[go: up one dir, main page]

WO2011072009A1 - Substrat solide poreux pouvant être dissous et revêtement résidant en surface comprenant des microsphères de matrice - Google Patents

Substrat solide poreux pouvant être dissous et revêtement résidant en surface comprenant des microsphères de matrice Download PDF

Info

Publication number
WO2011072009A1
WO2011072009A1 PCT/US2010/059455 US2010059455W WO2011072009A1 WO 2011072009 A1 WO2011072009 A1 WO 2011072009A1 US 2010059455 W US2010059455 W US 2010059455W WO 2011072009 A1 WO2011072009 A1 WO 2011072009A1
Authority
WO
WIPO (PCT)
Prior art keywords
personal care
dissolvable solid
solid substrate
porous dissolvable
care article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/059455
Other languages
English (en)
Inventor
Robert Wayne Glenn, Jr.
Kathleen Mary Kaufman
Joanne Roberta Willman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to BR112012013838A priority Critical patent/BR112012013838A2/pt
Priority to JP2012542246A priority patent/JP5639659B2/ja
Priority to MX2012006550A priority patent/MX339322B/es
Priority to EP10796222.7A priority patent/EP2509564B1/fr
Priority to CN2010800556722A priority patent/CN102647972B/zh
Publication of WO2011072009A1 publication Critical patent/WO2011072009A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0034—Fixed on a solid conventional detergent ingredient
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay

