WO2009007166A1 - Washing or cleaning composition comprising surfactants based on renewable raw materials - Google Patents

Abstract

Washing or cleaning compositions comprising surfactants based on renewable raw materials are described. These compositions are very suitable as manual dishwashing detergents. The surfactants used, especially a mixture of APG and FAS, enable excellent results in manual dishwashing, in particular concerning the removal of oily and/or greasy soiling, especially comprising oils such as sunflower oil or rapeseed oil, fats such as butter or lard, from dishware.

Description

 Detergents or cleaning agents with surfactants based on renewable raw materials

The present invention relates to surfactant-containing detergents or cleaners which comprise, at least for the most part, only those surfactants which are based on renewable raw materials. Furthermore, it relates to the use of such an agent as hand dishwashing detergents, in particular for the removal of greasy and / or oily stains of dishes. Furthermore, it relates to the use of a surfactant system which comprises, at least for the most part, only those surfactants based on renewable raw materials in a hand dishwashing detergent.

Commercially available detergents or cleaning agents, e.g. Hand dishwashing detergents usually contain surfactants which are produced from petrochemical raw materials. However, it is considered disadvantageous by some consumers that the reservoir of fossil raw materials is finite, which is why conservation of petrochemical resources and more sustainable management are advocated. In addition, surfactants based on fossil fuels are very often not degradable under anaerobic conditions.

It is therefore desirable to provide a detergent or cleaning agent whose surfactant content protects the petrochemical resources.

This object is solved by the subject matter of the invention.

The object of the invention is a surfactant-containing washing or cleaning agent, which

(a) less than 10% by weight of petrochemical-based surfactants, which in particular comprise alkanesulfonates (SAS), alkylbenzenesulfonates, betaines and / or alkoxylated surfactants, such as preferably fatty alcohol ethoxylates, fatty acid ethoxylates, fatty amine ethoxylates, fatty alcohol ether sulfates,

(B) more than 90 wt .-% surfactants based on renewable raw materials, which in particular

Sugar surfactants, preferably alkyl polyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular glucamides, soaps,

Fatty acid sarcosinates, ester sulfonates, fatty alcohol sulfates (FAS), alkanolamides, protein-fatty acid condensates and / or Fatty amines, contains, wt .-% in each case based on the total amount of surfactant contained.

For the purposes of the present invention, the alkoxylated surfactants are therefore added to the petrochemical-based surfactants because the necessary alkylene oxide, preferably ethylene oxide, results from petrochemical sources, namely usually either from naphtha or from methanol, which in turn consists of raw materials such as carbon dioxide and Produced hydrogen or carbon monoxide and hydrogen, which in turn originate for the most part either the coal gasification or are obtained from natural gas and heavy residual oils.

In the following, some of the preferably usable surfactants, nämlbh sugar surfactants, preferably alkylpolyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular glucamides, soaps, fatty acid sarcosinates, ester sulfonates, fatty alcohol sulfates (FAS), alkanolamides, protein-fatty acid condensates, fatty amines explained in more detail. However, this explanation is kept short because the surfactants mentioned have long been familiar to the person skilled in the art.

Sugar surfactants are known surface-active compounds, which include, for example, the sugar surfactant classes of the alkyl glucose esters, aldobionamides, gluconamides (sugar acid amides), glycerol amides, glycerol glycolipids, polyhydroxy fatty acid amide sugar surfactants (sugar amides) and alkyl polyglycosides.

Particularly suitable sugar surfactants which can be used in the context of the teaching according to the invention are the alkyl polyglycosides, the sugar amides (especially glucamides) and the sugar esters, such as preferably sucrose esters, but especially the alkyl polyglycosides.

Particularly preferred sugar amides can be described by the formula (I), R'C (O) N (R ") [Z], in which R 'is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, with 5 to 21, preferably 5 to 17, in particular 7 to 15, particularly preferably 7 to 13 carbon atoms, R "is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18 , in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, a C ^ s-alkyl radical, in particular a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl radical , or hydrogen and Z represent a sugar residue, ie a monosaccharide residue. Particularly preferred sugar amides are the amides of glucose, the glucamides, for example lauroyl-methyl-glucamide. Glucamides are N-alkylated, preferably N-methylated fatty acid amides, which can be obtained by reacting N-alkyl- (N-methyl-) glucosamine with fatty acid methyl esters.

