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WO2010090354A1 - Epaississant pour la production de détergents solides - Google Patents

Epaississant pour la production de détergents solides Download PDF

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Publication number
WO2010090354A1
WO2010090354A1 PCT/JP2010/052237 JP2010052237W WO2010090354A1 WO 2010090354 A1 WO2010090354 A1 WO 2010090354A1 JP 2010052237 W JP2010052237 W JP 2010052237W WO 2010090354 A1 WO2010090354 A1 WO 2010090354A1
Authority
WO
WIPO (PCT)
Prior art keywords
solid detergent
thickener
detergent composition
producing
mass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2010/052237
Other languages
English (en)
Japanese (ja)
Inventor
斎藤景太郎
吉田尚
池田直哲
服部達也
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Priority to CN2010800078699A priority Critical patent/CN102307980A/zh
Priority to JP2010549552A priority patent/JPWO2010090354A1/ja
Publication of WO2010090354A1 publication Critical patent/WO2010090354A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides

Definitions

  • the present invention relates to a thickener for producing a solid detergent and a solid detergent composition.
  • the frame kneading method was a method used as a method for producing a solid detergent composition having a higher fatty acid as a main component, particularly a transparent solid detergent.
  • the method is as follows: 1) Pour higher fatty acid salt, water, glycerin, sugar, polyhydric alcohol such as sorbitol, and lower monohydric alcohol such as ethanol into the main frame 2) Cut and mold after cooling and solidification 3) Next, a process of volatilizing the volatile components and aging to a certain amount was performed.
  • JP-A-63-275700 triethanolamine is used as a neutralizing agent, so that it is used only for extremely limited applications due to the problem of oxidative deterioration and yellowing due to long-term storage. could not.
  • the mechanical kneading method has also been an old method used as a method for producing a solid detergent composition mainly composed of higher fatty acids and / or synthetic surfactants.
  • the main cleaning component is acylamino acid salt, but it has excellent detergency in hard water, its pH is weakly acidic and less irritating to the skin. It has come to be widely used because it gives the skin a moist feeling.
  • solid detergent compositions containing acyl amino acid salts, especially acyl acidic amino acid salts have higher alcohols such as cetanol as an essential component to improve their difficult processability, but still have other physical properties, particularly prevention of melting and collapsing. It was a big issue.
  • the object of the present invention is to provide a solid detergent composition that can increase hardness without impairing foaming and prevent melting and collapse, and a transparent solid detergent composition does not require a lower monohydric alcohol and does not require an aging step.
  • the present invention provides a simple cleaning method and a solid detergent composition having improved transparency and durability (transparency with time).
  • the above-mentioned solid detergent is obtained by using an acylamino acid amide gelling agent and a thickener for producing a solid detergent containing a polyhydric alcohol and / or a higher alcohol.
  • the present inventors have found that a composition can be provided and have completed the present invention. That is, the present invention includes the following aspects.
  • a thickener for producing a solid detergent comprising a gelling agent and a polyhydric alcohol and / or a higher alcohol.
  • the solid detergent composition according to [6] which contains 25 to 40% by mass of water based on the total amount of the solid detergent composition.
  • a step of dissolving a higher fatty acid or a salt thereof by heating A step of adding the thickener for producing a solid detergent according to [1] to [5] and stirring with heating; Cooling step; The manufacturing method of the solid cleaning composition containing this.
  • the thickener for producing a solid detergent of the present invention contains a gelling agent and a polyhydric alcohol and / or a higher alcohol.
  • the gelling agent used in the thickener of the present invention is not particularly limited as long as it has the ability to harden oil to form a gel, but specifically, aromatic aldehydes such as benzylidene sorbitol and many others.
  • a condensate of a monohydric alcohol a condensate of a higher fatty acid with a polyhydric alcohol, a saccharide, such as behenic acid / glycosyl eicosandioate, behenic acid / polyglyceryl eicosandioate, dextrin palmitate, inulin stearate; lauroylglutamic acid dibutylamide, Examples include acylamino acid amides such as 2-ethylhexanoylglutamic acid dibutylamide, dioctanoyllysine amide, dioctanoyllysine 2-ethylhexylamide; acylamino acid esters such as lauroylglutamine ethyl ester; and peptide derivatives.
  • acylamino acid amides and acylamino acid esters are preferred.
