WO2010098479A1 - 三次元形状造形物の製造方法およびそれから得られる三次元形状造形物 - Google Patents
三次元形状造形物の製造方法およびそれから得られる三次元形状造形物 Download PDFInfo
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- WO2010098479A1 WO2010098479A1 PCT/JP2010/053188 JP2010053188W WO2010098479A1 WO 2010098479 A1 WO2010098479 A1 WO 2010098479A1 JP 2010053188 W JP2010053188 W JP 2010053188W WO 2010098479 A1 WO2010098479 A1 WO 2010098479A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/16—Both compacting and sintering in successive or repeated steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/007—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of moulds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/06—Permanent moulds for shaped castings
- B22C9/061—Materials which make up the mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/06—Permanent moulds for shaped castings
- B22C9/065—Cooling or heating equipment for moulds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/20—Direct sintering or melting
- B22F10/28—Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/30—Process control
- B22F10/38—Process control to achieve specific product aspects, e.g. surface smoothness, density, porosity or hollow structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/105—Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y80/00—Products made by additive manufacturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/30—Process control
- B22F10/36—Process control of energy beam parameters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/60—Treatment of workpieces or articles after build-up
- B22F10/66—Treatment of workpieces or articles after build-up by mechanical means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/30—Platforms or substrates
- B22F12/33—Platforms or substrates translatory in the deposition plane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/40—Radiation means
- B22F12/41—Radiation means characterised by the type, e.g. laser or electron beam
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/40—Radiation means
- B22F12/44—Radiation means characterised by the configuration of the radiation means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/40—Radiation means
- B22F12/49—Scanners
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2207/00—Aspects of the compositions, gradients
- B22F2207/11—Gradients other than composition gradients, e.g. size gradients
- B22F2207/17—Gradients other than composition gradients, e.g. size gradients density or porosity gradients
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2793/00—Shaping techniques involving a cutting or machining operation
- B29C2793/009—Shaping techniques involving a cutting or machining operation after shaping
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Definitions
- the present invention relates to a method for producing a three-dimensional shaped object and a three-dimensional shaped object. More specifically, the present invention manufactures a three-dimensional shaped object in which a plurality of solidified layers are laminated and integrated by repeatedly applying a light beam to a predetermined portion of a powder layer to form a solidified layer. It relates to the method as well as to the three-dimensional shaped object obtained thereby.
- a method (generally referred to as "powder sinter lamination method") of irradiating a powder material with a light beam to produce a three-dimensional shaped object is known.
- a powder layer is irradiated with a light beam to sinter or solidify the powder of the predetermined portion to form a solidified layer, and (ii) the solidified layer is obtained
- a new powder layer is applied on the top, and a light beam is similarly irradiated to form a solidified layer, and so on.
- the three-dimensional shaped object is manufactured repeatedly (Japanese Patent Application Laid-Open No. 1-502890 or See Japanese Patent Laid-Open Publication No. 2000-73108).
- the obtained three-dimensional shaped object can be used as a mold, and an organic powder material such as resin powder or plastic powder is used.
- the obtained three-dimensional shaped object can be used as a model. According to such a manufacturing technique, it is possible to manufacture a complicated three-dimensional shaped object in a short time.
- a three-dimensional shaped object is often produced in a chamber kept under an inert atmosphere from the viewpoint of oxidation prevention and the like.
- the powder layer 22 having a predetermined thickness t1 is formed on the forming plate 21.
- a light beam is irradiated to a predetermined portion of the powder layer 22 to form a solidified layer 24 on the shaping plate 21.
- a new powder layer 22 is placed on the formed solidified layer 24, and the light beam is irradiated again to form a new solidified layer.
- a three-dimensional shaped object in which a plurality of solidified layers 24 are integrally laminated can be obtained (see FIG. 1B).
- the solidified layer corresponding to the lowermost layer may be formed in a state of being adhered to the shaping plate surface. Therefore, the three-dimensional shaped object and the shaping plate are integrated with each other.
- the integrated three-dimensional shaped object and the forming plate can be used as a mold as it is.
- the three-dimensional shaped object is somewhat affected by the heat of the light beam. Specifically, the irradiated portion of the powder layer is once melted and becomes a molten state, and then solidified to form a solidified layer, but a shrinkage phenomenon may occur when the solidified layer is solidified. In particular, a shrinkage phenomenon occurs when the molten powder is cooled and solidified (see FIG. 2A).
- the shaping plate 21 supporting the solidified layer (that is, the three-dimensional shaped object) is a rigid body made of steel or the like and is separated from the irradiation position of the light beam.
- the shaping plate 21 is substantially less susceptible to the heat of the light beam.
- a curving force (moment) is generated in the three-dimensional shaped object 24 on the shaping plate.
- the warping force exceeds a certain limit, as shown in FIG. 2B, a phenomenon occurs in which the three-dimensional shaped object 24 peels off from the shaping plate 21 at the time of manufacturing. If the three-dimensional shaped object warps or peels from the forming plate, it is not desirable because the desired three-dimensional shaped object can not be manufactured. For example, when the three-dimensional shaped object (that is, the solidified layer) is warped, the shape accuracy of the obtained three-dimensional shaped object can not be obtained.
- JP-A-8-504139 As a method considering shrinkage of a three-dimensional shaped object, a manufacturing method as described in JP-A-8-504139 is proposed.
- the three-dimensional shaped object is manufactured separately into the inner core region and the outer shell region (see FIG. 17). Because the outer shell region has a higher consolidation density than the inner core region, its formation requires higher energy and longer times.
- the invention of Japanese Patent Publication No. 8-504139 does not consider the final use of the shaped object, and the outer shell region constitutes the "shell" as its name suggests. Therefore, according to the invention of Japanese Patent Publication No. 8-504139, the entire periphery of the three-dimensional shaped object is covered with a substantially uniform thickness (see FIG. 17), and it is never satisfactory in terms of manufacturing cost and shaping time It is not.
- the object of the present invention is to provide a “manufacturing method of a three-dimensional shaped object” which not only prevents warpage of the obtained three-dimensional shaped object but also reduces the manufacturing time and cost. is there.
- the present invention Irradiating a light beam (for example, a directional energy beam such as a laser beam) to a predetermined portion of the powder layer provided on the shaping plate to sinter or melt and solidify the powder of the predetermined portion to form a solidified layer And (ii) forming a new powder layer on the obtained solidified layer, and repeating the steps of irradiating a predetermined portion of the new powder layer with a light beam to form a further solidified layer.
- a light beam for example, a directional energy beam such as a laser beam
- a method of manufacturing a three-dimensional shaped object The solidified layer is formed to consist of a high density area of solid density 95-100% and a low density area of solid density 0-95% (not including 95%), and use of high density area by three-dimensional shaped object
- a method is provided for producing a three-dimensional shaped object, characterized in that it is an area which is sometimes stressed.
- the high density region is formed by completely melting the powder at a predetermined position irradiated with the light beam.
- the manufacturing method of the present invention is characterized in that the high density region is formed only at the necessary places. More specifically, the high-density area is formed only in the area (and sometimes the area near the area) to which force is applied when using the three-dimensional shaped object.
