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WO2019088711A2 - Frozen dough composition improved in freezing and thawing stability - Google Patents

Frozen dough composition improved in freezing and thawing stability Download PDF

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Publication number
WO2019088711A2
WO2019088711A2 PCT/KR2018/013128 KR2018013128W WO2019088711A2 WO 2019088711 A2 WO2019088711 A2 WO 2019088711A2 KR 2018013128 W KR2018013128 W KR 2018013128W WO 2019088711 A2 WO2019088711 A2 WO 2019088711A2
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WO
WIPO (PCT)
Prior art keywords
frozen
parts
weight
yeast
dough
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Ceased
Application number
PCT/KR2018/013128
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French (fr)
Korean (ko)
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WO2019088711A3 (en
Inventor
양지선
최종민
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CJ CheilJedang Corp
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CJ CheilJedang Corp
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Publication of WO2019088711A2 publication Critical patent/WO2019088711A2/en
Publication of WO2019088711A3 publication Critical patent/WO2019088711A3/en
Anticipated expiration legal-status Critical
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/18Carbohydrates
    • A21D2/181Sugars or sugar alcohols
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D10/00Batters, dough or mixtures before baking
    • A21D10/02Ready-for-oven doughs
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/18Carbohydrates
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D6/00Other treatment of flour or dough before baking, e.g. cooling, irradiating or heating
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D6/00Other treatment of flour or dough before baking, e.g. cooling, irradiating or heating
    • A21D6/001Cooling

Definitions

  • the present invention relates to a frozen edible composition containing alulose, wheat flour and yeast, and more particularly to a method for improving the preservation of yeast in frozen edible flakes, freezing frozen edible dough, and a cured frozen edible dough.
  • Frozen dough refers to a dough that can be quickly frozen and frozen to preserve the dough for a relatively long period of time, which can be thawed and fired as needed to produce a bakery product.
  • a series of processes such as fermentation, aging, molding, and firing are continuously required from the pastry to the dough, resulting in loss of time and labor. Therefore, By circulating in frozen form, production and working efficiency can be improved.
  • Frozen dough is mainly preserved by cryopreservation to inhibit the yeast and enzyme activity which may affect the durability of the dough, so that the dough can be preserved for a long time and the product can be maintained. have.
  • cryopreservation to inhibit the yeast and enzyme activity which may affect the durability of the dough, so that the dough can be preserved for a long time and the product can be maintained. have.
  • yeast which is a living yeast in frozen raw material
  • the yeast itself is killed or a reducing substance such as glutathione is eluted from the cells to weaken the dough and decrease the fermentation power.
  • the degree of gas generation of the yeast and the gas holding capacity of the dough are lowered, and the fermentation time required after thawing is prolonged.
  • the degree of expansion of the product is insufficient and the foam film of the product is formed thick, .
  • the above-mentioned problem of the frozen dough is that frozen dough is changed by the cryopreservation process. As the fermentation starts and at the same time the frozen dough grows according to the physiological change of the yeast itself, This is because alcohol accumulation as a fermentation metabolism is combined with wheat flour. In addition, the formation of ice crystals destroys the three-dimensional network structure of gluten, and glutathione leached from the frost-damaged yeast affects the gluten protein.
  • the present inventors have found that by adding a certain amount of alulose as a sugar source to the frozen dough, the yeast storage stability during storage of the frozen dough can be improved and the effect of suppressing the volume reduction and the curing of the frozen dough can be suppressed.
  • the present application has been completed.
  • One object of the present application is to provide a frozen edible composition comprising alulose, wheat flour and yeast.
  • Another object of the present application is to provide a bread made of the frozen raw material.
  • the frozen raw material of the present application has an effect of improving the preservability of yeast, thereby suppressing volume reduction due to freezing storage and hardening of the product, and consequently increasing shelf life.
  • Figure 1 shows the volume of the finished product prepared using frozen dough stored for 120 days. Comparative Example 1 was a frozen dough containing no alulose, Experiment 1 was a frozen dough containing 20% of alulose, Experiment 2 was a frozen dough containing 40% of alulose, Experiment 3 was 60% Experimental Example 4 is a frozen dough containing 80% of alulose, Experiment 5 is a frozen dough containing 100% of alulose, and Comparative Example 2 is a non-frozen dough containing no alulose.
  • One aspect of the present application to accomplish the above object provides a frozen edible composition comprising alulose, wheat flour and yeast.
  • alulose is a type of sugar having the formula C 6 H 12 O 6 , molecular weight of 180.16, which is known to exist in small quantities in figs, grapes and the like, and is also called psicose.
  • the above-mentioned aluloses include both D-aluloses and L-aluloses, and commercially available aluloses may be purchased and used, or they may be prepared by chemical or microbiological methods.
  • the allylose may be in the form of a liquid, a powder or a crystal, and in the case of a liquid phase, the solid content is 65 to 80 parts by weight, 65 to 78 parts by weight, 68 to 78 parts by weight, 68 to 75 parts by weight, , 68 to 73 parts by weight, or 70 to 72 parts by weight, which may be mixed with other raw materials and used in a diluted or concentrated form.
  • the purity of the pure alu- lose may be 85 to 99.5 parts by weight, 85 to 98 parts by weight, 90 to 98 parts by weight, 93 to 98 parts by weight, or 95 to 98 parts by weight based on 100 parts by weight of the solid content.
  • the purity of the pure aluloside on the whole 100 parts by weight may be 90 parts by weight or more, 95 parts by weight or more and 98 parts by weight or more and may be mixed with other raw materials to form a diluted form Can be used.
  • the alululose may be contained in an appropriate amount in the frozen dough composition, specifically, 0.01 to 20 parts by weight, 0.05 to 15 parts by weight, 0.1 to 10 parts by weight, 0.5 to 8 parts by weight, 0.75 to 0.75 parts by weight, To 5 parts by weight, 1 to 5 parts by weight, or 1.5 to 7.5 parts by weight.
  • the flour and the alulose are mixed in a ratio of 1: 0.02 to 1: 0.15, 1: 0.01 to 1: 0.15, 1: 0.02 to 1: 0.18, 1: 0.01 to 1: 0.18, 1: 0.05 to 1: 0.15, 1: 0.15, 1: 0.05 to 1: 0.18, 1: 0.04 to 1: 0.18, 1: 0.02 to 1: 0.12, But the present invention is not limited thereto in terms of a mixing ratio of 1: 0.13, 1: 0.05 to 1: 0.12, 1: 0.04 to 1: 0.12, 1: 0.05 to 1: 0.13, or 1: 0.04 to 1: 0.13.
  • the yeast and the allylose may be used in a ratio of 1: 0.5 to 1: 2.5, 1: 0.3 to 1: 2.5, 1: 0.5 to 1: 2.8, 1: 0.3 to 1: 1: 0.3 to 1: 2, 1: 0.5 to 1: 2.3, 1: 0.3 to 1: But the present invention is not limited thereto and may be contained at a mixing ratio of 1: 2, 1: 1 to 1: 2, 1: 0.7 to 1: 2, 1:
  • the aluloses of the present application may be those directly extracted from natural products, chemically synthesized, or produced by biological methods, but are not limited thereto.
  • wheat flour refers to a powder obtained by a process such as screening, souring, grinding, and separation of wheat, and the flour may be a strong, a gravity or a pulverizer. Specifically, the flour may be strong, but is not limited thereto.
  • the yeast may be cultured in a commercially available form, dried powdery yeast, or live yeast squeezed in a state containing moisture.
  • the yeast may be used in an amount of 0.01 to 10 parts by weight, 0.05 to 10 parts by weight , 0.1 to 7 parts by weight, 0.1 to 5 parts by weight, 0.5 to 5 parts by weight, 1 to 5 parts by weight, or 3 parts by weight, but is not limited thereto.
  • the frozen dough composition of the present application may further comprise vitamin C or amylase.
  • the vitamin C and the amylase may be contained in the freeze-dried composition as a composite, or may be separately contained.
  • the vitamin C and the amylase may be used in an amount of 0.0001 to 0.05 parts by weight, 0.0001 to 0.04 parts by weight, 0.0001 to 0.03 parts by weight, 0.0001 to 0.02 parts by weight, 0.0001 to 0.0125 parts by weight, 0.0025 to 0.05 parts by weight, 0.0025 to 0.04 parts by weight, 0.0025 to 0.03 parts by weight, 0.0025 to 0.02 parts by weight, 0.0025 to 0.0125 parts by weight, 0.005 to 0.0125 parts by weight, 0.0002 to 0.05 parts by weight, 0.0002 to 0.04 parts by weight, 0.0002 to 0.03 parts by weight, From 0.00025 to 0.012 parts by weight, from 0.00025 to 0.0125 parts by weight, from 0.00025 to 0.05 part by weight, from 0.00025 to 0.04 parts by weight, from 0.00025 to 0.03 parts by weight, from 0.00025 to 0.02 parts by weight, from 0.00025 to 0.0125 parts by weight, 0.0005 to 0.03 parts by weight, 0.0005 to 0.02
  • the frozen dough composition of the present application may be one that additionally or not contain sugar or fructose.
  • the frozen dough composition of the present application may further comprise at least one sweetener in addition to alulose.
  • sweeteners include, but are not limited to, known sweeteners (e.g., monosaccharides, disaccharides, oligosaccharides, sugar alcohols and high sweeteners).
  • the monosaccharide may be, for example, arabinose, xylose, fructose, tagatose, aloose, or galactose
  • the disaccharide is a sugar in which two monosaccharides are bonded to each other, such as lactose, maltose, trehalose, Cellobiose.
  • the oligosaccharide may be a sugar having three or more monosaccharides bound thereto, for example, fructo-oligosaccharide, isomaltooligosaccharide, xylooligosaccharide, gentio oligosaccharide, maltooligosaccharide or galacto-oligosaccharide.
  • the sugar alcohol is a substance formed by reducing a carbonyl group of a saccharide, and may be, for example, erythritol, xylitol, arabitol, mannitol, sorbitol, maltitol or lactitol.
  • the high-sweetening agent may be a substance having a sweetness ten times or more higher than that of sugar, such as, but not limited to, aspartame, acesulfame K, rebaudioside A or sucralose.
  • the sugar and the allyl are contained in an amount of 0.01 to 20 parts by weight, 0.05 to 15 parts by weight, 0.1 to 15 parts by weight, 0.1 to 10 parts by weight, 0.5 to 8 parts by weight, or 1.5 to 7.5 parts by weight, but not limited thereto.
  • the sugar and the allylose are mixed in a ratio of 1:20 to 1: 0.01, 1:10 to 1: 0.1, 1: 5 to 1: 0.2, 1: 5 to 1: 0.2, or 1: 4 to 1: 0.25, but the present invention is not limited thereto.
  • the frozen dough composition of the present application may not contain sugar.
  • the frozen raw material of the present application exhibits significantly improved yeast survival rate and improved physical properties of the frozen raw material both in the case of sugar, alulose alone or in the case of mixing sugar and alulose.
  • the yeast survival rate in the present application means the ratio of the number of remaining cell masses after the storage period has elapsed from the time of manufacturing the frozen raw material, that is, the ratio of the number of living cell colonies after the storage period to the initial number of cell aggregates.
  • CFU colony forming unit
  • the yeast survival rate in the frozen raw material of the present application is 24-72%, 20-72%, 24-75%, 20-75%, 63-72%, 58-72%, 63-75% To 75%, 58 to 75%, 50 to 72%, 63 to 78%, or 50 to 78%.
  • the frozen dough composition of the present application may further comprise an edible oil.
  • the edible oil includes vegetable oil, animal oil, edible oil and the like.
  • specific examples of vegetable oils include soybean oil, soybean oil, corn oil, rapeseed oil, rice bran oil, sesame oil, perilla oil, safflower oil, sunflower oil, cottonseed oil, peanut oil, olive oil, palm oil, palm oil, Specific examples thereof include pig grease (rod), horse oil (hate), sheep oil, tallow, fish oil, egg yolk oil and milk fat.
  • Examples of the edible oils and fats include mixed edible oil, flavored oil, And the like, and is specifically used in the form of margarine in the present application, but is not limited thereto, and the edible oil which can be used for the production of frozen dough can be included without limitation.
  • the frozen dough composition of the present application may further comprise eggs, milk powder, an emulsifier, a stabilizer, an acidity adjusting agent, a refined salt, a flavoring, or water in addition to the edible oil, alululose, fructose or sugar.
  • the frozen edible raw paper composition of the present application may further include known materials generally used for producing frozen edible raw materials.
  • the powdered milk is one of dairy products which provide a milk ingredient, and the powdered milk includes whole milk powder, skim milk powder, mixed milk powder and the like, and the ingredients for providing milk ingredients that can be used in the production of frozen dough can be included without limitation.
  • the frozen dough composition of the present application may be one in which the preservability and viability of the yeast are increased and the yeast storage stability is improved.
  • yeast preservation in this application means the degree to which the number of yeasts contained in the frozen biomass is preserved during rapid freezing and cryopreservation.
  • the frozen edible tissue composition of the present application contains alulose, vitamin C and amylase, thereby suppressing the decrease in yeast survival rate due to freezing disorder and exhibiting excellent yeast preservability.
  • a bread or bread made from the frozen raw material.
  • bread in the present application means a product which is prepared by mixing water with flour as a main raw material and baking it in an oven after being fermented, and may be included without limitation as far as it is classified as bread in the technical field.
  • the bread prepared from the frozen raw material of the present application may have an improved pore content.
  • the degree of gas generation and the gas holding amount of the dough are lowered due to the frost trouble of the yeast, which results in a problem that the degree of product expansion is insufficient.
  • the pastry made from the frozen dough of the present application may inhibit the frost from being affected by the yeast to improve the preservability of the yeast and improve the gas holding amount and expansion degree of the dough.
  • the bread made from the frozen raw paper of the present application may have improved physical properties.
  • the bread made from the frozen raw material of the present application may have a reduced volume (volume) in accordance with the storage period.
  • volume volume
  • an experiment for measuring the volume change by each experimental group was conducted.
  • the volume change rate of the finished product manufactured using the frozen raw paper of the present application is -54.7% to 8.84%, -57% to 8.84%, -54.7% to 10%, -57% to 10%, -10.5% to 8.84% -12% to 8.84%, -10.5% to 10%, or -12% to 10%.
  • Hardness means the degree of hardness of the material. In the case of breads made from frozen dough, the higher the hardness, the harder the product becomes, which is disadvantageous in terms of palatability. On the contrary, when the hardness is low, a soft texture can be obtained.
  • the elasticity means a property of returning to the original shape when the external force applied to the object is removed. In the case of the bread made of frozen raw material, the higher the elasticity, the more smooth and crispy texture can be obtained.
  • Another aspect of the present application for achieving the above object is to provide a method for improving the yeast preservability of frozen dough, comprising mixing alulose, wheat flour and yeast, and freezing the mixed dough.
  • Another aspect of the present application for achieving the above object is to provide a method for inhibiting curing of frozen dough, comprising mixing alulose, wheat flour and yeast, and freezing the mixed dough.
  • the flour, yeast, alulose, vitamin C, amylase, frozen dough, and yeast preservability are as described above.
  • the method may further comprise mixing vitamin C and amylase.
  • 'hardening means that the texture of the product is hardened, and in the case of frozen dough, it means that the surface or interior of the dough is hardened and cracked in the process of cold-soldering and aging phenomenon occurs.
  • the method of the present application improves the preservation of yeast in the freeze storage process of frozen dough by adding a step of mixing alulose, vitamin C and amylase in the process of manufacturing frozen dough, and can suppress the degree of curing of frozen dough have.
  • the frozen dough of Comparative Example 1 and Experiments 1 to 5 of Table 1 was prepared through the following procedure.
  • the mixture of high strength, yeast, sugar, alulose, amylase and vitamin C, salt, powdered milk, egg and water were added to the mixing machine according to the composition (% by weight) of Table 1 for 5 to 7 minutes, Were added and mixed for 8 to 10 minutes.
  • the temperature of the product was set at 17 ° C to 20 ° C. After the completion of the mixing, the finished product was allowed to stand at rest for 10 minutes at room temperature.
  • the ground paper after the stoppage was divided into 40 g portions, rounded in a circular shape, and then quickly frozen (-25 to -40 ⁇ ) for 30 to 45 minutes with a constant interval between the panes. Rapidly frozen raw materials were transferred to general freezing (-10 to -20 ° C) and stored for 30 days, 60 days, or 120 days.
  • a product (bread) was prepared using the frozen dough prepared in Example 1 above.
  • the frozen dough kept for 30 days, 60 days, or 120 days in general freezing was thawed at about 12 hours in the refrigerator, and then left at rest for 30 minutes at room temperature.
  • the resting pellets were rounded off and the gas was drained and the secondary fermentation was carried out in the same manner for 50 minutes at regular intervals in the pan.
  • the fermentation conditions were set at 37 to 38 DEG C and a humidity of 82 to 85%.
  • the fermented raw material was fired (11 minutes) in an oven preheated at an upper temperature of 210 ° C and a lower temperature of 180 ° C to prepare a finished product.
  • survival rate of yeast was measured and compared with each frozen dough. At this time, the frozen raw paper was used for measurement without thawing.
  • the survival rate of yeast was measured by taking each frozen dough from 30 days, 60 days, or 120 days storage immediately after the preparation, measuring single colonies of colonies, comparing the single colonies of colonies measured immediately after production, Fungal colonization was expressed as a ratio.
  • conventional microorganism test methods were used. Specifically, 20 g of each of the frozen dough samples per storage period was mixed with 180 mL of 0.9% sterilized physiological saline. The homogenized mixture was thoroughly pulverized and homogenized using a homogenizer (STOMACHER, B & F Korea) Diluted samples were prepared by dilution stepwise.
  • frozen dough can be provided in terms of fermentation time, merchandise quality and quality.
  • Example 4 Comparative analysis of the appearance of the finished product made from frozen dough
  • volume change was measured for each experimental group. Specifically, the volume was measured using a volume scanner (PERTEN, BVM6640), and the volume was measured after cooling and cooling in an oven at 210 ° C. for 120 days of storage time. The results are shown in Fig.
  • the porosity of the finished product manufactured using frozen raw material was measured. Specifically, the sample of the finished product was cut in half (1/2) in the longitudinal direction, and the amount of pores was visually measured.
  • the gas retention of the frozen dough containing a certain amount of alulose and the swelling force of the dough are improved, thereby improving the problems caused by the frost defect, and as a result, the product can be manufactured with excellent quality.
  • Example 5 Comparison of physical properties of finished products prepared from frozen dough