Particularly preferred glucamides can be described by the following general formula (II):

Fϊ ^? OH OH OH

I I S S t

R ^' - CO - N - CH, - C - C - C - C - CH <£> H

H OH H H

R ¹ in this aforementioned formula (II) is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 5 to 21, preferably 5 to 17, in particular 7 to 15, particularly preferably 7 to 13 carbon atoms, for example, for an n-Ci ₂ alkyl radical, R ² is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18, especially 8 to 16, particularly preferably 8 to 14 carbon atoms, a C ^ ₅ - alkyl radical, in particular a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl radical, or hydrogen, but in particular a lower one Alkyl radical, generally methyl.

The alkylpolyglycosides (APG) are very particularly preferred sugar surfactants within the scope of the teaching according to the invention and preferably satisfy the general formula (III), RO (AO) ₃ [G] _x in which R is a linear or branched, saturated or unsaturated alkyl radical with 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, [G] for a glycosidically linked sugar moiety and x for a number from 1 to 10 and AO for an alkyleneoxy group, for example an ethyleneoxy or propyleneoxy group, and a represents the average degree of alkoxylation from 0 to 20. In this case, the group (AO) _{3 may} also contain different alkylene oxyeinheiten, eg ethyleneoxy or propyleneoxy, wherein it is then a to the average Gesamtalkoxylierungsgrad, ie the sum of Ethoxylierungs- and Propoxylierungsgrad acts. Unless otherwise stated below, the alkyl radicals R ^{1 of} the APG are linear unsaturated radicals having the stated number of carbon atoms.

APG are nonionic surfactants and are known substances that can be obtained by the relevant methods of preparative organic chemistry. The index number x indicates the degree of oligomerization (DP degree), ie the distribution of mono- and oligoglycosides, and stands, as just described, for a number between 1 and 10. While x in a given compound must always be an integer, and Here, especially the values x = 1 to 6 can assume, the value x for a given alkyl glycoside is an analytically determined arithmetical variable, which usually represents a fractional number. Preferably, alkyl glycosides having a mean degree of oligomerization x of 1.1 to 3.0 are used. From an application point of view, those alkyl glycosides are preferred whose Oligomerisierungsgrad less than 1, 7 and in particular between 1, 2 and 1, 6 is. The glycosidic sugar used is preferably xylose, but especially glucose.

The alkyl or alkenyl radical R (based on the abovementioned formula (III) RO (AO) ₃ [G] _x ) can be derived from primary alcohols having 8 to 18, preferably 8 to 14, carbon atoms. Typical examples are caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol, and technical mixtures thereof, such as those obtained in the course of the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelene's oxosynthesis. Preferably, however, the alkyl or alkenyl radical R is derived from lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol. Also to be mentioned are elaidyl alcohol, petroselinyl alcohol, arachidyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and technical mixtures thereof.

Preferred APG are not alkoxylated (a = 0) and can therefore be described by formula (IV), RO [G] _x in which R is as previously described for a linear or branched, saturated or unsaturated alkyl radical having 4 to 22 carbon atoms, [G] is a glycosidically linked sugar residue, preferably glucose residue, and x is a number from 1 to 10, preferably 1, 1 to 3, in particular 1, 2 to 1, 6. Accordingly, preferred alkyl polyglycosides are, for example C ₈ io- and a Ci ₂ - ₁₄ -Alkylpoly- glucoside with a DP degree of 1, 4 or 1, 5, in particular C _8-I o- alkyl-1, 5-glucoside and C ₁₂ -i ₄ -alkyl-1,4-glucoside.

Particularly preferred APG may be e.g. are described by the following formula (V):

The average degree of oligomerization x is preferably 1, 2-1, 5. The alkyl radical is preferably in the range C8-C16 (thus n in the aforementioned formula is preferably 7-15).

Sugar esters likewise belong to the surfactants which can be used particularly preferably according to the invention. Sugar esters are esters of sugar alcohols, in particular sucrose (ie sucrose esters) with organic or inorganic acids, in particular with fatty acid (derivatives) n, for example obtainable by reactions of sucrose with fatty acid esters in solution or melt or from Alkali-catalyzed transesterification with triglycerides. Monoesters of short-chain fatty acids may be preferred, for example monoesters of lauric acid.