- the term "high density region” refers to the so-called “melting” (i.e., the region formed by solidifying the powder making up the powder layer and then solidifying it). There is. That is, the "high density region” substantially means a region where the solidification density is very high (solidification density is about 95 to 100%) and a fluid such as liquid or gas can not pass through.
- force means a force caused by pressure of fluid or the like, a force caused by contact, a force caused by frictional force, and the like.
- force substantially means a force that resin, cooling water, oil and / or steam is applied to a three-dimensional shaped object by contacting the three-dimensional shaped object.
- powder layer refers to, for example, "metal powder layer composed of metal powder” or “resin powder layer composed of resin powder”.
- the predetermined part of a powder layer means the area
- solidified layer substantially means “sintered layer” when the powder layer is a metal powder layer, and “hardened layer” when the powder layer is a resin powder layer. It means practically.
- the solidification density of the high density region is about 95 to 100%, preferably 98% to 100%, and more preferably substantially about 100%.
- the low density region may be any solidified density as long as the solidified density is 0 to 95% (not including 95%), taking into consideration the function of the three-dimensional shaped object, the production time, the production cost, etc. It should be decided.
- the low density region may have a consolidation density of 70 to 90%, and in some cases, a consolidation density lower than that.
- the high density area is formed on a part of the surface area of the three-dimensional shaped object. That is, the "melting" is formed only in the surface area where the "force” is applied.
- the high density region may be formed in the region in contact with the forming plate.
- “the high density region a formed in a part of the surface region” and the “high density region b formed in the region in contact with the shaping plate” are mutually connected. At least one high density region c may be formed in the inner region.
- the high density region is formed in part of the inner region of the three-dimensional shaped object. That is, if a portion to which "force” is applied (for example, a portion corresponding to the cooling water pipe wall of the mold) can be present in the interior of the three-dimensional object, the portion is "melted".
- a high density region is formed in a portion that becomes a heat transfer region when using a three-dimensional shaped object. That is, the surface in contact with the hot or cold substance is "melted".
- the present invention also provides a three-dimensional shaped object obtained by the above-described manufacturing method.
- a three-dimensional shaped object can be used as a mold, and the surface that forms the cavity space of the mold (ie, the wall surface inside the mold that forms the molded article) It corresponds to "a high density area” formed in a part of the surface area of the three-dimensional shaped object.
- the cooling water pipe wall of the mold may correspond to “a high density area formed in a part of the inner area of the three-dimensional shaped object”.
- the portion to which a force is applied when using the mold may correspond to the “junction between the high density region a and the high density region c of the three-dimensional shaped object” as described above. Effect of the invention
- the manufacturing method of the present invention since the high density region is formed only at the necessary place, not only the manufacturing time can be shortened but also the high density region requiring high energy is reduced and the manufacturing cost is reduced. It can be reduced.
- the high-density area can be said to be a "area with a relatively high shrinkage rate when the molten powder is cooled and solidified", but the area with such a large contraction is reduced as much as possible to produce a three-dimensional shaped object It takes place. Therefore, since it can contribute to the prevention or reduction of the warpage of the three-dimensional shaped object, the phenomenon that the three-dimensional shaped object (that is, the solidified layer) peels off from the surface of the forming plate can also be prevented. That is, not only the new powder layer can be spread with a predetermined thickness on the solidified layer, but also the shape accuracy of the finally obtained three-dimensional shaped object is improved.
- the present invention is also very useful in that the design which takes into consideration such a specifically difficult phenomenon can be omitted without increasing the manufacturing time and the manufacturing cost.
- FIG. 1 is a cross-sectional view schematically showing the operation of the optical forming compound processing machine.
- FIG. 2 is a cross-sectional view schematically showing a phenomenon that causes warping or peeling of a three-dimensional shaped object.
- FIG. 3 is a perspective view schematically showing an aspect in which the powder sinter lamination method is performed.
- FIG. 4 is the perspective view which showed typically the structure of the optical shaping compound processing machine with which the powder sinter lamination method is implemented.
- FIG. 5 is a flowchart of the operation of the optical forming combined processing machine.
- FIG. 6 is a schematic view showing the light shaping combined processing process with time.
- FIG. 7 is a schematic view conceptually showing the features of the three-dimensional shaped object obtained by the manufacturing method of the present invention.
- FIG. 1 is a cross-sectional view schematically showing the operation of the optical forming compound processing machine.
- FIG. 2 is a cross-sectional view schematically showing a phenomenon that causes warping or peeling of
- FIG. 8 is a SEM photograph (cross-sectional photograph in the dashed line portion of FIG. 7) of the three-dimensional shaped object obtained by the manufacturing method of the present invention.
- FIG. 9 is a SEM photograph (cross-sectional photograph of a three-dimensional shaped object) of a high density area (melted) and a low density area.
- FIG. 10 is a schematic view showing an aspect of a high density region formed on a part of the surface of a shaped object.
- FIG. 11 is a schematic view showing an aspect of a high density region formed at the interface with the shaping plate surface.
- FIG. 12 is a schematic view showing an aspect of a high density region in which a three-dimensional object is formed to have a cell structure or a truss structure.
- FIG. 13 is a perspective view of a three-dimensional shaped object schematically representing an aspect of the cell structure.
- FIG. 14 is a schematic view showing an aspect in which a high density area formed so as to have a cellular structure or a truss structure, in which a portion to which a force is applied is reinforced.
- FIG. 15 is a schematic view showing an aspect of a high density region formed in a part of the inside of a three-dimensional object.
- FIG. 16 is a schematic view showing a typical embodiment of a three-dimensional shaped object (mold) integrated with a shaping plate.
- FIG. 17 is a schematic view showing an embodiment of a three-dimensional shaped object according to the prior art (Japanese Patent Application Publication No. 8-504139).
- FIGS. 1, 3 and 4 show the function and configuration of an optical shaping compound processing machine 1 capable of carrying out the powder sinter lamination method.
- the stereolithography compound processing machine 1 includes “a powder layer forming means 2 for forming a powder layer by laying a powder such as a metal powder and a resin powder with a predetermined thickness” and “in a shaping tank 29 whose outer periphery is surrounded by a wall 27 And a modeling plate 21 arranged on the modeling table 20 and serving as a base of the modeling object, and a light beam irradiating means 3 for irradiating the light beam L to an arbitrary position. It mainly has “the cutting means 4 which cuts the circumference of a modeling thing”. As shown in FIG.
- the powder layer forming means 2 "powder table 25 vertically moved up and down by cylinder drive in powder material tank 28 whose outer periphery is surrounded by wall 26" and “powder layer 22 on the shaping plate” And a squeegeeing blade 23 "for forming.
- the light beam irradiating means 3 “a light beam oscillator 30 that emits a light beam L” and “a galvano mirror 31 (a scan that scans the light beam L on the powder layer 22 Optical system) ".
- the light beam irradiation means 3 has a beam shape correction means (for example, a pair of cylindrical lenses for correcting the shape of the light beam spot, and a rotational drive mechanism for rotating such lenses about the axis of the light beam). Means, an f ⁇ lens, etc. are provided.