Definitions

  • cationic surfactant conditioners interacted negatively with the anionic surfactants included in the shampoo/cleaning products for foaming. These new conditioning actives did not necessarily reproduce the conditioning benefit that was achieved by the traditional conditioning actives (i.e. cationic surfactant conditioners).
  • fragrance due to the water present in the personal care products, inclusion of fragrance is limited to either the solubilization or emulsification within aqueous amphiphile assemblies (micelles, liquid crystals etc.). As a result, a significant portion of the fragrance molecules are "trapped" within these aqueous assemblies which can limit the efficient delivery of the fragrance to the nostrils of the consumer during product usage (i.e. lower fragrance bloom) and to the target keratinous substrate (i.e. skin and hair). Moreover, choice of fragrance is limited to those that deliver a single scent experience to the consumer (i.e. the scent of the product as packaged is the same and the only fragrance experienced during use), and precludes delivery of a fragrance that is activated by water during use.
  • the porous dissolvable solid substrate of present invention is a flat, flexible substrate in the form of a pad, a strip or tape and having a thickness of from about 0.5 mm to about 10 mm, in one embodiment from about 1 mm to about 9 mm, in another embodiment from about 2 mm to about 8 mm, and in a further embodiment from about 3 mm to about 7 mm as measured by the below methodology.
  • the porous dissolvable solid substrate of the present invention can also take the form of a dissolvable fibrous web structure.
  • Non-ionic surfactants are included as a process aid in making a stable porous dissolvable solid substrate.
  • Suitable nonionic surfactants for use in the present invention include those described in McCutcheon's Detergents and Emulsifiers, North American edition (1986), Allured Publishing Corp., and McCutcheon's Functional Materials, North American edition (1992).
  • the one or more water-soluble polymers may be present from about 10% to about 50% by weight of the porous dissolvable solid substrate, in one embodiment from about 15% to about 40% by weight of the porous dissolvable solid substrate, and in yet another embodiment from about 20% to about 30% by weight of the porous dissolvable solid substrate.
  • At least one of the one or more water-soluble polymers is chosen such that about 2% by weight solution of the water-soluble polymer gives a viscosity at 20°C of from about 4 centipoise to about 80 centipoise; in an alternate embodiment from about 5 centipoise to about 70 centipoise; and in another embodiment from about 6 centipoise to about 60 centipoise.
  • the combined weight percentage of the water-soluble polymer(s) and starch-based material generally ranges from about 10% to about 50%, in one embodiment from about 15% to about 40%, and in a particular embodiment from about 20% to about 30% by weight relative to the total weight of the porous dissolvable solid substrate.
  • the weight ratio of the water-soluble polymer(s) to the starch-based material can generally range from about 1:10 to about 10:1, in one embodiment from about 1:8 to about 8:1, in still another embodiment from about 1:7 to about 7:1, and in yet another embodiment from about 6:1 to about 1:6.
  • polyols examples include, but are not limited to, glycerin, diglycerin, propylene glycol, ethylene glycol, butylene glycol, pentylene glycol, cyclohexane dimethanol, hexane diol, polyethylene glycol (200-600), sugar alcohols such as sorbitol, manitol, lactitol and other mono- and polyhydric low molecular weight alcohols (e.g., C2-C8 alcohols); mono di- and oligo- saccharides such as fructose, glucose, sucrose, maltose, lactose, and high fructose corn syrup solids and ascorbic acid.
  • sugar alcohols such as sorbitol, manitol, lactitol and other mono- and polyhydric low molecular weight alcohols (e.g., C2-C8 alcohols); mono di- and oligo- saccharides such as fructose, glucose, sucrose, maltose, lac
  • the matrix microsphere comprises (by weight of the matrix microsphere composition): i) a starch-derived material at a level of in one embodiment from about 25% to about 70%, in another embodiment from about 30% to about 60%, and in yet another embodiment from about 35% to about 50%; ii) a cationic surfactant conditioner at a level in one embodiment of from about 5% to about 60%, in another embodiment from about 15% to about 50%, and in yet another embodiment from about 20% to about 40%; and iii) a perfume at a level in one embodiment of from about 5% to about 60%, in another embodiment from about 15% to about 50%, and in yet another embodiment from about 20% to about 40%.
  • octenyl succinate (OSAN) substituted waxy corn starches of various types such as 1) waxy starch, acid thinned and OSAN substituted, (2) blend of corn syrup solids: waxy starch, OSAN substituted and dextrinized, 3) waxy starch: OSAN substituted and dextrinised, 4) blend of corn syrup solids or maltodextrins with waxy starch: acid thinned OSAN substituted then cooked and spray dried, 5) waxy starch: acid thinned OSAN substituted then cooked and spray dried; and 6) the high and low viscosities of the above modifications (based on the level of acid treatment) can also be used in the present invention. Mixtures of these, particularly mixtures of the high and low viscosity modified starches are also suitable.
  • the modified starches comprise a starch derivative containing a hydrophobic group or both a hydrophobic and a hydrophilic group which has been degraded by at least one enzyme capable of cleaving the 1,4 linkages of the starch molecule from the non-reducing ends to produce short chained saccharides to provide high oxidation resistance while maintaining substantially high molecular weight portions of the starch base.
  • a starch derivative containing a hydrophobic group or both a hydrophobic and a hydrophilic group which has been degraded by at least one enzyme capable of cleaving the 1,4 linkages of the starch molecule from the non-reducing ends to produce short chained saccharides to provide high oxidation resistance while maintaining substantially high molecular weight portions of the starch base.
  • starch- derived materials include, but are not limited to MALTRIN® Ml 00 Maltodextrin, manufactured by Grain Processing Corporation (Muscatine, IA); CAPSULTM, CAPSUL TATM, HI-CAP 100TM, CAPSUL ETM, NARLEXTM (ST and ST2), AND N-LOKTM, manufactured by Akzo Nobel (Bridgewater, NJ); the EmCapTM series including 12633, 12634, 12635, 12639, 12635, and 12671, manufactured by Cargill Inc. (Cedar Rapids, Iowa); and STA-DEX® 90 and MIRA-CAP® Starch, manufactured by Tate & Lyle (Decatur, IL).
  • modified starches suitable for the present invention are disclosed for example in WO 99/55819, WO 01/40430, EP-A-858828, EP-A- 1160311 and U.S. Pat. No. 5,955,419.
  • the aliphatic groups can contain, in addition to carbon and hydrogen atoms, ether linkages, and other groups such as amino groups.
  • the longer chain aliphatic groups e.g., those of about 12 carbons, or higher, can be saturated or unsaturated and can be branched or unbranched.
  • the class of cationic conditioner actives of general formula (I) R 1 and R 2 are each independently selected from C 16 to C 22 hydrocarbyl chains comprising at least one ester linkage in both R 1 and R2 , and R 3 and R 4 are each
  • the class of cationic conditioner actives of general formula (I), R 1 and R 2 are each independently selected from C 16 to C 22 saturated or unsaturated, and R 3 and R 4 are each independently selected from CH 3> CH 2 CH 2 OH, and CH 3 .
  • the class of cationic conditioner actives of general formula (I), R 1 is a C 16 to C 22 alkyl chain and R 2 ,
  • Suitable cationic surfactant conditioner actives can include salts of primary, secondary, and tertiary fatty amines.
  • the alkyl groups of such amines have from about 12 to about 22 carbon atoms, and can be substituted or unsubstituted. These amines are typically used in combination with an acid to provide the cationic species.
  • Suitable materials of general formula (II) are stearamidopropyldimethylamine, stearamidopropyldiethylamine, stearamidoethyldiethylamine,
  • alkyl amine salts can include dimethylstearamine, dimethylsoyamine, soyamine, myristylamine, tridecylamine, ethylstearylamine, N- tallowpropane diamine, ethoxylated (with 5 moles of ethylene oxide) stearylamine, dihydroxyethylstearylamine, and arachidyl behenylamine.
  • the alkyl amine salt is stearamidopropyldimethylamine. Mixtures of any of the foregoing materials may also be suitable.
  • the acid used to provide the cationic conditioner active can be any organic acid or mineral acid of sufficient acid strength to neutralize a free amine nitrogen.
  • Such acids include hydrochloric acid, sulphuric acid, nitric acid, phosphoric acid, lactic acid, citric acid, tartaric acid, acetic acid, gluconic acid, glycolic acid and propionic acid, or combinations thereof.
  • a sufficient amount of acid is added to neutralize the amidoamine compound and to adjust the final pH of the composition to within a range of from about 2.5 to about 6; in another embodiment, from about 3 to about 5.
  • the molar ratio of protonatable amine groups to H + from the acid is from about 1:0.3 to about 1:1.2; and in another embodiment, from about 1:0.5 to about 1:1.1. Mixtures of any of the above-described cationic conditioner actives may also be suitable.
  • the secondary fragrance of the present invention should be substantially different and distinct from the composition of the primary fragrance in order to overcome the effect of fragrance habituation and to make the second fragrance noticeable over the primary fragrance.
  • the secondary fragrance should be substantially the same and indistinct from the composition of the primary fragrance in order to provide a single, continuous, long-lasting fragrance experience.
  • the surface resident coatings comprising the cationic surfactant conditioner and perfume containing matrix microspheres of the present invention may also impart other desirable attributes to the personal care article including, but not limited to, improved visual appearance.
  • the surface resident coatings comprising the cationic surfactant conditioner and high impact perfume containing matrix microspheres of the present invention may provide additional benefits such as imparting anti-stick properties to minimize sticking of the article to the product packaging or to other articles in the case to where they are delivered as a stack of articles.
  • G Specific Surface Area
  • the Specific Surface Area of the personal care article and/or the porous dissolvable solid substrate is measured via a gas adsorption technique.
  • Surface Area is a measure of the exposed surface of a solid sample on the molecular scale.
  • the BET (Brunauer, Emmet, and Teller) theory is the most popular model used to determine the surface area and is based upon gas adsorption isotherms.
  • Gas Adsorption uses physical adsorption and capillary condensation to measure a gas adsorption isotherm. The technique is summarized by the following steps; a sample is placed in a sample tube and is heated under vacuum or flowing gas to remove contamination on the surface of the sample. The sample weight is obtained by subtracting the empty sample tube weight from the degassed sample + sample tube weight.
  • the presence of a surface resident coating comprising a starch-perfume complex of the present invention can be determined by a number of techniques.
  • the surface of application as well as the cross-sections perpendicular to the larger surfaces of the porous dissolvable solid substrate can be examined by microscopic techniques.
  • These microscopic techniques may include light microscopy and scanning electron microscopy (SEM).
  • SEM scanning electron microscopy
  • the light microscopy may include but are not necessarily limited to bright field, dark field, or confocal microscopy techniques.
  • Other techniques for mapping unique elements such as silicon or distinctive functional groups such as quaternary ammonium groups on the cross-sectional surface include: time of flight secondary ion mass spectroscopy (ToF-SIMS), or infrared microscopy.
  • the surface resident coating particles of the present invention generally do not spread uniformly across all exposed solid/air interfaces. Rather, it has been found that the surface resident coatings of the present invention typically spread, from the point of coating application, into cavities down to about 0.5 to about 3.0 mm according to gravity. Accordingly, the determination of surface resident particles of cosmetic actives of the present invention (as described above), should be conducted across many different cross sections from top-to-bottom and from edge-to- edge of the porous solid. If present, the surface resident cosmetic active particle will generally be within the regional vicinity (to within about 0.5 to about 3.0 mm from the surface) of the surface to where the coating was first applied.
  • An expert perfume sensory panel is conducted to quantify the fragrance performance within a normal shampoo protocol regimen with three expert perfumers evaluating the odor character and odor intensity on a 1 to 100 scale (no odor to the most intense odor possible) as described below.
  • a retail liquid shampoo product is included within each panel as a control leg (Herbal Essences Drama Clean Shampoo, Distributed by Procter & Gamble).
  • a target weight of 300 grams of the above composition is prepared with the use of a conventional overhead stirrer (IKA® RW20DZM Stirrer available from IKA® Works, Inc., Wilmington, DE) and a hot plate (Corning Incorporated Life Sciences, Lowell, MA).
  • a conventional overhead stirrer IKA® RW20DZM Stirrer available from IKA® Works, Inc., Wilmington, DE
  • a hot plate Cornning Incorporated Life Sciences, Lowell, MA.
  • the distilled water and glycerin are added with stirring at 100-150 rpm.
  • the cationic polymer when present, is then slowly added with constant stirring until homogenous.
  • the polyvinyl alcohol is weighed into a suitable container and slowly added to the main mixture in small increments using a spatula while continuing to stir while avoiding the formation of visible lumps. The mixing speed is adjusted to minimize foam formation.
  • a porous dissolvable solid substrate (also referred to in the examples herein as “substrate”) was prepared from the above liquid processing mixture as described in Table 2 below.
  • Table 3 summarizes the structural measurements and qualitative physical integrity ratings taken on the porous dissolvable solid substrates of Example 1. SEM and micro-CT images were also taken for the lower density Articles and are referenced in the attached figures. The data was collected by the methods as described herein.
  • Example 1 The above data and referenced images demonstrate the porous dissolvable solid substrate of Example 1 to be predominantly open-celled and to have good physical integrity.
  • the predominantly open-celled porous dissolvable solid substrate also exhibits fast dissolution performance (6 to 8 strokes) within the simulated hand dissolution protocol as described herein.
  • liquid processing composition is prepared at the indicated weight percentages as described below (all percentages are weight percentages) in Table 4.
  • the resulting emulsion is spray dried with a Mini Spray Dryer (Model B-290 available from BUCHI Labortechnik AG, CH-9230 Flawil 1 / Switzerland) with the aspirator set to 100%, the compressed air set at 4 cm, the pump set at 30% and with the inlet temperature operated from 165 to 180 degrees Celsius and the outlet temperature operated from 70 to 80 degrees Celsius.
  • Approximately 30.2 grams of a fine powder was recovered from the product vessel representing a yield of approximately 50.4%.
  • the resulting microspheres have a calculated theoretical solid composition (assuming 0% moisture for calculation purposes only) of approximately 53.33% maltodextrin, 23.33% gum arabic, and 23.33% perfume accord 2a.
  • the resulting emulsion is continuously stirred with a stirring bar and heated to between 40 and 50 degrees Celsius on a stirrer/hot plate while being spray dried with a Mini Spray Dryer (Model B-290 available from BLTCHI Labortechnik AG, CH-9230 Flawil 1 / Switzerland) with the aspirator set to 100%, the compressed air set at 4.2 cm, the pump set from 20 to 25% and with the inlet temperature operated from 170 to 180 degrees Celsius and the outlet temperature operated from 70 to 80 degrees Celsius. Approximately 36.4 grams of a fine powder is recovered from the product vessel representing a yield of approximately 60.6%.
  • the resulting microspheres have a calculated theoretical solid composition (assuming 0% moisture for calculation purposes only) of approximately 40% maltodextrin, 30% behentrimonium chloride, and 30% perfume accord 2a.
  • Example 6 Preparation of matrix microspheres comprising maltodextrin, and perfume accord 2c and additional cationic surfactant conditioner (to compensate for removal of the gum arabic relative to Example 3)
  • a small glass bottle with a pump spray is filled with the primary perfume fragrance oil la and then sprayed onto the surface of the solid from a distance of 2 to 3 inches.
  • the solid is then removed from the easel and returned to the weigh boat on the balance with the top side facing upwards.
  • the weight of perfume applied is recorded and in the instance that the target weight is not achieved, either another spray amount is applied or a Kim wipe to absorb excess perfume away from the substrate. This iterative process is repeated until the target weight range is achieved.
  • the target amount of primary perfume fragrance la applied is 0.06 grams.
  • the resulting substrate resting on the small weigh boat is stored within a zip-lock bag and sealed from the atmosphere.
  • the above process is repeated on subsequent substrates from Example 1 that have been previously coated with aminosilicone. A measured average of approximately 0.062 +/- 0.001 grams of perfume fragrance la is coated across multiple coated substrates.
  • Example 9 Porous dissolvable solid substrates shampoos with a surface coating of aminosilicone, a surface coating of primary fragrance la, and a surface coated powder blend comprising 35% of a calcium silicate complex of a secondary perfume accord 2c and 65% of microspheres comprising a cationic surfactant conditioner and a secondary perfume accord 2c
  • Porous dissolvable solid substrate shampoos with surface resident coatings are prepared according to the identical formulation and procedures as described in Example 8, but with the replacement of the surface coated powder blend comprising 15% of a calcium silicate complex of a secondary perfume accord 2c and 85% of microspheres comprising a cationic surfactant conditioner and a secondary perfume accord 2c with a surface coating of a powder blend comprising 50% of a calcium silicate complex of a secondary perfume accord 2c and 50% of microspheres comprising a cationic surfactant conditioner and a secondary perfume accord 2c. Measured averages of approximately 0.064 +/- 0.001 grams of primary fragrance la and 0.119 +/- 0.008 grams of the powder blend are coated onto the substrates.
  • Example 11 Porous dissolvable solid substrate shampoos with a surface coating of aminosilicone, a surface coating of primary fragrance la, and surface coated microspheres comprising a cationic surfactant conditioner and a secondary perfume accord 2b
  • Example 11 Porous dissolvable solid Cosmetic 80 80 65 55 20 5 20 substrate shampoo with a surface floral Greene
  • Example 12 Porous dissolvable solid Green 80/85 80 65 60 20 15 15/20 substrate shampoo with a surface cosmetic Green Green,