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Freezing, Cooling And Drying Of Foods (AREA)

Abstract

The present application relates to a frozen dough composition comprising allulose and a preparation method therefor.

Description

냉해동 안정성이 증진된 냉동생지 조성물A frozen dough composition having improved cold stability

본 출원은 알룰로스, 밀가루 및 효모를 포함하는 냉동생지 조성물에 관한 것으로, 구체적으로 상기 냉동생지로 제조된 빵류, 냉동생지의 효모 보존성 개선 방법, 및 냉동생지의 경화 억제 방법에 관한 것이다.The present invention relates to a frozen edible composition containing alulose, wheat flour and yeast, and more particularly to a method for improving the preservation of yeast in frozen edible flakes, freezing frozen edible dough, and a cured frozen edible dough.

냉동생지란 제조된 반죽을 비교적 오랜기간 보관하기 위해 급속 동결 및 냉동 보존하는 것으로 필요시 즉시 해동 및 소성하여 베이커리 제품을 제조할 수 있는 반죽을 말한다. 베이커리 제품을 즉시 제조하는 데에는 밀가루 반죽부터 발효, 숙성, 성형, 소성의 일련의 과정이 연속적으로 요구되어 시간 및 노동적 손실이 수반되므로, 대량으로 제조된 반죽(생지)을 매우 낮은 온도로 처리하여 냉동된 형태로 유통함으로써 생산 및 작업 효율이 증진될 수 있다. Frozen dough refers to a dough that can be quickly frozen and frozen to preserve the dough for a relatively long period of time, which can be thawed and fired as needed to produce a bakery product. In order to produce a bakery product immediately, a series of processes such as fermentation, aging, molding, and firing are continuously required from the pastry to the dough, resulting in loss of time and labor. Therefore, By circulating in frozen form, production and working efficiency can be improved.