- the cutting means 4 mainly has "a milling head 40 for shaving the periphery of a shaped object” and “an XY drive mechanism 41 (41a, 41b) for moving the milling head 40 to a cutting location" (FIG. 3 and FIG. 4).
- FIG. 5 shows the operation flow of the optical forming compound processing machine.
- FIG. 6 schematically and simply shows the stereolithography combined processing process.
- the operation of the optical forming combined processing machine includes a powder layer forming step (S1) of forming the powder layer 22, and a solidified layer forming step (S2) of irradiating the powder layer 22 with the light beam L to form the solidified layer 24; It mainly comprises from the cutting step (S3) which cuts the surface of a modeling thing.
- the powder layer forming step (S1) first, the shaping table 20 is lowered by ⁇ t1 (S11). Next, after raising the powder table 25 by ⁇ t 1, as shown in FIG. 1A, the squeegeeing blade 23 is moved in the arrow A direction.
- the powder for example, “iron powder with an average particle diameter of about 5 ⁇ m to 100 ⁇ m” or “powder of nylon, polypropylene, ABS or the like with an average particle diameter of about 30 ⁇ m to 100 ⁇ m”
- the powder layer 22 is formed to have a predetermined thickness ⁇ t1 (S13).
- the process proceeds to a solidified layer forming step (S2), and a light beam L (for example, carbon dioxide gas laser (500 W), Nd: YAG laser (500 W) or ultraviolet light) is emitted from the light beam oscillator 30 (S21).
- a light beam L for example, carbon dioxide gas laser (500 W), Nd: YAG laser (500 W) or ultraviolet light
- the powder is melted and solidified to form a solidified layer 24 integrated with the shaping plate 21 (S23).
- the light beam is not limited to transmission in air, but may be transmitted by an optical fiber or the like.
- the powder layer forming step (S1) and the solidified layer forming step (S2) are repeated until the thickness of the solidified layer 24 reaches a predetermined thickness obtained from the tool length of the milling head 40 and the like, and the solidified layer 24 is laminated (FIG. 1) (B)).
- stacked will be integrated with the solidified layer which forms the lower layer already formed in sintering or fusion-solidification.
- the cutting means to be used may be a general-purpose numerical control (NC) machine tool or the like.
- a machining center (MC) capable of automatically replacing a cutting tool (end mill) is preferable.
- the end mill for example, a two-blade ball end mill made of cemented carbide is mainly used.
- a square end mill, a radius end mill, a drill or the like may be used depending on the processing shape and purpose.
- the execution of the cutting step is started by driving the milling head 40 (S31).
- the milling head 40 when the tool (ball end mill) of the milling head 40 has a diameter of 1 mm and an effective blade length of 3 mm, cutting can be performed 3 mm deep, so if ⁇ t1 is 0.05 mm, 60 solidified layers are formed At this point, the milling head 40 is driven.
- the milling head 40 is moved in the directions of arrow X and arrow Y by the XY drive mechanism 41 (41a, 41b) to cut the surface of the object formed of the solidified layers 24 laminated (S32). And when manufacture of a three-dimensional-shaped molded article is not completed yet, it will return to a powder layer formation step (S1). Thereafter, the three-dimensional shaped object is manufactured by repeating S1 to S3 and laminating the additional solidified layer 24 (see FIG. 6).
- the irradiation path of the light beam L in the solidified layer forming step (S2) and the cutting path in the cutting step (S3) are created in advance from three-dimensional CAD data.
- contour processing is applied to determine a processing path.
- outline shape data of each cross section sliced at an equal pitch for example, 0.05 mm pitch when ⁇ t1 is 0.05 mm
- STL data generated from a three-dimensional CAD model is used for STL data generated from a three-dimensional CAD model .
- the production method of the present invention particularly considers the use of the obtained three-dimensional shaped object for the powder sintered lamination method described above.
- the solidified layer is formed such that the surface to which the force is applied becomes "melting" when using the three-dimensional shaped object. That is, the solidified layer is formed such that “the surface that contacts another substance when using a three-dimensional shaped object” is “melted”.
- the metal powder used in the present invention is a powder mainly composed of iron-based powder, and is optionally selected from the group consisting of nickel powder, nickel-based alloy powder, copper powder, copper-based alloy powder and graphite powder. It may be a powder further comprising at least one.
- the blending amount of iron-based powder having an average particle diameter of about 20 ⁇ m is 60 to 90% by weight
- the blending amount of nickel powder and / or nickel-based alloy powder is 5 to 35% by weight
- the area to which the force P is applied during use of the three-dimensional shaped object 24 is a high density area 24 'having a solidification density of 95 to 100%, and the other areas are solidified.
- the solidified layer is formed to be a low density region 24 ′ ′ with a density of 0 to 95% (not including 95%).
- a high density region i.e., high density melting
- FIG. 8 shows an SEM photograph of the boundary between the high density region and the low density region formed by the manufacturing method of the present invention.
- FIG. 9 shows cross-sectional photographs (SEM photographs) of the high density region and the low density region, respectively.
- the output energy of the light beam to be irradiated may be increased to cause complete melting of the powder.
- the output energy of the light beam to be irradiated may be lowered to prevent complete melting of the powder.
- 3D CAD data of the optical forming complex processing machine for example, two models of a 3D CAD model A in a high density region and a 3D CAD model B in a low density region are prepared, each condition is allocated and designated At the same time, unify the coordinate system as to where each is formed.
- the density change / intensity change is made by setting the light beam irradiation conditions etc. Is possible. More specifically, this is as follows.
- the irradiation path of the light beam should be prepared in advance from the data of the 3D CAD model, and use the contour shape data of each cross section obtained by slicing the STL data generated from the 3D CAD model at an equal pitch (for example, 0.05 mm)
- the three-dimensional CAD model is divided into a portion to be the high density region and a portion to be the low density region. Then, slice cross-sectional contour shape data of each of a portion to be a high density region and a portion to be a low density region is created, and light beam irradiation is performed on each portion using this to sinter or solidify the powder material.
- a high density area is a "dense area" to which no fluid such as liquid or gas can pass. More specifically, the high density region can be said to be a region through which fluid can not pass under conditions of use of the three-dimensional object. In such a high density region, the solidification density is 95 to 100%, preferably 98% to 100%, and more preferably substantially 100%.
- the higher the consolidation density of the high density region the higher the resistance to the forces exerted on the three-dimensional shaped object due to, for example, resin, cooling water, oil and / or steam.
- the high density region may have various shapes and sizes, depending on the use form of the three-dimensional shaped object (in particular, a mode in which force is applied at the time of use of the object, etc.).
- the high density region 24 ' when the high density region 24 'has a form as shown in FIG. 7, its thickness may be uniform (for example, about 0.01 mm to 10 mm) as shown in FIG. However, the thickness of the high density region 24 'is not limited to being “uniform”, but may be “nonuniform”. Regardless of the "uniform thickness” or “non-uniform thickness", the thickness of the high density region may vary depending on the function of the three-dimensional shaped object.
- the low density region 24 '' (see, for example, FIG. 7) has a solidification density of 0 to 95% (not including 95%), and is a "rough region".
