WO2010148527A1 - Procédé destiné au traitement thermique des résidus de combustion, en particulier de cendres de filtre, provenant dinstallations de combustion dordures ménagères et destiné à la récupération des métaux - Google Patents
Procédé destiné au traitement thermique des résidus de combustion, en particulier de cendres de filtre, provenant dinstallations de combustion dordures ménagères et destiné à la récupération des métaux Download PDFInfo
- Publication number
- WO2010148527A1 WO2010148527A1 PCT/CH2010/000156 CH2010000156W WO2010148527A1 WO 2010148527 A1 WO2010148527 A1 WO 2010148527A1 CH 2010000156 W CH2010000156 W CH 2010000156W WO 2010148527 A1 WO2010148527 A1 WO 2010148527A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- combustion residues
- ash
- mercury
- metals
- residues
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/40—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by heating to effect chemical change, e.g. pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/02—Working-up flue dust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/022—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
- F23J15/025—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/08—Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/24—Organic substances containing heavy metals
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/28—Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/40—Inorganic substances
- A62D2101/43—Inorganic substances containing heavy metals, in the bonded or free state
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/30—Pyrolysing
- F23G2201/301—Treating pyrogases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2209/00—Specific waste
- F23G2209/30—Solid combustion residues, e.g. bottom or flyash
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/60—Heavy metals; Compounds thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2700/00—Ash removal, handling and treatment means; Ash and slag handling in pulverulent fuel furnaces; Ash removal means for incinerators
- F23J2700/001—Ash removal, handling and treatment means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2900/00—Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
- F23J2900/01007—Thermal treatments of ash, e.g. temper or shock-cooling for granulation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the invention relates to a method for the thermal treatment of combustion residues, in particular filter ash, from refuse incineration plants (KVA) with the features of claim 1.
- Flammable domestic and commercial waste has been disposed of for decades in waste or incineration plants (KVA).
- KVA waste or incineration plants
- the waste incineration works perfectly in these modern plants.
- this filter ash is still deposited today without pretreatment in underground landfills. Another part of the filter ash is placed in a so-called neutral wash to remove salts. The remaining material from this filter ash is then solidified with cement and can be disposed of in a landfill.
- the filter ash first passes through an acidic wash with hydrochloric acid from the flue gas cleaning. Here, the heavy metals zinc, cadmium and lead are removed and the filter ash then deposited together with the slag from the KVA. Filter ash from the KVA contains up to 5 micrograms of dioxin per kilogram. Does this toxic substance come from improper storage? In contact with oil-contaminated seepage water, it can be mobilized and washed out.
- a device and a method of the same applicant relate to the mechanical treatment of the filter ash.
- the treated with this method filter ash from refuse or waste incineration plants is cleaned so far that a landfill of the resulting after this treatment residues can be carried out in underground landfills.
- other components of the filter ash eg dioxins (PCDD), furans (PCDF) and mercury (Hg)
- PCDD dioxins
- PCDF furans
- Hg mercury
- the overnight storage of the remaining filter ash fractions is therefore out of the question due to the residual contents of pollutants.
- the contaminated residues are problematic.
- mercury and metal oxides contained in the residues can not be recovered as raw materials and additionally problematize the landfill or prevent their economic recovery.
- a disadvantage of the mechanically processed filter ash is that the deposition must be due to the pollution in underground landfills. This goes hand in hand with much higher costs.
- the existing underground landfills are reaching their capacity limits. This necessitates the development of new deposits, resulting in further costs and acceptance problems.
- the object of the present invention is therefore to provide a method which improves the treatment of incineration residues from refuse or refuse incineration plants, in particular filter ash, to such an extent that landfill of the ash fractions remaining after the treatment can be carried out without difficulty in a subfloor Overground landfill can be done.
- mercury, salt and metal oxides are to be separated from the filter ash and recycled or recycled into the material cycle.
- the recyclable fractions of the filter ash thus obtained can either be separately landfilled or subsequently returned to the material cycle, if this makes more sense from an economic point of view.
- the inventive method can in conventional filter ash recovery, resp. Processing plants, including in those with a so-called. Acid laundry, preceded to improve the degree of purification of the ash.
- the process according to the invention comprises process steps for the elimination of dioxin and furan and for the recovery of mercury and / or metals from the filter ash to be treated.
- a first step the filter ash is heated to temperatures between 238 ° C and 1000 0 C (preferably between 356 0 C and 600 0 C, in particular 500 0 C).
- the filter ash passes through the heatable part of a treatment plant, in particular a heated screw or a heated rotary tube. Black particles in the filter ash are lighter and float up the product stream in the treatment plant.
