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WO2019027164A1 - Cosmetic composition comprising pigment and method for producing same - Google Patents

Cosmetic composition comprising pigment and method for producing same Download PDF

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Publication number
WO2019027164A1
WO2019027164A1 PCT/KR2018/008215 KR2018008215W WO2019027164A1 WO 2019027164 A1 WO2019027164 A1 WO 2019027164A1 KR 2018008215 W KR2018008215 W KR 2018008215W WO 2019027164 A1 WO2019027164 A1 WO 2019027164A1
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WO
WIPO (PCT)
Prior art keywords
pigment
cosmetic composition
coating layer
oil
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2018/008215
Other languages
French (fr)
Korean (ko)
Inventor
정하진
김경남
김준일
하주희
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amorepacific Corp
Original Assignee
Amorepacific Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amorepacific Corp filed Critical Amorepacific Corp
Priority to CN201880064138.4A priority Critical patent/CN111163748B/en
Publication of WO2019027164A1 publication Critical patent/WO2019027164A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27Zinc; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29Titanium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
    • A61K8/553Phospholipids, e.g. lecithin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585Organosilicon compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60Particulates further characterized by their structure or composition
    • A61K2800/61Surface treated
    • A61K2800/62Coated
    • A61K2800/622Coated by organic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60Particulates further characterized by their structure or composition
    • A61K2800/61Surface treated
    • A61K2800/62Coated
    • A61K2800/63More than one coating