- the solidification density of the low density region may be finally determined in consideration of the function of the three-dimensional shaped object, S construction time, manufacturing cost, and the like.
- the solidification density of the low density region may be, for example, 70 to 90%, and in some cases, the solidification density may be lower.
- the solidification density may be 0%. This means that the formation of the low density region does not particularly require the irradiation of the light beam.
- solidified density substantially means a sintered cross-sectional density (occupied percentage of a metal material) obtained by image processing a cross-sectional photograph of a shaped article.
- the image processing software used is Scion Image ver. It is 4.0.2 (freeware).
- the sintered cross-sectional density S S can be obtained by the following equation 1. [Equation 1]
- the area where force is applied when using a three-dimensional shaped object is a high density area with a solid density of 95 to 100%, and the other areas are a low density area with a solid density of 0 to 95% (not including 95%)
- various aspects are considered to the aspect of "forming a solidified layer”. The details will be described below. In the following description, an embodiment using "metal powder” as a powder will be described as an example.
- the high density area 24'a is formed only on the surface area to which the force P is applied when the three-dimensional shaped object 24 is used.
- the high density region formed in part of the surface area of the shaped object may correspond to the inner surface of the mold (i.e., the molding surface forming the cavity space).
- the solidification density of the high density region is preferably about 98% to 100%, and the thickness Ta (see FIG. 10) is preferably about 0.5 to 5 mm.
- the solidification density of the low density region 24 ′ ′ is preferably about 70 to 90%.
- the high density region 24'b may be formed in the region in contact with the forming plate 21 as illustrated.
- the joint surface with the shaping plate needs to be strong, so that energy is given to that part to make it “melted”. Increase the bonding strength.
- the solidification density of the high density region 24'b is about 98% to 100%, and the thickness Tb (see FIG. 11) may be relatively thin, about 0.05 to 0.3 mm.
- the solidification density of the low density region 24 ′ ′ is preferably about 70 to 90%.
- the solidification density of the low density region 24 ′ ′ is preferably about 70 to 90%.
- Cell structure or truss structure The aspect of “cell structure or truss structure” is shown in FIG. 12 or FIG. As illustrated, when used as a product without separation of a three-dimensional shaped object integrated with a forming plate, "high density area a (24'a) formed in a part of the surface area” and “forming plate At least one high density area c (24'c) in the inner area of the three-dimensional shaped object so that the high density area b (24'b) "formed in the area in contact with the May be In such a case, since the junction between the high density region a and the high density region c is stronger against external force, the high density region c can function as a reinforcing portion. In other words, as shown in FIG.
- the local portion is a high density area a (24'a) and a high density
- the high density area c (24'c) corresponds to the cooling water pipe wall of the mold as shown in FIG.
- the high-density area 24'd is formed only in the inner area to which the force P is applied when the three-dimensional shaped object 24 is used.
- the high density area 24'd formed in a part of the inner area corresponds to the cooling water pipe wall of the mold. That is, when the cooling water flows inside the mold, the cooling fluid flows in the cooling water pipe portion, so that the fluid pressure (“water pressure” in the case of the cooling water) is applied.
- the solidification density of the high density region 24'd is about 98% to 100%, and the thickness Tc (see FIG. 15) is preferably relatively large, and is about 2 to 5 mm. Is preferred.
- the solidification density of the low density region 24 ′ ′ is preferably about 70 to 90%.
- the high density area formed in the heat transfer area In the aspect of "the high density area formed in the heat transfer area", the high density area is formed only in the portion corresponding to the heat transfer area when the three-dimensional shaped object is used. In other words, when heat exchange is performed on the surface of the shaped object in contact with the high-temperature or low-temperature substance, the surface portion is “melted”.
- the high density region not only has high strength but also high thermal conductivity, thus enabling effective thermal efficiency.
- the high density area corresponds to the cooling water pipe wall 24'd of the mold (see FIG. 12)
- First aspect (i) a step of irradiating a light beam to a predetermined portion of the powder layer provided on the shaping plate to sinter or melt and solidify the powder of the predetermined portion to form a solidified layer; ) A three-dimensional shaped object to be formed by repeating the steps of forming a new powder layer on the obtained solidified layer and irradiating a predetermined portion of the new powder layer with a light beam to form a further solidified layer.
- the solidified layer is formed to consist of a high density area of solid density 95-100% and a low density area of solid density 0-95% (not including 95%), and use of high density area by three-dimensional shaped object
- Second aspect In the first aspect, a high density region is formed by completely melting the powder at the predetermined location.
- Third aspect In the first or second aspect, the solidification density in the low density region is 70 to 90%.
- Fourth aspect A manufacturing method according to any one of the first to third aspects, wherein the high density region is formed in part of the surface region of the three-dimensional shaped object.
- Eighth aspect The manufacturing method according to any one of the first to seventh aspects, wherein a high density region is formed in a portion to be a heat transfer region when using a three-dimensional shaped object.
- Ninth aspect A three-dimensional shaped object obtained by the manufacturing method of the fourth aspect described above, A three-dimensional shaped article using the three-dimensional shaped article as a mold, wherein a part of the surface area corresponds to a surface forming a cavity space of the mold.
- Tenth aspect A three-dimensional shaped object obtained by the manufacturing method of the sixth aspect, A three-dimensional shaped article using the three-dimensional shaped article as a mold, wherein a part of the inner region corresponds to a cooling water pipe wall of the mold.
- An eleventh aspect A three-dimensional shaped article obtained by the manufacturing method of the seventh aspect, which is provided by: A three-dimensional shaped article using the three-dimensional shaped article as a mold, wherein a joint between the high density area a and the high density area c is a part to which a force is applied when the mold is used.
- the three-dimensional shaped object to be obtained is a plastic injection molding die, a press die, a die casting die, It can be used as a mold such as a casting mold and a forging mold.
- the powder layer is an organic resin powder layer and the solidified layer is a hardened layer
- the resulting three-dimensional shaped article can be used as a resin molded article.
