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WO2010012997A3 - Process for production of bio-oil by coprocessing of biomass in a delayed coking unit - Google Patents

Process for production of bio-oil by coprocessing of biomass in a delayed coking unit Download PDF

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Publication number
WO2010012997A3
WO2010012997A3 PCT/GB2009/001863 GB2009001863W WO2010012997A3 WO 2010012997 A3 WO2010012997 A3 WO 2010012997A3 GB 2009001863 W GB2009001863 W GB 2009001863W WO 2010012997 A3 WO2010012997 A3 WO 2010012997A3
Authority
WO
WIPO (PCT)
Prior art keywords
biomass
oil
coprocessing
bio
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2009/001863
Other languages
French (fr)
Other versions
WO2010012997A2 (en
Inventor
Marcio De Figueiredo Portilho
Fernando Antonio Duarte Santiago
Gloria Maria Gomes Soares
Natalie Jorge Goncalves
Danielle Marins Pala
Ana Paula Saraiva De Araujo
Alexander Rangel Bastos
Francisco Carlos Da Costa Barros
Denis Monteiro Da Rocha
Moacir Taparo
Vladimir Albanez Gomes
Fabio Marcelo Souza Brogna
Bruno Milka Souza
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Petroleo Brasileiro SA Petrobras
BENSON JOHN EVERETT
Original Assignee
Petroleo Brasileiro SA Petrobras
BENSON JOHN EVERETT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleo Brasileiro SA Petrobras, BENSON JOHN EVERETT filed Critical Petroleo Brasileiro SA Petrobras
Priority to JP2011520580A priority Critical patent/JP2011529523A/en
Priority to CN2009801282619A priority patent/CN102099438A/en
Publication of WO2010012997A2 publication Critical patent/WO2010012997A2/en
Publication of WO2010012997A3 publication Critical patent/WO2010012997A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/12—Applying additives during coking
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/40—Thermal non-catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G51/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only
    • C10G51/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only
    • C10G51/023—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only only thermal cracking steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/005—Coking (in order to produce liquid products mainly)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1018—Biomass of animal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/26—Fuel gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/28—Propane and butane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Processing Of Solid Wastes (AREA)
  • Coke Industry (AREA)

Abstract

A process is described for production of Bio-Oil by delayed coking with modified feedstock, in which the feed of the conventional coke unit envisages, in addition to the usual fresh feed of hydrocarbon (vacuum residue, atmospheric residue etc.), the feeding of a biomass for coprocessing. Said biomass can be selected from the group comprising sugar cane straw, sugar cane bagasse, castor seed cake, coconut shells, rice husks, raw soya, castor seed, canola, oil palm, and cottonseed oils, and oils and fats of animal origin, which can be used separately, or as mixtures thereof in any proportions.
PCT/GB2009/001863 2008-07-31 2009-07-29 Process for production of bio-oil by coprocessing of biomass in a delayed coking unit Ceased WO2010012997A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2011520580A JP2011529523A (en) 2008-07-31 2009-07-29 A method for bio-oil production by co-processing biomass in a delayed coking unit
CN2009801282619A CN102099438A (en) 2008-07-31 2009-07-29 Process for producing bio-oil by co-processing of biomass in a delayed coker

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BRPI0803545-8A BRPI0803545A2 (en) 2008-07-31 2008-07-31 bio-oil production process by biomass co-processing in delayed coking unit
BRPI0803545-8 2008-07-31

Publications (2)

Publication Number Publication Date
WO2010012997A2 WO2010012997A2 (en) 2010-02-04
WO2010012997A3 true WO2010012997A3 (en) 2010-11-11

Family

ID=41462231

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2009/001863 Ceased WO2010012997A2 (en) 2008-07-31 2009-07-29 Process for production of bio-oil by coprocessing of biomass in a delayed coking unit

Country Status (6)