Non-limiting examples of sucrose esters are e.g. by the following illustrative formulas VI-VIII:

The number n in these formulas VI-VIII is preferably in the range from 1 to 20. The abovementioned formulas are intended primarily to illustrate, because not least because of the 8 hydroxy functions present, the sucrose esters are generally complex mixtures.

Also Fettsäuresarcosinate according to the invention are particularly preferably usable surfactants. The fatty acid sarcosinates are the condensation products of fatty acids with N-methylglycine. Fatty acid sarcosinates can be prepared by reacting N-methylglycine with fatty acid chloride. For example, fatty acid sarcosinates based on C 12 to C 18 fatty acids are particularly preferred. Fatty acid sarcosinates are characterized by a pronounced foaming power, while they also show a low sensitivity to water hardness and high skin tolerance. Preferred fatty acid sarcosinates can be described by the following general formula (IX):

CK ₁ 8 ^" R-CO-N-CK ₂ -COQH

(IX)

In this case, R is a linear or branched, saturated or unsaturated alkyl radical having preferably 8 to 22 carbon atoms.

Likewise, soaps can preferably be used according to the invention. Soaps are the water-soluble alkali metal salts (preferably sodium salts or potassium salts) of the saturated and unsaturated higher fatty acids (preferably C10 to C22), which are preferably present as solid or semisolid mixtures. Typical examples are the sodium, potassium, magnesium, ammonium and triethanolammonium salts of caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, Linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures. Preferably, coconut or palm kernel fatty acids are used in the form of their sodium or potassium salts.

Likewise, fatty alcohol sulfates can preferably be used according to the invention. Preferred fatty alcohol sulfates can be described by the formula (X), R ² O-SO ₃ X. They are available, for example, by reaction of preferably saturated fatty alcohols with concentrated sulfuric acid, gaseous sulfur trioxide, chlorosulfonic acid or sulfamic acid.

In the formula (X), R ² O-SO ₃ X, R ^{2 is} a linear or branched, aliphatic alkyl and / or alkenyl radical having 6 to 22, preferably 12 to 18 carbon atoms and X is an alkali and / or Alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium. Typical examples of alkyl sulfates which can be used for the purposes of the invention are the sulfation products of caproic alcohol, caprylic alcohol, capric alcohol, 2-ethylhexyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, Gadoleyl alcohol, behenyl and erucyl alcohol and their technical mixtures obtained by high-pressure hydrogenation of technical methyl ester fractions or aldehydes from the Roelen oxo synthesis. The sulfation products can preferably be used in the form of their alkali metal salts and in particular their sodium salts. Particularly preferred are alkyl sulfates based on Ci _{6 /} i ₈ tallow fatty alcohols or vegetable fatty alcohols of comparable C chain distribution in the form of their sodium salts. In the case of branched primary alcohols, they are oxo alcohols, as are obtainable, for example, by reacting carbon monoxide and hydrogen with alpha-olefins according to the Shop process. Such alcohol mixtures are commercially available under the trade names Dobanol® or Neodol®. Suitable alcohol mixtures are Dobanol 91®, 23®, 25®, 45®. Another possibility is oxo alcohols, as obtained by the classical oxo process of Enichema or the Condea by addition of carbon monoxide and hydrogen to olefins. These alcohol mixtures are a mixture of highly branched alcohols. Such alcohol mixtures are commercially available under the trade name Lial®. Suitable alcohol mixtures are Lial 91®, 111®, 123®, 125®, 145®.

Likewise, fatty acid alkanolamides can preferably be used according to the invention. Fatty acid alkanolamides may be e.g. by reaction of alkanolamines with fatty acids, fatty acid methyl esters or fatty acid glycerides. Preferred fatty acid alkanolamides can be described by the following formula (XI):

WI Ft'-CO- N - (CH- / ι _n - OH

(XI)

R ¹ -CO is generally a fatty acid radical, in particular a stearic, coconut oil or olein radical. As the alkanolamine, di-, monoethanolamine or aminopropanols can be used, whereby the meaning of R ² and n are defined in just mentioned formula.