냉동생지는 주요하게는 냉동 보존을 통해 반죽의 상품성에 영향을 미칠 수 있는 이스트 및 효소 활동을 억제함으로써 반죽을 장기간 보존하고 상품성을 유지할 수 있으며, 필요 시점에 해동하여 해당 제품을 만들 수 있다는 특징이 있다. 이로써 소비자에게 직접적으로 신선한 제품을 공급할 수 있고, 생산 스케쥴 관리가 용이하여 제품의 생산 및 보관 효율성이 높으며, 다품종 소량 생산이 가능하다는 등의 장점이 있어 그 사용이 일반화되고 있다. Frozen dough is mainly preserved by cryopreservation to inhibit the yeast and enzyme activity which may affect the durability of the dough, so that the dough can be preserved for a long time and the product can be maintained. have. As a result, it is possible to supply fresh products directly to consumers, easy production schedule management, high production and storage efficiency of products, and small quantity production of various kinds of products.

다만, 냉동생지 내의 살아있는 효모인 이스트는 동결에 영향을 받아 효모 자체가 사멸하거나, 글루타치온과 같은 환원성 물질을 균체에서 용출하여 반죽을 연약화시키고 발효력을 감소시키는 문제가 있다. 그 결과, 이스트의 가스 발생 정도 및 반죽의 가스 보유량이 저하되어 해동 후 필요한 발효 시간이 길어지게 되고, 이로 인해 제품 팽창 정도가 부족할 뿐만 아니라 제품 내상의 기포막이 두껍게 형성되어 결과적으로 제품의 최종 품질이 저하된다. 또한, 냉동생지에 형성된 얼음 결정이 냉동보관 중 성장함에 따라 글루텐이 동결 장애를 받아, 이산화탄소 가스 보유력 및 반죽의 팽창력이 저하되는 문제점도 있다.However, there is a problem that yeast, which is a living yeast in frozen raw material, is affected by freezing and thus the yeast itself is killed or a reducing substance such as glutathione is eluted from the cells to weaken the dough and decrease the fermentation power. As a result, the degree of gas generation of the yeast and the gas holding capacity of the dough are lowered, and the fermentation time required after thawing is prolonged. As a result, the degree of expansion of the product is insufficient and the foam film of the product is formed thick, . Further, there is also a problem that as the ice crystals formed on the frozen dough grow in the freeze storage, the gluten gets frozen and the carbon dioxide holding power and the expansion force of the dough are lowered.

이를 보다 구체적으로 살펴보면, 냉동생지의 상기와 같은 문제는 동결 보존 과정에 의해 반죽의 성상에 변화가 발생하기 때문으로, 이는 발효가 시작되면서 동시에 이스트 자체의 생리적 변화에 따라 출아 증식 상태 진행됨에 따라, 발효 대사물로서 알코올 축적물이 밀가루와 결합되기 때문이다. 또한, 얼음 결정체 형성으로 인해 글루텐의 3차원 망상구조가 파괴되며, 동결 변성으로 장애가 발생한 이스트로부터 침출되는 글루타치온이 글루텐 단백질에 영향을 미치기 때문이다.More specifically, the above-mentioned problem of the frozen dough is that frozen dough is changed by the cryopreservation process. As the fermentation starts and at the same time the frozen dough grows according to the physiological change of the yeast itself, This is because alcohol accumulation as a fermentation metabolism is combined with wheat flour. In addition, the formation of ice crystals destroys the three-dimensional network structure of gluten, and glutathione leached from the frost-damaged yeast affects the gluten protein.

따라서, 냉동생지를 이용해 양질의 제품을 생산하기 위해서는, 활성 물질인 이스트, 그리고 밀가루와 이스트로부터 생산되는 다양한 효소들이 오븐에 의해 불활성화되는 시점까지 생존해 있어야 한다. 이와 관련하여, 종래 메틸셀룰로오즈 등을 이용하여 반죽 강도, 용적, 질감 개선된 냉동생지는 연구된 바 있으나(KR 10-2016-7017772), 아직 냉동생지의 장기간 냉동 보관에 있어 효모 생존율 향상, 제품의 품질 저하 억제를 통한 유통기한 증진에 관한 연구는 미진한 상황이다.Therefore, in order to produce high-quality products using frozen dough, yeast, which is an active substance, and various enzymes produced from wheat flour and yeast must survive until they are inactivated by an oven. In this regard, frozen dough having improved dough strength, volume and texture has been studied using methyl cellulose (KR 10-2016-7017772). However, it has not yet been found that the frozen dough can be frozen for a long time, There is little research on the improvement of shelf life through suppression of quality deterioration.

본 발명자들은 냉동생지에 당원으로서 알룰로스를 일정량 첨가함으로써 냉동생지의 보관 중 효모 보존성을 증진시키고, 이에 따라 보관기간에 따른 체적 감소 억제, 경화 억제 등의 효과를 나타내어, 상기와 같은 문제점을 해결할 수 있음을 확인함으로써 본 출원을 완성하였다.The present inventors have found that by adding a certain amount of alulose as a sugar source to the frozen dough, the yeast storage stability during storage of the frozen dough can be improved and the effect of suppressing the volume reduction and the curing of the frozen dough can be suppressed. The present application has been completed.

본 출원의 하나의 목적은, 알룰로스, 밀가루 및 효모를 포함하는 냉동생지 조성물을 제공하는 것이다.One object of the present application is to provide a frozen edible composition comprising alulose, wheat flour and yeast.

본 출원의 또 다른 하나의 목적은, 상기 냉동생지로 제조된 빵류를 제공하는 것이다.Another object of the present application is to provide a bread made of the frozen raw material.

본 출원의 또 다른 하나의 목적은, 냉동생지의 효모 보존성 개선 방법을 제공하는 것이다.It is another object of the present application to provide a method for improving yeast preservability of frozen dough.

본 출원의 또 다른 하나의 목적은, 냉동생지의 경화 억제 방법을 제공하는 것이다.It is still another object of the present invention to provide a method of inhibiting curing of frozen dough.

본 출원의 냉동생지는 효모의 보존성이 증진되어, 그에 따라 냉동 보관에 의한 체적 감소, 제품의 경화를 억제하며, 결과적으로 유통기한이 증진된 효과를 갖는다.The frozen raw material of the present application has an effect of improving the preservability of yeast, thereby suppressing volume reduction due to freezing storage and hardening of the product, and consequently increasing shelf life.

도 1은 120일 동안 저장한 냉동생지를 이용하여 제조한 완제품의 부피를 나타낸다. 비교예 1은 알룰로스를 함유하지 않은 냉동생지, 실험예 1은 알룰로스를 20% 함유한 냉동생지, 실험예 2는알룰로스를 40% 함유한 냉동생지, 실험예 3은 알룰로스를 60% 함유한 냉동생지, 실험예 4는 알룰로스를 80% 함유한 냉동생지, 실험예 5는 알룰로스를 100% 함유한 냉동생지, 비교예 2는 알룰로스를 함유하지 않은 냉동되지 않은 생지이다.Figure 1 shows the volume of the finished product prepared using frozen dough stored for 120 days. Comparative Example 1 was a frozen dough containing no alulose, Experiment 1 was a frozen dough containing 20% of alulose, Experiment 2 was a frozen dough containing 40% of alulose, Experiment 3 was 60% Experimental Example 4 is a frozen dough containing 80% of alulose, Experiment 5 is a frozen dough containing 100% of alulose, and Comparative Example 2 is a non-frozen dough containing no alulose.

이를 구체적으로 설명하면 다음과 같다. 한편, 본 출원에서 개시된 각각의 설명 및 실시형태는 각각의 다른 설명 및 실시 형태에도 적용될 수 있다. 즉, 본 출원에서 개시된 다양한 요소들의 모든 조합이 본 출원의 범주에 속한다. 또한, 하기 기술된 구체적인 서술에 의하여 본 출원의 범주가 제한된다고 볼 수 없다.This will be described in detail as follows. On the other hand, each description and embodiment disclosed in the present application can be applied to each other description and embodiment. That is, all combinations of the various elements disclosed in this application fall within the scope of the present application. Further, the scope of the present application is not limited by the specific description described below.

상기 목적을 달성하기 위한 본 출원의 하나의 양태는 알룰로스, 밀가루 및 효모를 포함하는 냉동생지 조성물을 제공한다.One aspect of the present application to accomplish the above object provides a frozen edible composition comprising alulose, wheat flour and yeast.

본 출원에서 알룰로스는 화학식 C6H12O6, 분자량 180.16을 갖는 당의 한 종류로, 무화과, 포도 등에 소량 존재하는 것으로 알려져 있으며, 사이코스(psicose)로도 불린다. 상기 알룰로스는 D-알룰로스 및 L-알룰로스를 모두 포함하는 개념이며, 시판 중인 알룰로스를 구입하여 사용하거나 화학적 또는 미생물학적 방법으로 제조하여 사용할 수 있다.In the present application, alulose is a type of sugar having the formula C 6 H 12 O 6 , molecular weight of 180.16, which is known to exist in small quantities in figs, grapes and the like, and is also called psicose. The above-mentioned aluloses include both D-aluloses and L-aluloses, and commercially available aluloses may be purchased and used, or they may be prepared by chemical or microbiological methods.

또한 상기 알룰로스는 액상 또는 분말 및 결정의 형태일 수 있으며, 액상인 경우 전체 100 중량부 기준으로 고형분이 65 내지 80 중량부, 65 내지 78 중량부, 68 내지 78 중량부, 68 내지 75 중량부, 68 내지 73 중량부, 또는 70 내지 72 중량부 일 수 있으며, 이를 다른 원료와 혼합하여 희석 또는 농축된 형태로 사용될 수 있다. 또한 고형분 100 중량부 기준으로 순수한 알룰로스의 순도는 85 내지 99.5 중량부, 85 내지 98 중량부, 90 내지 98 중량부, 93 내지 98 중량부, 또는 95 내지 98 중량부일 수 있다. 상기 알룰로스가 분말 및 결정의 형태인 경우 전체 100 중량부 기준으로 순수한 알룰로스의 순도는 90 중량부 이상, 95 중량부 이상, 98 중량부 이상일 수 있으며, 이를 다른 원료와 혼합하여 희석된 형태로 사용될 수 있다.The allylose may be in the form of a liquid, a powder or a crystal, and in the case of a liquid phase, the solid content is 65 to 80 parts by weight, 65 to 78 parts by weight, 68 to 78 parts by weight, 68 to 75 parts by weight, , 68 to 73 parts by weight, or 70 to 72 parts by weight, which may be mixed with other raw materials and used in a diluted or concentrated form. The purity of the pure alu- lose may be 85 to 99.5 parts by weight, 85 to 98 parts by weight, 90 to 98 parts by weight, 93 to 98 parts by weight, or 95 to 98 parts by weight based on 100 parts by weight of the solid content. When the alulose is in the form of powder and crystal, the purity of the pure aluloside on the whole 100 parts by weight may be 90 parts by weight or more, 95 parts by weight or more and 98 parts by weight or more and may be mixed with other raw materials to form a diluted form Can be used.