  • Lauroyl glutamic acid dibutylamide, 2-ethylhexanoyl glutamic acid dibutylamide, lauroyl glutamine ethyl ester, dioctanoyl lysine amide, dioctyl Octanoyl lysine 2-ethylhexylamide is more preferable, lauroyl glutamic acid dibutylamide, 2-ethylhexanoyl glutamic acid dibutylamide, lauroyl glutamine ethyl ester, dioctanoyl lysine 2-ethylhexylamide is more preferable, lauroyl glutamic acid dibutylamide, 2-ethyl Hexanoyl glutamic acid dibutylamide is even more
  • a mixture of lauroyl glutamic acid dibutylamide and 2-ethylhexyl glutamic acid dibutylamide (mass mixing ratio 2: 8 to 8: 2) is particularly preferable from the viewpoint that transparency and strength of the product can be imparted.
  • polyhydric alcohol used in the thickener of the present invention examples include ethylene glycol, diethylene glycol, glycerin, propylene glycol, dipropylene glycol, erythritol, 1,3-butylene glycol, pentaerythritol, neopentyl glycol, 1,2- Pentanediol, 1,2-hexanediol, 1,6-hexanediol, 1,2,6-hexanetriol, 1,2-octanediol and the like can be mentioned. These may be used alone or in combination of two or more.
  • ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, neopentyl glycol, 1,2-pentanediol 1,2-hexanediol, 1,2-octanediol are preferred, propylene glycol, dipropylene glycol, 1,3-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octane Diol is more preferable, and propylene glycol, 1,3-butylene glycol, 1,2-pentanediol, and 1,2-hexanediol are still more preferable.
  • propylene glycol and 1,3-butylene glycol are particularly preferable.
  • a linear or branched monohydric alcohol having 8 to 30 carbon atoms can be used.
  • octanol, decanol, dodecanol, cetanol, stearyl Examples include alcohol, isostearyl alcohol, octyldodecanol, and behenyl alcohol. These may be used alone or in combination of two or more.
  • Octanol, decanol, dodecanol, cetanol, isostearyl alcohol, octyldodecanol are preferred, and dodecanol, cetanol, isostearyl alcohol, octyldodecanol from the viewpoint that a thickener capable of exhibiting an effective thickening effect can be obtained in a small amount.
  • cetanol, isostearyl alcohol, and octyldodecanol are still more preferable. From the viewpoint of improving foam quality, cetanol is particularly preferable.
  • the polyhydric alcohol and higher alcohol used in the thickener of the present invention may be used separately or in combination.
  • polyhydric alcohols are preferable, propylene glycol, 1,3-butylene glycol, 1,2-pentanediol, 1,2-hexanediol are more preferable, propylene glycol, 1,3-butylene glycol is more preferred.
  • the blending amount of the gelling agent used in the thickener of the present invention is not particularly limited as long as the thickener obtained by completely dissolving the gelling agent maintains effective thickening. From the viewpoint that effective thickening can be exhibited, the range of 1 to 30% by mass with respect to the total weight of the thickening agent is preferable.
  • the blending amount When the blending amount is lower than 1% by mass, the thickening effect of the obtained thickener tends to be poor, and when the blending amount is larger than 30% by mass, the obtained thickener is obtained. Although there is a thickening effect, the solubility tends to be poor.
  • the lower limit of the blending amount of the gelling agent with respect to the total mass of the gelling agent, polyhydric alcohol and higher alcohol is determined to be completely dissolved at a relatively low temperature in the frame kneading method. From the viewpoint that it is preferable that it is possible to maintain the effective thickening of the obtained thickener, 5% by mass is more preferable, 10% by mass is further preferable, and 15% by mass is even more preferable.
  • the upper limit of the amount of the gelling agent relative to the total mass of the gelling agent, polyhydric alcohol and higher alcohol is 25% by mass from the viewpoint that the effective thickening of the obtained thickener can be maintained and the solubility can be secured. Is more preferable, and 20 mass% is still more preferable.
  • the thickener of the present invention can be produced by heating and cooling the gelling agent until it is completely dissolved in the polyhydric alcohol and / or higher alcohol. The heating temperature is 95 ° C to 130 ° C. At the time of cooling, it can be commercialized as it is by filling the product container and cooling.
  • the resulting thickener is in the form of a gel, and can be commercialized by crushing, crushing, and crushing to a size that is easy to handle, such as pellets, cubes, and spheres.
  • the dissolution temperature of the resulting thickener is 40 ° C to 110 ° C. In the frame kneading method, it is required to be completely dissolved at a relatively low temperature. Therefore, it is preferable that the solution can be dissolved below the boiling point of water, and from the viewpoint that a transparent solid detergent composition can be produced, 70 ° C. ⁇ 95 ° C is preferred, 80 ° C to 95 ° C is more preferred, and 85 ° C to 95 ° C is even more preferred.
