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WO2017200036A1 - Agent exfoliant, et composition pour agent de nettoyage de la peau comprenant cet agent exfoliant - Google Patents

Agent exfoliant, et composition pour agent de nettoyage de la peau comprenant cet agent exfoliant Download PDF

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Publication number
WO2017200036A1
WO2017200036A1 PCT/JP2017/018632 JP2017018632W WO2017200036A1 WO 2017200036 A1 WO2017200036 A1 WO 2017200036A1 JP 2017018632 W JP2017018632 W JP 2017018632W WO 2017200036 A1 WO2017200036 A1 WO 2017200036A1
Authority
WO
WIPO (PCT)
Prior art keywords
wax particles
hydrocarbon wax
scrub
composition
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2017/018632
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English (en)
Japanese (ja)
Inventor
輝礁 松元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mandom Corp
Original Assignee
Mandom Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mandom Corp filed Critical Mandom Corp
Priority to JP2018518348A priority Critical patent/JPWO2017200036A1/ja
Publication of WO2017200036A1 publication Critical patent/WO2017200036A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations

Definitions

  • the present invention relates to a scrub agent and a composition for a skin cleanser containing the scrub agent.
  • various scrub agents are blended from the viewpoint of enhancing the effect of removing dirt on the skin and from the viewpoint of moderately stimulating the skin and imparting a massage effect.
  • a scrubbing agent which is a hard material scrubbing agent such as polyethylene beads, walnut shell particles, and crystalline cellulose powder is used, and among them, polyethylene beads that are remarkably excellent in the above effects are most widely used.
  • the above-mentioned hard scrub agent is excellent in the effect of removing dirt on the skin and the effect of stimulating and massaging the skin, but may feel uncomfortable skin irritation and foreign body feeling when used. In addition, there is a risk of damaging the eyeball when it enters the eye during washing. Furthermore, in recent years, there has been a movement in the cosmetics industry to refrain from using hard scrub agents such as polyethylene beads that are not biodegradable in consideration of environmental pollution.
  • soft scrub agents which are scrub agents made of a softer material than the hard scrub agent, are also used in conventional skin cleansing compositions. Specifically, agar, polyacrylate, alginate and the like are used. Such soft scrubbing agents do not feel uncomfortable skin irritation or foreign body feeling during use and are excellent in use feeling, but have a problem that they are inferior in scrubbing effect.
  • An object of the present invention is to provide a scrubbing agent that is excellent in feeling of use without an unpleasant skin irritation or foreign body feeling at the time of use, exhibits an appropriate scrubbing effect, and contains the scrubbing agent in consideration of the influence on environmental pollution. It is providing the composition for skin cleansing agents.
  • the present invention provides a scrub agent characterized by being hydrocarbon wax particles.
  • the average particle diameter of the hydrocarbon wax particles is preferably 100 to 1,000 ⁇ m.
  • the hydrocarbon wax particles are preferably selected from the group of petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles.
  • the present invention also provides a composition for a skin cleanser comprising the scrub agent described above.
  • the content of the scrub agent in the composition for skin cleanser is preferably 0.1 to 30% by mass.
  • composition for skin cleanser contains a higher fatty acid salt.
  • the scrub agent of the present invention Since the scrub agent of the present invention has biodegradability, it does not have an adverse effect on environmental pollution. Moreover, the composition for skin cleansing agents of the present invention containing the scrub agent exhibits an excellent scrub effect and also exhibits an excellent effect on the feeling of use with no unpleasant skin irritation or foreign body sensation during use.
  • the scrub agent of the present invention is hydrocarbon wax particles.
  • Hydrocarbon wax particles are particles mainly composed of hydrocarbon waxes such as linear hydrocarbons (normal paraffins), branched hydrocarbons (isoparaffins), saturated cyclic hydrocarbons (cycloparaffins), and are biodegradable. have. That is, there is no adverse effect on environmental pollution.
  • the scrub agent of this invention means that it is a scrub agent comprised only with the said hydrocarbon wax particle,
  • the hydrocarbon wax particle is used as a use of a scrub agent, It is characterized by the above-mentioned.
  • the particle diameter of the hydrocarbon wax particles is not particularly limited, but from the viewpoint of exhibiting an excellent scrub effect without unpleasant skin irritation, it is preferable to use particles having an average particle diameter in the range of 100 to 1,000 ⁇ m. More preferably, the thickness is 200 to 900 ⁇ m.
  • hydrocarbon wax particles examples include petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles.
  • the “petroleum-derived hydrocarbon wax particles” may be referred to as “component a1”.
  • the “synthetic hydrocarbon wax particles” may be referred to as “component a2”.