상기 알룰로스는 냉동생지 조성물에 적정량 포함될 수 있으며, 구체적으로는 냉동생지 조성물 전체 100 중량부 기준으로 0.01 내지 20 중량부, 0.05 내지 15 중량부, 0.1 내지 10 중량부, 0.5 내지 8 중량부, 0.75 내지 5 중량부, 1 내지 5 중량부, 또는 1.5 내지 7.5로 포함되는 것일 수 있으나, 이에 제한되지 않는다.The alululose may be contained in an appropriate amount in the frozen dough composition, specifically, 0.01 to 20 parts by weight, 0.05 to 15 parts by weight, 0.1 to 10 parts by weight, 0.5 to 8 parts by weight, 0.75 to 0.75 parts by weight, To 5 parts by weight, 1 to 5 parts by weight, or 1.5 to 7.5 parts by weight.

상기 밀가루 및 알룰로스는 1 : 0.02 내지 1 : 0.15, 1 : 0.01 내지 1 : 0.15, 1 : 0.02 내지 1 : 0.18, 1 : 0.01 내지 1 : 0.18, 1 : 0.05 내지 1 : 0.15, 1 : 0.04 내지 1 : 0.15, 1 : 0.05 내지 1 : 0.18, 1 : 0.04 내지 1 : 0.18, 1 : 0.02 내지 1 : 0.12, 1 : 0.01 내지 1 : 0.12, 1 : 0.02 내지 1 : 0.13, 1 : 0.01 내지 1 : 0.13, 1 : 0.05 내지 1 : 0.12, 1 : 0.04 내지 1 : 0.12, 1 : 0.05 내지 1 : 0.13, 또는 1 : 0.04 내지 1 : 0.13의 혼합비로 포함되는 것일 수 있으나, 이에 제한되는 것은 아니다.The flour and the alulose are mixed in a ratio of 1: 0.02 to 1: 0.15, 1: 0.01 to 1: 0.15, 1: 0.02 to 1: 0.18, 1: 0.01 to 1: 0.18, 1: 0.05 to 1: 0.15, 1: 0.15, 1: 0.05 to 1: 0.18, 1: 0.04 to 1: 0.18, 1: 0.02 to 1: 0.12, But the present invention is not limited thereto in terms of a mixing ratio of 1: 0.13, 1: 0.05 to 1: 0.12, 1: 0.04 to 1: 0.12, 1: 0.05 to 1: 0.13, or 1: 0.04 to 1: 0.13.

상기 효모 및 알룰로스는 1 : 0.5 내지 1 : 2.5, 1 : 0.3 내지 1 : 2.5, 1 : 0.5 내지 1 : 2.8, 1 : 0.3 내지 1 : 2.8, 1 : 1 내지 1 : 2.5, 1 : 0.7 내지 1 : 2.5, 1 : 1 내지 1 : 2.8, 1 : 0.7 내지 1 : 2.8, 1 : 0.5 내지 1 : 2, 1 : 0.3 내지 1 : 2, 1 : 0.5 내지 1 : 2.3, 1 : 0.3 내지 1 : 2.3, 1 : 1 내지 1 : 2, 1 : 0.7 내지 1 : 2, 1 : 1 내지 1 : 2.3, 또는 1 : 0.7 내지 1 : 2.3의 혼합비로 포함되는 것일 수 있으나, 이에 제한되는 것은 아니다.The yeast and the allylose may be used in a ratio of 1: 0.5 to 1: 2.5, 1: 0.3 to 1: 2.5, 1: 0.5 to 1: 2.8, 1: 0.3 to 1: 1: 0.3 to 1: 2, 1: 0.5 to 1: 2.3, 1: 0.3 to 1: But the present invention is not limited thereto and may be contained at a mixing ratio of 1: 2, 1: 1 to 1: 2, 1: 0.7 to 1: 2, 1:

본 출원의 알룰로스는 천연물로부터 직접 추출된 것일 수 있고, 화학적 합성, 또는 생물학적 방법으로 제조된 것일 수 있으나, 이에 한정되지 않는다.The aluloses of the present application may be those directly extracted from natural products, chemically synthesized, or produced by biological methods, but are not limited thereto.

본 출원에서 밀가루는 밀을 선별, 가수, 분쇄, 분리 등의 과정을 거쳐 얻은 분말을 의미하는 것으로, 상기 밀가루는 강력분, 중력분 또는 박력분일 수 있다. 구체적으로, 상기 밀가루는 강력분일 수 있으나, 이에 제한되지 않는다.In the present application, wheat flour refers to a powder obtained by a process such as screening, souring, grinding, and separation of wheat, and the flour may be a strong, a gravity or a pulverizer. Specifically, the flour may be strong, but is not limited thereto.

상기 밀가루는 냉동생지 조성물에 적정량 포함될 수 있으며, 구체적으로는 냉동생지 조성물 전체 100 중량부 기준으로, 40 내지 60 중량부, 40 내지 57 중량부, 44 내지 60 중량부, 40 내지 54 중량부, 47 내지 60 중량부, 40 내지 51 중량부, 50 내지 60 중량부, 44 내지 57 중량부, 44 내지 54 중량부, 47 내지 57 중량부, 44 내지 51 중량부, 50 내지 57 중량부, 47 내지 54 중량부, 47 내지 51 중량부, 50 내지 54 중량부, 또는 50 내지 51 중량부로 포함되는 것일 수 있으나, 이에 제한되지 않는다.40 to 57 parts by weight, 44 to 60 parts by weight, 40 to 54 parts by weight, 47 to 45 parts by weight, and 50 to 50 parts by weight, based on 100 parts by weight of the whole of the frozen raw material composition. 40 to 51 parts by weight, 50 to 60 parts by weight, 44 to 57 parts by weight, 44 to 54 parts by weight, 47 to 57 parts by weight, 44 to 51 parts by weight, 50 to 57 parts by weight, 47 to 54 parts by weight, 47 to 51 parts by weight, 50 to 54 parts by weight, or 50 to 51 parts by weight.

본 출원에서 효모는 시판되는 형태의 배양, 건조된 분말효모 또는 수분이 함유된 상태로 압착된 생효모일 수 있으며, 냉동생지 조성물 전체 100 중량부 기준으로 0.01 내지 10 중량부, 0.05 내지 10 중량부, 0.1 내지 7 중량부, 0.1 내지 5 중량부, 0.5 내지 5 중량부, 1 내지 5 중량부, 또는 3 중량부일 수 있으나, 이에 제한되는 것은 아니다.The yeast may be cultured in a commercially available form, dried powdery yeast, or live yeast squeezed in a state containing moisture. The yeast may be used in an amount of 0.01 to 10 parts by weight, 0.05 to 10 parts by weight , 0.1 to 7 parts by weight, 0.1 to 5 parts by weight, 0.5 to 5 parts by weight, 1 to 5 parts by weight, or 3 parts by weight, but is not limited thereto.

본 출원의 상기 냉동생지 조성물은 비타민 C 또는 아밀라아제를 추가로 포함하는 것일 수 있다. 상기 비타민 C 및 아밀라아제는 냉동생지 조성물에 복합물로 포함되거나, 각각 별도의 물질로 포함될 수 있다. The frozen dough composition of the present application may further comprise vitamin C or amylase. The vitamin C and the amylase may be contained in the freeze-dried composition as a composite, or may be separately contained.

상기 비타민 C 및 아밀라아제는 냉동생지 조성물 전체 100 중량부 기준으로 0.0001 내지 0.05 중량부, 0.0001 내지 0.04 중량부, 0.0001 내지 0.03 중량부, 0.0001 내지 0.02 중량부, 0.0001 내지 0.0125 중량부, 0.0025 내지 0.05 중량부, 0.0025 내지 0.04 중량부, 0.0025 내지 0.03 중량부, 0.0025 내지 0.02 중량부, 0.0025 내지 0.0125 중량부, 0.005 내지 0.0125 중량부, 0.0002 내지 0.05 중량부, 0.0002 내지 0.04 중량부, 0.0002 내지 0.03 중량부, 0.0002 내지 0.02 중량부, 0.0002 내지 0.0125 중량부, 0.00025 내지 0.05 중량부, 0.00025 내지 0.04 중량부, 0.00025 내지 0.03 중량부, 0.00025 내지 0.02 중량부, 0.00025 내지 0.0125 중량부, 0.0005 내지 0.05 중량부, 0.0005 내지 0.04 중량부, 0.0005 내지 0.03 중량부, 0.0005 내지 0.02 중량부, 또는 0.0005 내지 0.0125 중량부로 포함되는 것일 수 있으나, 이에 제한되지 않는다.The vitamin C and the amylase may be used in an amount of 0.0001 to 0.05 parts by weight, 0.0001 to 0.04 parts by weight, 0.0001 to 0.03 parts by weight, 0.0001 to 0.02 parts by weight, 0.0001 to 0.0125 parts by weight, 0.0025 to 0.05 parts by weight, 0.0025 to 0.04 parts by weight, 0.0025 to 0.03 parts by weight, 0.0025 to 0.02 parts by weight, 0.0025 to 0.0125 parts by weight, 0.005 to 0.0125 parts by weight, 0.0002 to 0.05 parts by weight, 0.0002 to 0.04 parts by weight, 0.0002 to 0.03 parts by weight, From 0.00025 to 0.012 parts by weight, from 0.00025 to 0.0125 parts by weight, from 0.00025 to 0.05 part by weight, from 0.00025 to 0.04 parts by weight, from 0.00025 to 0.03 parts by weight, from 0.00025 to 0.02 parts by weight, from 0.00025 to 0.0125 parts by weight, 0.0005 to 0.03 parts by weight, 0.0005 to 0.02 parts by weight, or 0.0005 to 0.0125 parts by weight, based on the total weight of the composition.

본 출원의 냉동생지 조성물은 설탕 또는 과당을 추가적으로 포함하거나, 또는 포함하지 않는 것일 수 있다. The frozen dough composition of the present application may be one that additionally or not contain sugar or fructose.