- the heating of these black particles in the specified temperature range produces gases in a gasification process.
- dioxin, furan, mercury and possibly also parts of the metals present are converted into the gas phase or vaporized and thereby removed from the filter ash.
- This is done at specific temperatures in a step-by-step process.
- vaporized mercury for example, at 356, 6 0 C
- chlorine evaporate at 238.5 ° C and sulfur at 444.7 ° C.
- the heating to 500 0 C thus evaporation of all aforementioned components to be eliminated can be achieved.
- the zinc economically well usable evaporated for example, at 907 0 C and is also recorded by heating to close to 1000 0 C.
- the pollutants including chlorine and sulfur
- metal residues are transferred to the gas phase.
- the ash remaining after heating and degassing thus no longer contains pollutants (such as dioxin).
- the vaporized pollutants are recovered from the steam and recycled (in the case of mercury, metals and metal oxides).
- the process can be carried out in any suitable reactor designed for the corresponding parameters. However, it is considered particularly favorable if the process is carried out in a pyrolysis reactor under exclusion of oxygen.
- the treatment of the residues is then depending on the starting material in indirect or direct pyrolysis.
- To control the pyrolysis and to achieve certain end products here is the ability to add certain pyrolysis excipients, as well as the pressure ratios, gas mixtures and the duration of treatment set exactly to achieve the best possible efficiency.
- a cooling of the hot gas takes place.
- this is passed through a heat exchanger and thereby cooled.
- the heat recovered in this case can be used to increase the energy efficiency of the system, to operate a heater or to generate electricity and the like. By cooling the gases before passing through the filter this is conserved and thus extends its service life.
- it is provided to filter out the heavy metals from the gas in order to deposit them separately. It is considered to be advisable to place the filters and / or the heavy metals in a separate depot and store them in order to prevent contamination of the remaining fractions and thus of the environment. It is also possible to exploit the heavy metals, which can be used as an alternative to landfill.
- the method according to the invention further provides for passing the gases which have formed during the heating of the filter ash and possibly cooled gases through an activated carbon filter in order to remove mercury and / or metals present in the gas phase.
- the mercury and / or the metals are thereby bound in the coal of the filter.
- the remaining after filtration gas now contains only still dioxins and furans.
- the acted upon with mercury and / or metals coal is recycled in an regarded as favorable, additional process step and the mercury and / or metals thereby recovered.
- the retrieved from the vapor mercury, resp. the activated carbon which has taken up mercury, collected in a mercury catch tank and fed to market and environmentally friendly mercury treatment. The same can be done for the collected metals.
- the gases which are freed of mercury and / or metals and still containing dioxin and furan, are introduced into a combustion furnace.
- a further cooling of the treated filter ash Preferably, a further cooling of the treated filter ash.
- a preferred development of the process according to the invention provides desalination and additional recovery of metal oxides from the filter ash. This is done in further steps, which are arranged downstream of the method described above.
- the filter ash which still contains metal oxides and has not yet been desalted, is first added with water for desalination.
- the water is preferably heated, wherein for heating the water, for example, the heat recovered in the heat exchanger can be used.
- the thus treated filter ash is stirred in a separation vessel. As low is considered when the stirring of the water-ash mixture using a stirrer.
- the cement-like material is removed mechanically (for example with a slide) from the separation tank and stored separately.
- the method also includes a filtration step for the unpurified salt water resulting from the mixing of filter ash and water.
- the filtered salt water can then be further treated as purified salt water in downstream process steps.
- the particles filtered out of the salt water are thermally dried with the filter ash or separately.
- the salt is in dissolved form in the water and can not be held back by the filter. As recommended is considered to dispose of the filtered, saline wastewater, since this is to be regarded as safe in terms of pollutant content.
- the heavier metal oxide-containing material remains in the separation vessel.
- the material is still moist and therefore preferably dried first. This is done in a favorable manner by dripping, for example, after spreading on a grid or sieve.
- the dripping water can also be disposed of as wastewater due to the safety of the residual content of pollutants.
- the complete thermal drying of the drained mass is carried out, which can be conveniently resorted to the waste heat from the or the heat exchanger (s).
- the magnetic metal oxides are removed from the material by magnetic separation and thus recovered.
- the dried mass is comminuted for this purpose in order to increase the efficiency of the magnetic separation. It is regarded as favorable if the recovered heavy metals are collected and further treated or separately landfilled.
- the filter ash is collected.
- the filter ash is now treated and cleaned and contains no salt and almost no metal oxides.
- the filter ash is now suitable for the daytime Landfill and can be deposited here inexpensively and free of environmental concerns.