Likewise, fatty amines according to the invention can preferably be used. Fatty amines are for example obtainable by a process starting from fatty alcohols, which are reacted at 210-260 ⁰ C in the presence of dehydrogenation catalysts with ammonia or short chain alkyl or dialkylamines. The salts of fatty amines are cationic emulsifiers. These are included in the term fatty amine. By alkylation, quaternary ammonium compounds can be obtained. These are included in the term fatty amine. By oxidation of the fatty amines, for example with hydrogen peroxide, amine oxides can be obtained. These are included in the term fatty amine.

The amine oxides which are particularly suitable according to the invention include alkylamine oxides, in particular alkyldimethylamine oxides, alkylamidoamine oxides and alkoxyalkylamine oxides. Preferred amine oxides can be described by the following formula (XII), R ⁶ R ⁷ R ⁸ N ⁺ -O ^" , in the R ^{6 is} a saturated or unsaturated C ₆ . ₂₂ alkyl, preferably C ₈ _i ₈ alkyl, in particular a saturated C ₁₀ -i ₆ alkyl, for example, a saturated C ₁₂ _ ₁₄ alkyl radical in the Alkylamidoaminoxiden via a Carbonylamidoalkylengruppe -CO-NH- (CH ₂ ) _Z - and in the Alkoxyalkylaminoxiden via an oxaalkylene group -O- (CH ₂ ) _Z - is bonded to the nitrogen atom N, wherein z is in each case a number from 1 to 10, preferably 2 to 5, in particular 3,

R ⁷ , R ⁸ independently of one another represent a C 1-4 -alkyl radical, optionally hydroxy-substituted, for example a hydroxyethyl radical, in particular a methyl radical.

Examples of suitable amine oxides are the following compounds designated as INCI: almond amidopropylamine oxides, babassuamidopropylamine oxides, behenamine oxides, cocamidopropyl amine oxides, cocamidopropylamine oxides, cocamine oxides, coco-morpholine oxides, decylamine oxides, decyltetradecylamine oxides, diaminopyrimidines oxides, dihydroxyethyl C8-10 Alkoxypropylamines oxides, dihydroxyethyl C9-11 alkoxypropylamines oxides, dihydroxyethyl C12-15 alkoxypropylamines oxides, dihydroxyethyl cocamines oxides, dihydroxyethyl lauramines oxides, dihydroxyethyl stearamines oxides, dihydroxyethyl tallowamine oxides, hydrogenated palm kernel amines oxides, hydrogenated tallowamine oxides, hydroxyethyl Hydroxypropyl C12-15 Alkoxypropylamines Oxides, Isostearamidopropylamines Oxides, Isostearamidopropyl Morpholine Oxides, Lauram Idopropylamic Oxide, Lauramine Oxides, Methyl Morpholine Oxide, Milkamidopropyl Amine Oxide, Mincamidoproparylamine Oxide, Myristamic Idopropylamic Oxide, Myristamine Oxide, Myristyl / Ce tyl Amine Oxide, Oleamidopropylamine Oxide, Oleamine Oxide, Olive Amide Propionamide, Palm Idamate Oxide, Palmitamine Oxide, PEG-3 Lauramine Oxide, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Trisphosphonomethylamine Oxides, Sesamidopropylamine Oxides, Soyamidopropylamides Oxides , Stearam idopropylam ine oxides, Stearamine oxides, Tallowamidopropylamine oxides, Tallowamine oxides, Undecylenamidopropylamine oxides and Wheat Germam idopropylam ine oxides. A preferred amine oxide is, for example, cocamidopropylamine oxides (cocoamidopropylamine oxide).

Likewise, ester sulfonates can preferably be used according to the invention. Preferably usable ester sulfonates contain in the molecule a terminal ester and a sulfonate function, usually adjacent in the α-position. This example α-ester can be obtained by reacting alkyl esters with usual sulfating agents, preferably luftverdünntem, dry sulfur trioxide (SO3), at 80 ⁰ C and subsequent neutralization. Preference is given in particular to methyl esters based on coconut oil (C12 / 14 chain), palm kernel oil (palm kernel sulfofatty acid ester), particularly preferably of taigmethyl ester (C16 / 18 chain). Particularly preferred ester sulfonates can be described by the formula:

H. ₍ C - (CH,) _t , - CH - COOR

* ° ^ (XlV)

Where n = 10-16 and R is an alkyl radical, preferably CH ₃ .