  • the thickener of the present invention can produce a transparent solid detergent composition even when a lower monohydric alcohol is not used by using a frame kneading method together with a higher fatty acid or a salt thereof.
  • the thickener of the present invention and a higher fatty acid or a salt thereof can be dissolved by heating and cooling.
  • the higher fatty acid or salt thereof used in the solid detergent composition by the frame kneading method of the present invention is not particularly limited as long as it forms a solid detergent composition.
  • a straight chain or branched chain higher fatty acid having 8 to 22 carbon atoms or a salt thereof can be used.
  • lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, linoleic acid examples include behenic acid, coconut oil fatty acid, and palm oil fatty acid. These may be used alone or in combination of two or more.
  • the salt used include sodium salts, potassium salts, basic amino acid salts such as lysine and arginine, and the like. These may be used alone or in combination of two or more.
  • the heating temperature is preferably lower than the boiling point of water, and is 40 ° C to 95 ° C.
  • a transparent solid detergent composition is preferably 70 ° C to 95 ° C, more preferably 80 ° C to 95 ° C, and still more preferably 85 ° C to 95 ° C.
  • the cooling temperature is not particularly limited as long as a solid detergent composition can be prepared, and is 50 ° C. or lower, preferably 40 ° C. or lower.
  • the blending amount of the thickener for producing the solid detergent of the present invention can be 0.05 to 3.0% by mass with respect to the total amount of the solid detergent composition. If it is less than 0.05% by mass, sufficient soap strength cannot be imparted, and if it exceeds 3.0% by mass, strength can be imparted, but foaming may be inhibited.
  • the solid detergent composition by the frame kneading method of the present invention preferably contains water from the viewpoint of foaming and foam quality.
  • the water content is not particularly limited as long as it forms a solid detergent composition, but the lower limit of the water content (% by mass) relative to the total mass of the solid detergent composition is good foaming and foam quality. From the viewpoint that it can be retained, it is preferably 5 or more, more preferably 10 or more, still more preferably 15 or more, still more preferably 20 or more, particularly preferably 25 or more, and particularly preferably 30 or more.
  • the upper limit of the content (% by mass) of water relative to the total mass of the solid detergent composition is preferably 60 or less, and 55 or less, from the viewpoint of maintaining good foaming and foam quality while maintaining the molded state. More preferably, it is more preferably 50 or less, still more preferably 45 or less, still more preferably 40 or less, and particularly preferably 35 or less.
  • the solid detergent composition may contain an optional component that is usually used for the solid detergent within a range not impairing the above-described action. For example, hydrocarbon oil, silicone oil, ester oil, higher alcohol, nonionic surfactant, anionic surfactant, amphoteric surfactant, moisturizer, powder, chelating agent, antioxidant, preservative, and fragrance It is done.
  • a solid detergent composition can be produced by using a mechanical kneading method with the surfactant of the present invention together with a surfactant. Specifically, it can be produced by kneading the thickener of the present invention and a surfactant.
  • the surfactant used in the solid detergent composition by the mechanical kneading method of the present invention is not particularly limited as long as it forms a solid detergent composition.
  • acyl amino acid salts such as lauroyl glutamate, lauroyl glycine salt, lauroyl alanine salt, lauroyl threonine salt, cocoyl glutamate, cocoyl glycine salt, cocoyl alanine salt, cocoyl threonine salt, acyl isethione sun salt, alkane Examples include sulfonates, ⁇ -olefin sulfonates, alkylsulfosuccinates, alkyl sulfates, and alkyl ether sulfates. These may be used alone or in combination of two or more.
  • Examples of the salt used include sodium salts, potassium salts, basic amino acid salts such as lysine and arginine, and the like. These may be used alone or in combination of two or more. Acyl amino acid salts are preferable from the viewpoint of having an assimilation property and providing a good feel.
  • the temperature at the time of kneading is not particularly limited as long as the solid detergent composition can be produced, but is preferably in the range of 10 to 100 ° C.
  • a solid detergent composition can be obtained with or without dissolving the thickener.
  • the blending amount of the thickener for producing the solid detergent of the present invention can be 0.05 to 3.0% by mass with respect to the total amount of the solid detergent composition. If it is less than 0.05% by mass, sufficient soap strength cannot be imparted, and if it exceeds 3.0% by mass, strength can be imparted, but foaming may be inhibited. From the viewpoint of imparting sufficient strength, 0.5% by mass or more is preferable, and 0.7% by mass or more is more preferable.
