calcium carbide in the range of 10-50wt.%.
  • the bio-hydrocarbon fuel composition comprises limonene(19wt.%), benzoyl peroxide (lwt.%), isopropyl alcohol (lwt.%), glycerine (5wt.%), tetrahydrofuran (10wt.%), tertiary butyl alcohol (10wt.%), ethyl formate (5wt.%), methyl formate (10wt.%), methylalcohol (5wt.%), cyclopentane (2wt.%), ethyl alcohol (22wt.%) and calcium carbide (10wt.%).
  • the present disclosure envisages a method for preparing a bio-hydrocarbon fuel comprising homogeneously mixing the following ingredients; limonene in the range of 2-60 wt.%, benzoyl peroxide in the range of 1-5 wt.%., isopropyl alcohol in the range of 1- 5wt.
  • the present disclosure envisages a composition for bio-hydrocarbon fuel that reduces emission of carbon monoxide and is eco-friendly.
  • the bio-hydrocarbon fuel composition comprises limonene in the range of 2-60 wt.%, benzoyl peroxide in the range of 1-5 wt.%., isopropyl alcohol in the range of l-5wt. %, glycerine in the range of 5-25wt.%, tetrahydrofuran in the range of 10-40wt.%, tertiary butyl alcohol in the range of 10-20wt.%, ethyl formate in the range of 5-30wt.%, methyl formate in the range of 10-30wt.%, methyl alcohol in the range of 5-25wt.%, cyclopentane in the range of 2-10wt.%, ethyl alcohol in the range of 22-40wt.%, and calcium carbide in the range of 10- 50wt.%.
  • the bio-hydrocarbon fuel composition comprises limonene (19wt.%), benzoyl peroxide (lwt.%), isopropyl alcohol (lwt.%), glycerine (5wt.%), tetrahydrofuran (10wt.%), tertiary butyl alcohol (10wt.%), ethyl formate (5wt.%), methyl formate (10wt.%), methylalcohol (5wt.%), cyclopentane (2wt.%), ethyl alcohol (22wt.%) and calcium carbide (10wt.%).
  • limonene is in the range of 5-15 wt.%
  • benzoyl peroxide is in the range of 1-5 wt.%
  • isopropyl alcohol is in the range of l-5wt.%
  • glycerine is in the range of 5-25wt.%
  • tetrahydrofuran is in the range of 15-40wt.%
  • tertiary butyl alcohol is in the range of 10-20wt.%
  • ethyl formate is in the range of 10-30wt.%
  • methyl formate is in the range of 10-30wt.%
  • methyl alcohol is in the range of 6-25wt.%
  • cyclopentane is in the range of 2- 10wt.%
  • ethyl alcohol is in the range of 22-40wt.%
  • calcium carbide is in the range of 10- 50wt.%.
  • limonene is in the range of 5-60 wt.%
  • benzoyl peroxide is in the range of 1-5 wt.%
  • isopropyl alcohol is in the range of l-5wt.%
  • glycerine is in the range of 5- 25wt.%
  • tetrahydrofuran is in the range of 10-40wt.%
  • tertiary butyl alcohol is in the range of 15-20wt.%
  • ethyl formate is in the range of 10-30wt.%
  • methyl formate is in the range of 10- 30wt.%
  • methyl alcohol is in the range of 5-25wt.%
  • cyclopentane is in the range of 2- 10wt.%
  • ethyl alcohol is in the range of 22-40wt.%
  • calcium carbide is in the range of 10- 50wt.%.
  • limonene is in the range of 10-60 wt.%
  • benzoyl peroxide is in the range of 1-5 wt.%
  • isopropyl alcohol is in the range of 1-5 wt.%
  • glycerine is in the range of 5-25 wt.%
  • tetrahydrofuran is in the range of 10-15 wt.%
  • tertiary butyl alcohol is in the range of 10-15 wt.%
  • ethyl formate is in the range of 5-30 wt.%
  • methyl formate is in the range of 10-30 wt.%
  • methyl alcohol is in the range of 5-25 wt.%
  • cyclopentane is in the range of 2-10 wt.%
  • ethyl alcohol is in the range of 22-40 wt.%
  • calcium carbide is in the range of 10-50 wt.%.
  • a method for preparing bio-hydrocarbon fuel comprising homogeneously mixing the following ingredients; limonene in the range of 2-60 wt.%, benzoyl peroxide in the range of 1-5 wt.%., isopropyl alcohol in the range of l-5wt. %, glycerine in the range of 5-25wt.%, tetrahydrofuran in the range of 10-40wt.
  • tertiary butyl alcohol in the range of 10-20wt.%, ethyl formate in the range of 5-30wt.%, methyl formate in the range of 10-30wt.%, methyl alcohol in the range of 5-25wt.%, cyclopentane in the range of 2-10wt.%, ethyl alcohol in the range of 22-40wt.%, and calcium carbide in the range of 10- 50wt.%, to obtain said bio-hydrocarbon fuel.
  • the aforesaid ingredients can be heated with aluminum oxide ( ⁇ 1 2 (3 ⁇ 4) in a vessel. During the heating step, large molecules are broken into smaller molecules. This results in a quality of the bio-hydrocarbon fuel matching that of aviation fuel.
  • ethyl formate, isopropyl alcohol, tetrahydrofuran and limonene are processed under a jet of hydrogen gas in the presence of a catalyst prior to homogeneously mixing said ingredients.
  • the catalyst is at least one selected from the group consisting of benzoyl peroxide and calcium carbide.
  • the ingredients used in the process for preparing the bio-hydrocarbon fuel can be obtained from bio-mass sources as listed below: a. Limonene can be obtained from Boswellia Ovalifololata Plant.
  • the Boswellia Ovalifololata plant is a moderate or large branching tree with a bole of 15 to 121 feet in height and 3-5 feet in girth, generally found in dry, hilly, deciduous forests of India, at an altitude of 450-950 Msl. It is discovered that only one species is found in India and the remaining species are found in Arabia and African continent.
  • Another variant, Serrata with serrated and pubescent leaves, can also be used.
  • Boswellia oil present in the Boswellia Ovalifololata Plant can be extracted by following method:
  • Limonene can be obtained from the Boswellia oil by processes well known in the art.
  • Ethyl alcohol can be obtained by fermentation of starch and sugar by processes well known in the art.
  • Ethyl formate can be obtained by fermentation of sugarcane base by processes well known in the art.
  • Cyclopentane can be obtained from ethyl ester of adipic acid found in beet juice by processes well known in the art.
  • Methyl alcohol can be obtained from wood by processes well known in the art. TECHNICAL ADVANCEMENTS

