WO2013065162A1 - Vacuum heat insulating material, method for manufacturing same, heat retaining tank using same, and heat pump water heater - Google Patents
Vacuum heat insulating material, method for manufacturing same, heat retaining tank using same, and heat pump water heater Download PDFInfo
- Publication number
- WO2013065162A1 WO2013065162A1 PCT/JP2011/075360 JP2011075360W WO2013065162A1 WO 2013065162 A1 WO2013065162 A1 WO 2013065162A1 JP 2011075360 W JP2011075360 W JP 2011075360W WO 2013065162 A1 WO2013065162 A1 WO 2013065162A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat insulating
- insulating material
- vacuum heat
- vacuum
- fiber sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/06—Arrangements using an air layer or vacuum
- F16L59/065—Arrangements using an air layer or vacuum using vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/18—Water-storage heaters
- F24H1/181—Construction of the tank
- F24H1/182—Insulation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H4/00—Fluid heaters characterised by the use of heat pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H9/00—Details
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0253—Polyolefin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D17/00—Domestic hot-water supply systems
- F24D17/02—Domestic hot-water supply systems using heat pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D2220/00—Components of central heating installations excluding heat sources
- F24D2220/08—Storage tanks
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D3/00—Hot-water central heating systems
- F24D3/08—Hot-water central heating systems in combination with systems for domestic hot-water supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D3/00—Hot-water central heating systems
- F24D3/18—Hot-water central heating systems using heat pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/54—Water heaters for bathtubs or pools; Water heaters for reheating the water in bathtubs or pools
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/12—Hot water central heating systems using heat pumps
Definitions
- the present invention relates to a vacuum heat insulating material that insulates an object having a non-planar surface, a method for manufacturing the same, a heat retaining tank and a heat pump type water heater using the same.
- Vacuum insulation has been widely used as an insulation material along with an improvement in energy conservation awareness because it can significantly reduce thermal conductivity compared to conventional glass wool insulation. For this reason, it is used not only in a planar shape but also in a curved surface shape.
- Patent Document 1 there has been a structure in which a three-dimensional shape of the vacuum heat insulating material is easily formed by forming a groove shape or an uneven shape on the vacuum heat insulating material.
- a protrusion is formed on the vacuum heat insulating material by clamping the outer packaging material into which the core material is inserted with a mold from above and below in vacuum (Patent Document 1).
- JP 2007-205530 A (p3 to p7, FIGS. 4 to 13)
- a core material made of a lump of fibers such as glass wool is vacuum-sealed by a jacket material, and in order to increase the heat insulating performance of the vacuum heat insulating material, the fiber of the core material Are arranged so as to be close to a right angle with the thickness direction of the vacuum heat insulating material.
- the core material (core material) is vacuum-sealed with an outer packaging material (cover material), so that the protrusion is formed.
- the direction of the fibers approaches the thickness direction of the vacuum heat insulating material.
- the fiber orientation of the core material which is arranged to be perpendicular to the thickness direction of the vacuum heat insulating material before bending, approaches the thickness direction of the vacuum heat insulating material, and the heat insulating performance is improved. There was a decline.
- the present invention was made to solve the above-described problems, and obtains a vacuum heat insulating material having high heat insulating performance even when bent and used, and a vacuum having high heat insulating performance even when bent and used. It aims at providing the manufacturing method of a heat insulating material, and providing the heat retention tank and heat pump type water heater to which this vacuum heat insulating material is applied.
- the vacuum heat insulating material of the present invention is formed by vacuum-sealing a core material having a fiber sheet and having a plurality of convex protrusions formed on one surface with a jacket material.
- the method for manufacturing a vacuum heat insulating material of the present invention includes a step of forming a plurality of convex protrusions on one surface of the fiber sheet, and a core material by arranging the fiber sheet so that the convex protrusions are on the surface. A step of forming, and a step of sealing the core material to the jacket material in a vacuum.
- the cylindrical heat insulating tank of the present invention is provided with the vacuum heat insulating material according to any one of claims 1 to 7.
- the vacuum heat insulating material of the present invention it is possible to prevent uneven wrinkles from occurring inside the bending of the vacuum heat insulating material even when bent, and a vacuum heat insulating material having high heat insulating performance when used by bending. Obtainable.
- vacuum heat insulating material of the present invention is applied to a cylindrical heat insulating tank, energy saving efficiency can be improved by higher heat insulating performance.
- Embodiment 1 of this invention It is a cross-sectional schematic diagram which represents typically the vacuum heat insulating material in Embodiment 1 of this invention. It is a perspective view which represents typically the core material of the vacuum heat insulating material in Embodiment 1 of this invention. It is a schematic diagram which shows the method of forming a convex-shaped protrusion in the fiber sheet of the vacuum heat insulating material in Embodiment 1 of this invention. It is a schematic diagram which shows an example of the embossing pattern for forming a convex protrusion in the fiber sheet of the vacuum heat insulating material in Embodiment 1 of this invention. It is a cross-sectional schematic diagram which represents typically the vacuum heat insulating material in Embodiment 1 of this invention.
- Embodiment 2 of this invention It is a cross-sectional schematic diagram which represents typically the vacuum heat insulating material in Embodiment 2 of this invention. It is a schematic diagram for demonstrating the manufacturing process of the vacuum heat insulating material in Embodiment 2 of this invention. It is a cross-sectional schematic diagram which represents typically the vacuum heat insulating material in Embodiment 3 of this invention. It is a cross-sectional schematic diagram which represents typically the vacuum heat insulating material in Embodiment 3 of this invention. It is a cross-sectional schematic diagram which represents typically the vacuum heat insulating material in Embodiment 4 of this invention. It is a cross-sectional schematic diagram which represents typically the vacuum heat insulating material in Embodiment 4 of this invention.
- FIG. 10 is a system flow diagram showing a system configuration of a heat pump type hot water heater showing another example in the sixth embodiment.
- Embodiment 1 is a schematic cross-sectional view showing a vacuum heat insulating material in Embodiment 1 of the present invention.
- a vacuum heat insulating material 1 is configured such that a core material 3 in which a plurality of fiber sheets 2 are laminated is covered with an outer covering material 4 and is vacuum-sealed.
- a plurality of convex protrusions 5 are formed on the fiber sheet 2 on the surface of the core material 3 on the inner side in the direction in which the vacuum heat insulating material 1 is bent.
- the fiber sheet 2 is made up of about 90% space and the rest is made of glass fibers, and the fibers themselves are arranged in a direction parallel to the sheet surface as much as possible in order to improve heat insulation performance.
- the jacket material 4 is an aluminum laminate sheet in which an AL (aluminum) foil is sandwiched between a plurality of polymer sheets.
- FIG. 2 is a perspective view showing the core material 3 before the vacuum heat insulating material 1 is bent in the present embodiment.
- the upper side of the figure corresponds to the inner side when the vacuum heat insulating material 1 is bent.
- the core material 3 is configured by laminating a plurality of fiber sheets 2, a fiber sheet 2 a with a protrusion is disposed at the uppermost part, and a plurality of protrusions are not provided at the lower part thereof.
- a fiber sheet 2b is arranged.
- the thickness of one fiber sheet 2 is approximately 0.5 mm.
- the convex protrusion 5 formed on the fiber sheet 2 on one surface of the core 3 that is inside the bend is made of the same glass fiber as the fiber sheet 2, and the tip of the convex protrusion 5 has a curved surface. ing.
- the height of the convex protrusion 5 is, for example, about 0.1 to 0.5 mm, and the area ratio of the convex protrusion 5 to the fiber sheet surface area is about 10 to 50%.
- the convex protrusion 5 is regularly arrange
- the manufacturing method of the vacuum heat insulating material 1 in this Embodiment is demonstrated.
- a method for forming the fiber sheet 2 by the papermaking method will be described.
- a large diameter fiber having a diameter of 4 ⁇ m to 13 ⁇ m and a small diameter fiber having a diameter of about 1 ⁇ m are dispersed in a liquid.
- the liquid is used to make a paper roll with an automatic feed paper machine and then dried to produce a sheet roll having a thickness of about 0.5 mm.
- the sheet roll is cut to the required area of the vacuum heat insulating material 1 to obtain a fiber sheet 2.
- the fiber direction of the fiber sheet 2 formed by paper making in this way is mostly perpendicular to the thickness direction of the fiber sheet 2.
- the fiber sheet 2b without protrusions the fiber sheet 2 may be used as it is.
- what is necessary is just to form the convex protrusion 5 in this fiber sheet 2, and to use it as the fiber sheet 2a with a protrusion.
- FIG. 3 is a schematic diagram for explaining a method of forming the convex protrusion 5 by sandwiching the fiber sheet 2 used for the vacuum heat insulating material 1 between the hot embossing roll 10 and the hot roll 11 which are pressurizing mechanisms. As shown in FIG. 3, the fiber sheet 2 is advanced on the roller 21, and the fiber sheet 2 is heated through the gap of the pressurizing mechanism configured by the heat roll 11 and the heat embossing roll 10 set at a predetermined interval. Pressurize.
- Convex protrusions 5 are formed on the surface of the fiber sheet 2 sandwiched between the heat embossing roll 10 and the heat roll 11 to form a fiber sheet 2a with protrusions.
- the hot embossing roll 10 may be a concave shape, and the hot roll 11 may be a convex shape corresponding thereto, and the heat roll 11 may be a flat roll having no unevenness. Further, the hot roll 11 may be used without heating.
- the embossing pattern of the hot embossing roll 10 does not need to have a specific shape, but for example, a regular octagonal shape of embossing 12 as shown in FIG. 4 is regularly arranged. I just need it.
- FIG. 4 is a schematic diagram illustrating an example of an embossing pattern provided on the hot embossing roll 10. In FIG. 4, a pattern of octagonal embosses 12 is regularly arranged. By processing the back side of the emboss 12 into a curved surface, it is possible to form the fiber sheet 2 that is processed with the hot embossing roll 10 to form the convex protrusion 5 having a curved tip.
- the fiber sheet 2a with protrusions and the fiber sheet 2b without protrusions, in which the convex protrusions 5 are formed, are laminated and arranged so that the convex protrusions 5 are on one surface.
- the core material 3 may be formed by laminating one protruding fiber sheet 2 a and one or a plurality of protruding fiber sheets 2 b. And as shown in the cross-sectional schematic diagram of the vacuum heat insulating material 1 of FIG.
- FIG. 5 is a schematic cross-sectional view showing an example of the vacuum heat insulating material 1 of the present embodiment.
- the core material 3 prepared by the above-described method or the like is covered with two outer cover material sheets (not shown) serving as the outer cover material 4 and placed in a vacuum chamber.
- the vacuum chamber is depressurized to a predetermined pressure, for example, a vacuum pressure of about 0.1 to 3 Pa.
- a vacuum pressure of about 0.1 to 3 Pa for example, a vacuum pressure of about 0.1 to 3 Pa.
- the outer peripheral portion of the covering material sheet that becomes the covering material 4 is sealed by heat sealing.
- the vacuum heat insulating material 1 of this Embodiment can be obtained by returning the inside of a vacuum chamber to atmospheric pressure, and cutting
- the envelope material 4 made into a bag in advance may be prepared, and the remaining opening may be sealed in the vacuum chamber after the core material 3 is inserted. Moreover, you may insert a gas adsorbent in the space covered with the jacket material 4 as needed. The internal space of the vacuum heat insulating material 1 manufactured in this way is maintained in a vacuum.
- the vacuum heat insulating material 1 evaluated for heat insulating performance is a core material 3 formed by laminating 25 fiber sheets 2 having a thickness of about 0.5 mm produced by making glass fibers having an average fiber diameter of 5 ⁇ m and 1 ⁇ m.
- the core material 3 is vacuum-sealed with an outer cover material 4 of an aluminum laminate sheet [15 ⁇ m-ONy (stretched nylon) / 12 ⁇ m-AL vapor-deposited PET (polyethylene terephthalate) / 6 ⁇ m-AL foil / 50 ⁇ mPE (unstretched polyethylene)). It was.
- the heat insulating performance is that of the vacuum heat insulating material A (vacuum heat insulating material of the present invention) in which 8 sheets are formed as fiber sheets 2a with protrusions from the surface (inner side in the bending direction) of the core material 3 and the remaining 17 sheets are fiber sheets 2b without protrusions.
- the heat insulating performance was evaluated in comparison with the heat insulating performance of the vacuum heat insulating material E in which the core material 3 is all the fiber sheet 2b without protrusions.
- the fiber sheet 2a with protrusions of the vacuum heat insulating material A softens the material of the heat embossing roll 10 in which the regular hexagonal emboss 12 having a circumscribed circle diameter of 8 mm is formed in a concave shape with an area ratio of 27%.
- the convex projection 5 is formed by pressing at a point temperature.
- the fiber sheet 2a with protrusions was laminated so that the convex protrusions 5 were all in the same direction.
