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WO2009102019A1 - Composition antioxydante pour matière première - Google Patents

Composition antioxydante pour matière première Download PDF

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Publication number
WO2009102019A1
WO2009102019A1 PCT/JP2009/052411 JP2009052411W WO2009102019A1 WO 2009102019 A1 WO2009102019 A1 WO 2009102019A1 JP 2009052411 W JP2009052411 W JP 2009052411W WO 2009102019 A1 WO2009102019 A1 WO 2009102019A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
feed raw
antioxidant
antioxidant composition
scum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2009/052411
Other languages
English (en)
Japanese (ja)
Inventor
Naohiro Gotoh
Shun Wada
Atsushi Tsunoda
Hai Meng Tan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo University of Marine Science and Technology NUC
University of Tokyo NUC
KEMIN JAPAN KK
Original Assignee
Tokyo University of Marine Science and Technology NUC
University of Tokyo NUC
KEMIN JAPAN KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo University of Marine Science and Technology NUC, University of Tokyo NUC, KEMIN JAPAN KK filed Critical Tokyo University of Marine Science and Technology NUC
Priority to JP2009553462A priority Critical patent/JP5429750B2/ja
Publication of WO2009102019A1 publication Critical patent/WO2009102019A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/10—Organic substances
    • A23K20/158—Fatty acids; Fats; Products containing oils or fats
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K10/00—Animal feeding-stuffs
    • A23K10/20—Animal feeding-stuffs from material of animal origin
    • A23K10/22—Animal feeding-stuffs from material of animal origin from fish
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K10/00—Animal feeding-stuffs
    • A23K10/30—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms
    • A23K10/37—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms from waste material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/80—Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
    • Y02P60/87—Re-use of by-products of food processing for fodder production