Likewise, protein-fatty acid condensates can preferably be used according to the invention. Protein-fatty acid condensates can be prepared, for example, by acylating protein hydrolysates, e.g. with fatty acids, fatty acid methyl esters, but preferably fatty acid chlorides or substituted maleic anhydrides.

Particularly preferred protein-fatty acid condensates can be described by the following formula:

N is preferably 1-13. Very well known are, for example, the Lamepon® types, Gluadin® types, Hostapon® KCG or the Amisoft® types.

In a preferred embodiment of the invention, the washing or cleaning agent according to the invention, preferably hand dishwashing detergent, contains more than 95% by weight, preferably more than 99% by weight, in particular 100% by weight, of surfactants based on renewable raw materials,% by weight on the total amount of surfactant contained.

Betaines can also be present in the agents according to the invention. Suitable betaines are the alkylbetaines, the alkylamidobetaines, the imidazolinium betaines, the sulfobetaines (INCI Sultaines) and the phosphobetaines and preferably satisfy the following formula,

R ¹ - [CO-X- (CH ₂ ) _n ] χ-N ⁺ (R ² ) (R ³ ) - (CH ₂ ) _m - [CH (OH) -CH ₂ ] _y -γ- (XIII) in R ¹ is a saturated or unsaturated C _6-22 -alkyl radical, preferably C ₈ -i ₈ -alkyl radical, in particular a saturated Ci -i _{O 6} alkyl radical, for example a saturated C ₁₂ .i ₄ alkyl, X is NH, NR ⁴ with the C _M -alkyl radical R ⁴ , O or S, n is a number from 1 to 10, preferably 2 to 5, in particular 3, x is 0 or 1, preferably 1, R ^2, R ³ independently represent a CI_ ₄ alkyl optionally hydroxysubstituted droxyethylrest such as a hybrid, but in particular a methyl radical, m is a number from 1 to 4, in particular 1, 2 or 3, y is 0 or 1 and

Y is COO, SO ₃ , OPO (OR ⁵ ) O or P (O) (OR ⁵ ) O, wherein R ^{5 is} a hydrogen atom H or a

C ^ alkyl.

The alkyl and alkylamido betaines, betaines of the formula XIII having a carboxylate group (Y ^" = COO ^" ) are also called carbobetaines.

Preferred betaines are the alkylbetaines of the formula (XIIIa), the alkylamidobetaines of the formula (Ib), the sulfobetaines of the formula (XIIIc) and the amidosulfobetaines of the formula XII (Id),

R ¹ -N ⁺ (CH ₃ ) ₂ -CH ₂ COO ^" (XIIIa)

R ¹ -CO-NH- (CH ₂ ) ₃ -N ⁺ (CH ₃ ) ₂ -CH ₂ COO ^" (XIIIb)

R ¹ -N ⁺ (CH ₃ ) ₂ -CH ₂ CH (OH) CH ₂ SO ₃ ^" (XIIIc)

R ¹ -CO-NH- (CH ₂ ) ₃ -N ⁺ (CH ₃ ) ₂ -CH ₂ CH (OH) CH ₂ SO ₃ ^" (XIIId) in which R ^{1 has} the same meaning as in formula I.

Particularly preferred betaines are the carbo-betaines, in particular the carbo-betaines of the formula (Ia) and (Ib), most preferably the alkylamido-betaines of the formula (Ib).