- the thermal conductivity in the flat state without bending was 0.0018 W / mK and 0.0017 W / mK for the vacuum heat insulating material A and the vacuum heat insulating material E, respectively, but a cylindrical shape with a curvature radius of 250 mm by a triaxial roll bender.
- the heat conductivity in the bent state was 0.0020 W / mK and 0.0025 W / mK for the vacuum heat insulating material A and the vacuum heat insulating material E, respectively.
- the fiber sheet 2 Since the fiber sheet 2 has about 90% of its volume as space and the rest as fibers, the void ratio (the ratio of space per volume) is high and stretchable. On the other hand, the jacket material 4 has almost no elasticity.
- the vacuum heat insulating material 1 When the vacuum heat insulating material 1 is bent, there is a difference in circumferential length between the outer side (outer periphery) and the inner side (inner periphery) of the vacuum heat insulating material 1, but the outer covering material 4 outside the bend has little stretchability. Wrinkles occur inside the bend.
- the contact area between the surface of the core material 3 inside the bend and the inner surface of the jacket material 4 can be reduced, and as a result, the core material 3 and the cover material 4 can be reduced from being caught by friction. Therefore, it is possible to prevent large and deep wrinkles from being formed at one place or a small number of places inside the core material 3 when the vacuum heat insulating material 1 is bent, and uniform and small wrinkles can be generated as a whole. And the angle with respect to the thickness direction of the vacuum heat insulating material 1 of the glass fiber of the core material 3 does not become small, and the heat insulation performance of the vacuum heat insulating material 1 can be improved.
- the adhesion between the heat insulating object placed inside the bending of the vacuum heat insulating material 1 and the outer cover material 4 of the vacuum heat insulating material 1 is improved. It can be made high and the heat insulation effect with respect to a heat insulation target object can further be improved.
- the vacuum heat insulating material 1 of this Embodiment of this invention can prevent that a local stress generate
- the vacuum heat insulating material of the present embodiment it is possible to obtain a vacuum heat insulating material having high heat insulating performance and high reliability even when bent and used. Moreover, according to the manufacturing method of the vacuum heat insulating material of this Embodiment, the heat insulating performance and the highly reliable vacuum heat insulating material can be manufactured easily.
- the fibers of the fiber sheet 2 are glass fibers.
- the fibers of the fiber sheet 2 are not necessarily glass fibers, and a polymer material such as polyester, polypropylene, or polystyrene. May be used.
- a polymer material such as polyester, polypropylene, or polystyrene.
- resin pellets are melted and extruded from a nozzle, and then cooled using an ejector or the like while being cooled. Good.
- the spun fibers are accumulated on a belt conveyor to form a low weight sheet (thin sheet). Thereafter, a part of the sheet is heat-sealed with a hot embossing roll 10 to form a sheet roll.
- the fiber sheet 2a with a protrusion can be formed by making the embossing 12 shape of this hot embossing roll 10 into a predetermined shape.
- the fiber sheet 2 is made into a thin sheet and laminated, so that most of the fibers in the fiber sheet 2 are perpendicular to the thickness direction of the fiber sheet 2. Can be directed in any direction.
- the jacket material 4 is an aluminum laminate sheet
- the jacket material 4 is not limited to the aluminum laminate sheet, and if the barrier property is maintained, Other materials may be used.
- the thickness is not limited to that described above.
- Aluminum laminate sheet of the present embodiment [15 ⁇ m-ONy (stretched nylon) / 12 ⁇ m-AL deposited PET (polyethylene terephthalate) / 6 ⁇ m-AL foil / 50 ⁇ m PE (unstretched polyethylene) AL foil or AL deposited film, for example, alumina deposited You may replace with a film, a silica vapor deposition film, etc. Furthermore, another film may be stacked, or the number of film types to be laminated may be reduced.
- FIG. 6 is a schematic diagram for explaining another method for forming the convex protrusion 5 on the fiber sheet 2 used for the vacuum heat insulating material 1.
- the fiber sheet 2 is placed on a mesh 13 having an opening ratio of about 5 to 30%, and hot air is blown by a hot air blower 14. If it does so, the fiber sheet 2 mounted in the part without the mesh 13 will soften, and it will hang down below with dead weight. The portion hanging down due to its own weight becomes a convex protrusion 5 having a curved shape, and thus the convex protrusion 5 can be formed on the fiber sheet 2.
- the height of the convex protrusion 5 can be adjusted by changing the temperature and flow velocity of the hot air.
- the pattern of the mesh 13 may be the same as the emboss pattern as shown in FIG.
- FIG. 7 is a schematic diagram for explaining another method of forming the fiber sheet with protrusions 2a.
- glass fibers are supplied from a fiber supply unit 16 provided on a belt traveling on a belt conveyor 15, and these glass fibers are deposited to form a sheet-like pre-press fiber sheet 18.
- molten glass is discharged from the nozzle by centrifugal force, and immediately after that, glass fiber manufactured by being drawn by a combustion gas (centrifugal method or the like) is supplied.
- a combustion gas centrifugal method or the like
- the sheet roll 19 in which the convex protrusions 5 are formed after being formed by the press roll 17 can be obtained.
- the fiber sheet 2a with protrusions can be obtained.
- a sheet roll 19 without convex protrusions can be formed by the same method, and by cutting this into a predetermined size, The fiber sheet 2b without protrusions can be obtained.
- the binder for binding glass fiber in the range which does not have a big bad influence on performance.
- a drying process for fixing the binder is provided.
- the tip of the convex projection 5 is not necessarily a curved surface, and may have a flat portion at the tip.
- the example of about 0.5 mm was shown as the thickness of the one fiber sheet 2, the thickness of the fiber sheet 2 is not restricted to this, It should just select suitably according to a use and required performance.
- the process of forming the convex protrusion 5 in the fiber sheet 2 was demonstrated separately from the formation process of the fiber sheet 2, the formation process of the fiber sheet 2
- the convex protrusion 5 may be formed during the drying step.
- FIG. 8 schematically shows another manufacturing method for forming the fiber sheet 2.
- the glass fiber discharged from the fiber supply part 16 which supplies the glass fiber produced by the centrifugation method becomes the fiber sheet 18 before a press, and is conveyed by the mesh conveyor 20, and the fiber sheet 18 before a press is carried out. Is formed to a predetermined thickness by the press roll 17.
- the hot air blower 14 blows hot air from above the mesh conveyor 20 onto the sheet roll 19 formed to a predetermined thickness by the press roll 17, thereby changing the fiber sheet 2 a with protrusions to the normal fiber sheet 2 b without protrusions. It can be manufactured in almost the same process.
- the fiber sheet 2 shown in FIG. 8 for example, when a fiber is produced by a centrifugal method or press for the purpose of ensuring the sheet tensile strength of the sheet roll 19 and maintaining the shape of the convex protrusion 5.
- a binder for binding glass fibers is added to the stage of the front fiber sheet 18.
- steam spraying) to the fiber sheet 18 before a press may be provided previously for the purpose of making the glass fiber axial direction which comprises the sheet roll 19 parallel to a conveyor direction. In this case, a drying step is necessary for fixing the binder and evaporating the additional moisture.
- a drying step is also required in the case of a manufacturing method for producing the fiber sheet 2 by a papermaking method.
- the hot air blowing described above also has a drying step, and the fiber sheet 2a with protrusions can be easily formed without particularly providing extra equipment.
- FIG. FIG. 9 is a schematic cross-sectional view of the vacuum heat insulating material 1 according to Embodiment 2 of the present invention.
- a fiber sheet 2 a with protrusions is provided on both inner and outer surfaces (front and back surfaces) of the core material 3 in the bending direction, and a fiber sheet 2 b without protrusions is provided inside the core material 3. Since the other points are the same as those in the first embodiment, detailed description thereof is omitted.
- the number of the fiber sheets 2a with protrusions disposed on both the inner and outer surfaces of the core member 3 in the bending direction may be plural.
- the manufacturing method of the vacuum heat insulating material 1 according to the present embodiment is the same as the manufacturing method of the vacuum heat insulating material 1 according to the first embodiment, and therefore detailed description thereof will be omitted.
- the heat insulation performance of the vacuum heat insulating material 1 of this Embodiment was evaluated.
- the vacuum heat insulating material 1 evaluated for heat insulation performance is obtained by laminating 25 fiber sheets 2 made by making glass fibers having average fiber diameters of 5 ⁇ m and 1 ⁇ m, and an aluminum laminate sheet. [15 ⁇ m-ONy (stretched nylon) / 12 ⁇ m-AL vapor-deposited PET (polyethylene terephthalate) / 6 ⁇ m-AL foil / 50 ⁇ mPE (unstretched polyethylene)].
- the heat insulating performance of the vacuum heat insulating material B (vacuum heat insulating material of the present embodiment) in which five sheets from both surfaces of the core material 3 are the fiber sheets 2a with protrusions and the remaining 15 sheets are the fiber sheets 2b without protrusions was evaluated.
- the thing of the same specification as Embodiment 1 was used.
- the thermal conductivity of the flat state without bending was 0.0019 W / mK for the vacuum heat insulating material B.
- the heat conductivity of the state bent to the cylindrical shape with a curvature radius of 250 mm was 0.0019 W / mK.
- the vacuum heat insulating material 1 of the present invention formed by putting the core material 3 provided with the convex protrusions 5 on the inner side and the outer side in the outer cover material 4, the convex protrusions 5 only on the inner side of the core material 3.
- the vacuum heat insulating material 1 having high heat insulating performance in a bent state could be obtained from the vacuum heat insulating material 1 of the first embodiment provided with the above.
- the vacuum heat insulating material 1 having a high heat insulating performance in a bent state can be obtained by acting so that the axial direction of the glass fiber does not face the laminating direction. Furthermore, according to the vacuum heat insulating material 1 of the present embodiment, there is an effect that the reliability of the jacket material 4 is improved.
- the vacuum heat insulating material 1 of the present embodiment is laminated so that half of the fiber sheets 2 a with protrusions are inward and half are outward, and the fiber sheet 2 a with protrusions. You may form the core material 3 only. Further, as shown in a schematic cross-sectional view of FIG. 11, two fiber sheets 2a with protrusions are laminated so that one protrusion is inward and the other is outward with the convex protrusion 5 facing. Then, the core material 3 may be formed.
- FIG. 12 is a schematic diagram showing a method of forming the sheet roll 19 in the method for manufacturing the vacuum heat insulating material 1 of the present embodiment.
- the fiber supply part 16 is provided in several places with respect to the advancing direction of the belt of the belt conveyor 15, and the sheet roll 19 of the characteristic like the some fiber sheet was laminated
- the sheet roll 19 manufactured by such a method can improve a heat insulation performance because a fiber becomes a perpendicular direction with respect to the thickness direction of the vacuum heat insulating material 1 in the boundary part of each step
- the multi-stage arrangement of the glass fiber discharge sections can substantially reduce the appearance of even one fiber sheet 2.
- the fiber configuration is such that a plurality of fiber sheets 2 are laminated, and the same performance and reliability as when the fiber sheets 2 are laminated with respect to the bent shape are obtained, and the number of parts of the fiber sheet 2 is reduced. Can do.
- the core material 3 is manufactured only by laminating
- the convex protrusion 5 formed on the protruding fiber sheet 2a disposed on the inner side of the bend and the convex protrusion 5 formed on the protruding fiber sheet 2a disposed on the outer side of the bending are the same.
- the convex protrusion 5 provided on the inner side and the convex protrusion 5 provided on the outer side do not necessarily have the same specification and arrangement, and the specification and arrangement suitable for the inner side and the outer side.
- Each of the convex projections 5 may be provided.
- this multi-stage fiber supply method includes a step of adding a binder application sheet and moisture (including water vapor spray), and blowing hot air on the mesh conveyor 20 in the drying step.
- a convex protrusion 5 may be provided.
- FIG. FIG. 13 shows the cross-sectional schematic diagram of the vacuum heat insulating material 1 of Embodiment 3 of this invention.
- the vacuum heat insulating material 1 of the present embodiment includes a core material 3 in which a single fiber sheet 2 a with protrusions is laminated on the surface of a plurality of fiber sheets 2 b without protrusions. Is vacuum-sealed by the jacket material 4.
- a sliding film 6 is disposed between the protruding fiber sheet 2a and the outer covering material 4 inside the bend.
- the sliding film 6 is provided between the fiber sheet 2 on the inner side of the bend and the covering material 4, and has almost no stretchability with the laminated fiber sheet 2 having a high porosity and stretchability at the time of bending.
- the outer cover material 4 is arranged to make it difficult to be restrained from each other.
- the sliding film 6 is configured by laminating a plurality of single film 7 having a small coefficient of friction such as a PET film.
- the thickness of one film single film 7 may be 100 ⁇ m or less.
- the occurrence of stress between the front side and the back side can be suppressed even when a deviation occurs between the front side and the back side of the slide film 6 due to the sliding of the film single films 7.
- the fibers of the fiber sheet 2 may rise at the wrinkles of the wrinkles generated by bending the vacuum heat insulating material 1.
