WO2014020673A1 - Method for producing solar cell module and solar cell module - Google Patents
Method for producing solar cell module and solar cell module Download PDFInfo
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- WO2014020673A1 WO2014020673A1 PCT/JP2012/069388 JP2012069388W WO2014020673A1 WO 2014020673 A1 WO2014020673 A1 WO 2014020673A1 JP 2012069388 W JP2012069388 W JP 2012069388W WO 2014020673 A1 WO2014020673 A1 WO 2014020673A1
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- solar cell
- cell module
- connection electrode
- crimping
- pressure
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/20—Electrodes
- H10F77/206—Electrodes for devices having potential barriers
- H10F77/211—Electrodes for devices having potential barriers for photovoltaic cells
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F19/00—Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
- H10F19/90—Structures for connecting between photovoltaic cells, e.g. interconnections or insulating spacers
- H10F19/902—Structures for connecting between photovoltaic cells, e.g. interconnections or insulating spacers for series or parallel connection of photovoltaic cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the present invention relates to a method for manufacturing a solar cell module and a solar cell module manufactured thereby.
- thermosetting conductive paste As one of the conductor formation methods for solar cells, a method using a thermosetting conductive paste is known.
- the thermosetting conductive paste is applied to a substrate or the like by screen printing or the like, and is heat-treated at a temperature of about 100 ° C. to 300 ° C., so that the resin is cured and a conductive electrode is formed.
- thermosetting conductive paste containing conductive particles and a resin two or more kinds of conductive particles may be mixed and used, and the shape of the conductive particles may be spherical, flaky, or dendritic.
- limiting such as a shape and a fibrous form, it is said that powder particles are easy to contact each other and it is advantageous at an electroconductive point.
- connection between the solar cell and the connection electrode it is to secure the connection between the solar cell and the connection electrode by balancing the adhesive strength between the solar cell and the connection electrode and the strength of the connection electrode itself.
- the method for manufacturing a solar cell module according to the present invention includes arranging a wiring material via an adhesive on a connection electrode of a solar cell, and pressing a crimping tool against the solar cell on which the wiring material is arranged with a predetermined pressure.
- the adhesive is heated to a curing temperature or higher and cured, and the predetermined crimping pressure of the crimping tool is such that the crimping pressure at the end of the solar cell along the longitudinal direction of the wiring material is greater than the crimping pressure at the center of the solar cell. Is also low.
- a solar cell module includes a solar cell having a connection electrode and a wiring material connected to the connection electrode via an adhesive, and the strength of the connection electrode itself is the length of the wiring material.
- the edge of the solar cell along the direction is weaker than the center of the solar cell.
- connection between the solar cell and the connection electrode can be secured at the end of the solar cell, which is an important part for the connection between the solar cell and the wiring member.
- FIG. 1 it is a figure which shows the process which forms the electrode for a connection of a solar cell with the electrically conductive paste which becomes a network structure by heating.
- FIG. 1 it is a figure which shows the process which arrange
- FIG. 1 it is a figure which shows the process which sets a crimping
- FIG. 4 it is a figure which shows distribution of pressure bonding pressure.
- FIG. 1 is a flowchart showing a procedure of a method for manufacturing a solar cell module.
- 2 to 4 are diagrams for explaining each procedure in this flowchart.
- the solar cell module is formed by connecting a plurality of solar cells with a wiring material, a solar cell is prepared in order to manufacture the solar cell module.
- the photoelectric conversion unit 11 is formed (S10).
- FIG. 2 is a diagram showing the solar cell 10, FIG. 2 (a) is a plan view, and FIG. 2 (b) is a side view.
- the solar cell 10 includes a photoelectric conversion unit 11 that generates light-generated carriers of holes and electrons by receiving light such as sunlight.
- the solar cell 10 has, as main surfaces, a light receiving surface that is a surface on which light from the outside of the solar cell 10 is mainly incident and a back surface that is a surface opposite to the light receiving surface, but in the plan view of FIG. The light receiving surface is shown.
- the photoelectric conversion unit 11 includes a substrate made of a semiconductor material such as crystalline silicon (c-Si), gallium arsenide (GaAs), indium phosphide (InP), for example.
- the structure of the photoelectric conversion unit 11 is a pn junction in a broad sense.
- a heterojunction of an n-type single crystal silicon substrate and amorphous silicon can be used.
- a transparent conductive film (TCO) 12 composed of a conductive oxide is stacked, and an i-type amorphous silicon layer and an n-type amorphous silicon layer doped with phosphorus (P) or the like are formed on the back side of the substrate,
- the transparent conductive film 13 can be laminated.
- the photoelectric conversion unit 11 may have a structure other than this as long as it has a function of converting light such as sunlight into electricity.
- a structure including a p-type polycrystalline silicon substrate, an n-type diffusion layer formed on the light-receiving surface side, and an aluminum metal film formed on the back surface side may be used.
- connection electrode 20 on the light receiving surface side is formed on the light receiving surface of the solar cell 10.
- the connection electrode 20 on the light receiving surface side is formed by printing a conductive paste in a predetermined pattern on the surface of the transparent conductive film 12.
- the conductive paste is obtained by mixing conductive particles into a resin using a solvent.
- conductive pastes which can be used properly according to the application.
- a conductive paste in which conductive particles such as silver (Ag) are dispersed in a binder resin can be used.
- the connection electrode 20 is formed using a sintered conductive paste that becomes a network structure by heating, as an improvement in conductivity (S11).
- the network structure is a structure in which conductive particles are fused to each other. For example, by heating a conductive paste containing conductive particles, the conductive particles can be fused together to form a network structure.
- the network structure is a structure in which 50% or more of conductive particles observed under a microscope are fused to each other.
- the sintered conductive paste that becomes a network structure by heating is obtained by mixing a plurality of spherical powders 21 with a resin such as an epoxy resin using a solvent.
- the spherical powder 21 is a substantially spherical conductive particle.
- the conductive paste is heated, the spherical powders 21 are fused together to form a network structure. Due to this network structure, the conductivity of the connection electrode 20 is improved.
- the connection electrode 20 may contain flakes in addition to the spherical powder 21.
- Flakes refer to conductive particles having a ratio of major axis to thickness of powder particles (major axis / thickness) ⁇ 10 and an average particle diameter of about 2 to 5 ⁇ m or more.
- the flakes can be obtained, for example, by crushing the spherical powder 21 into a flat shape. Since the flakes have an action of dividing the network structure, the flakes have a function of relieving stress caused by fusion.
- the mixing ratio of the spherical powder 21 and the flakes can be determined based on the balance between the improvement of conductivity and stress relaxation.
- a finger electrode is disposed in addition to the bus bar electrode serving as the connection electrode 20. In FIG. 2, the finger electrode is not shown.
- the finger electrode is a thin wire electrode that collects electricity from the entire light receiving surface but is thinned so as to reduce the light shielding property.
