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WO2012078019A3 - Electrorecuperación de oro y plata a partir de soluciones de tiosulfato - Google Patents

Electrorecuperación de oro y plata a partir de soluciones de tiosulfato Download PDF

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Publication number
WO2012078019A3
WO2012078019A3 PCT/MX2011/000150 MX2011000150W WO2012078019A3 WO 2012078019 A3 WO2012078019 A3 WO 2012078019A3 MX 2011000150 W MX2011000150 W MX 2011000150W WO 2012078019 A3 WO2012078019 A3 WO 2012078019A3
Authority
WO
WIPO (PCT)
Prior art keywords
copper
silver
anode
gold
sustaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/MX2011/000150
Other languages
English (en)
French (fr)
Other versions
WO2012078019A4 (es
WO2012078019A2 (es
Inventor
Gretchen Terri Lapidus Lavine
Alejandro Rafael ALONSO GÓMEZ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universidad Autonoma Metropolitana (UAM)
Original Assignee
Universidad Autonoma Metropolitana (UAM)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=45558361&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2012078019(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to RU2013131237/02A priority Critical patent/RU2013131237A/ru
Priority to US13/992,713 priority patent/US20140311896A1/en
Priority to CA2821042A priority patent/CA2821042A1/en
Priority to BR112013014261A priority patent/BR112013014261A2/pt
Priority to JP2013543122A priority patent/JP2014501850A/ja
Application filed by Universidad Autonoma Metropolitana (UAM) filed Critical Universidad Autonoma Metropolitana (UAM)
Priority to EP20110813914 priority patent/EP2650403A2/en
Priority to AU2011339119A priority patent/AU2011339119A1/en
Priority to CN201180067296.3A priority patent/CN103842557A/zh
Publication of WO2012078019A2 publication Critical patent/WO2012078019A2/es
Publication of WO2012078019A3 publication Critical patent/WO2012078019A3/es
Publication of WO2012078019A4 publication Critical patent/WO2012078019A4/es
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/22—Electrolytic production, recovery or refining of metals by electrolysis of solutions of metals not provided for in groups C25C1/02 - C25C1/20
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/20—Electrolytic production, recovery or refining of metals by electrolysis of solutions of noble metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/06—Operating or servicing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

La presente invención está relacionada con la industria minera, de tratamiento de minerales y materiales que contengan oro y plata. Específicamente se relaciona con un proceso para la recuperación de oro y plata, a partir de soluciones de tiosulfato de cobre, mediante un proceso de electrólisis autogenerada. Las ventajas de la presente invención con respecto a las del estado de la técnica radican en que la nuestra tiene una mayor velocidad en comparación con la cementación con cobre, sin utilizar corriente eléctrica. Nuestro proceso está caracterizado por llevarse a cabo en una celda electroquímica de autogeneración, en la que ánodo y cátodo se encuentren conectados en corto circuito; y los compartimientos anódíco y catódico se encuentren separados mediante una membrana de intercambio iónico. Además al contar con un ánodo de cobre y utilizar la solución despojada como anolito, los niveles de cobre soluble se mantienen estables, conservando así el poder lixivante de las soluciones de tiosulfato, con lo que es posible recircularlas a una nueva etapa de lixiviación.
PCT/MX2011/000150 2010-12-09 2011-12-09 Electrorecuperación de oro y plata a partir de soluciones de tiosulfato Ceased WO2012078019A2 (es)

Priority Applications (8)

Application Number Priority Date Filing Date Title
CN201180067296.3A CN103842557A (zh) 2010-12-09 2011-12-09 从硫代硫酸盐溶液电回收金和银
AU2011339119A AU2011339119A1 (en) 2010-12-09 2011-12-09 Electrorecovery of gold and silver from thiosulphate solutions
CA2821042A CA2821042A1 (en) 2010-12-09 2011-12-09 Gold and silver electrorecovery from thiosulfate leaching solutions
BR112013014261A BR112013014261A2 (pt) 2010-12-09 2011-12-09 célula de eletrólise autogerada e processo de recuperação de prata a partir de soluções lixiviantes de tiossulfato
JP2013543122A JP2014501850A (ja) 2010-12-09 2011-12-09 チオ硫酸塩溶液からの金および銀の電気的回収
RU2013131237/02A RU2013131237A (ru) 2010-12-09 2011-12-09 Электролитическое извлечение золота и серебра из тиосульфатных выщелачивающих растворов
EP20110813914 EP2650403A2 (en) 2010-12-09 2011-12-09 Electrorecovery of gold and silver from thiosulphate solutions
US13/992,713 US20140311896A1 (en) 2010-12-09 2011-12-09 Electrorecovery of gold and silver from thiosulphate solutions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
MXMX/A/2010/013510 2010-12-09
MX2010013510A MX2010013510A (es) 2010-12-09 2010-12-09 Electrorecuperacion de oro y plata a partir de soluciones de tiosulfato.

