[go: up one dir, main page]

WO2018132247A3 - Bridged bis(indenyl) transitional metal complexes, production, and use thereof - Google Patents

Bridged bis(indenyl) transitional metal complexes, production, and use thereof Download PDF

Info

Publication number
WO2018132247A3
WO2018132247A3 PCT/US2017/068158 US2017068158W WO2018132247A3 WO 2018132247 A3 WO2018132247 A3 WO 2018132247A3 US 2017068158 W US2017068158 W US 2017068158W WO 2018132247 A3 WO2018132247 A3 WO 2018132247A3
Authority
WO
WIPO (PCT)
Prior art keywords
indenyl
production
metal complexes
catalysts
transitional metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2017/068158
Other languages
French (fr)
Other versions
WO2018132247A2 (en
Inventor
Jian Yang
Xiongdong Lian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to EP17891908.0A priority Critical patent/EP3568418A4/en
Publication of WO2018132247A2 publication Critical patent/WO2018132247A2/en
Publication of WO2018132247A3 publication Critical patent/WO2018132247A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

The present disclosure relates to bridged metallocene catalysts that include at least one indenyl ligand substituted at the 2-position with a C3-C10 branched alkyl, such as isopropyl. Catalyst systems including the catalysts, polymerization processes using the catalysts, and polymers made using the catalysts are also described.
PCT/US2017/068158 2017-01-13 2017-12-22 Bridged bis(indenyl) transitional metal complexes, production, and use thereof Ceased WO2018132247A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP17891908.0A EP3568418A4 (en) 2017-01-13 2017-12-22 Bridged bis(indenyl) transitional metal complexes, production, and use thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201762446007P 2017-01-13 2017-01-13
US62/446,007 2017-01-13
EP17162056.0 2017-03-21
EP17162056 2017-03-21

Publications (2)

Publication Number Publication Date
WO2018132247A2 WO2018132247A2 (en) 2018-07-19
WO2018132247A3 true WO2018132247A3 (en) 2018-08-30

Family

ID=58412886

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2017/068158 Ceased WO2018132247A2 (en) 2017-01-13 2017-12-22 Bridged bis(indenyl) transitional metal complexes, production, and use thereof

Country Status (1)

Country Link
WO (1) WO2018132247A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114127129B (en) 2019-05-29 2024-07-30 博里利斯股份公司 Improved preparation of catalyst systems
WO2025016933A1 (en) * 2023-07-14 2025-01-23 Borealis Ag Preparation of a supported catalyst system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002583A2 (en) * 2001-06-29 2003-01-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US20100113717A1 (en) * 2004-12-16 2010-05-06 Voskoboynikov Alexander Z Process For Producing Substituted Metallocene Compounds For Olefin Polymerization
WO2014070655A1 (en) * 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems and methods of preparation thereof
WO2015009471A1 (en) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2016196331A1 (en) * 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002583A2 (en) * 2001-06-29 2003-01-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US20100113717A1 (en) * 2004-12-16 2010-05-06 Voskoboynikov Alexander Z Process For Producing Substituted Metallocene Compounds For Olefin Polymerization
WO2014070655A1 (en) * 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems and methods of preparation thereof
WO2015009471A1 (en) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2016196331A1 (en) * 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization

Also Published As

Publication number Publication date
WO2018132247A2 (en) 2018-07-19

Similar Documents

Publication Publication Date Title
WO2018236863A8 (en) Biaryl phenoxy group iv transition metal catalysts for olefin polymerization
WO2014022010A3 (en) Non-symmetric catalysts comprising salan ligands
WO2013028283A8 (en) Catalyst systems and methods for using same to produce polyolefin products
WO2001044324A3 (en) Polymerization of olefins
MX2010004418A (en) Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo-and copolymers.
WO2015123168A8 (en) Producing polyolefin products
EA033278B1 (en) METHOD FOR PRODUCING SOLID MgClSUPPORTED CATALYST COMPONENT
WO2016168788A3 (en) Containerized communications gateway
MX2018002229A (en) Ziegler-natta - metallocene dual catalyst systems with activator-supports.
WO2002088201A8 (en) Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
EA201590682A1 (en) METHOD OF POLYMERIZATION AND CATALYST
ATE236182T1 (en) CATALYST COMPONENT THAT CONTAINS AT LEAST ONE PHOSPHINIMINE LIGAND AND ONE HETEROATOM LIGAND
MX2018003413A (en) Heterogeneous ziegler-natta catalysts with fluorided silica-coated alumina.
ATE394431T1 (en) POLYMERIZATION CATALYSTS, PRODUCTION OF POLYOLEFINS, ORGANO TRANSITION METAL COMPOUNDS AND LIGANDS
EP3865516A4 (en) TRANSITION METAL COMPOUND FOR OLEFIN POLYMERIZATION CATALYST, AND OLEFIN POLYMERIZATION CATALYST COMPRISING THE SAME
MX2018003414A (en) Heterogeneous ziegler-natta catalysts with fluorided silica-coated alumina.
WO2018132247A3 (en) Bridged bis(indenyl) transitional metal complexes, production, and use thereof
WO2010036025A3 (en) TRANSITION METAL CATALYTIC SYSTEMS AND METHODS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND α- OLEFINS USING THE SAME.
WO2011056423A3 (en) Catalyst compounds and use thereof
WO2019078653A3 (en) Modified conjugated diene-based polymer and method for preparing same
WO2019067274A8 (en) Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility
WO2015077100A3 (en) Boron-bridged bis-indenyl metallocene catalyst systems and polymers produced therefrom
WO2012109012A3 (en) Ziegler-natta catalyst composition with controlled morphology
WO2018175277A8 (en) Ethylene-based polymers with improved optics
WO2018064044A3 (en) Polymerization catalysts with improved ethylene enchainment

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17891908

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2017891908

Country of ref document: EP

Effective date: 20190813