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention porte sur des compositions de soins personnels, et, en particulier, sur des compositions de soins personnels sous la forme d'un article de soins personnels qui est un substrat solide poreux pouvant être dissous. Le substrat solide poreux pouvant être dissous comporte un revêtement résidant en surface comprenant un revêtement résidant en surface comprenant d'environ 25 % à environ 70 % d'un matériau dérivé de l'amidon, d'environ 5 % à environ 60 % d'un agent de conditionnement tensioactif cationique, et d'environ 5 % à environ 60 % d'un parfum, qui peut produire un avantage pour le consommateur.
PCT/US2010/059455 2009-12-08 2010-12-08 Substrat solide poreux pouvant être dissous et revêtement résidant en surface comprenant des microsphères de matrice Ceased WO2011072009A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR112012013838A BR112012013838A2 (pt) 2009-12-08 2010-12-08 substrato sólido poroso dissolúvel e revestimento residente na superfície que compreende microesferas de matriz
JP2012542246A JP5639659B2 (ja) 2009-12-08 2010-12-08 多孔質溶解性固体基材と、マトリックスミクロスフェアを含む表面残留コーティング
MX2012006550A MX339322B (es) 2009-12-08 2010-12-08 Un sustrato solido, soluble y poroso y recubrimiento fijo de superficie que comprende microesferas de matriz.
EP10796222.7A EP2509564B1 (fr) 2009-12-08 2010-12-08 Substrat solide poreux pouvant être dissous et revêtement résidant en surface comprenant des microsphères de matrice
CN2010800556722A CN102647972B (zh) 2009-12-08 2010-12-08 可溶性多孔固体基质和包含基质微球体的表面驻留涂层

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US26768809P 2009-12-08 2009-12-08
US61/267,688 2009-12-08

Publications (1)

Publication Number Publication Date
WO2011072009A1 true WO2011072009A1 (fr) 2011-06-16

Family

ID=43827682

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/059455 Ceased WO2011072009A1 (fr) 2009-12-08 2010-12-08 Substrat solide poreux pouvant être dissous et revêtement résidant en surface comprenant des microsphères de matrice

Country Status (7)

Country Link
US (1) US9295859B2 (fr)
EP (1) EP2509564B1 (fr)
JP (1) JP5639659B2 (fr)
CN (1) CN102647972B (fr)
BR (1) BR112012013838A2 (fr)
MX (1) MX339322B (fr)
WO (1) WO2011072009A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015171531A1 (fr) * 2014-05-05 2015-11-12 The Procter & Gamble Company Produits de consommation
WO2015171532A1 (fr) * 2014-05-05 2015-11-12 The Procter & Gamble Company Produits de consommation
WO2015171536A1 (fr) * 2014-05-05 2015-11-12 The Procter & Gamble Company Produits de consommation
US9622956B2 (en) 2011-12-21 2017-04-18 Colgate-Palmolive Company Oral care compositions
GB2589402A (en) * 2019-07-10 2021-06-02 Henkel Kgaa Solid hair conditioning agent consisting of a least two components
WO2022055373A1 (fr) * 2020-09-11 2022-03-17 Ethique Limited Concentré solide d'une composition de soins personnels/ménagère destiné à être reconstitué avec de l'eau

