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WO2018221693A1 - Structure fonctionnelle et procédé de production de structure fonctionnelle - Google Patents

Structure fonctionnelle et procédé de production de structure fonctionnelle Download PDF

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Publication number
WO2018221693A1
WO2018221693A1 PCT/JP2018/021081 JP2018021081W WO2018221693A1 WO 2018221693 A1 WO2018221693 A1 WO 2018221693A1 JP 2018021081 W JP2018021081 W JP 2018021081W WO 2018221693 A1 WO2018221693 A1 WO 2018221693A1
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WIPO (PCT)
Prior art keywords
functional structure
skeleton
solid acid
precursor material
structure according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2018/021081
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English (en)
Japanese (ja)
Inventor
隆夫 増田
佑太 中坂
吉川　琢也
禎宏 加藤
將行 福嶋
稲森　康次郎
尋子 高橋
祐一郎 馬場
可織 関根
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Furukawa Electric Co Ltd
Hokkaido University NUC
Original Assignee
Furukawa Electric Co Ltd
Hokkaido University NUC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Furukawa Electric Co Ltd, Hokkaido University NUC filed Critical Furukawa Electric Co Ltd
Priority to JP2019521321A priority Critical patent/JP7352910B2/ja
Priority to EP18810208.1A priority patent/EP3632549A4/fr
Priority to CN201880035173.3A priority patent/CN110709165A/zh
Priority to AU2018277967A priority patent/AU2018277967B2/en
Publication of WO2018221693A1 publication Critical patent/WO2018221693A1/fr
Priority to US16/698,636 priority patent/US11655157B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • Y02P30/40—Ethylene production

Definitions

  • the present invention relates to a functional structure comprising a skeleton having a porous structure and a solid acid, and a method for producing the functional structure.
  • Oil refinery refineries produce petrochemical raw materials called naphtha and various fuels such as heavy oil, light oil, kerosene, gasoline, and LP gas from crude oil. Since crude oil is a mixture in which various impurities are mixed in addition to the above petrochemical raw materials and various fuels, a step of distilling and separating each component contained in the crude oil is required.
  • crude oil is heated on the shelf in the tower of the atmospheric distillation apparatus using the difference in boiling point of each component to separate the components, and the separated components are concentrated.
  • low-boiling substances such as LP gas and naphtha are extracted from the upper shelf of the atmospheric distillation apparatus, and high-boiling substances such as heavy oil are extracted from the bottom of the atmospheric distillation apparatus.
  • various fuel products are manufactured by giving secondary treatments, such as desulfurization, to each concentrated component.
  • petroleum reforming catalysts are used for producing gasoline having a high octane number by efficiently reforming naphtha having a low boiling point in the oil refining process.
  • the naphtha fraction in crude oil has a low octane number and is not suitable as gasoline for running vehicles. Therefore, reformed gasoline with properties suitable for vehicle fuel can be obtained by reforming paraffin and naphthene components having a low octane number in the naphtha fraction into aromatic components having a high octane number using an oil reforming catalyst.
  • hydrodesulfurization treatment is being carried out to increase production of desulfurized naphtha, desulfurized kerosene, desulfurized gas oil, and the like.
  • hydrocracking treatment is being carried out to increase production of desulfurized naphtha, desulfurized kerosene, desulfurized gas oil, and the like.
  • the yield of desulfurized kerosene oil fraction and desulfurized naphtha fraction is increased to reduce desulfurized heavy oil, and the desulfurized heavy oil is removed from the desulfurized heavy oil by a catalytic cracker.
  • Residual oil is reduced and light oil fraction is increased by producing LPG fraction, FCC gasoline fraction and LCO fraction.
  • a catalyst used for hydrocracking treatment a catalyst composed of a crystalline aluminosilicate support, which is a typical zeolite, and a hydrocracking catalyst containing zeolite and a porous inorganic oxide in a specific ratio have been proposed.
  • Patent Document 1 a metal made of a material selected from Pd, Pt, Co, Fe, Cr, Mo, W and a mixture thereof is formed on the surface of a support made of Y-type zeolite as a hydrocracking catalyst.
  • a deposited catalyst is disclosed.
  • Patent Document 2 as a catalyst structure for exhaust gas of a vehicle equipped with a diesel engine, a ceramic carrier is disposed on the surface of a base ceramic, and both the main catalyst component and the promoter component are supported on the ceramic carrier.
  • a ceramic catalyst body is disclosed.
  • this ceramic catalyst body a large number of pores made of lattice defects in the crystal lattice are formed on the surface of the ceramic carrier made of ⁇ -alumina, and the main catalyst component made of Ce—Zr, Pt, etc. is used as the ceramic carrier. It has the structure directly supported by the surface vicinity.
  • Patent Document 4 discloses a zeolite-containing molded catalyst as a catalyst used when producing ethylene and propylene from a hydrocarbon raw material containing an olefin having 4 to 12 carbon atoms (Patent Document 4).
  • the oil reforming catalyst is usually connected downstream of the atmospheric distillation apparatus and continuously used in the oil refining process, it is difficult to apply the catalyst reactivation technique. Even if the catalyst reactivation technique can be applied, the operation becomes very complicated. Suppression or prevention of such a function deterioration over time is cited as a problem not only in the catalyst field but also in various technical fields.
  • An object of the present invention is to provide a functional structure and a functional structure that can suppress the deterioration of the function of the solid acid and achieve a long life, do not require complicated replacement work, and can save resources. It is in providing the manufacturing method of a body.
  • the inventors of the present invention comprise a porous structure skeleton body composed of a zeolite-type compound and at least one solid acid inherent in the skeleton body.
  • the skeleton body has a passage communicating with each other, and the solid acid is present in at least the passage of the skeleton body, thereby suppressing the deterioration of the function of the solid acid and realizing a long life.
  • the present inventors have found that a sex structure can be obtained, and have completed the present invention based on such knowledge.
  • the gist configuration of the present invention is as follows.
  • the enlarged diameter portion communicates a plurality of holes constituting any one of the one-dimensional hole, the two-dimensional hole, and the three-dimensional hole. body.
  • the passage includes any one of a one-dimensional hole, a two-dimensional hole, and a three-dimensional hole defined by a skeleton structure of the zeolite-type compound, and the one-dimensional hole, the two-dimensional hole, and the three-dimensional hole.
  • the functional structure according to any one of [1] to [12] further comprising at least one functional substance held on the outer surface of the skeleton.
  • the content of the at least one solid acid inherent in the skeleton is greater than the content of the at least one functional substance held on the outer surface of the skeleton. 13].
  • the functional structure and functional structure which can suppress the functional fall of a solid acid, can implement
  • a method of manufacturing a body can be provided.
  • FIG. 1 schematically shows the internal structure of a functional structure according to an embodiment of the present invention
  • FIG. 1A is a perspective view (a part thereof is shown in cross section).
  • FIG. 1B is a partially enlarged sectional view.
  • 2 is a partially enlarged cross-sectional view for explaining an example of the function of the functional structure of FIG. 1
  • FIG. 2 (a) is a diagram illustrating a sieve function
  • FIG. 2 (b) is a diagram illustrating a catalyst function.
  • FIG. 3 is a flowchart showing an example of a method for manufacturing the functional structure of FIG.
  • FIG. 4 is a schematic diagram showing a modification of the functional structure of FIG.
  • FIG. 1 is a diagram schematically showing a configuration of a functional structure according to an embodiment of the present invention, in which (a) is a perspective view (a part is shown in cross section), and (b) is a partially enlarged cross section.
  • FIG. 1 The functional structure in FIG. 1 shows an example, and the shape, size, etc. of each component according to the present invention are not limited to those in FIG.
  • the functional structure 1 includes a skeleton 10 having a porous structure composed of a zeolite-type compound and at least one solid acid 20 present in the skeleton 10. .
  • the solid acid 20 is a substance that exhibits one or more functions by itself or in cooperation with the skeleton body 10. Specific examples of the function include a catalyst function, a light emission (or fluorescence) function, a light absorption function, and an identification function.
  • the solid acid 20 is a catalyst substance having a catalytic function, for example, and is preferably fine particles.
  • the skeleton 10 is a carrier that supports the catalyst material.
