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WO2009031317A1 - 可視光応答型光触媒粉末とその製造方法、およびそれを用いた可視光応答型の光触媒材料、光触媒塗料、光触媒製品 - Google Patents

可視光応答型光触媒粉末とその製造方法、およびそれを用いた可視光応答型の光触媒材料、光触媒塗料、光触媒製品 Download PDF

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Publication number
WO2009031317A1
WO2009031317A1 PCT/JP2008/002453 JP2008002453W WO2009031317A1 WO 2009031317 A1 WO2009031317 A1 WO 2009031317A1 JP 2008002453 W JP2008002453 W JP 2008002453W WO 2009031317 A1 WO2009031317 A1 WO 2009031317A1
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WIPO (PCT)
Prior art keywords
visible
light
same
responsive photocatalyst
thetav
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Ceased
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PCT/JP2008/002453
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English (en)
French (fr)
Inventor
Kayo Nakano
Akira Sato
Yasuhiro Shirakawa
Keiichi Fuse
Masami Okamura
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Toshiba Corp
Toshiba Materials Co Ltd
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Toshiba Corp
Toshiba Materials Co Ltd
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Priority to CN2008801061880A priority Critical patent/CN101821005B/zh
Priority to EP08829185.1A priority patent/EP2186560B1/en
Priority to JP2009531136A priority patent/JP5683812B2/ja
Priority to US12/676,097 priority patent/US9598584B2/en
Publication of WO2009031317A1 publication Critical patent/WO2009031317A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Abstract

 可視光応答型光触媒粉末は酸化タングステン粉末を具備する。酸化タングステン粉末はX線回折法で測定したとき、(1)ピークA(2θ=22.8~23.4°)、ピークB(2θ=23.4~23.8°)、ピークC(2θ=24.0~24.25°)、ピークD(2θ=24.25~24.5°)の強度比のうち、A/D比とB/D比が0.5~2.0の範囲、C/D比が0.04~2.5の範囲、(2)ピークE(2θ=33.85~34.05度)とピークF(2θ=34.05~34.25°)の強度比(E/F)が0.1~2.0の範囲、(3)ピークG(2θ=49.1~49.7°)とピークH(2θ=49.7~50.3°)の強度比(G/H)が0.04~2.0の範囲であり、かつ1.5~820m2/gの範囲のBET比表面積を有する。
PCT/JP2008/002453 2007-09-05 2008-09-05 可視光応答型光触媒粉末とその製造方法、およびそれを用いた可視光応答型の光触媒材料、光触媒塗料、光触媒製品 Ceased WO2009031317A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2008801061880A CN101821005B (zh) 2007-09-05 2008-09-05 可见光响应型光催化剂粉末及其制造方法,以及使用了该粉末的可见光响应型光催化剂材料、光催化剂涂料、光催化剂产品
EP08829185.1A EP2186560B1 (en) 2007-09-05 2008-09-05 Visible-light-responsive photocatalyst powder and method for manufacturing the same
JP2009531136A JP5683812B2 (ja) 2007-09-05 2008-09-05 可視光応答型光触媒粉末の製造方法
US12/676,097 US9598584B2 (en) 2007-09-05 2008-09-05 Visible-light-responsive photocatalyst powder, method of manufacturing the same, and visible-light-responsive photocatalytic material, photocatalytic coating material and photocatalytic product each using the same

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JP2007229697 2007-09-05
JP2007-229697 2007-09-05

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WO2009031317A1 true WO2009031317A1 (ja) 2009-03-12

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US (1) US9598584B2 (ja)
EP (1) EP2186560B1 (ja)
JP (2) JP5683812B2 (ja)
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2011018899A1 (ja) * 2009-08-12 2013-01-17 株式会社東芝 抗ウイルス性材料とそれを用いた膜、繊維および製品
JP2016034639A (ja) * 2011-08-23 2016-03-17 株式会社東芝 陽イオン吸着剤の製造方法
JP2018171620A (ja) * 2013-03-12 2018-11-08 株式会社東芝 光触媒部材