- the sliding film 6 between the fiber sheet 2 and the jacket material 4 the fibers The rising of the fibers of the sheet 2 can be prevented.
- the thermal conductivity in a flat state without bending of the vacuum heat insulating material C was 0.0017 W / mK.
- the heat conductivity of the state bent to the cylindrical shape with a curvature radius of 250 mm was 0.0018 W / mK.
- the vacuum heat insulating material 1 of the present embodiment since the sliding film 6 having a small coefficient of friction is inserted between the inner peripheral surface of the core material 3 and the outer covering material 4, it is bent and used. In this case, it was possible to obtain the vacuum heat insulating material 1 in which the heat insulating performance hardly deteriorates. Moreover, when the inside of the vacuum heat insulating material 1 bent into the cylindrical shape was observed, wrinkles were generated, but the irregularities were small.
- the sliding film 6 since the sliding film 6 is provided on the inner side where the vacuum heat insulating material 1 is bent, the sliding film 6 serves as a protective sheet for the outer covering material 4, and the outer covering. The damage of the material 4 can be prevented and the reliability can be improved.
- the vacuum heat insulating material 1 of this Embodiment is not restricted to what showed the cross-sectional schematic diagram in FIG. 13,
- the fiber sheet which comprises the core material 3 so that the cross-sectional schematic diagram may be shown in FIG. 2 may be composed of a total of two fiber sheets 2a with protrusions and one fiber sheet 2b without protrusions.
- FIG. 14 is a schematic cross-sectional view of the vacuum heat insulating material 1 according to Embodiment 3 of the present invention. According to the vacuum heat insulating material 1 whose cross-sectional view is shown in FIG. Manufacturing can be facilitated. Moreover, even if the sliding film 6 does not have a laminated structure, it does not necessarily have a laminated structure as long as it has the same function.
- FIG. 15 is a schematic cross-sectional view of the vacuum heat insulating material 1 according to the fourth embodiment of the present invention.
- the core material 3 of the vacuum heat insulating material 1 is composed of two protruding fiber sheets 2a, and the two protruding fiber sheets 2a are in close contact with each other on which the convex protrusions 5 are not formed. It is laminated so that. Further, a sliding film 6 is provided on the inner side surface of the jacket material 4 on the inner side in the bending direction. Since points other than this are the same as the vacuum heat insulating material 1 of Embodiment 3, detailed description is abbreviate
- FIG. A fiber sheet 2a with protrusions having a thickness of 6 mm is formed by the multistage fiber supply centrifugal method described in FIG. 12, and the fiber sheet with protrusions 2a and a sliding film 6 in which four 75 ⁇ m thick PET films are laminated.
- the jacket material 4 was vacuum-sealed, and the heat insulating performance of the vacuum heat insulating material D configured as shown in FIG. 15 was evaluated.
- the thermal conductivity in a flat state without bending of the vacuum heat insulating material D was 0.0018 W / mK.
- the heat conductivity of the state bent to the cylindrical shape with a curvature radius of 250 mm was 0.0018 W / mK.
- the vacuum heat insulating material 1 that shows the heat insulating performance equivalent to the case where it is used without bending even when it is used by bending, and the number of parts of the fiber sheet 2 is reduced. It can be manufactured easily.
- the vacuum heat insulating material 1 of this Embodiment is not only what showed the cross-sectional schematic diagram in FIG. 15, but is formed by laminating a plurality of fiber sheets 2a with protrusions so as to be halved face-up and face-down. You can do it.
- the fiber sheet 2 constituting the core material 3 is a single fiber sheet 2 c with front and back protrusions having a plurality of convex protrusions 5 on the front and back. This and the sliding film 6 may be vacuum-sealed in the jacket material 4.
- FIG. 16 is a schematic cross-sectional view of the vacuum heat insulating material 1 according to Embodiment 4 of the present invention.
- the sheet roll 19 is produced by the method described with reference to FIG. 8, and when the sheet roll 19 is advanced by the belt conveyor 15 in the drying process, the sheet roll 19 is dried while being pressed by the conveyor belt having the same opening from above and below.
- a single fiber sheet 2 having a large thickness such as the fiber sheet 2 c with front and back protrusions shown in FIG. 16
- attention should be paid so that the direction of the fibers is perpendicular to the thickness direction of the vacuum heat insulating material 1. It is important to ensure heat insulation performance. For this reason, using a device in which the fiber supply sections 16 as shown in FIG. 12 are arranged in multiple stages with respect to the traveling direction, a single fiber sheet 2 is formed by substantially laminating a plurality of fiber sheets 2.
- a fiber sheet 2 having a fiber configuration may be formed.
- the vacuum heat insulating material 1 described in the first to fourth embodiments is a vacuum heat insulating material 1 on the premise that it is used by bending, but the vacuum heat insulating material 1 of the first to fourth embodiments of the present invention is not necessarily provided. It is not necessary to be used by bending, and it may be used in a flat plate shape as manufactured. For example, when a structure surrounded by a flat surface and a curved surface is thermally insulated by vacuum, the vacuum heat insulating material 1 of the present invention may be used for the planar portion in the same manner as the curved surface portion.
- the embossing pattern is formed on the press roll 17 and the forming method of the convex protrusion 5 shape is shown as an example.
- An embossed pattern may be formed on a press plate such as the like, and pressure may be applied to form the convex protrusions 5.
- FIG. 5 By covering the outer shell of the heat insulation tank with the vacuum heat insulating material 1 shown in Embodiments 1 to 4, it is possible to realize a heat insulation tank having high heat insulation with the outside air. Although the heat insulation tank may be covered only with the vacuum heat insulating material 1, it is difficult to attach the vacuum heat insulating material 1 in the vicinity of the water supply pipe or the hot water supply pipe connected to the heat insulation tank. You may coat
- FIG. 17 illustrates a schematic cross-sectional view of the heat retaining tank 22 according to the fifth embodiment of the present invention.
- the heat retaining tank 22 has a cylindrical body portion 24a and an end plate portion 24b that covers the upper and lower sides thereof.
- Pipes such as a water supply pipe and a hot water supply pipe (not shown) are connected to the body portion 24a.
- the vacuum heat insulating material 1 is wound around the body portion 24a except for the vicinity of the pipe, and the vicinity of the pipe is covered with a non-vacuum heat insulating material 23 such as a foam member.
- the vacuum heat insulating material 1 is bent with the surface of the core material 3 having the convex protrusions inside, and is wound around a heat retaining tank in a C shape as viewed from above so that the surface is on the body portion 24a side.
- the upper and lower end plate portions 24b of the heat retaining tank 22 are covered with a non-vacuum heat insulating material 23 in the same manner as the vicinity of the pipe of the body portion 24a, and these non-vacuum heat insulating materials 23 are molded together with the outer shape of the end plate portion 24b.
- a non-vacuum heat insulating material 23 any of those described in the first to fourth embodiments may be used.
- the non-vacuum heat insulating material 23 for example, an EPS (bead method expanded polystyrene) heat insulating material or the like is molded or cut. Easy foaming members can be used.
- the vacuum heat insulating material wound in an upper C shape may be a single body or divided in the circumferential direction, and may be further divided in the axial direction along the tank side surface.
- the water supplied to the heat retaining tank 22 via a water supply pipe (not shown) is heated by direct heating by a heating source (not shown) provided inside the tank.
- a heating source (not shown) provided inside the tank.
- it can be boiled by directly heating the water in the tank with an electric heater provided in the tank.
- a heat source may be provided outside the heat retaining tank 22 and water heated by the heat source may be supplied into the heat retaining tank 22 through a water supply pipe.
- circulating water heated by an exhaust heat recovery system such as a fuel cell power generation system or water heated by exchanging heat with a high-temperature refrigerant by a heat pump system may be supplied into the heat retaining tank 22 via a water supply pipe. .
- heat radiation evaluation was performed on the heat retaining tank 22 shown in FIG.
- the body diameter of the heat retaining tank is 600 mm
- the capacity is 370 L
- about 2/3 of the body portion 24a of the heat retaining tank 22 is covered with the vacuum heat insulating material 1
- the remaining about 1/3 is covered with the non-vacuum heat insulating material 23.
- the vacuum heat insulating material 1 the thing of the structure shown in FIG. 9 of Embodiment 2 was manufactured in the procedure shown in FIG. 3 of Embodiment 1, and the thing bent into the cylindrical shape was used.
- an EPS heat insulating material was used as the non-vacuum heat insulating material.
- the evaluation was performed by heating the water inside the tank to 90 ° C. with an electric heater and then measuring the heat release before and after 8 hours in an environment where the outside air was set at 4 degrees.
- the heat insulating tank 22 shown in FIG. 17 was configured using the vacuum heat insulating material 1 of the present invention having a thickness of 8 mm and the EPS heat insulating material 23 having a thickness of 50 mm, and the heat radiation amount was measured before and after 8 hours.
- the heat radiation amount of the tank using the vacuum heat insulating material of the present invention can be reduced by about 8%. It was confirmed. Thereby, it was confirmed that the cylindrical heat insulation tank which has high heat insulation with external air is realizable by applying the vacuum heat insulating material of this invention.
- the water in the heat retaining tank 22 may be cold water cooled by a cold heat source.
- a cold heat source for example, even when water cooled by a refrigerator or the like or ice sherbet or the like directly or indirectly removes heat from the inside of the heat retaining tank 22 and keeps the inside of the tank at a temperature lower than the ambient temperature, the vacuum heat insulating material 1 of the present invention.
- FIG. 18 is a configuration diagram illustrating a heat pump hot water supply system according to a sixth embodiment of the present invention.
- the heat insulation tank 22 shown in Embodiment 5 is used as the heat insulation tank 22 shown in FIG.
- the heat pump unit 31 includes a plurality of devices connected to a refrigerant circulation system 36 through which refrigerant circulates.
- the heat pump unit 31 includes an air-refrigerant heat exchanger 35 that receives heat from the atmosphere and transfers it to the circulating refrigerant, a compressor 25 that pressurizes the circulating refrigerant, and a medium circulation system 37 that removes heat from the circulating refrigerant. It has a refrigerant circulation system 36 formed by connecting a refrigerant-medium heat exchanger 29 for heating a flowing medium and an expansion valve 26 for volume expansion of the circulating refrigerant.
- the medium circulation system 37 includes a refrigerant-medium heat exchanger 29, a three-way valve 28 that supplies the medium heated by the refrigerant-medium heat exchanger 29 to the upper or lower part of the heat retaining tank 22, and the heat retaining tank 22. And a water-pump 34 a that circulates the medium in the medium circulation system 37.
- hot water is taken out from the heat retaining tank 22 at the upper part of the heat retaining tank 22, and hot water is taken out from the heat retaining tank 22 by mixing the city water 32 with the mixing valve 27a and hot water from the heat retaining tank 22, and the mixing valve 27b.
- a bathtub system 40 that is mixed with city water 32 and supplied to the bathtub 33 is provided.
- the water or hot water from the bathtub 33 is circulated between the bathtub 33 and the bath heat exchanger 30 via the water pump 34b, and the water or hot water from the bathtub 33 is exchanged with the hot water from the heat retaining tank 22.
- a reheating system 41 for heating is provided.
- the city water supply system 42 is also connected to the lower part of the heat retaining tank 22.
- the heat pump unit 31 is circulated in the refrigerant circulation system 36 using, for example, CO 2 as a refrigerant.
- CO 2 absorbs heat in the atmosphere by the air-refrigerant heat exchanger 35.
- it is compressed by the compressor 25 and the temperature is raised to a few tens of degrees Celsius.
- the refrigerant-medium heat exchanger 29 exchanges heat with, for example, water that is a medium flowing through the medium heat circulation system 37.
- the CO 2 deprived of heat is further reduced in temperature by the expander 26, supplied to the air heat exchanger 35 again, and circulated.
- the water heated in the refrigerant-medium heat exchanger 29 is heated to, for example, a little over 90 ° C. and supplied to the upper part of the heat retaining tank 22. At this time, cold water having a low temperature is taken out from the lower part of the heat retaining tank 22 and supplied to the refrigerant-medium heat exchanger 29 by the water pump 34a.
- This water circulation constitutes a medium circulation system 37. In this way, the water inside the heat retaining tank 22 is heated using the heat pump unit as a heating source.
- the heated hot water is used depending on the application.
- the warm water taken out from the upper part of the heat retaining tank 22 push up by supplying water with the city water 32 to the lower part of the heat retaining tank 22
- the mixing valve 27a Is mixed with city water 32 and adjusted to an appropriate temperature, and then supplied to a hot water supply system 38 for hot water supply.
- hot water mixed with city water 32 by the mixing valve 27 b is supplied to the bathtub 33.
- the hot water in the bathtub 33 and the hot water in the heat retaining tank 22 are used by exchanging heat in the bath heat exchanger 30.
- the hot water supply system using the heat insulation tank to which the vacuum heat insulating material of the present invention is applied can provide a hot water supply system having more energy saving performance.