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Abstract
Description
(i)造形プレート上に設けた粉末層の所定箇所に光ビーム(例えばレーザ光のような指向性エネルギービーム)を照射して前記所定箇所の粉末を焼結又は溶融固化させて固化層を形成する工程、および
(ii)得られた固化層の上に新たな粉末層を形成し、前記新たな粉末層の所定箇所に光ビームを照射して更なる固化層を形成する工程
を繰り返して行う三次元形状造形物の製造方法であって、
固化層を固化密度95~100%の高密度領域と固化密度0~95%(95%を含まず)の低密度領域とから成るように形成し、高密度領域が三次元形状造形物の使用時に力のかかる領域であることを特徴とする、三次元形状造形物の製造方法が提供される。好ましくは、光ビームが照射された所定箇所の粉末を完全溶融させることによって高密度領域を形成する。
発明の効果
図2は、三次元形状造形物の反り上がり又は剥離を引き起こす現象を模式的に示した断面図である。
図3は、粉末焼結積層法が行われる態様を模式的に示した斜視図である。
図4は、粉末焼結積層法が実施される光造形複合加工機の構成を模式的に示した斜視図である。
図5は、光造形複合加工機の動作のフローチャートである。
図6は、光造形複合加工プロセスを経時的に表した模式図である。
図7は、本発明の製造方法で得られる三次元形状造形物の特徴を概念的に表した模式図である。
図8は、本発明の製造方法で得られた三次元形状造形物のSEM写真(図7の破線部内の断面写真図)である。
図9は、高密度領域(メルティング)および低密度領域のSEM写真(三次元形状造形物の断面写真)である。
図10は、造形物表面の一部に形成された高密度領域の態様を表した模式図である。
図11は、造形プレート面との界面部に形成された高密度領域の態様を表した模式図である。
図12は、造形物がセル構造またはトラス構造を有するように形成された高密度領域の態様を表した模式図である。
図13は、セル構造の態様を模式的に表した三次元形状造形物の斜視図である。
図14は、造形物がセル構造またはトラス構造を有するように形成された高密度領域を表した態様であって、力の加えられる箇所が補強されている態様を表した模式図である。
図15は、造形物内部の一部に形成された高密度領域の態様を表した模式図である。
図16は、造形プレートと一体化した三次元形状造形物(金型)の典型的な態様を表した模式図である。
図17は、従来技術(特表平8−504139号公報)の三次元形状造形物の態様を表した模式図である。
1 光造形複合加工機
2 粉末層形成手段
3 光ビーム照射手段
4 切削手段
19 粉末/粉末層(例えば金属粉末/金属粉末層または樹脂粉末/樹脂粉末層)
20 造形テーブル
21 造形プレート
22 粉末層(例えば金属粉末層または樹脂粉末層)
23 スキージング用ブレード
24 固化層(例えば焼結層または硬化層)またはそれから得られる三次元形状造形物
24’ 高密度領域(高密度メルティング)
24’a 高密度領域(=高密度メルティング、例えば“金型のキャビティ空間面”)
24’b 高密度領域(=高密度メルティング、例えば“プレート面との界面に形成された高密度領域”)
24’c 高密度領域(=高密度メルティング、例えば“セル構造またはトラス構造を構成する高密度領域”)
24’d 高密度領域(=高密度メルティング、例えば“金型の冷却水管壁”)
24’’ 低密度領域
25 粉末テーブル
26 粉末材料タンクの壁部分
27 造形タンクの壁部分
28 粉末材料タンク
29 造形タンク
30 光ビーム発振器
31 ガルバノミラー
32 反射ミラー
33 集光レンズ
40 ミーリングヘッド
41 XY駆動機構
41a X軸駆動部
41b Y軸駆動部
42 ツールマガジン
50 チャンバー
52 光透過窓
L 光ビーム
P 使用時に三次元形状造形物に加えられる“力”
まず、本発明の製造方法の前提となる粉末焼結積層法について説明する。図1,図3および図4には、粉末焼結積層法を実施できる光造形複合加工機1の機能および構成が示されている。光造形複合加工機1は、「金属粉末および樹脂粉末などの粉末を所定の厚みで敷くことによって粉末層を形成する粉末層形成手段2」と「外周が壁27で囲まれた造形タンク29内においてシリンダー駆動で上下に昇降する造形テーブル20」と「造形テーブル20上に配され造形物の土台となる造形プレート21」と「光ビームLを任意の位置に照射する光ビーム照射手段3」と「造形物の周囲を削る切削手段4」とを主として備えている。粉末層形成手段2は、図1に示すように、「外周が壁26で囲まれた粉末材料タンク28内においてシリンダー駆動で上下に昇降する粉末テーブル25」と「造形プレート上に粉末層22を形成するためのスキージング用ブレード23」とを主として有して成る。光ビーム照射手段3は、図3および図4に示すように、「光ビームLを発する光ビーム発振器30」と「光ビームLを粉末層22の上にスキャニング(走査)するガルバノミラー31(スキャン光学系)」とを主として有して成る。必要に応じて、光ビーム照射手段3には、光ビームスポットの形状を補正するビーム形状補正手段(例えば一対のシリンドリカルレンズと、かかるレンズを光ビームの軸線回りに回転させる回転駆動機構とを有して成る手段)やfθレンズなどが具備されている。切削手段4は、「造形物の周囲を削るミーリングヘッド40」と「ミーリングヘッド40を切削箇所へと移動させるXY駆動機構41(41a,41b)」とを主として有して成る(図3および図4参照)。
本発明の製造方法は、上述した粉末焼結積層法につき、得られる三次元形状造形物の用途を特に考慮したものである。具体的にいえば、本発明では、三次元形状造形物を使用するときに力のかかる面が“メルティング”となるように固化層を形成する。即ち、「三次元形状造形物を使用する時に他の物質を接触する面」が“メルティング”となるように固化層を形成する。
[式1]
「造形物表面の一部に形成された高密度領域」の態様を図10に示す。図示するように、三次元形状造形物24の使用時に力Pのかかる表面領域にのみ高密度領域24’aが形成されている。例えば、三次元形状造形物を金型として用いる場合、造形物の表面領域の一部に形成された高密度領域は金型の内面(即ち、キャビティー空間を成す成形面)に相当し得る。この場合、高密度領域の固化密度は98%~100%程度であって、その厚さTa(図10参照)は、0.5~5mm程度であることが好ましい。一方、低密度領域24’’の固化密度は70~90%程度であることが好ましい。
「造形プレート面との界面部に形成された高密度領域」の態様を図11に示す。造形プレート21と一体化した三次元形状造形物24を分離することなく製品として用いる場合、図示するように、造形プレート21と接する領域に高密度領域24’bを形成してもよい。換言すれば、三次元形状造形物を造形プレートと一体化して使用する場合、造形プレートとの接合面は強固にする必要があるので、その部分により高いエネルギーを与えて“メルティング”とすることによって接合強度を高める。かかる態様では、高密度領域24’bの固化密度は98%~100%程度であって、その厚さTb(図11参照)は、比較的薄くてよく、0.05~0.3mm程度であることが好ましい。一方、低密度領域24’’の固化密度は70~90%程度であることが好ましい。尚、三次元形状造形物を金型として用いる場合では、図11に示すように、造形プレートと接する領域24’bのみならず、金型のキャビティ空間面に相当する部分24’aにも高密度領域が形成され得る。
「セル構造またはトラス構造」の態様を図12または図13に示す。図示するように、造形プレートと一体化した三次元形状造形物を分離することなく製品として用いる場合、「表面領域の一部に形成された高密度領域a(24’a)」と「造形プレートと接する領域に形成された高密度領域b(24’b)」とが相互に接続されるように三次元形状造形物の内部領域に高密度領域c(24’c)を少なくとも1つ形成してもよい。かかる場合、高密度領域aと高密度領域cとの接合部は、外部の力に対してより強固なものとなるので、高密度領域cが補強部として機能し得る。換言すれば、図14のように、三次元形状造形物の使用時に力Pのかかる表面領域が局所的に存在する場合、その局所的な部分が高密度領域a(24’a)と高密度領域c(24’c)との接合部”となるようにする。また、図12に示すように、高密度領域c(24’c)が、金型の冷却水管壁に相当する高密度領域d(24’d)(“高密度領域d”については後述する)と接合した形態で形成される場合では、冷却水からの熱(=低熱)をより効果的に金型全体(特に、金型のキャビティ空間面)に伝えることが可能となる。
「造形物内部の一部に形成された高密度領域」の態様を図15に示す。図示するように、三次元形状造形物24の使用時に力Pのかかる内部領域にのみ高密度領域24’dが形成されている。例えば、三次元形状造形物を金型として用いる場合、内部領域の一部に形成された高密度領域24’dが金型の冷却水管壁に相当する。つまり、金型内部に冷却水を流す場合、冷却水管部分には冷却液が流れるので、液圧(冷却水の場合には“水圧”)がかかる。従って、そのような部分により高いエネルギーを与えて“メルティング”とすることによって、液漏れなどのトラブルを回避することができる。かかる態様では、高密度領域24’dの固化密度が98%~100%程度であって、その厚さTc(図15参照)は、比較的大きくすることが好ましく、2~5mm程度であることが好ましい。一方、低密度領域24’’の固化密度は70~90%程度であることが好ましい。尚、三次元形状造形物を造形プレートと一体化した金型として用いる場合、図16に示すように、造形物の内部領域24’dのみならず、「金型のキャビティ空間面に相当する部分24’a」および「造形プレートと接する領域24’b」にも高密度領域が形成されることになる。
