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WO2019054362A1 - Produit nettoyant huileux - Google Patents

Produit nettoyant huileux Download PDF

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Publication number
WO2019054362A1
WO2019054362A1 PCT/JP2018/033603 JP2018033603W WO2019054362A1 WO 2019054362 A1 WO2019054362 A1 WO 2019054362A1 JP 2018033603 W JP2018033603 W JP 2018033603W WO 2019054362 A1 WO2019054362 A1 WO 2019054362A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
water
hlb
detergent
poe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2018/033603
Other languages
English (en)
Japanese (ja)
Inventor
智行 苅谷
佐代子 河野
松尾　玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Priority to JP2019542061A priority Critical patent/JP7222897B2/ja
Priority to CN201880054257.1A priority patent/CN111032002A/zh
Publication of WO2019054362A1 publication Critical patent/WO2019054362A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen

Definitions

  • the present invention relates to an oil-based detergent that exhibits excellent cleansing effects without causing clouding or thickening even when water is mixed.
  • So-called cleansing oils are widely used as oil-based detergents for washing out makeup cosmetics containing oils such as lipstick, foundation, mascara, eye shadow and the like.
  • Cleansing oil is usually based on a large amount of oil and a small amount of nonionic surfactant, and in use, first make the cleansing oil compatible with the makeup cosmetic, then wash away the makeup cosmetic with the cleansing oil with water It is often used in the bathroom or bathroom because it is washed away.
  • the mixed water does not dissolve, and phenomena such as separation into two layers and whitening or thickening occur.
  • the cloudiness of the cleansing oil leads to a decrease in the cleansing effect of the makeup cosmetic since the surfactant is localized at the interface of the two layers, and thickening of the cleansing oil is applied to the makeup cosmetic. Is likely to be difficult. For this reason, the user should be careful not to use the cleansing oil with wet hands or to use it on the wet face after washing with a hair in the bathroom etc. It was not.
  • the present invention is an oil-based detergent comprising (A) HLB 9-16 nonionic surfactants, (B) liquid oil, and (C) propylene glycol laurate.
  • the present invention is also an oil-based detergent characterized by further containing (D) a polyalkylene glycol or polyoxyethylene / polyoxypropylene dimethyl ether.
  • oil-based cleaning agent of the present invention even if water is mixed, it does not become cloudy or thickened, and excellent cleaning effect can be obtained even if the user uses it with wet hands.
  • the oil-based detergent of the present invention is characterized by containing (A) nonionic surfactants of HLBs 9 to 16, (B) liquid oil, and (C) propylene glycol laurate.
  • the nonionic surfactants of HLB 9 to 16 are not particularly limited as long as they can be generally incorporated into cosmetics.
  • the liquid oil component is not particularly limited as long as it is a liquid oil component generally used for cosmetics, but, for example, hydrocarbon oil such as liquid paraffin, squalane, olefin oligomer, light isoparaffin, 2-ethyl Hexanoic acid triglyceride, cetyl 2-ethylhexanoate, pentaerythritol 2-ethylhexanoate, trimethylolpropane 2-ethylhexanoate, 2-ethylhexyl palmitate, isocetyl isononanoate, isopropyl myristate, cetyl octanoate, tripropylene dineopentanoate Ester oil such as polyglycol, jojoba oil, olive oil, macadamia nut oil, cottonseed oil, tea seed oil, safflower oil, natural vegetable oil such as rice bran oil, decamethylpentacyclosiloxane
  • polyalkylene glycol or polyoxyethylene / polyoxypropylene dimethyl ether it is preferable to further add (D) polyalkylene glycol or polyoxyethylene / polyoxypropylene dimethyl ether to the oil-based detergent of the present invention.
  • polyalkylene glycol polyethylene glycol, polypropylene glycol and polybutylene glycol can be blended.
  • polyoxyethylene / polyoxypropylene dimethyl ether POE (14) POP (7) dimethyl ether, POE (17) POP (4) dimethyl ether, etc. which are polyoxyethylene polyoxypropylene random copolymer dimethyl ether may be blended. it can.
  • the oil-based cleaner of the present invention may contain one or two or more other components that are usually blended in cosmetics and pharmaceuticals as long as the effects of the present invention are not impaired.