- FIG. 19 is a system configuration diagram flow showing a system configuration of a heat pump type water heater showing another example of the sixth embodiment of the present invention.
- the medium circulation system 37 is provided with a system that circulates through the heat retaining tank 22 by a three-way valve 28b, and a system that branches from this and connects to the radiator 39.
- the circulation system that circulates through the heat retaining tank 22 is geometrically separated from the water inside the heat retaining tank 22.
- R410A is used as the refrigerant of the refrigerant circulation system 36.
- Other configurations are the same as those in FIG.
- Hot water of about 70 ° C. that circulates through the medium circulation system 37 heated by the heat exchanger 29 constituting the heat pump unit 31 is normally supplied to the radiator 39 and used for room heating.
- the water whose temperature is lowered by applying heat to the atmosphere by the radiator 39 is returned to the refrigerant-medium heat exchanger 29 by the water pump 34a, thereby forming a medium circulation system 37.
- the supply of warm water to the radiator 39 is stopped by switching the three-way valve 28b, and the water filled in the heat retaining tank 22 is heated by passing through a spiral tube provided in the heat retaining tank 22.
- Store as hot water The hot water stored in the heat retaining tank 22 is used as hot water for a shower or the like.
- the present embodiment which is a hot water supply system mainly for heating, it is necessary to store warm water in a heat retaining tank and keep it warm in a time zone with a small heating load.
- the vacuum heat insulating material according to the present invention it is possible to provide a water heater system that reduces heat dissipation from the tank and is more energy efficient.
- the heating method of a heat retention tank, the reheating of a bathtub, or a hot water supply was shown above, nothing is limited to this,
- the water inside a tank is directly heated using the principle of a heat pump.
- the medium circulating in the medium circulation system 37 and the water inside the tank may be geometrically separated and indirectly heated.
- the refrigerant circulating in the coolant circulation system 36 showing an example using CO 2 or R401A refrigerant the present invention is not limited thereto, for example, it may be an isobutane by the use conditions.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Thermal Insulation (AREA)
Abstract
Description
この発明は、非平面を持つ物体を断熱する真空断熱材およびその製造方法ならびにそれを用いた保温タンクおよびヒートポンプ式給湯機に関するものである。 The present invention relates to a vacuum heat insulating material that insulates an object having a non-planar surface, a method for manufacturing the same, a heat retaining tank and a heat pump type water heater using the same.
真空断熱材は、従来からのグラスウール断熱材などと比較して熱伝導率を大幅に小さくできるため、省エネ意識の向上とともに断熱材として広く使われるようになってきた。このため、平面形状で使用されるばかりでなく曲面形状においても使用されるようになってきている。その中で、例えば特許文献1に記載されているように、真空断熱材に溝形状または凹凸形状を形成することにより、真空断熱材の立体形状の曲げ成形を容易にしたものがあった。
Vacuum insulation has been widely used as an insulation material along with an improvement in energy conservation awareness because it can significantly reduce thermal conductivity compared to conventional glass wool insulation. For this reason, it is used not only in a planar shape but also in a curved surface shape. Among them, for example, as described in
従来の真空断熱材においては、例えば、コア材を挿入した外包材を真空中で上下から金型にてクランプすることによって、真空断熱材に突起を形成していた(特許文献1)。 In the conventional vacuum heat insulating material, for example, a protrusion is formed on the vacuum heat insulating material by clamping the outer packaging material into which the core material is inserted with a mold from above and below in vacuum (Patent Document 1).
しかしながら、一般的な真空断熱材においては、グラスウールのような繊維のかたまりでできた芯材が外被材によって真空密閉されており、真空断熱材の断熱性能を高くするために、芯材の繊維の向きは真空断熱材の厚さ方向と直角に近くなるように配置されている。特許文献1に記載された真空断熱材においては、芯材(コア材)を外包材(外被材)で真空密閉しながら突起を形成しているので、突起形成加工により芯材(コア材)の繊維の向きが真空断熱材の厚さ方向に近づく。芯材の繊維の向きが真空断熱材の厚さ方向に近づくと、芯材の繊維を介した熱伝導が増加し、真空断熱材の断熱性能が低下する場合があった。
また、平板形状の真空断熱材を曲げ加工すると、真空断熱材の外側(外周)と内側(内周)との間に周長差が生じ、この周長差を吸収するために曲げの内側の外被材およびこれに隣接する芯材にシワが発生する。芯材に深くて大きなシワが発生すると、曲げる前に真空断熱材の厚さ方向と垂直に向くように配置された芯材の繊維の向きが真空断熱材の厚さ方向に近づき、断熱性能が低下することがあった。
However, in a general vacuum heat insulating material, a core material made of a lump of fibers such as glass wool is vacuum-sealed by a jacket material, and in order to increase the heat insulating performance of the vacuum heat insulating material, the fiber of the core material Are arranged so as to be close to a right angle with the thickness direction of the vacuum heat insulating material. In the vacuum heat insulating material described in
In addition, when a flat plate vacuum heat insulating material is bent, a circumferential length difference is generated between the outer side (outer periphery) and the inner side (inner periphery) of the vacuum heat insulating material, and in order to absorb this circumferential length difference, Wrinkles are generated in the jacket material and the core material adjacent thereto. When deep and large wrinkles occur in the core material, the fiber orientation of the core material, which is arranged to be perpendicular to the thickness direction of the vacuum heat insulating material before bending, approaches the thickness direction of the vacuum heat insulating material, and the heat insulating performance is improved. There was a decline.
この発明は、上記のような問題を解決するためになされたもので、曲げて使用した場合においても断熱性能が高い真空断熱材を得ること、および、曲げて使用しても断熱性能が高い真空断熱材の製造方法を提供すること、ならびにこの真空断熱材を適用した保温タンクおよびヒートポンプ式給湯機を提供することを目的とする。 The present invention was made to solve the above-described problems, and obtains a vacuum heat insulating material having high heat insulating performance even when bent and used, and a vacuum having high heat insulating performance even when bent and used. It aims at providing the manufacturing method of a heat insulating material, and providing the heat retention tank and heat pump type water heater to which this vacuum heat insulating material is applied.
本発明の真空断熱材は、繊維シートを有し一方の表面に複数の凸型突起が形成された芯材を外被材で真空密閉して形成されたものである。 The vacuum heat insulating material of the present invention is formed by vacuum-sealing a core material having a fiber sheet and having a plurality of convex protrusions formed on one surface with a jacket material.
また、本発明の真空断熱材の製造方法は、繊維シートの一方の表面上に複数の凸型突起を形成する工程と、凸型突起が表面にくるように繊維シートを配置して芯材を形成する工程と、芯材を真空中で外被材に密閉する工程とを備えたものである。 The method for manufacturing a vacuum heat insulating material of the present invention includes a step of forming a plurality of convex protrusions on one surface of the fiber sheet, and a core material by arranging the fiber sheet so that the convex protrusions are on the surface. A step of forming, and a step of sealing the core material to the jacket material in a vacuum.
そして、本発明の円筒形状保温タンクは、請求項1~7のいずれか記載の真空断熱材を備えたものである。
The cylindrical heat insulating tank of the present invention is provided with the vacuum heat insulating material according to any one of
本発明の真空断熱材によれば、曲げ加工したときにも真空断熱材の曲げの内側に不均一なシワが発生することを防止でき、曲げて使用したときに断熱性能が高い真空断熱材を得ることができる。 According to the vacuum heat insulating material of the present invention, it is possible to prevent uneven wrinkles from occurring inside the bending of the vacuum heat insulating material even when bent, and a vacuum heat insulating material having high heat insulating performance when used by bending. Obtainable.
さらに、本発明の真空断熱材の製造方法によれば、曲げて使用しても断熱性能が高い真空断熱材を製造することができる。 Furthermore, according to the method for manufacturing a vacuum heat insulating material of the present invention, it is possible to manufacture a vacuum heat insulating material having high heat insulating performance even when bent and used.
また、本発明の真空断熱材を円筒形状保温タンクに適用すれば、より高い断熱性能により省エネ効率の向上を図ることができる。 Moreover, if the vacuum heat insulating material of the present invention is applied to a cylindrical heat insulating tank, energy saving efficiency can be improved by higher heat insulating performance.
実施の形態1.
まず、この発明の実施の形態1における真空断熱材の構成を説明する。図1は、この発明の実施の形態1における真空断熱材を示す断面模式図である。図1において、真空断熱材1は、複数枚の繊維シート2を積層した芯材3が外被材4により覆われ真空密閉されて構成されている。真空断熱材1が曲げられる方向の内側の芯材3の表面の繊維シート2には凸型突起5が複数形成されている。
First, the structure of the vacuum heat insulating material in
繊維シート2は、約90%が空間で、残りがガラス繊維で構成されており、また、断熱性能を向上させるために、繊維自体は極力シート面と平行方向になるように配置されている。また、外被材4は、AL(アルミ)箔を複数の高分子シートで挟持したアルミラミネートシートである。
The
図2は、本実施の形態における真空断熱材1の曲げられる前の芯材3を示した斜視図である。図2において、図の上側が真空断熱材1を曲げたときの内側に対応する。図2に示すように、芯材3は、繊維シート2が複数枚積層されて構成されており、その最上部には、突起付き繊維シート2aが配置され、その下部には複数枚の突起無し繊維シート2bが配置されている。
例えば1枚の繊維シート2の厚さはおよそ0.5mmである。曲げの内側になる芯材3の一方の表面の繊維シート2に形成されている凸型突起5は、繊維シート2と同じガラス繊維で構成されており、凸型突起5の先端は曲面になっている。凸型突起5の高さは、例えば0.1~0.5mm程度で、また、繊維シート表面積に対する凸型突起5の面積比率は10~50%程度である。
また、凸型突起5は、図2に示すように繊維シート2の一方の面上に規則的に配置されている。このように、凸型突起5を規則的に配置することにより、曲げたときに局所的に大きく深いシワが発生することを防止し、曲げ方向に対して細かく浅いシワが入るようにしている。
FIG. 2 is a perspective view showing the
For example, the thickness of one
Moreover, the
次に、本実施の形態における真空断熱材1の製造方法について説明する。
まず、抄紙法による繊維シート2の形成方法について説明する。
はじめに、直径が4μm~13μmの太径繊維と直径が1μm程度の細径繊維とを液体中に分散させる。次に、その液体を用いて自動送り式抄紙機などで抄紙した後に乾燥させ、厚さ0.5mm程度のシートロールを作製する。つづいて、必要とする真空断熱材1の面積程度にシートロールを裁断し、繊維シート2とする。このように抄紙して形成された繊維シート2の繊維の方向は、多くが繊維シート2の厚さ方向と垂直方向をなしている。
突起無し繊維シート2bとしては、この繊維シート2をそのまま使用するとよい。また、突起付き繊維シート2aとしては、この繊維シート2に凸型突起5を形成して使用すればよい。
Next, the manufacturing method of the vacuum
First, a method for forming the
First, a large diameter fiber having a diameter of 4 μm to 13 μm and a small diameter fiber having a diameter of about 1 μm are dispersed in a liquid. Next, the liquid is used to make a paper roll with an automatic feed paper machine and then dried to produce a sheet roll having a thickness of about 0.5 mm. Subsequently, the sheet roll is cut to the required area of the vacuum