- the finger electrode and the bus bar electrode are arranged orthogonally to each other and electrically connected.
- the width of the finger electrode is preferably about 30 ⁇ m to 150 ⁇ m, and the thickness is preferably about 10 ⁇ m to 80 ⁇ m.
- the interval between adjacent finger electrodes is preferably about 0.5 mm to 3 mm.
- the width of the bus bar electrode as the connection electrode 20 is preferably about 50 ⁇ m to 3 mm, and the thickness is preferably about 10 ⁇ m to 160 ⁇ m.
- connection electrode 23 on the back surface side is formed on the surface of the transparent conductive film 13 on the back surface side of the photoelectric conversion unit 11.
- the connection electrode 23 on the back surface side is also formed using a sintered conductive paste containing the spherical powder 21 and having a network structure by heating.
- the connection electrode 23 on the back surface side may further contain flakes in addition to the spherical powder 21.
- the wiring material is arranged.
- the wiring material 25 is arranged on the connection electrode 20 on the light receiving surface side of the solar cell 10 via the adhesive 24, and similarly, the adhesive 26 is applied on the connection electrode 23 on the back surface side of the solar cell 10.
- the wiring material 27 is placed through the wire, and it is pressed lightly so as not to separate from each other and heated to an appropriate temperature (S12).
- FIG. 3 is a diagram showing the solar cell module in a state where the wiring members 25 and 27 are arranged on the connection electrodes 20 and 23 via the adhesives 24 and 26, and FIG. (B) is a side view.
- the wiring members 25 and 27 are thin plates made of a metal conductive material such as copper. Instead of a thin plate, a stranded wire can be used. As the conductive material, in addition to copper, silver, aluminum, nickel, tin, gold, or an alloy thereof can be used.
- the wiring member 25 is preferably arranged so as to cover the connection electrode 20 along the arrangement direction of the connection electrode 20 on the light receiving surface side of the solar cell 10, and the width of the wiring member 25 is set to be the connection electrode 20. It is better to set it to be the same as or slightly thicker. Similarly, the width of the wiring member 27 on the back surface side may be set to be the same as or slightly thicker than the width of the connection electrode 23 on the back surface side.
- the adhesive 24 is disposed between the connection electrode 20 and the wiring member 25 on the light receiving surface side, electrically connects the connection electrode 20 and the wiring member 25, and the light receiving surface side of the solar cell 10 and the wiring member. 25 is used for mechanically fixing.
- the adhesive 26 is disposed between the connection electrode 23 on the back surface side and the wiring material 27, electrically connects the connection electrode 23 and the wiring material 27, and connects the back surface side of the solar cell 10 and the wiring. Used to mechanically fix the material 27.
- thermosetting resin adhesives such as acrylic, highly flexible polyurethane, or epoxy can be used.
- the curing temperature ⁇ H of the adhesives 24 and 26 is selected between about 130 ° C. and 300 ° C. from the heat resistance of the solar cell 10 and the like.
- the adhesives 24 and 26 include conductive particles.
- conductive particles nickel, silver, nickel with gold coating, copper with tin plating, or the like can be used.
- insulating resin adhesives that do not contain conductive particles can also be used. In this case, one or both of the facing surfaces of the wiring members 25 and 27 or the connecting electrodes 20 and 23 are made uneven so that the wiring member 27 and the connecting electrode 20 are connected. Resin is appropriately removed from between the electrodes 23 to establish electrical connection.
- the light receiving surface side is bonded by an adhesive force between the facing surfaces of the wiring member 25 and the connection electrode 20 and an adhesive force by a resin fillet formed on the light receiving surface of the solar cell 10 and the side surface of the wiring member 25.
- adhesion is caused by the adhesive force between the facing surfaces of the wiring member 27 and the connection electrode 23 and the adhesive force by the resin fillet formed on the light receiving surface of the solar cell 10 and the side surface of the wiring member 27. Is done.
- the crimping process is performed.
- a crimping tool designed so that a low crimping pressure is applied to the end of the solar cell 10 on which the wiring members 25 and 27 are arranged is set (S13), and the crimping tool is pressed to a predetermined pressing pressure. This is a process of curing the adhesive by pressing at a predetermined temperature (S14).
- FIG. 3 shows the positional relationship between the end portion and the center portion, but the end portion is a region on the end face side of the solar cell 10 in the longitudinal direction of the wiring members 25 and 27.
- the end region can be determined in consideration of the contribution of the photogenerated carriers of the solar cell 10 to the current collection. For example, with respect to the total number of finger electrodes, a region having a predetermined number counted from the end face of the solar cell 10 can be set as the end. Or it can be set as the area
- FIG. 4 is a diagram illustrating a state in which a crimping process is performed using a crimping tool.
- the crimping tool includes a lower tool 30 and an upper tool 31 that moves up and down relatively with respect to the lower tool 30.
- the solar cell on which the wiring material is arranged is placed on the lower tool 30, and the upper tool 31 is moved upward with respect to the lower tool 30.
- This is a device that lowers the tool 31 and applies a predetermined pressing force F to the upper tool 31 against the lower tool 30.
- the heating parts 32 and 33 are arrange
- a resistance wire heater, a heating lamp, a heating air supply device, or the like can be used.
- the crimping tool is a pressure heating device.
- the lower tool 30 and the upper tool 31 have a convex shape in which the central portion protrudes from the end portion on the crimping surface.
- a gap is generated between the end of the lower tool 30 and the wiring member 27 in a part surrounded by a broken-line circle, and a gap is generated between the end of the upper tool 31 and the wiring member 25. Showed this. Note that the size of the gap in FIG. 4 is exaggerated for explanation.
- the shape of the central portion protruding from the end portion is such that the central portion is flat and the gap gradually increases from the flat portion toward the end surface.
- the degree of increase in the gap is preferably determined experimentally. Depending on the experimental result, for example, the gap may be increased linearly toward the end face, or may be increased in a curved manner.
- FIG. 4 one lower tool 30 and one upper tool 31 are shown, but as shown in FIGS. 2 and 3, there are three wiring members 25 and 27 in parallel. Accordingly, three lower tools 30 can be provided in parallel, and three upper tools 31 can be provided in parallel. In this case, one lower tool and one upper tool that face each other with one wiring member interposed therebetween form a pair. For example, three pairs may be integrated and moved up and down relatively.
- the heating temperature ⁇ in the crimping process is set to be equal to or higher than the curing temperature of the adhesives 24 and 26.
- ⁇ is set to a higher temperature as the heating time determined by the cycle time of the crimping process is shorter. For example, when the heating time can be taken sufficiently long, ⁇ can be set as the curing temperature, but when the heating time is several seconds, ⁇ is set to a temperature higher than the curing temperature.
- the pressing force F is set so that the pressure P is 0.1 MPa to 0.2 MPa.