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

La présente invention concerne une composition de biocarburant hydrocarboné qui réduit la concentration d'émission de monoxyde de carbone dans l'atmosphère. La composition de biocarburant hydrocarboné comprend du limonène dans la plage de 2 à 60 % en poids, du peroxyde de benzoyle dans la plage de 1 à 5 % en poids, de l'alcool isopropylique dans la plage de 1 à 5 % en poids, de la glycérine dans la plage de 5 à 25 % en poids, du tétrahydrofurane dans la plage de 10 à 40 % en poids, de l'alcool tert-butylique dans la plage de 10 à 20 % en poids, du formiate d'éthyle dans la plage de 5 à 30 % en poids, du formiate de méthyle dans la plage de 10 à 30 % en poids, de l'alcool méthylique dans la plage de 5 à 25 % en poids, du cyclopentane dans la plage de 2 à 10 % en poids, de l'alcool éthylique dans la plage de 22 à 40 % en poids, et du carbure de calcium dans la plage de 10 à 50 % en poids.
PCT/IB2018/056259 2017-08-20 2018-08-18 Composition de biocarburant hydrocarboné et procédé de préparation associé Ceased WO2019038650A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN201741006249 2017-08-20
IN201741006249 2017-08-20

Publications (1)

Publication Number Publication Date
WO2019038650A1 true WO2019038650A1 (fr) 2019-02-28

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2018/056259 Ceased WO2019038650A1 (fr) 2017-08-20 2018-08-18 Composition de biocarburant hydrocarboné et procédé de préparation associé

Country Status (1)

Country Link
WO (1) WO2019038650A1 (fr)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110016774A1 (en) * 2008-03-12 2011-01-27 Ponnupillai Ramar Velar Bio Hydrocarbon Fuel

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110016774A1 (en) * 2008-03-12 2011-01-27 Ponnupillai Ramar Velar Bio Hydrocarbon Fuel

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