  • the solid detergent composition by the mechanical kneading method of the present invention preferably contains water from the viewpoint of foaming and foam quality.
  • the water content is not particularly limited as long as it forms a solid detergent composition, but the lower limit of the water content (% by mass) relative to the total mass of the solid detergent composition is good foaming and foam quality. From the viewpoint that it can be retained, it is preferably 5 or more, more preferably 10 or more, still more preferably 15 or more, still more preferably 20 or more, particularly preferably 25 or more, and particularly preferably 30 or more.
  • the upper limit of the content (% by mass) of water relative to the total mass of the solid detergent composition is preferably 60 or less, and preferably 55 or less, from the viewpoint of maintaining good foaming and foam quality while maintaining the molded state.
  • the solid detergent composition of the present invention may contain an optional component that is usually used for a solid detergent within a range that does not impair the above-described action.
  • examples include hydrocarbon oils, silicone oils, ester oils, higher alcohols, nonionic surfactants, anionic surfactants, amphoteric surfactants, moisturizers, powders, chelating agents, antioxidants, preservatives, and fragrances. It is done.
  • the kneading machine to be used is not particularly limited as long as it is usually used, and examples thereof include a three-roll kneader, a kneading extruder, and a twin-screw kneading extruder.
  • Examples 1 to 4 Preparation of a frame kneading method solid detergent composition Among the components shown in Table 3, the components other than the thickener and the gelling agent were dissolved by heating at 85 ° C. Then, a thickener or a gelling agent was added thereto (in the comparative example 1, a gelling agent was added, in the comparative example 2, not added), and after stirring and heating at 85 ° C. for 30 minutes, a cylindrical frame having a diameter of 40 mm 20 g was poured into several pieces, cooled to 25 ° C., and then removed from the frame to prepare a solid detergent composition.
  • sample means “20 g-unit columnar solid detergent composition”.
  • sample means “20 g-unit columnar solid detergent composition”.
  • Examples 1 to 4 were remarkably superior in ease of detachment from the mold, hardness, transparency, and unraveling property.
  • Comparative Example 1 in which the solid gelling agent is added separately, the gelling agent remains undissolved due to the aqueous system even when heated to 95 ° C., and therefore, it is unsatisfactory below or equal to Comparative Example 2 on any evaluation axis. Stayed in results.
  • Table 3 it is clear from the results in Table 3 that a soap having excellent ease of removal, hardness, transparency, and unbreakability could be obtained without using ethanol.
  • Example 5 Preparation of mechanical kneading method solid detergent composition
  • the total amount of the blended formulation shown in Table 4 was roughly mixed by passing it through a three-roll kneader (manufactured by Nippon Kakko) three times at room temperature, Next, a kneader-extruder (manufactured by Nippon Kako) was passed three times at 45 ° C. to obtain a rod-shaped molded product having a diameter of about 40 mm. About 70 mm each was stamped into a size of 50 mm ⁇ 40 mm ⁇ 15 mm with a molding machine (manufactured by Nippon Kako) to obtain several solid detergent compositions.
  • the “sample” means a stamped “solid detergent composition in units of 50 mm ⁇ 40 mm ⁇ 15 mm”.
  • Hardness was measured using a rheometer (Fudo: NRM-2010J-CW) at 25 ° C. and a moving speed of 6 cm / min with a 1 mm diameter needle entering the sample and measuring the load (kg) when entering 3 mm. ⁇ when the strength is 1.4 kg or more, ⁇ when the strength is 1.1 kg or more and less than 1.4 kg, ⁇ when the strength is 0.8 kg or more and less than 1.1 kg, and x when it is less than 0.8 kg.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition de détergent solide, dont la dureté est améliorée sans altération des propriétés de moussage, et qui ne s'émiette pas ni ne se dissout; la production d'un détergent solide transparent par un procédé simple qui peut se passer d'étape de vieillissement; et un détergent solide transparent qui présente une transparence améliorée pendant une longue durée. La composition de détergent solide peut être produite en utilisant un épaississant pour la production de détergents solides qui contient un agent gélifiant de type amide d'acylamino acide, et un alcool polyhydrique et/ou un alcool supérieur.
PCT/JP2010/052237 2009-02-09 2010-02-09 Epaississant pour la production de détergents solides Ceased WO2010090354A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2010800078699A CN102307980A (zh) 2009-02-09 2010-02-09 制造固体清洗剂用增稠剂
JP2010549552A JPWO2010090354A1 (ja) 2009-02-09 2010-02-09 固形洗浄剤製造用増粘剤