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2864844B1 (fr) * 2004-01-07 2015-01-16 Saint Gobain Dispositif d'eclairage autonettoyant
US8003563B2 (en) * 2007-03-23 2011-08-23 Kabushiki Kaisha Toshiba Method for producing tungsten trioxide powder for photocatalyst, tungsten trioxide powder for photocatalyst, and photocatalyst product
WO2009096177A1 (ja) * 2008-01-28 2009-08-06 Kabushiki Kaisha Toshiba 可視光応答型光触媒粉末とそれを用いた可視光応答型の光触媒材料、光触媒塗料、光触媒製品
US20160175809A1 (en) * 2012-06-19 2016-06-23 Empire Technology Development Llc Recyclable and reusable oxygen scavenger
JP7098607B2 (ja) 2017-04-27 2022-07-11 株式会社東芝 ナノ金属化合物粒子およびそれを用いた塗料並びに膜、膜の製造方法、ナノ金属化合物粒子の製造方法
KR102124251B1 (ko) * 2018-08-16 2020-06-17 공주대학교 산학협력단 폴리카보네이트 재질의 신호등에 텅스텐 옥사이드를 코팅하는 방법 및 텅스텐 옥사이드가 코팅된 폴리카보네이트 재질의 신호등
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61242902A (ja) * 1985-04-19 1986-10-29 Natl Res Inst For Metals 高融点金属酸化物の超微粒子の製造法
JPH026339A (ja) * 1988-06-24 1990-01-10 High Frequency Heattreat Co Ltd タングステンもしくは酸化タングステン超微粒子の製造方法
JP2001152130A (ja) 1999-11-25 2001-06-05 Toto Ltd 光触媒性親水性部材、および、その製造方法
JP2002293544A (ja) 2001-03-30 2002-10-09 Allied Material Corp 微粒タングステン酸化物とその製造方法
JP2006102737A (ja) 2004-09-07 2006-04-20 Nisshin Seifun Group Inc 微粒子の製造方法
WO2006077839A1 (ja) * 2005-01-18 2006-07-27 Nippon Shokubai Co., Ltd. 可視光応答型光触媒組成物およびその製造方法
JP2008168277A (ja) * 2006-12-14 2008-07-24 Toshiba Lighting & Technology Corp 可視光応答型光触媒合成法
WO2008117655A1 (ja) * 2007-03-23 2008-10-02 Kabushiki Kaisha Toshiba 光触媒用三酸化タングステン粉末の製造方法、光触媒用三酸化タングステン粉末および光触媒製品

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5788738A (en) * 1996-09-03 1998-08-04 Nanomaterials Research Corporation Method of producing nanoscale powders by quenching of vapors
KR100518956B1 (ko) * 2001-04-25 2005-10-05 (주) 나노팩 광촉매활성과 고흡착성을 동시에 가지는 광촉매 코팅용 졸
JP2002370026A (ja) * 2001-06-14 2002-12-24 Sumitomo Chem Co Ltd 光触媒体およびそれを用いる光触媒機能製品
JP2003215328A (ja) 2002-01-18 2003-07-30 Sumitomo Metal Mining Co Ltd 日射遮蔽用微粒子とこの微粒子を含む日射遮蔽膜形成用塗布液および日射遮蔽膜
JP4182825B2 (ja) * 2002-07-01 2008-11-19 住友金属鉱山株式会社 日射遮蔽用アンチモン錫酸化物微粒子とこれを用いた日射遮蔽体形成用分散液および日射遮蔽体並びに日射遮蔽用透明基材
JP2004106303A (ja) 2002-09-17 2004-04-08 Asahi Kasei Chemicals Corp 防汚性能を有する化粧シート
WO2005087680A1 (ja) * 2004-03-16 2005-09-22 Sumitomo Metal Mining Co., Ltd. 日射遮蔽用合わせ構造体
WO2006028140A1 (ja) * 2004-09-07 2006-03-16 Nisshin Seifun Group Inc. 微粒子の製造方法および装置
JP2006175685A (ja) 2004-12-22 2006-07-06 Takiron Co Ltd 光触媒機能を有する成形品
JP4883912B2 (ja) * 2005-01-18 2012-02-22 株式会社日本触媒 可視光応答型光触媒およびその製造方法
JP4716776B2 (ja) 2005-04-18 2011-07-06 旭化成ケミカルズ株式会社 光触媒体
JP2006297350A (ja) 2005-04-25 2006-11-02 Showa Denko Kk 光触媒膜及びその製造方法
JP2006312150A (ja) 2005-05-09 2006-11-16 Matsushita Electric Ind Co Ltd 酸化触媒、一酸化炭素の除去方法、燃料電池用燃料精製装置および燃料電池発電装置
JP4714873B2 (ja) 2006-01-13 2011-06-29 国立大学法人 東京大学 光触媒用助触媒および光触媒材料
TW200732036A (en) * 2006-02-01 2007-09-01 Toshiba Lighting & Technology Photocatalysis material, photocatalysis body, photocatalysis product, luminaire and manufacturing method thereof
JP5374747B2 (ja) * 2006-02-01 2013-12-25 東芝マテリアル株式会社 光触媒材料およびそれを用いた光触媒組成物並びに光触媒製品
JP2008006429A (ja) * 2006-02-01 2008-01-17 Toshiba Lighting & Technology Corp 光触媒材料、光触媒体、光触媒製品、照明器具及び光触媒材料の製造方法
JP2008264758A (ja) * 2007-03-23 2008-11-06 Toshiba Lighting & Technology Corp 可視光応答型光触媒合成法、光触媒材料、光触媒塗料及び光触媒体
JP2009056398A (ja) * 2007-08-31 2009-03-19 Toshiba Lighting & Technology Corp 酸化タングステン可視光応答型光触媒体及び可視光応答型光触媒塗料