  • the plurality of solid acids 20, 20,... Are included in the porous structure of the skeleton body 10.
  • the skeleton body 10 has a porous structure and, as shown in FIG. 1B, preferably has a plurality of holes 11a, 11a,.
  • the solid acid 20 exists in at least the passage 11 of the skeleton body 10, and is preferably held in at least the passage 11 of the skeleton body 10.
  • the movement of the solid acid 20 in the skeleton body 10 is restricted, and aggregation of the solid acids 20 and 20 is effectively prevented.
  • the reduction of the effective surface area as the solid acid 20 can be effectively suppressed, and the function of the solid acid 20 lasts for a long time. That is, according to the functional structure 1, it is possible to suppress a decrease in function due to the aggregation of the solid acid 20, and to extend the life of the functional structure 1. Further, by extending the lifetime of the functional structure 1, the frequency of replacement of the functional structure 1 can be reduced, the amount of used functional structure 1 discarded can be greatly reduced, and resource saving can be achieved. be able to.
  • the fluid flows into the passage 11 from the hole 11a of the skeleton body 10, and therefore the speed of the fluid flowing in the passage 11 is determined by the flow resistance (friction force). This is considered to be slower than the speed of the fluid flowing on the outer surface of the skeleton body 10. Due to the influence of the flow path resistance, the pressure that the solid acid 20 existing in the passage 11 receives from the fluid is lower than the pressure that the solid acid receives from the fluid outside the skeleton 10. Therefore, it is possible to effectively suppress the solid acid 20 existing in the skeleton body 11 from being separated, and the function of the solid acid 20 can be stably maintained for a long period of time.
  • the flow path resistance as described above increases as the passage 11 of the skeleton body 10 has a plurality of bends and branches, and the inside of the skeleton body 10 has a more complicated and three-dimensional structure. Conceivable.
  • the passage 11 includes any one of a one-dimensional hole, a two-dimensional hole, and a three-dimensional hole defined by a skeleton structure of the zeolite type compound, and the one-dimensional hole, the two-dimensional hole, and the three-dimensional hole. It is preferable to have a diameter-expanded portion 12 that is different from each other. At this time, the solid acid 20 is preferably present at least in the diameter-expanded portion 12, and is included in at least the diameter-expanded portion 12. It is preferable.
  • a one-dimensional hole means a tunnel-type or cage-type hole forming a one-dimensional channel, or a plurality of tunnel-type or cage-type holes forming a plurality of one-dimensional channels (a plurality of one-dimensional holes).
  • Channel a two-dimensional hole refers to a two-dimensional channel in which a plurality of one-dimensional channels are two-dimensionally connected.
  • a three-dimensional hole refers to a three-dimensional channel in which a plurality of one-dimensional channels are three-dimensionally connected. Point to. Thereby, the movement of the solid acid 20 in the skeleton 10 is further restricted, and the separation of the solid acid 20 and the aggregation of the solid acids 20 and 20 can be more effectively prevented.
  • Inclusion refers to a state in which the solid acid 20 is encapsulated in the skeleton 10. At this time, the solid acid 20 and the skeleton body 10 are not necessarily in direct contact with each other, and another substance (for example, a surfactant or the like) is interposed between the solid acid 20 and the skeleton body 10. In this state, the solid acid 20 may be indirectly held by the skeleton body 10.
  • another substance for example, a surfactant or the like
  • FIG. 1B shows a case where the solid acid 20 is included in the enlarged diameter portion 12, the solid acid 20 is not limited to this configuration. You may hold
  • the passage 11 is three-dimensionally formed inside the skeleton body 10 including a branching portion or a merging portion, and the enlarged diameter portion 12 may be provided in the branching portion or the merging portion of the passage 11. preferable.
  • the average inner diameter DF of the passage 11 formed in the skeleton 10 is calculated from the average value of the short diameter and the long diameter of the hole 11a constituting any one of the one-dimensional hole, the two-dimensional hole, and the three-dimensional hole,
  • the thickness is 0.1 nm to 1.5 nm, and preferably 0.5 nm to 0.8 nm.
  • the inner diameter DE of the enlarged diameter portion 12 is, for example, 0.5 nm to 50 nm, preferably 1.1 nm to 40 nm, more preferably 1.1 nm to 3.3 nm.
  • the inner diameter D E of the enlarged diameter section 12 depends on for example the pore size of which will be described later precursor material (A), and the average particle diameter D C of the solid acid 20 that is inclusion.
  • the inner diameter DE of the expanded diameter portion 12 is a size that can include the solid acid 20.
  • the skeleton 10 is composed of a zeolite type compound.
  • Zeolite type compounds include, for example, zeolites (aluminosilicates), cation exchange zeolites, silicate compounds such as silicalite, zeolite related compounds such as aluminoborate, aluminoarsenate, germanate, molybdenum phosphate, etc. And phosphate-based zeolite-like substances.
  • the zeolite type compound is preferably a silicate compound.
  • the framework structure of zeolite type compounds is FAU type (Y type or X type), MTW type, MFI type (ZSM-5), FER type (ferrierite), LTA type (A type), MWW type (MCM-22) , MOR type (mordenite), LTL type (L type), BEA type (beta type), etc., preferably MFI type, more preferably ZSM-5.
  • a plurality of pores having a pore size corresponding to each skeleton structure are formed.
  • the maximum pore size of the MFI type is 0.636 nm (6.36 mm), and the average pore size is 0.560 nm (5.60 mm). is there.
  • the solid acid 20 When the solid acid 20 is a fine particle, the fine particle is present in the passage 11 as a primary particle, and the fine particle is present in the passage 11 as a secondary particle formed by aggregation of the primary particles.
  • the average particle diameter D C of the fine particles is preferably larger than the average inner diameter D F of the passage 11 and not more than the inner diameter D E of the enlarged diameter portion 12 (D F ⁇ D C ⁇ D E ).
  • Such a solid acid 20 is preferably enclosed by the enlarged diameter portion 12 in the passage 11, and movement of the solid acid 20 in the skeleton 10 is restricted.
  • the average particle diameter D C of the fine particles in any case of the primary particles and secondary particles, and preferably 0.1nm ⁇ 50 nm, more preferably 0.1nm
  • the thickness is less than 30 nm, more preferably 0.45 nm to 14.0 nm, and particularly preferably 1.0 nm to 3.3 nm.
  • the ratio (D C / D F ) of the average particle diameter D C of the solid acid 20 to the average inner diameter D F of the passage 11 is preferably 0.06 to 500, more preferably 0.1 to 36. More preferably, it is 1.1 to 36, and particularly preferably 1.7 to 4.5.
  • the solid acid 20 include metal oxides and hydrates, sulfides, metal salts, composite oxides, and heteropoly acids.
  • the metal oxide include iron oxide (FeOx), zinc oxide (ZnO), aluminum oxide (Al 2 O 3 ), zirconium oxide (ZrO 2 ), titanium oxide (TiO 2 ), selenium trioxide (SeO 3 ), dioxide dioxide Selenium (SeO 2 ), tellurium trioxide (TeO 3 ), tellurium dioxide (TeO 2 ), tin dioxide (SnO 2 ), manganese oxide (Mn 2 O 7 ), technetium oxide (Tc 2 O 7 ) and rhenium oxide (Re 2 O 7 ).
  • Examples of the sulfide include cadmium sulfide (CdS) and zinc sulfide (ZnS).
  • Examples of the metal salt include magnesium sulfate (MgSO 4 ), iron sulfate (FeSO 4 ), and aluminum chloride (AlCl 3 ).
  • examples of the composite oxide include SiO 2 —TiO 2 , SiO 2 —MgO, and TiO 2 —ZrO 2 .
  • examples of the heteropolyacid include phosphotungstic acid, silicotungstic acid, phosphomolybdic acid, and silicomolybdic acid. These solid acids 20 may be used alone or in combination of a plurality of types.
  • the solid acid 20 is preferably at least one selected from the group consisting of aluminum oxide (Al 2 O 3 ), zirconium oxide (ZrO 2 ), and zinc oxide (ZnO).
  • the solid acid 20 is distinguished from the zeolite type compound constituting the skeleton 10.
  • the solid acid 20 does not include, for example, zeolite.
