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WO2013150305A3 - Alcohol production process - Google Patents

Alcohol production process Download PDF

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Publication number
WO2013150305A3
WO2013150305A3 PCT/GB2013/050881 GB2013050881W WO2013150305A3 WO 2013150305 A3 WO2013150305 A3 WO 2013150305A3 GB 2013050881 W GB2013050881 W GB 2013050881W WO 2013150305 A3 WO2013150305 A3 WO 2013150305A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
precipitate
polyhydric alcohol
palladium
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2013/050881
Other languages
French (fr)
Other versions
WO2013150305A2 (en
Inventor
Shik Chi Edman Tsang
Cheng-Tar Wu
Kai Man YU
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oxford University Innovation Ltd
Original Assignee
Oxford University Innovation Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxford University Innovation Ltd filed Critical Oxford University Innovation Ltd
Publication of WO2013150305A2 publication Critical patent/WO2013150305A2/en
Publication of WO2013150305A3 publication Critical patent/WO2013150305A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention provides a process for producing a monohydric alcohol by hydrogenolysis of a polyhydric alcohol, which process comprises treating a polyhydric alcohol with hydrogen in the presence of a solid catalyst, which solid catalyst comprises (a) iron oxide and (b) a metal which is a noble metal or nickel. The invention further provides a catalyst, which catalyst comprises iron oxide and nanoparticles which comprise palladium. A process for producing the catalyst is also provided, which process comprises: (1) a co-precipitation step, comprising contacting (a) a solution, which solution comprises a palladium salt and an iron salt dissolved in a solvent, with (b) a base, to produce a precipitate which comprises one or more compounds comprising said iron and said palladium; (2) a separation step, comprising separating the precipitate from the solvent; and (3) a calcination step, comprising calcining the precipitate by heating the precipitate in air. Further provided is the use of the catalyst of the invention for the hydrogenolysis of a polyhydric alcohol.
PCT/GB2013/050881 2012-04-04 2013-04-04 Alcohol production process Ceased WO2013150305A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1206042.2 2012-04-04
GBGB1206042.2A GB201206042D0 (en) 2012-04-04 2012-04-04 Alcohol production process

Publications (2)

Publication Number Publication Date
WO2013150305A2 WO2013150305A2 (en) 2013-10-10
WO2013150305A3 true WO2013150305A3 (en) 2013-11-28

Family

ID=46160329

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2013/050881 Ceased WO2013150305A2 (en) 2012-04-04 2013-04-04 Alcohol production process

Country Status (2)

Country Link
GB (1) GB201206042D0 (en)
WO (1) WO2013150305A2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107262045A (en) * 2017-08-03 2017-10-20 中国科学院化学研究所 Application of the fullerene MOF composites in volatile organic matter is removed
CN107490610A (en) * 2017-09-05 2017-12-19 济南大学 A kind of chiral MOF graphene hybrid materials and its preparation method and application

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103922893B (en) * 2014-04-19 2015-11-25 青岛科技大学 A kind of composite catalyst hydrogenolysis catalysis of glycerin prepares the method for 1,2-PD
CN104086369B (en) * 2014-06-18 2017-04-05 华南理工大学 The method that manioc waste hydrogenolysis prepares lower alcohol
CN104492436B (en) * 2014-12-12 2016-09-07 中国科学院西双版纳热带植物园 A kind of carbon back magnetic solid base catalyst and application thereof
CN106565393A (en) * 2015-10-13 2017-04-19 吴倍任 Composite material for catalytic hydrogenolysis reaction and preparation method and application thereof
JP2018153735A (en) * 2017-03-16 2018-10-04 株式会社東芝 Chemical reaction system
CN106902842A (en) * 2017-03-20 2017-06-30 北京工业大学 A kind of preparation and application for deriving load type palladium catalyst of the carbon-based material as carrier with MOFs
CN109304213B (en) * 2017-07-28 2021-04-02 中国科学院宁波材料技术与工程研究所 A kind of hydrocracking catalyst and its preparation method and application
CN108579810B (en) * 2018-03-12 2020-09-11 北京科技大学 Method for synthesizing precious metal MOFs composite material
CN116037111B (en) * 2023-02-14 2025-01-14 西安理工大学 Bimetallic single atom catalyst and its preparation method and application

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1826180A1 (en) * 2004-10-21 2007-08-29 Peking University A composite material composed of nanoparticles of transition metal and magnetic ferric oxide, a methode of preparing the same, and uses of the same
WO2008156320A1 (en) * 2007-06-19 2008-12-24 Postech Academy-Industry Foundation Magnetic nanocatalyst composition and method for the preparation thereof
US20090088317A1 (en) * 2007-09-28 2009-04-02 Frye Jr John G Multi-metal reduction catalysts and methods of producing reduction catalysts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1826180A1 (en) * 2004-10-21 2007-08-29 Peking University A composite material composed of nanoparticles of transition metal and magnetic ferric oxide, a methode of preparing the same, and uses of the same
WO2008156320A1 (en) * 2007-06-19 2008-12-24 Postech Academy-Industry Foundation Magnetic nanocatalyst composition and method for the preparation thereof
US20090088317A1 (en) * 2007-09-28 2009-04-02 Frye Jr John G Multi-metal reduction catalysts and methods of producing reduction catalysts

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107262045A (en) * 2017-08-03 2017-10-20 中国科学院化学研究所 Application of the fullerene MOF composites in volatile organic matter is removed
CN107490610A (en) * 2017-09-05 2017-12-19 济南大学 A kind of chiral MOF graphene hybrid materials and its preparation method and application
CN107490610B (en) * 2017-09-05 2019-09-27 济南大学 A kind of chiral MOF-graphene hybrid material and its preparation method and application

Also Published As

Publication number Publication date
WO2013150305A2 (en) 2013-10-10
GB201206042D0 (en) 2012-05-16

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