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WO2016068828A1 - Procédé de production d'un combustible de chauffage "biomazout" - Google Patents

Procédé de production d'un combustible de chauffage "biomazout" Download PDF

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Publication number
WO2016068828A1
WO2016068828A1 PCT/UA2015/000007 UA2015000007W WO2016068828A1 WO 2016068828 A1 WO2016068828 A1 WO 2016068828A1 UA 2015000007 W UA2015000007 W UA 2015000007W WO 2016068828 A1 WO2016068828 A1 WO 2016068828A1
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
raw materials
producing
feedstock
emulsifier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/UA2015/000007
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English (en)
Russian (ru)
Inventor
Игорь Борисович ТРОЦКО
Владимир Александрович МИКУЛЕНКО
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2016068828A1 publication Critical patent/WO2016068828A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions

Definitions

  • the invention relates to technologies for the production of environmentally friendly composite fuels and can be used for the production of water-oil-emulsion emulsions (VME) and water-coal-oil-fuel suspensions (VUMS), water-peat, water-bio-mixtures.
  • VME water-oil-emulsion emulsions
  • VUMS water-coal-oil-fuel suspensions
  • the prepared raw materials are heated at a temperature of 55-60 ° C, followed by the separation of moisture and impurities, and the prepared raw materials are processed in a reaction boiler by the simultaneous esterification and transesterification reaction when mixing the raw materials with alcohol in a ratio of 5: 1-7: 1, respectively, and by adding heterogeneous acid catalyst in an amount of 5-10% to mass, while the process is carried out at a temperature of 120-150 ° C for 60 to 120 minutes with turbulent mixing at 1200-1500 rpm and atmospheric pressure.
  • the disadvantage of this known method is the complexity and energy intensity of the method in view of the need for complex energy-intensive equipment for heating prepared raw materials and subsequent separation of moisture and impurities, as well as for processing prepared raw materials in a reaction boiler.
  • it is necessary to perform additional operations to separate moisture, sediment and separation of components, distillation of alcohol, and so on.
  • Another disadvantage of this method is the limited use in view of the use of expensive components such as alcohol, glycerin, a catalyst, as well as vegetable raw materials of oilseeds.
  • the basis of the invention is the task of simplifying the implementation and reducing the energy intensity of the method, as well as the task of expanding the scope of the method.
  • the method of producing biomass includes preparation of raw materials, dosing of components with subsequent processing and obtaining fuel.
  • both raw materials use organic raw materials (bioil), as well as heavy fuels or chemical waste, unsuitable for use as fuel.
  • organic raw materials are mixed with heavy fuels, and then the mixture is fed into an emulsifier-dispersant, where the substance is ground and structured into a highly dispersed fluid emulsion using the phenomenon of cavitation with a particle size of not more than 1-5 microns in diameter and a moisture content of 1 to 58%.
  • the input and output of the emulsifier-dispersant is controlled by a lock apparatus (controlled valves) with the possibility of regulating the watering of the raw material and its state of aggregation, after which the fuel suspension is fed into a consumable container.
  • the invention solves the problem of simplifying the method and reducing it energy intensity due to the use of organic raw materials (bioil), which is mixed with heavy fuels or chemical waste unsuitable for use as fuel, and then the mixture is fed into an emulsifier-dispersant, where the substance is ground and structured into a highly dispersed fluid emulsion using the cavitation phenomenon with particle size with a diameter of not more than 1-5 microns and a moisture content of from 1 to 58%.
  • bioil organic raw materials
  • the method is implemented in this way.
  • organic raw materials are poured (poured) into the hopper of the metering mixer, after which the previous metered mixing of bioil is carried out.
  • the mixture is then fed into an emulsifier to grind and structure the substance into a fluid emulsion using the phenomenon of cavitation.
  • the input and output of the emulsifier is controlled by a lock apparatus
  • the prepared fuel suspension is fed into a consumable container.
  • Cooked fuel can be used for burning in boiler houses, replacing fuel oil of the M-100 brand, and also be raw material ("artificial oil”) for the production of agile fuels.
  • water (up to 30%) in such fuel compositions is not a ballast, but a kind of a catalyst that improves and speeds up the combustion of the hydrocarbon base.
  • the presence of bound water in such fuels contributes to a higher completeness of hydrocarbon combustion with less air consumption.
  • the amount of soot (less smoke), oxides of nitrogen and sulfur, benzopyrene, etc., is significantly reduced in combustion products.
  • the environmental situation is significantly improved.
  • biomass oil in accordance with the invention, allows to increase the efficiency of power plants, primarily by reducing chemical and mechanical underburning, as well as reducing pollution of the heating surfaces in boilers.
  • the degree of burnout of hydrocarbons can reach 99.5%.
  • the saving of hydrocarbon fuel due to the introduction of water and the improvement of the processes of fuel burning can be from 5 to 25%.
  • bioil as a component of biomass, that makes it possible to achieve the high-calorie effect of the resulting fuel due to its biochemical properties.
  • the percentage composition of the feedstock, its processing and additives, as well as the temperature and pressure conditions, can vary depending on the composition of the feedstock.
  • the goal is to simplify the implementation and reduce the energy intensity of the method, as well as the task of expanding the scope of the method.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Le procédé se rapporte aux technologies de production de composants biologiquement propres et peut s'utiliser pour produire des émulsions eau-mazout; il comprend la préparation d'une matière de base, le dosage des composants avec son traitement ultérieur et la production combustible, la matière de base employée étant une matière de base organique (limon biologique) et des sortes lourds de combustibles ou des déchets de l'industrie chimique inutilisables comme combustible. La matière de base organique est mélangée à des types lourds de combustible, le mélange obtenu étant acheminé dans un appareil d'émulsion et de dispersion qui broie et structure la substance en une émulsion à haut degré de dispersion grâce à la cavitation, avec une taille de particules ayant un diamètre de 1-5 micromètres au maximum et une humidité de 1 à 58 %. Le procédé permet de simplifier la mise en oeuvre du procédé et de réduire sa consommation d'énergie ainsi que d'élargir le domaine de son application.
PCT/UA2015/000007 2014-10-27 2015-01-26 Procédé de production d'un combustible de chauffage "biomazout" Ceased WO2016068828A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
UAU201411641 2014-10-27
UA201411641 2014-10-27

