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WO2013092322A3 - Verfahren zur herstellung von expandierbaren, graphit- und flammschutzmittelhaltigen styrolpolymerisaten - Google Patents

Verfahren zur herstellung von expandierbaren, graphit- und flammschutzmittelhaltigen styrolpolymerisaten Download PDF

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Publication number
WO2013092322A3
WO2013092322A3 PCT/EP2012/075150 EP2012075150W WO2013092322A3 WO 2013092322 A3 WO2013092322 A3 WO 2013092322A3 EP 2012075150 W EP2012075150 W EP 2012075150W WO 2013092322 A3 WO2013092322 A3 WO 2013092322A3
Authority
WO
WIPO (PCT)
Prior art keywords
flame retardant
styrene polymers
producing expandable
polymers containing
expandable styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/075150
Other languages
English (en)
French (fr)
Other versions
WO2013092322A2 (de
Inventor
Frank Braun
Patrick Spies
Sabine Fuchs
Rainer Ostermann
Andreas Kleinke
Klaus Hahn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
BASF SE
Original Assignee
BASF Schweiz AG
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Schweiz AG, BASF SE filed Critical BASF Schweiz AG
Priority to US14/367,253 priority Critical patent/US20140364524A1/en
Priority to CN201280063539.0A priority patent/CN104011119B/zh
Priority to KR1020147019285A priority patent/KR20140105823A/ko
Priority to EP12808760.8A priority patent/EP2794740A2/de
Publication of WO2013092322A2 publication Critical patent/WO2013092322A2/de
Publication of WO2013092322A3 publication Critical patent/WO2013092322A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2400/00—Characterised by the use of unspecified polymers
    • C08J2400/30—Polymeric waste or recycled polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02—Homopolymers or copolymers of hydrocarbons
    • C08J2425/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02—Homopolymers or copolymers of hydrocarbons
    • C08J2425/04—Homopolymers or copolymers of styrene
    • C08J2425/08—Copolymers of styrene
    • C08J2425/10—Copolymers of styrene with conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten durch Polymerisation von mindestens einem vinylaromatischen Monomeren in wässriger Suspension in Gegenwart von mindestens einem halogenierten Polymeren als Flammschutzmittel, Graphit und Treibmittel, dadurch gekennzeichnet, dass die wässrige Suspension zu Beginn der Polymerisation 1 bis 30 Gew.-% mindestens eines Styrolpolymerisates, bezogen auf die Summe aus Monomeren und Styrolpolymerisat, enthält und das zu Beginn der Polymerisation eingesetzte Styrolpolymerisat ebenfalls mindestens ein halogeniertes Polymer als Flammschutzmittel enthält.
PCT/EP2012/075150 2011-12-21 2012-12-12 Verfahren zur herstellung von expandierbaren, graphit- und flammschutzmittelhaltigen styrolpolymerisaten Ceased WO2013092322A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US14/367,253 US20140364524A1 (en) 2011-12-21 2012-12-12 Method for producing expandable styrene polymers containing graphite and flame retardant
CN201280063539.0A CN104011119B (zh) 2011-12-21 2012-12-12 制备包含石墨和阻燃剂的可膨胀苯乙烯聚合物的方法
KR1020147019285A KR20140105823A (ko) 2011-12-21 2012-12-12 그래파이트 및 난연제 함유 발포성 스티렌 폴리머의 제조 방법
EP12808760.8A EP2794740A2 (de) 2011-12-21 2012-12-12 Verfahren zur herstellung von expandierbaren, graphit- und flammschutzmittelhaltigen styrolpolymerisaten

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11194869.1 2011-12-21
EP11194869 2011-12-21

Publications (2)

Publication Number Publication Date
WO2013092322A2 WO2013092322A2 (de) 2013-06-27
WO2013092322A3 true WO2013092322A3 (de) 2013-12-27

Family

ID=47469939

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2012/075150 Ceased WO2013092322A2 (de) 2011-12-21 2012-12-12 Verfahren zur herstellung von expandierbaren, graphit- und flammschutzmittelhaltigen styrolpolymerisaten

Country Status (5)