- Fig. 1 is a schematic representation of the sequence of the inventive method
- Fig. 2 shows an advantageous development of the inventive method.
- the inventive method is used for the thermal treatment of combustion residues and in particular for the treatment of dioxin, furan, mercury and heavy metal contaminated filter ash from garbage or waste incineration plants (here generally designated by the numeral 10).
- the process can be preceded or followed by any existing filter ash processing plant.
- the upstream is preferable to the downstream, so that the dioxin and furan are removed right at the beginning. It follows thus first a mechanical or chemical treatment of the filter ash and then a thermal treatment. However, it is also conceivable that the thermal of the chemical or mechanical treatment is connected upstream.
- dioxin (PCDD), furan (PCDF) and mercury are removed from the ash, which is taken from the investment filter 20 of a KVA 10 or a mechanical / chemical treatment plant 30.
- the filter ash treated in this way is capable of being disposed of underground after treatment. Due to the thermal treatment, the specific weight of the ash is increased by about 20%, which is ecologically and economically very important.
- the mercury is recirculated (as are all metal oxides excreted at this temperature).
- filter ash which is taken from the (a KVA 10 or a mechanical / chemical treatment plant 30 associated) investment filter 20 is heated in a reactor 11 at 500 0 C.
- a reactor 11 arranged in the heated screw or by a heated rotary tube (both not shown).
- the black particles in the filter ash are lighter, float up here and are therefore the most heated.
- This heating of the black particles to 500 ° C. produces gases (gasification process).
- the dioxin, furan and mercury go into the gas phase during the gasification process or evaporate and are thereby removed from the filter ash.
- a reactor temperature of about 500 ° C. is selected in the process according to the invention.
- the dioxin-containing residues (including chlorine and sulfur) are thus transferred to the gas phase and in the reactor 11 remains only ash, which contains no dioxin more.
- the hot gas is introduced into a gas heat exchanger 2, cooled there and thus recovered heat. By this cooling of the gases before passing through the heavy metal filter 3 this is conserved. After the gas heat exchanger 2 heavy metals are filtered out of the gas in the heavy metal filter 3, which can then be spent in the depot 7 and stored.
- the resulting in the first steps and subsequently cooled gases flow through the heavy metal filter 3, an activated carbon filter 4, which binds the mercury in the coal.
- This mercury-laden coal can later be reprocessed and the mercury recovered.
- the filtration through the activated carbon filter 4 can be further improved by chemical bonding of mercury.
- the gas is after filtration through the activated carbon filter 4 only dioxin and furanhaltig.
- the gaseous phase separated mercury or the activated carbon, which received the mercury has, is collected in a mercury catch tank 17 and can then be provided from the mercury catch tank 17 for umweit- and market fair mercury treatment.
- the liberated from mercury, but still dioxin and furan-containing gases are returned via a gas inlet 5 (for example, a valve) in the combustion furnace 12 of the KVA 10 and eliminated by the high temperatures prevailing there.
- the ash heated to separate the pollutants is passed over or through an ash heat exchanger 8 and the filter ash is cooled in this case.
- the recovered heat can then be fed, for example, into the heat cycle of the KVA 10 and the efficiency of the system can be increased thereby.
- the processed filter ash After passing through the ash heat exchanger 8, the processed filter ash is collected in a bearing 9. Since the filter ash after removal of mercury, dioxin and furan is not desalted and since the metal oxides have been removed only incomplete, this ash is usually suitable only for underground landfill. Due to the treatment described above, the filter ash is sandy consistency while at the beginning of the process it was flaky. Also, the specific gravity of this recycled filter ash is higher.
- FIG. 2 shows a further development of the method from FIG. 1 schematically. This was modified by additional method steps to the effect that desalination and recovery of metal oxides from the filter ash can now also take place.
- the method shown in Fig. 1 is extended to further process steps for the desalination and recovery of metal oxides.
- the steps of the method described with reference to FIG. 1 are identical until the filter ash is cooled in the gas heat exchanger 2. After the filter ash has been cooled while passing through the ash heat exchanger 8, it is passed to a desalination plant 22. There, the filter ash, which still contains metal oxides and which has not yet desalted de, with warm water added for desalination. Subsequently, the thus treated filter ash is stirred in a separation vessel 23 by means of a stirrer 14. By stirring, the heavier parts of the filter ash, namely the metal oxides settle down in the separation vessel 23, while the lighter parts float up and form a white, cement-like layer.
- the cement-like material which floats above in the separation vessel 23 under the influence of the agitator 14, has a lower specific gravity than the remainder of the filter ash in the separation vessel 23, which still contains heavy metal.