- the pressing force F is a load force applied from the upper tool 31 to the lower tool 30, and has a dimension of N (Newton).
- the pressure P is a force per unit area having a dimension of N / m 2 and applied to the surface where the lower tool 30 and the wiring member 27 are in contact and the surface where the upper tool 31 and the wiring member 27 are in contact.
- the amount of deformation in the thickness direction is large at the center of the solar cell, and the amount of deformation in the thickness direction is small at the end.
- the amount of deformation is the total thickness from the wiring material 25 on the light receiving surface side to the wiring material 27 on the back surface side. In the central portion where the amount of deformation is large, a large compressive stress is applied in the thickness direction, but the compressive stress received at the end portion where the amount of deformation is small is small. This compressive stress corresponds to the pressure P.
- FIG. 5 shows the distribution of the pressure P.
- the horizontal axis is the position of the solar cell along the longitudinal direction of the wiring material, and the vertical axis is the pressure P.
- P P 0 is a constant value, and the pressure P is gradually reduced from P 0 toward the end face of the solar cell from the boundary between the central part and the end part.
- the remaining process for obtaining the solar cell module is performed (S15).
- the solar cell module subjected to the crimping process is positioned between the light-receiving surface side protection member and the back-surface side protection member, and the filler is provided between the light-receiving surface-side protection member and the back surface-side protection member.
- Place. Frames are arranged at the ends of the light receiving surface side protective member and the back surface side protective member.
- a transparent plate or film is used as the protective member on the light receiving surface side.
- a translucent member such as a glass plate, a resin plate, or a resin film can be used.
- the protective member on the back surface side the same protective member as that on the light receiving surface side can be used.
- an opaque plate or film can be used as the protective member on the back side.
- a laminated film such as a resin film having an aluminum foil inside can be used.
- EVA, EEA, PVB, silicone resin, urethane resin, acrylic resin, epoxy resin, or the like can be used.
- connection electrodes 34 and 35 may be made thinner than the thickness of the central portion.
- the connection electrodes 34 and 35 can be crimped using the lower tool 36 and the upper tool 37 whose entire crimping surface is flat. Thereby, the crimping surfaces of the lower tool 36 and the upper tool 37 can be flattened from the center to the end, and a crimping tool common to the prior art can be used.
- a gap is formed between the end portion of the connection electrode 35 on the back surface side and the wiring member 27 in a portion surrounded by a broken-line circle, and the end portion of the connection electrode 34 on the light receiving surface side and the wiring member 25. This was shown by the gap between the two. As in FIG. 4, the size of the gap is exaggerated for the sake of explanation. In the shape in which the thickness of the end portion is thinner than the thickness of the central portion, the thickness of the central portion is constant, and the thickness gradually decreases from the central portion toward the end surface. The degree of thickness reduction should be determined experimentally. Depending on the experimental result, for example, the thickness may be decreased linearly toward the end face, or may be decreased in a curved manner.
- the pressure at the end of the solar cell 10 is lower than the pressure at the center so that the end of the solar cell 10 is an important part for the connection between the solar cell 10 and the wiring members 25 and 27. This is because the connection between the solar cell 10 and the connection electrodes 20 and 23 is suppressed and the connection is secured.
- FIG. 7 shows a cross-sectional view of the light receiving surface side of the solar cell 10 in order to explain the separation regarding the connection between the solar cell 10 and the wiring members 25 and 27.
- the first is peeling of the first junction between the transparent conductive film 12 on the photoelectric conversion unit 11 and the connection electrode 20.
- the first junction is shown as (12-20).
- the second is peeling between electrodes between the connection electrodes 20 itself. In FIG. 7, this portion is shown as (20-20).
- the third is peeling of the second joint between the connection electrode 20 and the wiring member 25 via the adhesive 24.
- the second junction is shown as (20-25).
- the boundary between the photoelectric conversion unit 11 and the transparent conductive film 12 and the separation between the wiring materials between the wiring material 25 itself can be considered, but these hardly cause the separation.
- the crimping pressure of the central portion and the end portion of the solar cell 10 is the same.
- peeling tends to occur at the first bonding portion.
- the strength of the connection electrode 20 itself is increased because the bonding strength of the network structure is strong. Therefore, if the adhesive strength of the first joint is relatively weak and the pressure bonding stress is too high, the possibility that peeling may occur in the first joint increases.
- the first junction is an electrical junction for taking out current from the solar cell 10, if peeling occurs, it is a problem even if the connection electrode 20 itself and the second junction are strong. Therefore, prevention of peeling of the first joint is important.
- the wiring member 25 is bent between the adjacent solar cells 10, and is generated in the wiring member 25 at an adhesive portion with the wiring member 25 near the end of the solar cell 10 near the bent portion. Stress is often concentrated. Therefore, it is highly necessary to suppress peeling at the first junction at the end of the solar cell 10.
- FIG. 8 is a diagram showing the rate of occurrence of peeling in the first bonding when the pressure bonding pressure distribution is shown in FIG.
- the horizontal axis is the same as in FIG. 5, the solar cell position along the longitudinal direction of the wiring members 25 and 27, and the vertical axis is the (12-20) mode peeling rate.
- the (12-20) mode peeling rate refers to the location where peeling occurred in the peeling test of the solar cell module, and peeling occurred at the location (12-20) which is the first bonding described in FIG. It is a value obtained by dividing the number by the total number of peeling.
- the (12-20) mode peeling rate is lower than the central portion at the end of the solar cell 10.
- the strength of the fusion aggregation of the conductive particles at the connection electrodes 20 and 23 is at the center at the end. Become weaker. Therefore, at the end portion of the solar cell 10, the adhesive strength of the first bonding is relatively stronger than the strength of the fusion aggregation of the conductive particles in the connection electrodes 20 and 23.
- peeling at the connection electrodes 20 and 23 is more likely to occur at the end portion of the solar cell 10 than at the first junction, and the (12-20) mode peeling rate at the end portion of the solar cell 10 is the central portion.
- the (12-20) mode peeling rate at the end portion of the solar cell 10 is the central portion.
- FIG. 9 and FIG. 10 are diagrams for explaining the effect of the above-described pressure bonding pressure. These figures are diagrams showing the peeling at the end of the solar cell in the result of the peeling test of the solar cell module, and FIG. 9 is a comparative example in which the crimping pressure at the end is the same as the crimping pressure at the center. FIG. 7 shows a case where the crimping stress distribution shown in FIG. 5 is used.
- the solar cell is connected to the solar cell at the end of the solar cell, which is an important part for the connection between the solar cell and the wiring material. Connection between the electrodes can be secured.
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Abstract
Description
本発明は、太陽電池モジュールの製造方法とそれにより製造される太陽電池モジュールに関する。 The present invention relates to a method for manufacturing a solar cell module and a solar cell module manufactured thereby.