  • oil-based detergents components that are usually formulated into detergent compositions can be blended.
  • titanium dioxide, mica, talc and the like can be blended.
  • ultraviolet light absorbers benzoic acid-based ultraviolet light absorbers such as para-aminobenzoic acid, anthranyl-based ultraviolet light absorbers such as homomentyl-7N-acetyl anthranilate, benzoyl-based ultraviolet light absorbers such as butyl methoxybenzoylmethane, octyl cinnamate
  • glyceric acid ultraviolet light absorbers such as glyceryl such as diparamethoxycinnamic acid-mono 2-ethylhexanoate
  • salicylate ultraviolet light absorbers such as amyl salicylate
  • benzophenone ultraviolet light absorbers such as 2,4-dihydroxybenzophenone, etc. be able to.
  • moisturizer polyethylene glycol, glycerin, sorbitol, xylitol, maltitol, mucopolysaccharide, hyaluronic acid, chondroitin sulfate, chitosan and the like can be blended.
  • a thickener methylcellulose, ethylcellulose, gum arabic, polyvinyl alcohol, montmorillonite, laponite and the like can be blended.
  • ethanol, 1,3-butylene glycol or the like can be blended as an organic solvent.
  • dyes, perfumes, purified water and the like can be appropriately blended.
  • the oily detergent was adjusted according to a conventional method and evaluated for "stability”, "make-off” and "rinseability".
  • the “stability” was evaluated after leaving for 3 days under high temperature of 50 ° C. and low temperature of 0 ° C., and then, by appearance, evaluated the presence or absence of haze or cracking according to the following criteria.
  • “Make-off” is the remaining state of the liquid foundation after making 20 reciprocations while applying a weight of 300 g with tissue paper containing 0.2 g of oily detergent, on the upper surface of the artificial leather to which the liquid foundation has been uniformly applied. It evaluated by visual observation.
  • the "rinseability" was determined by sensory evaluation on the time required to feel no sliminess after applying 3 g of an oily detergent to the entire face, letting it soak well, and then washing with water.
  • Oily detergents may increase in viscosity or become cloudy when water is mixed. As the viscosity increases, the oily detergent becomes less familiar to the make. In addition, in the case of a detergent that is turbid, it is difficult for the surfactant of the cleansing component to bind to the make, and the effect of removing the make tends to be reduced. Therefore, the viscosity, transparency, and make-off were evaluated when water was mixed.
  • the viscosity at the time of mixing with water water is added to the oily detergent so that the compounding ratio of the oily detergent: water becomes 7: 3, and after mixing by inversion mixing, 40 g of the mixed liquid It was filled in a 50 ml glass bottle and measured using a BL type No. 3 rotor (rotation speed 12 rpm) at a temperature of 30 ° C., and then evaluated according to the following criteria.
  • the viscosity of the oil-based detergent before mixing in water is about 40 mPa ⁇ s (BL type No. 1 rotor rotational speed 60 rpm). It is preferable that the oil-based cleaning agent has the smallest possible increase in viscosity due to the mixing of water.
  • As a standard of evaluation it was set as the standard of the pass that the viscosity at the time of mixing with water is 3500 mPa ⁇ s or less.
  • evaluations can be made not only by polypropylene glycol but also by the blending of polyalkylene glycols such as polyethylene glycol and polybutylene glycol or polyoxyethylene / polyoxypropylene dimethyl ether. Was confirmed to improve.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention fournit un produit nettoyant huileux qui ne se trouble pas ni ne s'épaissit y compris lorsqu'il est mélangé à une eau, et qui permet de développer un excellent effet nettoyant même par exemple lorsque l'utilisateur le met en œuvre avec les mains mouillées. Plus précisément, l'invention concerne un produit nettoyant huileux qui est caractéristique en ce qu'il comprend (A) un tensioactif non ionique de valeur HLB comprise entre 9 et 16, (B) une huile liquide, et (C) un propylène glycol d'acide laurique.
PCT/JP2018/033603 2017-09-13 2018-09-11 Produit nettoyant huileux Ceased WO2019054362A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2019542061A JP7222897B2 (ja) 2017-09-13 2018-09-11 油性洗浄料
CN201880054257.1A CN111032002A (zh) 2017-09-13 2018-09-11 油性清洁剂