  • the component a1 and the component a2 one type may be used alone, or two or more types may be used in appropriate combination.
  • the component a1 include paraffin wax particles and microcrystalline wax particles.
  • the melting point of the paraffin wax particles is not particularly limited, but is preferably 40 to 80 ° C., more preferably 60 to 80 ° C.
  • the melting point of the microcrystalline wax particles is not particularly limited, but is preferably 60 to 105 ° C.
  • the granulation method of component a1 is not particularly limited as long as it is a known method. For example, a method of separating and extracting hydrocarbons with good crystallinity from a crude oil vacuum distillation distillate part, a crude oil vacuum distillation residue oil part, The method of taking out is mentioned.
  • specific examples of the component a2 include Fischer-Tropsch wax particles.
  • the Fischer-Tropsch wax particles are obtained by the Fischer-Tropsch manufacturing method.
  • the melting point of the Fischer-Tropsch wax particles is not particularly limited, but is preferably 35 to 115 ° C, and more preferably 60 to 115 ° C.
  • the granulation method of component a2 is not particularly limited as long as it is a known method, and examples thereof include a Fischer-Tropsch manufacturing method.
  • the above Fischer-Tropsch production method uses a steam reforming method or partial oxidation method from natural gas and air to produce a synthesis gas of carbon monoxide and hydrogen, and in a high temperature and high pressure state, iron, cobalt, nickel, etc. This refers to a production method obtained by synthesizing by using a catalyst to cause a catalytic reaction, purifying and reforming (molding) after fractional distillation.
  • the scrub agent which is the said hydrocarbon wax particle can use a commercial item.
  • paraffin wax particles include trade name “Paraffin Wax-155” (manufactured by Nippon Seiwa Co., Ltd.), trade name “HNP-51” (manufactured by Nippon Seiwa Co., Ltd.), and the like.
  • microcrystalline wax particles include trade name “Hi-Mic-1080” (manufactured by Nippon Seiwa Co., Ltd.), trade name “Hi-Mic-2065” (manufactured by Nippon Seiwa Co., Ltd.), and the like.
  • Fischer-Tropsch wax particles include trade name “Synscrub 20PC” (manufactured by Micro Powders), trade name “Synscrub 50PC” (manufactured by Micro Powders), and the like.
  • composition for skin cleanser of the present invention contains a scrub agent that is the above hydrocarbon wax particles. That is, the present invention is characterized in that the hydrocarbon wax particles are blended in the composition for skin cleanser as a scrub agent.
  • composition for skin cleanser of the present invention contains the scrub agent which is the hydrocarbon wax particles described above, thereby exhibiting an excellent scrubbing effect and excellent in usability without unpleasant skin irritation and foreign body sensation during use. The effect can be demonstrated. Therefore, the composition for skin cleanser of the present invention can be suitably used as a skin cleanser in the form of a face cleanser (face cleanser scrub), body shampoo (body scrub) or the like.
  • the scrub is the hydrocarbon wax particle described above from the viewpoint of exhibiting an optimal scrub effect without uncomfortable skin irritation and foreign body sensation during use.
  • the average particle diameter of the agent is preferably in the range of 100 to 800 ⁇ m, more preferably 150 to 600 ⁇ m.
  • the average particle diameter of the scrub agent as the hydrocarbon wax particles is 200 from the viewpoint of exerting an optimal scrub effect. It is preferable to use those in the range of ⁇ 1,000 ⁇ m, more preferably 250 to 900 ⁇ m.
  • the content of the scrubbing agent that is the hydrocarbon wax particles in the skin cleansing composition of the present invention is not particularly limited, but is 0 in 100% by weight of the skin cleansing composition from the viewpoint of exerting a scrubbing effect. It is preferably 1% by mass or more, and more preferably 0.5% by mass or more. Further, the content of the scrub agent which is the hydrocarbon wax particles in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of skin irritation and maintaining foaming, the composition for skin cleanser It is preferable that it is 30 mass% or less in 100 mass% of things, and it is more preferable that it is 20 mass% or less.
  • the content of the scrub agent as the hydrocarbon wax particles is the total content of the scrub agent as all the hydrocarbon wax particles blended in the skin cleansing composition of the present invention.
  • the composition for skin cleanser of the present invention preferably contains a higher fatty acid salt from the viewpoint of imparting a clean feeling and further enhancing the scrub effect of the scrub agent.
  • the higher fatty acid salt may be used alone or in combination of two or more.
  • any higher fatty acid used as a cosmetic raw material can be used.
  • the salt of the higher fatty acid a salt obtained by saponifying or neutralizing the higher fatty acid with an alkaline agent can be used.
  • the alkali agent include alkali metals and organic alkalis. Specific examples of the alkali metal include sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate and the like. Specific organic alkalis include, for example, triethanolamine, isopropanolamine, arginine and the like.