太陽電池の導体形成方法の一つとして、熱硬化型導電性ペーストを用いたものが知られている。この場合、熱硬化型導電性ペーストはスクリーン印刷等で基板等に塗布され、100℃から300℃程度の温度で熱処理されることにより、樹脂が硬化し導電性の電極が形成される。 As one of the conductor formation methods for solar cells, a method using a thermosetting conductive paste is known. In this case, the thermosetting conductive paste is applied to a substrate or the like by screen printing or the like, and is heat-treated at a temperature of about 100 ° C. to 300 ° C., so that the resin is cured and a conductive electrode is formed.
特許文献1には、導電性粒子と樹脂を含む熱硬化型導電ペーストにおいて、2種以上の導電性粒子を混合して用いてもよく、導電性粒子の形状としては、球状、フレーク状、樹枝状、繊維状など制限がないが、粉末粒子同士が接触しやすく、導電性の点で有利であると述べられている。
In
太陽電池と接続用電極の間の接着強度と、接続用電極自体の強度との間のバランスをとって、太陽電池と接続用電極の間の接続を確保することである。 It is to secure the connection between the solar cell and the connection electrode by balancing the adhesive strength between the solar cell and the connection electrode and the strength of the connection electrode itself.
本発明に係る太陽電池モジュールの製造方法は、太陽電池の接続用電極に接着剤を介して配線材を配置し、配線材が配置された太陽電池に対し、圧着ツールを所定の圧着圧力で押し付け、接着剤を硬化温度以上に加熱して硬化させ、圧着ツールの所定の圧着圧力は、配線材の長手方向に沿った太陽電池の端部における圧着圧力が、太陽電池の中央部における圧着圧力よりも低い。 The method for manufacturing a solar cell module according to the present invention includes arranging a wiring material via an adhesive on a connection electrode of a solar cell, and pressing a crimping tool against the solar cell on which the wiring material is arranged with a predetermined pressure. The adhesive is heated to a curing temperature or higher and cured, and the predetermined crimping pressure of the crimping tool is such that the crimping pressure at the end of the solar cell along the longitudinal direction of the wiring material is greater than the crimping pressure at the center of the solar cell. Is also low.
本発明に係る太陽電池モジュールは、接続用電極を有する太陽電池と、接続用電極に対し接着剤を介して接続された配線材と、を備え、接続用電極自体の強度は、配線材の長手方向に沿った太陽電池の端部において太陽電池の中央部より弱い。 A solar cell module according to the present invention includes a solar cell having a connection electrode and a wiring material connected to the connection electrode via an adhesive, and the strength of the connection electrode itself is the length of the wiring material. The edge of the solar cell along the direction is weaker than the center of the solar cell.
接続用電極に接着剤を介して配線材を接続するときの圧着圧力が高すぎると、太陽電池と接続用電極との間の剥離が生じやすい。上記構成によって、太陽電池と配線材との接続にとって重要な個所である太陽電池の端部において、太陽電池と接続用電極の間の接続を確保できる。 If the pressure contact pressure when connecting the wiring material to the connection electrode via an adhesive is too high, peeling between the solar cell and the connection electrode is likely to occur. With the above configuration, the connection between the solar cell and the connection electrode can be secured at the end of the solar cell, which is an important part for the connection between the solar cell and the wiring member.
以下に図面を用いて、本発明の実施の形態を詳細に説明する。以下で述べる温度、圧着応力、寸法等は説明のための例示であって、太陽電池モジュールの仕様に応じ、適宜変更が可能である。以下では、全ての図面において一または対応する要素には同一の符号を付し、重複する説明を省略する。 Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. The temperature, pressure stress, dimensions, and the like described below are illustrative examples, and can be appropriately changed according to the specifications of the solar cell module. Hereinafter, in all the drawings, one or the corresponding element is denoted by the same reference numeral, and redundant description is omitted.
図1は、太陽電池モジュールの製造方法の手順を示すフローチャートである。図2から図4は、このフローチャートにおける各手順を説明する図である。 FIG. 1 is a flowchart showing a procedure of a method for manufacturing a solar cell module. 2 to 4 are diagrams for explaining each procedure in this flowchart.
太陽電池モジュールは、複数の太陽電池を配線材で接続したものであるので、太陽電池モジュールを製造するには、太陽電池を準備する。太陽電池の準備のためには、まず光電変換部11を形成する(S10)。
Since the solar cell module is formed by connecting a plurality of solar cells with a wiring material, a solar cell is prepared in order to manufacture the solar cell module. In order to prepare the solar cell, first, the
図2は、太陽電池10を示す図で、図2(a)は平面図、(b)は側面図である。太陽電池10は、太陽光等の光を受光することで正孔および電子の光生成キャリアを生成する光電変換部11を備える。太陽電池10は、主面として、太陽電池10の外部からの光が主に入射する面である受光面と、受光面と反対側の面である裏面とを有するが、図2の平面図では受光面が示されている。
FIG. 2 is a diagram showing the
光電変換部11は、例えば、結晶性シリコン(c-Si)、ガリウム砒素(GaAs)、インジウム燐(InP)等の半導体材料の基板を有する。光電変換部11の構造は、広義のpn接合である。例えば、n型単結晶シリコン基板と非晶質シリコンのヘテロ接合を用いることができる。この場合、受光面側の基板上に、i型非晶質シリコン層と、ボロン(B)等がドープされたp型非晶質シリコン層と、酸化インジウム(In2O3)の透光性導電酸化物で構成される透明導電膜(TCO)12を積層し、基板の裏面側に、i型非晶質シリコン層と、燐(P)等がドープされたn型非晶質シリコン層と、透明導電膜13を積層する構造とできる。
The
光電変換部11は、太陽光等の光を電気に変換する機能を有すれば、これ以外の構造であってもよい。例えば、p型多結晶シリコン基板と、その受光面側に形成されたn型拡散層と、その裏面側に形成されたアルミニウム金属膜とを備える構造であってもよい。
The
図1に戻り、光電変換部11が形成されると、太陽電池10の受光面に受光面側の接続用電極20が形成される。受光面側の接続用電極20は、透明導電膜12の表面に導電ペーストを所定のパターンに印刷して形成される。
1, when the
導電ペーストは、溶剤を用いて導電性粒子を樹脂に混入させたものである。導電ペーストとしては様々な種類があり、用途に応じて使い分けることができる。例えば、バインダ樹脂中に銀(Ag)等の導電性粒子が分散された導電性ペーストを用いることができる。ここでは、導電性を向上させたものとして、加熱によりネットワーク構造となる焼結型導電ペーストを用いて、接続用電極20を形成する(S11)。
The conductive paste is obtained by mixing conductive particles into a resin using a solvent. There are various types of conductive pastes, which can be used properly according to the application. For example, a conductive paste in which conductive particles such as silver (Ag) are dispersed in a binder resin can be used. Here, the
ネットワーク構造は、導電性粒子が互いに融着した構造である。例えば、導電性粒子を含む導電性ペーストを加熱することで、導電性粒子を互いに融着させてネットワーク構造を形成することができる。本実施の形態では、ネットワーク構造とは、顕微鏡下で観察される導電性粒子の50%以上が互いに融着した構造とする。 The network structure is a structure in which conductive particles are fused to each other. For example, by heating a conductive paste containing conductive particles, the conductive particles can be fused together to form a network structure. In this embodiment mode, the network structure is a structure in which 50% or more of conductive particles observed under a microscope are fused to each other.