Definitions

  • the present invention relates to an antioxidant technology for feed raw materials, and more particularly to an antioxidant composition for effectively and safely preventing oxidation of feed raw materials such as fish meal.
  • Fish meal such as brown meal made from colored fish such as salmon, anchovies, salmon, salmon, salmon, or white meal based on white fish such as salmon or salmon, such as lysine, methionine, and mistin, are important for feed. Since it contains abundant amino acids and proteins, it has been widely used as a feed material for livestock, poultry, fish farming or pet food.
  • Such fish meal as a feed material is usually distributed in a state where a specific antioxidant is added because fish oil contained in fish meal is about 8% relatively easily oxidized.
  • Fish meal to which antioxidants have not been added is not only subject to oxidative degradation during distribution and storage, but also under certain conditions such as when the ocean is transported by the ocean or during storage at relatively high temperatures. In addition, there is a risk of fire due to oxidation heat.
  • ethoxyquin (6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline) has been used as an antioxidant to prevent oxidation of such feed materials.
  • Ethoxyn as a synthetic antioxidant itself is a drug with excellent antioxidant capacity.
  • a certain reference amount 150 ppm or less
  • conventional synthetic antioxidants are not always satisfactory from the viewpoints of the safety of feed materials for pets and the safety of human bodies through meat such as livestock and fish farming, and they are replaced by ethoxynes.
  • antioxidants are not always sufficient in terms of long-term sustainability of the antioxidant effect on feed materials from the viewpoint of practicality, and are not satisfactory in terms of production cost.
  • natural product-derived tocopherol (vitamin E) itself is known to have antioxidant ability and its purification method is also known (see, for example, JP-A-60-149582). ), Refined tocopherol is expensive and it is not practical to apply it to feed ingredients.
  • An object of the present invention is to provide a safe and inexpensive antioxidant composition which can be produced from a relatively inexpensive raw material derived from a natural product and is excellent in the antioxidant effect of a feed raw material.
  • the antioxidant composition for feed raw materials according to the present invention includes scum generated in the process of producing vegetable oil, an oil-soluble electron donor component, and a liquid oil derived from plants as a viscosity reducing agent. It is characterized by comprising.
  • the scum is selected from the group consisting of soybean oil, rapeseed oil, rice oil, sesame oil, perilla oil, sesame oil, coconut oil, cottonseed oil, sunflower oil, corn oil, bean flower oil and palm oil.
  • the oil-soluble electron donor component is lecithin
  • the plant-derived liquid oil is soy sauce oil, soybean oil, rapeseed oil, It consists of at least one selected from the group consisting of sesame oil, perilla oil, cottonseed oil, sunflower oil, corn oil, benflower oil, salad oil, and MCT.
  • the blending ratio of the scum, the oil-soluble electron donor component, and the plant-derived liquid oil is Scum: 10-60 parts by weight, Oil-soluble electron donor component: 1 to 45 parts by weight, and plant-derived liquid oil: 10 to 90 parts by weight.
  • the viscosity of the composition according to the present invention is in the range of 0.1 dPa ⁇ s to 1.0 dPa ⁇ s.
  • the present invention includes a feed raw material antioxidant method comprising spraying or spraying the above antioxidant composition onto a feed raw material.
  • the present invention includes a method for producing a feed raw material excellent in antioxidant property comprising spraying or spraying the above antioxidant composition to a feed raw material, and fish meal as a feed raw material containing the antioxidant composition. To do.
  • the scum produced in the process of producing edible vegetable oil is effectively used, and the antioxidant composition is constituted by combining it with an oil-soluble electron donor component and a plant-derived liquid oil. It is possible to provide an antioxidant composition for feed raw materials that can be replaced by conventional synthetic ethoxynes and has excellent safety and anti-oxidation ability at low cost, and is extremely useful in the food industry.
  • the graph which shows the experimental result of the Example of this invention and a comparative example The graph which shows the experimental result of the Example of this invention and a comparative example.
  • the graph which shows the experimental result of the Example of this invention and a comparative example The graph which shows the experimental result of the Example of this invention and a comparative example.
  • the graph which shows the experimental result of the Example of this invention and a comparative example The graph which shows the experimental result of the Example of this invention and a comparative example.
  • the graph which shows the experimental result of the Example of this invention and a comparative example The graph which shows the experimental result of the Example of this invention and a comparative example.
  • the graph which shows the experimental result of the Example of this invention and a comparative example The graph which shows the experimental result of the Example of this invention and a comparative example.
  • the graph which shows the experimental result of the Example of this invention and a comparative example The graph which shows the experimental result of the Example of this invention and a comparative example.
  • the antioxidant composition for feed raw materials according to the present invention comprises scum generated in the process of producing vegetable oil, an oil-soluble electron donor component, and a plant-derived liquid oil as a viscosity reducing agent. It is what. Hereinafter, the components of the present invention will be described.
  • scum produced in the process of producing vegetable oil is used as a component having antioxidant ability.
  • Such scum is a refined residue produced as a by-product in the production process of edible vegetable oil, such as soybean oil, rapeseed oil, rice oil, sesame oil, perilla oil, sesame oil, coconut oil, cottonseed oil, sunflower oil, corn oil, It means deodorizing scum generated in the process of producing edible vegetable oils such as flower oil and palm oil.
  • refined oil is usually produced from soybean crude oil through a degumming step, a drying step, a decoloring step, a dewaxing step, and a deodorizing step, and this occurs during the deodorizing step.
  • Scum deodorized scum
  • the deodorized scum produced as a by-product in this way consists of a sludge-like substance, and the scum contains about 1 to 13 parts by weight of tocopherol having antioxidant ability. In the present invention, it is obtained as a by-product.