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61242902A (ja) * 1985-04-19 1986-10-29 Natl Res Inst For Metals 高融点金属酸化物の超微粒子の製造法
JPH026339A (ja) * 1988-06-24 1990-01-10 High Frequency Heattreat Co Ltd タングステンもしくは酸化タングステン超微粒子の製造方法
JP2001152130A (ja) 1999-11-25 2001-06-05 Toto Ltd 光触媒性親水性部材、および、その製造方法
JP2002293544A (ja) 2001-03-30 2002-10-09 Allied Material Corp 微粒タングステン酸化物とその製造方法
JP2006102737A (ja) 2004-09-07 2006-04-20 Nisshin Seifun Group Inc 微粒子の製造方法
WO2006077839A1 (ja) * 2005-01-18 2006-07-27 Nippon Shokubai Co., Ltd. 可視光応答型光触媒組成物およびその製造方法
JP2008168277A (ja) * 2006-12-14 2008-07-24 Toshiba Lighting & Technology Corp 可視光応答型光触媒合成法
WO2008117655A1 (ja) * 2007-03-23 2008-10-02 Kabushiki Kaisha Toshiba 光触媒用三酸化タングステン粉末の製造方法、光触媒用三酸化タングステン粉末および光触媒製品

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
BAMWENDA G.R.,ET AL.: "The visible light induced photocatalytic activity of tungsten trioxide powders", APPLIED CATALYSIS A:GENERAL, vol. 210, no. 1,2, 2001, pages 181 - 191, XP027370740 *
KIYOSHI OZAWA,ET AL.: "Arc Plasma-ho ni yoru Kinzoku Sankabutsu Biryushi no Sakusei", THE CERAMIC SOCIETY OF JAPAN "NENKAI KOEN YOKOSHU", 22 March 2003 (2003-03-22), pages 40 *
KURUMADA M.,ET AL.: "Structure of WO3 ultrafine particles and their characteristic solid states", JOURNAL OF CRYSTAL GROWTH, vol. 275, 2005, pages 1673 - 1678, XP008131591 *
See also references of EP2186560A4

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2011018899A1 (ja) * 2009-08-12 2013-01-17 株式会社東芝 抗ウイルス性材料とそれを用いた膜、繊維および製品
JP2015193973A (ja) * 2009-08-12 2015-11-05 株式会社東芝 抗ウイルス性繊維
US10327445B2 (en) 2009-08-12 2019-06-25 Kabushiki Kaisha Toshiba Antiviral material, antiviral film, antiviral fiber, and antiviral product
JP2016034639A (ja) * 2011-08-23 2016-03-17 株式会社東芝 陽イオン吸着剤の製造方法
US10081850B2 (en) 2011-08-23 2018-09-25 Kabushiki Kaisha Toshiba Treatment method for solution containing metal ions using cation adsorbent
JP2018171620A (ja) * 2013-03-12 2018-11-08 株式会社東芝 光触媒部材

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CN101821005A (zh) 2010-09-01
US20100204040A1 (en) 2010-08-12
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