  • the metal element (M) of the solid acid 20 is preferably contained in an amount of 0.5 to 2.5% by mass with respect to the functional structure 1, and 0.5% with respect to the functional structure 1. More preferably, it is contained in an amount of ⁇ 1.5% by mass.
  • the content (mass%) of the Zr element is represented by (mass of Zr element) / (mass of all elements of the functional structure 1) ⁇ 100.
  • the ratio of the silicon (Si) constituting the skeleton 10 to the metal element (M) constituting the solid acid 20 is preferably 10 to 1000, preferably 50 to 200. More preferably. If the ratio is greater than 1000, the activity is low, and the action as a solid acid may not be sufficiently obtained. On the other hand, when the ratio is smaller than 10, the ratio of the solid acid 20 becomes too large, and the strength of the skeleton 10 tends to decrease.
  • the solid acid 20 here refers to a solid acid held or supported inside the skeleton body 10 and does not include a solid acid attached to the outer surface of the skeleton body 10.
  • the functional structure 1 includes the skeleton 10 having a porous structure and at least one solid acid 20 inherent in the skeleton.
  • the functional structure 1 exhibits a function corresponding to the function of the solid acid 20 when the solid acid 20 inherent in the skeleton body 10 comes into contact with the fluid.
  • the fluid that has contacted the outer surface 10 a of the functional structure 1 flows into the skeleton body 10 through the holes 11 a formed in the outer surface 10 a, is guided into the passage 11, and passes through the passage 11. It moves and goes out of the functional structure 1 through the other hole 11a.
  • a reaction for example, a catalytic reaction
  • the functional structure 1 has molecular sieving ability because the skeleton body has a porous structure.
  • the molecular sieving ability of the functional structure 1 will be described with reference to FIG. 2A as an example where the fluid is a liquid containing benzene, propylene and mesitylene.
  • a compound for example, benzene, propylene
  • a compound composed of molecules having a size smaller than the diameter of the hole 11a, in other words, smaller than the inner diameter of the passage 11, enters the skeleton body 10.
  • a compound for example, mesitylene
  • the reaction of the compound that cannot enter the skeleton body 10 is restricted, and the compound that can enter the skeleton body 10 can be reacted. it can.
  • the solid acid 20 is preferably included in the enlarged diameter portion 12 of the passage 11.
  • the solid acid 20 is a fine particle
  • the average particle diameter D C of the solid acid 20 is larger than the average inner diameter D F of the passage 11 and smaller than the inner diameter D E of the enlarged diameter portion 12 (D F ⁇ D C ⁇ D E )
  • a small passage 13 is formed between the solid acid 20 and the enlarged diameter portion 12. Therefore, as shown by the arrow in FIG. 2B, the fluid that has entered the small passage 13 comes into contact with the solid acid 20. Since each solid acid 20 is included in the enlarged diameter portion 12, movement within the skeleton body 10 is limited. Thereby, aggregation of the solid acids 20 in the skeleton 10 is prevented. As a result, a large contact area between the solid acid 20 and the fluid can be stably maintained.
  • the solid acid 20 has a catalytic function
  • a case where the solid acid 20 is zinc oxide (ZnO x ) fine particles and dodecylbenzene, which is a heavy oil, is infiltrated into the skeleton 10 of the functional structure 1 will be described as an example.
  • dodecylbenzene permeates into the skeleton body 10 as shown below, dodecylbenzene is decomposed into various alcohols and ketones by oxidative decomposition reaction.
  • benzene which is light oil is produced
  • FIG. 3 is a flowchart showing a method for manufacturing the functional structure 1 of FIG.
  • an example of a method for producing a functional structure will be described, taking as an example the case where the solid acid present in the skeleton is metal oxide fine particles.
  • Step S1 Preparation process
  • a precursor material (A) for obtaining a porous skeleton composed of a zeolite-type compound is prepared.
  • the precursor material (A) is preferably a regular mesoporous material, and can be appropriately selected according to the type (composition) of the zeolite-type compound constituting the skeleton of the functional structure.
  • the regular mesoporous material has one-dimensional, two-dimensional pores with a pore diameter of 1 nm to 50 nm.
  • a compound composed of a Si—O skeleton that is three-dimensionally uniform and regularly developed is preferable.
  • Such regular mesoporous materials can be obtained as various composites depending on the synthesis conditions. Specific examples of the composites include, for example, SBA-1, SBA-15, SBA-16, KIT-6, FSM- 16, MCM-41, etc., among which MCM-41 is preferable.
  • the pore size of SBA-1 is 10 nm to 30 nm
  • the pore size of SBA-15 is 6 nm to 10 nm
  • the pore size of SBA-16 is 6 nm
  • the pore size of KIT-6 is 9 nm
  • the pore size of FSM-16 is 3 nm.
  • the pore diameter of MCM-41 is 1 nm to 10 nm. Examples of such regular mesoporous materials include mesoporous silica, mesoporous aluminosilicate, and mesoporous metallosilicate.
  • the precursor material (A) may be a commercially available product or a synthetic product.
  • synthesizing the precursor material (A) a known method for synthesizing regular mesoporous materials can be employed. For example, a mixed solution containing a raw material containing the constituent elements of the precursor material (A) and a templating agent for defining the structure of the precursor material (A) is prepared, and the pH is adjusted as necessary. Hydrothermal treatment (hydrothermal synthesis) is performed. Thereafter, the precipitate (product) obtained by hydrothermal treatment is recovered (for example, filtered), washed and dried as necessary, and further calcined to form a regular mesoporous material in powder form. A precursor material (A) is obtained.
  • a solvent of the mixed solution for example, water, an organic solvent such as alcohol, or a mixed solvent thereof can be used.
  • a raw material is selected according to the kind of frame
  • TEOS tetraethoxysilane
  • quartz sand etc.
  • various surfactants, block copolymers and the like can be used, and it is preferable to select according to the kind of the compound of the regular mesoporous material.
  • a surfactant such as hexadecyltrimethylammonium bromide is preferred.
  • the hydrothermal treatment can be performed, for example, in a sealed container at 80 to 800 ° C., 5 hours to 240 hours, and treatment conditions of 0 to 2000 kPa.
  • the firing treatment can be performed, for example, in air at 350 to 850 ° C. for 2 to 30 hours.
  • Step S2 impregnation step
  • the prepared precursor material (A) is impregnated with the metal-containing solution to obtain the precursor material (B).
  • the metal-containing solution may be a solution containing (for example, metal ions) corresponding to the metal element (M) constituting the metal oxide fine particles, for example, a metal salt containing the metal element (M) in a solvent.
  • a metal salt containing the metal element (M) in a solvent can be prepared by dissolving.
  • metal salts include chlorides, hydroxides, oxides, sulfates, nitrates, and the like, and nitrates are particularly preferable.
  • organic solvents such as water and alcohol, these mixed solvents, etc. can be used, for example.
  • the method for impregnating the precursor material (A) with the metal-containing solution is not particularly limited.
  • a plurality of metal-containing solutions are mixed while stirring the powdery precursor material (A) before the firing step described later. It is preferable to add in small portions in portions.
  • a surfactant as an additive is added in advance to the precursor material (A) before adding the metal-containing solution. It is preferable to add it.
  • Such an additive has a function of coating the outer surface of the precursor material (A), suppresses the metal-containing solution added thereafter from adhering to the outer surface of the precursor material (A), and the metal It is considered that the contained solution is more likely to enter the pores of the precursor material (A).
  • nonionic surfactants such as polyoxyethylene alkyl ethers such as polyoxyethylene oleyl ether and polyoxyethylene alkylphenyl ethers. Since these surfactants have a large molecular size and cannot penetrate into the pores of the precursor material (A), they do not adhere to the inside of the pores, and the metal-containing solution penetrates into the pores. It is thought not to interfere.
  • the nonionic surfactant is preferably added in an amount of 50 to 500% by mass with respect to the precursor material (A) before the firing step described later.
  • the addition amount of the nonionic surfactant to the precursor material (A) is less than 50% by mass, the above-described inhibitory action is hardly exhibited, and the nonionic surfactant is added to the precursor material (A) at 500. Addition of more than% by mass is not preferable because the viscosity increases excessively. Therefore, the addition amount of the nonionic surfactant with respect to the precursor material (A) is set to a value within the above range.