본 출원의 냉동생지 조성물은 알룰로스 이외에도 감미료 1종 이상을 추가적으로 포함할 수 있다. 상기 감미료는 공지된 감미료(예컨대, 단당류, 이당류, 올리고당류, 당알코올 및 고감미료)를 포함하나, 이에 제한되지 않는다. 구체적으로, 상기 단당류는 예를 들어 아라비노스, 자일로스, 과당, 타가토스, 알로스 또는 갈락토스일 수 있고, 상기 이당류는 두 단당이 결합한 당으로, 예를 들어 유당, 맥아당, 트레할로스, 투라노스 또는 셀로비오스일 수 있다. 상기 올리고당류는 단당이 3분자 이상 결합된 당으로, 예를 들어 프락토올리고당, 이소말토올리고당, 자일로올리고당, 겐티오올리고당, 말토올리고당 또는 갈락토올리고당일 수 있다. 상기 당알코올은 당류의 카보닐기를 환원하여 생긴 물질로, 예를 들어 에리스리톨, 자일리톨, 아라비톨, 만니톨, 소르비톨, 말티톨 또는 락티톨일 수 있다. 상기 고감미료는 설탕에 비해 10배 이상의 단맛을 가지는 물질로, 예를 들어 아스파탐, 아세설팜 K, 레바우디오사이드 A 또는 수크랄로스일 수 있으나, 이에 제한되지 않는다.The frozen dough composition of the present application may further comprise at least one sweetener in addition to alulose. Such sweeteners include, but are not limited to, known sweeteners (e.g., monosaccharides, disaccharides, oligosaccharides, sugar alcohols and high sweeteners). Specifically, the monosaccharide may be, for example, arabinose, xylose, fructose, tagatose, aloose, or galactose, and the disaccharide is a sugar in which two monosaccharides are bonded to each other, such as lactose, maltose, trehalose, Cellobiose. The oligosaccharide may be a sugar having three or more monosaccharides bound thereto, for example, fructo-oligosaccharide, isomaltooligosaccharide, xylooligosaccharide, gentio oligosaccharide, maltooligosaccharide or galacto-oligosaccharide. The sugar alcohol is a substance formed by reducing a carbonyl group of a saccharide, and may be, for example, erythritol, xylitol, arabitol, mannitol, sorbitol, maltitol or lactitol. The high-sweetening agent may be a substance having a sweetness ten times or more higher than that of sugar, such as, but not limited to, aspartame, acesulfame K, rebaudioside A or sucralose.

본 출원의 냉동생지 조성물이 설탕을 추가적으로 포함하는 경우, 설탕 및 알룰로스는 냉동생지 조성물 전체 100 중량부 기준으로 0.01 내지 20 중량부, 0.05 내지 15 중량부, 0.1 내지 15 중량부, 0.1 내지 10 중량부, 0.5 내지 8 중량부, 또는 1.5 내지 7.5로 포함되는 것일 수 있으나, 이에 제한되지 않는다.When the frozen edible composition of the present invention further comprises sugar, the sugar and the allyl are contained in an amount of 0.01 to 20 parts by weight, 0.05 to 15 parts by weight, 0.1 to 15 parts by weight, 0.1 to 10 parts by weight, 0.5 to 8 parts by weight, or 1.5 to 7.5 parts by weight, but not limited thereto.

본 출원의 냉동생지 조성물이 설탕을 추가적으로 포함하는 경우, 상기 설탕 및 알룰로스는 1 : 20 내지 1 : 0.01, 1 : 10 내지 1 : 0.1, 1 : 5 내지 1: 0.2, 1 : 5 내지 1: 0.2, 또는 1: 4 내지 1 : 0.25의 혼합비로 포함되는 것일 수 있으나, 이에 제한되는 것은 아니다.When the frozen edible composition of the present application further comprises sugar, the sugar and the allylose are mixed in a ratio of 1:20 to 1: 0.01, 1:10 to 1: 0.1, 1: 5 to 1: 0.2, 1: 5 to 1: 0.2, or 1: 4 to 1: 0.25, but the present invention is not limited thereto.

본 출원의 냉동생지 조성물은 설탕을 포함하지 않은 것일 수 있다. The frozen dough composition of the present application may not contain sugar.

본 출원의 냉동생지는 당류로서 알룰로스 단독, 또는 설탕 및 알룰로스가 혼합된 경우 모두에서 냉동생지의 물성 특성이 향상되고, 현저히 향상된 효모 생존율을 나타낸다. The frozen raw material of the present application exhibits significantly improved yeast survival rate and improved physical properties of the frozen raw material both in the case of sugar, alulose alone or in the case of mixing sugar and alulose.

본 출원에서 효모 생존율이란 냉동생지 제조 시점으로부터 저장 기간이 경과함에 따른 잔존 균체집락 수의 비율, 즉 초기 균체집락 수 대비 저장 기간 경과 후 생존한 균체집락 수의 비율을 의미한다. 상기 균체집락 수에 희석배수를 곱하여 산출한 시료 g당 CFU(colony forming unit)를 이용한 수학식 1을 통해 계산할 수 있다.The yeast survival rate in the present application means the ratio of the number of remaining cell masses after the storage period has elapsed from the time of manufacturing the frozen raw material, that is, the ratio of the number of living cell colonies after the storage period to the initial number of cell aggregates. (1) using CFU (colony forming unit) per gram of the sample, which is calculated by multiplying the number of bacterial colonies by the dilution factor.

Figure PCTKR2018013128-appb-M000001
Figure PCTKR2018013128-appb-M000001

본 출원의 냉동생지에서 효모 생존율은 24 내지 72%, 20 내지 72%, 24 내지 75%, 20 내지 75%, 63 내지 72%, 58 내지 72%, 63 내지 75%, 60 내지 72%, 60 내지 75%, 58 내지 75%, 50 내지 72%, 63 내지 78%, 또는 50 내지 78%일 수 있다.The yeast survival rate in the frozen raw material of the present application is 24-72%, 20-72%, 24-75%, 20-75%, 63-72%, 58-72%, 63-75% To 75%, 58 to 75%, 50 to 72%, 63 to 78%, or 50 to 78%.

본 출원의 냉동생지 조성물은 식용유지를 추가로 포함하는 것일 수 있다. 상기 식용유지에는 식물성 유지, 동물성 유지, 식용유지 가공품 등이 포함된다. 식물성 유지의 구체적인 예시로서 콩기름, 대두유, 옥수수기름, 채종유, 미강유, 참기름, 들기름, 홍화유, 해바라기유, 목화씨기름, 땅콩기름, 올리브유, 팜유류, 야자유, 혼합식용유 등을 들 수 있으며, 동물성 유지의 구체적인 예시로서 돼지기름(라드), 쇠기름(헷트), 양기름, 탈로우, 어유, 난황유, 유지방 등을 들 수 있고, 식용유지 가공품의 구체적인 예시로서 혼합식용유, 향미유, 가공유지, 쇼트닝, 마가린 등을 들 수 있으며, 구체적으로 본 출원에서 마가린의 형태로 사용되었으나 이에 제한되는 것은 아니며, 냉동생지 제조에 사용될 수 있는 식용유지는 제한 없이 포함될 수 있다.The frozen dough composition of the present application may further comprise an edible oil. The edible oil includes vegetable oil, animal oil, edible oil and the like. Specific examples of vegetable oils include soybean oil, soybean oil, corn oil, rapeseed oil, rice bran oil, sesame oil, perilla oil, safflower oil, sunflower oil, cottonseed oil, peanut oil, olive oil, palm oil, palm oil, Specific examples thereof include pig grease (rod), horse oil (hate), sheep oil, tallow, fish oil, egg yolk oil and milk fat. Examples of the edible oils and fats include mixed edible oil, flavored oil, And the like, and is specifically used in the form of margarine in the present application, but is not limited thereto, and the edible oil which can be used for the production of frozen dough can be included without limitation.

본 출원의 냉동생지 조성물은 상기 식용유지, 알룰로스, 과당, 또는 설탕 이외에도 계란, 분유, 유화제, 안정제, 산도 조정제, 정제염, 향료, 또는 물을 추가로 포함하는 것일 수 있다. 또한 본 출원의 냉동생지 조성물은 그 이외에도 냉동생지를 제조하는 데 일반적으로 사용되는 공지의 재료를 추가로 포함할 수 있다. The frozen dough composition of the present application may further comprise eggs, milk powder, an emulsifier, a stabilizer, an acidity adjusting agent, a refined salt, a flavoring, or water in addition to the edible oil, alululose, fructose or sugar. In addition, the frozen edible raw paper composition of the present application may further include known materials generally used for producing frozen edible raw materials.

상기 분유는 유성분을 제공하는 유제품 중의 하나로, 상기 분유에는 전지분유, 탈지분유, 혼합분유 등이 포함되며, 냉동생지 제조에 사용될 수 있는 유성분 제공 물질은 제한 없이 포함될 수 있다. The powdered milk is one of dairy products which provide a milk ingredient, and the powdered milk includes whole milk powder, skim milk powder, mixed milk powder and the like, and the ingredients for providing milk ingredients that can be used in the production of frozen dough can be included without limitation.

본 출원의 냉동생지 조성물은 효모의 보존성, 생존력이 증가되어, 효모 보존성이 개선된 것일 수 있다. 본 출원에서 '효모 보존성'은 냉동생지 내에 함유된 효모의 개체수가 급속 동결 및 냉동 저장 과정에서 보존되는 정도를 의미한다.The frozen dough composition of the present application may be one in which the preservability and viability of the yeast are increased and the yeast storage stability is improved. The term "yeast preservation" in this application means the degree to which the number of yeasts contained in the frozen biomass is preserved during rapid freezing and cryopreservation.

냉동생지는 저온 조건에서 보관되기 때문에, 냉동생지 내의 효모는 동결장애에 의해 사멸하여 개체수가 감소되거나 글루타치온과 같은 환원성 물질을 균체에서 용출하여 반죽을 연약화시키고 발효력을 감소시키는 문제가 있다. 이에 본 출원의 냉동생지 조성물은 알룰로스, 비타민 C 및 아밀라아제를 함유함으로써 동결장애에 의한 효모 생존율 감소가 억제되어, 우수한 효모 보존성을 나타낸다.Since the frozen biomass is stored at low temperature, the yeast in the frozen biomass is killed by the frozen disorder and the population is reduced or the reducing material such as glutathione is eluted from the bacteria to weaken the dough and decrease the fermentation power. Thus, the frozen edible tissue composition of the present application contains alulose, vitamin C and amylase, thereby suppressing the decrease in yeast survival rate due to freezing disorder and exhibiting excellent yeast preservability.

