[go: up one dir, main page]

WO2011066270A3 - Hydrogenation of solid carbonaceous materials using mixed catalysts - Google Patents

Hydrogenation of solid carbonaceous materials using mixed catalysts Download PDF

Info

Publication number
WO2011066270A3
WO2011066270A3 PCT/US2010/057773 US2010057773W WO2011066270A3 WO 2011066270 A3 WO2011066270 A3 WO 2011066270A3 US 2010057773 W US2010057773 W US 2010057773W WO 2011066270 A3 WO2011066270 A3 WO 2011066270A3
Authority
WO
WIPO (PCT)
Prior art keywords
solid carbonaceous
hydrogenation
carbonaceous materials
mixed catalysts
carbonaceous material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/057773
Other languages
French (fr)
Other versions
WO2011066270A2 (en
Inventor
Alexander E. Kuperman
Jinyi Han
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron USA Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron USA Inc filed Critical Chevron USA Inc
Priority to CA2781416A priority Critical patent/CA2781416A1/en
Publication of WO2011066270A2 publication Critical patent/WO2011066270A2/en
Publication of WO2011066270A3 publication Critical patent/WO2011066270A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of zinc at a reaction temperature of greater than 350°C and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product.
PCT/US2010/057773 2009-11-24 2010-11-23 Hydrogenation of solid carbonaceous materials using mixed catalysts Ceased WO2011066270A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2781416A CA2781416A1 (en) 2009-11-24 2010-11-23 Hydrogenation of solid carbonaceous materials using mixed catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/625,390 US20110120914A1 (en) 2009-11-24 2009-11-24 Hydrogenation of solid carbonaceous materials using mixed catalysts
US12/625,390 2009-11-24

Publications (2)

Publication Number Publication Date
WO2011066270A2 WO2011066270A2 (en) 2011-06-03
WO2011066270A3 true WO2011066270A3 (en) 2011-11-24

Family

ID=44061314

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/057773 Ceased WO2011066270A2 (en) 2009-11-24 2010-11-23 Hydrogenation of solid carbonaceous materials using mixed catalysts

Country Status (3)

Country Link
US (1) US20110120914A1 (en)
CA (1) CA2781416A1 (en)
WO (1) WO2011066270A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CO5980161A1 (en) * 2008-09-02 2008-11-28 Univ Nac De Colombia PREPARATION PROCESS OF USEFUL CATALYSTS IN DIRECT CARBON LICUEFACTION AND THE CATALYST SO OBTAINED
CN113617296B (en) * 2020-05-08 2023-08-25 北京机械设备研究所 Carbon dioxide catalytic hydrogenation system and method
CN113528146B (en) * 2021-08-19 2022-01-28 河南大学 Preparation and application of surface-modified silicon dioxide-doped ferrous sulfide soil heavy metal passivator
CN116020505B (en) * 2021-10-25 2024-11-05 中国石油化工股份有限公司 Catalyst for selective oxidation of hydrocarbons and its preparation method and application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223698A (en) * 1961-01-09 1965-12-14 Inst Noguchi Method for liquefying lignin
JPS5761082A (en) * 1980-09-30 1982-04-13 Kobe Steel Ltd Liquefaction of coal
US4441983A (en) * 1982-08-19 1984-04-10 Air Products And Chemicals, Inc. Zinc sulfide liquefaction catalyst
US4617106A (en) * 1985-07-26 1986-10-14 Air Products And Chemicals, Inc. Catalysts for coal liquefaction processes
JPH10121055A (en) * 1996-10-21 1998-05-12 Nippon Brown Coal Liquefaction Corp Method for liquefying coal