Examples of suitable betaines and sulfobetaines are the following INCI compounds: almondamidopropyl betaines, apricotamidopropyl betaines, avocadamidopropyl betaines, bassoramidopropyl betaines, behenamidopropyl betaines, behenyl betaines, betaines, canolamidopropyl betaines, caprylic / capramidopropyl betaines, camitines, cetyl betaines, cocamidoethyl betaines , Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Coco Betaines, Coco Hydroxysultaine, Coco / Oleamidopropyl Betaine, Coco Sultaine, Decyl Betaine, Dihydroxyethyl Oleyl Glycinate, Dihydroxyethyl Soy Glycinate, Dihydroxyethyl Stearyl Glycinate, Dihydroxyethyl Tallow Glycinate, Dimethicone Propyl PG- Betaines, erucamidopropyl hydroxysultaines, hydrogenated tallow betaines, isostearamidopropyl betaines, lauram idopropyl betaines, lauryl betaines, lauryl hydroxysultaines, lauryl sultaines, milkamido propyl betaines, minkamidopropyl betaines, myristamine idopropyl betaines, myristyl betaines, oleamidopropyl propenes, oleam idopropyl Hydroxysultaines, oleyl betaines, olivamidopropyl betaines, palmamidopropyl betaines, palm itamidopropyl betaines, palmitoyl camitines, palm ketamido betweens, polytetrafluoroethylene acetoxypropyl betaines, ricinoleam idopropyl betaines, sesamidopropyl betaines, soyamidopropyl betaines, stearam idopropyl betaines, stearyl betaines, tallowamidopropyl betaines, tallowam idopropyl hydroxysultaine, tallow betaine, tallow dihydroxyethyl betaine, undecylenamido propyl betaine and wheat germamidopropyl betaine. A preferred betaine is, for example, cocamidopropyl betaine (cocoamidopropylbetaine).

According to a preferred embodiment, the washing or cleaning agent according to the invention contains no betaine, if necessary in amounts of <10% by weight, <5% by weight or <1% by weight, based on the total amount of surfactant contained in the washing or cleaning agent but especially no betaine is included.

If the washing or cleaning agent according to the invention should contain alkylbenzenesulfonates, but this is not preferred according to the invention, then at most in amounts of <10% by weight, <5% by weight or <1% by weight, based on the total, in the wash or detergent contained amount of surfactant. In particular, however, no alkylbenzenesulfonate is included. Alkylbenzenesulfonates have the following general formula:

Where R is an alkyl radical (usually C8-C12) and M ^{1 is} a monovalent cation, preferably sodium.

If the washing or cleaning agent according to the invention should contain alkanesulfonates, but this is not preferred according to the invention, then at most in amounts of <10% by weight, <5% by weight or <1% by weight, based on the total, in the wash or detergent contained amount of surfactant. In particular, however, no alkanesulfonate is included. Alkanesulfonate is the collective name for compounds of the general formula R-SO ₂ -OM, where R is a - usually secondary - alkyl radical and M is a monovalent cation, preferably sodium.

If the washing or cleaning agent according to the invention should contain alkoxylated surfactants, but this is not preferred according to the invention, then at most in amounts of <10% by weight, <5% by weight or <1% by weight, based on the total, in Detergent containing detergent amount. In particular, however, no alkoxylated surfactant is included. Alkoxylated surfactants are alkylene oxide adducts, in particular fatty alcohol ethoxylates, fatty acid ethoxylates, fatty amine ethoxylates, fatty alcohol ether sulfates.

The total amount of surfactants present in the washing or cleaning agent according to the invention is in principle variable. A total amount of> 0.1 wt .-%, advantageously> 1 wt .-%, in further Advantageously, 5-50 wt .-%, preferably 10 -35 wt .-%, in particular 15-30 wt .-% of surfactants in the washing or cleaning agent according to the invention, preferably hand dishwashing detergents, but has, in particular as far as the removal of and greasy stains on dishes, proved to be very advantageous and therefore corresponds to a preferred embodiment of the invention.

Commercially available detergents or cleaners often contain combinations of several surfactants, for example to meet different requirements for the agent, e.g. in terms of cleaning performance and foaming, to better meet. Even with the washing or cleaning agent according to the invention, the use of a combination of a plurality of surfactants is very advantageous. In particular, it is advantageous if the washing or cleaning agent according to the invention, preferably hand dishwashing, contains a mixture of at least 2 surfactants based on renewable raw materials, preferably selected from sugar surfactants, preferably alkylpolyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular gluc - amides, soaps, fatty acid sarcosinates, ester sulfonates, fatty alcohol sulfates (FAS), alkanolamides, protein-fatty acid condensates and / or fatty amines. This corresponds to a preferred embodiment of the invention.