Definitions

  • the present invention relates to a cosmetic composition
  • a cosmetic composition comprising a pigment, which is improved in feeling and functionality through the uniformization of the particle size distribution of the pigment, and a process for producing the same.
  • make-up cosmetics are used for the purpose of concealing the defects of the skin using the pigment, giving a beautiful color and protecting the skin from ultraviolet rays, and furthermore, it is used for a secondary purpose of giving psychological stability feeling by skin beautification and skin protection function .
  • titanium dioxide (TiO2) is the most widely used as a representative white pigment for color impartation and skin defect.
  • TiO2 titanium dioxide
  • the better the function of concealing skin defect the more the re-agglutination phenomenon occurs, causing the phenomenon of bundle after make-up.
  • the structure is a tetrahedron, This is very bad and causes deterioration of usability.
  • Japanese Patent No. 5667330 discloses a multi-layer coated pigment in which the coating layer comprises a high refractive index coating (TiO2, 10-100 nm thick), a colorless coating (20-100 nm thick) and a high refractive index coating (TiO2, 10-100 nm thickness).
  • the coating layer comprises a high refractive index coating (TiO2, 10-100 nm thick), a colorless coating (20-100 nm thick) and a high refractive index coating (TiO2, 10-100 nm thickness).
  • a method of uniformizing the particle size distribution of the pigment including the coating is not proposed, it may be difficult to secure the feeling of use and functionality when applied to cosmetics .
  • US Patent Publication No. 2004-0258640 discloses an interference pigment which can be used in cosmetics for skin flaw cover, and discloses a multi-layer coated pigment. However, since the particle size of the pigment is improved, Is not mentioned.
  • Patent Document 1 Japanese Patent No. 5667330, " Silver Gloss Pigment "
  • Patent Document 2 US Patent Publication No. 2004-0258640, " INTERFERENCE PIGMENT AND COMPOSITION INCLUDING SAME "
  • the inventors of the present invention conducted various studies to solve the above problems. As a result, the present inventors have found that a cosmetic composition having uniform particle size distribution can be obtained by dispersing a pigment coated with a double coating layer comprising an oil phase layer and a water phase layer using a spinning dispersing device And the cosmetic composition thus prepared was adhered thinly when applied to the skin to give the skin luster and moisturization, and it was confirmed that the covering force and the agglomeration after the lapse of time were prevented.
  • an object of the present invention is to provide a cosmetic composition comprising a pigment having improved stability.
  • Another object of the present invention is to provide a method for producing a cosmetic composition comprising a pigment having a uniform particle size distribution.
  • the present invention provides a cosmetic composition comprising pigment particles coated with a coating layer comprising an oil phase and an aqueous phase.
  • the particle size of the pigment may be 0.1 ⁇ to 1 ⁇ .
  • the pigment may be selected from the group consisting of titanium dioxide (TiO 2 ), micro TiO 2 , zinc oxide (ZnO), micro ZnO, iron oxide, alumina, Al 2 O 3 ), Barium sulfate (BaSO 3 ), silica (SiO 2 ), talc, kaolin, sericite, and mica.
  • the oil phase may include at least one member selected from the group consisting of Dimethicone, Methicone, Hydrogen Dimethicone, Caprylic Silanes and Fluorine-based Silicone.
  • the water phase may include at least one selected from the group consisting of lecithins and silicas.
  • the coating layer may be a single coating layer comprising a mixture of oil phase and water phase.
  • the coating layer may be a double coating layer including an oil phase layer and a water phase layer.
  • the cosmetic composition may be formulated in the form of water dispersion, oil dispersion, water in oil (W / O) or oil in water (O / W).
  • the cosmetic composition may be formulated in the form of a liquid, a cream or a cake-like foundation, a make-up base cosmetic, or a UV-blocking cosmetic.
  • the present invention also provides a process for producing a cosmetic composition comprising dispersing a pigment and an emulsifier in an aqueous phase and dispersing the same using a rotating dispersing machine to form a coating layer comprising oil phase and water phase on the surface of the pigment do.
  • the rotating speed of the dispersing device may be 5 to 50 m / s.
  • the surface of the pigment particles contained in the cosmetic composition is coated with a double coating layer comprising an oil phase layer and a water phase layer, a thin and uniform cosmetic film can be formed when applied to the skin, A moisturizing feeling can be given.
  • the cosmetic composition according to the present invention can maintain the viscosity at an appropriate level while uniformizing the particle size distribution of the pigment by using a thin film swirling type high-speed mixer during the manufacturing process.
  • the cosmetic composition of the present invention is applied to skin-based cosmetics such as cushions, facts, and foundations, the covering power is improved, and after the lapse of time, The problem can be improved.
  • FIGS. 1A and 1B are schematic diagrams of a cosmetic composition comprising a pigment according to the present invention.
  • Fig. 2 is a schematic view of a process of dispersing pigment particles using a thin film swirling type high-speed mixer according to the method for producing a cosmetic composition of the present invention.
  • 3A and 3B are microscope photographs of the cosmetic composition prepared in Example 1 and Comparative Example 1, respectively.
  • Fig. 5 is a graph showing the results of sensory evaluation of the cosmetic composition of the liquid foundation formulation according to Examples 1, 2, and Comparative Examples 1 and 2.
  • a cosmetic composition comprising a pigment
  • the present invention relates to a cosmetic composition comprising a pigment, and relates to a cosmetic composition having uniform particle size distribution of pigment particles contained in a cosmetic composition.
  • the cosmetic composition according to the present invention is particularly useful as a cosmetic composition for base makeup of the skin, which is capable of forming a thin cosmetic film when applied to the skin, imparting gloss and moisturization to the skin, It is possible to prevent lifting or aggregation after elapse of time.
  • the cosmetic composition according to the present invention may comprise pigment particles coated with a coating layer comprising an oil phase and an aqueous phase.
  • the pigment contained in the cosmetic composition according to the present invention has a particle size of 0.1 to 1 ⁇ ⁇ , and when the particle size of the cosmetic composition is less than 0.1 ⁇ ⁇ , there is a problem in the reliability analysis of the particle size analyzer. Lt; / RTI >
  • the pigment plays a role of enhancing coverage, hiding power, durability, oil repellency, water repellency and usability, such as titanium dioxide, titanium dioxide (TiO 2 ), micro titanium oxide (Micro TiO 2 ) zinc zinc oxide (zinc oxide, ZnO), micro-oxidation (micro ZnO), iron oxide (ii) (FeO (ii) ), iron oxide, aluminum oxide (alumina, Al 2 O 3) , barium sulfate (barium sulfate, BaSO 3) , Silica, SiO 2 , talc, kaolin, sericite, and mica. Particularly, when titanium oxide is used, it may be more advantageous in terms of coverage and hiding power.
  • the iron oxide may be iron oxide (II) (FeO (II)), iron oxide (III) (FeO (III)) or iron oxide (IV) (FeO (IV)).
  • the coating layer formed on the surface of the pigment may be in the form of a single layer or a double layer.
  • FIGS. 1A and 1B are schematic diagrams of a cosmetic composition comprising a pigment according to the present invention.
  • a pigment 1 including an oil phase and an aqueous phase contained in a cosmetic composition according to the present invention is a form in which a single coating layer 20 is formed on the surface of a pigment particle 10, And a mixture of water and water.
  • the pigment 1 including the oil phase and the water phase contained in the cosmetic composition according to the present invention comprises a pigment layer 10 having an oil phase layer 30a and a water phase layer 30b, Coating layer 30 may be coated.
  • the weight ratio of the oil phase layer to the water phase layer may be 1: 0.1 to 1, preferably 1: 0.3 to 0.6. If the weight ratio of the water phase to the oil phase is less than 0.1, If it is more than 1, there may be a problem in terms of dispersibility.
  • the oil phase layer serves to improve water repellency and dispersibility in oil phase, and is selected from the group consisting of Dimethicone, Methicone, Hydrogen Dimethicone, Caprylic Silanes and Fluorine-based Silicones
  • the oil phase layer is made of triethoxycaprylyl silane (TRIETHOXYCAPRYLYLSILANE)
  • TETHOXYCAPRYLYLSILANE triethoxycaprylyl silane
  • the water-repellent layer serves to improve the oil-repellency and dispersibility in water, and may include at least one member selected from the group consisting of lecithins and silicas. Particularly, May be advantageous from the viewpoint of dispersibility when it is made of hygrogenated lecithin.
  • the content of the pigment is 0.01 to 40% by weight, preferably 1 to 10% by weight based on the total weight of the cosmetic composition. If the content of the pigment is less than the above range, the covering power and hiding power may be poor.
  • the cosmetic composition of the present invention can be applied to various cosmetics, especially skin cosmetics such as cushion and emulsion foundation, as well as solid cosmetics such as loose powder, powder foundation, compression foundation, ball touch, eye shadow, , Body powders and other solid form cosmetics.
  • skin cosmetics such as cushion and emulsion foundation
  • solid cosmetics such as loose powder, powder foundation, compression foundation, ball touch, eye shadow, , Body powders and other solid form cosmetics.
  • solid it is meant that the composition is solid at 25 ° C. and is non-flowable.
  • the cosmetic composition of the present invention can be formulated in the form of water dispersion, oil dispersion, water in oil (W / O) or oil in water (O / W).
  • the cosmetic composition of the present invention can be formulated in the form of a liquid, a make-up base cosmetic, or a UV-blocking cosmetic in the form of a liquid, a cream or a cake.
  • the cosmetic composition of the present invention may be prepared in any form conventionally produced in the art, and examples thereof include solutions, suspensions, emulsions, pastes, gels, creams, lotions, powders, soaps, surfactants- Containing cleansing, oil, powder foundation, emulsion foundation, wax foundation and spray, but is not limited thereto. More specifically, it can be manufactured in the form of a soft lotion, a nutritional lotion, a nutritional cream, a massage cream, an essence, an eye cream, a cleansing cream, a cleansing foam, a cleansing water, a pack, a spray or a powder.
  • the formulation of the present invention is a paste, cream or gel
  • an animal oil, vegetable oil, wax, paraffin, starch, tracant, cellulose derivative, polyethylene glycol, silicone, bentonite, silica, talc or zinc oxide may be used as the carrier component .
  • the formulation of the present invention is a powder or a spray
  • lactose, talc, silica, aluminum hydroxide, calcium silicate or polyamide powder may be used as a carrier component.
  • a spray a chlorofluorohydrocarbon, / Propane or dimethyl ether.
  • a solvent, a solubilizing agent or an emulsifying agent is used as a carrier component, and examples thereof include water, ethanol, isopropanol, ethylcarbonate, ethyl acetate, glycerin, carbomer, benzyl alcohol, Propylene glycol, 1,3-butyl glycol oil, glycerol aliphatic ester, caprylic capric triglyceride, hydrone- nylidene polydecene, cetearyl glucoside, sorbidestearate, polyethylene glycol, cetearyl alcohol and the like have.
  • the formulation of the present invention is a suspension
  • a carrier such as water, a liquid diluent such as ethanol or propylene glycol, a suspending agent such as ethoxylated isostearyl alcohol, polyoxyethylene sorbitol ester and polyoxyethylene sorbitan ester, Cellulose, aluminum metahydroxide, bentonite, agar or tracant, etc.
  • a suspending agent such as ethoxylated isostearyl alcohol, polyoxyethylene sorbitol ester and polyoxyethylene sorbitan ester
  • the carrier component may include aliphatic alcohol sulfate, aliphatic alcohol ether sulfate, sulfosuccinic acid monoester, isethionate, imidazolinium derivative, methyltaurate, sarcosinate, fatty acid amide Ether sulfates, alkylamidobetaines, aliphatic alcohols, fatty acid glycerides, fatty acid diethanolamides, vegetable oils, lanolin derivatives, or ethoxylated glycerol fatty acid esters.
  • the present invention also relates to a process for producing a cosmetic composition
  • a cosmetic composition comprising dispersing a pigment and an emulsifier in an aqueous phase and dispersing the same using a rotating dispersing machine to form a coating layer comprising oil phase and water phase on the surface of the pigment will be.
  • Fig. 2 is a schematic view of a process of dispersing pigment particles using a thin film swirling type high-speed mixer according to the method for producing a cosmetic composition of the present invention.
  • a velocity difference is generated due to the centrifugal force generated by turning the treatment liquid around the inner wall of the container, thereby releasing secondary agglomeration and preventing re-aggregation, so that the particle size distribution of the pigment can be uniform.
  • the rotation speed of the dispersing device may be from 5 m / s to 50 m / s. If the rotation speed is less than 5 m / s, the improvement of the particle size distribution is insignificant. When the rotation speed is more than 50 m / Can be deformed.
  • the emulsifier is added so that the pigment can be dispersed in the aqueous phase, and a surfactant having a high hydrophile-liphophile balance (HLB) of 9 to 15 is used as an O / W (oil in water) 30 Hydrogenated Castor Oil, glyceryl Stearate and PEG-100 Stearate, Polyethylene Glycol Monoisostearate, Cetearyl Olivate, / Sorbitan Olivate, Hydrogenated Lecithin, Arachidyl Alcohol and Behenyl Alcohol and Arachidyl Glucoside, Cetearyl Alcohol, ) / Cetearyl Glucoside, Polysorbate 80, and Polysorbate 60 may be included. have.
  • HLB hydrophile-liphophile balance
  • the emulsifier may be contained in an amount of 0.1 to 1.5% by weight based on the total weight of the cosmetic composition. When the content of the emulsifier is within the above range, the dispersibility of the pigment particles may be excellent.
  • the cosmetic composition of the present invention produced according to the above-described production method can be advantageous for formulation into various formulations since the particle size distribution is uniform and the viscosity retention rate is high even after prolonged time.
  • a cosmetic composition having a liquid foundation formulation of W / O type as shown in Table 1 below was prepared.
  • TiO 2 having a particle size of 0.3 ⁇ to 0.5 ⁇ was added to a water-in-oil hydrogeled lecithin together with an emulsifier POLYSORBATE 80 and dispersed at a rotation speed of 30 m / s using a peel mixer as a thin film swirling type high speed mixer
  • a liquid foundation formulation of a cosmetic composition comprising TiO 2 pigment particles coated with oil and water.
  • the content of the TiO 2 pigment particles was adjusted to 7 wt% based on the total weight of the cosmetic composition.
  • Pigment particles TiO 2 having a particle diameter of 0.3 ⁇ to 0.5 ⁇
  • Emulsifier POLYSORBATE 80
  • Example 2 The same procedure as in Example 1 was carried out except that the content of the TiO 2 pigment particles was 10% by weight based on the total weight of the cosmetic composition.
  • a cosmetic composition was prepared in the same manner as in Example 1, except that TiO 2 pigment particles coated with oil phase and water phase were prepared using a ring mill instead of a thin film swirling type high speed mixer.
  • a cosmetic composition comprising TiO 2 pigment particles coated with an oil phase and a water phase was prepared in the same manner as in Example 2 except that a ring mill was used instead of the thin film swirling type high speed mixer.
  • 3A and 3B are microscope photographs of the cosmetic composition prepared in Example 1 and Comparative Example 1, respectively.
  • Example 1 particles having a large size were hardly observed, whereas in FIG. 3B, particles having a large size were observed in Comparative Example 1. From this, it can be seen that, when a thin film swirling type high-speed mixer for dispersing pigment particles using the centrifugal force of a rotating dispersing device is used, the particle size distribution can be made uniform compared to the case of using the ring mill in the past.
  • each cosmetic composition was measured on the day of the first viscosity measurement, the first day, the seventh day, The viscosity of the composition was measured and the viscosity aging ratios for three months were compared.
  • the cosmetic composition prepared in each of Examples 1 and 2 had a viscosity retention rate of about 96% for 3 months, and a viscosity of about 74% for 3 months in Comparative Example 2, It is difficult to apply to various formulations because it maintains 20,000 cps level.
  • the average particle sizes of the cosmetic compositions prepared in Examples 1 and 2 and Comparative Examples 1 and 2 were measured by measuring the particle size distribution.
  • Table 3 below shows the average particle sizes of the cosmetic compositions prepared in Examples 1 and 2 and Comparative Examples 1 and 2, respectively.
  • Examples 1 and 2 even when the content of the pigment increases, the size of the pigment is similar to that of the existing pigment.
  • Comparative Examples 1 and 2 the larger the content of the pigment, the larger the particle size. This is presumably because the pigments are not re-agglomerated and the size of the existing pigments stably and well maintained when applying the technique of the embodiment, while the comparative example of the prior art is enlarged in size as pigments cohere in the formulations.
  • Example 2 the smoothness, the glossiness, the moistness, the residual feeling, and the prosperity were excellent. Particularly, in Example 2, the content of pigment was higher than that in Example 1, .
  • the formulation of the cosmetic composition comprising pigment particles coated with the coating layer comprising oil phase and water phase according to the present invention is not limited to these examples.
  • Pigment particles TiO 2 having a particle diameter of 0.3 ⁇ to 0.5 ⁇
  • Emulsifier POLYSORBATE 80
  • HYDROGENATED LECITHIN 16.5 Icari seed B2 0.5 Wax 10.0 Polysorbate 60 1.5 PEG 60 hardened castor oil 2.0 Sorbitan sesquioleate 0.8 Liquid paraffin 40.0
  • Squalane 5.0 Caprylic / capric triglyceride 4.0 glycerin 5.0 Butylene glycol 3.0 Propylene glycol 3.0 Triethanolamine 0.2
  • a nutrition lotion comprising a pigment coated with a coating layer comprising an oil phase and an aqueous phase of the present invention was prepared in a conventional manner according to the composition of Table 5 below.
  • Pigment particles TiO 2 having a particle diameter of 0.3 ⁇ to 0.5 ⁇
  • Emulsifier POLYSORBATE 80
  • a pack containing pigments coated with a coating layer comprising oil phase and water phase was prepared in a conventional manner according to the composition of Table 6 below.
  • Pigment particles TiO 2 having a particle diameter of 0.3 ⁇ to 0.5 ⁇
  • Emulsifier POLYSORBATE 80
  • HYDROGENATED LECITHIN 15 glycerin 4.0
  • Polyvinyl alcohol 15.0
  • Hyaluronic acid extract 5.0
  • Nonyl phenyl ether 0.4
  • Polysorbate 60 1.2 ethanol 6.0 Purified water Remainder
  • Ointments were prepared in a conventional manner according to the composition of Table 7 below, including pigments coated with a coating layer comprising an oil phase and an aqueous phase of the present invention.
  • Pigment particles TiO 2 having a particle diameter of 0.3 ⁇ to 0.5 ⁇
  • Emulsifier POLYSORBATE 80
  • One HYDROGENATED LECITHIN 15 Alpha-keto glutaric acid 1.0 Niacinamide 1.0 Beta-1,3-glucan 10.0 Wax 10.0
  • Polysorbate 5.0 Piggy 60 hardened castor oil 2.0 Sorbitan sesquioleate 0.5 Vaseline 5.0 Liquid paraffin 10.0 Squalane 5.0 Sheer butter 3.0
  • Caprylic / capric triglyceride 5.0 glycerin 10.0 Propylene glycol 10.2
  • Triethanolamine 0.2
  • fragrance Purified water Remainder
  • a gel comprising pigments coated with a coating layer comprising an oil phase and an aqueous phase was prepared in a conventional manner according to the composition shown in Table 8 below.
  • Pigment particles TiO 2 having a particle diameter of 0.3 ⁇ to 0.5 ⁇
  • Emulsifier POLYSORBATE 80
  • HYDROGENATED LECITHIN 16 Panthenol 5.0 Seaweed oil 0.01 Alpha-keto glutaric acid 1.0 Niacinamide 1.0 Beta-1,3-glucan 0.1
  • pigment containing a coating layer including an oil phase and water phase

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  • Cosmetics (AREA)

Abstract

The present invention relates to a cosmetic composition comprising a pigment, and a method for producing the same, characterized in that the particle size distribution of the pigment, which is coated with a coating layer comprising an oil phase and a water phase, is uniformized, thereby improving the feeling of using the cosmetic composition and the functionality thereof.