Country Link
US (1) US20140364524A1 (de)
EP (1) EP2794740A2 (de)
KR (1) KR20140105823A (de)
CN (1) CN104011119B (de)
WO (1) WO2013092322A2 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9458301B2 (en) 2012-12-28 2016-10-04 Total Research & Technology Feluy Expandable vinyl aromatic polymers containing graphite particles having a polymodal particle size distribution
WO2015065393A1 (en) * 2013-10-30 2015-05-07 Dow Global Technologies Llc Foamed styrenic polymers containing a brominated styrene-butadiene copolymer and having enhanced cell size homogeneity
KR102209565B1 (ko) 2013-11-14 2021-02-01 가부시키가이샤 가네카 스티렌계 수지 압출 발포체 및 그의 제조 방법
CN105860305A (zh) * 2015-01-23 2016-08-17 江苏业达鑫化工有限公司 一种功能性石墨母粒的制备方法及其应用
CA3023668C (en) 2016-05-11 2024-02-06 Owens Corning Intellectual Capital, Llc Polymeric foam comprising low levels of brominated flame retardant and method of making same
KR102265483B1 (ko) 2019-04-29 2021-06-15 한국세라믹기술원 난연성 에폭시 조성물 및 그 제조 방법
US11970598B2 (en) * 2020-08-07 2024-04-30 Abb Schweiz Ag Reinforced intumescent polymer

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3956203A (en) * 1972-08-03 1976-05-11 Badische Anilin- & Soda-Fabrik Aktiengesellschaft Manufacture of particulate expandable styrene polymers requiring shot minimum residence times in the mold
WO2010140882A1 (en) * 2009-06-02 2010-12-09 Synbra Technology B.V. Particulate, expandable polystyrene as well as a method for preparing the same
WO2011133035A1 (en) * 2010-04-21 2011-10-27 Synbra Technology B.V. Insulating foamed moulded part

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4431211A1 (de) * 1994-09-02 1996-03-07 Basf Ag Recyclat enthaltende, expandierbare Styrolpolymerisate
PL186332B1 (pl) 1997-05-14 2003-12-31 Basf Ag Sposób wytwarzania spienialnych polimerów styrenuzawierających cząstki grafitu, spienialne polimery styrenu oraz sposób wytwarzania pianek polistyrenowych
DE19742910A1 (de) 1997-09-29 1999-04-01 Basf Ag Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten
DE10101432A1 (de) * 2001-01-13 2002-07-18 Basf Ag Kohlenstoffpartikel enthaltende expandierbare Styrolpolymerisate
DE10150405A1 (de) 2001-10-11 2003-04-17 Basf Ag Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten
ATE455796T1 (de) 2005-11-12 2010-02-15 Dow Global Technologies Inc Brominierte butadien-/vinylaromatische copolymere,mischungen solcher copolymere mit einem vinylaromatischen polymer und aus solchen mischungen geformte polymerschaumstoffe
PL1994085T3 (pl) 2006-03-07 2009-10-30 Basf Se Sposób wytwarzania spienialnych polimerów styrenu
AU2010329986B2 (en) * 2009-12-10 2014-12-04 Akzo Nobel Chemicals International B.V. Process for the polymerization of styrene
DE102009059781A1 (de) 2009-12-18 2011-06-22 Basf Se, 67063 Flammgeschützte Polymerschaumstoffe

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3956203A (en) * 1972-08-03 1976-05-11 Badische Anilin- & Soda-Fabrik Aktiengesellschaft Manufacture of particulate expandable styrene polymers requiring shot minimum residence times in the mold
WO2010140882A1 (en) * 2009-06-02 2010-12-09 Synbra Technology B.V. Particulate, expandable polystyrene as well as a method for preparing the same
WO2011133035A1 (en) * 2010-04-21 2011-10-27 Synbra Technology B.V. Insulating foamed moulded part

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2794740A2 *

Also Published As

Publication number Publication date
WO2013092322A2 (de) 2013-06-27
EP2794740A2 (de) 2014-10-29
KR20140105823A (ko) 2014-09-02
CN104011119A (zh) 2014-08-27
US20140364524A1 (en) 2014-12-11
CN104011119B (zh) 2016-08-24

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