Country Link
US (1) US20100024283A1 (en)
JP (1) JP2011529523A (en)
CN (1) CN102099438A (en)
AR (1) AR071766A1 (en)
BR (1) BRPI0803545A2 (en)
WO (1) WO2010012997A2 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8333949B2 (en) * 2009-05-14 2012-12-18 University Of North Dakota Method for creating high carbon content products from biomass oil
US20100326880A1 (en) * 2009-06-25 2010-12-30 Bp Corporation North America Inc. Hydrocarbon Conversion Process Additive and Related Processes
US8603325B2 (en) * 2010-03-25 2013-12-10 Exxonmobil Research And Engineering Company Biomass oil conversion process
US8658025B2 (en) * 2010-03-25 2014-02-25 Exxonmobil Research And Engineering Company Biomass conversion process
CN101805647A (en) * 2010-04-23 2010-08-18 倪建辉 Method for preparing natural gas by biomass material thermal cracking and thermal cracking furnace used by same
ES2393464B1 (en) * 2011-06-09 2013-11-18 Ingelia, S.L. PROCEDURE FOR THE EXTRACTION OF BIOCHEMICAL PRODUCTS OBTAINED FROM A BIOMASS HYDROTERMAL CARBONIZATION PROCESS.
ES2482915B1 (en) * 2011-06-23 2015-07-03 Foster Wheeler Usa Corporation Process for the production of biofuels by coprocessing biomass in a thermal processing unit in a refinery.
IN2013MU03691A (en) 2013-11-23 2015-07-31 Indian Oil Corp Ltd
US10202557B2 (en) * 2014-12-19 2019-02-12 The United States Of America, As Represented By The Secretary Of Agriculture Methods of producing calcined coke from bio-oil and calcined coke produced thereby
CN106032470B (en) * 2015-12-04 2017-11-28 中国石油大学(华东) A kind of coking method for processing bio oil
WO2022120318A1 (en) 2020-12-01 2022-06-09 ExxonMobil Technology and Engineering Company Co-processing of biomass oil in coker
EP4112702A1 (en) 2021-06-29 2023-01-04 Indian Oil Corporation Limited Pre-treatment process for conversion of residual oils in a delayed coker unit
WO2025054690A1 (en) * 2023-09-13 2025-03-20 Petroleo Brasileiro S.A. – Petrobras Method for converting liquid plant biomass in a delayed coking unit

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL36977C (en) *
US1864686A (en) * 1930-03-08 1932-06-28 John D Fields Process of cracking and coking
US1864720A (en) * 1931-06-29 1932-06-28 John D Fields Method of distilling hydrocarbons and producing coke and product thereof
US5667669A (en) * 1996-03-22 1997-09-16 Betzdearborn Inc. Methods for inhibiting foam
US20020179493A1 (en) * 1999-08-20 2002-12-05 Environmental & Energy Enterprises, Llc Production and use of a premium fuel grade petroleum coke
CN1891789A (en) * 2005-07-06 2007-01-10 华东理工大学 Delayed coking treatment method for waste biomass
WO2008012484A1 (en) * 2006-07-28 2008-01-31 Petroleo Brasileiro S.A. - Petrobras Process of modification of a feedstock in a delayed coking unit

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1082080C (en) * 1996-09-19 2002-04-03 中国石油化工集团公司 Delayed coking technology for producing more diesel oil
CN1132895C (en) * 1998-10-07 2003-12-31 中国冶金建设集团鞍山焦化耐火材料设计研究总院 Two-stage coking preparation method for needle-shaped coke of coal series
CN1180055C (en) * 2001-04-28 2004-12-15 中国石油化工股份有限公司 A needle coke production method for removing solid particles in raw oil

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL36977C (en) *
US1864686A (en) * 1930-03-08 1932-06-28 John D Fields Process of cracking and coking
US1864720A (en) * 1931-06-29 1932-06-28 John D Fields Method of distilling hydrocarbons and producing coke and product thereof
US5667669A (en) * 1996-03-22 1997-09-16 Betzdearborn Inc. Methods for inhibiting foam
US20020179493A1 (en) * 1999-08-20 2002-12-05 Environmental & Energy Enterprises, Llc Production and use of a premium fuel grade petroleum coke
CN1891789A (en) * 2005-07-06 2007-01-10 华东理工大学 Delayed coking treatment method for waste biomass
WO2008012484A1 (en) * 2006-07-28 2008-01-31 Petroleo Brasileiro S.A. - Petrobras Process of modification of a feedstock in a delayed coking unit

Also Published As

Publication number Publication date
CN102099438A (en) 2011-06-15
AR071766A1 (en) 2010-07-14
US20100024283A1 (en) 2010-02-04
BRPI0803545A2 (en) 2010-06-15
WO2010012997A2 (en) 2010-02-04
JP2011529523A (en) 2011-12-08

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