Families Citing this family (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8765170B2 (en) 2008-01-30 2014-07-01 The Procter & Gamble Company Personal care composition in the form of an article
CA2721640C (fr) 2008-04-16 2014-12-09 The Procter & Gamble Company Composition non moussante de soins personnels sous forme d'article
US8461091B2 (en) 2008-12-08 2013-06-11 The Procter & Gamble Company Personal care composition in the form of an article having a porous, dissolvable solid structure
BRPI0922185A2 (pt) * 2008-12-08 2018-06-05 The Procter & Gamble um substrato sólido poroso dissoluvel e complexos de particulados inorganicos de perfume residentes de superficie.
US8466099B2 (en) * 2008-12-08 2013-06-18 The Procter & Gamble Company Process of making an article for dissolution upon use to deliver surfactants
JP5718246B2 (ja) * 2008-12-08 2015-05-13 ザ プロクター アンド ギャンブルカンパニー 多孔質溶解性固体構造を有する物品形態のパーソナルケア組成物
WO2011071969A1 (fr) * 2009-12-08 2011-06-16 The Procter & Gamble Company Substrat solide, poreux et soluble et revitalisant capillaire à base d'un tensioactif cationique
WO2011071964A1 (fr) 2009-12-08 2011-06-16 The Procter & Gamble Company Substrat solide, poreux et soluble et revêtement destiné à gainer le cheveu constitué d'un revitalisant capillaire à base d'un tensioactif cationique
EP2509564B1 (fr) 2009-12-08 2013-11-20 The Procter and Gamble Company Substrat solide poreux pouvant être dissous et revêtement résidant en surface comprenant des microsphères de matrice
EP2536386A1 (fr) 2010-02-16 2012-12-26 The Procter & Gamble Company Substrat solide soluble poreux et revêtement de surface comprenant du pyrithione de zinc
US20180163325A1 (en) 2016-12-09 2018-06-14 Robert Wayne Glenn, Jr. Dissolvable fibrous web structure article comprising active agents
CA2803382C (fr) * 2010-07-02 2015-03-31 The Procter & Gamble Company Procede de diffusion d'un agent actif
EP2588589B2 (fr) 2010-07-02 2023-07-19 The Procter & Gamble Company Procédé de fabrication d'un produit détergent
WO2012003319A2 (fr) 2010-07-02 2012-01-05 The Procter & Gamble Company Filaments comprenant des bandes non tissées avec agent actif et procédés de fabrication associés
BR122019015741B1 (pt) 2010-07-02 2021-12-21 The Procter & Gamble Company Artigo de estrutura de manta fibrosa dissolvível que compreende agentes ativos
AU2012229476B2 (en) 2011-03-01 2016-02-25 The Procter & Gamble Company Porous disintegratable solid substrate for personal health care applications
MX336048B (es) 2011-05-27 2016-01-07 Procter & Gamble Articulo colorante solido soluble para el pelo.
MX336047B (es) 2011-05-27 2016-01-07 Procter & Gamble Articulo colorante solido soluble para el pelo.
US9180083B2 (en) 2012-02-08 2015-11-10 Elc Management Llc Personal care compositions containing volumizing, fixative, and conditioning particles for fine hair
US9427390B2 (en) 2012-02-08 2016-08-30 Elc Management Llc Method for forming volumizing, fixative, and conditioning particles for fine hair
ES2647083T3 (es) * 2012-02-08 2017-12-19 Elc Management Llc Composiciones para cuidado personal que contienen partículas voluminizadoras, fijadoras y acondicionadoras para cabello fino
KR20140127853A (ko) * 2012-02-08 2014-11-04 이엘씨 매니지먼트 엘엘씨 가는 모발용 볼륨화, 고정화 및 컨디셔닝 입자를 형성하는 방법
US8444716B1 (en) 2012-05-23 2013-05-21 The Procter & Gamble Company Soluble solid hair coloring article
EP2906189B1 (fr) 2012-10-12 2019-06-12 The Procter and Gamble Company Composition de soin personnel sous forme d'un article soluble
CN105025873A (zh) * 2013-03-15 2015-11-04 宝洁公司 形成个人护理制品的方法
WO2014152081A1 (fr) * 2013-03-15 2014-09-25 The Procter & Gamble Company Procédé de formation d'un article de soin personnel
US20150315350A1 (en) 2014-04-22 2015-11-05 The Procter & Gamble Company Compositions in the Form of Dissolvable Solid Structures
US9861559B2 (en) * 2014-05-05 2018-01-09 The Procter & Gamble Company Consumer product comprising a porous, dissolvable, fibrous web solid structure with a silicone coating
US9861558B2 (en) * 2014-05-05 2018-01-09 The Procter & Gamble Company Methods of forming an aqueous treatment liquor by dissolving a porous solid with a benefit agent coating
US9827173B2 (en) 2014-05-05 2017-11-28 The Procter & Gamble Company Porous dissolvable solid structure with two benefit agents and methods of forming an aqueous treatment liquor therefrom
US20150313805A1 (en) * 2014-05-05 2015-11-05 The Procter & Gamble Company Consumer Products
JP6651503B2 (ja) 2014-05-08 2020-02-19 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ パッケージの群
EP3139885B1 (fr) 2014-05-08 2021-01-06 The Procter & Gamble Company Gammes de silhouettes d'articles absorbants pour adulte définies selon le rapport entre la hanche et la taille
EP3848011A1 (fr) 2014-05-08 2021-07-14 The Procter & Gamble Company Formes allant de la taille jusqu'au côté d'articles absorbants jetables pour adultes et ensembles associés
US10864117B2 (en) 2014-10-09 2020-12-15 The Procter & Gamble Company Length-to-waist and hip-to-side silhouettes of adult disposable absorbent articles and arrays
WO2016102527A1 (fr) * 2014-12-22 2016-06-30 Rhodia Operations Composition solide comprenant un composé d'ammonium quaternaire et un polysaccharide, son procédé et son utilisation
WO2017079576A1 (fr) 2015-11-06 2017-05-11 The Procter & Gamble Company Silhouettes d'articles absorbants et séries de silhouettes
MX380727B (es) 2017-01-27 2025-03-12 Procter & Gamble Composiciones en la forma de estructuras sólidas solubles que comprenden partículas aglomeradas efervescentes.
CN110191700A (zh) 2017-01-27 2019-08-30 宝洁公司 可溶性固体结构形式的组合物
JP6923673B2 (ja) 2017-05-16 2021-08-25 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ 溶解性固形構造体の形態のコンディショニングヘアケア組成物
USD861980S1 (en) 2017-06-22 2019-10-01 The Procter & Gamble Company Oval dentifrice patch
USD861981S1 (en) 2017-06-22 2019-10-01 The Procter & Gamble Company Oval dentifrice patch
JP2020524034A (ja) 2017-06-30 2020-08-13 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ ボクサーブリーフ型使い捨て吸収性物品及び群の臀部対側部シルエット
JP1639110S (fr) 2018-07-16 2019-08-13
US11666514B2 (en) 2018-09-21 2023-06-06 The Procter & Gamble Company Fibrous structures containing polymer matrix particles with perfume ingredients
US11850293B2 (en) 2018-09-21 2023-12-26 The Procter & Gamble Company Active agent-containing matrix particles and processes for making same
CN114206307B (zh) 2019-06-28 2024-08-23 宝洁公司 包含阴离子表面活性剂的可溶性固体纤维制品
WO2021003492A1 (fr) 2019-07-03 2021-01-07 The Procter & Gamble Company Structures fibreuses contenant des tensioactifs cationiques et des acides solubles
US11485934B2 (en) * 2019-08-02 2022-11-01 The Procter & Gamble Company Foaming compositions for producing a stable foam and methods for making same
USD939359S1 (en) 2019-10-01 2021-12-28 The Procter And Gamble Plaza Packaging for a single dose personal care product
US11597191B2 (en) 2019-10-14 2023-03-07 The Procter & Gamble Company Biodegradable and/or home compostable sachet containing a solid article
CA3157576A1 (fr) 2019-11-20 2021-05-27 The Procter & Gamble Company Structure solide poreuse soluble
JP7617104B2 (ja) 2019-12-01 2025-01-17 ザ プロクター アンド ギャンブル カンパニー 安息香酸ナトリウム、並びにグリコール及び／又はグリセリルエステルを含有する防腐剤系を有する、ヘアコンディショナー組成物
US12104141B2 (en) * 2019-12-23 2024-10-01 Vitiprints, LLC Printable surfactant composite
WO2021174188A1 (fr) * 2020-02-27 2021-09-02 Henkel IP & Holding GmbH Produit de soins personnels et procédé de fabrication d'un produit de soins personnels par procédé additif
USD941051S1 (en) 2020-03-20 2022-01-18 The Procter And Gamble Company Shower hanger
USD962050S1 (en) 2020-03-20 2022-08-30 The Procter And Gamble Company Primary package for a solid, single dose beauty care composition
BR112022021833A2 (pt) * 2020-04-29 2023-01-17 Stepan Co Composições sólidas contendo amina, amina protonada ou compostos de amônio quaternário
USD965440S1 (en) 2020-06-29 2022-10-04 The Procter And Gamble Company Package
WO2022027067A1 (fr) 2020-07-31 2022-02-03 The Procter & Gamble Company Sachet fibreux soluble dans l'eau contenant des granules pour soins capillaires
WO2022036352A1 (fr) 2020-08-11 2022-02-17 The Procter & Gamble Company Compositions d'après-shampooing à rinçage propre contenant de l'ésylate de valinate de brassicyle (bve)
MX2023001045A (es) 2020-08-11 2023-02-16 Procter & Gamble Composiciones acondicionadoras humectantes para el cabello que contienen esilato de valinato de brassicilo.
CN116456957A (zh) 2020-08-11 2023-07-18 宝洁公司 含有芸苔油醇缬氨酸酯乙磺酸盐的低粘度毛发调理剂组合物
JP7614333B2 (ja) 2020-09-10 2025-01-15 ザ プロクター アンド ギャンブル カンパニー 抗細菌活性物質を含有する溶解性固体物品
EP4255384A1 (fr) 2020-12-01 2023-10-11 The Procter & Gamble Company Compositions aqueuses de conditionneur capillaire contenant des agents actifs antipelliculaires solubilisés
CN112494358B (zh) * 2020-12-08 2022-01-11 江南大学 一种以淀粉为填充剂的粉底液及其制备方法
USD1045064S1 (en) 2020-12-17 2024-10-01 The Procter & Gamble Company Single-dose dissolvable personal care unit
CN116761578A (zh) 2021-01-21 2023-09-15 宝洁公司 含有防腐剂的可溶性固体制品
JP2024529019A (ja) 2021-08-20 2024-08-01 ザ プロクター アンド ギャンブル カンパニー シリコーンを含有する溶解性固体物品
WO2023034763A1 (fr) 2021-08-30 2023-03-09 The Procter & Gamble Company Structure solide soluble comprenant des premier et second agents structurants polymères
DE102022202834A1 (de) * 2022-03-23 2023-09-28 Henkel Ag & Co. Kgaa Pulverzusammensetzung für die kosmetische Reinigung der Haut oder der Haare
FR3134718A1 (fr) * 2022-04-26 2023-10-27 Capsum Composition cosmétique parfumante solide comprenant au moins une cavité
FR3134714A1 (fr) * 2022-04-26 2023-10-27 Capsum Composition cosmétique solide comprenant au moins une cavité
FR3134717A1 (fr) * 2022-04-26 2023-10-27 Capsum Composition cosmétique solide de soin comprenant au moins une cavité
FR3137107A1 (fr) * 2022-06-28 2023-12-29 Capsum Composition de nettoyage solide comprenant au moins une cavité
FR3136963B1 (fr) * 2022-06-28 2025-06-06 Capsum Composition cosmétique solide de soin capillaire comprenant au moins une cavité

