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WO2012030639A3 - Very long cycling of lithium ion batteries with lithium rich cathode materials - Google Patents

Very long cycling of lithium ion batteries with lithium rich cathode materials Download PDF

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Publication number
WO2012030639A3
WO2012030639A3 PCT/US2011/049304 US2011049304W WO2012030639A3 WO 2012030639 A3 WO2012030639 A3 WO 2012030639A3 US 2011049304 W US2011049304 W US 2011049304W WO 2012030639 A3 WO2012030639 A3 WO 2012030639A3
Authority
WO
WIPO (PCT)
Prior art keywords
discharge
capacity
lithium
lithium ion
cycling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2011/049304
Other languages
French (fr)
Other versions
WO2012030639A2 (en
Inventor
Shabab Amiruddin
Bing Li
Sujeet Kumar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Envia Systems Inc
Original Assignee
Envia Systems Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/213,756 external-priority patent/US8928286B2/en
Application filed by Envia Systems Inc filed Critical Envia Systems Inc
Priority to CN2011800500651A priority Critical patent/CN103168383A/en
Priority to KR1020137008541A priority patent/KR20130108332A/en
Priority to EP11822392.4A priority patent/EP2612393A4/en
Priority to JP2013527139A priority patent/JP2013539594A/en
Publication of WO2012030639A2 publication Critical patent/WO2012030639A2/en
Publication of WO2012030639A3 publication Critical patent/WO2012030639A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Lithium ion batteries can be activated and then cycled to exploit a moderate fraction of the discharge cycling capacity such that the discharge capacity and average discharge voltage stay within initial values for thousands of cycles. The superior cycling performance has been achieved at relatively high discharge rates and for practical battery formats. Lithium ion battery performance can also be achieved with superior cycling performance with partially activated batteries such that good discharge capacities can be exploited for many thousands of cycles before the discharge capacity and average discharge voltage drops more than 20% from initial values. The positive electrode active material can be a lithium rich metal oxide. The activation of the battery can comprise phase changes of the active materials. As described herein, the phase changes can be manipulated to exploit a reasonable fraction of the available high capacity of the material while providing outstanding cycling stability.
PCT/US2011/049304 2010-09-03 2011-08-26 Very long cycling of lithium ion batteries with lithium rich cathode materials Ceased WO2012030639A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2011800500651A CN103168383A (en) 2010-09-03 2011-08-26 Very long cycling of lithium ion batteries with lithium rich cathode materials
KR1020137008541A KR20130108332A (en) 2010-09-03 2011-08-26 Very long cycling of lithium ion batteries with lithium rich cathode materials
EP11822392.4A EP2612393A4 (en) 2010-09-03 2011-08-26 Very long cycling of lithium ion batteries with lithium rich cathode materials
JP2013527139A JP2013539594A (en) 2010-09-03 2011-08-26 Extremely long-term cycling of lithium-ion batteries using lithium-rich cathode materials

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US38000410P 2010-09-03 2010-09-03
US61/380,004 2010-09-03
US13/213,756 US8928286B2 (en) 2010-09-03 2011-08-19 Very long cycling of lithium ion batteries with lithium rich cathode materials
US13/213,756 2011-08-19

Publications (2)

Publication Number Publication Date
WO2012030639A2 WO2012030639A2 (en) 2012-03-08
WO2012030639A3 true WO2012030639A3 (en) 2012-08-16

Family

ID=48536638

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/049304 Ceased WO2012030639A2 (en) 2010-09-03 2011-08-26 Very long cycling of lithium ion batteries with lithium rich cathode materials

Country Status (6)