상기 목적을 달성하기 위한 본 출원의 또 다른 하나의 양태는 상기 냉동생지로 제조된 빵류, 또는 빵을 제공한다.According to another aspect of the present invention, there is provided a bread or bread made from the frozen raw material.

본 출원에서 '빵류'는 밀가루를 주원료로 하여 물을 섞어 발효시킨 뒤 오븐 등에서 구워낸 제품을 의미하며, 해당 기술분야에서 빵류로 분류되는 한 제한 없이 포함할 수 있다.The term "bread" in the present application means a product which is prepared by mixing water with flour as a main raw material and baking it in an oven after being fermented, and may be included without limitation as far as it is classified as bread in the technical field.

본 출원의 냉동생지로 제조된 상기 빵류는 기공 함량이 개선된 것일 수 있다. 냉동생지는 저온 조건에서 보관됨에 따라, 효모의 냉동장애에 의해 가스 발생 정도 및 반죽의 가스 보유량이 저하되고, 이로 인해 제품 팽창 정도가 부족하다는 문제가 있다.The bread prepared from the frozen raw material of the present application may have an improved pore content. As the frozen dough is stored at a low temperature, the degree of gas generation and the gas holding amount of the dough are lowered due to the frost trouble of the yeast, which results in a problem that the degree of product expansion is insufficient.

본 출원의 냉동생지로 제조된 빵류는 종래의 냉동생지와는 달리 효모가 냉동 장애를 받는 것을 억제하여 효모의 보존성을 증가시켜, 반죽의 가스 보유량 및 팽창 정도가 개선된 것일 수 있다. Unlike the conventional frozen dough, the pastry made from the frozen dough of the present application may inhibit the frost from being affected by the yeast to improve the preservability of the yeast and improve the gas holding amount and expansion degree of the dough.

본 출원의 냉동생지로 제조된 상기 빵류는 물성 특성이 개선된 것일 수 있다. The bread made from the frozen raw paper of the present application may have improved physical properties.

본 출원의 냉동생지로 제조된 상기 빵류는 보관기간에 따른 체적(부피) 감소가 억제된 것일 수 있다. 본 출원에서는 냉동생지를 이용해 제조한 완제품의 체적이 감소하였는지 여부를 확인하기 위하여, 각 실험군 별로 체적 변화를 측정하는 실험을 진행하였다. The bread made from the frozen raw material of the present application may have a reduced volume (volume) in accordance with the storage period. In this application, in order to check whether the volume of the finished product manufactured using the frozen raw paper has decreased, an experiment for measuring the volume change by each experimental group was conducted.

본 출원의 냉동생지를 이용하여 제조한 완제품의 체적 변화율은 -54.7% 내지 8.84%, -57% 내지 8.84%, -54.7% 내지 10%, -57% 내지 10%, -10.5% 내지 8.84%, -12% 내지 8.84%, -10.5% 내지 10%, 또는 -12% 내지 10% 일 수 있다.The volume change rate of the finished product manufactured using the frozen raw paper of the present application is -54.7% to 8.84%, -57% to 8.84%, -54.7% to 10%, -57% to 10%, -10.5% to 8.84% -12% to 8.84%, -10.5% to 10%, or -12% to 10%.

본 출원의 상기 빵류는 1 내지 5,000g, 1 내지 4,500g, 1 내지 4,000g, 1 내지 3,500g, 1 내지 3,000g, 1 내지 2,500g, 1 내지 2,000g, 30 내지 5,000g, 30 내지 4,500g, 30 내지 4,000g, 30 내지 3,500g, 30 내지 3,000g, 30 내지 2,500g, 30 내지 2,000g, 50 내지 5,000g, 50 내지 4,500g, 50 내지 4,000g, 50 내지 3,500g, 50 내지 3,000g, 50 내지 2,500g, 50 내지 2,000g, 100 내지 5,000g, 100 내지 4,500g, 100 내지 4,000g, 100 내지 3,500g, 100 내지 3,000g, 100 내지 2,500g, 100 내지 2,000g, 200 내지 5,000g, 200 내지 4,500g, 200 내지 4,000g, 200 내지 3,500g, 200 내지 3,000g, 200 내지 2,500g, 200 내지 2,000g, 300 내지 5,000g, 300 내지 4,500g, 300 내지 4,000g, 300 내지 3,500g, 300 내지 3,000g, 300 내지 2,500g, 300 내지 2,000g, 300 내지 1,500g, 300 내지 1,000g, 500 내지 5,000g, 500 내지 4,000g, 500 내지 3,500g, 500 내지 3,000g, 500 내지 2,500g, 500 내지 2,000g, 500 내지 1,500g, 500 내지 1,000g, 1,000 내지 3,000g, 1,000 내지 2,000g 정도의 경도를 갖는 것일 수 있다. 경도는 물질의 단단한 정도를 의미하며, 냉동생지로 제조한 빵류에 있어서는 경도가 높을 수록 제품이 단단하게 굳어져 기호성 측면에서 불리하며, 반대로 경도가 낮을 경우 부드러운 식감을 낼 수 있다. 1 to 5,000 g, 1 to 4,500 g, 1 to 4,000 g, 1 to 3,500 g, 1 to 3,000 g, 1 to 2,500 g, 1 to 2,000 g, 30 to 5,000 g, 30 to 4,500 g 30 to 4,000 g, 30 to 3,500 g, 30 to 3,000 g, 30 to 2,500 g, 30 to 2,000 g, 50 to 5,000 g, 50 to 4,500 g, 50 to 4,000 g, 50 to 3,500 g, 50 to 3,000 g 100 to 2,500 g, 100 to 2,000 g, 100 to 5,000 g, 100 to 4,500 g, 100 to 4,000 g, 100 to 3,500 g, 100 to 3,000 g, 100 to 2,500 g, 200 to 4,500 g, 200 to 4,000 g, 200 to 3,500 g, 200 to 3,000 g, 200 to 2,500 g, 200 to 2,000 g, 300 to 5,000 g, 300 to 4,500 g, 300 to 4,000 g, 300 to 3,000 g, 300 to 2,500 g, 300 to 2,000 g, 300 to 1,500 g, 300 to 1,000 g, 500 to 5,000 g, 500 to 4,000 g, 500 to 3,500 g, 500 to 3,000 g, , 500 to 2,000 g, 500 to 1,500 g, 500 to 1,000 g, 3,000 g, and a hardness of 1,000 to 2,000 g. Hardness means the degree of hardness of the material. In the case of breads made from frozen dough, the higher the hardness, the harder the product becomes, which is disadvantageous in terms of palatability. On the contrary, when the hardness is low, a soft texture can be obtained.

본 출원의 상기 빵류는 10 내지 99%, 10 내지 95%, 10 내지 90%, 10 내지 85%, 10 내지 80%, 10 내지 75%, 10 내지 70%, 20 내지 99%, 20 내지 95%, 20 내지 90%, 20 내지 85%, 20 내지 80%, 20 내지 75%, 20 내지 70%, 30 내지 99%, 30 내지 95%, 30 내지 90%, 30 내지 85%, 30 내지 80%, 30 내지 75%, 30 내지 70%, 40 내지 90%, 40 내지 85%, 40 내지 80%, 40 내지 75%, 40 내지 70%, 50 내지 90%, 50 내지 85%, 50 내지 80%, 50 내지 75%, 50 내지 70%, 45 내지 95%, 60 내지 95%, 75 내지 95% 정도의 탄성을 갖는 것일 수 있다. 탄성은 물체에 가해진 외력을 제거하였을 때 원래의 형태로 되돌아가는 성질을 의미하며, 냉동생지로 제조한 빵류에 있어서는 탄성이 높을 수록 말랑하고 쫀득한 식감을 낼 수 있다.10 to 95%, 10 to 90%, 10 to 85%, 10 to 80%, 10 to 75%, 10 to 70%, 20 to 99%, 20 to 95% , 20-90%, 20-85%, 20-80%, 20-75%, 20-70%, 30-99%, 30-95%, 30-90%, 30-85%, 30-80% , 40 to 70%, 50 to 90%, 50 to 85%, 50 to 80%, 30 to 75%, 30 to 70%, 40 to 90% , 50 to 75%, 50 to 70%, 45 to 95%, 60 to 95%, and 75 to 95%. The elasticity means a property of returning to the original shape when the external force applied to the object is removed. In the case of the bread made of frozen raw material, the higher the elasticity, the more smooth and crispy texture can be obtained.

상기 목적을 달성하기 위한 본 출원의 또 다른 하나의 양태는 알룰로스, 밀가루 및 효모를 혼합하는 단계, 혼합된 생지를 냉동하는 단계를 포함하는, 냉동생지의 효모 보존성 개선 방법을 제공한다.Another aspect of the present application for achieving the above object is to provide a method for improving the yeast preservability of frozen dough, comprising mixing alulose, wheat flour and yeast, and freezing the mixed dough.

상기 목적을 달성하기 위한 본 출원의 또 다른 하나의 양태는 알룰로스, 밀가루 및 효모를 혼합하는 단계, 혼합된 생지를 냉동하는 단계를 포함하는, 냉동생지의 경화 억제 방법을 제공한다.Another aspect of the present application for achieving the above object is to provide a method for inhibiting curing of frozen dough, comprising mixing alulose, wheat flour and yeast, and freezing the mixed dough.

상기 밀가루, 효모, 알룰로스, 비타민 C, 아밀라아제, 냉동생지, 효모 보존성에 대해서는 상기 설명한 바와 같다.The flour, yeast, alulose, vitamin C, amylase, frozen dough, and yeast preservability are as described above.

상기 방법은 비타민 C 및 아밀라아제를 혼합하는 단계를 추가로 포함할 수 있다.The method may further comprise mixing vitamin C and amylase.

본 출원에서 '경화'는 물건의 조직이 단단하게 굳어지는 것으로, 냉동생지에 있어서는 냉해동 과정에서 생지의 표면 또는 내부가 단단하게 경화되어 갈라지는 노화 현상이 일어나는 것을 의미한다.In the present application, 'hardening' means that the texture of the product is hardened, and in the case of frozen dough, it means that the surface or interior of the dough is hardened and cracked in the process of cold-soldering and aging phenomenon occurs.