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2009-026926 2009-02-09
JP2009026926 2009-02-09

Publications (1)

Publication Number Publication Date
WO2010090354A1 true WO2010090354A1 (fr) 2010-08-12

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PCT/JP2010/052237 Ceased WO2010090354A1 (fr) 2009-02-09 2010-02-09 Epaississant pour la production de détergents solides

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JP (1) JPWO2010090354A1 (fr)
CN (1) CN102307980A (fr)
WO (1) WO2010090354A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014529675A (ja) * 2011-09-13 2014-11-13 ザ プロクター アンド ギャンブルカンパニー 安定な水溶性単位用量物品
JP2016034923A (ja) * 2014-08-04 2016-03-17 アサヌマ コーポレーション株式会社 皮膚洗浄剤組成物
JP2017214314A (ja) * 2016-05-31 2017-12-07 味の素株式会社 ゲル状組成物
WO2018198523A1 (fr) * 2017-04-28 2018-11-01 味の素株式会社 Dérivé d'acide n-acylamino
JP2020029408A (ja) * 2018-08-20 2020-02-27 日本エマルジョン株式会社 水性固形化粧料または外用剤、およびその製造方法
JP2021529212A (ja) * 2018-08-14 2021-10-28 トス． ベントレー アンド サン リミテッドＴｈｏｓ． Ｂｅｎｔｌｅｙ ＆ Ｓｏｎ Ｌｉｍｉｔｅｄ 個人用クレンジング組成物（ｐｅｒｓｏｎａｌ ｃｌｅａｎｓｉｎｇ ｃｏｍｐｏｓｉｔｉｏｎｓ）の製造に関する改善
US12274768B2 (en) 2021-09-24 2025-04-15 Amorepacific Corporation Cleaner base, cleaning composition including the same, and method of preparing the cleaning composition