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017-175405 2017-09-13
JP2017175405 2017-09-13

Publications (1)

Publication Number Publication Date
WO2019054362A1 true WO2019054362A1 (fr) 2019-03-21

Family

ID=65723966

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2018/033603 Ceased WO2019054362A1 (fr) 2017-09-13 2018-09-11 Produit nettoyant huileux

Country Status (4)

Country Link
JP (1) JP7222897B2 (fr)
CN (1) CN111032002A (fr)
TW (1) TW201922205A (fr)
WO (1) WO2019054362A1 (fr)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003113023A (ja) * 2001-09-28 2003-04-18 Shiseido Co Ltd 皮膚外用剤用基剤及びそれを配合してなる化粧品
WO2003080004A1 (fr) * 2002-03-26 2003-10-02 Kao Corporation Preparation demaquillante
JP2004161659A (ja) * 2002-11-12 2004-06-10 Kawaken Fine Chem Co Ltd 乳化剤組成物及びそれを含む透明自己乳化型油性化粧料
JP2005206557A (ja) * 2004-01-26 2005-08-04 Sansho Kaken Kk クレンジング
JP2005264110A (ja) * 2004-03-22 2005-09-29 Shiseido Co Ltd 油性洗浄料
JP2005298635A (ja) * 2004-04-09 2005-10-27 Shiseido Co Ltd ゲル状組成物及びその製造方法
JP2006225403A (ja) * 2005-06-17 2006-08-31 Asahi Kasei Chemicals Corp 油性ゲル状クレンジング
JP2006306780A (ja) * 2005-04-28 2006-11-09 Kao Corp 液状クレンジング剤組成物
US20080044372A1 (en) * 2000-07-10 2008-02-21 Vatter Michael L Transfer-resistant makeup removing compositions
JP2012126664A (ja) * 2010-12-14 2012-07-05 Mikimoto Pharmaceut Co Ltd 油性洗浄剤

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4757446B2 (ja) * 2004-01-09 2011-08-24 株式会社 資生堂 油性クレンジング組成物

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080044372A1 (en) * 2000-07-10 2008-02-21 Vatter Michael L Transfer-resistant makeup removing compositions
JP2003113023A (ja) * 2001-09-28 2003-04-18 Shiseido Co Ltd 皮膚外用剤用基剤及びそれを配合してなる化粧品
WO2003080004A1 (fr) * 2002-03-26 2003-10-02 Kao Corporation Preparation demaquillante
JP2004161659A (ja) * 2002-11-12 2004-06-10 Kawaken Fine Chem Co Ltd 乳化剤組成物及びそれを含む透明自己乳化型油性化粧料
JP2005206557A (ja) * 2004-01-26 2005-08-04 Sansho Kaken Kk クレンジング
JP2005264110A (ja) * 2004-03-22 2005-09-29 Shiseido Co Ltd 油性洗浄料
JP2005298635A (ja) * 2004-04-09 2005-10-27 Shiseido Co Ltd ゲル状組成物及びその製造方法
JP2006306780A (ja) * 2005-04-28 2006-11-09 Kao Corp 液状クレンジング剤組成物
JP2006225403A (ja) * 2005-06-17 2006-08-31 Asahi Kasei Chemicals Corp 油性ゲル状クレンジング
JP2012126664A (ja) * 2010-12-14 2012-07-05 Mikimoto Pharmaceut Co Ltd 油性洗浄剤

Also Published As

Publication number Publication date
JPWO2019054362A1 (ja) 2020-10-15
CN111032002A (zh) 2020-04-17
TW201922205A (zh) 2019-06-16
JP7222897B2 (ja) 2023-02-15

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