본 출원의 상기 방법은 냉동생지 제조 과정에 있어 알룰로스, 비타민 C 및 아밀라아제를 혼합하는 단계를 추가함으로써, 냉동생지의 냉동 보관 과정에서의 효모 보존성을 개선하고, 냉동생지의 경화 정도를 억제시킬 수 있다.The method of the present application improves the preservation of yeast in the freeze storage process of frozen dough by adding a step of mixing alulose, vitamin C and amylase in the process of manufacturing frozen dough, and can suppress the degree of curing of frozen dough have.

이하 본 출원을 실시예를 통하여 보다 상세하게 설명한다. 그러나 이들 실시예는 본 출원을 예시적으로 설명하기 위한 것으로 본 출원의 범위가 이들 실시예에 한정되는 것은 아니다. Hereinafter, the present application will be described in more detail by way of examples. However, these embodiments are for illustrative purposes only, and the scope of the present application is not limited to these embodiments.

실시예 1: 냉동생지의 제조 Example 1: Preparation of frozen dough

먼저, 다음과 같은 과정을 거쳐 표 1의 비교예 1 및 실험예 1 내지 5의 냉동생지를 제조하였다. 강력분, 효모, 설탕, 알룰로스, 아밀라아제 및 비타민 C 복합물, 소금, 분유, 계란, 물을 각각 표 1의 구성 (중량%)에 따라 믹싱기에 첨가하여 5 내지 7분 간 혼합한 후, 마지막으로 마가린을 투입하여 8 내지 10분 간 혼합하였다. 생지 품온 (제품 내부의 온도)은 17℃ 내지 20℃로 설정하였으며, 혼합이 완료된 완료된 생지는 상온에서 10분간 휴지(休止)를 두었다.First, the frozen dough of Comparative Example 1 and Experiments 1 to 5 of Table 1 was prepared through the following procedure. The mixture of high strength, yeast, sugar, alulose, amylase and vitamin C, salt, powdered milk, egg and water were added to the mixing machine according to the composition (% by weight) of Table 1 for 5 to 7 minutes, Were added and mixed for 8 to 10 minutes. The temperature of the product was set at 17 ° C to 20 ° C. After the completion of the mixing, the finished product was allowed to stand at rest for 10 minutes at room temperature.

휴지가 끝난 생지는 40g씩 분할하여 원형으로 둥글리기 한 후, 팬에 일정한 간격을 두고 마르지 않게 덮어 30 내지 45분간 급속 냉동(-25 내지 -40℃) 하였다. 급속 냉동한 생지는 일반 냉동(-10 내지 -20℃)으로 옮겨 30일, 60일, 또는 120일 동안 저장하였다.The ground paper after the stoppage was divided into 40 g portions, rounded in a circular shape, and then quickly frozen (-25 to -40 캜) for 30 to 45 minutes with a constant interval between the panes. Rapidly frozen raw materials were transferred to general freezing (-10 to -20 ° C) and stored for 30 days, 60 days, or 120 days.

system 강력분Strong 효모leaven 설탕Sugar 알룰로스Alulous 아밀라아제 및 비타민C 복합물Amylase and vitamin C complex 기타 원료Other raw materials 급수rating 비교예 1Comparative Example 1 100.0100.0 50.250.2 3.03.0 7.57.5 -- 0.010.01 16.6916.69 22.622.6 실험예 1Experimental Example 1 100.0100.0 50.250.2 3.03.0 6.06.0 1.51.5 0.010.01 16.6916.69 22.622.6 실험예 2Experimental Example 2 100.0100.0 50.250.2 3.03.0 4.54.5 3.03.0 0.010.01 16.6916.69 22.622.6 실험예 3Experimental Example 3 100.0100.0 50.250.2 3.03.0 3.03.0 4.54.5 0.010.01 16.6916.69 22.622.6 실험예 4Experimental Example 4 100.0100.0 50.250.2 3.03.0 1.51.5 6.06.0 0.010.01 16.6916.69 22.622.6 실험예 5Experimental Example 5 100.0100.0 50.250.2 3.03.0 -- 7.57.5 0.010.01 16.6916.69 22.622.6

기타원료: 소금, 분유, 마가린, 계란, 글리세린지방산에스테르, 탄산칼슘, 헤미셀룰라아제Other raw materials: salt, powdered milk, margarine, egg, glycerin fatty acid ester, calcium carbonate, hemicellulase

실시예 2: 냉동생지를 이용한 완제품 제조 Example 2: Preparation of articles using frozen dough

상기 실시예 1에서 제조한 냉동생지를 이용해 제품 (빵)을 제조하였다.A product (bread) was prepared using the frozen dough prepared in Example 1 above.

구체적으로, 일반 냉동에서 30일, 60일, 또는 120일 동안 보관한 냉동생지를 냉장에서 12시간 전후로 해동한 후, 상온에서 30분간 휴지를 두었다. 휴지된 생지는 둥글리기를 하여 가스를 빼주고, 팬에 일정 간격을 두고 50분간 동일하게 2차 발효를 진행하였다. 이 때 발효조건은 37 내지 38℃, 습도 82 내지 85%로 설정하였다.Specifically, the frozen dough kept for 30 days, 60 days, or 120 days in general freezing was thawed at about 12 hours in the refrigerator, and then left at rest for 30 minutes at room temperature. The resting pellets were rounded off and the gas was drained and the secondary fermentation was carried out in the same manner for 50 minutes at regular intervals in the pan. At this time, the fermentation conditions were set at 37 to 38 DEG C and a humidity of 82 to 85%.

상기 발효가 완료된 생지를 상단 210℃, 하단 180℃로 예열된 오븐에서 소성(11분)하여 완제품으로 제조하였다.The fermented raw material was fired (11 minutes) in an oven preheated at an upper temperature of 210 ° C and a lower temperature of 180 ° C to prepare a finished product.

실시예 3: 해동되지 않은 냉동생지의 효모 생존율 비교Example 3: Comparison of yeast survival rate of frozen ungrafted frozen dough

30일, 60일, 또는 120일의 저장기간 도과 후, 각 냉동생지 실험군 별로 효모의 생존율을 측정하여 비교하였다. 이 때, 냉동생지는 해동하지 않고 측정에 사용하였다.After 30 days, 60 days, or 120 days storage period, survival rate of yeast was measured and compared with each frozen dough. At this time, the frozen raw paper was used for measurement without thawing.

구체적으로 효모의 생존율은 제조 직후부터 30일, 60일, 또는 120일 저장 후의 각 냉동생지를 꺼내어 단일 균체집락을 측정하고 이를 제조직후에 측정된 단일 균체집락과 비교하여 보관 중 잔존된 효모의 단일 균체집락을 비율로 나타내었다. 단일 균체집락의 계측은 통상의 미생물 시험법을 사용하였다. 구체적으로 상기 저장기간별 냉동생지 시료 각 20g을 0.9% 멸균생리식염수 180mL에 혼합하였으며, 균질기(STOMACHER, 비앤에프코리아)를 이용해 충분히 분쇄 및 균질하였으며, 균질된 혼합액을 다시 0.9% 멸균생리식염수에 10배 희석법으로 단계적으로 희석하여 희석 시료를 제조하였다. 이후, 페트리 접시에 상기 희석 시료 1mL를 담은 후 아가가 추가된 통상의 배양배지(Potato Dextrose medium)를 25mL 첨가하여 잘 혼합 후 굳히는 푸어링(pouring) 방식으로 접종하였다. 접종된 배지는 25℃에서 보관 후 균체집락을 계측하였으며, 측정된 균체집락수에 희석배수를 곱하여 시료 g당 CFU(colony forming unit)를 산출하였다. 그 결과는 하기 표 2에 나타내었다.Specifically, the survival rate of yeast was measured by taking each frozen dough from 30 days, 60 days, or 120 days storage immediately after the preparation, measuring single colonies of colonies, comparing the single colonies of colonies measured immediately after production, Fungal colonization was expressed as a ratio. For the measurement of single colonies, conventional microorganism test methods were used. Specifically, 20 g of each of the frozen dough samples per storage period was mixed with 180 mL of 0.9% sterilized physiological saline. The homogenized mixture was thoroughly pulverized and homogenized using a homogenizer (STOMACHER, B & F Korea) Diluted samples were prepared by dilution stepwise. Thereafter, 1 mL of the above diluted sample was placed in a Petri dish, and then 25 mL of a normal culture medium supplemented with agar (Potato Dextrose medium) was added, and the mixture was inoculated in a pouring manner. The inoculated culture medium was stored at 25 ° C, and the colonies were counted. CFU (colony forming unit) per g of the sample was calculated by multiplying the measured colonies by the dilution factor. The results are shown in Table 2 below.

  비교예 1Comparative Example 1 실험예1Experimental Example 1 실험예2Experimental Example 2 실험예3Experimental Example 3 실험예4Experimental Example 4 실험예5Experimental Example 5 [Initial][Initial] 1.3.E+081.3.E + 08 9.5.E+079.5.E + 07 9.6.E+079.6.E + 07 1.1.E+081.1.E + 08 1.2.E+081.2.E + 08 9.5.E+079.5.E + 07 [120일차][Day 120] 1.5.E+071.5.E + 07 2.3.E+072.3.E + 07 6.0.E+076.0.E + 07 7.3.E+077.3.E + 07 7.0.E+077.0.E + 07 6.8.E+076.8.E + 07 잔존률Remaining rate 12%12% 24%24% 63%63% 65%65% 61%61% 72%72%

그 결과, 알룰로스의 대체비율이 증가할수록 효모의 생존 개체수가 증가되는 경향이 확인되었으며, 특히 알룰로스가 3 중량부 이상 포함된 실험예 2 내지 5의 냉동생지에서 비교예와 비교하여 유의적으로 높은 효모의 생존율이 확인되었다. 또한 별개로 비교예 및 실험예 1 내지 5의 냉동생지에 사용된 것과 동일한 양의 생효모를 바로 현탁하여 측정하였을 때, 상기 실험예 2 내지 5의 효모 생존 개체수와 동등한 수준으로 확인되었으며, 이를 통해 냉동생지에 알룰로스가 사용되는 경우 가공 및 냉동 보관 중 효모의 냉해를 현저히 저감한다는 것을 확인할 수 있었다 (표 2).As a result, it was confirmed that as the substitution ratio of alulose increased, the survival population of yeast tended to increase. Especially, in the frozen dough of Experimental Examples 2 to 5 containing 3 parts by weight or more of alulose, The survival rate of high yeast was confirmed. Separately, when the same amount of live yeast as used in the frozen dough of Comparative Examples and Experimental Examples 1 to 5 was immediately suspended and measured, it was confirmed to be equivalent to the number of yeast survival populations of Experimental Examples 2 to 5, When alululose was used in frozen dough, it was confirmed that the cold weather of the yeast was remarkably reduced during processing and cryopreservation (Table 2).

