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WO2012030639A3 - Très long cycle de vie des batteries au lithium-ion avec des matériaux cathodiques riches en lithium - Google Patents

Très long cycle de vie des batteries au lithium-ion avec des matériaux cathodiques riches en lithium Download PDF

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Publication number
WO2012030639A3
WO2012030639A3 PCT/US2011/049304 US2011049304W WO2012030639A3 WO 2012030639 A3 WO2012030639 A3 WO 2012030639A3 US 2011049304 W US2011049304 W US 2011049304W WO 2012030639 A3 WO2012030639 A3 WO 2012030639A3
Authority
WO
WIPO (PCT)
Prior art keywords
discharge
capacity
lithium
lithium ion
cycling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2011/049304
Other languages
English (en)
Other versions
WO2012030639A2 (fr
Inventor
Shabab Amiruddin
Bing Li
Sujeet Kumar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Envia Systems Inc
Original Assignee
Envia Systems Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/213,756 external-priority patent/US8928286B2/en
Application filed by Envia Systems Inc filed Critical Envia Systems Inc
Priority to CN2011800500651A priority Critical patent/CN103168383A/zh
Priority to KR1020137008541A priority patent/KR20130108332A/ko
Priority to EP11822392.4A priority patent/EP2612393A4/fr
Priority to JP2013527139A priority patent/JP2013539594A/ja
Publication of WO2012030639A2 publication Critical patent/WO2012030639A2/fr
Publication of WO2012030639A3 publication Critical patent/WO2012030639A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention se rapporte à des batteries à lithium-ion qui peuvent être activées et ensuite utilisées pour exploiter une petite fraction de la capacité du cycle de décharge de telle sorte que la capacité de décharge et la tension de décharge moyenne restent dans des valeurs initiales pendant plusieurs milliers de cycles. Une meilleure performance de cycle d'utilisation a été obtenue à des vitesses de décharge relativement élevées et pour des formats de batterie pratiques. On peut également obtenir une performance de batterie à lithium-ion présentant une meilleure performance de cycle d'utilisation avec des batteries partiellement activées de telle sorte que les bonnes capacités de décharge et la tension de décharge moyenne chutent de plus de 20 % par rapport aux valeurs initiales. Le matériau actif pour l'électrode positive peut être un oxyde métallique riche en lithium. L'activation de la batterie peut comprendre des changements de phase des matériaux actifs. Comme décrit dans les présentes, les changements de phase peuvent être manipulés pour exploiter une fraction raisonnable de la capacité élevée disponible du matériau tout en assurant une stabilité remarquable du cycle d'utilisation.
PCT/US2011/049304 2010-09-03 2011-08-26 Très long cycle de vie des batteries au lithium-ion avec des matériaux cathodiques riches en lithium Ceased WO2012030639A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2011800500651A CN103168383A (zh) 2010-09-03 2011-08-26 具有富含锂的阴极材料的极长循环锂离子电池
KR1020137008541A KR20130108332A (ko) 2010-09-03 2011-08-26 리튬 풍부한 캐소드 물질을 가진 리튬 이온 전지의 매우 긴 사이클링
EP11822392.4A EP2612393A4 (fr) 2010-09-03 2011-08-26 Très long cycle de vie des batteries au lithium-ion avec des matériaux cathodiques riches en lithium
JP2013527139A JP2013539594A (ja) 2010-09-03 2011-08-26 リチウムリッチカソード材料を用いたリチウムイオン電池の非常に長期のサイクリング

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US38000410P 2010-09-03 2010-09-03
US61/380,004 2010-09-03
US13/213,756 US8928286B2 (en) 2010-09-03 2011-08-19 Very long cycling of lithium ion batteries with lithium rich cathode materials
US13/213,756 2011-08-19

Publications (2)

Publication Number Publication Date
WO2012030639A2 WO2012030639A2 (fr) 2012-03-08
WO2012030639A3 true WO2012030639A3 (fr) 2012-08-16

Family

ID=48536638

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/049304 Ceased WO2012030639A2 (fr) 2010-09-03 2011-08-26 Très long cycle de vie des batteries au lithium-ion avec des matériaux cathodiques riches en lithium

Country Status (6)