If the washing or cleaning agent according to the invention, preferably hand dishwashing detergent, but in particular contains a mixture of APG and FAS, preferably in a ratio of 3: 1 to 1: 3, advantageously 2: 1 to 1: 2 and especially 1, 5: 1 to 1 : 1, 5, so there is a very particularly preferred embodiment of the invention. It could be surprisingly found that just the aforementioned surfactant combination leads to extremely good results in the removal of grease and oily stains of dishes. In particular, in the removal of oily and greasy soil, e.g. comprising oils, such as sunflower oil or rapeseed oil, fats, such as butter or lard, of tableware very good cleaning results could be achieved, which is even slightly superior to the very good cleaning performance of conventional means. It is particularly advantageous if the combination of APG and FAS accounts for> 80% by weight, advantageously> 90% by weight, more advantageously> 95% by weight, in particular even 100% by weight, of the total amount of the surfactants present. It has also been found that such combinations lead to particularly storage-stable agents.

According to a further preferred embodiment of the invention, the fatty alcohol sulfate contained, in particular when it is used in a mixture with APG, a C ₈ -C ₂₀ - alcohol sulfate, preferably a Cio-Ci ₈ -Alkoholsulfat, in particular a Ci ₂ -C ₁₄ alcohol sulphate. If the washing or cleaning agent according to the invention, preferably hand dishwashing detergent, contains 3-30% by weight, preferably 5-20% by weight, in particular 8-15% by weight, of fatty alcohol sulphate, based on the total agent, this likewise constitutes a preferred embodiment of the invention. Furthermore, it is advantageous if the washing or cleaning agent according to the invention, preferably hand dishwashing detergent, 3-30 wt .-%, preferably 5-20 wt .-%, in particular 8-15 wt .-% APG contains based on the total agent. This, too, corresponds to a preferred embodiment of the invention. It is particularly advantageous to combine the aforementioned embodiments, ie the preferred amounts of fatty alcohol sulfate and APG used. This corresponds to a further preferred embodiment of the invention.

According to yet another preferred embodiment of the invention, a washing or cleaning agent according to the invention, preferably hand dishwashing detergent, additionally contains components selected from the following, preferably all the following components:

(a) pH adjusting agent, preferably citric acid and / or alkali citrate,

(b) hydrotrope, preferably aromatic sulfonate, in particular cumene sulfonate, advantageously in amounts of 0-5% by weight, more preferably 0.5-2.5% by weight

(c) refatting agents, preferably fatty acid amides,

(d) care components, preferably plant extracts,

(e) fragrances,

(f) dyes

(g) antibacterial agents, preferably sodium benzoate or sodium salicylate (h) preservative

(i) auxiliaries for adjusting the viscosity, preferably water-soluble salt, in particular sodium chloride, advantageously in amounts of 0-10% by weight, more preferably 0.1-7% by weight, particularly preferably 0.5% to 5% by weight

(i) alcohol, preferably bioalcohol, advantageously in amounts of from 0 to 15% by weight, preferably from 1 to 12% by weight, in particular from 3 to 8% by weight, in each case based on the total agent.

According to the invention, the agent may therefore also contain hydrotropes. These are solubilizers. Preferred hydrotropes are short-chain aromatic sulfonates, for example sodium cumene sulfonate or sodium xylene sulfonate. In addition, it is also possible to use urea, butyl glycol, glycol ether sulfates or else aliphatic short-chain anionic or amphoteric solubilizers, for example octyl sulfate or butyl glucoside. However, sodium cumene sulfonate and / or sodium xylene sulfonate are the preferred hydrotropes, which are preferably present in amounts of from 0 to 5% by weight, more preferably 0.5 to 2.5% by weight, on average. The agent according to the invention may preferably additionally comprise one or more water-soluble salts. It may be inorganic and / or organic salts, in a preferred embodiment, the agent contains at least one inorganic salt. The water-soluble salt can be used in detergents with a high surfactant concentration to set a lower viscosity.

Inorganic salts which can be used according to the invention are preferably selected from the group consisting of colorless water-soluble halides, sulfates, sulfites, carbonates, hydrogen carbonates, nitrates, nitrites, phosphates and / or oxides of the alkali metals, alkaline earth metals, aluminum and / or transition metals; Furthermore, ammonium salts can be used. Particularly preferred are halides and sulfates of the alkali metals; Preferably, therefore, the inorganic salt is selected from the group comprising sodium chloride, potassium chloride, sodium sulfate, potassium sulfate and mixtures thereof.