Description

안료를 포함하는 화장료 조성물 및 그 제조방법Cosmetic composition comprising pigment and method for producing the same

본 출원은 2017년 7월 31일자 한국 특허출원 제10-2017-0097300호에 기초한 우선권의 이익을 주장하며, 해당 한국 특허 출원의 문헌에 개시된 모든 내용을 본 명세서의 일부로서 포함한다.This application claims the benefit of priority based on Korean Patent Application No. 10-2017-0097300, filed on July 31, 2017, which is incorporated herein by reference in its entirety.

본 발명은 안료를 포함하는 화장료 조성물로서, 안료의 입도 분포 균일화를 통해 사용감과 기능성이 향상된 화장료 조성물 및 그 제조방법에 관한 것이다.The present invention relates to a cosmetic composition comprising a pigment, which is improved in feeling and functionality through the uniformization of the particle size distribution of the pigment, and a process for producing the same.

일반적으로 메이크업 화장료는 안료를 사용하여 피부의 결점을 은폐하고 아름다운 색상을 부여하며 자외선으로부터 피부보호 등을 위한 목적으로 사용되고 나아가 피부미화와 피부보호 기능에 의해 심리적으로 안정감을 주는 부수적인 목적으로 사용되고 있다.In general, make-up cosmetics are used for the purpose of concealing the defects of the skin using the pigment, giving a beautiful color and protecting the skin from ultraviolet rays, and furthermore, it is used for a secondary purpose of giving psychological stability feeling by skin beautification and skin protection function .

상기 메이크업 화장료는 유화타입, 분산형타입, 파우더타입의 제형 형태에 따라 약간의 차이점이 있으나 색상부여와 피부결점을 커버하기 위한 대표적인 백색안료로서 이산화티탄(TiO2)을 가장 많이 사용하고 있다. 하지만 표면 개질되지 않은 이산화티탄의 경우 피부결점을 은폐시키는 기능이 우수할수록 재응집 현상이 발생하여 화장 후 뭉치는 현상을 야기하게 되고, 특히 상기 그 구조가 사면체이어서 피부에 도포시 피부를 손상시키며 전연성이 매우 나빠 사용성을 저하시키는 요인이 된다.Although the makeup cosmetic material has a slight difference depending on the form of the emulsified type, the dispersed type, and the powder type, titanium dioxide (TiO2) is the most widely used as a representative white pigment for color impartation and skin defect. However, in the case of titanium dioxide which is not surface-modified, the better the function of concealing skin defect, the more the re-agglutination phenomenon occurs, causing the phenomenon of bundle after make-up. In particular, the structure is a tetrahedron, This is very bad and causes deterioration of usability.

이러한 단점을 극복하기 위하여 안료의 표면을 다양한 기재로 코팅 또는 복합화하여 사용되는 방법이 사용되고 있다. 종래에는 실리콘, 불소, 아미노산, 키토산, 금속염 등으로 표면처리를 실시하여 밀착성과 지속성 등의 기능을 개선시킬 수 있다. 그러나, 제형 내에서의 퍼짐성과 재응집 방지성 및 사용시나 시간 경과 후 화장붕괴를 방지하는데는 아직도 만족스럽지 못한 실정이다. In order to overcome such disadvantages, a method of coating or compounding the surface of the pigment with various substrates has been used. Conventionally, surface treatment is performed with silicon, fluorine, amino acid, chitosan, metal salt or the like to improve functions such as adhesion and persistence. However, the spreadability within the formulation, the prevention of re-aggregation, and the prevention of cosmetic collapse after use or over time are still unsatisfactory.

예를 들어, 일본 등록특허 제5667330호는 다층 피복된 형태의 안료를 제시하며, 피복층은 고굴절성 피막(TiO2, 10-100nm 두께), 무색피막(20-100nm 두께) 및 고굴절성 피막(TiO2, 10-100nm 두께) 중 적어도 하나를 포함한다고 개시되어 있으나, 이와 같이 피막을 포함하는 안료의 입도 분포를 균일하게 하는 방법은 제시하지 못하여, 화장품에 적용시 사용감과 기능성을 확보하는데 어려움이 있을 수 있다.For example, Japanese Patent No. 5667330 discloses a multi-layer coated pigment in which the coating layer comprises a high refractive index coating (TiO2, 10-100 nm thick), a colorless coating (20-100 nm thick) and a high refractive index coating (TiO2, 10-100 nm thickness). However, since a method of uniformizing the particle size distribution of the pigment including the coating is not proposed, it may be difficult to secure the feeling of use and functionality when applied to cosmetics .

또한, 미국공개특허 제2004-0258640호는 피부 결점 커버를 위한 화장품에 사용될 수 있는 interference pigment에 관한 것으로, 다층 피복된 형태의 안료가 개시되어 있으나 안료의 입도를 개선시킴으로서 화장품에 적용시 사용감과 기능성을 확보할 수 있는 기술에 대해서는 언급되어 있지 않다.In addition, US Patent Publication No. 2004-0258640 discloses an interference pigment which can be used in cosmetics for skin flaw cover, and discloses a multi-layer coated pigment. However, since the particle size of the pigment is improved, Is not mentioned.

따라서, 안료를 보호할 수 있는 코팅층을 포함하면서도 입도 분포를 개선하여 피부에 적용시 사용감과 기능성을 동시에 향상시킬 수 있는 화장료 조성물 제조 기술 개발이 시급한 실정이다.Therefore, it is urgently required to develop a cosmetic composition manufacturing technology that can improve the feel and functionality when applied to the skin by improving the particle size distribution while including a coating layer capable of protecting the pigment.

[선행기술문헌][Prior Art Literature]

[특허문헌][Patent Literature]

(특허문헌 1) 일본 등록특허 제5667330호, “은색 광택 안료”(Patent Document 1) Japanese Patent No. 5667330, " Silver Gloss Pigment "

(특허문헌 2) 미국공개특허 제2004-0258640호, “INTERFERENCE PIGMENT AND COMPOSITION INCLUDING SAME”(Patent Document 2) US Patent Publication No. 2004-0258640, " INTERFERENCE PIGMENT AND COMPOSITION INCLUDING SAME "

이에 본 발명자들은 상기 문제점을 해결하기 위해 다각적으로 연구를 수행한 결과, 유상층 및 수상층을 포함하는 이중 코팅층으로 코팅된 안료를 회전하는 분산기기를 이용하여 분산시킴으로써 입도 분포가 균일한 화장료 조성물을 제조할 수 있으며, 이렇게 제조된 화장료 조성물은 피부 도포시 얇게 밀착되어 피부에 윤기와 촉촉함을 부여하는 동시에 커버력과 시간 경과 후 들뜸과 뭉침이 방지되는 것을 확인하였다.The inventors of the present invention conducted various studies to solve the above problems. As a result, the present inventors have found that a cosmetic composition having uniform particle size distribution can be obtained by dispersing a pigment coated with a double coating layer comprising an oil phase layer and a water phase layer using a spinning dispersing device And the cosmetic composition thus prepared was adhered thinly when applied to the skin to give the skin luster and moisturization, and it was confirmed that the covering force and the agglomeration after the lapse of time were prevented.

따라서, 본 발명의 목적은 안정성이 향상된 안료를 포함하는 화장료 조성물을 제공하는데 있다.Accordingly, an object of the present invention is to provide a cosmetic composition comprising a pigment having improved stability.

본 발명의 다른 목적은 입도 분포가 균일한 안료를 포함하는 화장료 조성물의 제조방법을 제공하는데 있다.Another object of the present invention is to provide a method for producing a cosmetic composition comprising a pigment having a uniform particle size distribution.

상기 목적을 달성하기 위해, 본 발명은 유상과 수상을 포함하는 코팅층으로 코팅된 안료 입자를 포함하는 화장료 조성물을 제공한다.In order to achieve the above object, the present invention provides a cosmetic composition comprising pigment particles coated with a coating layer comprising an oil phase and an aqueous phase.

상기 안료의 입도는 0.1 ㎛ 내지 1 ㎛일 수 있다.The particle size of the pigment may be 0.1 탆 to 1 탆.

상기 안료는 산화티탄(titanium dioxide, TiO2), 마이크로 산화티탄(Micro TiO2), 산화아연(zinc oxide, ZnO), 마이크로 산화아연(Micro ZnO), 산화철, 산화알루미늄(alumina, Al2O3), 황산바륨(barium sulfate, BaSO3), 이산화규소(silica, SiO2), 탈크, 카올린, 세리사이트(sericite) 및 마이카로 이루어진 군에서 선택되는 1종 이상의 무기 안료일 수 있다.The pigment may be selected from the group consisting of titanium dioxide (TiO 2 ), micro TiO 2 , zinc oxide (ZnO), micro ZnO, iron oxide, alumina, Al 2 O 3 ), Barium sulfate (BaSO 3 ), silica (SiO 2 ), talc, kaolin, sericite, and mica.

상기 유상은 디메치콘류, 메치콘류, 하이드로겐 디메치콘류, 카플릴릭 실란류 및 불소계 실리콘류로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있다.The oil phase may include at least one member selected from the group consisting of Dimethicone, Methicone, Hydrogen Dimethicone, Caprylic Silanes and Fluorine-based Silicone.

또한, 상기 수상은 레시틴류 및 실리카류로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있다.In addition, the water phase may include at least one selected from the group consisting of lecithins and silicas.

또한, 상기 코팅층은 유상과 수상의 혼합물을 포함하는 단일 코팅층일 수 있다.Further, the coating layer may be a single coating layer comprising a mixture of oil phase and water phase.

