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WO2008108346A1 - 水性ポリウレタン系樹脂組成物及びそれを用いた塗料組成物 - Google Patents

水性ポリウレタン系樹脂組成物及びそれを用いた塗料組成物 Download PDF

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Publication number
WO2008108346A1
WO2008108346A1 PCT/JP2008/053795 JP2008053795W WO2008108346A1 WO 2008108346 A1 WO2008108346 A1 WO 2008108346A1 JP 2008053795 W JP2008053795 W JP 2008053795W WO 2008108346 A1 WO2008108346 A1 WO 2008108346A1
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WO
WIPO (PCT)
Prior art keywords
polyurethane resin
composition
water
ingredient
crosslinking agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/053795
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English (en)
French (fr)
Inventor
Takaki Jono
Naotaka Izumi
Iku Oki
Mitsuru Chiba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Polyurethane Industry Co Ltd
Original Assignee
Nippon Polyurethane Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Polyurethane Industry Co Ltd filed Critical Nippon Polyurethane Industry Co Ltd
Priority to JP2009502580A priority Critical patent/JPWO2008108346A1/ja
Priority to KR1020097017262A priority patent/KR101159151B1/ko
Priority to CN200880006932XA priority patent/CN101627068B/zh
Publication of WO2008108346A1 publication Critical patent/WO2008108346A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/36—Hydroxylated esters of higher fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

　本発明は、水性ポリウレタン系樹脂塗料組成物に内部架橋剤と外部架橋剤を用いて塗膜の硬度をより高める二液型組成物において、外部架橋剤と主剤エマルジョンとの混合性を良くするために、外部架橋剤を高沸点溶剤にて希釈分散する場合に、塗膜の光沢性を向上させることを発明の課題とし、その解決手段は、（Ａ）成分として、（ａ）ジイソシアネート化合物に（ｂ）活性水素基を有す脂肪酸及び（ｃ）ポリオール化合物を反応させたウレタンプレポリマーに、多官能ポリイソシアネート化合物とサクシネート系スルホン酸塩を配合し、中和処理後に鎖延長反応を行った水性ポリウレタン系樹脂、及び（Ｂ）成分として、（Ａ）成分に分散可能な多官能ポリイソシアネート化合物を含有することを特徴とする、二液型水性ポリウレタン系樹脂組成物である。
PCT/JP2008/053795 2007-03-02 2008-03-03 水性ポリウレタン系樹脂組成物及びそれを用いた塗料組成物 Ceased WO2008108346A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2009502580A JPWO2008108346A1 (ja) 2007-03-02 2008-03-03 水性ポリウレタン系樹脂組成物及びそれを用いた塗料組成物
KR1020097017262A KR101159151B1 (ko) 2007-03-02 2008-03-03 수성 폴리우레탄계 수지 조성물 및 이것을 사용한 도료 조성물
CN200880006932XA CN101627068B (zh) 2007-03-02 2008-03-03 水性聚氨酯类树脂组合物以及使用它的涂料组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-053526 2007-03-02
JP2007053526 2007-03-02

Publications (1)

Publication Number Publication Date
WO2008108346A1 true WO2008108346A1 (ja) 2008-09-12

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ID=39738224

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Application Number Title Priority Date Filing Date
PCT/JP2008/053795 Ceased WO2008108346A1 (ja) 2007-03-02 2008-03-03 水性ポリウレタン系樹脂組成物及びそれを用いた塗料組成物

Country Status (4)

Country Link
JP (1) JPWO2008108346A1 (ja)
KR (1) KR101159151B1 (ja)
CN (1) CN101627068B (ja)
WO (1) WO2008108346A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013155335A (ja) * 2012-01-31 2013-08-15 Dai Ichi Kogyo Seiyaku Co Ltd 水性ポリウレタン樹脂組成物の製造方法
JP6076478B2 (ja) * 2013-06-27 2017-02-08 旭化成株式会社 ポリイソシアネート組成物及びその製造方法、ブロックポリイソシアネート組成物及びその製造方法、樹脂組成物、硬化性樹脂組成物、並びに硬化物
CN110776817A (zh) * 2019-10-29 2020-02-11 河北晨阳工贸集团有限公司 一种水性变色隔热玻璃漆及其制备方法
JP2023139823A (ja) * 2022-03-22 2023-10-04 Ｕｂｅ株式会社 水性ポリウレタン樹脂分散体組成物

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102019581B1 (ko) * 2015-06-09 2019-09-06 아사히 가세이 가부시키가이샤 터치 패널용 수성 수지 조성물, 전사 필름 및 경화막 적층체, 그리고 수지 패턴의 제조 방법 및 터치 패널 표시 장치
KR101714740B1 (ko) * 2016-05-17 2017-03-09 주식회사 노루알앤씨 폴리우레탄 수분산액을 포함하는 수성 박리성 도료 조성물
KR102109975B1 (ko) 2018-11-16 2020-05-28 (주)진주에스이씨 방오용 우레탄수지 수성 분산액 조성물
KR102172886B1 (ko) * 2019-06-07 2020-11-02 애경특수도료 주식회사 유리 비산방지용 도료
KR102420431B1 (ko) 2022-03-17 2022-07-14 한서포리머주식회사 2액형 수용성 상도제 조성물

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08259884A (ja) * 1995-03-22 1996-10-08 Mitsubishi Chem Corp 水性ポリウレタン樹脂塗料
JP2003183347A (ja) * 2001-10-26 2003-07-03 Solutia Austria Gmbh 高分子量ポリウレタン分散物
JP2003292565A (ja) * 2002-01-29 2003-10-15 Achilles Corp 二液型水系ウレタン樹脂接着剤用の水性ポリウレタン樹脂エマルジョンおよび該エマルジョンを含む接着剤
JP2005194375A (ja) * 2004-01-07 2005-07-21 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤用ポリウレタンエマルジョンの製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08259884A (ja) * 1995-03-22 1996-10-08 Mitsubishi Chem Corp 水性ポリウレタン樹脂塗料
JP2003183347A (ja) * 2001-10-26 2003-07-03 Solutia Austria Gmbh 高分子量ポリウレタン分散物
JP2003292565A (ja) * 2002-01-29 2003-10-15 Achilles Corp 二液型水系ウレタン樹脂接着剤用の水性ポリウレタン樹脂エマルジョンおよび該エマルジョンを含む接着剤
JP2005194375A (ja) * 2004-01-07 2005-07-21 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤用ポリウレタンエマルジョンの製造方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013155335A (ja) * 2012-01-31 2013-08-15 Dai Ichi Kogyo Seiyaku Co Ltd 水性ポリウレタン樹脂組成物の製造方法
JP6076478B2 (ja) * 2013-06-27 2017-02-08 旭化成株式会社 ポリイソシアネート組成物及びその製造方法、ブロックポリイソシアネート組成物及びその製造方法、樹脂組成物、硬化性樹脂組成物、並びに硬化物
CN110776817A (zh) * 2019-10-29 2020-02-11 河北晨阳工贸集团有限公司 一种水性变色隔热玻璃漆及其制备方法
JP2023139823A (ja) * 2022-03-22 2023-10-04 Ｕｂｅ株式会社 水性ポリウレタン樹脂分散体組成物

Also Published As

Publication number Publication date
KR101159151B1 (ko) 2012-06-22
KR20090101385A (ko) 2009-09-25
CN101627068A (zh) 2010-01-13
CN101627068B (zh) 2012-05-23
JPWO2008108346A1 (ja) 2010-06-17

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