「伝熱領域部に形成された高密度領域」の態様では、三次元形状造形物の使用時に伝熱領域部に相当する部分のみ高密度領域が形成されている。換言すれば、造形物において高温または低温の物質と接する面において熱交換を行う場合、その面部分を“メルティング”にする。高密度領域は、その強度が高いだけでなく、熱伝導率が高いので、効果的な熱効率を可能にする。例えば、高密度領域が金型の冷却水管壁24’dに相当する場合(図12参照)では、かかる高密度領域は冷却水などの圧力に耐える強度を金型に供するだけでなく、冷却水からの熱(=低熱)をより効果的に金型全体に伝えることが可能となる。
第1の態様:(i)造形プレート上に設けた粉末層の所定箇所に光ビームを照射して前記所定箇所の粉末を焼結又は溶融固化させて固化層を形成する工程、および、(ii)得られた固化層の上に新たな粉末層を形成し、前記新たな粉末層の所定箇所に光ビームを照射して更なる固化層を形成する工程を繰り返して行う三次元形状造形物の製造方法であって、
固化層を固化密度95~100%の高密度領域と固化密度0~95%(95%を含まず)の低密度領域とから成るように形成し、高密度領域が三次元形状造形物の使用時に力のかかる領域であることを特徴とする、三次元形状造形物の製造方法。
第2の態様:上記第1の態様において、前記所定箇所の粉末を完全溶融させることを通じて高密度領域を形成することを特徴とする製造方法。
第3の態様:上記第1または第2の態様において、低密度領域の固化密度が70~90%であることを特徴とする製造方法。
第4の態様:上記第1~3の態様のいずれかにおいて、高密度領域を三次元形状造形物の表面領域の一部に形成することを特徴とする製造方法。
第5の態様:上記第1~4の態様のいずれかにおいて、高密度領域を造形プレートと接する領域に形成することを特徴とする製造方法。
第6の態様:上記第1~3の態様のいずれかにおいて、高密度領域を三次元形状造形物の内部領域の一部に形成することを特徴とする製造方法。
第7の態様:上記第4の態様に従属する上記第5の態様において、表面領域の一部に形成された高密度領域aと、造形プレートと接する領域に形成された高密度領域bとが相互に接続されるように、三次元形状造形物の内部領域に高密度領域cを少なくとも1つ形成することを特徴とする製造方法。
第8の態様:上記第1~第7の態様のいずれかにおいて、三次元形状造形物の使用時に伝熱領域となる部分に高密度領域を形成することを特徴とする製造方法。
第9の態様:上記第4の態様の製造方法で得られた三次元形状造形物であって、
前記三次元形状造形物を金型として用い、前記表面領域の一部が金型のキャビティ空間を形成する面に相当することを特徴とする三次元形状造形物。
第10の態様:上記第6の態様の製造方法で得られた三次元形状造形物であって、
前記三次元形状造形物を金型として用い、前記内部領域の一部が金型の冷却水管壁に相当することを特徴とする三次元形状造形物。
第11の態様:上記第7の態様の製造方法で得られた三次元形状造形物であって、
前記三次元形状造形物を金型として用い、高密度領域aと高密度領域cとの接合部分には金型の使用時に力がかかる部分であることを特徴とする三次元形状造形物。
関連出願の相互参照
Claims (11)
- (i)造形プレート上に設けた粉末層の所定箇所に光ビームを照射して前記所定箇所の粉末を焼結又は溶融固化させて固化層を形成する工程、および
(ii)得られた固化層の上に新たな粉末層を形成し、前記新たな粉末層の所定箇所に光ビームを照射して更なる固化層を形成する工程
を繰り返して行う三次元形状造形物の製造方法であって、
固化層を固化密度95~100%の高密度領域と固化密度0~95%(95%を含まず)の低密度領域とから成るように形成し、高密度領域が三次元形状造形物の使用時に力のかかる領域であることを特徴とする、三次元形状造形物の製造方法。 - 前記所定箇所の粉末を完全溶融させることを通じて高密度領域を形成することを特徴とする、請求項1に記載の製造方法。
- 低密度領域の固化密度が70~90%であることを特徴とする、請求項1に記載の製造方法。
- 高密度領域を三次元形状造形物の表面領域の一部に形成することを特徴とする、請求項1に記載の製造方法。
- 高密度領域を造形プレートと接する領域に形成することを特徴とする、請求項1に記載の製造方法。
- 高密度領域を三次元形状造形物の内部領域の一部に形成することを特徴とする、請求項1に記載の製造方法。
- 三次元形状造形物の表面領域の一部に高密度領域aを形成すると共に、造形プレートと接する領域にも高密度領域bを形成し、
高密度領域aと高密度領域bとが相互に接続されるように、三次元形状造形物の内部領域に高密度領域cを少なくとも1つ形成することを特徴とする、請求項1に記載の製造方法。 - 三次元形状造形物の使用時に伝熱領域となる部分に高密度領域を形成することを特徴とする、請求項1に記載の製造方法。
- 請求項4に記載の製造方法で得られた三次元形状造形物であって、
前記三次元形状造形物を金型として用い、前記表面領域の一部が金型のキャビティ空間を形成する面に相当することを特徴とする、三次元形状造形物。 - 請求項6に記載の製造方法で得られた三次元形状造形物であって、
前記三次元形状造形物を金型として用い、前記内部領域の一部が金型の冷却水管壁に相当することを特徴とする、三次元形状造形物。 - 請求項7に記載の製造方法で得られた三次元形状造形物であって、
前記三次元形状造形物を金型として用い、高密度領域aと高密度領域cとの接合部分は金型の使用時に力がかかる部分であることを特徴とする、三次元形状造形物。
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|---|---|---|---|
| CN2010800091208A CN102333607B (zh) | 2009-02-24 | 2010-02-23 | 三维形状造型物的制造方法及由其得到的三维形状造型物 |
| US13/202,827 US8738166B2 (en) | 2009-02-24 | 2010-02-23 | Method for manufacturing three-dimensional shaped object and three-dimensional shaped object obtained by the same |
| KR1020117021974A KR101330977B1 (ko) | 2009-02-24 | 2010-02-23 | 삼차원 형상 조형물의 제조 방법 및 그로부터 얻어지는 삼차원 형상 조형물 |
| EP10746356.4A EP2402097A4 (en) | 2009-02-24 | 2010-02-23 | METHOD FOR PRODUCING A THREE-DIMENSIONAL FORM AND THREE-DIMENSIONAL FORM DERIVED FROM THIS METHOD |
| JP2011501688A JP5555222B2 (ja) | 2009-02-24 | 2010-02-23 | 三次元形状造形物の製造方法およびそれから得られる三次元形状造形物 |
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| JP2009-040860 | 2009-02-24 | ||
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| US (1) | US8738166B2 (ja) |
| EP (1) | EP2402097A4 (ja) |
| JP (1) | JP5555222B2 (ja) |
| KR (1) | KR101330977B1 (ja) |
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| WO (1) | WO2010098479A1 (ja) |
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| WO2016076211A1 (ja) * | 2014-11-10 | 2016-05-19 | 株式会社ブリヂストン | 立体形状物の製造方法及び立体形状物 |
| KR20170117120A (ko) * | 2015-02-11 | 2017-10-20 | 케이에스비 악티엔게젤샤프트 | 유동 부품 |
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Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5364439B2 (ja) | 2009-05-15 | 2013-12-11 | パナソニック株式会社 | 三次元形状造形物の製造方法 |