또한, 상기 코팅층은 유상층 및 수상층을 포함하는 이중 코팅층일 수 있다.Further, the coating layer may be a double coating layer including an oil phase layer and a water phase layer.

또한, 상기 화장료 조성물은 수분산, 유분산, W/O(water in oil) 또는 O/W(oil in water)의 형태로 제형화 될 수 있다.The cosmetic composition may be formulated in the form of water dispersion, oil dispersion, water in oil (W / O) or oil in water (O / W).

또한, 상기 화장료 조성물은 리퀴드, 크림 또는 케익 형태의 파운데이션, 메이크업베이스 화장료 또는 자외선 차단용 화장료의 형태로 제형화될 수 있다.The cosmetic composition may be formulated in the form of a liquid, a cream or a cake-like foundation, a make-up base cosmetic, or a UV-blocking cosmetic.

본 발명은 또한, 안료와 유화제를 수상에 분산시키되, 회전하는 분산기기를 이용하여 분산시켜, 상기 안료의 표면에 유상과 수상을 포함하는 코팅층을 형성하는 단계를 포함하는 화장료 조성물의 제조방법을 제공한다.The present invention also provides a process for producing a cosmetic composition comprising dispersing a pigment and an emulsifier in an aqueous phase and dispersing the same using a rotating dispersing machine to form a coating layer comprising oil phase and water phase on the surface of the pigment do.

상기 분산기기의 회전속도는 5 내지 50 m/s일 수 있다.The rotating speed of the dispersing device may be 5 to 50 m / s.

본 발명에 따른 화장료 조성물에 의하면, 상기 화장료 조성물 내에 포함된 안료 입자의 표면이 유상층 및 수상층을 포함하는 이중 코팅층으로 코팅되어 있어 피부에 도포시 얇고 균일한 화장막을 형성할 수 있고, 윤기와 보습감을 부여할 수 있다.According to the cosmetic composition of the present invention, since the surface of the pigment particles contained in the cosmetic composition is coated with a double coating layer comprising an oil phase layer and a water phase layer, a thin and uniform cosmetic film can be formed when applied to the skin, A moisturizing feeling can be given.

또한, 본 발명에 따른 화장료 조성물은 제조 공정 중 박막선회형 고속믹서를 이용함으로써 안료의 입도 분포를 균일화하면서도 점도를 적정 수준으로 유지할 수 있다.In addition, the cosmetic composition according to the present invention can maintain the viscosity at an appropriate level while uniformizing the particle size distribution of the pigment by using a thin film swirling type high-speed mixer during the manufacturing process.

이와 같이, 입도 분포가 균일하면서도 적정 수준의 점도를 가짐으로 인하여, 본 발명의 화장료 조성물을 쿠션, 팩트, 파운데이션과 같은 피부 베이스 화장품에 적용할 경우 커버력이 향상되고, 시간 경과 후 들뜸이나 뭉침과 같은 문제점을 개선시킬 수 있다.Since the cosmetic composition of the present invention is applied to skin-based cosmetics such as cushions, facts, and foundations, the covering power is improved, and after the lapse of time, The problem can be improved.

도 1a 및 1b는 본 발명에 따른 안료를 포함하는 화장료 조성물의 모식도이다.1A and 1B are schematic diagrams of a cosmetic composition comprising a pigment according to the present invention.

도 2는 본 발명의 화장료 조성물의 제조방법에 따라 박막선회형 고속믹서를 이용하여 안료 입자를 분산시키는 공정의 모식도를 나타낸 것이다.Fig. 2 is a schematic view of a process of dispersing pigment particles using a thin film swirling type high-speed mixer according to the method for producing a cosmetic composition of the present invention.

도 3a 및 3b는 각각 실시예 1 및 비교예 1에서 각각 제조된 화장료 조성물의 현미경 사진이다.3A and 3B are microscope photographs of the cosmetic composition prepared in Example 1 and Comparative Example 1, respectively.

도 4는 실시예 1,2 및 비교예 1,2의 화장료 조성물에 대한 점도 경시율 측정 결과를 나타낸 그래프이다.4 is a graph showing the results of viscosifi- cation rate measurement for the cosmetic compositions of Examples 1 and 2 and Comparative Examples 1 and 2.

도 5는 실시예 1,2 및 비교예 1,2에 따른 리퀴드 파운데이션 제형의 화장료 조성물에 대해 관능평가를 실시한 결과를 나타낸 그래프이다.Fig. 5 is a graph showing the results of sensory evaluation of the cosmetic composition of the liquid foundation formulation according to Examples 1, 2, and Comparative Examples 1 and 2. Fig.

이하, 본 발명에 대한 이해를 돕기 위하여 본 발명을 더욱 상세하게 설명한다.Hereinafter, the present invention will be described in detail in order to facilitate understanding of the present invention.

본 명세서 및 청구범위에서 사용된 용어나 단어는 통상적이거나 사전적인 의미로 한정해서 해석되어서는 아니 되며, 발명자는 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 원칙에 입각하여 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야만 한다.The terms and words used in the present specification and claims should not be construed in an ordinary or dictionary sense and the inventor can properly define the concept of the term to describe its invention in the best possible way It should be construed as meaning and concept consistent with the technical idea of the present invention.

안료를 포함하는 화장료 조성물A cosmetic composition comprising a pigment

본 발명은 안료를 포함하는 화장료 조성물에 관한 것으로, 화장료 조성물에 포함된 안료 입자의 입도 분포가 균일한 화장료 조성물에 관한 것이다.The present invention relates to a cosmetic composition comprising a pigment, and relates to a cosmetic composition having uniform particle size distribution of pigment particles contained in a cosmetic composition.

본 발명에 따른 화장료 조성물은 특히, 피부의 베이스 화장을 위한 화장료 조성물로 사용되어, 피부에 도포시 얇은 화장막을 형성할 수 있고, 피부에 윤기와 촉촉함을 부여할 뿐만 아니라, 커버력이 우수하며, 시간 경과 후 들뜸이나 뭉침을 방지할 수 있다.The cosmetic composition according to the present invention is particularly useful as a cosmetic composition for base makeup of the skin, which is capable of forming a thin cosmetic film when applied to the skin, imparting gloss and moisturization to the skin, It is possible to prevent lifting or aggregation after elapse of time.

본 발명에 따른 화장료 조성물은 유상과 수상을 포함하는 코팅층으로 코팅된 안료 입자를 포함할 수 있다.The cosmetic composition according to the present invention may comprise pigment particles coated with a coating layer comprising an oil phase and an aqueous phase.

본 발명에 따른 화장료 조성물에 포함된 안료는 입도가 0.1 ㎛ 내지 1 ㎛ 이고, 상기 화장료 조성물의 입도가 0.1 ㎛ 미만이면 입도분석기기의 신뢰구간에서 벗어나) 문제가 있고, 1 ㎛ 초과이면 재응집이 발생할 수 있다. The pigment contained in the cosmetic composition according to the present invention has a particle size of 0.1 to 1 占 퐉, and when the particle size of the cosmetic composition is less than 0.1 占 퐉, there is a problem in the reliability analysis of the particle size analyzer. Lt; / RTI >

본 발명에 있어서, 상기 안료는 커버력, 은폐력, 지속성, 발유성, 발수성 및 사용성, 예컨대, 발림성 개선의 역할을 하는 것으로, 산화티탄(titanium dioxide, TiO2), 마이크로 산화티탄(Micro TiO2), 산화아연(zinc oxide, ZnO), 마이크로 산화아연(Micro ZnO), 산화철(Ⅱ)(FeO(Ⅱ)), 산화철, 산화알루미늄(alumina, Al2O3), 황산바륨(barium sulfate, BaSO3), 이산화규소(silica, SiO2), 탈크, 카올린, 세리사이트(sericite) 및 마이카로 이루어진 군에서 선택되는 1종 이상일 수 있으며, 특히, 산화티탄을 사용할 경우 커버력과 은폐력 측면에서 더욱 유리할 수 있다. 상기 산화철은 산화철(Ⅱ)(FeO(Ⅱ)), 산화철(Ⅲ)(FeO(Ⅲ)) 또는 산화철(Ⅳ)(FeO(Ⅳ))일 수 있다.In the present invention, the pigment plays a role of enhancing coverage, hiding power, durability, oil repellency, water repellency and usability, such as titanium dioxide, titanium dioxide (TiO 2 ), micro titanium oxide (Micro TiO 2 ) zinc zinc oxide (zinc oxide, ZnO), micro-oxidation (micro ZnO), iron oxide (ⅱ) (FeO (ⅱ) ), iron oxide, aluminum oxide (alumina, Al 2 O 3) , barium sulfate (barium sulfate, BaSO 3) , Silica, SiO 2 , talc, kaolin, sericite, and mica. Particularly, when titanium oxide is used, it may be more advantageous in terms of coverage and hiding power. The iron oxide may be iron oxide (II) (FeO (II)), iron oxide (III) (FeO (III)) or iron oxide (IV) (FeO (IV)).

본 발명에 있어서, 상기 안료의 표면에 형성된 코팅층은 단일층 또는 이중층 형태일 수 있다.In the present invention, the coating layer formed on the surface of the pigment may be in the form of a single layer or a double layer.

도 1a 및 1b는 본 발명에 따른 안료를 포함하는 화장료 조성물의 모식도이다.1A and 1B are schematic diagrams of a cosmetic composition comprising a pigment according to the present invention.

도 1a를 참조하면 본 발명에 따른 화장료 조성물에 포함된 유상과 수상을 포함하는 안료(1)는 안료 입자(10)의 표면에 단일 코팅층(20)이 형성된 형태로서, 단일 코팅층(20)은 유상과 수상의 혼합물을 포함할 수 있다.Referring to FIG. 1A, a pigment 1 including an oil phase and an aqueous phase contained in a cosmetic composition according to the present invention is a form in which a single coating layer 20 is formed on the surface of a pigment particle 10, And a mixture of water and water.

또한, 도 1b를 참조하면 본 발명에 따른 화장료 조성물에 포함된 유상과 수상을 포함하는 안료(1)는 안료 입자(10)의 표면에 유상층(30a) 및 수상층(30b)를 포함하는 이중 코팅층(30)이 코팅된 형태일 수 있다. 1B, the pigment 1 including the oil phase and the water phase contained in the cosmetic composition according to the present invention comprises a pigment layer 10 having an oil phase layer 30a and a water phase layer 30b, Coating layer 30 may be coated.