Country Link
EP (1) EP2612393A4 (en)
JP (1) JP2013539594A (en)
KR (1) KR20130108332A (en)
CN (1) CN103168383A (en)
TW (1) TW201230441A (en)
WO (1) WO2012030639A2 (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8663849B2 (en) * 2010-09-22 2014-03-04 Envia Systems, Inc. Metal halide coatings on lithium ion battery positive electrode materials and corresponding batteries
JP6133878B2 (en) * 2011-10-21 2017-05-24 コリア インスティテュート オブ インダストリアル テクノロジー High energy density cathode composite material synthesis and electrode manufacturing technology for lithium secondary batteries for electric vehicles
CN105556715A (en) * 2013-07-18 2016-05-04 罗伯特·博世有限公司 An oxide coated xLi2MnO3(1-x)LiNiyCozMn1-y-zO2 core-shell structured cathode materials
JP2015084303A (en) * 2013-10-25 2015-04-30 三星エスディアイ株式会社Ｓａｍｓｕｎｇ ＳＤＩ Ｃｏ．，Ｌｔｄ． Rechargeable lithium ion battery
CN103840151B (en) * 2013-12-13 2016-04-13 山东海特电子新材料有限公司 Tertiary cathode material of a kind of special mono-crystalline structures and preparation method thereof
CN104749525B (en) * 2013-12-31 2017-11-17 华为技术有限公司 Battery aging status detection means, system, method
KR102152370B1 (en) * 2013-12-31 2020-09-07 삼성에스디아이 주식회사 Cathode active material and lithium secondary batteries comprising the same
FR3017489B1 (en) * 2014-02-11 2016-01-29 Renault Sas LITHIUM ION BATTERY COMPRISING A LITHIUM RICH CATHODE AND A GRAPHITE-BASED ANODE
CN104319419A (en) * 2014-11-10 2015-01-28 海宁兰博电源科技有限公司 High-voltage special-shaped Li-polymer soft-package battery
CN106469838A (en) * 2015-08-14 2017-03-01 深圳市比克动力电池有限公司 The charging method of cylinder power lithium-ion battery and device
KR102010015B1 (en) * 2015-08-31 2019-08-12 주식회사 엘지화학 Lithium secondary battery and operating method thereof
KR102010014B1 (en) * 2015-08-31 2019-08-12 주식회사 엘지화학 Lithium secondary battery and operating method thereof
US10128675B2 (en) 2015-09-14 2018-11-13 Toyota Jidosha Kabushiki Kaisha All-solid-state battery system and method of manufacturing the same
JP6699473B2 (en) * 2015-09-14 2020-05-27 トヨタ自動車株式会社 All-solid-state battery system and manufacturing method thereof
KR102473532B1 (en) * 2015-12-31 2022-12-05 삼성전자주식회사 Positive active material, and positive electrode and lithium battery containing the material
KR102589963B1 (en) * 2016-04-12 2023-10-13 삼성에스디아이 주식회사 Charge and discharge control device of battery and control method thereof
CN106025256B (en) * 2016-05-09 2019-10-29 北京工业大学 One kind " twin crystal farmland " lithium-rich oxide material and preparation method
CN105810934B (en) * 2016-05-09 2019-07-05 北京工业大学 A kind of stabilizing lithium rich layered oxide material crystalline domain structure method
KR102859981B1 (en) 2019-04-08 2025-09-15 주식회사 엘지에너지솔루션 Positive electrode for secondary battery and lithium secondary battery comprising the same
KR102659679B1 (en) * 2019-04-22 2024-04-19 주식회사 엘지에너지솔루션 Apparatus and method for determining differential voltage curve of battery, and battery pack including the apparatus
JP7683485B2 (en) * 2019-11-22 2025-05-27 株式会社Ｇｓユアサ Energy storage element and energy storage device
TWI711203B (en) 2019-12-19 2020-11-21 國立臺灣科技大學 Treating method of non-auqeous electrolyte and method of fabricating battery
KR102722397B1 (en) 2020-10-16 2024-10-24 주식회사 엘지에너지솔루션 Activation protocol generation method, activation method and activation device using the same
EP4576256A1 (en) * 2022-09-15 2025-06-25 SK On Co., Ltd. Lithium secondary battery and operation method therefor
JP7743852B2 (en) * 2023-04-21 2025-09-25 トヨタ自動車株式会社 Lithium-ion battery manufacturing method and lithium-ion battery

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080099132A (en) * 2007-05-07 2008-11-12 한양대학교 산학협력단 Method for producing positive electrode active material for lithium secondary battery, positive electrode active material for lithium secondary battery manufactured by this method and lithium secondary battery comprising same
KR20090078128A (en) * 2008-01-14 2009-07-17 한양대학교 산학협력단 Cathode active material for lithium secondary battery, preparation method thereof, and lithium secondary battery comprising same
US20100151332A1 (en) * 2008-12-11 2010-06-17 Herman Lopez Positive electrode materials for high discharge capacity lithium ion batteries

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100822013B1 (en) * 2005-04-15 2008-04-14 주식회사 에너세라믹 Fluorine compound coated lithium secondary battery positive electrode active material and its manufacturing method
JP5072056B2 (en) * 2005-06-07 2012-11-14 日立マクセルエナジー株式会社 Non-aqueous electrolyte secondary battery
JP2008300180A (en) * 2007-05-31 2008-12-11 Sanyo Electric Co Ltd Nonaqueous electrolyte secondary battery
JP5050834B2 (en) * 2007-12-21 2012-10-17 株式会社Ｇｓユアサ Active material for lithium secondary battery, lithium secondary battery and method for producing the same
US8187752B2 (en) * 2008-04-16 2012-05-29 Envia Systems, Inc. High energy lithium ion secondary batteries
US10056644B2 (en) * 2009-07-24 2018-08-21 Zenlabs Energy, Inc. Lithium ion batteries with long cycling performance
US8475959B2 (en) * 2009-08-27 2013-07-02 Envia Systems, Inc. Lithium doped cathode material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080099132A (en) * 2007-05-07 2008-11-12 한양대학교 산학협력단 Method for producing positive electrode active material for lithium secondary battery, positive electrode active material for lithium secondary battery manufactured by this method and lithium secondary battery comprising same
KR20090078128A (en) * 2008-01-14 2009-07-17 한양대학교 산학협력단 Cathode active material for lithium secondary battery, preparation method thereof, and lithium secondary battery comprising same
US20100151332A1 (en) * 2008-12-11 2010-06-17 Herman Lopez Positive electrode materials for high discharge capacity lithium ion batteries

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2612393A4 *

Also Published As

Publication number Publication date
CN103168383A (en) 2013-06-19
EP2612393A2 (en) 2013-07-10
JP2013539594A (en) 2013-10-24
KR20130108332A (en) 2013-10-02
WO2012030639A2 (en) 2012-03-08
TW201230441A (en) 2012-07-16
EP2612393A4 (en) 2014-11-05

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