  • the deodorized scum thus obtained is used as a raw material as it is, and the production process is simple and the production cost is very advantageous in that it is not necessary to purify and separate the tocopherol in the scum.
  • soybean scum is highly safe because it has been conventionally used as an intestinal preparation or a nutrient by adding a Ca source and mixing it in the form of fatty acid soap.
  • an oil-soluble electron donor component and a plant-derived liquid oil are compounded in the scum.
  • the oil-soluble electron donor component in the present invention is used in combination with scum, thereby synergistically enhancing the antioxidant action inherent in tocopherol contained in scum and improving the sustainability of the action.
  • scum a synergistically enhancing the antioxidant action inherent in tocopherol contained in scum and improving the sustainability of the action.
  • scum a synergistically enhancing the antioxidant action inherent in tocopherol contained in scum and improving the sustainability of the action.
  • scum a synergistically enhancing the antioxidant action inherent in tocopherol contained in scum and improving the sustainability of the action.
  • scum e.gistically enhancing the antioxidant action inherent in tocopherol contained in scum and improving the sustainability of the action.
  • lecithin, ascorbic acid, polyphenols, green tea extract, ascorbic acid fatty acid ester, kephalin, spermine, or a mixture appropriately selected from these can be preferably used.
  • plant-derived liquid oil is added as an essential component in addition to the above components. Since the mixture of the scum and the oil-soluble electron donor component such as lecithin described above has a relatively high viscosity, it is extremely difficult to use the mixture in a manner of spraying it on fish meal. Therefore, in the present invention, a liquid oil component derived from a natural product is added as a viscosity reducing agent.
  • soy sauce oil olive oil, soybean oil, rapeseed oil, sesame oil, perilla oil, cottonseed oil, sunflower oil, corn oil, bean flower oil, and medium chain
  • vegetable oil consisting of at least one selected from the group consisting of fatty acid triglycerides (MCT) can be used, soy sauce oil can be used most preferably.
  • Soy sauce oil is a by-product produced mainly in the brewing process of soy soy beans, and more specifically, in the process of producing soy sauce by using koji molds and soybeans as raw materials, soy sauce is produced. It is a fat component produced in the process. Soy sauce oil, which is a by-product in such a soy sauce manufacturing process, has been conventionally discarded or burned, but in the present invention, it is industrially useful for effectively using such a by-product.
  • soy sauce oil effectively lowers the viscosity of the above mixture of deodorized scum and the oil-soluble electron donor component is not necessarily clear, but soy sauce oil is more hydrolyzed than soybean oil during its production. It is thought that the cause is that the viscosity is lower than that of normal vegetable oil because free fatty acids generated by decomposition are contained as a main component.
  • the viscosity of the antioxidant composition for feed raw material according to the present invention can be appropriately selected depending on the performance of the spraying device when used in a spray form, but in the normal case, it is 0.1 dPa ⁇ s to 1.0 dPa ⁇ s.
  • the range is preferably in the range of 0.1 dPa ⁇ s to 0.8 dPa ⁇ s.
  • the scum, the oil-soluble electron donor component, and the plant-derived liquid oil are used from the viewpoints of expression of the above-mentioned antioxidant ability and improvement of the sustainability and preparation of a viscosity suitable for spraying.
  • the compounding ratio is Scum: 10 to 60 parts by weight, preferably 20 to 50 parts by weight
  • Oil-soluble electron donor component 1 to 45 parts by weight, preferably 1 to 30 parts by weight
  • plant-derived liquid oil 10 to 90 parts by weight, preferably The range of 20 to 60 parts by weight is desirable.
  • the scum contains approximately 1 to 13 parts by weight of tocopherol, and it is desirable to add 130 ppm or more of tocopherol to the fish meal in order to effectively suppress the oxidation of the fish meal. Therefore, the amount of scum is greatly affected by the amount of tocopherol contained in the scum, but since scum contains a large amount of free saturated fatty acids, scum is added to the antioxidant composition in excess of 60 parts by weight. This is unfavorable from the viewpoints of many liquid layer portions being absorbed by free saturated fatty acids, resulting in a decrease in yield in manufacturing the antioxidant composition and a decrease in handling.
  • the blending amount of the plant-derived liquid oil is less than 10 parts by weight, it becomes impossible to disperse other blends uniformly.
  • adding more than 90 parts by weight results in a sufficient amount of scum. This is undesirable in that it cannot be added.
  • the present invention includes a feed raw material antioxidant method comprising spraying or spraying the above-mentioned antioxidant composition onto a feed raw material.
  • the present invention includes a method for producing a feed raw material having excellent antioxidant properties, including spraying or spraying the antioxidant composition onto the feed raw material.
  • the feed material to which the antioxidant composition according to the present invention is applied is not particularly limited, and any material that has been conventionally used as a feed material and needs to be oxidized can be used. It can be suitably used for fish meal for raw materials. Therefore, the present invention includes fish meal as a feed material containing the antioxidant composition according to the present invention.
  • Antioxidant preparation liquid layer of soy sauce oil + lecithin + soybean scum (mixing ratio 1: 1: 2)) to fish meal at 2,000 ppm, 4,000 ppm, 6,000 ppm, 8,000 ppm, 10,000 ppm, or Ethoxyquin was added at 150 ppm to the fish meal, and the fish meal was stored in a 60 ° C. incubator for 5 weeks. Sampling was performed during the second, third, fourth, and fifth weeks of storage. Fish oil was extracted from the sampled fish meal by the Bligh & Dyer method, and the peroxide value (FIG. 4) and the amount of residual tocopherol (FIG. 5) of the fish oil were measured. These measurements were in accordance with the Japan Oil Chemical Society established standard oil and fat analysis test method.
  • FIG. 8 shows changes in the oxidation degree (average value of three sampled values) of three types of fish meal
  • FIG. 9 shows changes in temperature of the control fish meal during storage. From FIG. 9, it was found that the fish meal had reached 55 ° C. immediately after production, and then dropped to near room temperature over 1 to 2 weeks. Therefore, it is considered that strong oxidative degradation of fish meal occurs first immediately after production. Furthermore, it was found from the storage test results (FIG. 8) that the fish meal not added with the antioxidant was strongly oxidized within one week after production ((3) control fish meal).