加熱によりネットワーク構造となる焼結型導電ペーストは、溶剤を用いて複数の球状粉21をエポキシ樹脂等の樹脂と混ぜ合わせたものである。球状粉21は、ほぼ球状の導電性の粒子である。導電ペーストを加熱すると、球状粉21が互いに融着して、ネットワーク構造を形成する。このネットワーク構造のため、接続用電極20の導電性が向上する。
The sintered conductive paste that becomes a network structure by heating is obtained by mixing a plurality of
接続用電極20は、球状粉21に加えてフレークを含んでもよい。フレークは、粉末粒子の長径と厚さの比が(長径/厚さ)≧10であり、平均粒子径が約2~5μm以上の導電性粒子のことをいう。フレークは、例えば、球状粉21を押しつぶして扁平な形状とすることで得ることができる。フレークはネットワーク構造を分断する作用を有するので、融着によって生じる応力を緩和する働きを有する。導電性の向上と応力緩和の兼ね合い等に基づいて、球状粉21とフレークの混合比を定めることができる。
The
なお、太陽電池10の受光面に光生成キャリアを集電するために設けられる受光面電極としては、接続用電極20として働くバスバー電極の他に、フィンガ電極が配置される。図2では、フィンガ電極の図示を省略した。
In addition, as a light-receiving surface electrode provided for collecting photogenerated carriers on the light-receiving surface of the
フィンガ電極は、受光面の全体から集電するが、遮光性を少なくするように、細線化した細線電極である。フィンガ電極とバスバー電極は、互いに直交して配置されて電気的に接続される。フィンガ電極の幅としては30μmから150μm程度が好ましく、厚さは10μmから80μm程度が好ましい。隣接するフィンガ電極の間隔は、0.5mmから3mm程度が好ましい。接続用電極20であるバスバー電極の幅としては50μmから3mm程度が好ましく、厚さは10μmから160μm程度が好ましい。
The finger electrode is a thin wire electrode that collects electricity from the entire light receiving surface but is thinned so as to reduce the light shielding property. The finger electrode and the bus bar electrode are arranged orthogonally to each other and electrically connected. The width of the finger electrode is preferably about 30 μm to 150 μm, and the thickness is preferably about 10 μm to 80 μm. The interval between adjacent finger electrodes is preferably about 0.5 mm to 3 mm. The width of the bus bar electrode as the
太陽電池10の裏面においても、光電変換部11の裏面側の透明導電膜13の表面に裏面側の接続用電極23が形成される。裏面側の接続用電極23も、受光面側の接続用電極20と同様に、球状粉21を含み、加熱によりネットワーク構造となる焼結型導電ペーストを用いて形成される。裏面側の接続用電極23も受光面側と同様に、球状粉21に加えてさらにフレークを含んでもよい。
Also on the back surface of the
再び図1に戻り、次に、配線材の配置が行われる。配線材の配置は、太陽電池10の受光面側の接続用電極20に接着剤24を介して配線材25を配置し、同様に、太陽電池10の裏面側の接続用電極23に接着剤26を介して配線材27を配置し、互いに分離しないように、軽く押え、適当な温度に加熱して行われる(S12)。
Returning to FIG. 1 again, next, the wiring material is arranged. As for the arrangement of the wiring material, the
図3は、接続用電極20,23に対し接着剤24,26を介して配線材25,27の配置が行われた状態の太陽電池モジュールを示す図で、図3(a)は平面図、(b)は側面図である。
FIG. 3 is a diagram showing the solar cell module in a state where the
配線材25,27は、銅等の金属導電性材料を構成材料とする薄板である。薄板に代えて撚り線状のものを用いることもできる。導電性材料としては、銅の他に、銀、アルミニウム、ニッケル、錫、金、あるいはこれらの合金を用いることができる。配線材25は、太陽電池10の受光面側の接続用電極20の配置方向に沿って、接続用電極20を覆うように配置されることが好ましく、配線材25の幅は、接続用電極20の幅と同じか、やや太めに設定するとよい。同様に、裏面側の配線材27の幅は、裏面側の接続用電極23の幅と同じか、やや太めに設定するとよい。
The
接着剤24は、受光面側の接続用電極20と配線材25との間に配置され、接続用電極20と配線材25とを電気的に接続し、太陽電池10の受光面側と配線材25とを機械的に固定するために用いられる。同様に、接着剤26は、裏面側の接続用電極23と配線材27との間に配置され、接続用電極23と配線材27とを電気的に接続し、太陽電池10の裏面側と配線材27とを機械的に固定するために用いられる。
The adhesive 24 is disposed between the
接着剤24,26としては、アクリル系、柔軟性の高いポリウレタン系、あるいはエポキシ系等の熱硬化性樹脂接着剤を用いることができる。接着剤24,26の硬化温度θHは、太陽電池10の耐熱性等から、約130℃~300℃の間で選定される。
As the
接着剤24,26には、導電性粒子が含まれる。導電性粒子としては、ニッケル、銀、金コート付ニッケル、錫メッキ付銅等を用いることができる。接着剤24,26として、導電性粒子を含まない絶縁性の樹脂接着剤を用いることもできる。この場合には、配線材25,27または接続用電極20,23の互いに対向する面のいずれか一方または双方を凹凸化して、配線材25と接続用電極20の間、配線材27と接続用電極23の間から樹脂を適当に排除して電気的接続を取るようにする。受光面側は、配線材25と接続用電極20の向かい合う面の間の接着力と、太陽電池10の受光面と配線材25の側面に形成される樹脂のフィレットによる接着力によって接着される。同様に、裏面側においても、配線材27と接続用電極23の向かい合う面の間の接着力と、太陽電池10の受光面と配線材27の側面に形成される樹脂のフィレットによる接着力によって接着される。
The
再び図1に戻り、配線材の配置処理が終わると、次に、圧着処理が行われる。圧着処理は、配線材25,27が配置された太陽電池10に対し、端部に低い圧着圧力が印加されるように設計された圧着ツールをセットし(S13)、圧着ツールを所定の押付圧で押し付け、所定温度で加熱して接着剤を硬化させる処理である(S14)。
Referring back to FIG. 1 again, after the wiring material placement process is completed, the crimping process is performed. In the crimping process, a crimping tool designed so that a low crimping pressure is applied to the end of the
図3で端部と中央部の位置関係を示したが、端部は、配線材25,27の長手方向において、太陽電池10の端面側の領域である。端部の領域は、太陽電池10の光生成キャリアの集電に対する寄与を考慮して定めることができる。例えば、フィンガ電極の総本数に対し、太陽電池10の端面から数えて予め定めた本数となる領域を端部とすることができる。あるいは、太陽電池10の端面から内側に予め定めた幅の領域とすることができる。一例として、太陽電池10の端面から内側に約20mmを端部とすることができる。この数字は一例であって、太陽電池10の仕様に応じて変更できる。
FIG. 3 shows the positional relationship between the end portion and the center portion, but the end portion is a region on the end face side of the