이때, 상기 유상층과 수상층의 중량비는 1 : 0.1 내지 1, 바람직하게는 1: 0.3 내지 0.6일 수 있으며, 상기 유상에 대한 수상의 중량비가 0.1 미만이면 기능적인 측면에서 효능이 저하될 수 있고, 1 초과이면 분산성 측면에서 문제가 있을 수 있다.At this time, the weight ratio of the oil phase layer to the water phase layer may be 1: 0.1 to 1, preferably 1: 0.3 to 0.6. If the weight ratio of the water phase to the oil phase is less than 0.1, If it is more than 1, there may be a problem in terms of dispersibility.

본 발명에 있어서, 상기 유상층은 발수성 및 유상에서의 분산성을 향상시키는 역할을 하는 것으로, 디메치콘류, 메치콘류, 하이드로겐 디메치콘류, 카플릴릭 실란류 및 불소계 실리콘류로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있으며, 특히, 상기 유상층이 트리에톡시카프릴릴실란(TRIETHOXYCAPRYLYLSILANE)으로 이루어질 경우 커버력 및 분산성 측면에서 유리할 수 있다.In the present invention, the oil phase layer serves to improve water repellency and dispersibility in oil phase, and is selected from the group consisting of Dimethicone, Methicone, Hydrogen Dimethicone, Caprylic Silanes and Fluorine-based Silicones In particular, when the oil phase layer is made of triethoxycaprylyl silane (TRIETHOXYCAPRYLYLSILANE), it may be advantageous in terms of coverage and dispersibility.

본 발명에 있어서, 상기 수상층은 발유성 및 수상에서의 분산성을 향상시키는 역할을 하는 것으로, 레시틴류 및 실리카류로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있으며, 특히, 상기 수상층이 하이드로제네이티드 레시틴(HYDROGENATED LECITHIN)으로 이루어질 경우 분산성 측면에서 유리할 수 있다. In the present invention, the water-repellent layer serves to improve the oil-repellency and dispersibility in water, and may include at least one member selected from the group consisting of lecithins and silicas. Particularly, May be advantageous from the viewpoint of dispersibility when it is made of hygrogenated lecithin.

본 발명에 있어서, 상기 안료의 함량은 상기 화장료 조성물 전체 중량을 기준으로 0.01 내지 40 중량%, 바람직하게는, 1 내지 10 중량%이다. 상기 안료의 함량의 상기 범위 미만이면 커버력과 은폐력이 좋지 않을 수 있고, 상기 범위 초과이면 안정화시키기 어려운 문제점이 있다.In the present invention, the content of the pigment is 0.01 to 40% by weight, preferably 1 to 10% by weight based on the total weight of the cosmetic composition. If the content of the pigment is less than the above range, the covering power and hiding power may be poor.

본 발명의 화장료 조성물은 다양한 화장품, 특히, 쿠션, 에멀젼 파운데이션과같은 피부 베이스 화장품 뿐만 아니라, 고형 화장품, 예를 들어, 루스형 파우더, 파우더 파운데이션, 압축형 파운데이션, 볼터치, 아이섀도우, 아이브로우 케이크, 바디 파우더 및 기타 고체 형태의 화장품에 유용하다. 이때, “고형”이라는 것이 의미하는 것은 조성물이 25℃에서 고체이며 비유동성이라는 것이다. The cosmetic composition of the present invention can be applied to various cosmetics, especially skin cosmetics such as cushion and emulsion foundation, as well as solid cosmetics such as loose powder, powder foundation, compression foundation, ball touch, eye shadow, , Body powders and other solid form cosmetics. By "solid" it is meant that the composition is solid at 25 ° C. and is non-flowable.

본 발명의 화장료 조성물은 수분산, 유분산, W/O(water in oil) 또는 O/W(oil in water)의 형태로 제형화될 수 있다.The cosmetic composition of the present invention can be formulated in the form of water dispersion, oil dispersion, water in oil (W / O) or oil in water (O / W).

또한, 본 발명의 화장료 조성물은 리퀴드, 크림 또는 케익의 형태의 파운데이션, 메이크업베이스 화장료 또는 자외선 차단용 화장료의 형태로 제형화될 수 있다.In addition, the cosmetic composition of the present invention can be formulated in the form of a liquid, a make-up base cosmetic, or a UV-blocking cosmetic in the form of a liquid, a cream or a cake.

또한, 본 발명의 화장료 조성물은 당 업계에서 통상적으로 제조되는 어떠한 제형으로도 제조될 수 있으며, 예를 들어, 용액, 현탁액, 유탁액, 페이스트, 겔, 크림, 로션, 파우더, 비누, 계면활성제-함유 클렌징, 오일, 분말 파운데이션, 유탁액 파운데이션, 왁스 파운데이션 및 스프레이 등으로 제형화될 수 있으나, 이에 한정되는 것은 아니다. 보다 상세하게는, 유연 화장수, 영양 화장수, 영양 크림, 마사지 크림, 에센스, 아이 크림, 클렌징 크림, 클렌징 포옴, 클렌징 워터, 팩, 스프레이 또는 파우더의 제형으로 제조될 수 있다.In addition, the cosmetic composition of the present invention may be prepared in any form conventionally produced in the art, and examples thereof include solutions, suspensions, emulsions, pastes, gels, creams, lotions, powders, soaps, surfactants- Containing cleansing, oil, powder foundation, emulsion foundation, wax foundation and spray, but is not limited thereto. More specifically, it can be manufactured in the form of a soft lotion, a nutritional lotion, a nutritional cream, a massage cream, an essence, an eye cream, a cleansing cream, a cleansing foam, a cleansing water, a pack, a spray or a powder.

본 발명의 제형이 페이스트, 크림 또는 겔인 경우에는 담체 성분으로서 동물성유, 식물성유, 왁스, 파라핀, 전분, 트라칸트, 셀룰로오스 유도체, 폴리에틸렌 글리콜, 실리콘, 벤토나이트, 실리카, 탈크 또는 산화아연 등이 이용될 수 있다.When the formulation of the present invention is a paste, cream or gel, an animal oil, vegetable oil, wax, paraffin, starch, tracant, cellulose derivative, polyethylene glycol, silicone, bentonite, silica, talc or zinc oxide may be used as the carrier component .

본 발명의 제형이 파우더 또는 스프레이인 경우에는 담체 성분으로서 락토스, 탈크, 실리카, 알루미늄 히드록시드, 칼슘 실리케이트 또는 폴리아미드 파우더가 이용될 수 있고, 특히 스프레이인 경우에는 추가적으로 클로로플루오로하이드로카본, 프로판/부탄 또는 디메틸 에테르와 같은 추진체를 포함할 수 있다.In the case where the formulation of the present invention is a powder or a spray, lactose, talc, silica, aluminum hydroxide, calcium silicate or polyamide powder may be used as a carrier component. Especially, in the case of a spray, a chlorofluorohydrocarbon, / Propane or dimethyl ether.

본 발명의 제형이 용액 또는 유탁액인 경우에는 담체 성분으로서 용매, 용해화제 또는 유탁화제가 이용되고, 예컨대 물, 에탄올, 이소프로판올, 에틸 카보네이, 에틸 아세테이트, 글리세린, 카보머, 벤질 알코올, 벤질 벤조에이트, 프로필렌글리콜, 1,3-부틸글리콜 오일, 글리세롤 지방족 에스테르, 카프릴릭 카프릭 트리글리세라이드, 하이드로지네이티드 폴리데센, 세테아릴 글루코사이드, 소르비단 스테아레이트, 폴리에틸렌 글리콜, 세테아릴 알코올 등이 있다.When the formulation of the present invention is a solution or an emulsion, a solvent, a solubilizing agent or an emulsifying agent is used as a carrier component, and examples thereof include water, ethanol, isopropanol, ethylcarbonate, ethyl acetate, glycerin, carbomer, benzyl alcohol, Propylene glycol, 1,3-butyl glycol oil, glycerol aliphatic ester, caprylic capric triglyceride, hydrone- nylidene polydecene, cetearyl glucoside, sorbidestearate, polyethylene glycol, cetearyl alcohol and the like have.

본 발명의 제형이 현탁액인 경우에는 담체 성분으로서 물, 에탄올 또는 프로필렌 글리콜과 같은 액상의 희석제, 에톡실화 이소스테아릴 알코올, 폴리옥시에틸렌 소르비톨 에스테르 및 폴리옥시에틸렌 소르비탄 에스테르와 같은 현탁제, 미소 결정성 셀룰로오스, 알루미늄 메타히드록시드, 벤토나이트, 아가 또는 트라칸트 등이 이용될 수 있다.In the case where the formulation of the present invention is a suspension, a carrier such as water, a liquid diluent such as ethanol or propylene glycol, a suspending agent such as ethoxylated isostearyl alcohol, polyoxyethylene sorbitol ester and polyoxyethylene sorbitan ester, Cellulose, aluminum metahydroxide, bentonite, agar or tracant, etc. may be used.

본 발명의 제형이 계면-활성제 함유 클린징인 경우에는 담체 성분으로서 지방족 알코올 설페이트, 지방족 알코올 에테르 설페이트, 설포숙신산 모노에스테르, 이세티오네이트, 이미다졸리늄 유도체, 메틸타우레이트, 사르코시네이트, 지방산아미드 에테르 설페이트, 알킬아미도베타인, 지방족 알코올, 지방산 글리세라이드, 지방산 디에탄올아미드, 식물성유, 라놀린 유도체 또는 에톡실화 글리세롤 지방산에스테르 등이 이용될 수 있다.When the formulation of the present invention is an interfacial active agent-containing cleansing, the carrier component may include aliphatic alcohol sulfate, aliphatic alcohol ether sulfate, sulfosuccinic acid monoester, isethionate, imidazolinium derivative, methyltaurate, sarcosinate, fatty acid amide Ether sulfates, alkylamidobetaines, aliphatic alcohols, fatty acid glycerides, fatty acid diethanolamides, vegetable oils, lanolin derivatives, or ethoxylated glycerol fatty acid esters.

안료를 포함하는 화장료 조성물의 제조방법Process for preparing cosmetic composition containing pigment

본 발명은 또한, 안료와 유화제를 수상에 분산시키되, 회전하는 분산기기를 이용하여 분산시켜, 상기 안료의 표면에 유상과 수상을 포함하는 코팅층을 형성하는 단계를 포함하는 화장료 조성물의 제조방법에 관한 것이다.The present invention also relates to a process for producing a cosmetic composition comprising dispersing a pigment and an emulsifier in an aqueous phase and dispersing the same using a rotating dispersing machine to form a coating layer comprising oil phase and water phase on the surface of the pigment will be.