Publications (3)

Publication Number Publication Date
WO2012078019A2 WO2012078019A2 (es) 2012-06-14
WO2012078019A3 true WO2012078019A3 (es) 2012-12-06
WO2012078019A4 WO2012078019A4 (es) 2013-01-24

Family

ID=45558361

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/MX2011/000150 Ceased WO2012078019A2 (es) 2010-12-09 2011-12-09 Electrorecuperación de oro y plata a partir de soluciones de tiosulfato

Country Status (12)

Country Link
US (1) US20140311896A1 (es)
EP (1) EP2650403A2 (es)
JP (1) JP2014501850A (es)
CN (1) CN103842557A (es)
AU (1) AU2011339119A1 (es)
BR (1) BR112013014261A2 (es)
CA (1) CA2821042A1 (es)
CO (1) CO6801690A2 (es)
MX (1) MX2010013510A (es)
PE (1) PE20140643A1 (es)
RU (1) RU2013131237A (es)
WO (1) WO2012078019A2 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101349305B1 (ko) * 2013-05-24 2014-01-13 한국지질자원연구원 유로형 셀을 이용한 희유 금속의 전해 채취 장치, 및 그 방법
AU2015259608B2 (en) 2014-05-12 2019-10-03 Sumitomo Corporation Of Americas Brine leaching process for recovering valuable metals from oxide materials
CN104499003A (zh) * 2014-11-13 2015-04-08 黄石市英柯有色金属有限公司 从水溶液中提取金属的方法
WO2016168930A1 (en) 2015-04-21 2016-10-27 University Of Saskatchewan Methods for simultaneous leaching and extraction of precious metals
CN104911351A (zh) * 2015-06-07 2015-09-16 长春黄金研究院 一种生物浸出金及浸出液中金自发电回收方法
US9777346B2 (en) 2015-09-03 2017-10-03 Battelle Energy Alliance, Llc Methods for recovering metals from electronic waste, and related systems
US10807085B2 (en) * 2017-11-17 2020-10-20 University Of Massachusetts Silver recovery as Ag0nanoparticles from ion-exchange regenerant solution
CN108642091B (zh) * 2018-05-02 2021-03-30 江南大学 一种同步回收金属与单质硫的方法
CN108660314B (zh) * 2018-05-02 2019-11-26 江南大学 一步法回收金属的方法
CN108624912B (zh) * 2018-05-25 2020-04-24 王勇 一种贵金属元素电化回收工艺及系统
CN113621995B (zh) * 2021-07-16 2023-12-26 武汉理工大学 一种基于电化学联合催化技术回收硫代硫酸盐浸出液中贵金属的方法
CN114774686A (zh) * 2022-05-06 2022-07-22 河南理工大学 一种在硫代硫酸盐浸金体系中置换回收金的装置及方法
CN115928150B (zh) * 2022-11-08 2025-07-15 重庆川仪自动化股份有限公司 一种从含银废料中回收银的方法
CN116334695B (zh) * 2023-02-20 2025-07-18 中国机械总院集团郑州机械研究所有限公司 一种熔盐电解制备银铜复合材料的方法及银铜复合材料
CN118007193B (zh) * 2024-01-12 2024-10-18 武汉理工大学 一种硫代硫酸盐电化学浸出-回收一体化短流程提取贵金属的方法
CN118345450B (zh) * 2024-04-03 2024-12-03 武汉理工大学 一种电化学还原回收硫代硫酸金中金的方法
PL448742A1 (pl) * 2024-05-29 2025-12-01 Sieć Badawcza Łukasiewicz - Instytut Metali Nieżelaznych Sposób rozdziału metali szlachetnych z roztworów tiomocznika z kwasem chlorowodorowym

Citations (1)

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Family Cites Families (3)

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US3994789A (en) * 1974-10-02 1976-11-30 Progressive Scientific Associates, Inc. Galvanic cementation process
CN85103707B (zh) * 1985-05-13 1987-05-06 华东化工学院 从金矿中综合提取金、银 、铜的工艺过程
CA1334745C (en) * 1989-03-28 1995-03-14 Paul Spira Continuous silver refining cell

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5607619A (en) * 1988-03-07 1997-03-04 Great Lakes Chemical Corporation Inorganic perbromide compositions and methods of use thereof

Non-Patent Citations (4)

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Title
CHIN YEAN YAP ET AL: "Electrogenerative Processes for Environmental Applications", CLEAN - SOIL, AIR, WATER, vol. 36, no. 5-6, 1 June 2008 (2008-06-01), pages 443 - 452, XP055036200, ISSN: 1863-0650, DOI: 10.1002/clen.200800072 *
CIFUENTES L ET AL: "Aspects of the development of a copper electrowinning cell based on reactive electrodialysis", CHEMICAL ENGINEERING SCIENCE, OXFORD, GB, vol. 59, no. 5, 1 March 2004 (2004-03-01), pages 1087 - 1101, XP004494390, ISSN: 0009-2509, DOI: 10.1016/J.CES.2003.12.013 *
HOR Y P ET AL: "Removal and recovery of copper via a galvanic cementation system part II: batch-recycle reactor", JOURNAL OF APPLIED ELECTROCHEMISTRY, KLUWER ACADEMIC PUBLISHERS, DO, vol. 35, no. 6, 1 June 2005 (2005-06-01), pages 609 - 613, XP019247420, ISSN: 1572-8838 *
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Also Published As

Publication number Publication date
RU2013131237A (ru) 2015-01-20
AU2011339119A1 (en) 2013-08-01
CO6801690A2 (es) 2013-11-29
US20140311896A1 (en) 2014-10-23
EP2650403A2 (en) 2013-10-16
PE20140643A1 (es) 2014-06-02
BR112013014261A2 (pt) 2017-08-01
WO2012078019A4 (es) 2013-01-24
JP2014501850A (ja) 2014-01-23
WO2012078019A2 (es) 2012-06-14
CA2821042A1 (en) 2012-06-14
MX2010013510A (es) 2012-06-08
CN103842557A (zh) 2014-06-04

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