  • the higher fatty acid and the alkaline agent may be blended after preparing as a higher fatty acid salt in advance. It is good also as a higher fatty acid salt in a composition by mix
  • the content of the higher fatty acid salt in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of imparting detergency and more efficiently exerting the scrub effect, it is used as a higher fatty acid for skin cleanser. In 100% by mass of the composition, it is preferably 0.5% by mass or more, and more preferably 1% by mass or more. Further, the content of the higher fatty acid salt in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of stability of the preparation, 80% of the composition for skin cleanser as a higher fatty acid is 80% by mass. The content is preferably at most mass%, more preferably at most 60 mass%. In addition, content as the said higher fatty acid is a total amount of content as all the higher fatty acids mix
  • composition for skin cleansing agent of the present invention components usually used in cosmetics can be blended in addition to the above-described components within the range where the effects of the present invention are not impaired.
  • Other components include, for example, nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, polyhydric alcohols, fatty acid ester oils, vegetable oils, thickening polymers, higher alcohols. , Refreshing agents, lipids, fragrances, antiseptic / bactericidal agents, moisturizing agents, scrubbing agents other than the scrubbing agent that is the hydrocarbon wax particles, and the like.
  • the said other component can be mix
  • nonionic surfactant examples include sorbitan fatty acid ester, glycerin fatty acid ester, castor oil, hydrogenated castor oil, and alkylene oxide adducts thereof, polyglycerin fatty acid ester, polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester. , Polyoxyalkylene alkylphenol, polyoxyethylene sorbite fatty acid ester, polyoxyethylene alkylphenyl formaldehyde condensate, polyoxyethylene sterol and its derivatives, polyoxyethylene lanolin and its derivatives, polyoxyethylene beeswax derivatives, sugar esters, etc. It is done.
  • anionic surfactant examples include alkyl sulfates, alkyl phosphates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, alkyl ether phosphates, alkyl ether carboxylates.
  • N-acyl-N-methyl- ⁇ -alanine N-acyl glycine
  • N-acyl glutamate polyoxyethylene alkyl carboxylate, alkyl phenyl ether sulfonate, alkyl sulfosuccinic acid and And salts thereof, N-acyl sarcosine and its salts, polyoxyethylene coconut oil fatty acid monoethanolamide sulfate and the like.
  • Examples of the cationic surfactant include amine salts such as alkylamine salts, fatty acid amide amine salts, and ester-containing tertiary amine salts, monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, and trialkyl type 4 salts.
  • Examples include quaternary ammonium salts, alkyl quaternary ammonium salts such as benzalkonium-type quaternary ammonium salts, cyclic quaternary ammonium salts such as alkyl pyridinium salts, and benzethonium chloride.
  • amphoteric surfactant examples include glycine-type amphoteric surfactants such as alkyl glycine salt, carboxymethyl glycine salt, N-acylaminoethyl-N-2-hydroxyethyl glycine salt, alkylaminopropionate, alkylimino.
  • Aminopropionic acid type amphoteric surfactants such as dipropionate
  • aminoacetic acid betaine type amphoteric surfactants such as alkyldimethylaminoacetic acid betaine, fatty acid amidopropyldimethylaminoacetic acid betaine, and sulfobetaine type amphoteric interfaces such as alkylhydroxysulfobetaine An active agent etc. are mentioned.
  • the surfactants such as the nonionic surfactant, the anionic surfactant, the cationic surfactant and the amphoteric surfactant may be used alone or in combination of two or more. It may be used.
  • polyhydric alcohol examples include ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, and mannitol. Sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and the like.
  • the said polyhydric alcohol may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
  • fatty acid ester oil examples include ethyl oleate, isopropyl myristate, isopropyl palmitate, butyl stearate, myristyl myristate, cetyl myristate, cetyl palmitate, stearyl stearate, decyl oleate, oleyl oleate, myristine Octyldodecyl acid, octyldodecyl oleate, ethyl isostearate, isocetyl stearate, isopropyl isostearate, isocetyl isostearate, propylene glycol isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, neopentyl glycol dicaprate , Neopentyl glycol dioctanoate, glyceryl tri-2-ethylhexanoate,
  • Examples of the vegetable oil include orange oil, olive oil, camellia oil, macadamia nut oil, jojoba oil, rose oil, lavender oil, and tea tree oil.
  • the said vegetable oil may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
  • thickening polymer examples include natural polymers, semi-synthetic polymers, synthetic polymers, and clay minerals. One of these thickening polymers may be used alone, or two or more thereof may be used in appropriate combination.
  • Examples of the natural polymer include gum arabic, gum tragacanth, guar gum, xanthan gum, locust bean gum, karaya gum, iris moss, quince seed, gelatin, shellac, rosin, and casein.
  • Examples of the semi-synthetic polymer include sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, sodium alginate, ester gum, nitrocellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, and crystalline cellulose.
