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WO2009025079A1 - ブロックイソシアネート含有水性エマルジョン組成物を硬化剤とする水性樹脂組成物及びそれを使用する水性焼付け型塗料用又は接着剤用組成物 - Google Patents

ブロックイソシアネート含有水性エマルジョン組成物を硬化剤とする水性樹脂組成物及びそれを使用する水性焼付け型塗料用又は接着剤用組成物 Download PDF

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Publication number
WO2009025079A1
WO2009025079A1 PCT/JP2008/002215 JP2008002215W WO2009025079A1 WO 2009025079 A1 WO2009025079 A1 WO 2009025079A1 JP 2008002215 W JP2008002215 W JP 2008002215W WO 2009025079 A1 WO2009025079 A1 WO 2009025079A1
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WO
WIPO (PCT)
Prior art keywords
block
isocyanate
aqueous
composition
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/002215
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English (en)
French (fr)
Inventor
Iku Oki
Naotaka Izumi
Takaki Jono
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Polyurethane Industry Co Ltd
Original Assignee
Nippon Polyurethane Industry Co Ltd
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Filing date
Publication date
Application filed by Nippon Polyurethane Industry Co Ltd filed Critical Nippon Polyurethane Industry Co Ltd
Publication of WO2009025079A1 publication Critical patent/WO2009025079A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6541—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

ブロックイソシアネート化合物含有一液型水性樹脂組成物において、下記の主剤（Ｉ）と硬化剤（ＩＩ）を含有させることにより、水分散性や貯蔵安定性を改善し、ブロック体の解離温度付近での被膜に発現される各種被膜性能を向上し、また、耐候性を改良する。 主剤（Ｉ）：アクリル系樹脂 　　硬化剤（ＩＩ）：有機ポリイソシアネート（ａ１）とノニオン性極性基含有高分子ポリオール（ａ２）を反応させ、イソシアネート基をブロック剤（Ｃ）にて封鎖して、ブロックポリイソシアネート成分（Ａ）を生成させ、その反応系において、有機ポリイソシアネート（ｂ１）と高分子ポリオール（ｂ２）及びカルボキシル基含有アニオン性低分子グリコール（ｂ３）を反応させて、カルボキシル基含有イソシアネート基末端ウレタンプレポリマー（Ｂ）を製造し、反応系中のカルボキシル基を中和剤（Ｄ）にて中和させた後、反応混合物を水に乳化させ、鎖延長剤（Ｅ）により鎖延長反応を行って高架橋型ポリウレタン樹脂を生成させた、ブロックイソシアネート含有水性エマルジョン組成物。
PCT/JP2008/002215 2007-08-17 2008-08-14 ブロックイソシアネート含有水性エマルジョン組成物を硬化剤とする水性樹脂組成物及びそれを使用する水性焼付け型塗料用又は接着剤用組成物 Ceased WO2009025079A1 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007213091A JP5446077B2 (ja) 2007-08-17 2007-08-17 ブロックイソシアネート含有水性エマルジョン組成物を硬化剤とする水性樹脂組成物及びそれを使用する水性焼付け型塗料用又は接着剤用組成物
JP2007-213091 2007-08-17

Publications (1)

Publication Number Publication Date
WO2009025079A1 true WO2009025079A1 (ja) 2009-02-26

Family

ID=40377988

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/002215 Ceased WO2009025079A1 (ja) 2007-08-17 2008-08-14 ブロックイソシアネート含有水性エマルジョン組成物を硬化剤とする水性樹脂組成物及びそれを使用する水性焼付け型塗料用又は接着剤用組成物

Country Status (2)

Country Link
JP (1) JP5446077B2 (ja)
WO (1) WO2009025079A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2561986A4 (en) * 2010-04-22 2014-01-15 Mitsubishi Plastics Inc LAMINATED POLYESTER FILM
EP2716675A4 (en) * 2011-05-31 2014-11-26 Ube Industries AQUEOUS POLYURETHANE-DISPERSION AND COATING COMPOSITION THEREWITH
JP2015120821A (ja) * 2013-12-24 2015-07-02 東ソー株式会社 水性一液焼き付け被覆塗料用組成物、及び該組成物を用いた被覆材料
CN109233726A (zh) * 2018-07-03 2019-01-18 南京理工大学 Ipdi三聚体型水性聚氨酯胶黏剂及其制备方法
CN111171285A (zh) * 2020-02-15 2020-05-19 常州大学 一种以聚氨酯为壳材的环氧树脂固化剂微胶囊及其制备方法
CN112080197A (zh) * 2014-12-23 2020-12-15 帝斯曼知识产权资产管理有限公司 干燥之后具有柔软触感的水性涂料组合物
JP2022540688A (ja) * 2019-07-16 2022-09-16 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング 一液型のポリウレタン分散体、その製造及び使用