| US10000021B2 (en) * | 2009-06-23 | 2018-06-19 | Panasonic Intellectual Property Management Co., Ltd. | Method for manufacturing three-dimensional shaped object and three-dimensional shaped object obtained by the same |
| CN102574333B (zh) | 2009-10-21 | 2015-07-29 | 松下电器产业株式会社 | 三维形状造型物的制造方法及其制造装置 |
| WO2011102382A1 (ja) | 2010-02-17 | 2011-08-25 | パナソニック電工株式会社 | 三次元形状造形物の製造方法および三次元形状造形物 |
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| FR3080306B1 (fr) * | 2018-04-19 | 2021-02-19 | Michelin & Cie | Procede de fabrication additive d'une piece metallique en trois dimensions |
| DE102019217434A1 (de) * | 2019-11-12 | 2021-05-12 | Siemens Aktiengesellschaft | Verfahren zur schichtweisen additiven Herstellung eines Verbundwerkstoffs |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01502890A (ja) | 1986-10-17 | 1989-10-05 | ボード、オブ、リージェンツ、ザ、ユニバーシティー、オブ、テキサス、システム | 選択的焼結によって部品を製造する方法 |
| JPH08504139A (ja) | 1993-03-24 | 1996-05-07 | イーオーエス ゲゼルシャフト ミット ベシュレンクテル ハフツング イレクトロ オプティカル システムズ | 三次元物体作製方法 |
| JP2000073108A (ja) | 1998-08-26 | 2000-03-07 | Matsushita Electric Works Ltd | 金属粉末焼結部品の表面仕上げ方法 |
| JP2001277368A (ja) * | 2000-03-28 | 2001-10-09 | Matsushita Electric Works Ltd | 立体形状物体の造形方法 |
| JP2002322501A (ja) * | 2001-04-24 | 2002-11-08 | Matsushita Electric Works Ltd | 三次元形状造形物の製造方法および成形金型 |
| JP2004142427A (ja) * | 2002-09-30 | 2004-05-20 | Matsushita Electric Works Ltd | 三次元形状造形物の製造方法 |
| JP2008231490A (ja) * | 2007-03-19 | 2008-10-02 | Kyushu Institute Of Technology | 粉末材料を用いた積層造形法による構造体の設計方法 |
| JP2008280582A (ja) * | 2007-05-10 | 2008-11-20 | Matsushita Electric Works Ltd | 三次元形状造形物の製造方法 |
| JP2009001916A (ja) * | 2008-10-06 | 2009-01-08 | Oki Electric Ind Co Ltd | 光造形による造形方法 |
| JP2009040860A (ja) | 2007-08-08 | 2009-02-26 | Konica Minolta Holdings Inc | スクアリリウム化合物、組成物、光学フィルター、ディスプレイ用前面フィルター、及び金属キレート色素 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0615681A (ja) * | 1992-07-03 | 1994-01-25 | Mazda Motor Corp | 射出成形装置 |
| CA2296587A1 (en) * | 1997-07-21 | 1999-02-04 | Ciba Specialty Chemicals Holding Inc. | Viscosity stabilization of radiation-curable compositions |
| JP3557926B2 (ja) * | 1998-12-22 | 2004-08-25 | 松下電工株式会社 | 三次元形状造形物の製造方法および金型 |
| TW506868B (en) * | 2000-10-05 | 2002-10-21 | Matsushita Electric Works Ltd | Method of and apparatus for making a three-dimensional object |
| JP4201103B2 (ja) * | 2000-10-16 | 2008-12-24 | 三菱マテリアルPmg株式会社 | 複合部材及びその製造方法 |
| DE10065594C2 (de) * | 2000-10-30 | 2003-07-17 | Concept Laser Gmbh | Verfahren zum Herstellen von 3-dimensionalen Sinter Werkstücken |
| JP3856654B2 (ja) * | 2001-02-23 | 2006-12-13 | 松下電工株式会社 | 三次元形状造形物の製造方法 |
| DE10229952B4 (de) | 2002-07-03 | 2007-08-30 | Cl Schutzrechtsverwaltungs Gmbh | Metallisches Werkstück sowie Verfahren zur Herstellung desselben |
| DE10344902B4 (de) | 2002-09-30 | 2009-02-26 | Matsushita Electric Works, Ltd., Kadoma | Verfahren zum Herstellen eines dreidimensionalen Objekts |
| DE10344901B4 (de) * | 2002-09-30 | 2006-09-07 | Matsushita Electric Works, Ltd., Kadoma | Verfahren zum Herstellen eines dreidimensionalen gesinterten Produkts |
| US7232850B2 (en) * | 2003-10-03 | 2007-06-19 | Huntsman Advanced Materials Americas Inc. | Photocurable compositions for articles having stable tensile properties |
| JP4487636B2 (ja) * | 2004-05-26 | 2010-06-23 | パナソニック電工株式会社 | 三次元形状造形物の製造方法 |
| BRPI0607442A2 (pt) * | 2005-03-11 | 2017-05-16 | Howmet Corp | matriz formadora de vidro e métodos de fazer uma matriz formadora de vidro e de remover calor de uma matriz formadora de vidro |
| JP4889266B2 (ja) * | 2005-09-05 | 2012-03-07 | パナソニック株式会社 | 3次元形状造形物およびその製造方法 |
| EP1949989B1 (en) | 2005-11-15 | 2012-01-11 | Panasonic Electric Works Co., Ltd. | Process for producing three-dimensionally shaped object |
| EP2001656B1 (en) * | 2006-04-06 | 2014-10-15 | 3D Systems Incorporated | KiT FOR THE PRODUCTION OF THREE-DIMENSIONAL OBJECTS BY USE OF ELECTROMAGNETIC RADIATION |
| US7614866B2 (en) * | 2007-01-17 | 2009-11-10 | 3D Systems, Inc. | Solid imaging apparatus and method |
| JP2010121187A (ja) * | 2008-11-20 | 2010-06-03 | Panasonic Electric Works Co Ltd | 三次元造形物及びその製造方法 |