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Animal Husbandry (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Molecular Biology (AREA)
  • Physiology (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Biomedical Technology (AREA)
  • Botany (AREA)
  • Mycology (AREA)
  • Fodder In General (AREA)
  • Fats And Perfumes (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)

Abstract

L'invention concerne une composition antioxydante qui peut être fabriquée à partir de matières premières relativement bon marché dérivées de produits naturels, qui présente un excellent effet antioxydant sur une matière première, et qui est sans danger et bon marché. L'invention concerne spécifiquement une composition antioxydante pour matière première, qui est caractérisée en ce qu'elle comprend une écume produite pendant le procédé de fabrication d'une huile végétale, un donneur d'électrons soluble dans les huiles et une huile liquide d'origine végétale en tant qu'agent de réduction de la viscosité.
PCT/JP2009/052411 2008-02-13 2009-02-13 Composition antioxydante pour matière première Ceased WO2009102019A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009553462A JP5429750B2 (ja) 2008-02-13 2009-02-13 飼料原料用抗酸化組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008-031561 2008-02-13
JP2008031561 2008-02-13

Publications (1)

Publication Number Publication Date
WO2009102019A1 true WO2009102019A1 (fr) 2009-08-20

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ID=40957049

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Application Number Title Priority Date Filing Date
PCT/JP2009/052411 Ceased WO2009102019A1 (fr) 2008-02-13 2009-02-13 Composition antioxydante pour matière première

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Country Link
JP (1) JP5429750B2 (fr)
CL (1) CL2009000348A1 (fr)
WO (1) WO2009102019A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015192617A (ja) * 2014-03-31 2015-11-05 理研ビタミン株式会社 ナッツ類の酸化防止用組成物
BE1026087B1 (nl) * 2018-03-12 2019-10-14 Impextraco Nv Voederadditief voor het stabiliseren van vet en geherwaardeerde meelbronnen
EP3672420A1 (fr) * 2017-08-25 2020-07-01 DSM IP Assets B.V. Nouvelle formulation

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5569688A (en) * 1978-11-17 1980-05-26 Tanabe Seiyaku Co Ltd Antioxidant
JPH08308509A (ja) * 1995-05-18 1996-11-26 Kodama Yuka Kogyo Kk 低コレステロール化家禽畜用飼料
JP2001323295A (ja) * 2000-05-19 2001-11-22 Ise Shokuhin Kk 抗酸化魚油
JP2006333791A (ja) * 2005-06-02 2006-12-14 Ikeda Shokken Kk 食品用酸化防止剤及び該食品用酸化防止剤を含有する乾燥食品。
WO2007132688A1 (fr) * 2006-05-15 2007-11-22 Nippon Suisan Kaisha, Ltd. Farine de poisson inhibant l'oxydation et son procédé de production

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5569688A (en) * 1978-11-17 1980-05-26 Tanabe Seiyaku Co Ltd Antioxidant
JPH08308509A (ja) * 1995-05-18 1996-11-26 Kodama Yuka Kogyo Kk 低コレステロール化家禽畜用飼料
JP2001323295A (ja) * 2000-05-19 2001-11-22 Ise Shokuhin Kk 抗酸化魚油
JP2006333791A (ja) * 2005-06-02 2006-12-14 Ikeda Shokken Kk 食品用酸化防止剤及び該食品用酸化防止剤を含有する乾燥食品。
WO2007132688A1 (fr) * 2006-05-15 2007-11-22 Nippon Suisan Kaisha, Ltd. Farine de poisson inhibant l'oxydation et son procédé de production

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015192617A (ja) * 2014-03-31 2015-11-05 理研ビタミン株式会社 ナッツ類の酸化防止用組成物
EP3672420A1 (fr) * 2017-08-25 2020-07-01 DSM IP Assets B.V. Nouvelle formulation
JP2020531012A (ja) * 2017-08-25 2020-11-05 ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． 新規の製剤
JP7130908B2 (ja) 2017-08-25 2022-09-06 ディーエスエム アイピー アセッツ ビー．ブイ． 新規の製剤
BE1026087B1 (nl) * 2018-03-12 2019-10-14 Impextraco Nv Voederadditief voor het stabiliseren van vet en geherwaardeerde meelbronnen

Also Published As

Publication number Publication date
JP5429750B2 (ja) 2014-02-26
CL2009000348A1 (es) 2010-01-15
JPWO2009102019A1 (ja) 2011-06-16

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