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103890034B (zh) * 2011-10-25 2016-05-18 旭化成化学株式会社 封端多异氰酸酯的水分散体、纤维处理剂组合物以及布帛
KR102115519B1 (ko) * 2013-09-30 2020-05-26 코오롱인더스트리 주식회사 광학필름

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6131422A (ja) * 1984-07-24 1986-02-13 Nippon Polyurethan Kogyo Kk 水分散性ブロツクイソシアネ−トの製造法
JPH04198210A (ja) * 1990-11-27 1992-07-17 Dainippon Ink & Chem Inc 新規なアクリル―ウレタン水性分散液の製造法
JP2005154674A (ja) * 2003-11-28 2005-06-16 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤用ポリウレタンエマルジョンの製造方法
JP2005247897A (ja) * 2004-03-01 2005-09-15 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤用ポリウレタンエマルジョンの製造方法
JP2008045072A (ja) * 2006-08-18 2008-02-28 Nippon Polyurethane Ind Co Ltd ブロックイソシアネート含有エマルジョン組成物及びその製造方法並びに焼付け型塗料用又は接着剤用組成物

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6131422A (ja) * 1984-07-24 1986-02-13 Nippon Polyurethan Kogyo Kk 水分散性ブロツクイソシアネ−トの製造法
JPH04198210A (ja) * 1990-11-27 1992-07-17 Dainippon Ink & Chem Inc 新規なアクリル―ウレタン水性分散液の製造法
JP2005154674A (ja) * 2003-11-28 2005-06-16 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤用ポリウレタンエマルジョンの製造方法
JP2005247897A (ja) * 2004-03-01 2005-09-15 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤用ポリウレタンエマルジョンの製造方法
JP2008045072A (ja) * 2006-08-18 2008-02-28 Nippon Polyurethane Ind Co Ltd ブロックイソシアネート含有エマルジョン組成物及びその製造方法並びに焼付け型塗料用又は接着剤用組成物

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2561986A4 (en) * 2010-04-22 2014-01-15 Mitsubishi Plastics Inc LAMINATED POLYESTER FILM
EP2716675A4 (en) * 2011-05-31 2014-11-26 Ube Industries AQUEOUS POLYURETHANE-DISPERSION AND COATING COMPOSITION THEREWITH
US9169420B2 (en) 2011-05-31 2015-10-27 Ube Industries, Ltd. Aqueous polyurethane resin dispersion and coating composition comprising the same
JP2015120821A (ja) * 2013-12-24 2015-07-02 東ソー株式会社 水性一液焼き付け被覆塗料用組成物、及び該組成物を用いた被覆材料
CN112080197A (zh) * 2014-12-23 2020-12-15 帝斯曼知识产权资产管理有限公司 干燥之后具有柔软触感的水性涂料组合物
CN112080197B (zh) * 2014-12-23 2022-09-20 科思创(荷兰)有限公司 干燥之后具有柔软触感的水性涂料组合物
CN109233726A (zh) * 2018-07-03 2019-01-18 南京理工大学 Ipdi三聚体型水性聚氨酯胶黏剂及其制备方法
CN109233726B (zh) * 2018-07-03 2020-12-25 南京理工大学 Ipdi三聚体型水性聚氨酯胶黏剂及其制备方法
JP2022540688A (ja) * 2019-07-16 2022-09-16 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング 一液型のポリウレタン分散体、その製造及び使用
JP7433411B2 (ja) 2019-07-16 2024-02-19 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング 一液型のポリウレタン分散体、その製造及び使用
CN111171285A (zh) * 2020-02-15 2020-05-19 常州大学 一种以聚氨酯为壳材的环氧树脂固化剂微胶囊及其制备方法
CN111171285B (zh) * 2020-02-15 2022-04-26 常州大学 一种以聚氨酯为壳材的环氧树脂固化剂微胶囊及其制备方法

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JP5446077B2 (ja) 2014-03-19

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