As the fiber sheet 2b without protrusions, the
つづいて、繊維シート2の一方の表面に凸型突起5を形成する方法について説明する。
図3は、真空断熱材1に使用する繊維シート2に加圧機構である熱エンボスロール10と熱ロール11とで挟み込んで凸型突起5を形成する方法を説明する模式図である。図3に示すように、繊維シート2をローラ21に載せて進め、所定の間隔に設定された熱ロール11と熱エンボスロール10で構成された加圧機構の隙間を通して繊維シート2を加熱させながら加圧する。熱エンボスロール10と熱ロール11とで挟み込まれた繊維シート2の表面には凸型突起5が形成され、突起付き繊維シート2aができる。なお、熱エンボスロール10を凹型とし熱ロール11をこれに応じた凸型としても良く、また熱ロール11は凹凸のないフラットロールでも良い。さらに、熱ロール11は加熱せずに使用しても良い。
Next, a method for forming the
FIG. 3 is a schematic diagram for explaining a method of forming the
熱エンボスロール10のエンボスパターンについては、特に決まった形状である必要はないが、例えば、図4に示すような正八角形の形状の掘り込まれたエンボス12が規則的に配置されたものなどであればよい。図4は、熱エンボスロール10に設けるエンボスパターンの一例を示す模式図である。図4において、八角形のエンボス12のパターンが規則的に配置されている。エンボス12の奥側を曲面加工しておくことにより、熱エンボスロール10で加工して先端が曲面の凸型突起5を形成した繊維シート2を形成することができる。
The embossing pattern of the
次に、芯材3を形成する方法について説明する。
凸型突起5を形成した突起付き繊維シート2aと突起無し繊維シート2bとを積層し、凸型突起5が一方の表面にくるように配置して、芯材3とする。芯材3は、図2にその芯材3の例を示したように、1枚の突起付き繊維シート2aと1枚または複数枚の突起無し繊維シート2bとを積層して形成してもよいし、図5の真空断熱材1の断面模式図に示すように、複数枚の突起付き繊維シート2aと1枚または複数枚の突起無し繊維シート2bとを積層して形成してもよい。ここで、図5は、本実施の形態の真空断熱材1の一例を示す断面模式図である。
Next, a method for forming the
The fiber sheet 2a with protrusions and the fiber sheet 2b without protrusions, in which the
複数枚の突起付き繊維シート2aを積層する場合には、隣接する繊維シート2の凸型突起5どうしが互いに重ならないように積層した方よい。凸型突起5どうしが重ならない方が、繊維シート2間の接触点が減り、断熱性能を高くでき、さらに積層された繊維シート2どうしが固定されないことから曲げ加工が容易になる。
When laminating a plurality of fiber sheets 2a with projections, it is better to laminate so that the
つづいて、芯材3を外被材4に挿入して真空断熱材1を製造する方法について説明する。
前述の方法などにより準備した芯材3を外被材4となる2枚の外被材シート(図示せず)で上下を覆い、真空チャンバ内に配置する。次に、真空チャンバ内を減圧にして、所定の圧力、例えば0.1~3Pa程度の真空圧にする。この状態で、外被材4になる外被材シートの外周部をヒートシールにより密閉する。真空チャンバ内を大気圧に戻し、不要な部分の外被材シートを切断することにより、本実施の形態の真空断熱材1を得ることができる。
Next, a method for manufacturing the vacuum
The
なお、予め製袋化した外被材4を作製しておき、芯材3を挿入した後に真空チャンバ内で残りの開口部を密閉するようにしてもよい。また、必要に応じて、外被材4で覆われた空間にガス吸着剤を挿入してもよい。
このようにして製造された真空断熱材1の内部空間は、真空に保持されている。
It should be noted that the
The internal space of the vacuum
次に、このようにして作製した本発明の本実施の形態の真空断熱材1の断熱性能を評価した。
断熱性能を評価した真空断熱材1は、平均繊維直径が5μmと1μmとのガラス繊維を抄紙して作製した厚さが約0.5mmの25枚の繊維シート2を積層して芯材3とし、この芯材3をアルミラミネートシート[15μm-ONy(延伸ナイロン)/12μm-AL蒸着PET(ポリエチレンテレフタレート)/6μm-AL箔/50μmPE(無延伸ポリエチレン)]の外被材4で真空密閉したものとした。
Next, the heat insulating performance of the vacuum
The vacuum
断熱性能は、芯材3の表面(曲げる方向の内側)から8枚を突起付き繊維シート2aとし、残り17枚を突起無し繊維シート2bとした真空断熱材A(本発明の真空断熱材)の断熱性能を、芯材3を全て突起無し繊維シート2bとした真空断熱材Eの断熱性能と比較して評価した。ここで、真空断熱材Aの突起付き繊維シート2aは、繊維シート2に外接円直径が8mmの正六角形のエンボス12が27%の面積率で凹型に形成された熱エンボスロール10を材料の軟化点となる温度で押し当てて凸型突起5を形成したものである。また、突起付き繊維シート2aは、凸型突起5が全て同じ向きになる様に積層した。
The heat insulating performance is that of the vacuum heat insulating material A (vacuum heat insulating material of the present invention) in which 8 sheets are formed as fiber sheets 2a with protrusions from the surface (inner side in the bending direction) of the
曲げがない平面状態の熱伝導率は、真空断熱材A、真空断熱材Eでそれぞれ0.0018W/mK、0.0017W/mKであったが、3軸ロールベンダにて曲率半径250mmの円筒形状に曲げた状態の熱伝導率は、真空断熱材A、真空断熱材Eでそれぞれ0.0020W/mK、0.0025W/mKであった。
このように、突起付き繊維シート2aを積層した芯材3を真空密閉して作製した真空断熱材1を、凸型突起5が内側になる様に曲げ加工した場合に、断熱性能の高い真空断熱材1を得ることができた。
The thermal conductivity in the flat state without bending was 0.0018 W / mK and 0.0017 W / mK for the vacuum heat insulating material A and the vacuum heat insulating material E, respectively, but a cylindrical shape with a curvature radius of 250 mm by a triaxial roll bender. The heat conductivity in the bent state was 0.0020 W / mK and 0.0025 W / mK for the vacuum heat insulating material A and the vacuum heat insulating material E, respectively.
Thus, when the vacuum
繊維シート2は、その体積の90%程度が空間で、残りが繊維であるため、空隙率(体積当たりの空間の割合)が高く、伸縮性がある。一方、外被材4は、伸縮性がほとんどない。真空断熱材1を曲げたとき、真空断熱材1の外側(外周)と内側(内周)との間に周長差が生じるが、曲げの外側の外被材4に伸張性がほとんどないため、曲げの内側にシワが発生する。
本発明の本実施の形態の真空断熱材1によれば、曲げの内側の芯材3の表面と、外被材4の内側面との接触面積を小さくすることができ、その結果、芯材3と外被材4との間の摩擦によるひっかかりを少なくすることができる。したがって、真空断熱材1を曲げたときの芯材3の内側で一箇所または少数箇所に大きく深いシワがかたまって発生することを防止でき、全体に均一に小さく浅いシワが発生させることができる。そして、芯材3のガラス繊維の真空断熱材1の厚さ方向に対する角度が小さくならず、真空断熱材1の断熱性能を向上させることができる。さらに、真空断熱材1の曲げの内側に深く大きなシワが発生しないことから、真空断熱材1の曲げの内側に配置される断熱対象物と真空断熱材1の外被材4との密着性を高くでき、断熱対象物に対する断熱効果をさらに高めることができる。
Since the
According to the vacuum
また、本発明の本実施の形態の真空断熱材1によれば、外被材4に局所的な応力が発生することを防ぐことができ、薄い外被材4が深い凹凸を有した芯材3のシワによって局部的な応力を受けて損傷を受け、外被材4に穴または空気の隔絶に対して弱い箇所ができることを防止できる。したがって、真空断熱材1の外被材4の破損による急激な真空度低下による断熱性能の低下や、外被材4やヒートシール部を介した空気のスローリークによる真空度低下によって断熱寿命が短くなることを抑制できる。
Moreover, according to the vacuum
このように、本実施の形態の真空断熱材によれば、曲げて使用した場合においても断熱性能が高く、また、信頼性の高い真空断熱材を得ることができる。また、本実施の形態の真空断熱材の製造方法によれば、断熱性能が高く信頼性の高い真空断熱材を容易に製造することができる。 As described above, according to the vacuum heat insulating material of the present embodiment, it is possible to obtain a vacuum heat insulating material having high heat insulating performance and high reliability even when bent and used. Moreover, according to the manufacturing method of the vacuum heat insulating material of this Embodiment, the heat insulating performance and the highly reliable vacuum heat insulating material can be manufactured easily.
なお、本実施の形態においては、繊維シート2の繊維がガラス繊維である例を説明したが、繊維シート2の繊維は必ずしもガラス繊維である必要はなく、ポリエステル、ポリプロピレン、ポリスチレンなどの高分子材料の繊維であってもよい。
繊維シート2の繊維がこのような高分子材料である場合は、例えばスパンボンド製法を用い、樹脂ペレットを溶融させノズルから押出した後、冷却しながらエジェクタ等を利用して延伸させて紡糸すればよい。紡糸された繊維は、ベルトコンベアに集積して、低目付シート(薄肉シート)にする。その後熱エンボスロール10にて一部熱融着させてシートロールを形成する。また、この熱エンボスロール10のエンボス12形状を所定の形状にしておくことにより、突起付き繊維シート2aを形成することができる。このように、繊維が高分子材料であっても、繊維シート2を薄肉シート化して、これを積層することによって、繊維シート2の繊維の向きの大部分を繊維シート2の厚さ方向に垂直な方向に向けることができる。
In the present embodiment, an example in which the fibers of the
When the fiber of the
また、本実施の形態においては、外被材4がアルミラミネートシートである例で説明したが、外被材4は、アルミラミネートシートに限るものではなく、バリア性が維持されるのであれば、他の材料であってもよい。また、その厚さも先に説明したものに限るものでない。本実施の形態のアルミラミネートシート[15μm-ONy(延伸ナイロン)/12μm-AL蒸着PET(ポリエチレンテレフタレート)/6μm-AL箔/50μmPE(無延伸ポリエチレン)のAL箔やAL蒸着フィルムを、例えばアルミナ蒸着フィルムやシリカ蒸着フィルムなどに置き換えてもよい。さらに、別のフィルムを積み増してもよいし、逆に積層するフィルム種を減らしてもよい。
Further, in the present embodiment, the example in which the
なお、突起付き繊維シート2aは、次のような方法で形成することもできる。
図6は、真空断熱材1に使用する繊維シート2に凸型突起5を形成する別の方法を説明する模式図である。図6に示すように、繊維シート2を開口率が5~30%程度のメッシュ13に載せて熱風送風機14で熱風を吹き付ける。そうすると、メッシュ13のない部分に載った繊維シート2が軟化し、自重により下方に垂れ下がる。自重により垂れ下がった部分が曲面形状を持つ凸型突起5になり、このようにして、繊維シート2に凸型突起5を形成することができる。このとき、熱風の温度や流速を変えることにより、凸型突起5の高さを調節することができる。メッシュ13のパターンについては、例えば、図4に示したようなエンボスパターンと同じようなものであればよい。
In addition, the fiber sheet 2a with a protrusion can also be formed by the following method.
FIG. 6 is a schematic diagram for explaining another method for forming the
また、突起無し繊維シート2bおよび突起付き繊維シート2aは、次のような方法で形成することもできる。
図7は、突起付き繊維シート2aを形成する別の方法を説明する模式図である。図7において、ベルトコンベア15を進むベルト上に設けられた繊維供給部16からガラス繊維が供給され、これらのガラス繊維が堆積し、シート状のプレス前繊維シート18となる。ここで、繊維供給部16からは、例えば溶融したガラスがノズルから遠心力で吐出され、その直後に燃焼ガスによって延伸される(遠心法など)ことによって製造されたガラス繊維が供給される。プレス前繊維シート18が完全に固化する前にプレロール(図示せず)で一旦予備加圧し、その後段でプレスロール17により圧力を印加してシートロール19ができる。
Moreover, the fiber sheet 2b without a protrusion and the fiber sheet 2a with a protrusion can also be formed with the following method.
FIG. 7 is a schematic diagram for explaining another method of forming the fiber sheet with protrusions 2a. In FIG. 7, glass fibers are supplied from a
このとき、プレスロール17に図4に例示したような形状のエンボス12パターンを形成しておくと、プレスロール17により成形された後に凸型突起5が形成されたシートロール19を得ることができる。凸型突起5を備えたシートロール19を所定の大きさに裁断することにより、突起付き繊維シート2aを得ることができる。
At this time, if the emboss 12 pattern having the shape illustrated in FIG. 4 is formed on the
また、この方法において、プレスロール17をエンボスパターンのないものに取り替えることにより、同じ方法で凸型突起のないシートロール19を形成することができ、これを所定の大きさに裁断することにより、突起無し繊維シート2bを得ることができる。
Further, in this method, by replacing the
なお、このとき、シートロール19のシート引張強度を確保し、さらに凸型突起5の形状を維持することを目的として、例えば遠心法での繊維作製時やプレス前繊維シート18の段階で、断熱性能に大きな悪影響を与えない範囲でガラス繊維を結着させるためのバインダを添加させてもよい。但しこの場合は、シートロール19作製後に、バインダを固着させるための乾燥工程を設ける。
また、凸型突起5の先端は必ずしも曲面でなく先端に平面部分があってもよい。さらに、1枚の繊維シート2の厚さとして0.5mm程度の例を示したが、繊維シート2の厚さはこれに限るものでなく、用途、要求性能に応じて適宜選択すればよい。
At this time, for the purpose of ensuring the sheet tensile strength of the sheet roll 19 and further maintaining the shape of the
Further, the tip of the
また、本実施の形態の真空断熱材1の製造方法においては、繊維シート2に凸型突起5を形成する工程が繊維シート2の形成工程とは別と説明したが、繊維シート2の形成工程の乾燥工程の中で凸型突起5を形成してもよい。
Moreover, in the manufacturing method of the vacuum
図8は、繊維シート2を形成する他の製造方法を模式的に示したものである。
図8に示すように、遠心法で作製されたガラス繊維を供給する繊維供給部16から吐出されるガラス繊維が、プレス前繊維シート18となってメッシュコンベア20で運ばれ、プレス前繊維シート18がプレスロール17により所定の厚さに成形される。次に、プレスロール17により所定の厚さに成形されたシートロール19に、メッシュコンベア20の上方から熱風送風機14により熱風を吹き付けることにより、突起付き繊維シート2aを通常の突起無し繊維シート2bとほぼ同じ工程で作製することができる。
FIG. 8 schematically shows another manufacturing method for forming the
As shown in FIG. 8, the glass fiber discharged from the
図8に示した繊維シート2の製造に際しても、シートロール19のシート引張強度を確保し、さらに凸型突起5の形状を維持することを目的として、例えば遠心法での繊維作製した時やプレス前繊維シート18の段階にガラス繊維を結着させるためのバインダを添加させる場合がある。また、シートロール19を構成するガラス繊維軸方向がコンベア方向と平行にさせることを目的に、予めプレス前繊維シート18に水分(水蒸気噴霧を含む)を付加する工程を設けることもある。この場合、バインダを固着させるためや、付加水分を蒸発させために乾燥工程が必要である。
また遠心法とは別に、抄紙法によって繊維シート2を作製する製造方法の場合にも、乾燥工程が必要となる。このような場合、上記で示した熱風送風が乾燥工程を兼ね備えており、特に余分な設備を設けなくても突起付き繊維シート2aが容易に成形できる。
In the production of the
In addition to the centrifugal method, a drying step is also required in the case of a manufacturing method for producing the
なお、突起付き繊維シート2aの凸型突起5の配置については、芯材3のコーナー部に凸型突起5が他の部分より細かく配置されるようにすると、芯材3のコーナー部で芯材3と外被材4とがひっかかることを防止でき、さらに断熱性能が高く、信頼性の高い真空断熱材1を得ることができる。
また、エンボス12の平面形状は、六角形や八角形のような円に近い平面形状の例を示したが、必ずしも円のような形状である必要はなく、例えば菱形などであってもよい。
In addition, about arrangement | positioning of the convex processus |
Moreover, although the example of the planar shape close | similar to a circle like a hexagon or an octagon showed the planar shape of the embossing 12, it does not necessarily need to be a shape like a circle, For example, a rhombus etc. may be sufficient.