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JPH0734100A (ja) * 1993-07-21 1995-02-03 Kao Corp 固形洗浄剤組成物
JP2001064691A (ja) * 1999-08-31 2001-03-13 Tsumura & Co 洗浄剤組成物
JP2002114994A (ja) * 2000-10-06 2002-04-16 Kao Corp 機械練り石鹸組成物
JP2002316971A (ja) * 2001-02-13 2002-10-31 Ajinomoto Co Inc 油性基剤のゲル化剤
JP2005298635A (ja) * 2004-04-09 2005-10-27 Shiseido Co Ltd ゲル状組成物及びその製造方法
JP2006525969A (ja) * 2003-05-10 2006-11-16 ユニリーバー・ナームローゼ・ベンノートシヤープ スティック組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0734100A (ja) * 1993-07-21 1995-02-03 Kao Corp 固形洗浄剤組成物
JP2001064691A (ja) * 1999-08-31 2001-03-13 Tsumura & Co 洗浄剤組成物
JP2002114994A (ja) * 2000-10-06 2002-04-16 Kao Corp 機械練り石鹸組成物
JP2002316971A (ja) * 2001-02-13 2002-10-31 Ajinomoto Co Inc 油性基剤のゲル化剤
JP2006525969A (ja) * 2003-05-10 2006-11-16 ユニリーバー・ナームローゼ・ベンノートシヤープ スティック組成物
JP2005298635A (ja) * 2004-04-09 2005-10-27 Shiseido Co Ltd ゲル状組成物及びその製造方法

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014529675A (ja) * 2011-09-13 2014-11-13 ザ プロクター アンド ギャンブルカンパニー 安定な水溶性単位用量物品
JP2016034923A (ja) * 2014-08-04 2016-03-17 アサヌマ コーポレーション株式会社 皮膚洗浄剤組成物
JP2017214314A (ja) * 2016-05-31 2017-12-07 味の素株式会社 ゲル状組成物
WO2018198523A1 (fr) * 2017-04-28 2018-11-01 味の素株式会社 Dérivé d'acide n-acylamino
JP2021529212A (ja) * 2018-08-14 2021-10-28 トス． ベントレー アンド サン リミテッドＴｈｏｓ． Ｂｅｎｔｌｅｙ ＆ Ｓｏｎ Ｌｉｍｉｔｅｄ 個人用クレンジング組成物（ｐｅｒｓｏｎａｌ ｃｌｅａｎｓｉｎｇ ｃｏｍｐｏｓｉｔｉｏｎｓ）の製造に関する改善
JP7138236B2 (ja) 2018-08-14 2022-09-15 トス． ベントレー アンド サン リミテッド 個人用クレンジング組成物（ｐｅｒｓｏｎａｌ ｃｌｅａｎｓｉｎｇ ｃｏｍｐｏｓｉｔｉｏｎｓ）の製造に関する改善
US11446216B2 (en) 2018-08-14 2022-09-20 Thos. Bentley & Son Limited Relation to the manufacture of personal cleansing compositions
JP2020029408A (ja) * 2018-08-20 2020-02-27 日本エマルジョン株式会社 水性固形化粧料または外用剤、およびその製造方法
JP7066181B2 (ja) 2018-08-20 2022-05-13 日本エマルジョン株式会社 固形化粧料、およびその製造方法
US12274768B2 (en) 2021-09-24 2025-04-15 Amorepacific Corporation Cleaner base, cleaning composition including the same, and method of preparing the cleaning composition

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Publication number Publication date
JPWO2010090354A1 (ja) 2012-08-09
CN102307980A (zh) 2012-01-04

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