  • Examples of the synthetic polymer include acrylic acid / alkyl methacrylate copolymer, acrylic acid / polyoxyethylene alkyl itaconic acid copolymer, alkyl acrylate / polyoxyethylene alkyl ether copolymer, acrylic acid / Examples include hydroxyalkyl acrylate copolymers, acrylic acid / polyoxyethylene alkyl ether cross-polymers of methacrylic acid, acrylic acid / vinyl neodecanoate cross-polymers, polyvinyl alcohol, sodium polyacrylate, carboxyvinyl polymer, polyvinyl methyl cellulose, polyamide resins, etc. It is done.
  • Examples of the clay mineral include fluorosilicic acid (sodium / magnesium) and synthetic silicic acid (sodium / magnesium).
  • Examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, and behenyl alcohol.
  • the above higher alcohols may be used alone or in combination of two or more.
  • Examples of the refreshing agent include l-menthol, menthyl glyceryl ether, menthyl lactate, 1-menthyl-3-hydroxybutyrate, dl-camphor, eugenol, menthone, mint, menthyl salicylate, and eucalyptus oil.
  • the said refreshing agent may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
  • composition for skin cleanser of the present invention can be prepared in various dosage forms such as paste, cream, emulsion, gel, and liquid. Among these, it is preferable to prepare a paste-like, cream-like, or gel-like skin cleansing composition from the viewpoint of excellent dispersion state of the scrub agent that is the hydrocarbon wax particles.
  • the method for producing the composition for skin cleanser of the present invention is not particularly limited as long as it is a known production method.
  • the above components are mixed as appropriate and stirred using a disper mixer, homomixer, disper mill or the like. A method is mentioned.
  • the hydrocarbon wax particles are used as a scrub agent. That is, in the present invention, in order to exert the scrub effect, it is necessary to be present as hydrocarbon wax particles in the skin cleansing composition. Therefore, as a suitable method for producing the composition for skin cleanser of the present invention, for example, a composition is prepared by heating and mixing and stirring components other than the hydrocarbon wax particles at a temperature of about 70 ° C. or higher. Examples thereof include a method in which the hydrocarbon wax particles are added in a state where the temperature of the composition is about 40 ° C. or less and then stirred to prepare.
  • the blending amount represents “% by mass” unless otherwise specified, and all blending components were converted to pure. All the evaluations were performed under constant conditions of 23 ° C. and 60% humidity.
  • Scrub agent 1 paraffin wax particles: trade name “HNP-51” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 250 ⁇ m)
  • Scrub agent 2 Fischer-Tropsch wax particles: trade name “Synscrub 50PC” (manufactured by Micro Powders, particle diameter: 180-297 ⁇ m)
  • Scrub agent 3 paraffin wax particles: trade name “Paraffin Wax-155” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 900 ⁇ m)
  • Scrub agent 4 microcrystalline wax particles: trade name “Hi-Mic-1080” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 900 ⁇ m)
  • Scrub agent 5 Fischer-Tropsch wax particles: trade name “Synscrub 20PC” (manufactured by Micro Powders, particle diameter: 500 to 840 ⁇ m)
  • Apricot kernel 1 Trade name “AP grid ⁇ spherical># 40-60” (manufactured by Ichimaru Falcos, particle size: 177 ⁇ m to 420 ⁇ m)
  • Apricot kernel 2 Trade name “AP grid ⁇ spherical># 60-80” (manufactured by Ichimaru Falcos, particle size: 149 ⁇ m to 297 ⁇ m)
  • Polyethylene beads trade name “Microscrub 1435PC” (manufactured by Micro Powders, particle size: 500-1410 ⁇ m)
  • Silica beads Trade name “SCRUB SILICA 850G” (manufactured by JGC Catalysts & Chemicals, average particle size: about 720 ⁇ m)
  • the skin cleansing composition of each example which is a facial cleanser, is superior to the feeling of use without giving an unpleasant skin irritation or foreign body feeling, as compared with those of each comparative example. It can be seen that the optimum scrubbing effect is exhibited.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dermatology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention a pour objet de fournit un agent exfoliant et une composition pour agent de nettoyage de la peau comprenant cet agent exfoliant qui sont dotés d'une excellente sensation lors de leur mise en œuvre ne présentent pas d'irritation désagréable de la peau ni de sensation de substance étrangère lors de leur mise en œuvre, qui développent un effet exfoliant adéquat, et simultanément dont l'impact sur la pollution environnementale est pris en considération. L'agent exfoliant de l'invention est caractéristique en ce qu'il consiste en des particules de cire d'hydrocarbure, de préférence des particules de cire d'hydrocarbure choisies dans un groupe de particules de cire d'hydrocarbure dérivées du pétrole et de particules de cire d'hydrocarbure synthétiques. Enfin, la composition pour agent de nettoyage de la peau de l'invention est caractéristique en ce qu'elle comprend ledit agent exfoliant.
PCT/JP2017/018632 2016-05-19 2017-05-18 Agent exfoliant, et composition pour agent de nettoyage de la peau comprenant cet agent exfoliant Ceased WO2017200036A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2018518348A JPWO2017200036A1 (ja) 2016-05-19 2017-05-18 スクラブ剤および当該スクラブ剤を含有する皮膚洗浄剤用組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016100880 2016-05-19
JP2016-100880 2016-05-19