- This cement-like material is pushed out of the separation vessel with a slide 15 and stored in a storage container 18.
- the unpurified salt water from the separation tank 23 is filtered in an intermediate step 19 and then disposed of as purified salt water via a sewer line 13.
- the filtered out of the salt water particles are transferred with the remaining part of the filter ash from the separation vessel 23 in a drying plant 16.
- the heavier and metal oxide containing portions of the filter ash remaining in the separation vessel 23 are deposited in a drip tray 25 (e.g., on a screen or grate).
- the dripping water is also disposed of via the sewer 13.
- the drained mass is dried completely thermally in the drying unit 16.
- the dried mass is crushed and all magnetic metal oxides are recovered by magnetic separation 26. These are then provided for further processing 27.
- the prepared and cleaned filter ash, which contains no salt and only traces of metal oxides, can then be easily stored on an overground landfill 12.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Toxicology (AREA)
- Emergency Management (AREA)
- Business, Economics & Management (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Processing Of Solid Wastes (AREA)
- Treating Waste Gases (AREA)
Abstract
Linvention concerne un procédé de traitement thermique de résidus de combustion (en particulier, de cendres de filtre) provenant dinstallations de combustion dordures ménagères (10). Le procédé comprend les étapes suivantes : - chauffage des résidus de combustion pour faire passer les constituants toxiques des résidus de combustion en phase gazeuse; - extraction par filtration des métaux lourds à partir de la phase gazeuse; - séparation par filtration du mercure à partir de la phase gazeuse; - passage des gaz résiduels contenant des dioxines et des furannes, dans une installation de combustion des déchets (10) et mise à la décharge des résidus de combustion traités. Des modes de réalisation avantageux du procédé prévoient un autre traitement des résidus de combustion, de sorte que finalement, une mise à la décharge ultérieure des résidus de combustion traités est possible, car ils ne contiennent plus déléments toxiques (dioxines, furannes, oxydes de mercure et/ou métalliques).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH00986/09A CH701352B1 (de) | 2009-06-24 | 2009-06-24 | Verfahren zur thermischen Aufbereitung von Verbrennungsrückständen, insbesondere von Filter-Asche, aus Müll- oder Kehrichtverbrennungsanlagen und zur Metall-Rückgewinnung. |
| CH986/09 | 2009-06-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2010148527A1 true WO2010148527A1 (fr) | 2010-12-29 |
Family
ID=42340674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CH2010/000156 Ceased WO2010148527A1 (fr) | 2009-06-24 | 2010-06-15 | Procédé destiné au traitement thermique des résidus de combustion, en particulier de cendres de filtre, provenant dinstallations de combustion dordures ménagères et destiné à la récupération des métaux |
Country Status (2)
| Country | Link |
|---|---|
| CH (1) | CH701352B1 (fr) |
| WO (1) | WO2010148527A1 (fr) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0465406A2 (fr) * | 1990-07-06 | 1992-01-08 | Sulzer Chemtech AG | Procédé de fusion en continu des produits solides ou pâteux |
| EP0515792A2 (fr) * | 1991-05-28 | 1992-12-02 | Deutsche Babcock Anlagen Gmbh | Procédé pour le traitement des résidus d'une installation d'incinération de déchets, et installation d'incinération de déchets pour la mise en oeuvre dudit procédé |
| EP0572769A2 (fr) * | 1992-05-12 | 1993-12-08 | Holderbank Financiere Glarus Ag | Procédé pour la conversion des résidus de l'incinération de déchets en produit non-polluant et utilisable pour la construction |
-
2009
- 2009-06-24 CH CH00986/09A patent/CH701352B1/de active IP Right Maintenance
-
2010
- 2010-06-15 WO PCT/CH2010/000156 patent/WO2010148527A1/fr not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0465406A2 (fr) * | 1990-07-06 | 1992-01-08 | Sulzer Chemtech AG | Procédé de fusion en continu des produits solides ou pâteux |
| EP0515792A2 (fr) * | 1991-05-28 | 1992-12-02 | Deutsche Babcock Anlagen Gmbh | Procédé pour le traitement des résidus d'une installation d'incinération de déchets, et installation d'incinération de déchets pour la mise en oeuvre dudit procédé |
| EP0572769A2 (fr) * | 1992-05-12 | 1993-12-08 | Holderbank Financiere Glarus Ag | Procédé pour la conversion des résidus de l'incinération de déchets en produit non-polluant et utilisable pour la construction |
Also Published As
| Publication number | Publication date |
|---|---|
| CH701352A2 (de) | 2010-12-31 |
| CH701352B1 (de) | 2014-05-30 |
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