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WO2011050345A8 - Catalyst materials for reforming carbon dioxide and related devices, systems, and methods - Google Patents

Catalyst materials for reforming carbon dioxide and related devices, systems, and methods Download PDF

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Publication number
WO2011050345A8
WO2011050345A8 PCT/US2010/053880 US2010053880W WO2011050345A8 WO 2011050345 A8 WO2011050345 A8 WO 2011050345A8 US 2010053880 W US2010053880 W US 2010053880W WO 2011050345 A8 WO2011050345 A8 WO 2011050345A8
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WO
WIPO (PCT)
Prior art keywords
systems
methods
catalyst materials
carbon dioxide
related devices
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/053880
Other languages
French (fr)
Other versions
WO2011050345A1 (en
Inventor
Giancarlo Corti
Timothy C. Cantrell
Miles F. Beaux Ii
Tejasvi Prakash
David N. Mcilroy
M. Grant Norton
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GONANO Tech Inc
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GONANO Tech Inc
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Publication of WO2011050345A1 publication Critical patent/WO2011050345A1/en
Publication of WO2011050345A8 publication Critical patent/WO2011050345A8/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/41—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenolysis or reduction of carboxylic groups or functional derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Electrochemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present teachings relate to catalyst materials based on a composite of nanoscale components. These catalyst materials can be used for the photocatalytic reduction Of CO2. The present teachings also relate to devices, apparatus, systems, and methods that incorporate a catalayst material based on a composite of nanoscale components. The devices, apparatus, systems, and methods can be used to reform CO2 into partially reduced products (such as methanol or formaldehyde) at high conversion efficiences and selectivity.
PCT/US2010/053880 2009-10-23 2010-10-22 Catalyst materials for reforming carbon dioxide and related devices, systems, and methods Ceased WO2011050345A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US25420509P 2009-10-23 2009-10-23
US61/254,205 2009-10-23

Publications (2)

Publication Number Publication Date
WO2011050345A1 WO2011050345A1 (en) 2011-04-28
WO2011050345A8 true WO2011050345A8 (en) 2011-10-06

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ID=43720167

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PCT/US2010/053880 Ceased WO2011050345A1 (en) 2009-10-23 2010-10-22 Catalyst materials for reforming carbon dioxide and related devices, systems, and methods

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106582600A (en) * 2016-12-21 2017-04-26 重庆中鼎三正科技有限公司 Preparation method for photocatalytic ceramic device used for photoelectrocatalysis
CN107497471A (en) * 2017-10-13 2017-12-22 华中农业大学 A kind of preparation method of photochemical catalyst and its application for reducing chromate waste water
CN108423749A (en) * 2018-03-23 2018-08-21 岭南师范学院 A kind of low pressure mercury lamp photocatalysis apparatus

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US8728464B2 (en) 2010-12-02 2014-05-20 University Of Idaho Method for stimulating osteogenesis
US20130008775A1 (en) * 2011-07-05 2013-01-10 Osman Ahmed Photocatalytic Panel and System for Recovering Output Products Thereof
US8567133B2 (en) * 2011-07-05 2013-10-29 Siemens Aktiengesellschaft Photocatalytic panel and system for recovering output products thereof
US20140256532A1 (en) * 2013-03-07 2014-09-11 Sunpower Technologies Llc Oriented Photocatalytic Semiconductor Surfaces
US9873115B2 (en) 2013-07-01 2018-01-23 The Regents Of The University Of Colorado, A Body Corporate Nanostructured photocatalysts and doped wide-bandgap semiconductors
CN104475167A (en) * 2014-12-21 2015-04-01 福建师范大学 Preparation method and application of 1-3 generation aryl ether dendritic phthalocyanine complex modified TiO2 visible light photocatalyst
CN105126799B (en) * 2015-08-21 2017-09-05 湖北师范学院 Preparation of TiO2/SiO2 Composite Oxide and Its Photocatalytic Degradation Method
US10668462B2 (en) 2017-02-09 2020-06-02 King Abdulaziz University Multiphasic titanium dioxide photocatalyst for the reduction of carbon dioxide
FR3073429B1 (en) * 2017-11-15 2022-01-07 Ifp Energies Now METHOD FOR THE PHOTOCATALYTIC REDUCTION OF CARBON DIOXIDE USING A PHOTOCATALYST BASED ON MOLYBDENUM SULPHIDE OR SUPPORTED TUNGSTEN SULPHIDE
EP4247544A1 (en) * 2020-11-17 2023-09-27 Teva Czech Industries s.r.o. Uv-leds photoreactor apparatus and associated methods
CN114367286B (en) * 2022-01-21 2023-05-26 中国科学院地球环境研究所 A metal single-atom catalyst and its preparation method
CN115430450B (en) * 2022-08-30 2024-05-14 上海交通大学 Preparation method and application of Rh nanoparticle-modified group III nitrogen oxide Si catalyst
CN116078429B (en) * 2023-02-15 2025-01-10 福州大学 Promoting CO2Photocatalyst for reduction and oxidative coupling of 1-phenethyl alcohol
DE102023203407B4 (en) * 2023-04-14 2024-11-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein Flow reactor, process for catalyzing at least two reactions and use of the flow reactor
CN116554914B (en) * 2023-05-04 2024-06-07 重庆工商大学 Application of modified CdSe QDs/B-SiO2 in photocatalytic preparation of fuel precursor and syngas from lignin oil and carbon dioxide

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* Cited by examiner, † Cited by third party
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US6685889B1 (en) * 1999-12-14 2004-02-03 Purdue Research Foundation Photochemical catalysts and methods for their manufacture and use
CA2613004C (en) 2005-06-24 2012-03-06 Washington State University Method for manufacture and coating of nanostructured components
US7771512B2 (en) 2005-06-24 2010-08-10 Washington State University Research Foundation Apparatus with high surface area nanostructures for hydrogen storage, and methods of storing hydrogen

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106582600A (en) * 2016-12-21 2017-04-26 重庆中鼎三正科技有限公司 Preparation method for photocatalytic ceramic device used for photoelectrocatalysis
CN106582600B (en) * 2016-12-21 2019-03-26 重庆中鼎三正科技有限公司 A kind of preparation method for the photocatalysis ceramics device can be used for photoelectrocatalysis
CN107497471A (en) * 2017-10-13 2017-12-22 华中农业大学 A kind of preparation method of photochemical catalyst and its application for reducing chromate waste water
CN107497471B (en) * 2017-10-13 2019-12-06 华中农业大学 A preparation method of photocatalyst and its application in reducing chromium-containing wastewater
CN108423749A (en) * 2018-03-23 2018-08-21 岭南师范学院 A kind of low pressure mercury lamp photocatalysis apparatus

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Publication number Publication date
WO2011050345A1 (en) 2011-04-28

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