즉, 설탕 대신 알룰로스의 함량이 높아질수록 냉동생지에 포함된 효모의 생존율이 현저히 향상되었으며, 이로써 발효 시간, 상품성, 품질 측면에서 더욱 우수한 냉동생지로 제공될 수 있음을 알 수 있다. That is, as the content of alululose is increased in place of sugar, the survival rate of the yeast contained in the frozen dough is remarkably improved, and as a result, frozen dough can be provided in terms of fermentation time, merchandise quality and quality.

실시예 4: 냉동생지로 제조한 완제품의 외관 비교 분석Example 4: Comparative analysis of the appearance of the finished product made from frozen dough

4-1. 완제품의 부피 측정4-1. Volume measurement of finished product

냉동생지를 이용해 제조한 완제품의 부피(체적)가 감소하였는지 여부를 확인하기 위하여, 각 실험군 별로 부피 변화를 측정하였다. 구체적으로 Volume scanner(PERTEN, BVM6640)를 이용해 측정하였으며, 120일의 저장기간에 따른 냉동생지 실험군 별로 약 210℃ 오븐에서 소성 및 냉각 후 부피를 측정하였다. 그 결과를 도 1에 나타내었다.To determine whether the volume (volume) of the finished product made using frozen dough was reduced, the volume change was measured for each experimental group. Specifically, the volume was measured using a volume scanner (PERTEN, BVM6640), and the volume was measured after cooling and cooling in an oven at 210 ° C. for 120 days of storage time. The results are shown in Fig.

그 결과, 설탕이 전혀 첨가되지 않은 실험예 5의 체적이 전반적으로 작은 것으로 확인되었으며, 이는 발효성 당질이 현저히 부족한 것에 기인한 것으로 판단되었다. 반면 알룰로스 및 설탕이 일정량 혼합 사용된 실험예 1 내지 4의 경우 비교예와 비교하여 동등한 수준의 체적이 확인되었으며, 보관 기간 중 부피 변화에도 유의적 차이가 확인되지 않았다 (도 1).As a result, it was confirmed that the volume of Experimental Example 5 in which sugar was not added at all was small overall, and it was judged that this was due to a considerable lack of fermentable saccharide. On the other hand, in Experimental Examples 1 to 4 in which alululose and sugar were mixed in a certain amount, the volume was found to be equivalent to that of Comparative Example, and no significant difference was observed in the volume change during the storage period (FIG.

따라서, 알룰로스 및 설탕이 혼합된 냉동생지의 경우 완제품 자체의 체적은 상품성 측면에서 별다른 문제가 없는 것으로 확인되었다.Therefore, in the case of frozen dough mixed with alulose and sugar, the volume of the finished product itself was found to have no problem in terms of merchantability.

4-2. 완제품의 기공 측정4-2. Pore measurement of finished product

냉동생지 내 가스 보유력을 비교하기 위하여, 냉동생지를 이용해 제조한 완제품의 기공을 측정하였다. 구체적으로, 완제품 시료를 세로로 절반 (1/2) 절단하여 육안으로 기공의 양을 측정하였다.In order to compare the gas holding capacity of the frozen raw material, the porosity of the finished product manufactured using frozen raw material was measured. Specifically, the sample of the finished product was cut in half (1/2) in the longitudinal direction, and the amount of pores was visually measured.

그 결과, 알룰로스가 일정량 첨가된 실험예 1 내지 5는 모두 비교예와 비교하여 형성된 기공의 형태가 양호하고, 전반적으로 형성된 양이 동등 이상인 것으로 판단되었다.As a result, in Experimental Examples 1 to 5 in which aluloses were added in a certain amount, all of the pores formed in comparison with the Comparative Example were in good condition, and it was judged that the overall formed amount was equal or more.

따라서, 알룰로스가 일정량 함유된 냉동생지의 가스 보유력 및 반죽의 팽창력이 향상되어 동결 장애에 따른 문제점이 개선되고, 결과적으로 품질이 우수한 제품으로 제조될 수 있음을 알 수 있다.Therefore, it is found that the gas retention of the frozen dough containing a certain amount of alulose and the swelling force of the dough are improved, thereby improving the problems caused by the frost defect, and as a result, the product can be manufactured with excellent quality.

실시예 5: 냉동생지로 제조한 완제품의 물성 비교Example 5: Comparison of physical properties of finished products prepared from frozen dough

냉동생지를 이용해 제조한 완제품의 물성 변화를 확인하고자 하였다. 구체적으로, Texture analyzer(STABLE MICRO SYSTEMS, TAXT plus)를 이용해 저장기간에 따른 냉동생지 실험군 별로 상단 210℃, 하단 180℃로 예열된 오븐에서 소성(11분) 및 냉각 후, 물성 (경도, 탄성)을 측정하였다.The purpose of this study was to investigate the physical properties of the frozen edible jars. (11 min) and cooling (11 min) in an oven preheated at the upper 210 ° C and lower 180 ° C according to the storage period of the frozen dough experiment group using a texture analyzer (STABLE MICRO SYSTEMS, TAXT plus) Were measured.

그 결과, 알룰로스가 일정량 함유된 실험예 1 내지 5의 경우, 비교예와 비교하여 경도가 저감되고 탄성이 증가되는 경향을 나타내었으며, 이는 첨가된 알룰로스가 빵에 부드럽고 탄력있는 식감을 증진하였음을 나타낸다.As a result, in Examples 1 to 5, in which aluloses were contained in a certain amount, the hardness was lowered and the elasticity was increased as compared with the comparative example, and the added alululose improved the soft and elastic texture of the bread .

이상의 설명으로부터, 본 출원이 속하는 기술분야의 당업자는 본 출원이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 이와 관련하여, 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적인 것이 아닌 것으로 이해해야만 한다. 본 출원의 범위는 상기 상세한 설명보다는 후술하는 특허 청구범위의 의미 및 범위 그리고 그 등가 개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본 출원의 범위에 포함되는 것으로 해석되어야 한다.From the above description, it will be understood by those skilled in the art that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. In this regard, it should be understood that the embodiments described above are illustrative in all aspects and not restrictive. The scope of the present application is to be interpreted as being within the scope of the present application, all changes or modifications derived from the meaning and scope of the appended claims and from their equivalents rather than the detailed description.

Claims (13)

알룰로스, 밀가루 및 효모를 포함하는 냉동생지 조성물.Allylose, wheat flour and yeast. 제1항에 있어서, 상기 알룰로스는 냉동생지 조성물 전체 100 중량부 기준으로 0.1 내지 10 중량부로 포함되는 것인, 냉동생지 조성물.2. The frozen mortar composition according to claim 1, wherein the alulose is contained in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the whole of the frozen raw material composition. 제1항에 있어서, 설탕을 추가적으로 포함하고, 상기 설탕 및 알룰로스는 냉동생지 조성물 전체 100 중량부 기준으로 3 내지 50 중량부로 포함되며, 상기 설탕 및 알룰로스는 1 : 10 내지 1 : 0.1의 혼합비로 포함되는 것인, 냉동생지 조성물.The method of claim 1, further comprising a sugar, wherein the sugar and the allyl are included in an amount of 3 to 50 parts by weight based on 100 parts by weight of the whole of the frozen dough composition, and the sugar and the allylose are mixed at a mixing ratio of 1:10 to 1: ≪ / RTI > 제1항에 있어서, 상기 효모 및 알룰로스는 1 : 0.3 내지 1 : 2.8의 혼합비로 포함되는 것인, 냉동생지 조성물.2. The frozen edible raw material composition according to claim 1, wherein the yeast and the allylose are contained in a mixing ratio of 1: 0.3 to 1: 2.8. 제1항에 있어서, 상기 밀가루는 냉동생지 조성물 전체 100 중량부 기준으로 40 내지 60 중량부로 포함되는 것인, 냉동생지 조성물.2. The frozen mortar composition according to claim 1, wherein the flour is contained in an amount of 40 to 60 parts by weight based on 100 parts by weight of the whole of the frozen raw material composition. 제1항에 있어서, 상기 효모는 냉동생지 조성물 전체 100 중량부 기준으로 0.01 내지 10 중량부로 포함되는 것인, 냉동생지 조성물.2. The frozen edible raw material composition according to claim 1, wherein the yeast is contained in an amount of 0.01 to 10 parts by weight based on 100 parts by weight of the whole of the frozen raw material composition. 제1항에 있어서, 비타민 C, 아밀라아제, 또는 식용유지를 추가로 포함하는 것인, 냉동생지 조성물.The frozen edible composition of claim 1, further comprising vitamin C, amylase, or an edible oil. 제1항에 있어서, 상기 조성물은 알룰로스가 포함되지 않은 냉동생지 조성물에 비해 효모생존율이 증가된 것인, 냉동생지 조성물.The frozen edible composition of claim 1, wherein the composition has an increased yeast survival rate as compared to a frozen edible composition not comprising aluloses. 제1항 내지 제8항 중 어느 한 항의 냉동생지로 제조된 빵류.9. A bread made from frozen dough according to any one of claims 1 to 8. 제9항에 있어서, 상기 빵류는 냉동 보관에 따른 체적 감소가 억제되는 것인, 빵류[10] The method of claim 9, wherein the bread is reduced in volume by freezing storage, 제9항에 있어서, 상기 빵류의 냉동 보관에 따른 체적 변화율은 -57% 내지 10%인, 빵류[10] The method according to claim 9, wherein the volume change rate of the bread according to the frozen storage is -57% to 10% 알룰로스, 밀가루 및 효모를 혼합하는 단계, 혼합된 생지를 냉동하는 단계를 포함하는, 냉동생지의 효모 보존성 개선 방법.Mixing alulose, wheat flour and yeast, and freezing the mixed raw material. 알룰로스, 밀가루 및 효모를 혼합하는 단계, 혼합된 생지를 냉동하는 단계를 포함하는, 냉동생지의 경화 억제 방법.Mixing alulose, wheat flour and yeast, and freezing the mixed raw material.
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