  • the amount of the metal-containing solution added to the precursor material (A) is the amount of the metal element (M) contained in the metal-containing solution impregnated in the precursor material (A) (that is, the precursor material (B It is preferable to adjust appropriately in consideration of the amount of the metal element (M) contained in ().
  • the amount of the metal-containing solution added to the precursor material (A) before the firing step described later is relative to the metal element (M) contained in the metal-containing solution added to the precursor material (A).
  • the ratio of silicon (Si) constituting the precursor material (A) atomic ratio Si / M
  • it is preferably adjusted to be 10 to 1000, and adjusted to be 50 to 200. It is more preferable.
  • the addition of the metal-containing solution to be added to the precursor material (A) By converting the amount to 50 to 200 in terms of atomic ratio Si / M, the metal element (M) of the metal oxide fine particles is 0.5 to 2.5 mass% with respect to the functional structure. It can be included. Yes.
  • the amount of the metal element (M) present in the pores is the same as the metal concentration of the metal-containing solution, the presence or absence of the additive, and other conditions such as temperature and pressure. If so, it is roughly proportional to the amount of the metal-containing solution added to the precursor material (A).
  • the amount of the metal element (M) inherent in the precursor material (B) is proportional to the amount of the metal element constituting the metal oxide fine particles inherent in the skeleton of the functional structure. Therefore, by controlling the amount of the metal-containing solution added to the precursor material (A) within the above range, the metal-containing solution can be sufficiently impregnated inside the pores of the precursor material (A), and thus The amount of the metal oxide fine particles incorporated in the skeleton of the functional structure can be adjusted.
  • a cleaning treatment may be performed as necessary.
  • the washing solution water, an organic solvent such as alcohol, a mixed solvent thereof or the like can be used.
  • the drying treatment include natural drying overnight or high temperature drying at 150 ° C. or lower.
  • the regular mesoporous material of the precursor material (A) is obtained. Therefore, it is preferable to dry the skeleton structure sufficiently.
  • Step S3 Firing step
  • the precursor material (B) obtained by impregnating the precursor material (A) for obtaining a porous structure composed of a zeolite-type compound with the metal-containing solution is fired, and the precursor material (C )
  • the calcination treatment is preferably performed, for example, in air at 350 to 850 ° C. for 2 to 30 hours.
  • the metal component impregnated in the pores of the regular mesoporous material grows in crystal, and metal oxide fine particles are formed in the pores.
  • Step S4 Hydrothermal treatment process
  • a mixed solution in which the precursor material (C) and the structure-directing agent are mixed is prepared, and the precursor material (C) obtained by firing the precursor material (B) is hydrothermally treated to provide functionality. Get a structure.
  • the structure directing agent is a templating agent for defining the skeletal structure of the skeleton of the functional structure.
  • a surfactant can be used.
  • the structure directing agent is preferably selected according to the skeleton structure of the skeleton of the functional structure, for example, an interface such as tetramethylammonium bromide (TMABr), tetraethylammonium bromide (TEABr), tetrapropylammonium bromide (TPABr), etc.
  • An activator is preferred.
  • the mixing of the precursor material (C) and the structure directing agent may be performed during the hydrothermal treatment step or before the hydrothermal treatment step.
  • the preparation method of the said mixed solution is not specifically limited, A precursor material (C), a structure directing agent, and a solvent may be mixed simultaneously, or precursor material (C) and structure prescription
  • each agent is dispersed in each solution, each dispersion solution may be mixed.
  • organic solvents such as water and alcohol, these mixed solvents, etc. can be used, for example.
  • the hydrothermal treatment can be performed by a known method.
  • the hydrothermal treatment is preferably performed in a sealed container at 80 to 800 ° C., 5 hours to 240 hours, and 0 to 2000 kPa.
  • the hydrothermal treatment is preferably performed in a basic atmosphere.
  • the reaction mechanism here is not necessarily clear, by performing hydrothermal treatment using the precursor material (C) as a raw material, the skeleton structure of the precursor material (C) as a regular mesoporous material gradually collapses. While maintaining the position of the metal oxide fine particles inside the pores of the precursor material (C) in general, a new skeleton structure (porous structure) as a skeleton of the functional structure by the action of the structure-directing agent Is formed.
  • the functional structure thus obtained includes a skeleton having a porous structure and metal oxide fine particles inherent in the skeleton, and the skeleton has a passage in which a plurality of pores communicate with each other due to the porous structure. At least a part of the metal oxide fine particles is held in the passage of the skeleton body.
  • a mixed solution in which the precursor material (C) and the structure directing agent are mixed is prepared, and the precursor material (C) is hydrothermally treated.
  • the precursor material (C) may be hydrothermally treated without mixing the precursor material (C) and the structure directing agent.
  • the precipitate (functional structure) obtained after the hydrothermal treatment is preferably subjected to washing treatment, drying treatment and firing treatment as necessary after collection (for example, filtration).
  • the cleaning solution water, an organic solvent such as alcohol, or a mixed solution thereof can be used.
  • the drying treatment include natural drying for about one night and high temperature drying at 150 ° C. or lower. Note that if the baking treatment is performed in a state where a lot of moisture remains in the precipitate, the skeleton structure as the skeleton of the functional structure may be broken.
  • the firing treatment can be performed, for example, in air at 350 to 850 ° C. for 2 to 30 hours. By such baking treatment, the structure directing agent attached to the functional structure is burned out.
  • a functional structure can also be used as it is, without performing baking processing with respect to the deposit after collection
  • the environment in which the functional structure is used is a high-temperature environment in an oxidizing atmosphere
  • the structure-directing agent is burned away by being exposed to the environment for use for a certain period of time. In this case, since the same functional structure as that obtained when the baking treatment is performed is obtained, it is not necessary to perform the baking treatment.
  • FIG. 4 is a schematic diagram showing a modification of the functional structure 1 of FIG.
  • the functional structure 1 in FIG. 1 includes a skeleton body 10 and a solid acid 20 inherent in the skeleton body 10, but is not limited to this configuration.
  • the functional structure body 2 may further include at least one functional substance 30 held on the outer surface 10 a of the skeleton body 10.
  • This functional substance 30 is a substance that exhibits one or more functions.
  • the function of the functional substance 30 may be the same as or different from the function of the solid acid 20. Specific examples of the function of the functional substance 30 are the same as those described for the solid acid 20.
  • the functional material 30 preferably has a catalytic function. At this time, the functional material 30 is a catalytic material.
  • the functional substance 30 may be a solid acid, and when the functional substance 30 is a solid acid, the functional substance 30 may be the same substance as the solid acid 20 or a different substance. Also good. In particular, when the functional substance 30 is a solid acid, the content of the solid acid held in the functional structure 2 can be increased as compared with the functional structure 1, and the catalytic reaction with the solid acid can be performed. It can be further promoted.
  • the content of the solid acid 20 inherent in the skeleton body 10 is preferably larger than the content of the functional substance 30 held on the outer surface 10a of the skeleton body 10.
  • maintained inside the skeleton 10 becomes dominant, and the function of a solid acid is exhibited stably.
  • type of precursor material (A) (“type of precursor material (A): surfactant”).
  • CTL-41 hexadecyltrimethylammonium bromide (CTAB) (manufactured by Wako Pure Chemical Industries, Ltd.)
  • SBA-1 Pluronic P123 (BASF)
  • ZnO X zinc nitrate hexahydrate (manufactured by Wako Pure Chemical Industries, Ltd.)
  • AlO X Aluminum nitrate nonahydrate (manufactured by Wako Pure Chemical Industries, Ltd.)
  • ZrO X Zirconyl nitrate dihydrate (manufactured by Wako Pure Chemical Industries, Ltd.)
  • the metal-containing aqueous solution is added to the powdery precursor material (A) in small portions in small portions, and dried at room temperature (20 ° C. ⁇ 10 ° C.) for 12 hours or more to obtain the precursor material (B).
  • polyoxyethylene (15) as an additive with respect to the precursor material (A) before adding the metal-containing aqueous solution Pretreatment was performed by adding an aqueous solution of oleyl ether (NIKKOL BO-15V, manufactured by Nikko Chemicals Co., Ltd.), and then the metal-containing aqueous solution was added as described above.
