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WO2018056869A3 - Method for deactivating radioactive ion-exchange resins - Google Patents

Method for deactivating radioactive ion-exchange resins Download PDF

Info

Publication number
WO2018056869A3
WO2018056869A3 PCT/RU2017/000699 RU2017000699W WO2018056869A3 WO 2018056869 A3 WO2018056869 A3 WO 2018056869A3 RU 2017000699 W RU2017000699 W RU 2017000699W WO 2018056869 A3 WO2018056869 A3 WO 2018056869A3
Authority
WO
WIPO (PCT)
Prior art keywords
ion
exchange resins
radioactive
deactivating
ier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/RU2017/000699
Other languages
French (fr)
Russian (ru)
Other versions
WO2018056869A2 (en
Inventor
Виктор Павлович РЕМЕЗ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eksorb Ltd
Original Assignee
Eksorb Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eksorb Ltd filed Critical Eksorb Ltd
Publication of WO2018056869A2 publication Critical patent/WO2018056869A2/en
Publication of WO2018056869A3 publication Critical patent/WO2018056869A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04Treating liquids
    • G21F9/06Processing
    • G21F9/12Processing by absorption; by adsorption; by ion-exchange

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention "Method for deactivating radioactive ion-exchange resins" relates to the field of radioactive waste treatment, and more particularly to the deactivation of spent ion-exchange resins (IER). The technical result of this invention consists in completely deactivating ion-exchange resins and minimizing the quantity of secondary radioactive waste that is formed. The technical result of the claimed invention is achieved in that spent radioactive ion-exchange resins are treated with solutions of alkali metal salts having a concentration of from 3 to 5 moles/liter and a pH of from 8 to 12, with the addition of an oxidizing agent as the IERs are simultaneously exposed to ultrasonic oscillations with an intensity of from 2 to 5 W/cm2 and a frequency of from 22 to 44 kHz at a temperature of from 50 to 80°С. The radioactive solution formed upon desorption is purified by selective sorbents placed in filtration columns. The deactivated ion-exchange resin is transferred to an industrial waste disposal site, and the deactivating solution, which is purified with selective sorbents, is sent, once its composition has been corrected, for re-use, i.e. for removing radionuclides from the next batch of IER.
PCT/RU2017/000699 2016-09-22 2017-09-22 Method for deactivating radioactive ion-exchange resins Ceased WO2018056869A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2016137930 2016-09-22
RU2016137930A RU2631942C1 (en) 2016-09-22 2016-09-22 Method of deactivating radioactive ion-exchange resins

Publications (2)

Publication Number Publication Date
WO2018056869A2 WO2018056869A2 (en) 2018-03-29
WO2018056869A3 true WO2018056869A3 (en) 2018-06-14

Family

ID=60040819

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2017/000699 Ceased WO2018056869A2 (en) 2016-09-22 2017-09-22 Method for deactivating radioactive ion-exchange resins

Country Status (2)

Country Link
RU (1) RU2631942C1 (en)
WO (1) WO2018056869A2 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4389253A (en) * 1980-10-30 1983-06-21 Hitachi, Ltd. Process for removing crud from ion exchange resin
US4401591A (en) * 1980-01-31 1983-08-30 Asea Aktiebolag Treatment of organic ion exchange material containing radioactive waste products

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3849196A (en) * 1970-05-20 1974-11-19 Gen Electric Ultrasonic cleaning of resin
DE2607292C2 (en) * 1976-02-23 1985-08-29 Kraftwerk Union AG, 4330 Mülheim Process for the removal of radioactive corrosion products from ion exchange resins used in nuclear reactor operation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4401591A (en) * 1980-01-31 1983-08-30 Asea Aktiebolag Treatment of organic ion exchange material containing radioactive waste products
US4389253A (en) * 1980-10-30 1983-06-21 Hitachi, Ltd. Process for removing crud from ion exchange resin

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A. D. ZIMON: "Desaktivatsiya", vol. 336, 1994, IZDAT, Moscow, pages: 167 - 175 *

Also Published As

Publication number Publication date
RU2631942C1 (en) 2017-09-29
WO2018056869A2 (en) 2018-03-29

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