Family Cites Families (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3645885A (en) * 1970-05-04 1972-02-29 Exxon Research Engineering Co Upflow coal liquefaction
US4077667A (en) * 1974-04-08 1978-03-07 Allerheiligen Arnold G Means for cushioning wooden pews or the like
AU506174B2 (en) * 1976-05-28 1979-12-13 Kobe Steel Limited Coal liquefaction
US4077867A (en) * 1976-07-02 1978-03-07 Exxon Research & Engineering Co. Hydroconversion of coal in a hydrogen donor solvent with an oil-soluble catalyst
US4155832A (en) * 1977-12-23 1979-05-22 The United States Of America As Represented By The United States Department Of Energy Hydrogenation process for solid carbonaceous materials
US4369106A (en) * 1980-04-10 1983-01-18 Exxon Research And Engineering Co. Coal liquefaction process
US4450066A (en) * 1980-09-02 1984-05-22 Exxon Research And Engineering Co. Hydrothermal pretreatment to prevent scale during liquefaction of certain solid carbonaceous materials
US4485008A (en) * 1980-12-05 1984-11-27 Exxon Research And Engineering Co. Liquefaction process
US4417972A (en) * 1981-11-04 1983-11-29 Exxon Research And Engineering Co. Recovery of coal liquefaction catalysts
US4401549A (en) * 1981-11-17 1983-08-30 Uop Inc. Liquefaction of calcium-containing coals
US4447972A (en) * 1981-12-15 1984-05-15 Mccabe Stanley G Laundry spreader, counter, and folder
US4401550A (en) * 1982-01-11 1983-08-30 Uop Inc. Liquefaction of calcium-containing coals
US4485006A (en) * 1982-03-04 1984-11-27 Exxon Research And Engineering Co. Start-up method for a hydrorefining process
US4434043A (en) * 1982-06-01 1984-02-28 Exxon Research And Engineering Co. Recovery of catalyst from coal liquefaction residues
US4578176A (en) * 1982-06-09 1986-03-25 Institute Of Gas Technology Fuel production by free fall countercurrent flow
JPS59109588A (en) * 1982-12-15 1984-06-25 Kobe Steel Ltd Liquefaction method of lignite
IT1163480B (en) * 1983-06-08 1987-04-08 Anic Spa STAGE PROCEDURE FOR DIRECT CHARCOAL LIQUEFATION
US5484755A (en) * 1983-08-29 1996-01-16 Lopez; Jaime Process for preparing a dispersed Group VIB metal sulfide catalyst
US5094991A (en) * 1983-08-29 1992-03-10 Chevron Research Company Slurry catalyst for hydroprocessing heavy and refractory oils
US4573176A (en) * 1983-11-18 1986-02-25 Rca Corporation Fractional frequency divider
US4493761A (en) * 1983-12-05 1985-01-15 Standard Oil Company (Indiana) Catalytic hydroliquefaction using a Cr-Mo-Group VIII catalyst
US4917791A (en) * 1984-06-01 1990-04-17 Kang Chia Chen Chu Process and catalysts for hydroconversion of coal or petroleum asphaltene to distillate liquids
US4595486A (en) * 1985-02-01 1986-06-17 Allied Corporation Electrochemical gas sensor
US4617105A (en) * 1985-09-26 1986-10-14 Air Products And Chemicals, Inc. Coal liquefaction process using pretreatment with a binary solvent mixture
US4824568A (en) * 1986-05-16 1989-04-25 Millipore Corporation Composite ultrafiltration membranes
US5236881A (en) * 1986-08-22 1993-08-17 Coal Industry (Patents) Limited Coal extract hydrocracking catalyst
US4923836A (en) * 1987-07-16 1990-05-08 Union Oil Company Of California Ni/Cu absorbent/catalyst for desulfurization and isomerization of N-paraffins
US4824558A (en) * 1987-09-04 1989-04-25 Exxon Research And Engineering Company Coal liquefaction process with metal/iodine cocatalyst
US4831003A (en) * 1987-09-14 1989-05-16 Exxon Research And Engineering Company Catalyst composition and process of making
US5051389A (en) * 1987-09-16 1991-09-24 Exxon Research And Engineering Company Catalyst composition prepared by vapor depositing onto a carbon support
US4948523A (en) * 1987-09-30 1990-08-14 Amoco Corporation Chlorine-free silver protective lubricant composition (I)
US4816141A (en) * 1987-10-16 1989-03-28 Hri, Inc. Catalytic two-stage liquefaction of coal utilizing cascading of used ebullated-bed catalyst
CA1317585C (en) * 1988-02-02 1993-05-11 Chandra Prakash Khulbe Hydrocracking of heavy oils in presence of iron-coal slurry
US5070064A (en) * 1989-08-07 1991-12-03 Exxon Research And Engineering Company Catalyst pretreatment method
US5151173A (en) * 1989-12-21 1992-09-29 Exxon Research And Engineering Company Conversion of coal with promoted carbon monoxide pretreatment
US5336395A (en) * 1989-12-21 1994-08-09 Exxon Research And Engineering Company Liquefaction of coal with aqueous carbon monoxide pretreatment
US5183561A (en) * 1990-01-25 1993-02-02 Mobil Oil Corp. Demetallation of hydrocarbon feedstocks with a synthetic mesoporous crystalline material
PL293013A1 (en) * 1990-02-15 1992-06-15 Amoco Corp Preliminary treatment of coal before its liquefaction
US5015366A (en) * 1990-04-10 1991-05-14 The United States Of America As Represented By The United States Department Of Energy Process and apparatus for coal hydrogenation
US5039392A (en) * 1990-06-04 1991-08-13 Exxon Research And Engineering Company Hydroconversion process using a sulfided molybdenum catalyst concentrate
US5200063A (en) * 1990-06-21 1993-04-06 Exxon Research And Engineering Company Coal hydroconversion process comprising solvent enhanced pretreatment with carbon monoxide
US5001369A (en) * 1990-07-02 1991-03-19 Micron Technology, Inc. Low noise output buffer circuit