-
2010
- 2010-02-23 KR KR1020117021974A patent/KR101330977B1/ko not_active Expired - Fee Related
- 2010-02-23 WO PCT/JP2010/053188 patent/WO2010098479A1/ja not_active Ceased
- 2010-02-23 CN CN2010800091208A patent/CN102333607B/zh not_active Expired - Fee Related
- 2010-02-23 EP EP10746356.4A patent/EP2402097A4/en not_active Withdrawn
- 2010-02-23 US US13/202,827 patent/US8738166B2/en not_active Expired - Fee Related
- 2010-02-23 JP JP2011501688A patent/JP5555222B2/ja active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01502890A (ja) | 1986-10-17 | 1989-10-05 | ボード、オブ、リージェンツ、ザ、ユニバーシティー、オブ、テキサス、システム | 選択的焼結によって部品を製造する方法 |
| JPH08504139A (ja) | 1993-03-24 | 1996-05-07 | イーオーエス ゲゼルシャフト ミット ベシュレンクテル ハフツング イレクトロ オプティカル システムズ | 三次元物体作製方法 |
| JP2000073108A (ja) | 1998-08-26 | 2000-03-07 | Matsushita Electric Works Ltd | 金属粉末焼結部品の表面仕上げ方法 |
| JP2001277368A (ja) * | 2000-03-28 | 2001-10-09 | Matsushita Electric Works Ltd | 立体形状物体の造形方法 |
| JP2002322501A (ja) * | 2001-04-24 | 2002-11-08 | Matsushita Electric Works Ltd | 三次元形状造形物の製造方法および成形金型 |
| JP2004142427A (ja) * | 2002-09-30 | 2004-05-20 | Matsushita Electric Works Ltd | 三次元形状造形物の製造方法 |
| JP2008231490A (ja) * | 2007-03-19 | 2008-10-02 | Kyushu Institute Of Technology | 粉末材料を用いた積層造形法による構造体の設計方法 |
| JP2008280582A (ja) * | 2007-05-10 | 2008-11-20 | Matsushita Electric Works Ltd | 三次元形状造形物の製造方法 |
| JP2009040860A (ja) | 2007-08-08 | 2009-02-26 | Konica Minolta Holdings Inc | スクアリリウム化合物、組成物、光学フィルター、ディスプレイ用前面フィルター、及び金属キレート色素 |
| JP2009001916A (ja) * | 2008-10-06 | 2009-01-08 | Oki Electric Ind Co Ltd | 光造形による造形方法 |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP2402097A4 |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015124395A (ja) * | 2013-12-25 | 2015-07-06 | トヨタ自動車株式会社 | 三次元形状造形物の製造方法 |
| WO2016076211A1 (ja) * | 2014-11-10 | 2016-05-19 | 株式会社ブリヂストン | 立体形状物の製造方法及び立体形状物 |
| JP2016089247A (ja) * | 2014-11-10 | 2016-05-23 | 株式会社ブリヂストン | 立体形状物の製造方法及びタイヤ金型 |
| CN107073822A (zh) * | 2014-11-10 | 2017-08-18 | 株式会社普利司通 | 三维物体的制造方法以及三维物体 |
| CN107073822B (zh) * | 2014-11-10 | 2019-12-27 | 株式会社普利司通 | 三维物体的制造方法以及三维物体 |
| KR20170117120A (ko) * | 2015-02-11 | 2017-10-20 | 케이에스비 악티엔게젤샤프트 | 유동 부품 |
| JP2018506647A (ja) * | 2015-02-11 | 2018-03-08 | カーエスベー・アクチエンゲゼルシャフトKsb Aktiengesellschaft | 流導コンポーネント |
| KR102420522B1 (ko) * | 2015-02-11 | 2022-07-13 | 케이에스비 에스이 앤드 코. 카게아아 | 유동 부품 |
| US11033966B2 (en) | 2015-02-11 | 2021-06-15 | Ksb Aktiengesellschaft | Flow-conducting component |
| US10898953B2 (en) | 2016-03-09 | 2021-01-26 | Panasonic Intellectual Property Management Co., Ltd. | Method for manufacturing three-dimensional shaped object |
| KR20180110075A (ko) * | 2016-03-09 | 2018-10-08 | 파나소닉 아이피 매니지먼트 가부시키가이샤 | 3차원 형상 조형물의 제조 방법 |
| KR102277612B1 (ko) * | 2016-03-09 | 2021-07-14 | 파나소닉 아이피 매니지먼트 가부시키가이샤 | 3차원 형상 조형물의 제조 방법 |
| WO2018097157A1 (ja) * | 2016-11-28 | 2018-05-31 | 東レエンジニアリング株式会社 | 立体造形方法 |
| JP2020084195A (ja) * | 2018-11-14 | 2020-06-04 | 株式会社ジェイテクト | 付加製造装置、付加製造方法及び付加製造物 |
| JP2021011615A (ja) * | 2019-07-08 | 2021-02-04 | 櫻護謨株式会社 | 金属成形品、リブ構造および金属成形品の製造方法 |
| WO2021172331A1 (ja) * | 2020-02-27 | 2021-09-02 | 三菱重工業株式会社 | 熱交換コア、熱交換器及び熱交換コアの製造方法 |
| JP2021135038A (ja) * | 2020-02-27 | 2021-09-13 | 三菱重工業株式会社 | 熱交換コア、熱交換器及び熱交換コアの製造方法 |
| JP2021134986A (ja) * | 2020-02-27 | 2021-09-13 | 三菱重工業株式会社 | 熱交換コア及び熱交換コアの製造方法 |
| JP7437971B2 (ja) | 2020-02-27 | 2024-02-26 | 三菱重工業株式会社 | 熱交換コアの製造方法 |
| JP7568540B2 (ja) | 2020-02-27 | 2024-10-16 | 三菱重工業株式会社 | 熱交換コア、熱交換器及び熱交換コアの製造方法 |
| US12345475B2 (en) | 2020-02-27 | 2025-07-01 | Mitsubishi Heavy Industries, Ltd. | Heat exchanger core, heat exchanger, and method of producing heat exchanger core |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2402097A4 (en) | 2014-04-09 |
| JP5555222B2 (ja) | 2014-07-23 |
| US20120041586A1 (en) | 2012-02-16 |
| EP2402097A1 (en) | 2012-01-04 |
| JPWO2010098479A1 (ja) | 2012-09-06 |
| KR20110122195A (ko) | 2011-11-09 |
| CN102333607B (zh) | 2013-10-09 |
| CN102333607A (zh) | 2012-01-25 |
| US8738166B2 (en) | 2014-05-27 |
| KR101330977B1 (ko) | 2013-11-18 |
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