도 2는 본 발명의 화장료 조성물의 제조방법에 따라 박막선회형 고속믹서를 이용하여 안료 입자를 분산시키는 공정의 모식도를 나타낸 것이다.Fig. 2 is a schematic view of a process of dispersing pigment particles using a thin film swirling type high-speed mixer according to the method for producing a cosmetic composition of the present invention.

도 2를 참조하면, 처리액이 용기 내벽 따라 선회하여 생성되는 원심력으로 속도차가 발생하여 2차 응집을 풀고 재응집 방지 효과가 있어 안료의 입도 분포가 균일하게 될 수 있다.Referring to FIG. 2, a velocity difference is generated due to the centrifugal force generated by turning the treatment liquid around the inner wall of the container, thereby releasing secondary agglomeration and preventing re-aggregation, so that the particle size distribution of the pigment can be uniform.

상기 분산기기의 회전 속도는 5 m/s 내지 50 m/s 일 수 있으며, 상기 회전 속도가 5 m/s 미만이면 입도 분포가 개선되는 정도가 미미하고, 50 m/s 초과이면 안료입자의 형태가 변형될 수 있다.The rotation speed of the dispersing device may be from 5 m / s to 50 m / s. If the rotation speed is less than 5 m / s, the improvement of the particle size distribution is insignificant. When the rotation speed is more than 50 m / Can be deformed.

또한, 상기 유화제는 안료가 수상에 잘 분산될 수 있도록 하기 위해 첨가하며, O/W(oil in water) 유화제로서 HLB(hydrophile-liphophile balance)가 높은 9~15 사이의 계면활성제를 사용하며 PEG-30 수소화된 캐스터 오일(Hydrogenated Castor Oil), 글리세릴 스테아레이트(glyceryl Stearate) 및 PEG-100 스테아레이트(Stearate), 폴리에틸렌 글리콜 모노이소스테아레이트(Polyethylene Glycol Monoisostearate), 세테아릴 올리베이트(Cetearyl Olivate)/소르비탄 올리베이트(Sorbitan Olivate), 수소화된 레시틴(Hydrogenated Lecithin), 아라치딜 알코올(Arachidyl Alcohol) 및 베헤닐 알코올(Behenyl Alcohol) 및 아라치딜 글루코시드(Arachidyl Glucoside), 세테아릴 알코올(Cetearyl Alcohol)/세테아릴 글루코시드(Cetearyl Glucoside), 폴리소르베이트(Polysorbate) 80 및 폴리소르베이트(Polysorbate) 60 로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있다.In addition, the emulsifier is added so that the pigment can be dispersed in the aqueous phase, and a surfactant having a high hydrophile-liphophile balance (HLB) of 9 to 15 is used as an O / W (oil in water) 30 Hydrogenated Castor Oil, glyceryl Stearate and PEG-100 Stearate, Polyethylene Glycol Monoisostearate, Cetearyl Olivate, / Sorbitan Olivate, Hydrogenated Lecithin, Arachidyl Alcohol and Behenyl Alcohol and Arachidyl Glucoside, Cetearyl Alcohol, ) / Cetearyl Glucoside, Polysorbate 80, and Polysorbate 60 may be included. have.

상기 유화제는 화장료 조성물 총 중량에 대하여 0.1 내지 1.5 중량% 만큼 포함될 수 있으며, 유화제의 함량이 상기 범위에 포함될 경우 안료 입자의 분산성이 우수할 수 있다.The emulsifier may be contained in an amount of 0.1 to 1.5% by weight based on the total weight of the cosmetic composition. When the content of the emulsifier is within the above range, the dispersibility of the pigment particles may be excellent.

상술한 바와 같은 제조방법에 따라 제조된, 본 발명의 화장료 조성물은 입도 분포가 균일하고, 장시간이 경과하여도 점도 유지율이 높아 다양한 제형으로 제형화하기에 유리할 수 있다.The cosmetic composition of the present invention produced according to the above-described production method can be advantageous for formulation into various formulations since the particle size distribution is uniform and the viscosity retention rate is high even after prolonged time.

이하, 실시예를 통하여 본 발명을 더욱 구체적으로 설명하기로 하지만, 하기 실시예가 본 발명의 범위를 제한하는 것은 아니며, 이는 본 발명의 이해를 돕기 위한 것으로 해석되어야 할 것이다.Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the following examples should not be construed as limiting the scope of the present invention, and should be construed to facilitate understanding of the present invention.

실시예Example 1 One

하기 표 1에 나타난 바와 같은 조성으로 W/O 형태의 리퀴드 파운데이션 제형을 가지는 화장료 조성물을 제조하였다. A cosmetic composition having a liquid foundation formulation of W / O type as shown in Table 1 below was prepared.

입경이 0.3 ㎛ 내지 0.5 ㎛ 인 TiO2를 유화제인 POLYSORBATE 80 과 함께 수상인 하이드로제네이티드 레시틴(HYDROGENATED LECITHIN)에 첨가하여 박막선회형 고속믹서인 필믹서를 이용하여 30 m/s 의 회전속도로 분산시켜, 유상과 수상으로 코팅된 TiO2 안료 입자를 포함하는 리퀴드 파운데이션 제형의 화장료 조성물을 제조하였다.TiO 2 having a particle size of 0.3 탆 to 0.5 탆 was added to a water-in-oil hydrogeled lecithin together with an emulsifier POLYSORBATE 80 and dispersed at a rotation speed of 30 m / s using a peel mixer as a thin film swirling type high speed mixer To prepare a liquid foundation formulation of a cosmetic composition comprising TiO 2 pigment particles coated with oil and water.

이때, 상기 TiO2 안료 입자의 함량은 화장료 조성물 전체 중량을 기준으로 7 중량% 가 되도록 하였다. At this time, the content of the TiO 2 pigment particles was adjusted to 7 wt% based on the total weight of the cosmetic composition.

성분ingredient 중량%weight% 안료 입자(입경이 0.3 ㎛ 내지 0.5 ㎛ 인 TiO2)Pigment particles (TiO 2 having a particle diameter of 0.3 탆 to 0.5 탆) 77 유화제(POLYSORBATE 80)Emulsifier (POLYSORBATE 80) 1One 수상(HYDROGENATED LECITHIN)HYDROGENATED LECITHIN 0.50.5 부틸렌 글라이콜Butylene glycol 33 유화제(세틸 피이지/피피지-10/1 디메티콘)Emulsifier (cetyl phage / piperazine-10/1 dimethicone) 33 안료입자(디메티콘으로 코팅된 산화철) Pigment particles (iron oxide coated with dimethicone) 5.05.0 디메치콘(Dimethicone)Dimethicone 잔부Remainder 사이클로펜타실록산 및 PEG/PEG-19/19 디메치콘(Cyclopentasiloxane and PEG/PPG-19/19 Dimethicone)Cyclopentasiloxane and PEG / PEG-19/19 dimethicone (Cyclopentasiloxane and PEG / PPG-19/19 dimethicone) 5.05.0 디스테아르디모니움 헥토라이트 (Disteardimonium Hectorite)Disteardimonium Hectorite < RTI ID = 0.0 > 1.01.0 방부제antiseptic 적량Suitable amount 정제수Purified water 잔부Remainder

실시예Example 2  2

실시예 1과 동일하게 실시하되, 상기 TiO2 안료 입자의 함량은 화장료 조성물 전체 중량을 기준으로 10 중량% 가 되도록 하였다.The same procedure as in Example 1 was carried out except that the content of the TiO 2 pigment particles was 10% by weight based on the total weight of the cosmetic composition.

비교예Comparative Example 1  One

실시예 1과 동일하게 실시하되, 박막선회형 고속믹서 대신 링밀을 이용하여 유상과 수상으로 코팅된 TiO2 안료 입자를 포함하는 화장료 조성물을 제조하였다.A cosmetic composition was prepared in the same manner as in Example 1, except that TiO 2 pigment particles coated with oil phase and water phase were prepared using a ring mill instead of a thin film swirling type high speed mixer.

비교예Comparative Example 2  2

실시예 2와 동일하게 실시하되, 박막선회형 고속믹서 대신 링밀을 이용하여 유상과 수상으로 코팅된 TiO2 안료 입자를 포함하는 화장료 조성물을 제조하였다.A cosmetic composition comprising TiO 2 pigment particles coated with an oil phase and a water phase was prepared in the same manner as in Example 2 except that a ring mill was used instead of the thin film swirling type high speed mixer.

실험예Experimental Example 1: 입도 분포 측정 1: Measurement of particle size distribution

실시예 1 및 비교예 1에서 각각 제조된 리퀴드 파운데이션 제형의 화장료 조성물을 3D 레이저 현미경을 이용하여 관찰하였다.The cosmetic compositions of the liquid foundation formulations prepared in Example 1 and Comparative Example 1 were observed using a 3D laser microscope.

도 3a 및 도 3b는 각각 실시예 1 및 비교예 1에서 각각 제조된 화장료 조성물의 현미경 사진이다.3A and 3B are microscope photographs of the cosmetic composition prepared in Example 1 and Comparative Example 1, respectively.

도 3a를 참조하면 실시예 1은 크기가 큰 입자가 거의 관찰되지 않는 반면, 도 3b를 참조하면 비교예 1은 크기가 큰 입자가 다수 관찰되었다. 이로부터, 회전하는 분산기기의 원심력을 이용하여 안료 입자를 분산시키는 박막선회형 고속믹서를 사용하는 경우, 종래 링밀을 이용하는 경우에 비해 입도 분포를 균일하게 할 수 있음을 알 수 있다.Referring to FIG. 3A, in Example 1, particles having a large size were hardly observed, whereas in FIG. 3B, particles having a large size were observed in Comparative Example 1. From this, it can be seen that, when a thin film swirling type high-speed mixer for dispersing pigment particles using the centrifugal force of a rotating dispersing device is used, the particle size distribution can be made uniform compared to the case of using the ring mill in the past.