Citations (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2396278A (en) 1933-11-15 1946-03-12 Procter & Gamble Detergent composition
US2486922A (en) 1945-11-09 1949-11-01 Procter & Gamble Stabilized detergent composition
US2486921A (en) 1944-10-16 1949-11-01 Procter & Gamble Detergent composition
US3929678A (en) 1974-08-01 1975-12-30 Procter & Gamble Detergent composition having enhanced particulate soil removal performance
EP0397410A2 (fr) 1989-05-10 1990-11-14 Ciba Specialty Chemicals Water Treatments Limited Produits absorbants et leur préparation
US5104646A (en) 1989-08-07 1992-04-14 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
US5106609A (en) 1990-05-01 1992-04-21 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
EP0283165B1 (fr) 1987-03-06 1992-10-28 The Procter & Gamble Company Composition et méthode pour le soin de la peau
US5582786A (en) 1992-08-19 1996-12-10 Courtaulds Fibres Limited Method of producing fibre or film
EP0858828A1 (fr) 1997-02-12 1998-08-19 LEWA Herbert Ott GmbH + Co. Procédé et dispositif pour la distribution par pulvérisation avec ultrasons
EP0922449A2 (fr) 1997-10-31 1999-06-16 National Starch and Chemical Investment Holding Corporation Utilisation d'un dérivé d'amidon traité par enzymes en tant qu'agent d'encapsulage
US5955419A (en) 1995-09-18 1999-09-21 The Procter & Gamble Company High efficiency delivery system comprising zeolites
WO1999055819A1 (fr) 1998-04-23 1999-11-04 The Procter & Gamble Company Particules de parfum en inclusion et compositions detergentes contenant ces particules
US6106849A (en) * 1998-01-21 2000-08-22 Dragoco Gerberding & Co. Ag Water soluble dry foam personal care product
WO2001040430A1 (fr) 1999-12-03 2001-06-07 The Procter & Gamble Company Systeme de liberation dote d'un support poreux encapsule charge d'additifs, notamment d'additifs detergents tels que des parfums
EP1160311A2 (fr) 1995-09-18 2001-12-05 The Procter & Gamble Company Système de diffusion de parfum
WO2003037294A2 (fr) * 2001-11-01 2003-05-08 The Procter & Gamble Company Compositions de soins personnels contenant une mousse polymere se desagregeant en presence d'eau
EP1317916A2 (fr) * 2001-11-16 2003-06-11 National Starch and Chemical Investment Holding Corporation Des films comprenant de l'amidon modifié
WO2003088933A1 (fr) * 2002-04-15 2003-10-30 Salvona, L.L.C. Systemes a liberation declenchee par l'humidite renfermant des ingredients d'aromes provoquant un eclatement de parfum en reponse a l'humidite
US20030215522A1 (en) 2002-04-22 2003-11-20 The Procter & Gamble Company Personal care compositions comprising a zinc containing material in an aqueous surfactant composition
US20030232183A1 (en) * 2000-09-13 2003-12-18 The Procter & Gamble Company Process for making a foam component
WO2004032859A2 (fr) * 2002-10-09 2004-04-22 The Dial Corporation Composition en feuille hydrosoluble
WO2004041991A1 (fr) * 2002-11-01 2004-05-21 Salvona Llc Systeme de liberation controlee d'un multicomposant pour pains de savon
US12076508B2 (en) 2018-10-22 2024-09-03 Hi-Lex Corporation Fixing device
US12078608B2 (en) 2021-11-02 2024-09-03 Acer Incorporated Power supply device with protection function when water ingress occurs
US12079008B2 (en) 2017-09-25 2024-09-03 State Farm Mutual Automobile Insurance Company Dynamic autonomous vehicle train