図4は、圧着ツールを用いて圧着処理が行われる様子を示す図である。圧着ツールは、下ツール30と、下ツール30に対し相対的に昇降する上ツール31を含み、配線材が配置された太陽電池を下ツール30の上に載置し、下ツール30に対し上ツール31を下降させて、下ツール30に対し上ツール31に所定の押付力Fを印加する装置である。また、下ツール30と上ツール31にはそれぞれ加熱部32,33が配置され、配線材が配置された太陽電池が所定の加熱温度で加熱される。加熱部32,33としては、抵抗線ヒータ、加熱ランプ、加熱風供給装置等を用いることができる。このように、圧着ツールは、加圧加熱装置である。
FIG. 4 is a diagram illustrating a state in which a crimping process is performed using a crimping tool. The crimping tool includes a
下ツール30と上ツール31は、圧着面において、端部よりも中央部が突き出す凸形状を有する。図4では、破線の円形で囲んだ部分において、下ツール30の端部と配線材27との間に隙間が生じ、上ツール31の端部と配線材25との間に隙間が生じることで、このことを示した。なお、図4の隙間の大きさは説明のために誇張してある。端部より中央部が突き出す形状は、中央部が平坦で、その平坦部から端面に向かって徐々に隙間が大きくなるようにする。隙間の増加の程度は、実験的に定めることがよい。実験結果によって、例えば、端面に向かって隙間を直線的に増加するようにしてもよく、曲線的に増加するようにしてもよい。
The
図4では、下ツール30と上ツール31がそれぞれ1つずつ図示されているが、図2、図3で示されるように、配線材25,27は、それぞれ平行に3本ある。これに合わせ、下ツール30をそれぞれ平行に3つ備えられるものとし、上ツール31もそれぞれ平行に3つ備えたものとできる。この場合には、1本の配線材を挟んで向かい合う1つの下ツールと1つの上ツールが対となり、例えば、3つの対が一体となって、相対的に昇降するようにすればよい。
In FIG. 4, one
圧着処理における加熱温度θは、接着剤24,26の硬化温度以上に設定される。θは、圧着処理のサイクルタイムで定まる加熱時間が短いほど高温に設定される。例えば、加熱時間を十分長く取れるときは、θを硬化温度とできるが、加熱時間が数秒のときは、θを硬化温度よりも高い温度とする。
The heating temperature θ in the crimping process is set to be equal to or higher than the curing temperature of the
押付力Fは、圧着圧力Pが0.1MPa~0.2MPaとなるように設定される。ここで、押付力Fは、下ツール30に対して上ツール31から印加される荷重力であってN(ニュートン)の次元を有する。圧着圧力Pは、N/m2の次元を有し、下ツール30と配線材27が接触する面、上ツール31と配線材27が接触する面に印加される単位面積当たりの力である。
The pressing force F is set so that the pressure P is 0.1 MPa to 0.2 MPa. Here, the pressing force F is a load force applied from the
端部よりも中央部が突き出す凸形状を有する下ツール30と上ツール31の間に、配線材が配置された太陽電池を挟み、下ツール30に対し上ツール31に押付力Fを印加すると、太陽電池の中央部で厚さ方向の変形量が大きく、端部で厚さ方向の変形量が小さくなる。変形量は、受光面側の配線材25から裏面側の配線材27までの全体の厚さについてである。変形量が大きい中央部では、厚さ方向に大きな圧縮応力を受けるが、変形量が小さい端部で受ける圧縮応力は小さくなる。この圧縮応力が圧着圧力Pに対応する。
When a solar cell in which a wiring material is arranged is sandwiched between a
図5に圧着圧力Pの分布を示した。横軸は、配線材の長手方向に沿った太陽電池の位置で、縦軸は圧着圧力Pである。中央部ではP=P0の一定値で、中央部と端部の境界から太陽電池の端面に向かって、圧着圧力PはP0から徐々に小さくなる。 FIG. 5 shows the distribution of the pressure P. The horizontal axis is the position of the solar cell along the longitudinal direction of the wiring material, and the vertical axis is the pressure P. In the central part, P = P 0 is a constant value, and the pressure P is gradually reduced from P 0 toward the end face of the solar cell from the boundary between the central part and the end part.
再び図1に戻り、圧着処理が終了すると、太陽電池モジュールとするための残りの処理が行われる(S15)。ここでは、受光面側の保護部材と、裏面側の保護部材の間に、圧着処理が終わった太陽電池モジュールを位置決めし、受光面側の保護部材と、裏面側の保護部材の間に充填材を配置する。受光面側の保護部材および裏面側の保護部材の端部には、フレームが配置される。 Returning to FIG. 1 again, when the crimping process is completed, the remaining process for obtaining the solar cell module is performed (S15). Here, the solar cell module subjected to the crimping process is positioned between the light-receiving surface side protection member and the back-surface side protection member, and the filler is provided between the light-receiving surface-side protection member and the back surface-side protection member. Place. Frames are arranged at the ends of the light receiving surface side protective member and the back surface side protective member.
受光面側の保護部材としては、透明な板体、フィルムが用いられる。例えば、ガラス板、樹脂板、樹脂フィルム等の透光性を有する部材を用いることができる。裏面側の保護部材は、受光面側の保護部材と同じものを用いることができる。裏面側からの受光を必要としない構造の太陽電池モジュールの場合は、裏面側の保護部材として、不透明な板体やフィルムを用いることができる。例えば、アルミ箔を内部に有する樹脂フィルム等の積層フィルムを用いることができる。充填材は、EVA、EEA、PVB、シリコーン系樹脂、ウレタン系樹脂、アクリル系樹脂、エポキシ系樹脂等を用いることができる。このようにして、太陽電池モジュールが製造される。 A transparent plate or film is used as the protective member on the light receiving surface side. For example, a translucent member such as a glass plate, a resin plate, or a resin film can be used. As the protective member on the back surface side, the same protective member as that on the light receiving surface side can be used. In the case of a solar cell module having a structure that does not require light reception from the back side, an opaque plate or film can be used as the protective member on the back side. For example, a laminated film such as a resin film having an aluminum foil inside can be used. As the filler, EVA, EEA, PVB, silicone resin, urethane resin, acrylic resin, epoxy resin, or the like can be used. Thus, a solar cell module is manufactured.