실험예Experimental Example 2: 장기 안정성 실험 2: Long term stability experiment

실시예 1,2 및 비교예 1,2에서 각각 제조된 화장료 조성물에 대해서 점도 경시율을 측정하기 위하여, 점도 최초 측정 당일, 점도 최초 측정일로부터 1일째, 7일째 및 3달째 되던 날에 각 화장료 조성물의 점도를 측정하여, 3달 동안의 점도 경시율을 비교하였다.For the cosmetic composition prepared in each of Examples 1, 2 and Comparative Examples 1 and 2, in order to measure the viscosity retention rate, each cosmetic composition was measured on the day of the first viscosity measurement, the first day, the seventh day, The viscosity of the composition was measured and the viscosity aging ratios for three months were compared.

도 4는 실시예 1,2 및 비교예 1,2의 화장료 조성물에 대한 점도 경시율 측정 결과를 나타낸 그래프이다.4 is a graph showing the results of viscosifi- cation rate measurement for the cosmetic compositions of Examples 1 and 2 and Comparative Examples 1 and 2.

도 4 및 하기 표 2를 참조하면, 실시예 1,2에서 각각 제조된 화장료 조성물은 3달 점도 경시율이 96% 정도이나, 비교예 2의 경우 3달 점도 경시율이 74% 정도이며 점도가 2만 cps 수준을 유지하므로 다양한 제형에 적용하기에 어려움이 있다.4 and Table 2, the cosmetic composition prepared in each of Examples 1 and 2 had a viscosity retention rate of about 96% for 3 months, and a viscosity of about 74% for 3 months in Comparative Example 2, It is difficult to apply to various formulations because it maintains 20,000 cps level.

단위:cpsUnit: cps 당일day 1일1 day 7일7 days 3달3 months 점도 경시율Viscosity aging rate 실시예 1Example 1 14450 cps14450 cps 14000 cps14000 cps 13800 cps13800 cps 11200 cps11200 cps 80%80% 실시예 2Example 2 14250 cps14250 cps 13600 cps13600 cps 13100 cps13100 cps 13067 cps13067 cps 96%96% 비교예 1Comparative Example 1 15050 cps15050 cps 13550 cps13550 cps 12650 cps12650 cps 10133 cps10133 cps 74%74% 비교예 2Comparative Example 2 21350 cps21350 cps 20400 cps20400 cps 20000 cps20000 cps 16533 cps16533 cps 81%81%

실험예Experimental Example 3:  3: 입도분포Particle size distribution

실시예 1,2 및 비교예 1,2에서 각각 제조된 화장료 조성물을 입도분포도를 측정하여 평균입도를 관찰하였다.The average particle sizes of the cosmetic compositions prepared in Examples 1 and 2 and Comparative Examples 1 and 2 were measured by measuring the particle size distribution.

하기 표 3은 실시예 1,2 및 비교예 1,2에서 각각 제조된 화장료 조성물의 평균입도이다. 실시예 1,2는 안료의 함량이 늘어나도 기존 안료의 입도와 유사한 사이즈를 유지하나, 비교예 1,2는 안료의 함량이 늘어날수록 기존 안료보다 입자가 커진다. 이는 실시예의 기술을 적용 시 안료가 재응집이 되지 않고 기존 안료의 사이즈를 안정적으로 잘 유지하는 반면, 종래 기술인 비교예는 제형 내에서 안료들이 응집되면서 사이즈가 커진 것으로 추정된다.Table 3 below shows the average particle sizes of the cosmetic compositions prepared in Examples 1 and 2 and Comparative Examples 1 and 2, respectively. In Examples 1 and 2, even when the content of the pigment increases, the size of the pigment is similar to that of the existing pigment. In Comparative Examples 1 and 2, the larger the content of the pigment, the larger the particle size. This is presumably because the pigments are not re-agglomerated and the size of the existing pigments stably and well maintained when applying the technique of the embodiment, while the comparative example of the prior art is enlarged in size as pigments cohere in the formulations.

안료Pigment 0.59 ㎛0.59 탆 실시예1Example 1 0.69 ㎛0.69 탆 실시예2Example 2 0.628 ㎛0.628 탆 비교예1Comparative Example 1 3.03 ㎛3.03 탆 비교예2Comparative Example 2 12.9 ㎛12.9 탆

실험예Experimental Example 4: 관능평가 4: Sensory evaluation

실시예 1,2 및 비교예 1,2에서 각각 제조된 화장료 조성물에 대해서 관능평가를 실시하였다.The cosmetic compositions prepared in Examples 1 and 2 and Comparative Examples 1 and 2 were subjected to sensory evaluation.

20~40세의 여성 30명을 대상으로 실시예 1,2 및 비교예 1,2에서 각각 제조된 화장료 조성물을 사용하게 하고, 하기와 같은 제1 특성 내지 제4 특성에 대해서 평가하여 그 결과를 도 5에 나타내었다.30 women aged 20 to 40 years were used to make the cosmetic compositions prepared in Examples 1 and 2 and Comparative Examples 1 and 2, and the following first to fourth characteristics were evaluated, 5.

- 제1 특성: 매끈함, 윤기, 촉촉함, 잔여감, 골끼임- First property: smooth, shiny, moist, residual, and

- 제2 특성: 두께감, 끈적임, 커버력- Second characteristic: Thickness, stickiness, coverage

- 제3 특성: 밀착감- Third characteristic: adhesion

- 제4 특성: 펴발림성- Fourth characteristic: spreadability

도 5는 실시예 1,2 및 비교예 1,2에 따른 화장료 조성물에 대해 관능평가를 실시한 결과를 나타낸 그래프이다.5 is a graph showing the results of sensory evaluation of the cosmetic compositions according to Examples 1 and 2 and Comparative Examples 1 and 2.

도 5를 참조하면, 실시예 1,2의 경우 매끈함, 윤기, 촉촉함, 잔여감, 골끼임이 모두 우수하며, 특히, 실시예 2의 경우 실시예 1에 비해 안료의 함량이 높으며 이에 따라 커버력도 우수한 것을 알 수 있다.Referring to FIG. 5, in Examples 1 and 2, the smoothness, the glossiness, the moistness, the residual feeling, and the prosperity were excellent. Particularly, in Example 2, the content of pigment was higher than that in Example 1, .

이에, 촉촉함과 커버력을 동시에 구현할 수 있는 화장료 조성물을 개발할 수 있음을 확인하였다.Thus, it was confirmed that a cosmetic composition capable of simultaneously realizing moisturizing and covering power could be developed.

이하 본 발명의 또 다른 제형예를 설명하지만, 본 발명에 따른 유상과 수상을 포함하는 코팅층으로 코팅된 안료 입자를 포함하는 화장료 조성물의 제형이 이들 예로만 한정되는 것은 아니다.Hereinafter, another formulation example of the present invention will be described. However, the formulation of the cosmetic composition comprising pigment particles coated with the coating layer comprising oil phase and water phase according to the present invention is not limited to these examples.

제형예Formulation Example 1: 마사지 크림 1: Massage cream

하기 표 4의 조성에 따라 통상적인 방법으로 본 발명의 유상과 수상을 포함하는 코팅층으로 코팅된 안료를 포함하는 마사지 크림을 제조하였다.Massage creams comprising pigments coated with a coating layer comprising an oil phase and an aqueous phase of the present invention were prepared in a conventional manner according to the composition of Table 4 below.

성분ingredient 중량%weight% 안료 입자(입경이 0.3 ㎛ 내지 0.5 ㎛ 인 TiO2)Pigment particles (TiO 2 having a particle diameter of 0.3 탆 to 0.5 탆) 0.50.5 유화제(POLYSORBATE 80)Emulsifier (POLYSORBATE 80) 1One 수상(HYDROGENATED LECITHIN)HYDROGENATED LECITHIN 16.516.5 이카리시드 B2Icari seed B2 0.50.5 밀납Wax 10.010.0 폴리솔베이트 60Polysorbate 60 1.51.5 PEG 60 경화피마자유PEG 60 hardened castor oil 2.02.0 솔비탄세스퀴올레이트Sorbitan sesquioleate 0.80.8 유동파라핀Liquid paraffin 40.040.0 스쿠알란Squalane 5.05.0 카프릴릭/카프릭트리글리세라이드Caprylic / capric triglyceride 4.04.0 글리세린glycerin 5.05.0 부틸렌글리콜Butylene glycol 3.03.0 프로필렌글리콜Propylene glycol 3.03.0 트리에탄올아민Triethanolamine 0.20.2 방부제,색소,향료Preservative, coloring, fragrance 적량Suitable amount 정제수Purified water 잔부Remainder

제형예Formulation Example 2: 영양 화장수 2: Nourishing lotion

하기 표 5의 조성에 따라 통상적인 방법으로 본 발명의 유상과 수상을 포함하는 코팅층으로 코팅된 안료를 포함하는 영양 화장수를 제조하였다.A nutrition lotion comprising a pigment coated with a coating layer comprising an oil phase and an aqueous phase of the present invention was prepared in a conventional manner according to the composition of Table 5 below.

성분ingredient 중량%weight% 안료 입자(입경이 0.3 ㎛ 내지 0.5 ㎛ 인 TiO2)Pigment particles (TiO 2 having a particle diameter of 0.3 탆 to 0.5 탆) 0.10.1 유화제(POLYSORBATE 80)Emulsifier (POLYSORBATE 80) 1One 수상(HYDROGENATED LECITHIN)HYDROGENATED LECITHIN 16.916.9 알파-케토글루타르산Alpha-keto glutaric acid 1.01.0 나이아신아마이드Niacinamide 1.01.0 베타-1,3-글루칸Beta-1,3-glucan 1.01.0 밀납Wax 4.04.0 폴리솔베이트Polysorbate 1.51.5 솔비탄세스퀴올레이트Sorbitan sesquioleate 1.51.5 유동파라핀Liquid paraffin 0.50.5 카프릴릭/카프릭트리글리세라이드Caprylic / capric triglyceride 5.05.0 글리세린glycerin 3.03.0 부틸렌글리콜Butylene glycol 3.03.0 프로필렌글리콜Propylene glycol 3.03.0 카르복시비닐폴리머Carboxyvinyl polymer 0.10.1 트리에탄올아민Triethanolamine 0.20.2 방부제, 향료Preservative, fragrance 0.10.1 정제수Purified water 잔부Remainder

제형예Formulation Example 3: 팩 3: Pack

하기 표 6의 조성에 따라 통상적인 방법으로 유상과 수상을 포함하는 코팅층으로 코팅된 안료를 포함하는 팩을 제조하였다.A pack containing pigments coated with a coating layer comprising oil phase and water phase was prepared in a conventional manner according to the composition of Table 6 below.