Family Cites Families (188)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2356168A (en) 1941-08-16 1944-08-22 Clarence W Mabley Soap leaf
US2438091A (en) 1943-09-06 1948-03-16 American Cyanamid Co Aspartic acid esters and their preparation
US2528378A (en) 1947-09-20 1950-10-31 John J Mccabe Jr Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same
US2658072A (en) 1951-05-17 1953-11-03 Monsanto Chemicals Process of preparing amine sulfonates and products obtained thereof
US2694668A (en) 1952-03-10 1954-11-16 Abbott Lab Liquid multiple vitamin preparation and process of preparing the same
US2809971A (en) 1955-11-22 1957-10-15 Olin Mathieson Heavy-metal derivatives of 1-hydroxy-2-pyridinethiones and method of preparing same
US3152046A (en) 1956-11-09 1964-10-06 Kapral Ales Maria Selenium disulfide dispersions
NL251355A (fr) 1959-05-23
US3236733A (en) 1963-09-05 1966-02-22 Vanderbilt Co R T Method of combatting dandruff with pyridinethiones metal salts detergent compositions
DE1195013B (de) 1963-09-24 1965-06-16 Spitzner Arzneimittelfabrik G Verfahren zur Herstellung von geformten, festen Badezusaetzen
US3332880A (en) 1965-01-04 1967-07-25 Procter & Gamble Detergent composition
US3426440A (en) 1966-06-24 1969-02-11 Monsanto Co Detergent fluidized drying process
US3761418A (en) 1967-09-27 1973-09-25 Procter & Gamble Detergent compositions containing particle deposition enhancing agents
US3653383A (en) 1969-07-30 1972-04-04 Freeze Dry Products Algin sponge and process therefor
US3695989A (en) 1970-08-12 1972-10-03 Robert E Albert Cold water soluble foam plastic package
US3753196A (en) 1971-10-05 1973-08-14 Kulite Semiconductor Products Transducers employing integral protective coatings and supports
CH575453A5 (fr) 1972-08-01 1976-05-14 Ciba Geigy Ag
US4051081A (en) 1973-03-14 1977-09-27 Bayer Aktiengesellschaft Process for making hydrophilic polyurethane foams
US4217914A (en) 1974-05-16 1980-08-19 L'oreal Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin
US4422853A (en) 1974-05-16 1983-12-27 L'oreal Hair dyeing compositions containing quaternized polymer
US4089945A (en) 1975-06-30 1978-05-16 The Procter & Gamble Company Antidandruff shampoos containing metallic cation complex to reduce in-use sulfide odor
US4197865A (en) 1975-07-04 1980-04-15 L'oreal Treating hair with quaternized polymers
AT365448B (de) 1975-07-04 1982-01-11 Oreal Kosmetische zubereitung
US4020156A (en) 1976-02-13 1977-04-26 Norda Incorporated Controlled fragrance releasing crystal beads
US4196190A (en) 1976-07-19 1980-04-01 Rohm And Haas Company Acrylic hair setting resins having high resistance to moisture and rapid removability from the hair with shampoo
US4149551A (en) 1977-03-28 1979-04-17 The Procter & Gamble Company Method of conditioning hair using a flexible substrate
US4206196A (en) 1978-06-06 1980-06-03 The Procter & Gamble Company Hair conditioning article and a method of its use
US4272511A (en) 1978-06-23 1981-06-09 L'oreal Cosmetic compositions for treating hair
US4663158A (en) 1979-07-02 1987-05-05 Clairol Incorporated Hair conditioning composition containing cationic polymer and amphoteric surfactant and method for use
US4507280A (en) 1979-07-02 1985-03-26 Clairol Incorporated Hair conditioning composition and method for use
US4323683A (en) 1980-02-07 1982-04-06 The Procter & Gamble Company Process for making pyridinethione salts
US4379753A (en) 1980-02-07 1983-04-12 The Procter & Gamble Company Hair care compositions
US4345080A (en) 1980-02-07 1982-08-17 The Procter & Gamble Company Pyridinethione salts and hair care compositions
US4529586A (en) 1980-07-11 1985-07-16 Clairol Incorporated Hair conditioning composition and process
US4470982A (en) 1980-12-22 1984-09-11 The Procter & Gamble Company Shampoo compositions
JPS5821608A (ja) 1981-07-31 1983-02-08 Kenji Nakamura パツク化粧シ−ト及びその製造方法
LU83949A1 (fr) 1982-02-16 1983-09-02 Oreal Composition destinee au traitement des matieres keratiniques contenant au moins un polymere cationique et au moins un latex anionique
US4565647B1 (en) 1982-04-26 1994-04-05 Procter & Gamble Foaming surfactant compositions
JPS58216109A (ja) 1982-06-10 1983-12-15 Pola Chem Ind Inc 乾燥性膜状化粧料及び積層膜状化粧料
USRE34584E (en) 1984-11-09 1994-04-12 The Procter & Gamble Company Shampoo compositions
US5094853A (en) 1985-04-26 1992-03-10 S. C. Johnson & Son, Inc. Method of preparing a water-soluble stable arthropodicidally-active foam matrix
JPH0653657B2 (ja) 1985-09-26 1994-07-20 サンスタ−株式会社 浴用剤
JPH0796493B2 (ja) 1985-09-26 1995-10-18 サンスタ−株式会社 浴用剤
JPS6281432A (ja) 1985-10-04 1987-04-14 Shiseido Co Ltd 水溶性高分子成形物
US5280079A (en) 1986-11-20 1994-01-18 Allied Colloids Limited Absorbent products and their manufacture
US4822613A (en) 1986-12-15 1989-04-18 S. C. Johnson & Son, Inc. Water-soluble foamable insecticidally-active compositions
US4885107A (en) 1987-05-08 1989-12-05 The Procter & Gamble Company Shampoo compositions
GB8806016D0 (en) 1988-03-14 1988-04-13 Danochemo As Encapsulated photoactivator dyes for detergent use
US5061481A (en) 1989-03-20 1991-10-29 Kobayashi Kose Co., Ltd. Cosmetic composition having acryl-silicone graft copolymer
US5055384A (en) 1989-05-10 1991-10-08 Agfa Gevaert Aktiengesellschaft Granulated photographic fixative and its preparation
US5166276A (en) 1989-07-12 1992-11-24 Mitsubishi Petrochemical Company Ltd. Polymer for hair-care products
DE3923144A1 (de) 1989-07-13 1991-01-24 Wolff Walsrode Ag Verfahren zur herstellung von hydrokolloidmischungen mit verbesserter dispergierbarkeit
FR2650180B1 (fr) 1989-07-31 1995-03-03 Chisso Corp Procede de production d'une feuille facilement soluble dans l'eau a base d'acide hyaluronique ou de hyaluronate et feuille ainsi obtenue
US5100658A (en) 1989-08-07 1992-03-31 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
CA2013485C (fr) 1990-03-06 1997-04-22 John Michael Gardlik Produit solide contenant de petites particules de complexes de cyclodextrine
US5100657A (en) 1990-05-01 1992-03-31 The Procter & Gamble Company Clean conditioning compositions for hair
US5220033A (en) 1990-06-13 1993-06-15 Shin-Etsu Chemical Co., Ltd. Siloxane compounds and their preparation
JPH0753349B2 (ja) 1991-05-17 1995-06-07 アサダ株式会社 継管のカシメ検査方法及び検査工具
US5261426A (en) 1991-05-30 1993-11-16 Creative Products Resource Associates, Ltd. Hydrophilic foam pad for hair styling
DE69409683T2 (de) 1993-02-02 1998-09-17 Tokai Pulp Kk Wärmeempfindlich klebendes, wasserlösliches oder wasserdispergierbares Papier, und Verfahren zu seiner Herstellung
US5429628A (en) 1993-03-31 1995-07-04 The Procter & Gamble Company Articles containing small particle size cyclodextrin for odor control
US5409703A (en) 1993-06-24 1995-04-25 Carrington Laboratories, Inc. Dried hydrogel from hydrophilic-hygroscopic polymer
US5391368A (en) 1993-08-09 1995-02-21 Revlon Consumer Products Corporation Hair styling shampoos
JP3357453B2 (ja) 1993-09-10 2002-12-16 花王株式会社 液体柔軟仕上剤組成物並びに新規第４級アンモニウム塩並びに該塩の製造法
US5457895A (en) 1993-10-01 1995-10-17 R. P. Scherer Corporation Method of identifying freeze-dried dosage forms
AU5616094A (en) 1993-11-22 1995-06-13 Chemia Corporation Air freshener and moth and insect repellant products
CN1138091A (zh) 1995-06-14 1996-12-18 曹德胜 一次性肥皂纸及制造方法
EP0750905B1 (fr) 1995-06-27 2003-01-02 Kao Corporation Pansement comprenant une feuille adhésive soluble dans l'eau
US5750122A (en) 1996-01-16 1998-05-12 The Procter & Gamble Company Compositions for treating hair or skin
US5674478A (en) 1996-01-12 1997-10-07 The Procter & Gamble Company Hair conditioning compositions
US6365142B1 (en) 1996-02-28 2002-04-02 The Procter & Gamble Company Hair conditioning compositions which provide superior wet hair feel attributes and which are substantially free of quaternary ammonium compounds
DE19607851A1 (de) 1996-03-01 1997-09-04 Bayer Ag Polyfunktionelle Reaktivfarbstoffe
US5672576A (en) 1996-03-15 1997-09-30 The Procter & Gamble Co. High lather styling shampoos
US5976454A (en) 1996-04-01 1999-11-02 Basf Aktiengesellschaft Process for producing open-celled, inorganic sintered foam products
JP3103839B2 (ja) 1997-03-14 2000-10-30 トスコ株式会社 吸水性ポリウレタンフォーム及びその製造方法
US6010719A (en) 1997-09-16 2000-01-04 Universiteit Gent Freeze-dried disintegrating tablets
CN1088356C (zh) 1997-12-11 2002-07-31 华健医药科技股份有限公司 拔粉刺贴片
DE19803362A1 (de) 1998-01-29 1999-08-05 Sartorius Gmbh Geschäumte poröse Membranen aus thermoplastischen Polymeren sowie Verfahren und Vorrichtung zu ihrer Herstellung
CN1268558A (zh) 1999-03-24 2000-10-04 尹小林 多功能一次性洗洁膜
US6329353B1 (en) 1999-05-12 2001-12-11 Goldschmidt Chemical Corporation Clear personal care formulations containing quaternary ammonium compounds and other nitrogen-containing compounds
US6177391B1 (en) 1999-05-27 2001-01-23 Alam Zafar One time use disposable soap and method of making
DE19944416A1 (de) 1999-09-16 2001-03-22 Henkel Kgaa Klarspülmittel
GB2355008A (en) 1999-10-05 2001-04-11 Procter & Gamble Foam matrix coating material
CA2385213A1 (fr) 1999-10-05 2001-04-12 Didier Marcel Corrand Produit elastique
DE19947684A1 (de) 1999-10-05 2001-04-12 Henkel Kgaa Filmbildendes Hautreinigungsmittel
AU7752400A (en) 1999-10-05 2001-05-10 Procter & Gamble Company, The Water unstable foam
US6943200B1 (en) 1999-10-05 2005-09-13 Procter & Gamble Company Water unstable foam compositions
US6790814B1 (en) 1999-12-03 2004-09-14 Procter & Gamble Company Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes
US6200949B1 (en) 1999-12-21 2001-03-13 International Flavors And Fragrances Inc. Process for forming solid phase controllably releasable fragrance-containing consumable articles
PL356924A1 (en) 2000-01-28 2004-07-12 Smithkline Beecham Corporation Electrospun pharmaceutical compositions
US6835678B2 (en) 2000-05-04 2004-12-28 Kimberly-Clark Worldwide, Inc. Ion sensitive, water-dispersible fabrics, a method of making same and items using same
ATE366299T1 (de) 2000-05-17 2007-07-15 Henkel Kgaa Wasch- oder reinigungsmittelformkörper
KR20020003442A (ko) 2000-07-03 2002-01-12 김대원 세정용 시트 조성물
GB2365018A (en) 2000-07-24 2002-02-13 Procter & Gamble Water soluble pouches
GB2366797A (en) 2000-09-13 2002-03-20 Procter & Gamble Process for making foam component by pressurising/depressurising
US6503521B1 (en) 2000-11-22 2003-01-07 L'ORéAL S.A. Fiber-containing base composition for use with mascara
JP2002179509A (ja) 2000-12-12 2002-06-26 Takasago Internatl Corp 抗カビ香料組成物
US6959346B2 (en) * 2000-12-22 2005-10-25 Mosaid Technologies, Inc. Method and system for packet encryption
CA2433169A1 (fr) 2000-12-26 2002-07-04 Takeda Chemical Industries, Ltd. Substances poreuses et son procede de fabrication
US20020098994A1 (en) 2001-01-22 2002-07-25 Alam Zafar One time use disposable paper soap and method of making
US6365152B1 (en) * 2001-03-15 2002-04-02 Bovine Health Products, Inc. Scours treatment and method of making same
US20020187181A1 (en) 2001-05-14 2002-12-12 3M Innovative Properties Company System for delivering cosmetics and pharmaceuticals
BRPI0211039B1 (pt) 2001-06-22 2015-07-14 Unilever Nv Composição condicionadora sólida para os cabelos e uso de uma composição condicionadora sólida para os cabelos
US20030032573A1 (en) 2001-07-11 2003-02-13 Tanner Paul Robert Cleansing compositions containing chelating surfactants
DE10140597A1 (de) 2001-08-18 2003-03-06 Kuraray Specialities Europe Teilvernetzter Polyvinylalkohol
US20030045441A1 (en) 2001-08-28 2003-03-06 Unilever Home And Personal Care, Usa, Division Of Conopco, Inc. Water-soluble package with hydrophobic capsules in the film
US20030069154A1 (en) 2001-08-28 2003-04-10 Unilever Home And Personal Care, Usa, Division Of Conopco, Inc. Water-soluble package containing a fluid composition with a visually discrete capsule or emulsion or dispersion layer
JP2003073700A (ja) 2001-09-04 2003-03-12 Komecho:Kk 紙石鹸
JP2003082397A (ja) 2001-09-11 2003-03-19 Komecho:Kk 紙石鹸
GB0122665D0 (en) 2001-09-20 2001-11-14 Cussons Int Ltd Dispenser for personal care composition
US7025813B2 (en) 2001-10-25 2006-04-11 Agfa-Gevaert Ink composition containing a particular type of dye, and corresponding ink-jet printing process
US20030209166A1 (en) 2001-10-25 2003-11-13 Luc Vanmaele Ink composition containing a particular type of dye, and corresponding ink jet printing process
US20030186826A1 (en) 2001-11-01 2003-10-02 The Procter & Gamble Company Method of using personal care compositions containing a high density, water disintegratable, polymeric foam
US20030099691A1 (en) 2001-11-16 2003-05-29 Susan Lydzinski Films containing starch
CN1357613A (zh) 2001-11-22 2002-07-10 成都洁利康实业发展有限公司 全融型纸香皂及其制备方法
AU2003209479A1 (en) * 2002-03-11 2003-09-29 First Water Limited Absorbent hydrogels
US20040175404A1 (en) 2002-04-15 2004-09-09 Adi Shefer Moisture triggered sealed release system
US20030199412A1 (en) 2002-04-17 2003-10-23 Gargi Gupta Fragrance containing cleaning product
US6740631B2 (en) * 2002-04-26 2004-05-25 Adi Shefer Multi component controlled delivery system for fabric care products
US7208460B2 (en) 2002-04-26 2007-04-24 Salvona Ip, Llc Multi component controlled delivery system for soap bars
JP4151885B2 (ja) 2002-07-12 2008-09-17 旭化成ケミカルズ株式会社 水分散性セルロースおよびその製造方法
TW200410714A (en) 2002-08-07 2004-07-01 Smithkline Beecham Corp Electrospun amorphous pharmaceutical compositions
US20040029762A1 (en) 2002-08-09 2004-02-12 Charles Hensley Dry, solid, thin, non-elastic, frangible surfactant sheet
US20040032859A1 (en) 2002-08-15 2004-02-19 Miao Kai X. Managing a remote resource
US7960326B2 (en) 2002-09-05 2011-06-14 Kimberly-Clark Worldwide, Inc. Extruded cleansing product
DE10241597B4 (de) 2002-09-07 2004-09-16 Scs Skin Care Systems Gmbh Seifenzubereitung mit Luftblasen
US20040071742A1 (en) 2002-10-10 2004-04-15 Popplewell Lewis Michael Encapsulated fragrance chemicals
GB0228584D0 (en) 2002-12-07 2003-01-15 Unilever Plc Detergent compositions
US20040108615A1 (en) 2002-12-09 2004-06-10 Foley Daphne Gayle Durable water-dispersible foam
US8877316B2 (en) 2002-12-20 2014-11-04 The Procter & Gamble Company Cloth-like personal care articles
US20040126585A1 (en) 2002-12-27 2004-07-01 Kerins John E. Water dispersible commode/bedpan liner
US6846784B2 (en) 2003-01-30 2005-01-25 Access Business Group International Llc Water soluble pouch package
CN1261558C (zh) 2003-03-13 2006-06-28 鲁人康 肥皂纸
US20040202632A1 (en) 2003-04-10 2004-10-14 Unilever Home & Personal Care Usa, Division Of Conocpo, Inc. Fragranced solid cosmetic compositions based on a starch delivery system
JP4013200B2 (ja) 2003-05-21 2007-11-28 味の素株式会社 シート状パック化粧料およびその製造方法
WO2005003423A1 (fr) 2003-07-03 2005-01-13 L'oreal Article cosmetique apte au mouillage et a la desintegration
DE10331767A1 (de) 2003-07-11 2005-02-10 Kuraray Specialities Europe Gmbh Verfahren zur Herstellung von Formkörpern
DK1663326T3 (da) 2003-09-08 2010-06-21 Fmc Biopolymer As Gel-skum baseret på biopolymer
US7285520B2 (en) 2003-12-01 2007-10-23 Kimberly-Clark Worldwide, Inc. Water disintegratable cleansing wipes
JP2005171063A (ja) 2003-12-10 2005-06-30 Inoac Corp 樹脂複合体
US7378360B2 (en) 2003-12-17 2008-05-27 Kimberly-Clark Worldwide, Inc. Water dispersible, pre-saturated wiping products
US7846462B2 (en) 2003-12-22 2010-12-07 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Personal care implement containing a stable reactive skin care and cleansing composition
GB0401950D0 (en) 2004-01-28 2004-03-03 Unilever Plc Porous bodies and method of production thereof
US7015181B2 (en) 2004-03-08 2006-03-21 Lambino Danilo L Rehydratable personal care compositions
EP1574561A1 (fr) 2004-03-11 2005-09-14 The Procter & Gamble Company Comprimé détergent parfumé
US20050220745A1 (en) 2004-04-01 2005-10-06 L'oreal S.A. Cosmetic compositions containing swelled silicone elastomer powders and gelled block copolymers
CN100519716C (zh) 2004-05-31 2009-07-29 华中师范大学 软膜纸香皂及其生产方法和装置
US20050287106A1 (en) 2004-06-22 2005-12-29 Jean-Yves Legendre Method for shaving with at least one anhydrous film, use of at least one anhydrous film for the preparation of a shaving product, and shaving kits
US8623341B2 (en) 2004-07-02 2014-01-07 The Procter & Gamble Company Personal care compositions containing cationically modified starch and an anionic surfactant system
FR2873896B1 (fr) 2004-08-06 2007-06-01 Juris Union Ltd Particule(s) solides(s) soluble(s) a base de fibre(s) alimentaire(s)
US8197830B2 (en) 2005-01-18 2012-06-12 Gojo Industries, Inc. Dissolvable pads for solution delivery to a surface
US20060228319A1 (en) 2005-04-11 2006-10-12 Vona Samuel A Jr Personal cleansing and shaving films
CN1935881B (zh) 2005-09-21 2012-05-09 李小鲁 水溶性可生物降解材料及其制备方法以及发泡类制品
JP2007091954A (ja) 2005-09-29 2007-04-12 Toshiba Corp 発泡体、その製造方法、およびその再生方法
US7901696B2 (en) 2005-10-31 2011-03-08 J&J Consumer Companies, Inc. Cosmetic device comprising discrete elements
WO2007062347A2 (fr) 2005-11-22 2007-05-31 Smithkline Beecham Corporation Substrat mousse et son procede de fabrication
FR2894136B1 (fr) 2005-12-07 2008-01-18 Oreal Article cosmetique soluble moussant
US20070149435A1 (en) 2005-12-28 2007-06-28 Kimberly-Clark Worldwide, Inc. Cleansing composition including microencapsulated delivery vehicles
JP4668798B2 (ja) 2006-01-25 2011-04-13 株式会社ツキオカ 水溶性洗浄用フィルム
WO2007093558A2 (fr) 2006-02-14 2007-08-23 L'oréal Article cosmetique soluble
US20080090939A1 (en) 2006-04-20 2008-04-17 Netravali Anil N Biodegradable soy protein-based compositions and composites formed therefrom
US7786027B2 (en) 2006-05-05 2010-08-31 The Procter & Gamble Company Functionalized substrates comprising perfume microcapsules
EP2029292A4 (fr) 2006-06-08 2012-12-05 Spongeables Llc Système de libération spongieux perfusé
US20080293839A1 (en) 2006-09-07 2008-11-27 Stobby William G Stabilized extruded alkenyl aromatic polymer foams and processes for extruding stabilized alkenyl aromatic polymer foams
US20080083420A1 (en) 2006-10-09 2008-04-10 The Procter & Gamble Company Hair treatment application system
EP1958532A3 (fr) 2006-10-09 2013-06-05 The Procter and Gamble Company Système d'application de traitement capillaire
US20080152894A1 (en) 2006-12-20 2008-06-26 Amcol Health & Beauty Solutions Treated substrates having improved delivery of impregnated ingredients
US20080215023A1 (en) 2007-03-01 2008-09-04 Timothy Alan Scavone Compositions and/or articles comprising cyclodextrin complexing material
FR2919802B1 (fr) 2007-08-06 2011-05-06 Cll Pharma Procede de solubilisation d'huiles essentielles dans l'eau
KR100937625B1 (ko) 2007-08-10 2010-01-20 주식회사 제닉 가용성 웹 공극필름 및 이의 제조방법
EP2085434A1 (fr) 2008-01-11 2009-08-05 Universita' Degli Studi di Firenze Colorants dispersés hydrosolubles
US8765170B2 (en) * 2008-01-30 2014-07-01 The Procter & Gamble Company Personal care composition in the form of an article
CA2721640C (fr) 2008-04-16 2014-12-09 The Procter & Gamble Company Composition non moussante de soins personnels sous forme d'article
BRPI0922185A2 (pt) 2008-12-08 2018-06-05 The Procter & Gamble um substrato sólido poroso dissoluvel e complexos de particulados inorganicos de perfume residentes de superficie.
WO2010077653A2 (fr) * 2008-12-08 2010-07-08 The Procter & Gamble Company Composition de soin d'hygiène personnelle sous la forme d'un article possédant un revêtement hydrophobe se situant en surface
JP5718246B2 (ja) 2008-12-08 2015-05-13 ザ プロクター アンド ギャンブルカンパニー 多孔質溶解性固体構造を有する物品形態のパーソナルケア組成物
US8461091B2 (en) 2008-12-08 2013-06-11 The Procter & Gamble Company Personal care composition in the form of an article having a porous, dissolvable solid structure
US8466099B2 (en) 2008-12-08 2013-06-18 The Procter & Gamble Company Process of making an article for dissolution upon use to deliver surfactants
WO2011014401A2 (fr) 2009-07-30 2011-02-03 The Procter & Gamble Company Articles et procédés de soin oral
US8309505B2 (en) 2009-07-30 2012-11-13 The Procter & Gamble Company Hand dish composition in the form of an article
US8367596B2 (en) 2009-07-30 2013-02-05 The Procter & Gamble Company Laundry detergent compositions in the form of an article
US8288332B2 (en) 2009-07-30 2012-10-16 The Procter & Gamble Company Fabric care conditioning composition in the form of an article
EP2509564B1 (fr) 2009-12-08 2013-11-20 The Procter and Gamble Company Substrat solide poreux pouvant être dissous et revêtement résidant en surface comprenant des microsphères de matrice
EP2509561B1 (fr) 2009-12-08 2017-08-02 The Procter and Gamble Company Substrat solide dissoluble poreux et revêtement résident de surface comprenant des substances actives sensibles à l'eau
WO2011071969A1 (fr) 2009-12-08 2011-06-16 The Procter & Gamble Company Substrat solide, poreux et soluble et revitalisant capillaire à base d'un tensioactif cationique
WO2011071964A1 (fr) 2009-12-08 2011-06-16 The Procter & Gamble Company Substrat solide, poreux et soluble et revêtement destiné à gainer le cheveu constitué d'un revitalisant capillaire à base d'un tensioactif cationique
BR122019015741B1 (pt) 2010-07-02 2021-12-21 The Procter & Gamble Company Artigo de estrutura de manta fibrosa dissolvível que compreende agentes ativos
US20120270029A1 (en) 2011-04-07 2012-10-25 Glenn Jr Robert Wayne Continuous Process of Making an Article of Dissolution Upon Use to Deliver Surfactants

