[go: up one dir, main page]

WO2018132247A3 - Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci - Google Patents

Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci Download PDF

Info

Publication number
WO2018132247A3
WO2018132247A3 PCT/US2017/068158 US2017068158W WO2018132247A3 WO 2018132247 A3 WO2018132247 A3 WO 2018132247A3 US 2017068158 W US2017068158 W US 2017068158W WO 2018132247 A3 WO2018132247 A3 WO 2018132247A3
Authority
WO
WIPO (PCT)
Prior art keywords
indenyl
production
metal complexes
catalysts
transitional metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2017/068158
Other languages
English (en)
Other versions
WO2018132247A2 (fr
Inventor
Jian Yang
Xiongdong Lian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to EP17891908.0A priority Critical patent/EP3568418A4/fr
Publication of WO2018132247A2 publication Critical patent/WO2018132247A2/fr
Publication of WO2018132247A3 publication Critical patent/WO2018132247A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La présente invention concerne des catalyseurs métallocènes pontés qui comprennent au moins un ligand indényle substitué en position 2 par un alkyle ramifié C3-C10, tel que l'isopropyle. L'invention concerne également des systèmes de catalyseur comprenant les catalyseurs, des procédés de polymérisation utilisant les catalyseurs, et des polymères fabriqués à l'aide des catalyseurs.
PCT/US2017/068158 2017-01-13 2017-12-22 Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci Ceased WO2018132247A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP17891908.0A EP3568418A4 (fr) 2017-01-13 2017-12-22 Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201762446007P 2017-01-13 2017-01-13
US62/446,007 2017-01-13
EP17162056.0 2017-03-21
EP17162056 2017-03-21

Publications (2)

Publication Number Publication Date
WO2018132247A2 WO2018132247A2 (fr) 2018-07-19
WO2018132247A3 true WO2018132247A3 (fr) 2018-08-30

Family

ID=58412886

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2017/068158 Ceased WO2018132247A2 (fr) 2017-01-13 2017-12-22 Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci

Country Status (1)

Country Link
WO (1) WO2018132247A2 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3976669A1 (fr) 2019-05-29 2022-04-06 Borealis AG Préparation améliorée d'un système de catalyseur
WO2025016933A1 (fr) * 2023-07-14 2025-01-23 Borealis Ag Préparation d'un système catalyseur supporté

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002583A2 (fr) * 2001-06-29 2003-01-09 Exxonmobil Chemical Patents Inc. Metallocenes et compositions catalytiques derives de ceux-ci
US20100113717A1 (en) * 2004-12-16 2010-05-06 Voskoboynikov Alexander Z Process For Producing Substituted Metallocene Compounds For Olefin Polymerization
WO2014070655A1 (fr) * 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Systèmes catalytiques à base de métallocène supporté et procédés pour les préparer
WO2015009471A1 (fr) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Métallocènes et compositions catalytiques dérivées de ceux-ci
WO2016196331A1 (fr) * 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Systèmes de catalyseurs métallocènes supportés pour polymérisation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002583A2 (fr) * 2001-06-29 2003-01-09 Exxonmobil Chemical Patents Inc. Metallocenes et compositions catalytiques derives de ceux-ci
US20100113717A1 (en) * 2004-12-16 2010-05-06 Voskoboynikov Alexander Z Process For Producing Substituted Metallocene Compounds For Olefin Polymerization
WO2014070655A1 (fr) * 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Systèmes catalytiques à base de métallocène supporté et procédés pour les préparer
WO2015009471A1 (fr) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Métallocènes et compositions catalytiques dérivées de ceux-ci
WO2016196331A1 (fr) * 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Systèmes de catalyseurs métallocènes supportés pour polymérisation

Also Published As

Publication number Publication date
WO2018132247A2 (fr) 2018-07-19

Similar Documents

Publication Publication Date Title
WO2018236863A8 (fr) Catalyseurs biarylphénoxy à métal de transition du groupe iv pour la polymérisation d'oléfines
WO2012098521A8 (fr) Complexes métalliques de ligands de type salan et leurs utilisations comme catalyseurs pour la polymérisation d'alpha-oléfines
WO2014022010A3 (fr) Catalyseurs non symétriques comprenant des ligands salan
WO2013028283A8 (fr) Systèmes de catalyseur et leurs procédés d'utilisation pour la production de produits de polyoléfine
WO2001044324A3 (fr) Polymerisation d'olefines
MX2010004418A (es) Compuestos de metaloceno, catalizadores que comprenden los mismos, proceso para producir un polimero de olefina mediante el uso de los catalizadores y homo- y copolimeros de olefina.
WO2015123168A8 (fr) Production de produits de polyoléfines
EA033278B1 (ru) СПОСОБ ПОЛУЧЕНИЯ ТВЕРДОГО КОМПОНЕНТА КАТАЛИЗАТОРА НА ПОДЛОЖКЕ MgCl
WO2016168788A3 (fr) Passerelle de communication conteneurisée
WO2002088201A8 (fr) Procede de preparation de systemes catalyseurs de metaux de transition a supports et systemes catalyseurs prepares selon ce procede
EA201590682A1 (ru) Способ полимеризации и катализатор
ATE236182T1 (de) Katalysatorkomponente die mindestens einen phosphinimine-liganden und einen heteroatom- liganden enthält
ATE394431T1 (de) Polymerisationskatalysatoren, herstellung von polyolefinen, organoübergangsmetallverbindungen und liganden
EP3865516A4 (fr) Composé de métal de transition pour catalyseur de polymérisation d'oléfines, et catalyseur de polymérisation d'oléfines le comprenant
MX2018003414A (es) Catalizadores de ziegler-natta heterogeneos con alumina revestida de silice fluorada.
WO2018132247A3 (fr) Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci
WO2010036025A3 (fr) Systèmes catalytiques à métal de transition et procédés de préparation d'homopolymères d'éthylène ou de copolymères d'éthylène et d'α-oléfines utilisant ceux-ci
WO2011056423A3 (fr) Composés catalytiques et leur utilisation
WO2019067274A8 (fr) Catalyseurs de type bis-phényl-phénoxy-polyoléfine ayant deux ligands de type méthylènetrialkylsilicium sur le métal pour une solubilité améliorée
WO2015077100A3 (fr) Systèmes de catalyseur à base de bis-indényl-métallocène à pont boré et polymères produits à partir de ceux-ci
WO2012109012A3 (fr) Composition de catalyseur de ziegler-natta ayant une morphologie contrôlée
WO2018175277A8 (fr) Polymères à base d'éthylène à optique améliorée
WO2011056431A8 (fr) Composés catalyseurs et application associée
WO2018064044A3 (fr) Catalyseurs de polymérisation ayant un meilleur enchaînement des unités éthylène
WO2017189120A8 (fr) Activateurs à base d'organoaluminium sur des argiles

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17891908

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2017891908

Country of ref document: EP

Effective date: 20190813