  • the condition for the presence or absence of the additive is “none”
  • the pretreatment with the additive as described above is not performed.
  • the addition amount of the metal-containing aqueous solution added to the precursor material (A) is the ratio of silicon (Si) constituting the precursor material (A) to the metal element (M) contained in the metal-containing aqueous solution (
  • the numerical values when converted into the atomic ratio (Si / M) were adjusted to the values shown in Tables 1-6.
  • precursor material (B) impregnated with the metal-containing aqueous solution obtained as described above was fired in the air at 600 ° C. for 24 hours to obtain a precursor material (C).
  • Comparative Example 1 Comparative Example 1, cobalt oxide powder (II, III) (manufactured by Sigma Aldrich Japan LLC) having an average particle size of 50 nm or less was mixed with MFI type silicalite, and a functional substance was formed on the outer surface of silicalite as a skeleton. As a result, a functional structure having cobalt oxide fine particles adhered thereto was obtained. MFI type silicalite was synthesized in the same manner as in Examples 52 to 57 except for the step of adding metal.
  • Comparative Example 2 MFI type silicalite was synthesized by the same method as Comparative Example 1 except that the step of attaching the cobalt oxide fine particles was omitted.
  • the solid acid fine particles were present and retained inside the skeleton composed of silicalite.
  • the silicalite of Comparative Example 1 the solid acid fine particles were only attached to the outer surface of the skeleton, and were not present inside the skeleton.
  • the functional structure in which the solid acid fine particle is ZrOx is cut out by FIB (focused ion beam) processing, and SEM (SU8020, manufactured by Hitachi High-Technologies Corporation), EDX (X-Max, Cross-sectional elemental analysis was performed using HORIBA, Ltd.
  • Zr element was detected from the inside of the skeleton. From the results of cross-sectional observation using the TEM and SEM / EDX, it was confirmed that ZrOx fine particles were present inside the skeleton.
  • iron oxide fine particles of various sizes are randomly present in a particle size range of about 50 nm to 400 nm, whereas the average particle size obtained from the TEM image is 1.2 nm to 2.0 nm.
  • a scattering peak having a particle size of 10 nm or less was detected in the SAXS measurement results. From the SAXS measurement result and the cross-sectional measurement result by SEM / EDX, it was found that a functional substance having a particle size of 10 nm or less was present in a very high dispersion state with a uniform particle size within the skeleton body.
  • M Al, Zr, Zn
  • a functional structure in which a solid acid is included in the skeleton body is prepared, and then the amount of metal (mass%) included in the skeleton body of the functional structure prepared in the above addition amount is measured. did.
  • the amount of metal was determined by using ICP (high frequency inductively coupled plasma) alone or a combination of ICP and XRF (fluorescence X-ray analysis).
  • XRF energy dispersive X-ray fluorescence spectrometer “SEA1200VX”, manufactured by SSI Nanotechnology Inc.
  • SEA1200VX energy dispersive X-ray fluorescence spectrometer “SEA1200VX”, manufactured by SSI Nanotechnology Inc.
  • the product gas analyzer includes TRACE 13 10GC (manufactured by Thermo Fisher Scientific Co., Ltd., detector: thermal conductivity detector), and the product liquid analyzer is TRACE DSQ (manufactured by Thermo Fisher Scientific Co., Ltd., detector: mass detector, Ionization method: EI (ion source temperature 250 ° C., MS transfer line temperature 320 ° C., detector: thermal conductivity detector)) was used.
  • the yield of compounds having a lower molecular weight than butylbenzene (specifically, benzene, toluene, ethylbenzene, styrene, cumene, methane, ethane, ethylene, propane, propylene, butane, butene, etc.) (Mol%) was determined.
  • the yield of the above compound is expressed as a percentage (mol%) of the total amount (mol) of a compound having a molecular weight smaller than that of butylbenzene contained in the product solution with respect to the amount (mol) of butylbenzene before the start of the reaction. Calculated.
  • the yield of the compound having a molecular weight smaller than that of butylbenzene contained in the product solution is 40 mol% or more, it is determined that the catalytic activity (resolution) is excellent, and “ ⁇ ”, 25 mol%
  • the catalyst activity is good, the catalyst activity is good when it is less than 40 mol%, and when the catalyst activity is not good, the pass level is acceptable.
  • the catalyst activity was judged to be inferior (impossible), and “x” was assigned.
  • the yield (mol%) of a compound having a molecular weight smaller than that of butylbenzene was determined in the same manner as in the evaluation (1). And how much the yield of the said compound by the functional structure after a heating is maintained with respect to the yield of the said compound by the functional structure before a heating (yield calculated
  • the yield of the compound by the functional structure after heating is the yield of the compound by the functional structure before heating (Evaluation (1)).
  • the case where 80% or more is maintained compared to the obtained yield) is judged to be excellent in durability (heat resistance), and “ ⁇ ”, the case where 60% or more and less than 80% are maintained is durable.
  • Judgment is good (heat resistance), " ⁇ ”, if it is maintained at 40% or more and less than 60%, the durability (heat resistance) is not good, but it is judged as acceptable level (possible) In this case, it was judged that the durability (heat resistance) was inferior (impossible) and was evaluated as “x”.
  • Reference Example 1 For Reference Example 1, the same performance evaluation as in the evaluations (1) and (2) was performed. Reference Example 1 is a skeleton itself and does not have solid acid fine particles. Therefore, in the performance evaluation, only the skeleton of Reference Example 1 was filled instead of the functional structure. The results are shown in Table 6.
  • the evaluation method was the same as the evaluation method performed in “(1) Catalytic activity” in [D] “Performance evaluation”.
  • the yield of the compound having a molecular weight smaller than that of butylbenzene contained in the product liquid is 32 mol% or more, and butyl It was found that the catalytic activity in the decomposition reaction of benzene was above the acceptable level.
  • Comparative Example 1 in which the solid acid fine particles are attached only to the outer surface of the skeleton body has a butylbenzene structure as compared with the skeleton body of Comparative Example 2 that does not have any solid acid fine particles.
  • the catalytic activity in the decomposition reaction was improved, the durability as a catalyst was inferior to the functional structures of Examples 1 to 288.

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Abstract

L'invention concerne une structure fonctionnelle qui supprime la dégradation fonctionnelle et peut ainsi atteindre une longue durée de vie, qui ne nécessite pas de travail de remplacement compliqué, et qui permet d'économiser des ressources. Une structure fonctionnelle (1) qui comprend: un squelette qui a une structure poreuse qui est configurée à partir d'un composé de type zéolite; et au moins un acide solide qui est à l'intérieur du squelette. Le squelette comporte des passages qui communiquent les uns avec les autres, et l'acide solide se trouve dans au moins les passages du squelette.
PCT/JP2018/021081 2017-05-31 2018-05-31 Structure fonctionnelle et procédé de production de structure fonctionnelle Ceased WO2018221693A1 (fr)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3892604A4 (fr) * 2018-12-03 2022-08-17 Furukawa Electric Co., Ltd. Dispositif de production de gaz contenant des oléfines légères et procédé de production de gaz contenant des oléfines légères

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7352909B2 (ja) 2017-05-31 2023-09-29 国立大学法人北海道大学 機能性構造体及び機能性構造体の製造方法
EP3632555A4 (fr) 2017-05-31 2021-01-27 Furukawa Electric Co., Ltd. Structure de catalyseur d'hydrodésulfuration, dispositif d'hydrodésulfuration pourvu de ladite structure de catalyseur et procédé de production d'une structure de catalyseur d'hydrodésulfuration
WO2018221690A1 (fr) 2017-05-31 2018-12-06 国立大学法人北海道大学 Structure fonctionnelle et procédé de production pour structure fonctionnelle
EP3632542A4 (fr) 2017-05-31 2021-01-06 Furukawa Electric Co., Ltd. Structure de catalyseur de conversion directe ou inverse et procédé de production de celle-ci, dispositif de réaction directe ou inverse, procédé de production de dioxyde de carbone et d'hydrogène, et procédé de production de monoxyde de carbone et d'eau
WO2018221691A1 (fr) 2017-05-31 2018-12-06 国立大学法人北海道大学 Structure fonctionnelle et procédé de production de structure fonctionnelle
JP7269169B2 (ja) 2017-05-31 2023-05-08 古河電気工業株式会社 メタノール改質触媒構造体、メタノール改質用装置、メタノール改質触媒構造体の製造方法及びオレフィンまたは芳香族炭化水素の少なくとも一方の製造方法
JP7328145B2 (ja) 2017-05-31 2023-08-16 古河電気工業株式会社 水蒸気改質用触媒構造体、該水蒸気改質用触媒構造体を備える改質装置、及び水蒸気改質用触媒構造体の製造方法
WO2018221696A1 (fr) 2017-05-31 2018-12-06 古河電気工業株式会社 Structure de catalyseur d'oxydation pour purification de gaz d'échappement et son procédé de production, dispositif de traitement de gaz d'échappement pour véhicule, corps moulé de catalyseur et procédé de purification de gaz.