Patent Citations (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2396278A (en) 1933-11-15 1946-03-12 Procter & Gamble Detergent composition
US2486921A (en) 1944-10-16 1949-11-01 Procter & Gamble Detergent composition
US2486922A (en) 1945-11-09 1949-11-01 Procter & Gamble Stabilized detergent composition
US3929678A (en) 1974-08-01 1975-12-30 Procter & Gamble Detergent composition having enhanced particulate soil removal performance
EP0283165B1 (fr) 1987-03-06 1992-10-28 The Procter & Gamble Company Composition et méthode pour le soin de la peau
EP0397410A2 (fr) 1989-05-10 1990-11-14 Ciba Specialty Chemicals Water Treatments Limited Produits absorbants et leur préparation
US5104646A (en) 1989-08-07 1992-04-14 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
US5106609A (en) 1990-05-01 1992-04-21 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
US5582786A (en) 1992-08-19 1996-12-10 Courtaulds Fibres Limited Method of producing fibre or film
US5955419A (en) 1995-09-18 1999-09-21 The Procter & Gamble Company High efficiency delivery system comprising zeolites
EP1160311A2 (fr) 1995-09-18 2001-12-05 The Procter & Gamble Company Système de diffusion de parfum
EP0858828A1 (fr) 1997-02-12 1998-08-19 LEWA Herbert Ott GmbH + Co. Procédé et dispositif pour la distribution par pulvérisation avec ultrasons
EP0922449A2 (fr) 1997-10-31 1999-06-16 National Starch and Chemical Investment Holding Corporation Utilisation d'un dérivé d'amidon traité par enzymes en tant qu'agent d'encapsulage
US6106849A (en) * 1998-01-21 2000-08-22 Dragoco Gerberding & Co. Ag Water soluble dry foam personal care product
WO1999055819A1 (fr) 1998-04-23 1999-11-04 The Procter & Gamble Company Particules de parfum en inclusion et compositions detergentes contenant ces particules
WO2001040430A1 (fr) 1999-12-03 2001-06-07 The Procter & Gamble Company Systeme de liberation dote d'un support poreux encapsule charge d'additifs, notamment d'additifs detergents tels que des parfums
US20030232183A1 (en) * 2000-09-13 2003-12-18 The Procter & Gamble Company Process for making a foam component
WO2003037294A2 (fr) * 2001-11-01 2003-05-08 The Procter & Gamble Company Compositions de soins personnels contenant une mousse polymere se desagregeant en presence d'eau
EP1317916A2 (fr) * 2001-11-16 2003-06-11 National Starch and Chemical Investment Holding Corporation Des films comprenant de l'amidon modifié
WO2003088933A1 (fr) * 2002-04-15 2003-10-30 Salvona, L.L.C. Systemes a liberation declenchee par l'humidite renfermant des ingredients d'aromes provoquant un eclatement de parfum en reponse a l'humidite
US20030215522A1 (en) 2002-04-22 2003-11-20 The Procter & Gamble Company Personal care compositions comprising a zinc containing material in an aqueous surfactant composition
WO2004032859A2 (fr) * 2002-10-09 2004-04-22 The Dial Corporation Composition en feuille hydrosoluble
WO2004041991A1 (fr) * 2002-11-01 2004-05-21 Salvona Llc Systeme de liberation controlee d'un multicomposant pour pains de savon
US12079008B2 (en) 2017-09-25 2024-09-03 State Farm Mutual Automobile Insurance Company Dynamic autonomous vehicle train
US12076508B2 (en) 2018-10-22 2024-09-03 Hi-Lex Corporation Fixing device
US12078608B2 (en) 2021-11-02 2024-09-03 Acer Incorporated Power supply device with protection function when water ingress occurs