Country Link
EP (1) EP2612393A4 (fr)
JP (1) JP2013539594A (fr)
KR (1) KR20130108332A (fr)
CN (1) CN103168383A (fr)
TW (1) TW201230441A (fr)
WO (1) WO2012030639A2 (fr)

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US8663849B2 (en) * 2010-09-22 2014-03-04 Envia Systems, Inc. Metal halide coatings on lithium ion battery positive electrode materials and corresponding batteries
JP6133878B2 (ja) * 2011-10-21 2017-05-24 コリア インスティテュート オブ インダストリアル テクノロジー 電気自動車用リチウム二次電池用の高エネルギー密度の正極複合素材合成及び電極製造技術
CN105556715A (zh) * 2013-07-18 2016-05-04 罗伯特·博世有限公司 氧化物涂覆的xLi2MnO3·(1-x)LiNiyCozMn1-y-zO2核-壳结构的阴极材料
JP2015084303A (ja) * 2013-10-25 2015-04-30 三星エスディアイ株式会社Ｓａｍｓｕｎｇ ＳＤＩ Ｃｏ．，Ｌｔｄ． リチウムイオン二次電池
CN103840151B (zh) * 2013-12-13 2016-04-13 山东海特电子新材料有限公司 一种特殊单晶结构的三元正极材料及其制备方法
CN104749525B (zh) * 2013-12-31 2017-11-17 华为技术有限公司 电池老化状态检测装置、系统、方法
KR102152370B1 (ko) * 2013-12-31 2020-09-07 삼성에스디아이 주식회사 양극 활물질 및 이를 포함하는 리튬 이차전지
FR3017489B1 (fr) * 2014-02-11 2016-01-29 Renault Sas Batterie lithium-ion comprenant une cathode riche en lithium et une anode a base de graphite
CN104319419A (zh) * 2014-11-10 2015-01-28 海宁兰博电源科技有限公司 一种高电压异形锂聚合物软包装电池
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US10128675B2 (en) 2015-09-14 2018-11-13 Toyota Jidosha Kabushiki Kaisha All-solid-state battery system and method of manufacturing the same
JP6699473B2 (ja) * 2015-09-14 2020-05-27 トヨタ自動車株式会社 全固体電池システム及びその製造方法
KR102473532B1 (ko) * 2015-12-31 2022-12-05 삼성전자주식회사 양극 활물질 및 상기 양극 활물질을 채용한 양극과 리튬 전지
KR102589963B1 (ko) * 2016-04-12 2023-10-13 삼성에스디아이 주식회사 배터리의 충방전 제어 장치 및 그 제어 방법
CN106025256B (zh) * 2016-05-09 2019-10-29 北京工业大学 一种“双晶畴”富锂层状氧化物材料及制备方法
CN105810934B (zh) * 2016-05-09 2019-07-05 北京工业大学 一种稳定富锂层状氧化物材料晶畴结构方法
KR102859981B1 (ko) 2019-04-08 2025-09-15 주식회사 엘지에너지솔루션 이차전지용 양극 및 이를 포함하는 리튬 이차전지
KR102659679B1 (ko) * 2019-04-22 2024-04-19 주식회사 엘지에너지솔루션 배터리의 미분 전압 커브를 결정하기 위한 장치 및 방법과, 상기 장치를 포함하는 배터리 팩
JP7683485B2 (ja) * 2019-11-22 2025-05-27 株式会社Ｇｓユアサ 蓄電素子及び蓄電装置
TWI711203B (zh) 2019-12-19 2020-11-21 國立臺灣科技大學 非水性電解液的處理方法以及電池的製造方法
KR102722397B1 (ko) 2020-10-16 2024-10-24 주식회사 엘지에너지솔루션 활성화 프로토콜 생성 방법, 이를 이용한 활성화 방법 및 활성화 장치
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Also Published As

Publication number Publication date
CN103168383A (zh) 2013-06-19
EP2612393A2 (fr) 2013-07-10
JP2013539594A (ja) 2013-10-24
KR20130108332A (ko) 2013-10-02
WO2012030639A2 (fr) 2012-03-08
TW201230441A (en) 2012-07-16
EP2612393A4 (fr) 2014-11-05

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