CN110730687A (zh) 2017-05-31 2020-01-24 古河电气工业株式会社 催化裂化用或加氢脱硫用催化剂结构体、具有该催化剂结构体的催化裂化装置以及加氢脱硫装置、以及催化裂化用或加氢脱硫用催化剂结构体的制造方法
CN113164944A (zh) * 2018-12-03 2021-07-23 国立大学法人北海道大学 功能性结构体
EP3892376A4 (fr) 2018-12-03 2022-09-07 National University Corporation Hokkaido University Structure fonctionnelle

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57376B2 (fr) 1972-08-23 1982-01-06
JPH1133412A (ja) * 1997-07-23 1999-02-09 Unitika Ltd 金属担持触媒の製造方法
JP2000511107A (ja) * 1996-05-29 2000-08-29 エクソン・ケミカル・パテンツ・インク 金属含有ゼオライト触媒、その製造、及び炭化水素の転化のための使用
JP2002255537A (ja) * 2001-02-22 2002-09-11 National Institute Of Advanced Industrial & Technology 固体酸触媒
US20030109383A1 (en) 2001-12-06 2003-06-12 Kazuhiko Koike Ceramic catalyst body
WO2007023558A1 (fr) * 2005-08-26 2007-03-01 Suminoe Textile Co., Ltd. Photo-catalyseur à l'oxyde de tungstène, son procédé de production et tissu de fibres ayant une fonction de désodorisation/antisalissure
WO2009096548A1 (fr) * 2008-02-01 2009-08-06 Shimadzu System Solutions Co., Ltd. Matériau adsorbant/décomposant un complexe argent - (oxyde de titane) - zéolite et son procédé de fabrication
WO2010097108A1 (fr) * 2009-02-27 2010-09-02 Haldor Topsøe A/S Procédé de préparation de zéolithe hybride ou de matériaux de type zéolithe
JP4879574B2 (ja) 2005-09-16 2012-02-22 旭化成ケミカルズ株式会社 エチレン及びプロピレンの製造方法
WO2012105581A1 (fr) * 2011-02-02 2012-08-09 ソニー株式会社 Procédé pour produire une couche d'oxyde semi-conducteur
JP2012170951A (ja) * 2011-02-24 2012-09-10 Kyushu Univ 光触媒−吸着材複合粉体
JP2015165138A (ja) * 2015-04-30 2015-09-17 日野自動車株式会社 排ガス浄化装置
US20160030934A1 (en) 2009-07-01 2016-02-04 Chevron U.S.A. Inc. Hydroprocessing catalyst and hydroprocessing catalyst of making the same
JP2016069318A (ja) * 2014-09-30 2016-05-09 国立大学法人山口大学 第二級アルコールの保管方法および充填体
JP2016529190A (ja) * 2013-07-05 2016-09-23 ダンマークス・テクニスケ・ユニヴェルシテット ゼオライト及びゼオ型を製造する方法
CN106362787A (zh) * 2016-08-06 2017-02-01 浙江大学 一种沸石固载光催化剂的制备方法
JP2017128480A (ja) * 2016-01-20 2017-07-27 日揮触媒化成株式会社 金属粒子を内包したゼオライト

Family Cites Families (104)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3898180A (en) 1970-07-23 1975-08-05 Ici Ltd Catalyst pellet
JPS5746925A (en) 1980-09-03 1982-03-17 Res Assoc Petroleum Alternat Dev<Rapad> Preparation of hydrocarbon
US4552855A (en) * 1982-12-30 1985-11-12 Ozin Geoffrey A Metal zeolite catalyst preparation
US5026673A (en) 1989-06-23 1991-06-25 University Of Delaware Stable zeolite-supported transition metal catalysts, methods for making them, and uses thereof
JP2771321B2 (ja) 1990-11-09 1998-07-02 日本碍子株式会社 排気ガス浄化用触媒組成物、排気ガス浄化用触媒及びその製造方法
US5275720A (en) 1990-11-30 1994-01-04 Union Oil Company Of California Gasoline hydrocracking catalyst and process
US5236575A (en) 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
JPH0549943A (ja) * 1991-08-20 1993-03-02 Sakai Chem Ind Co Ltd 酸化触媒
JPH06142456A (ja) 1992-11-08 1994-05-24 Sekiyu Sangyo Kasseika Center 排ガス中の窒素酸化物の除去方法
JPH0796195A (ja) 1993-09-29 1995-04-11 Hino Motors Ltd 排ガス浄化触媒
JP2006021994A (ja) 1993-12-28 2006-01-26 Toto Ltd 光触媒機能を有する多機能材の製造方法
US5849652A (en) * 1994-03-14 1998-12-15 Northeastern University Metal containing catalysts and methods for making same
JPH08155303A (ja) 1994-12-01 1996-06-18 Toyota Central Res & Dev Lab Inc 排ガス浄化用触媒担体と排ガス浄化用触媒及び排ガス浄化用触媒担体の製造方法ならびに排ガス浄化方法
WO1997045387A1 (fr) 1996-05-29 1997-12-04 Exxon Chemical Patents Inc. Methylation de toluene en para-xylene
CN1223602A (zh) 1996-05-29 1999-07-21 埃克森化学专利公司 含金属的沸石催化剂,其制备方法及其在烃转化中的应用
JPH11151440A (ja) 1997-07-18 1999-06-08 Tokyo Gas Co Ltd 窒素酸化物の分解除去用触媒及び窒素酸化物の分解除去方法
JP2000197822A (ja) 1999-01-08 2000-07-18 Tokyo Gas Co Ltd 窒素酸化物の分解除去用触媒及び窒素酸化物の分解除去方法
JP3897143B2 (ja) 1999-05-11 2007-03-22 富士電機ホールディングス株式会社 改質装置とその起動方法及び燃料電池発電装置
US6930219B2 (en) 1999-09-07 2005-08-16 Abb Lummus Global Inc. Mesoporous material with active metals
US7074373B1 (en) 2000-11-13 2006-07-11 Harvest Energy Technology, Inc. Thermally-integrated low temperature water-gas shift reactor apparatus and process
FR2819432B1 (fr) 2001-01-18 2003-04-11 Rhodia Chimie Sa Catalyseur mesostructure integrant des particules de dimensions nanometriques
JP2002336704A (ja) 2001-05-18 2002-11-26 Masaru Ichikawa メタンの芳香族化反応触媒およびその調製方法
US6881703B2 (en) 2001-08-08 2005-04-19 Corning Incorporated Thermally conductive honeycombs for chemical reactors
EP1572579A2 (fr) 2002-12-20 2005-09-14 Honda Giken Kogyo Kabushiki Kaisha De nickel exemptes de metaux nobles, destinees a la generation d'hydrogene
JP2005170903A (ja) 2003-12-15 2005-06-30 Idemitsu Kosan Co Ltd ビシクロ［２．２．１］ヘプタン誘導体の製造方法
JP4334336B2 (ja) 2003-12-26 2009-09-30 株式会社フジクラ 光スイッチ
WO2005083013A1 (fr) 2004-01-30 2005-09-09 Millennium Chemicals Composition de revetement presentant des proprietes de depollution de surface
JP4469975B2 (ja) 2004-03-23 2010-06-02 国立大学法人広島大学 光触媒複合体およびこれを用いた有機物質変換方法
JP5194249B2 (ja) 2004-03-29 2013-05-08 国立大学法人広島大学 複合多孔体およびその製造方法、並びにこれを用いた有機物質変換方法
WO2006002116A2 (fr) 2004-06-17 2006-01-05 Yale University Agregats de metaux de transition a dimensions reglables dans mcm-41 pour ameliorer des catalyseurs chimiques
CN103059899A (zh) 2005-03-16 2013-04-24 弗尔科有限责任公司 用于生产合成烃化合物的系统、方法及组合物
EP1866083B1 (fr) 2005-03-24 2021-06-30 University of Regina Catalyseur contentant du Nickel déposé sur un support Ceria/Zirconia.