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
"McCutcheon's Detergents and Emulsifiers", 1986, ALLURED PUBLISHING CORP.
"McCutcheon's, Functional Materials", 1992, ALLURED PUBLISHING CORP.
"The Cosmetic", 1988, TOILETRIES, AND FRAGRANCE ASSOCIATION, INC., article "reference books such as the CTFA Cosmetic Ingredient Handbook"
MCCUTCHEON'S FUNCTIONAL MATERIALS, 1992
T. HILDEBRAND; P. RÜEGSEGGER: "Quantification of bone microarchitecture with the structure model index", COMP METH BIOMECH BIOMED ENG, vol. 1, 1997, pages 15 - 23
VESTERBY, A., ANAT REC., vol. 235, no. 2, February 1993 (1993-02-01), pages 325 - 334

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9622956B2 (en) 2011-12-21 2017-04-18 Colgate-Palmolive Company Oral care compositions
WO2015171531A1 (fr) * 2014-05-05 2015-11-12 The Procter & Gamble Company Produits de consommation
WO2015171532A1 (fr) * 2014-05-05 2015-11-12 The Procter & Gamble Company Produits de consommation
WO2015171536A1 (fr) * 2014-05-05 2015-11-12 The Procter & Gamble Company Produits de consommation
GB2589402A (en) * 2019-07-10 2021-06-02 Henkel Kgaa Solid hair conditioning agent consisting of a least two components
GB2589402B (en) * 2019-07-10 2022-04-20 Henkel Kgaa Solid hair conditioning agent consisting of a least two components
WO2022055373A1 (fr) * 2020-09-11 2022-03-17 Ethique Limited Concentré solide d'une composition de soins personnels/ménagère destiné à être reconstitué avec de l'eau

Also Published As

Publication number Publication date
EP2509564A1 (fr) 2012-10-17
JP2013512283A (ja) 2013-04-11
CN102647972B (zh) 2013-12-11
MX339322B (es) 2016-05-20
US20110182956A1 (en) 2011-07-28
JP5639659B2 (ja) 2014-12-10
US9295859B2 (en) 2016-03-29
CN102647972A (zh) 2012-08-22
MX2012006550A (es) 2012-11-06
BR112012013838A2 (pt) 2016-05-10
EP2509564B1 (fr) 2013-11-20

Similar Documents

Publication Publication Date Title
US9295859B2 (en) Porous, dissolvable solid substrate and surface resident coating comprising matrix microspheres
US8476211B2 (en) Porous, dissolvable solid substrates and surface resident starch perfume complexes
EP2509560B1 (fr) Substrat solide, poreux et soluble et revêtement destiné à gainer le cheveu constitué d'un revitalisant capillaire à base d'un tensioactif cationique
US8349787B2 (en) Porous, dissolvable solid substrate and a cationic surfactant conditioner material

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 201080055672.2

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10796222

Country of ref document: EP

Kind code of ref document: A1

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10796222

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 4326/DELNP/2012

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 2010796222

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2012542246

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: MX/A/2012/006550

Country of ref document: MX

NENP Non-entry into the national phase

Ref country code: DE

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112012013838

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 112012013838

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20120608