BR9004200A (en) * 1990-08-24 1992-03-03 Petroleo Brasileiro Sa DEPARING PROCESS FOR PRODUCING FORMATIONS
US5336441A (en) * 1991-05-29 1994-08-09 Petrolite Corporation Corrosion inhibition in highly acidic environments by use of pyridine salts in combination with certain cationic surfactants
US5246570A (en) * 1992-04-09 1993-09-21 Amoco Corporation Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst
GB2267233B (en) * 1992-05-15 1996-09-04 Nikki Universal Co Ltd Hydrodesulfurization catalyst and preparation thereof
US5783065A (en) * 1992-09-03 1998-07-21 University Of Utah Research Foundation Method for coal liquefaction
US5338441A (en) * 1992-10-13 1994-08-16 Exxon Research And Engineering Company Liquefaction process
US5344553A (en) * 1993-02-22 1994-09-06 Mobil Oil Corporation Upgrading of a hydrocarbon feedstock utilizing a graded, mesoporous catalyst system
US5389230A (en) * 1993-06-11 1995-02-14 Exxon Research & Engineering Co. Catalytic hydroconversion process
US5332489A (en) * 1993-06-11 1994-07-26 Exxon Research & Engineering Co. Hydroconversion process for a carbonaceous material
US5489375A (en) * 1994-06-08 1996-02-06 Amoco Corporation Resid hydroprocessing method
JP3338190B2 (en) * 1994-08-17 2002-10-28 三菱化学株式会社 Catalyst component for .ALPHA.-olefin polymerization and method for producing .ALPHA.-olefin polymer using the same
US5489875A (en) * 1994-09-21 1996-02-06 Simon Fraser University Adaptive feedforward linearizer for RF power amplifiers
US5464034A (en) * 1994-09-27 1995-11-07 Kestin; Hesh Pocket-portable rain covering
US5573556A (en) * 1994-11-03 1996-11-12 Exxon Research And Engineering Company Conversion of solid carbonaceous material using polyoxoanions
US5620591A (en) * 1994-12-22 1997-04-15 Exxon Research & Engineering Company Hydroconversion process with plug-flow molybdenum catalyst concentrate preparation
JP2853612B2 (en) * 1995-08-30 1999-02-03 日本電気株式会社 Semiconductor storage device
US6139723A (en) * 1996-02-23 2000-10-31 Hydrocarbon Technologies, Inc. Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds
US6190542B1 (en) * 1996-02-23 2001-02-20 Hydrocarbon Technologies, Inc. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds
US5728656A (en) * 1997-03-20 1998-03-17 Chevron Chemical Company Lower-ash lubricating oil having ultra-neutral zinc dialkyldithiophosphates
US5744026A (en) * 1997-04-10 1998-04-28 Eastman Chemical Company Catalyst system and process for benzyl ether fragmentation and coal liquefaction
US6153155A (en) * 1997-12-31 2000-11-28 Exxon Research And Engineering Company Recovery of the transition metal component of catalyst used in heavy feed hydroconversion
US6064043A (en) * 1999-06-01 2000-05-16 France/Scott Fetzer Company Dryer control circuit
US7095708B1 (en) * 1999-06-23 2006-08-22 Cingular Wireless Ii, Llc Methods and apparatus for use in communicating voice and high speed data in a wireless communication system
US6153156A (en) * 1999-08-02 2000-11-28 Gnb Technologies, Inc. Method for purifying leady oxides
US6569516B1 (en) * 1999-12-10 2003-05-27 Nitto Denko Corporation Transparent laminate and plasma display panel filter utilizing same
US6551965B2 (en) * 2000-02-14 2003-04-22 Chevron Oronite Company Llc Marine diesel engine lubricating oil composition having improved high temperature performance
GB0011115D0 (en) * 2000-05-09 2000-06-28 Infineum Int Ltd Lubricating oil compositions
TW504497B (en) * 2000-05-23 2002-10-01 Sumitomo Chemical Co Alpha-alumina powder and heat-conductive sheet containing the same
DE10143742A1 (en) * 2001-09-06 2003-03-27 Consortium Elektrochem Ind Process for the preparation of alpha-halogen ketones
US7163911B2 (en) * 2003-05-22 2007-01-16 Chevron Oronite Company Llc Carboxylated detergent-dispersant additive for lubricating oils
US20050043191A1 (en) * 2003-08-22 2005-02-24 Farng L. Oscar High performance non-zinc, zero phosphorus engine oils for internal combustion engines
ITMI20032207A1 (en) * 2003-11-14 2005-05-15 Enitecnologie Spa INTEGRATED PROCEDURE FOR THE CONVERSION OF CHARGES CONTAINING CARBON IN LIQUID PRODUCTS.
US8030258B2 (en) * 2005-07-29 2011-10-04 Chevron Oronite Company Llc Overbased alkaline earth metal alkylhydroxybenzoates having low crude sediment
JP3920304B1 (en) * 2005-11-22 2007-05-30 株式会社神戸製鋼所 Method and apparatus for producing solid fuel using low-grade coal as raw material
US8734682B2 (en) * 2008-02-13 2014-05-27 David Walker Taylor Process for preparing fuel solids for gasification
US8123934B2 (en) * 2008-06-18 2012-02-28 Chevron U.S.A., Inc. System and method for pretreatment of solid carbonaceous material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223698A (en) * 1961-01-09 1965-12-14 Inst Noguchi Method for liquefying lignin
JPS5761082A (en) * 1980-09-30 1982-04-13 Kobe Steel Ltd Liquefaction of coal
US4441983A (en) * 1982-08-19 1984-04-10 Air Products And Chemicals, Inc. Zinc sulfide liquefaction catalyst
US4617106A (en) * 1985-07-26 1986-10-14 Air Products And Chemicals, Inc. Catalysts for coal liquefaction processes
JPH10121055A (en) * 1996-10-21 1998-05-12 Nippon Brown Coal Liquefaction Corp Method for liquefying coal