FR2886636B1 (fr) 2005-06-02 2007-08-03 Inst Francais Du Petrole Materiau inorganique presentant des nanoparticules metalliques piegees dans une matrice mesostructuree
CN100392047C (zh) 2005-06-09 2008-06-04 中国科学院大连化学物理研究所 一种石油烃类催化氧化裂解制烯烃的方法
CN100574882C (zh) 2005-06-29 2009-12-30 揖斐电株式会社 蜂窝结构体
MXPA05009283A (es) 2005-08-31 2007-02-27 Mexicano Inst Petrol Procedimiento para la preparacion de una composicion catalitica para el hidroprocesamiento de fracciones del petroleo.
EP1935865B1 (fr) 2005-09-16 2016-11-16 Asahi Kasei Kabushiki Kaisha Procede pour produire de l'ethylene et du propylene
JP2007130525A (ja) 2005-11-08 2007-05-31 Nissan Motor Co Ltd 包接触媒及びその製造方法
JP5076377B2 (ja) 2006-07-03 2012-11-21 トヨタ自動車株式会社 排ガス浄化触媒
US7879749B2 (en) 2006-08-15 2011-02-01 Battelle Energy Alliance, Llc Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons
US7592291B2 (en) 2006-08-15 2009-09-22 Batelle Energy Alliance, Llc Method of fabricating a catalytic structure
CN101130466B (zh) 2006-08-23 2011-05-04 中国科学院大连化学物理研究所 制取低碳烯烃流态化催化反应装置的开工方法
US8993468B2 (en) 2007-05-24 2015-03-31 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites
CN101362959B (zh) 2007-08-09 2012-09-05 中国石油化工股份有限公司 一种制取丙烯和高辛烷值汽油的催化转化方法
FR2929264B1 (fr) 2008-03-31 2010-03-19 Inst Francais Du Petrole Materiau inorganique forme de particules spheriques de taille specifique et presentant des nanoparticules metalliques piegees dans une matrice mesostructuree
JP2009255014A (ja) 2008-04-21 2009-11-05 Mitsubishi Chemicals Corp メタノールからオレフィンを製造するための触媒
EP2292573B1 (fr) 2008-06-10 2018-01-10 Mitsui Chemicals, Inc. Procédé de fabrication d un composé aromatique alkylé et procédé de fabrication de phénol
JP4639247B2 (ja) 2008-07-23 2011-02-23 石油資源開発株式会社 炭化水素リフォーミング用触媒およびその製造方法ならびにこれを用いた合成ガスの製法
JP2010099638A (ja) 2008-10-27 2010-05-06 Nissan Motor Co Ltd 触媒、排ガス浄化用触媒及び触媒の製造方法
EA019862B1 (ru) 2009-07-30 2014-06-30 Мицубиси Кемикал Корпорейшн Способ получения пропилена и катализатор получения пропилена
JP2012250133A (ja) 2009-09-30 2012-12-20 Toto Ltd 光触媒塗装体およびそのための光触媒コーティング液
EP2505261A4 (fr) 2009-11-27 2013-05-15 Murata Manufacturing Co Catalyseur de réaction anti-conversion catalytique, et procédé de production de gaz synthétique utilisant ce catalyseur
WO2011128968A1 (fr) 2010-04-12 2011-10-20 株式会社メタルテック Matériau de revêtement photocatalytique
US8772529B2 (en) 2010-06-10 2014-07-08 Ube Industries, Ltd Catalyst for alkylation and process for producing alkylaromatic hydrocarbon compound using the catalyst
US20120042631A1 (en) 2010-08-20 2012-02-23 Gm Global Technology Operations, Inc. Catalyst materials for ammonia oxidation in lean-burn engine exhaust
US8539760B2 (en) 2010-09-14 2013-09-24 GM Global Technology Operations LLC Catalyst materials for NOx oxidation in an exhaust aftertreatment system that uses passive ammonia SCR
FR2969513B1 (fr) 2010-12-22 2013-04-12 IFP Energies Nouvelles Procede de preparation d'un materiau spherique a porosite hierarchisee comprenant des particules metalliques piegees dans une matrice mesostructuree
JP5552067B2 (ja) 2011-01-26 2014-07-16 住友ゴム工業株式会社 合成システム、タイヤ用ゴム薬品、タイヤ用合成ゴム及び空気入りタイヤ
BR112012030796A2 (pt) 2011-01-26 2016-11-01 Sumitomo Rubber Iindustries Ltd sistema de síntese, substância química de borracha para pneus, borracha sintética para pneus, e pneumático
JP2012210557A (ja) 2011-03-30 2012-11-01 Panasonic Corp 撥水性光触媒組成物及び撥水性光触媒塗膜
CN102247887B (zh) 2011-05-20 2013-03-06 汕头大学 一种高效低载量甲烷芳构化催化剂的制备方法
KR101938432B1 (ko) 2011-06-05 2019-01-14 존슨 맛쎄이 퍼블릭 리미티드 컴파니 배기 가스를 처리하기 위한 백금족 금속(ｐｇｍ) 촉매
BR112014009541B1 (pt) 2011-10-21 2019-08-06 Igtl Technology Ltd Métodos de preparação e formação de catalisadores e precursores suportados de metal ativo
GB201118228D0 (en) * 2011-10-21 2011-12-07 Ingen Gtl Ltd Methods of preparation and forming supported active metal catalysts and precursors
JP6061872B2 (ja) 2012-01-31 2017-01-18 国立研究開発法人科学技術振興機構 酸化チタンメソ結晶
WO2013123299A1 (fr) 2012-02-17 2013-08-22 Kior, Inc. Catalyseurs contenant une zéolite mésoporeuse pour la conversion thermochimique de biomasse et pour la valorisation de bio-huiles
JP5972678B2 (ja) 2012-06-14 2016-08-17 三菱化学株式会社 合成ガス製造用触媒および合成ガスの製造方法
CN103663490B (zh) 2012-09-26 2016-04-20 中国科学院大连化学物理研究所 一种sapo-34分子筛及其合成方法
US9573121B2 (en) 2012-11-08 2017-02-21 Rive Technology, Inc. Mesoporous zeolite catalyst supports
JP5762386B2 (ja) 2012-11-28 2015-08-12 株式会社日立製作所 シフト触媒、石炭ガス化プラントのガス精製方法及びガス精製設備
WO2014083772A1 (fr) 2012-11-30 2014-06-05 国立大学法人広島大学 Procédé de fabrication de complexe de nanoparticule métallique et complexe de nanoparticule métallique produit par ledit procédé
US10137438B2 (en) 2013-02-09 2018-11-27 Indian Oil Corporation Limited Hydroprocessing catalyst composition and process thereof
WO2014129585A1 (fr) 2013-02-21 2014-08-28 Ｊｘ日鉱日石エネルギー株式会社 Procédé de production d'hydrocarbures aromatiques monocycliques
US20160032202A1 (en) 2013-02-27 2016-02-04 Mitsubishi Heavy Industries, Ltd. Co shift catalyst, co shift reaction apparatus, and method for purifying gasified gas
KR102221550B1 (ko) 2013-03-22 2021-03-02 삼성전자주식회사 탄화수소 개질용 촉매 및 그 제조 방법
EP2992984B1 (fr) 2013-05-01 2020-08-05 University of Yamanashi Procédé de production de particules métalliques fines
CN104650291B (zh) 2013-11-19 2018-02-02 中国石油天然气股份有限公司 采用烯烃复分解催化剂制备补强丁苯橡胶的方法
CN104774639A (zh) 2014-01-13 2015-07-15 通用电气公司 烃类裂解方法和装置
JP6234297B2 (ja) 2014-03-27 2017-11-22 株式会社タカギ ゼオライト成形体およびその製造方法
CN106457229A (zh) * 2014-04-10 2017-02-22 丹麦技术大学 在沸石和类沸石中引入金属纳米粒子的通用方法
JP6303850B2 (ja) 2014-06-18 2018-04-04 株式会社Ihi 触媒の製造方法