実施の形態2.
図9は、本発明の実施の形態2の真空断熱材1の断面模式図を示したものである。図9において、芯材3の曲げ方向の内側と外側の両表面(表面と裏面)に突起付き繊維シート2aを設け、芯材3の内部に突起無し繊維シート2bを設けている。その他の点については実施の形態1と同様であるので、詳しい説明は省略する。ここで、芯材3の曲げ方向の内側と外側の両表面に配置する突起付き繊維シート2aは、複数枚であってもよい。
FIG. 9 is a schematic cross-sectional view of the vacuum
また、本実施の形態の真空断熱材1の製造方法についても、実施の形態1の真空断熱材1の製造方法と同様であるので、これについても詳しい説明は省略する。
Also, the manufacturing method of the vacuum
次に、本実施の形態の真空断熱材1の断熱性能を評価した。
断熱性能を評価した真空断熱材1は、実施の形態1の場合と同様に、平均繊維直径が5μmと1μmのガラス繊維を抄紙して作製した25枚の繊維シート2を積層し、アルミラミネートシート[15μm-ONy(延伸ナイロン)/12μm-AL蒸着PET(ポリエチレンテレフタレート)/6μm-AL箔/50μmPE(無延伸ポリエチレン)]の外被材4で密閉したものである。
Next, the heat insulation performance of the vacuum
As in the case of the first embodiment, the vacuum
芯材3の両表面から5枚ずつを突起付き繊維シート2aとし残り15枚を突起無し繊維シート2bとした真空断熱材B(本実施の形態の真空断熱材)の断熱性能を評価した。突起付き繊維シート2aおよび突起無し繊維シート2bについては、実施の形態1と同じ仕様のものを使用した。
The heat insulating performance of the vacuum heat insulating material B (vacuum heat insulating material of the present embodiment) in which five sheets from both surfaces of the
曲げがない平面状態の熱伝導率は、真空断熱材Bで0.0019W/mKであった。また、曲率半径250mmの円筒形状に曲げた状態の熱伝導率は、0.0019W/mKであった。 The thermal conductivity of the flat state without bending was 0.0019 W / mK for the vacuum heat insulating material B. Moreover, the heat conductivity of the state bent to the cylindrical shape with a curvature radius of 250 mm was 0.0019 W / mK.
このように、凸型突起5を内側および外側に設けた芯材3を外被材4に入れて形成した本発明の真空断熱材1によれば、芯材3の内側にのみ凸型突起5を設けた実施の形態1の真空断熱材1より、曲げた状態で断熱性能の高い真空断熱材1を得ることができた。凸型突起5を芯材3の外側にも形成することにより、芯材3と外被材4との拘束が緩和され、従来、芯材3にも強く加わっていた引張と曲げの応力が弱められたことにより、ガラス繊維の軸方向が積層方向に向かないように作用し、曲げた状態で断熱性能の高い真空断熱材1を得ることができたと推定される。さらに、本実施の形態の真空断熱材1によれば、外被材4の信頼性が向上する効果もある。
Thus, according to the vacuum
なお、本実施の形態の真空断熱材1は、図10にその断面模式図を示すように、突起付き繊維シート2aの半数を内向き、半数を外向きに積層して、突起付き繊維シート2aだけで芯材3を形成してもよい。
さらに、図11にその断面模式図を示すように、2枚の突起付き繊維シート2aを、1枚を内向きに、また、もう1枚を外向きに凸型突起5が向くように積層して、芯材3を形成してもよい。
In addition, as shown in the schematic cross-sectional view of FIG. 10, the vacuum
Further, as shown in a schematic cross-sectional view of FIG. 11, two fiber sheets 2a with protrusions are laminated so that one protrusion is inward and the other is outward with the
図11に示す真空断熱材1の場合には、1枚の繊維シート2の厚さが厚くなることが多いので、図12にその製造工程の模式図を示すように、遠心法で作製したガラス繊維を多段の繊維供給によってシートロール19を製造する方法などがある。
図12は、本実施の形態の真空断熱材1の製造方法の、シートロール19を形成する方法を示した模式図である。図12において、繊維供給部16が、ベルトコンベア15のベルトの進行方向に対して複数箇所に設けられており、複数の繊維シートが積層されたような特性のシートロール19を製造することができる。
また、このような方法により製造したシートロール19は、各段の境界部分で真空断熱材1の厚み方向に対して繊維が垂直方向になり、断熱性能を高めることができる。
In the case of the vacuum
FIG. 12 is a schematic diagram showing a method of forming the sheet roll 19 in the method for manufacturing the vacuum
Moreover, the sheet roll 19 manufactured by such a method can improve a heat insulation performance because a fiber becomes a perpendicular direction with respect to the thickness direction of the vacuum
図12に示した多段の繊維供給によるシートロール形成方法によれば、ガラス繊維の吐出部(繊維供給部16)の多段配置によって、見かけ上は1枚の繊維シート2であっても実質的に複数枚の繊維シート2を積層したような繊維構成になり、曲げ形状に対して繊維シート2を積層した場合と同等の性能および信頼性が得られるとともに、繊維シート2の部品点数を削減することができる。
According to the sheet roll forming method with multi-stage fiber supply shown in FIG. 12, the multi-stage arrangement of the glass fiber discharge sections (fiber supply section 16) can substantially reduce the appearance of even one
このように、図10および図11に示したような本実施の形態の真空断熱材1によれば、同じ仕様の突起付き繊維シート2aを向きを変えて積層するだけで芯材3を製造することができるので、部品点数を低減して容易に製造でき、製造コストを低減できる。
Thus, according to the vacuum
なお、本実施の形態においては、曲げの内側に配置する突起付き繊維シート2aに形成する凸型突起5と曲げの外側に配置する突起付き繊維シート2aに形成する凸型突起5とは、同じ仕様で同じ配置であるように説明したが、内側に設ける凸型突起5と外側に設ける凸型突起5は必ずしも同じ仕様、配置である必要はなく、内側用と外側用に適した仕様、配置の凸型突起5をそれぞれ設けてもよい。
In the present embodiment, the
また、この多段の繊維供給方法は、図8に示したように、バインダ適用シートや水分(水蒸気噴霧を含む)を付加する工程を設け、乾燥工程においてメッシュコンベア20上で熱風を吹付けることによって凸型突起5を設けてもよい。
In addition, as shown in FIG. 8, this multi-stage fiber supply method includes a step of adding a binder application sheet and moisture (including water vapor spray), and blowing hot air on the
実施の形態3.
図13は、本発明の実施の形態3の真空断熱材1の断面模式図を示したものである。図13において、本実施の形態の真空断熱材1は、複数枚の突起無し繊維シート2bの表面に1枚の突起付き繊維シート2aが積層されて芯材3が構成されており、芯材3が外被材4によって真空密閉されている。突起付き繊維シート2aと曲げの内側の外被材4との間に挟持されて、滑りフィルム6が配置されている。芯材3と外被材4との間に滑りフィルム6を配置した点以外は、実施の形態1の真空断熱材1と同様であるので、詳しい説明は省略する。
また、本実施の形態の真空断熱材1の製造方法については、滑りフィルム6を入れて真空密閉すること以外は実施の形態1の真空断熱材1の製造方法と同様であるので、これについても詳しい説明は省略する。
FIG. 13: shows the cross-sectional schematic diagram of the vacuum
Moreover, since the manufacturing method of the vacuum
この滑りフィルム6は、曲げの内側の繊維シート2と外被材4との間に設けられ、曲げ加工時において、空隙率が高く伸縮性のある積層された繊維シート2と伸縮性のほとんどない外被材4とが互いに拘束され難くするために配置されたものである。
The sliding
滑りフィルム6は、PETフィルムなどの小摩擦係数のフィルム単膜7を複数枚積層したもので構成される。1枚のフィルム単膜7の厚さは100μm以下などであればよい。フィルム単膜7どうしが滑ることにより、滑りフィルム6の表側と裏側にずれが発生した場合にも、表側と裏側との間で応力の発生を抑えることができる。また、真空断熱材1を曲げて発生したシワの折れ目で繊維シート2の繊維が立ち上がる場合があるが、繊維シート2と外被材4との間に滑りフィルム6を配置することにより、繊維シート2の繊維の立ち上がりを防止できる。
The sliding
このようにして作製した本実施の形態の真空断熱材1の断熱性能を、実施の形態1と同様に評価した。
実施の形態1で説明した真空断熱材Aに厚さ75μmのPETフィルム(フィルム単膜7)を4枚積層した滑りフィルム6を追加した真空断熱材Cを作製した。
この真空断熱材Cの曲げがない平面状態の熱伝導率は0.0017W/mKであった。また、曲率半径250mmの円筒形状に曲げた状態の熱伝導率は0.0018W/mKであった。
Thus, the heat insulation performance of the vacuum
A vacuum heat insulating material C in which a sliding
The thermal conductivity in a flat state without bending of the vacuum heat insulating material C was 0.0017 W / mK. Moreover, the heat conductivity of the state bent to the cylindrical shape with a curvature radius of 250 mm was 0.0018 W / mK.
このように、本実施の形態の真空断熱材1によれば、芯材3の内周面と外被材4との間に小摩擦係数の滑りフィルム6を挿入しているので、曲げて使用した場合にも断熱性能がほとんど低下しない真空断熱材1を得ることができた。
また、円筒形状に曲げた真空断熱材1の内側を観察したところ、シワが発生していたがその凹凸は小さかった。
Thus, according to the vacuum
Moreover, when the inside of the vacuum
さらに、実施の形態の真空断熱材1によれば、真空断熱材1を曲げた内側に滑りフィルム6を備えているため、滑りフィルム6が外被材4の保護シートの役割を果たし、外被材4の破損を防止し、信頼性を向上できる。
Furthermore, according to the vacuum
なお、本実施の形態の真空断熱材1は、図13にその断面模式図を示したものに限らず、例えば、図14にその断面模式図を示すように、芯材3を構成する繊維シート2は、突起付き繊維シート2aが1枚と突起無し繊維シート2bが1枚の計2枚で構成されているものであってもよい。図14は、本発明の実施の形態3の真空断熱材1の断面模式図を示したものであり、図14に断面図を示した真空断熱材1によれば、部品数を少なくでき、その製造を容易にすることができる。
また、滑りフィルム6は、積層構造のものでなくても、同じ機能のものであれば、必ずしも積層構造である必要はない。
In addition, the vacuum
Moreover, even if the sliding
実施の形態4.