Also Published As

Publication number Publication date
US20110120914A1 (en) 2011-05-26
CA2781416A1 (en) 2011-06-03
WO2011066270A2 (en) 2011-06-03

Similar Documents

Publication Publication Date Title
WO2011066249A3 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
WO2010008841A3 (en) Processes for producing fermentation products
ECSP10010220A (en) METAL RECOVERY FROM HEAVY CONVERTED EFFLUENT
WO2010077940A3 (en) Water-insoluble reaction product of a polyamine and an oil-soluble high carbon polar modified polymer
WO2011138678A3 (en) Compositions, gels and foams with rheology modulators and uses thereof
EP4299070A3 (en) Process and system for obtaining botulinum neurotoxin
WO2014009938A3 (en) Products made from biomass
WO2009054878A3 (en) Compositions and methods for the treatment of neoplasia
MX349674B (en) Terminal-modified difunctional sulfur-containing polymers, compositions thereof and methods of use.
WO2009155186A3 (en) System and method for pretreatment of solid carbonaceous material
WO2008079250A3 (en) Hydrogenation of caryophyllene
WO2010118299A3 (en) System and method for pretreatment of solid carbonaceous material
WO2009003051A3 (en) Method of making linear alkylbenzenes
WO2009102959A8 (en) Apparatus and processes for production of coke and activated carbon from coal products
WO2011066257A3 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
WO2011066270A3 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
WO2011066250A3 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
WO2009048141A1 (en) Microreactor and liquid phase chemical reaction method using the microreactor
WO2010141953A3 (en) Biomaterials, compositions, and methods
WO2011004066A3 (en) Process and apparatus for producing hydrocarbons by hydrogenating a terpene feed
WO2014023758A3 (en) Selective catalytic deoxygenation of biomass and catalysts therefor
WO2012087905A3 (en) Thermoplastic composition
WO2006091849A3 (en) New catalytic systems for the conversion of hydrocarbons to functionalized products
MY157741A (en) Apparatus for removing catalyst surface substances
WO2014184287A3 (en) Process for converting a solid biomass material

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10833848

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2781416

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 10833848

Country of ref document: EP

Kind code of ref document: A2