US9938157B2 (en) 2014-07-23 2018-04-10 Chevron U.S.A. Inc. Interzeolite transformation and metal encapsulation in the absence of an SDA
JP6604501B2 (ja) 2014-09-16 2019-11-13 国立大学法人山梨大学 アンモニア分解触媒とその製造方法および、これを用いた装置
US9682367B2 (en) 2014-10-22 2017-06-20 King Fahd University Of Petroleum And Minerals Monolith structure loaded with metal promoted nanozeolites for enhanced propylene selectivity in methanol conversion
JP6427387B2 (ja) 2014-10-31 2018-11-21 地方独立行政法人東京都立産業技術研究センター 量子ドット複合光触媒
WO2016181622A1 (fr) 2015-05-12 2016-11-17 日本曹達株式会社 Liquide de revêtement contenant un photocatalyseur et structure support de photocatalyseur
WO2017000427A1 (fr) 2015-07-02 2017-01-05 中国科学院大连化学物理研究所 Catalyseur et procédé de préparation d'oléfine légère directement à partir d'un gaz de synthèse par un procédé en une étape
JP6598576B2 (ja) 2015-08-17 2019-10-30 学校法人東京理科大学 積層体及び積層体の製造方法
JP6489990B2 (ja) 2015-09-30 2019-03-27 Ｊｘｔｇエネルギー株式会社 炭化水素油の水素化脱硫触媒およびその製造方法
CN108136379A (zh) 2015-10-30 2018-06-08 沙特基础工业全球技术公司 双金属或三金属颗粒掺杂的中空沸石用于烃重整反应的用途
CN105347359B (zh) * 2015-11-27 2017-10-03 中国石油大学(北京) 一种孔道内含固体酸的沸石分子筛的合成及其应用
EP3632555A4 (fr) 2017-05-31 2021-01-27 Furukawa Electric Co., Ltd. Structure de catalyseur d'hydrodésulfuration, dispositif d'hydrodésulfuration pourvu de ladite structure de catalyseur et procédé de production d'une structure de catalyseur d'hydrodésulfuration
WO2018221691A1 (fr) 2017-05-31 2018-12-06 国立大学法人北海道大学 Structure fonctionnelle et procédé de production de structure fonctionnelle
JP7328145B2 (ja) 2017-05-31 2023-08-16 古河電気工業株式会社 水蒸気改質用触媒構造体、該水蒸気改質用触媒構造体を備える改質装置、及び水蒸気改質用触媒構造体の製造方法
WO2018221696A1 (fr) 2017-05-31 2018-12-06 古河電気工業株式会社 Structure de catalyseur d'oxydation pour purification de gaz d'échappement et son procédé de production, dispositif de traitement de gaz d'échappement pour véhicule, corps moulé de catalyseur et procédé de purification de gaz.
CN110730687A (zh) 2017-05-31 2020-01-24 古河电气工业株式会社 催化裂化用或加氢脱硫用催化剂结构体、具有该催化剂结构体的催化裂化装置以及加氢脱硫装置、以及催化裂化用或加氢脱硫用催化剂结构体的制造方法
JP7269169B2 (ja) 2017-05-31 2023-05-08 古河電気工業株式会社 メタノール改質触媒構造体、メタノール改質用装置、メタノール改質触媒構造体の製造方法及びオレフィンまたは芳香族炭化水素の少なくとも一方の製造方法
WO2018221704A1 (fr) 2017-05-31 2018-12-06 古河電気工業株式会社 Structure de catalyseur pour la production d'hydrocarbures aromatiques, dispositif de production d'hydrocarbures aromatiques pourvu de ladite structure de catalyseur pour la production d'hydrocarbures aromatiques, procédé de production d'une structure de catalyseur pour la production d'hydrocarbures aromatiques, et procédé de production d'hydrocarbures aromatiques
US11161101B2 (en) 2017-05-31 2021-11-02 Furukawa Electric Co., Ltd. Catalyst structure and method for producing the catalyst structure
EP3632542A4 (fr) 2017-05-31 2021-01-06 Furukawa Electric Co., Ltd. Structure de catalyseur de conversion directe ou inverse et procédé de production de celle-ci, dispositif de réaction directe ou inverse, procédé de production de dioxyde de carbone et d'hydrogène, et procédé de production de monoxyde de carbone et d'eau
JP7352909B2 (ja) 2017-05-31 2023-09-29 国立大学法人北海道大学 機能性構造体及び機能性構造体の製造方法
JPWO2018221702A1 (ja) 2017-05-31 2020-03-26 古河電気工業株式会社 光触媒構造体、光触媒構造体組成物、光触媒被覆材、光触媒構造体の製造方法及びアルデヒド類の分解方法
WO2018221690A1 (fr) 2017-05-31 2018-12-06 国立大学法人北海道大学 Structure fonctionnelle et procédé de production pour structure fonctionnelle
US11590483B2 (en) 2017-09-29 2023-02-28 President And Fellows Of Harvard College Enhanced catalytic materials with partially embedded catalytic nanoparticles

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57376B2 (fr) 1972-08-23 1982-01-06
JP2000511107A (ja) * 1996-05-29 2000-08-29 エクソン・ケミカル・パテンツ・インク 金属含有ゼオライト触媒、その製造、及び炭化水素の転化のための使用
JPH1133412A (ja) * 1997-07-23 1999-02-09 Unitika Ltd 金属担持触媒の製造方法
JP2002255537A (ja) * 2001-02-22 2002-09-11 National Institute Of Advanced Industrial & Technology 固体酸触媒
US20030109383A1 (en) 2001-12-06 2003-06-12 Kazuhiko Koike Ceramic catalyst body
WO2007023558A1 (fr) * 2005-08-26 2007-03-01 Suminoe Textile Co., Ltd. Photo-catalyseur à l'oxyde de tungstène, son procédé de production et tissu de fibres ayant une fonction de désodorisation/antisalissure
JP4879574B2 (ja) 2005-09-16 2012-02-22 旭化成ケミカルズ株式会社 エチレン及びプロピレンの製造方法
WO2009096548A1 (fr) * 2008-02-01 2009-08-06 Shimadzu System Solutions Co., Ltd. Matériau adsorbant/décomposant un complexe argent - (oxyde de titane) - zéolite et son procédé de fabrication
WO2010097108A1 (fr) * 2009-02-27 2010-09-02 Haldor Topsøe A/S Procédé de préparation de zéolithe hybride ou de matériaux de type zéolithe
US20160030934A1 (en) 2009-07-01 2016-02-04 Chevron U.S.A. Inc. Hydroprocessing catalyst and hydroprocessing catalyst of making the same
WO2012105581A1 (fr) * 2011-02-02 2012-08-09 ソニー株式会社 Procédé pour produire une couche d'oxyde semi-conducteur
JP2012170951A (ja) * 2011-02-24 2012-09-10 Kyushu Univ 光触媒−吸着材複合粉体
JP2016529190A (ja) * 2013-07-05 2016-09-23 ダンマークス・テクニスケ・ユニヴェルシテット ゼオライト及びゼオ型を製造する方法
JP2016069318A (ja) * 2014-09-30 2016-05-09 国立大学法人山口大学 第二級アルコールの保管方法および充填体
JP2015165138A (ja) * 2015-04-30 2015-09-17 日野自動車株式会社 排ガス浄化装置
JP2017128480A (ja) * 2016-01-20 2017-07-27 日揮触媒化成株式会社 金属粒子を内包したゼオライト
CN106362787A (zh) * 2016-08-06 2017-02-01 浙江大学 一种沸石固载光催化剂的制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3892604A4 (fr) * 2018-12-03 2022-08-17 Furukawa Electric Co., Ltd. Dispositif de production de gaz contenant des oléfines légères et procédé de production de gaz contenant des oléfines légères
US11925930B2 (en) 2018-12-03 2024-03-12 Furukawa Electric Co., Ltd. Apparatus for producing lower olefin-containing gas and method for producing lower olefin-containing gas

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