図15は、本発明の実施の形態4の真空断熱材1の断面模式図を示したものである。図15において、真空断熱材1の芯材3が、2枚の突起付き繊維シート2aで構成されており、2枚の突起付き繊維シート2aは凸型突起5が形成されていない面どうしが密着するように積層されている。さらに、曲げ方向の内側の外被材4の内側面に、滑りフィルム6が設けられている。これ以外の点は、実施の形態3の真空断熱材1と同様であるので、詳しい説明は省略する。
また、本実施の形態の真空断熱材1の製造方法については、実施の形態1~3の真空断熱材1の製造方法と同様であるので、これについても詳しい説明は省略する。
FIG. 15 is a schematic cross-sectional view of the vacuum
Further, the manufacturing method of the vacuum
このようにして作製した本実施の形態の真空断熱材1の断熱性能を、実施の形態1と同様に評価した。
厚さ6mmの突起付き繊維シート2aを図12で説明した多段の繊維供給の遠心法で形成し、この突起付き繊維シート2aと厚さ75μmのPETフィルムが4枚積層された滑りフィルム6とを外被材4に真空密閉して、図15に示すように構成した真空断熱材Dの断熱性能を評価した。
Thus, the heat insulation performance of the vacuum
A fiber sheet 2a with protrusions having a thickness of 6 mm is formed by the multistage fiber supply centrifugal method described in FIG. 12, and the fiber sheet with protrusions 2a and a sliding
この真空断熱材Dの曲げがない平面状態の熱伝導率は0.0018W/mKであった。また、曲率半径250mmの円筒形状に曲げた状態の熱伝導率は0.0018W/mKであった。 The thermal conductivity in a flat state without bending of the vacuum heat insulating material D was 0.0018 W / mK. Moreover, the heat conductivity of the state bent to the cylindrical shape with a curvature radius of 250 mm was 0.0018 W / mK.
このように、本実施の形態によれば、曲げて使用した場合においても、曲げないで使用した場合と同等の断熱性能を示し、また、繊維シート2の部品点数を減らした真空断熱材1を容易に製造することができる。
As described above, according to the present embodiment, the vacuum
なお、本実施の形態の真空断熱材1は、図15にその断面模式図を示したものに限らず、複数枚の突起付き繊維シート2aを表向きと裏向きに半分ずつ向けて積層して形成してよい。また、例えば、図16に断面模式図を示すように、芯材3を構成する繊維シート2が、表と裏に複数の凸型突起5を備えた1枚の表裏突起付き繊維シート2cであり、これと滑りフィルム6とが外被材4に真空密閉されているものであってもよい。図16は、本発明の実施の形態4の真空断熱材1の断面模式図を示したものである。
In addition, the vacuum
図16に説明したような、1枚の表裏突起付き繊維シート2cは、例えば、以下の方法で形成できる。図8で説明したような方法でシートロール19を作製し、乾燥工程においてベルトコンベヤ15でシートロール19が進むときに、上下から同じ開口のコンベアベルトで押さえ込みながら乾燥させる。図16に示した表裏突起付き繊維シート2cのように厚さの厚い1枚ものの繊維シート2を作成する場合には、繊維の方向が真空断熱材1の厚さ方向に垂直に向くように留意することが断熱性能を確保するためには重要である。このため、図12で示したような繊維供給部16を進行方向に対して多段に配置した装置を用いて、1枚の繊維シート2が実質的に複数枚の繊維シート2を積層したような繊維の構成の繊維シート2を形成するとよい。
16 can be formed by the following method, for example, as described in FIG. The sheet roll 19 is produced by the method described with reference to FIG. 8, and when the sheet roll 19 is advanced by the
なお、実施の形態1~4において説明した真空断熱材1は、曲げて使用することが前提の真空断熱材1であるが、本発明の実施の形態1~4の真空断熱材1は、必ずしも曲げて使用する必要はなく、製造されたままの平板状で使用されてもよい。例えば、平面と曲面で囲まれた構造物を真空断熱する場合などには、曲面部分に使用するのと同様に平面部分に本発明の真空断熱材1を使用してもよい。
The vacuum
また、上記実施の形態では、プレスロール17にエンボスパターンを形成しておき、凸型突起5形状の成形方法を例に示したが、これに限定されるものではなく、バッチ式の平板熱プレス等のプレス板にエンボスパターンを形成させておいて、圧力を印加させて凸型突起5を成形させてもよい。
In the above embodiment, the embossing pattern is formed on the
実施の形態5.
実施の形態1~4に示した真空断熱材1を用いて保温タンクの外郭を被覆することにより、外気との高い断熱性を有する保温タンクを実現することができる。保温タンクを真空断熱材1のみで被覆してもよいが、保温タンクに接続される給水配管や出湯配管などの近傍は真空断熱材1を取り付け難いため、それら配管の近傍は成型や切削加工しやすい発泡部材などの非真空断熱材で被覆してもよい。
By covering the outer shell of the heat insulation tank with the vacuum
図17は、本発明の実施の形態5の保温タンク22の断面模式図を例示するものである。図17において、保温タンク22は円筒形状の胴部分24aとその上下を塞ぐ鏡板部24bを有している。胴部分24aには不図示の給水配管や出湯配管などの配管が接続されている。胴部分24aの配管近傍を除く位置には真空断熱材1が巻きつけられ、配管近傍は発泡部材などの非真空断熱材23で被覆されている。真空断熱材1は芯材3の凸型突起を有する表面を内側にして曲げ加工されており、当該表面が胴部分24a側になるように上方視C字状に保温タンクに巻きつけられる。
FIG. 17 illustrates a schematic cross-sectional view of the
保温タンク22の上下の鏡板部24bは、胴部分24aの配管近傍と同様に非真空断熱材23で被覆されており、それら非真空断熱材23は鏡板部24bの外郭形状に併せて成型されている。真空断熱材1としては、実施の形態1~4に記載したいずれのものを用いてもよく、非真空断熱材23としては、例えばEPS(ビーズ法発泡ポリスチレン)断熱材などの成型や切削加工しやすい発泡部材を用いることができる。また、上方C字状に巻きつけられた真空断熱材は、一体物でも周方向に分割されていてもよく、さらに、タンク側面に沿って、軸方向に分割されていてもよい。
The upper and lower
保温タンク22内に不図示の給水配管を介し供給された水は、タンク内部に設けられた加熱源(図示せず)により直接加熱することで沸き上げられる。例えば、タンク内部に設けられた電気ヒータでタンク内の水を直接加熱することで沸き上げられる。あるいは、保温タンク22の外部に加熱源を設け、当該加熱源で加熱された水を給水配管を介して保温タンク22内に供給するようにしてもよい。例えば、燃料電池発電システムなどの排熱回収系統で加熱された循環水や、ヒートポンプシステムで高温冷媒と熱交換して加熱された水を給水配管を介して保温タンク22内に供給してもよい。
The water supplied to the
実際、図17に示した保温タンク22について放熱評価を実施した。評価では、保温タンクの胴径を600mm、容量を370Lとし、保温タンク22の胴部分24aの約2/3を真空断熱材1で覆い、残りの約1/3を非真空断熱材23で覆った。また、真空断熱材1としては、実施の形態2の図9で示した構造のものを、実施の形態1の図3で示した手順で製作し、円筒形状に曲げ加工したものを用いた。非真空断熱材23としては、EPS断熱材を用いた。評価は、電気ヒータでタンク内部の水を90℃まで加熱した後、外気を4度に設定した環境下にて8時間経過した前後の放熱量を測定することで行った。
Actually, heat radiation evaluation was performed on the
まず、厚み8mmの本発明の真空断熱材1と厚み50mmのEPS断熱材23を用いて図17に示した保温タンク22を構成し、8時間経過した前後で放熱量を測定した。次に、実施の形態1で比較例として示した真空断熱材Eを用いたタンクと比較したところ、本発明の真空断熱材を適用したタンクの方が、約8%放熱量が低減できていることを確認した。これにより、本発明の真空断熱材を適用することによって、外気との高い断熱性を有する円筒形状保温タンクが実現できることが確認された。
First, the
また本例では、保温タンク22内の水が加熱源により加熱された温水である例について説明したが、保温タンク22内の水が冷熱源により冷却された冷水であっても良い。例えば冷凍機などによって冷却された水もしくはアイスシャーベットなどが直接もしくは間接的に保温タンク22内部を除熱し、タンク内部を周囲温度より低温に維持するものであっても、本発明の真空断熱材1を適用することでより熱遮蔽性の高い低温の保温タンクが実現できる。
In this example, the example in which the water in the
実施の形態6.
実施の形態5に示した保温タンク22を用いてヒートポンプ式給湯機システムを構成することにより、タンクの断熱性に優れ、省エネ性に優れた給湯機システムを得ることができる。図18は、本発明の実施の形態6のヒートポンプ式給湯機システムを例示する構成図である。ここでは、図18に示す保温タンク22として、実施の形態5に示した保温タンク22を用いている。
By configuring the heat pump type water heater system using the
図18において、ヒートポンプユニット31は、冷媒が循環する冷媒循環系統36に接続された複数の機器で構成されている。詳しくは、ヒートポンプユニット31は、大気から熱を授受し循環冷媒に授与する空気-冷媒熱交換器35と、循環冷媒を加圧する圧縮機25と、循環冷媒から熱を除去し媒体循環系統37を流れる媒体を加熱する冷媒-媒体熱交換器29と、循環冷媒を体積膨張させる膨張弁26とを接続してなる冷媒循環系統36を有する。
18, the
また、媒体循環系統37は、冷媒-媒体熱交換器29と、冷媒-媒体熱交換器29で加熱された媒体を保温タンク22の上部または下部に切り替えて供給する三方弁28と、保温タンク22の下部と冷媒-媒体熱交換器29との間に設けられ、媒体循環系統37内に媒体を循環させる水ポンプ34aから構成されている。
The
また、保温タンク22の上部には、保温タンク22から温水を取り出して、混合弁27aで市水32を混合して給湯に用いる給湯系統38と、保温タンク22から温水を取り出して、混合弁27bにて市水32と混合して浴槽33に供給する浴槽系統40が設けられる。さらに、浴槽33からの水または温水を、水ポンプ34bを介して浴槽33と風呂熱交換器30との間を循環させ、浴槽33からの水またはお湯を保温タンク22からの温水と熱交換させて加熱する追い焚き系統41が設けられている。また、市水供給系統42は保温タンク22の下部にも接続されている。
In addition, hot water is taken out from the
ヒートポンプユニット31を用いた保温タンク内部の水を加熱する動作について説明する。ヒートポンプユニット31は、例えばCO2を冷媒として用い、冷媒循環系統36にて循環される。まず、CO2は、空気-冷媒熱交換器35で大気中の熱を吸収する。次に、圧縮機25で圧縮されて百数十℃まで温度が上昇される。そして、冷媒-媒体熱交換器29で媒体熱循環系統37を流通する媒体である例えば水と熱交換が行われる。熱を奪われたCO2は、膨張器26にてさらに温度が低下されて、再度空気熱交換器35に供給されて循環される。冷媒-媒体熱交換器29にて加熱された水は、例えば90℃強まで加熱され、保温タンク22の上部に供給される。またこの時、保温タンク22の下部からは温度の低い冷水が取り出され、水ポンプ34aにて冷媒-媒体熱交換器29に供給される。この水循環が媒体循環系統37を構成している。この様にヒートポンプユニットを加熱源として用いて、保温タンク22内部の水を加熱させる。
An operation of heating the water inside the heat retaining tank using the
加熱された温水は用途に応じて使用されるが、例えば、保温タンク22の上部から取り出した温水(保温タンク22の下部に市水32を供給することで水圧にて押し上げる)は、混合弁27aにて市水32と混合させて適切な温度になる様に調整された後、給湯用として給湯系統38に供給される。また、同様に混合弁27bにて市水32と混合された温水が浴槽33に供給される。一方、浴槽33の追い焚きには、風呂熱交換器30にて、浴槽33内の温水と、保温タンク22内の温水を熱交換させて利用する。
The heated hot water is used depending on the application. For example, the warm water taken out from the upper part of the heat retaining tank 22 (push up by supplying water with the
図18の保温タンク22として、実施の形態5で示した保温タンク22を適用し、家庭用の給湯機システムの性能を評価した。JIS C 9220に基づいて、給湯機システムの効率を評価した結果、年間給湯効率が約1%向上することが確認された。これにより、本発明の真空断熱材を適用した保温タンクを用いた給湯機システムは、より省エネ性に優れた給湯機システムを提供することができる。
18 was applied as the
図19は、本発明の実施の形態6の他の実施例を示すヒートポンプ式給湯機のシステム構成を示すシステム構成図フローである。図19において図18と同一または相当部分には同一符号を付して説明を省略する。図19において、媒体循環系統37は、三方弁28bによって、保温タンク22を循環する系統と、これと分岐してラジエータ39に接続する系統が設けられている。また、保温タンク22を流通する循環系統は、保温タンク22内部の水とは幾何学的に分離されている。冷媒循環系統36の冷媒には例えばR410Aを用いている。その他の構成は、図18と同じである。
FIG. 19 is a system configuration diagram flow showing a system configuration of a heat pump type water heater showing another example of the sixth embodiment of the present invention. In FIG. 19, the same or corresponding parts as in FIG. In FIG. 19, the
ヒートポンプユニット31を構成する熱交換器29で加熱された媒体循環系統37を流通する約70℃弱の温水は、通常はラジエータ39に供給されて、部屋の暖房に用いられる。ラジエータ39で大気に熱を与えて温度が低下した水は、水ポンプ34aによって冷媒-媒体熱交換器29に戻ることによって、媒体循環系統37を形成している。一方で、三方弁28bの切り替えにより、ラジエータ39への温水の供給を停止し、保温タンク22に設けられた螺旋形状の管を通過させることによって、保温タンク22に満たされた水を加温し、温水として貯える。保温タンク22の貯えられた温水は、シャワー等の給湯として利用される。
Hot water of about 70 ° C. that circulates through the
暖房を主目的とした給湯システムである本実施例では、暖房負荷の小さい時間帯に保温タンクに温水を貯え保温しておくことが必要である。本発明による真空断熱材を適用することで、タンクからの放熱が低減され、より省エネ性に優れた給湯機システムを提供することができる。 In the present embodiment, which is a hot water supply system mainly for heating, it is necessary to store warm water in a heat retaining tank and keep it warm in a time zone with a small heating load. By applying the vacuum heat insulating material according to the present invention, it is possible to provide a water heater system that reduces heat dissipation from the tank and is more energy efficient.