上記では、端部における圧着圧力を中央部における圧着応力より低くするために、端部よりも中央部が突き出す凸形状を有する下ツール30と上ツール31を用いたが、図6に示すように、接続用電極34,35の端部の厚さを中央部の厚さより薄くしてもよい。この場合、圧着面の全体が平坦な下ツール36と上ツール37を用いて接続用電極34,35の圧着処理を行うことができる。これにより、下ツール36と上ツール37の圧着面を中央部から端部に渡って平坦面とすることができ、従来技術と共通の圧着ツールを用いることができる。
In the above, the
図6では、破線の円形で囲んだ部分において、裏面側の接続用電極35の端部と配線材27との間に隙間が生じ、受光面側の接続用電極34の端部と配線材25との間に隙間が生じることで、このことを示した。図4と同様に、隙間の大きさは説明のために誇張してある。中央部の厚さよりも端部の厚さが薄くなる形状は、中央部の厚さを一定とし、中央部から端面に向かって徐々に厚さが薄くなるようにする。厚さの減少の程度は、実験的に定めることがよい。実験結果によって、例えば、端面に向かって厚さを直線的に減少するようにしてもよく、曲線的に減少するようにしてもよい。
In FIG. 6, a gap is formed between the end portion of the
図5のように、太陽電池10の端部における圧着圧力を中央部における圧着圧力より低くするのは、太陽電池10と配線材25,27との接続にとって重要な個所である太陽電池10の端部において、太陽電池10と接続用電極20,23の間の剥離を抑制して、接続を確保するためである。
As shown in FIG. 5, the pressure at the end of the
太陽電池10と配線材25,27との接続に関する剥離を説明するために、太陽電池10の受光面側の断面図を図7に示す。太陽電池10と配線材25との間において剥離が生じ得る箇所は3つある。1つ目は、光電変換部11上の透明導電膜12と接続用電極20との間の第1の接合の剥離である。図7では、第1の接合を(12-20)として示した。2つ目は、接続用電極20自体の間での電極間剥離である。図7では、この部分を(20-20)として示した。3つ目は、接着剤24を介した接続用電極20と配線材25との間の第2の接合の剥離である。図7では、第2の接合を(20-25)として示した。これ以外に、光電変換部11と透明導電膜12との境界、配線材25自体の間での配線材間剥離が考えられるが、これらで剥離が生じることはほとんどない。
FIG. 7 shows a cross-sectional view of the light receiving surface side of the
ここで、従来技術で用いられる圧着面が平坦な圧着ツールを用いて配線材の圧着処理を行った場合、太陽電池10の中央部と端部の圧着圧力が同じとなる。ここで、圧着応力が高すぎて第1の接合で圧着応力を受け止めきれないときには、第1の接合の部分において剥離が生じ易くなる。特に、ネットワーク構造を有する焼結型導電ペーストを接続用電極20に用いると、ネットワーク構造の結合力が強いので、接続用電極20自体の強度が高くなる。したがって、相対的に第1の接合の接着強度が弱く、圧着応力が高すぎると、第1の接合で剥離が生じ得る可能性が高まる。
Here, when the crimping process of the wiring material is performed using a crimping tool having a flat crimping surface used in the prior art, the crimping pressure of the central portion and the end portion of the
第1の接合は太陽電池10から電流を取り出すための電気的接合であるので、ここで剥離が生じると、接続用電極20自体および第2の接合が強固であっても問題である。したがって、第1の接合の剥離の防止が重要となる。特に、太陽電池モジュールでは、隣り合う太陽電池10の間において配線材25が屈曲しており、屈曲部分に近い太陽電池10の端部付近の配線材25との接着部に、配線材25に生ずる応力が集中する場合が多い。したがって、太陽電池10の端部において、第1の接合における剥離を抑制する必要性が高い。
Since the first junction is an electrical junction for taking out current from the
第1の接合の接着強度と接続用電極20,23における導電性粒子の融着凝集自体の強度との関係は、剥離の発生率によって確認することができる。図8は、図5の圧着圧力分布のときの第1の接合における剥離の発生率を示す図である。横軸は図5と同じで、配線材25,27の長手方向に沿った太陽電池の位置で、縦軸は、(12-20)モード剥離率である。(12-20)モード剥離率とは、太陽電池モジュールの剥離テストにおいて、どの箇所で剥離が生じたかを調べ、図7で説明した第1の接合である(12-20)の箇所で剥離した数を剥離の全体数で除した値である。
The relationship between the adhesive strength of the first joint and the strength of the fusion aggregation of the conductive particles in the
図8に示すように、本実施の形態における太陽電池モジュールでは、(12-20)モード剥離率は、太陽電池10の端部において中央部より低くなる。配線材25,27の圧着処理において太陽電池10の端部における圧着圧力を中央部における圧着圧力より低くすると、接続用電極20,23における導電性粒子の融着凝集の強度が端部において中央部より弱くなる。したがって、太陽電池10の端部において、第1の接合の接着強度が接続用電極20,23における導電性粒子の融着凝集自体の強度よりも相対的に強くなる。これによって太陽電池10の端部においては第1の接合における剥離よりも接続用電極20,23での剥離が生じ易くなり、太陽電池10の端部における(12-20)モード剥離率は中央部に比べ低くなる。このように、太陽電池10の端部における圧着圧力を中央部における圧着圧力より低くすることで、太陽電池10の端部において、太陽電池10と接続用電極20,23の間の剥離を大幅に抑制することができる。
As shown in FIG. 8, in the solar cell module in the present embodiment, the (12-20) mode peeling rate is lower than the central portion at the end of the
図9と図10は、上記の圧着圧力の作用効果を説明する図である。これらの図は、太陽電池モジュールの剥離テストの結果において、太陽電池の端部における剥離を示す図で、図9は、端部の圧着圧力を中央部の圧着圧力と同じとした比較例の場合であり、図7は、図5で示した圧着応力分布とした場合である。 FIG. 9 and FIG. 10 are diagrams for explaining the effect of the above-described pressure bonding pressure. These figures are diagrams showing the peeling at the end of the solar cell in the result of the peeling test of the solar cell module, and FIG. 9 is a comparative example in which the crimping pressure at the end is the same as the crimping pressure at the center. FIG. 7 shows a case where the crimping stress distribution shown in FIG. 5 is used.