Publications (1)

Publication Number Publication Date
WO2016068828A1 true WO2016068828A1 (fr) 2016-05-06

Family

ID=55857956

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/UA2015/000007 Ceased WO2016068828A1 (fr) 2014-10-27 2015-01-26 Procédé de production d'un combustible de chauffage "biomazout"

Country Status (1)

Country Link
WO (1) WO2016068828A1 (fr)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5211723A (en) * 1991-09-19 1993-05-18 Texaco Inc. Process for reacting pumpable high solids sewage sludge slurry
KZ22398A4 (ru) * 2009-02-10 2010-03-15 Tovarischestvo S Ogranichennoj Способ получения водотопливной эмульсии и композиционного многокомпонентного топлива
UA96400C2 (uk) * 2010-12-27 2011-10-25 Валерій Валерійович Третьяков Спосіб одержання біомазуту

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5211723A (en) * 1991-09-19 1993-05-18 Texaco Inc. Process for reacting pumpable high solids sewage sludge slurry
KZ22398A4 (ru) * 2009-02-10 2010-03-15 Tovarischestvo S Ogranichennoj Способ получения водотопливной эмульсии и композиционного многокомпонентного топлива
UA96400C2 (uk) * 2010-12-27 2011-10-25 Валерій Валерійович Третьяков Спосіб одержання біомазуту

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
KARAS V.: "Biomazut - alternativa nefti. «Delovoi Vestnik» N°6(205", 2011, Retrieved from the Internet <URL:http:www.ucci.org.ua/synopsis/dv/2011/dvl106151.ra.html> *

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