Publications (1)

Publication Number Publication Date
WO2017200036A1 true WO2017200036A1 (fr) 2017-11-23

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PCT/JP2017/018632 Ceased WO2017200036A1 (fr) 2016-05-19 2017-05-18 Agent exfoliant, et composition pour agent de nettoyage de la peau comprenant cet agent exfoliant

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WO (1) WO2017200036A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7571352B1 (ja) 2024-03-21 2024-10-23 資生堂ホネケーキ工業株式会社 粉末造粒物

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004269494A (ja) * 2002-09-23 2004-09-30 Johnson & Johnson Consumer Co Inc 皮膚を剥離し、かつ、にきびを治療するための組成物
JP2005537275A (ja) * 2002-07-18 2005-12-08 ユニリーバー・ナームローゼ・ベンノートシヤープ 剥離特性および保湿特性を同時に有する化粧品スティック
JP2006512309A (ja) * 2002-11-08 2006-04-13 ユニリーバー・ナームローゼ・ベンノートシヤープ 皮膚剥脱特性及び湿潤化特性の双方を有している液体クレンジング組成物
JP2015172187A (ja) * 2014-02-19 2015-10-01 株式会社コーセー 洗浄剤組成物
US20150320674A1 (en) * 2014-05-08 2015-11-12 Micro Powders, Inc. Compositions Comprising Synthetic Waxes
JP2017039660A (ja) * 2015-08-19 2017-02-23 株式会社マンダム 皮膚洗浄用組成物及び皮膚洗浄用組成物の製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005537275A (ja) * 2002-07-18 2005-12-08 ユニリーバー・ナームローゼ・ベンノートシヤープ 剥離特性および保湿特性を同時に有する化粧品スティック
JP2004269494A (ja) * 2002-09-23 2004-09-30 Johnson & Johnson Consumer Co Inc 皮膚を剥離し、かつ、にきびを治療するための組成物
JP2006512309A (ja) * 2002-11-08 2006-04-13 ユニリーバー・ナームローゼ・ベンノートシヤープ 皮膚剥脱特性及び湿潤化特性の双方を有している液体クレンジング組成物
JP2015172187A (ja) * 2014-02-19 2015-10-01 株式会社コーセー 洗浄剤組成物
US20150320674A1 (en) * 2014-05-08 2015-11-12 Micro Powders, Inc. Compositions Comprising Synthetic Waxes
JP2017039660A (ja) * 2015-08-19 2017-02-23 株式会社マンダム 皮膚洗浄用組成物及び皮膚洗浄用組成物の製造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7571352B1 (ja) 2024-03-21 2024-10-23 資生堂ホネケーキ工業株式会社 粉末造粒物
JP2025145089A (ja) * 2024-03-21 2025-10-03 資生堂ホネケーキ工業株式会社 粉末造粒物

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