比較例の図9では、光電変換部上の透明導電膜と接続用電極との間の接合で剥離が生じ、太陽電池の光電変換部の透明導電膜が露出した面40が現われ、接着剤が一部失われた層42、接続用電極の痕跡41が見えた。
In FIG. 9 of the comparative example, peeling occurs at the junction between the transparent conductive film on the photoelectric conversion portion and the connection electrode, and the
端部の圧着応力を中央部に比べ低くすると、光電変換部上の透明導電膜と接続用電極との間の接合では剥離が生じず、接続用電極において導電性粒子が融着して凝集している部分で剥離が生じた。図10では、接着剤の層43が見え、その下に、接続用電極の融着凝集層で剥離したが透明導電膜に残った層44が示されている。
If the pressure stress at the end is lower than that at the center, peeling does not occur at the joint between the transparent conductive film on the photoelectric conversion portion and the connection electrode, and the conductive particles are fused and aggregated at the connection electrode. Peeling occurred in the part where it was. In FIG. 10, the
このように、太陽電池の端部における圧着圧力を中央部における圧着圧力より低くすることで、太陽電池と配線材との接続にとって重要な個所である太陽電池の端部において、太陽電池と接続用電極の間の接続を確保できる。 Thus, by making the pressure-bonding pressure at the end of the solar cell lower than the pressure-bonding pressure at the center, the solar cell is connected to the solar cell at the end of the solar cell, which is an important part for the connection between the solar cell and the wiring material. Connection between the electrodes can be secured.
10 太陽電池、11 光電変換部、12,13 透明導電膜、20,23,34,35 接続用電極、21 球状粉、24,26 接着剤、25,27 配線材、30,36 下ツール、31,37 上ツール、32,33 加熱部、40 透明導電膜が露出した面、41 接続用電極の痕跡、42 接着剤が一部失われた層、43 接着剤の層、44 接続用電極の融着凝集層で透明導電膜に残った層。 10 solar cell, 11 photoelectric conversion part, 12, 13 transparent conductive film, 20, 23, 34, 35 connection electrode, 21 spherical powder, 24, 26 adhesive, 25, 27 wiring material, 30, 36 lower tool, 31 37, upper tool, 32, 33 heating section, 40 exposed surface of transparent conductive film, 41 trace of connecting electrode, 42 layer partially lost adhesive, 43 adhesive layer, 44 melting of connecting electrode A layer that remains on the transparent conductive film in an aggregated layer.
Claims (5)
前記配線材が配置された前記太陽電池に対し、圧着ツールを所定の圧着圧力で押し付け、前記接着剤を前記硬化温度以上に加熱して硬化させ、
前記圧着ツールの前記所定の圧着圧力は、前記配線材の長手方向に沿った前記太陽電池の端部における圧着圧力が、前記太陽電池の中央部における圧着圧力よりも低い、太陽電池モジュールの製造方法。 Arrange the wiring material through the adhesive to the connection electrode of the solar cell,
Pressing a crimping tool with a predetermined crimping pressure against the solar cell in which the wiring material is disposed, and curing the adhesive by heating it to the curing temperature or higher,
The method for producing a solar cell module, wherein the predetermined pressure of the crimping tool is such that the pressure at the end of the solar cell along the longitudinal direction of the wiring member is lower than the pressure at the center of the solar cell. .
前記太陽電池の前記接続用電極は、加熱により導電性粒子が互いに融着してネットワーク構造を形成した電極である、太陽電池モジュールの製造方法。 In the method for manufacturing a solar cell module according to claim 1,
The method for manufacturing a solar cell module, wherein the connection electrode of the solar cell is an electrode in which conductive particles are fused to each other by heating to form a network structure.
前記接続用電極に対し接着剤を介して接続された配線材と、
を備え、
前記接続用電極自体の強度は、前記配線材の長手方向に沿った前記太陽電池の端部において前記太陽電池の中央部より弱い、太陽電池モジュール。 A solar cell having a connection electrode;
A wiring material connected to the connection electrode via an adhesive;
With
The solar cell module in which the strength of the connection electrode itself is weaker than the central portion of the solar cell at the end of the solar cell along the longitudinal direction of the wiring member.
前記配線材の長手方向に沿った前記太陽電池の端部において、前記接続用電極と前記太陽電池との間の接着強度は前記接続用電極自体の強度よりも強い、太陽電池モジュール。 The solar cell module according to claim 3, wherein
The solar cell module in which the bonding strength between the connection electrode and the solar cell is stronger than the strength of the connection electrode itself at the end of the solar cell along the longitudinal direction of the wiring member.
前記太陽電池の前記接続用電極は、加熱により導電性粒子が互いに融着してネットワーク構造を形成した電極である、太陽電池モジュール。 In the solar cell module according to claim 3 or 4,
The connection electrode of the solar cell is a solar cell module in which conductive particles are fused to each other by heating to form a network structure.
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| JP2014527846A JP5934985B2 (en) | 2012-07-31 | 2012-07-31 | Solar cell module manufacturing method and solar cell module |
| PCT/JP2012/069388 WO2014020673A1 (en) | 2012-07-31 | 2012-07-31 | Method for producing solar cell module and solar cell module |
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| JP2018107217A (en) * | 2016-12-22 | 2018-07-05 | パナソニックIpマネジメント株式会社 | Manufacturing method of solar cell module, and solar cell module |
| CN111009596A (en) * | 2019-12-18 | 2020-04-14 | 许娟娣 | A solar module laminating edge pressing device with automatic feeding |
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| JP2008010857A (en) * | 2006-05-30 | 2008-01-17 | Kyocera Corp | Solar cell module |
| WO2009090915A1 (en) * | 2008-01-17 | 2009-07-23 | Nichia Corporation | Method for producing conductive material, conductive material obtained by the method, electronic device containing the conductive material, light-emitting device, and method for manufacturing light-emitting device |
| WO2012057125A1 (en) * | 2010-10-26 | 2012-05-03 | 三洋電機株式会社 | Method for producing solar cell module |
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2012
- 2012-07-31 WO PCT/JP2012/069388 patent/WO2014020673A1/en not_active Ceased
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| JP2001102727A (en) * | 1999-09-28 | 2001-04-13 | Seiko Epson Corp | Structure of temporary crimping tool for resin film |
| JP2008010857A (en) * | 2006-05-30 | 2008-01-17 | Kyocera Corp | Solar cell module |
| WO2009090915A1 (en) * | 2008-01-17 | 2009-07-23 | Nichia Corporation | Method for producing conductive material, conductive material obtained by the method, electronic device containing the conductive material, light-emitting device, and method for manufacturing light-emitting device |
| WO2012057125A1 (en) * | 2010-10-26 | 2012-05-03 | 三洋電機株式会社 | Method for producing solar cell module |
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| JP2018107217A (en) * | 2016-12-22 | 2018-07-05 | パナソニックIpマネジメント株式会社 | Manufacturing method of solar cell module, and solar cell module |
| CN111009596A (en) * | 2019-12-18 | 2020-04-14 | 许娟娣 | A solar module laminating edge pressing device with automatic feeding |
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| JPWO2014020673A1 (en) | 2016-07-11 |
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