성분ingredient 중량%weight% 안료 입자(입경이 0.3 ㎛ 내지 0.5 ㎛ 인 TiO2)Pigment particles (TiO 2 having a particle diameter of 0.3 탆 to 0.5 탆) 22 유화제(POLYSORBATE 80)Emulsifier (POLYSORBATE 80) 1One 수상(HYDROGENATED LECITHIN)HYDROGENATED LECITHIN 1515 글리세린glycerin 4.04.0 폴리비닐알코올Polyvinyl alcohol 15.015.0 히알루론산 추출물Hyaluronic acid extract 5.05.0 베타글루칸Beta Glucan 7.07.0 알란토인Allantoin 0.10.1 노닐페닐에테르Nonyl phenyl ether 0.40.4 폴리솔베이트 60Polysorbate 60 1.21.2 에탄올ethanol 6.06.0 정제수Purified water 잔부Remainder

제형예Formulation Example 4: 연고 4: Ointment

하기 표 7의 조성에 따라 통상적인 방법으로 본 발명의 유상과 수상을 포함하는 코팅층으로 코팅된 안료를 포함하는 연고를 제조하였다.Ointments were prepared in a conventional manner according to the composition of Table 7 below, including pigments coated with a coating layer comprising an oil phase and an aqueous phase of the present invention.

성분ingredient 중량%weight% 안료 입자(입경이 0.3 ㎛ 내지 0.5 ㎛ 인 TiO2)Pigment particles (TiO 2 having a particle diameter of 0.3 탆 to 0.5 탆) 22 유화제(POLYSORBATE 80)Emulsifier (POLYSORBATE 80) 1One 수상(HYDROGENATED LECITHIN)HYDROGENATED LECITHIN 1515 알파-케토글루타르산Alpha-keto glutaric acid 1.01.0 나이아신아마이드Niacinamide 1.01.0 베타-1,3-글루칸Beta-1,3-glucan 10.010.0 밀납Wax 10.010.0 폴리솔베이트Polysorbate 5.05.0 피이지 60 경화피마자유Piggy 60 hardened castor oil 2.02.0 솔비탄세스퀴올레이트Sorbitan sesquioleate 0.50.5 바세린Vaseline 5.05.0 유동파라핀Liquid paraffin 10.010.0 스쿠알란Squalane 5.05.0 쉐어버터Sheer butter 3.03.0 카프릴릭/카프릭트리글리세라이드Caprylic / capric triglyceride 5.05.0 글리세린glycerin 10.010.0 프로필렌글리콜Propylene glycol 10.210.2 트리에탄올아민Triethanolamine 0.20.2 방부제, 향료Preservative, fragrance 0.10.1 정제수Purified water 잔부Remainder

제형예Formulation Example 5: 겔 5: Gel

하기 표 8의 조성에 따라 통상적인 방법으로 유상과 수상을 포함하는 코팅층으로 코팅된 안료를 포함하는 겔을 제조하였다.A gel comprising pigments coated with a coating layer comprising an oil phase and an aqueous phase was prepared in a conventional manner according to the composition shown in Table 8 below.

성분ingredient 중량%weight% 안료 입자(입경이 0.3 ㎛ 내지 0.5 ㎛ 인 TiO2)Pigment particles (TiO 2 having a particle diameter of 0.3 탆 to 0.5 탆) 1One 유화제(POLYSORBATE 80)Emulsifier (POLYSORBATE 80) 1One 수상(HYDROGENATED LECITHIN)HYDROGENATED LECITHIN 1616 판테놀Panthenol 5.05.0 해송자 오일Seaweed oil 0.010.01 알파-케토글루타르산Alpha-keto glutaric acid 1.01.0 나이아신아마이드Niacinamide 1.01.0 베타-1,3-글루칸Beta-1,3-glucan 0.10.1 에틸렌디아민초산나트륨Ethylenediamine sodium acetate 0.050.05 글리세린glycerin 5.05.0 카르복시비닐폴리머Carboxyvinyl polymer 0.30.3 에탄올ethanol 5.05.0 피이지 60 경화피마자유Piggy 60 hardened castor oil 0.50.5 트리에탄올아민Triethanolamine 0.30.3 방부제, 향료Preservative, fragrance 0.10.1 정제수Purified water 잔부Remainder

[부호의 설명][Description of Symbols]

1: 유상과 수상을 포함하는 코팅층을 포함하는 안료1: pigment containing a coating layer including an oil phase and water phase

10: 안료 입자10: pigment particle

20: 단일 코팅층20: single coating layer

30: 이중 코팅층30: Duplex coating layer

30a: 유상층30a: Oil phase layer

30b: 수상층30b:

Claims (11)

유상과 수상을 포함하는 코팅층으로 코팅된 안료 입자를 포함하는 화장료 조성물.A cosmetic composition comprising pigment particles coated with a coating layer comprising oil phase and water phase. 제1항에 있어서,The method according to claim 1, 상기 안료의 입도는 0.1 ㎛ 내지 1 ㎛인, 화장료 조성물.Wherein the pigment has a particle size of 0.1 mu m to 1 mu m. 제1항에 있어서,The method according to claim 1, 상기 안료는 산화티탄(titanium dioxide, TiO2), 마이크로 산화티탄(Micro TiO2), 산화아연(zinc oxide, ZnO), 마이크로 산화아연(Micro ZnO), 산화철, 산화알루미늄(alumina, Al2O3), 황산바륨(barium sulfate, BaSO3), 이산화규소(silica, SiO2), 탈크, 카올린, 세리사이트(sericite) 및 마이카로 이루어진 군에서 선택되는 1종 이상의 무기 안료인, 화장료 조성물.The pigment may be selected from the group consisting of titanium dioxide (TiO 2 ), micro TiO 2 , zinc oxide (ZnO), micro ZnO, iron oxide, alumina, Al 2 O 3 Wherein the inorganic pigment is at least one inorganic pigment selected from the group consisting of barium sulfate, BaSO 3 , silica, SiO 2 , talc, kaolin, sericite and mica. 제1항에 있어서,The method according to claim 1, 상기 유상은 디메치콘류, 메치콘류, 하이드로겐 디메치콘류, 카플릴릭 실란류 및 불소계 실리콘류로 이루어진 군에서 선택되는 1종 이상을 포함하는, 화장료 조성물.Wherein the oil phase comprises at least one member selected from the group consisting of Dimethicone, Methicone, Hydrogen Dimethicone, Caprylic Silanes, and Fluorochemicals. 제1항에 있어서,The method according to claim 1, 상기 수상은 레시틴류 및 실리카류로 이루어진 군에서 선택되는 1종 이상을 포함하는, 화장료 조성물.Wherein the water phase comprises at least one member selected from the group consisting of lecithins and silicas. 제1항에 있어서,The method according to claim 1, 상기 코팅층은 유상과 수상의 혼합물을 포함하는 단일 코팅층인, 화장료 조성물.Wherein the coating layer is a single coating layer comprising a mixture of oil phase and water phase. 제1항에 있어서,The method according to claim 1, 상기 코팅층은 유상층 및 수상층을 포함하는 이중 코팅층인, 화장료 조성물.Wherein the coating layer is a double coating layer comprising an oil phase layer and a water phase layer. 제1항에 있어서,The method according to claim 1, 상기 화장료 조성물은 수분산, 유분산, W/O(water in oil) 또는 O/W(oil in water)의 형태로 제형화되는 것인, 화장료 조성물.Wherein the cosmetic composition is formulated in the form of water dispersion, oil dispersion, W / O (water in oil) or O / W (oil in water). 제1항에 있어서,The method according to claim 1, 상기 화장료 조성물은 리퀴드, 크림 또는 케익 형태의 파운데이션, 메이크업베이스 화장료 또는 자외선 차단용 화장료의 형태로 제형화되는 것인, 화장료 조성물.Wherein the cosmetic composition is formulated in the form of a liquid, cream or cake type foundation, a make-up base cosmetic or an ultraviolet screening cosmetic. 안료와 유화제를 수상에 분산시키되, 박막선회형 고속믹서 분산기기를 이용하여 분산시켜, 상기 안료의 표면에 유상과 수상을 포함하는 코팅층을 형성하는 단계를 포함하는, 화장료 조성물의 제조방법.Dispersing a pigment and an emulsifier in an aqueous phase and dispersing the mixture using a thin film swirling type high-speed mixer dispersing apparatus to form a coating layer including oil phase and water phase on the surface of the pigment. 제10항에 있어서,11. The method of claim 10, 상기 분산기기의 회전속도는 5 내지 50 m/s인, 화장료 조성물의 제조방법.Wherein the rotational speed of the dispersing device is 5 to 50 m / s.
PCT/KR2018/008215 2017-07-31 2018-07-20 Cosmetic composition comprising pigment and method for producing same Ceased WO2019027164A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3771188B2 (en) * 2002-04-10 2006-04-26 花王株式会社 Cosmetics
KR100768113B1 (en) * 2005-12-02 2007-10-18 주식회사 케미랜드 Cosmetic composition on powder
US20110110995A1 (en) * 2008-05-21 2011-05-12 Miyoshi Kasei, Inc. Surface-treated powder and cosmetic comprising the same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10061178A1 (en) 2000-12-07 2002-06-20 Merck Patent Gmbh Silver-colored gloss pigment
CN105982832B (en) * 2015-03-05 2021-06-01 株式会社爱茉莉太平洋 Solid makeup cosmetic composition
CN106389153A (en) * 2015-08-12 2017-02-15 科丝美诗(中国)化妆品有限公司 Cosmetic composition used for makeup and containing volatile organic gel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3771188B2 (en) * 2002-04-10 2006-04-26 花王株式会社 Cosmetics
KR100768113B1 (en) * 2005-12-02 2007-10-18 주식회사 케미랜드 Cosmetic composition on powder
US20110110995A1 (en) * 2008-05-21 2011-05-12 Miyoshi Kasei, Inc. Surface-treated powder and cosmetic comprising the same

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"PRIMIX Corporation Mixers Guide", SINJUNG PRECISION MACHINE, 17 August 2009 (2009-08-17), pages 1 - 39, XP055571435, Retrieved from the Internet <URL:http://www.sinjung.co.kr/product/gg-ih/uhg/PRIMIX%20Products.pdf> *
ECOTECH HOMEPAGE: "Surface Treatment Pigments for Cosmetics", PRODUCT BOARD, 25 August 2016 (2016-08-25), pages 1 - 3, Retrieved from the Internet <URL:http://www.ecotechl.com/bbs/?t=1P> *

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