なお、上記にて保温タンクの加熱方法や浴槽の追い焚きや給湯の一例を示したが、何もこれに限定されるものではなく、ヒートポンプの原理を利用してタンク内部の水を直接加熱するものや、媒体循環系統37を流通させる媒体とタンク内部の水を幾何学的に分離して間接加熱するものであっても良い。また、冷媒循環系統36を循環する冷媒にはCO2やR401A冷媒を利用した例を示したが、これに限定されるものではなく、例えば、使用条件等によってはイソブタンなどであっても良い。
In addition, although the example of the heating method of a heat retention tank, the reheating of a bathtub, or a hot water supply was shown above, nothing is limited to this, The water inside a tank is directly heated using the principle of a heat pump. Alternatively, the medium circulating in the
1 真空断熱材、2 繊維シート、2a 突起付き繊維シート、2b 突起無し繊維シート、2c 表裏突起付き繊維シート、3 芯材、4 外被材、5 凸型突起、6 滑りフィルム、7 フィルム単膜、10 熱エンボスロール、11 熱ロール、12 エンボス、13 メッシュ、14 熱風送風機、15 ベルトコンベア、16 繊維供給部、17 プレスロール、18 プレス前繊維シート、19 シートロール、20 メッシュコンベア、21 ローラ、22 保温タンク、23 非真空断熱材、24a タンク胴部、24b タンク鑑板部、25 圧縮機、26 膨張弁、27a 混合弁、27b 混合弁、28 三方弁、28b 三方弁、29 熱交換器、30 風呂熱交換器、31 ヒートポンプユニット、32 市水、33 浴槽、34a 水ポンプ、34b 水ポンプ、35 空気熱交換器、36 冷媒循環系統、37 媒体循環系統、38 給湯系統、39 ラジエータ、40 浴槽系統、41 追い焚き系統、42 市水供給系統。
1 vacuum heat insulating material, 2 fiber sheet, 2a fiber sheet with protrusions, 2b fiber sheet without protrusions, 2c fiber sheet with front and back protrusions, 3 core material, 4 jacket material, 5 convex protrusions, 6 slip film, 7 film
Claims (13)
前記凸型突起が表面にくるように前記繊維シートを配置して芯材を形成する工程と、
前記芯材を外被材で真空密閉する工程とを備えたことを特徴とする真空断熱材の製造方法。 Forming a plurality of convex protrusions on one surface of the fiber sheet;
Arranging the fiber sheet so that the convex protrusions are on the surface and forming a core material;
And a step of vacuum-sealing the core material with a jacket material.
前記繊維シートに加圧機構で圧力を印加する工程を備えたことを特徴とする請求項8に記載の真空断熱材の製造方法。 The step of forming a plurality of convex protrusions on one surface of the fiber sheet,
The method for producing a vacuum heat insulating material according to claim 8, further comprising a step of applying pressure to the fiber sheet with a pressurizing mechanism.
前記繊維シートをメッシュに載せて熱風を吹き付ける工程を備えたことを特徴とする請求項8に記載の真空断熱材の製造方法。 The step of forming a plurality of convex protrusions on one surface of the fiber sheet,
The method for producing a vacuum heat insulating material according to claim 8, further comprising a step of placing the fiber sheet on a mesh and blowing hot air.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201180074561.0A CN103917818B (en) | 2011-11-03 | 2011-11-03 | Vacuum insulation part and manufacture method thereof and employ HEATING BOX and the heat pump water heater of this vacuum insulation part |
| DE201111105810 DE112011105810T5 (en) | 2011-11-03 | 2011-11-03 | Vacuum insulation material, manufacturing process for this, and insulated tank and heat pump water heaters using this |
| PCT/JP2011/075360 WO2013065162A1 (en) | 2011-11-03 | 2011-11-03 | Vacuum heat insulating material, method for manufacturing same, heat retaining tank using same, and heat pump water heater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2011/075360 WO2013065162A1 (en) | 2011-11-03 | 2011-11-03 | Vacuum heat insulating material, method for manufacturing same, heat retaining tank using same, and heat pump water heater |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2013065162A1 true WO2013065162A1 (en) | 2013-05-10 |
Family
ID=48191553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2011/075360 Ceased WO2013065162A1 (en) | 2011-11-03 | 2011-11-03 | Vacuum heat insulating material, method for manufacturing same, heat retaining tank using same, and heat pump water heater |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN103917818B (en) |
| DE (1) | DE112011105810T5 (en) |
| WO (1) | WO2013065162A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013204734A (en) * | 2012-03-29 | 2013-10-07 | Mitsubishi Electric Corp | Vacuum heat insulator, and refrigerator using the same |
| JP2016044800A (en) * | 2014-08-27 | 2016-04-04 | 国立研究開発法人産業技術総合研究所 | Vacuum heat insulating material and manufacturing method thereof |
| JP2016138675A (en) * | 2015-01-26 | 2016-08-04 | 株式会社コロナ | Hot water storage type water heater |
| JP2016138674A (en) * | 2015-01-26 | 2016-08-04 | 株式会社コロナ | Hot water storage water heater |
| JP2018017476A (en) * | 2016-07-29 | 2018-02-01 | 日立アプライアンス株式会社 | Vacuum heat insulating material and refrigerator using the same |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6202174B1 (en) * | 2016-09-30 | 2017-09-27 | 大日本印刷株式会社 | Vacuum insulation outer packaging, vacuum insulation, and articles with vacuum insulation |
| DE102016223057B4 (en) * | 2016-11-22 | 2022-01-13 | Röchling Automotive SE & Co. KG | Thermally insulating flat component with a small component thickness, in particular as a functional space lining of a motor vehicle |
| CN109595682B (en) * | 2018-12-03 | 2020-12-22 | 湖南达道新能源开发有限公司 | Hot water circulating system for geothermal water heating |
| CN111810770B (en) * | 2019-04-10 | 2022-09-20 | 青岛海尔电冰箱有限公司 | Vacuum heat insulation plate, preparation method thereof and refrigerator using vacuum heat insulation plate |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2736468B2 (en) * | 1988-04-15 | 1998-04-02 | デビッド ケー ベンソン | Simple vacuum insulation |
| JP2007205530A (en) * | 2006-02-06 | 2007-08-16 | Hitachi Appliances Inc | Vacuum heat insulating material and manufacturing method thereof |
| JP2008025750A (en) * | 2006-07-24 | 2008-02-07 | Asahi Fiber Glass Co Ltd | Light transmissive vacuum insulation |
| JP2009185408A (en) * | 2008-02-05 | 2009-08-20 | Kao Corp | Non-woven |
| JP2010043759A (en) * | 2008-08-08 | 2010-02-25 | Mitsubishi Electric Corp | Storage type water heater |
| JP2011196392A (en) * | 2010-03-17 | 2011-10-06 | Mitsubishi Electric Corp | Vacuum heat insulation material and method for producing the same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004012125A (en) * | 2003-07-31 | 2004-01-15 | Matsushita Refrig Co Ltd | Heat insulating box |
| JP2007192440A (en) * | 2006-01-18 | 2007-08-02 | Matsushita Electric Ind Co Ltd | Heat pump water heater |
| JP4857999B2 (en) * | 2006-08-04 | 2012-01-18 | 株式会社デンソー | Insulation structure of hot water storage system |
| JP5301816B2 (en) * | 2007-11-21 | 2013-09-25 | 光洋サーモシステム株式会社 | Heat resistant vacuum insulation |
-
2011
- 2011-11-03 CN CN201180074561.0A patent/CN103917818B/en not_active Expired - Fee Related
- 2011-11-03 WO PCT/JP2011/075360 patent/WO2013065162A1/en not_active Ceased
- 2011-11-03 DE DE201111105810 patent/DE112011105810T5/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2736468B2 (en) * | 1988-04-15 | 1998-04-02 | デビッド ケー ベンソン | Simple vacuum insulation |
| JP2007205530A (en) * | 2006-02-06 | 2007-08-16 | Hitachi Appliances Inc | Vacuum heat insulating material and manufacturing method thereof |
| JP2008025750A (en) * | 2006-07-24 | 2008-02-07 | Asahi Fiber Glass Co Ltd | Light transmissive vacuum insulation |
| JP2009185408A (en) * | 2008-02-05 | 2009-08-20 | Kao Corp | Non-woven |
| JP2010043759A (en) * | 2008-08-08 | 2010-02-25 | Mitsubishi Electric Corp | Storage type water heater |
| JP2011196392A (en) * | 2010-03-17 | 2011-10-06 | Mitsubishi Electric Corp | Vacuum heat insulation material and method for producing the same |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013204734A (en) * | 2012-03-29 | 2013-10-07 | Mitsubishi Electric Corp | Vacuum heat insulator, and refrigerator using the same |
| JP2016044800A (en) * | 2014-08-27 | 2016-04-04 | 国立研究開発法人産業技術総合研究所 | Vacuum heat insulating material and manufacturing method thereof |
| JP2016138675A (en) * | 2015-01-26 | 2016-08-04 | 株式会社コロナ | Hot water storage type water heater |
| JP2016138674A (en) * | 2015-01-26 | 2016-08-04 | 株式会社コロナ | Hot water storage water heater |
| JP2018017476A (en) * | 2016-07-29 | 2018-02-01 | 日立アプライアンス株式会社 | Vacuum heat insulating material and refrigerator using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| DE112011105810T5 (en) | 2014-08-14 |
| CN103917818B (en) | 2016-04-27 |
| CN103917818A (en) | 2014-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2013065162A1 (en) | Vacuum heat insulating material, method for manufacturing same, heat retaining tank using same, and heat pump water heater | |
| JP5618756B2 (en) | Vacuum insulation material and manufacturing method thereof | |
| JP6025969B2 (en) | Vacuum heat insulating material, heat insulation tank equipped with the same, heat insulation body, and heat pump water heater | |
| JP5599383B2 (en) | Vacuum heat insulating material, heat insulating box using vacuum heat insulating material, equipment using vacuum heat insulating material, and method for manufacturing vacuum heat insulating material | |
| JP4969436B2 (en) | Vacuum insulation material and equipment using the same | |
| JP5111331B2 (en) | Vacuum heat insulating material and heat insulating box using this vacuum heat insulating material | |
| US20190001626A1 (en) | Thermal insulator, vacuum insulation member, and method of manufacturing vacuum insulation member | |
| CN102628539A (en) | Vacuum heat-insulating material and heat-insulating box | |
| CN102174974A (en) | Vacuum insulation panel supported by full-paperboard structure and manufacturing method thereof | |
| JP5788081B2 (en) | Composite insulation, thermal insulation tank and heat pump water heater | |
| JP2010054183A5 (en) | ||
| JP2018017314A (en) | Vacuum heat insulating material and refrigerator using the same | |
| EP3133330B1 (en) | Vacuum heat-insulating material and heat-retaining body with same | |
| CN103363250B (en) | Vacuum heat insulating material and refrigerator using the vacuum heat insulating material | |
| JP5216510B2 (en) | Vacuum insulation material and equipment using the same | |
| JP6016435B2 (en) | Vacuum insulation material and insulated device | |
| EP2985376B1 (en) | Core material for vacuum insulator, comprising organic synthetic fiber, and vacuum insulator containing same | |
| KR101764947B1 (en) | Method for forming multi-insulation structure of hot water heating apparatus and hot water heating apparatus having the multi-insulation structure | |
| CN106123343A (en) | Heat preservation liquid storage tank and water heater | |
| JP2006090499A (en) | Vacuum insulation material and manufacturing method thereof | |
| JP2018204711A (en) | Vacuum heat insulation material and refrigerator using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WWE | Wipo information: entry into national phase |
Ref document number: 201180074561.0 Country of ref document: CN |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 11875187 Country of ref document: EP Kind code of ref document: A1 |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 112011105810 Country of ref document: DE Ref document number: 1120111058101 Country of ref document: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 11875187 Country of ref document: EP Kind code of ref document: A1 |
|
| NENP | Non-entry into the national phase |
Ref country code: JP |