The organic salts which can be used according to the invention are, in particular, colorless water-soluble alkali metal, alkaline earth metal, ammonium, aluminum and / or transition metal salts of the carboxylic acids. Preferably, the salts are selected from the group comprising formate, acetate, propionate, citrate, malate, tartrate, succinate, malonate, oxalate, lactate and mixtures thereof. The washing or cleaning agent according to the invention contains in a preferred embodiment 0 to 10 wt .-%, preferably 0.1 to 7 wt .-%, particularly preferably 0.5 to 5 wt .-% of at least one water-soluble inorganic and / or at least one water-soluble organic salt.

If the washing or cleaning agent according to the invention, preferably hand dishwashing detergent, is in liquid form and contains> 50% by weight, preferably> 60% by weight, advantageously> 70% by weight and in particular> 80% by weight of water to the entire agent, so there is again a preferred embodiment of the invention.

In addition to the water, the washing or cleaning agent according to the invention, preferably hand dishwashing detergents, may also contain organic solvents.

One or more, preferably water-soluble, organic solvents may advantageously be present in an amount of from 0 to 15% by weight, preferably from 1 to 12% by weight, in particular from 3 to 8% by weight, based on the total agent.

The solvent can be used in the context of the teaching of the invention as needed in particular as a hydrotrope and viscosity regulator. It acts as a solubilizer, in particular for surfactants and electrolyte, as well as perfume and dye, and thus contributes to their incorporation, prevents the formation of liquid-crystalline phases and contributes to the formation of clear products. The viscosity of the agent according to the invention preferably decreases with increasing amount of solvent. Finally, as the amount of solvent increases, the cloudiness and clear point of the agent according to the invention preferably also decreases.

A particularly suitable alcohol in the context of this invention is bioalcohol. Bioalcohol (bioethanol) refers to ethanol produced from biomass. By alcoholic fermentation, the sugar, starch or cellulose components contained in plant components (for example in sugar beet, sugarcane, cereals, corn, wood) can be converted into ethanol. In the context of a preferred embodiment, the washing or cleaning agent according to the invention contains exclusively organic alcohol as the organic solvent.

Apart from this, suitable solvents are, for example, saturated or unsaturated, preferably saturated, branched or unbranched Ci. _20- hydrocarbons, preferably C ₂ _i ₅ -Kohlen- hydrogens, with at least one hydroxy group and optionally one or more ether functions COC, ie the carbon atom chain interrupting oxygen atoms.

Preferred solvents are the - optionally unilaterally etherified with a Ci_ ₆ alkanol - C ₂ - ₆ alkylene glycols and poly C ₂ - ₃ -alkylene glycol having an average of 1 to 9 identical or different, preferably the same, alkylene glycol groups per molecule as well as the C ^ ₆ -AlkOhOIe, preferably ethanol, n-propanol or iso-propanol, especially ethanol.

Exemplary solvents are the following INCI compounds: alcohol (ethanol), buteth-3, butoxy diglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, n-butyl alcohol, t-butyl alcohol, butylene glycol, butyloctanol, diethylene glycol, dimethoxy diglycol, dimethyl ether, Dipropylene glycol, ethoxydiglycol, ethoxyethanol, ethyl hexanediol, glycol, hexanediol, 1, 2,6-hexanetriol, hexyl alcohol, hexylene glycol, isobutoxypropanol, isopentyldiol, isopropyl alcohol (isopropanol), 3-methoxybutanol, methoxy diglycol, methoxyethanol, methoxyisopropanol, Methoxy methyl butanol, methoxy PEG-10, methylal, methyl alcohol, methyl hexyl ether, methyl propane diol, neopentyl glycol, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-6 methyl ether, pentylenes Glycol, phenoxyethanol, PPG-7, PPG-2-buteth-3, PPG-2 butyl ether, PPG-3 butyl ether, PPG-2 methyl ether, PPG-3 methyl ether, PPG-2 propyl ether, propanediol, propyl alcohol (n-propanol), propylene glycol, propylene glycol butyl ethe r, propylene glycol, propyl ether, tetrahydrofurfuryl alcohol, trimethylhexanol.

Also preferred are longer-chain polyalkylene glycols, in particular polypropylene glycols. Particularly preferred are, for example, the PPG-400 or the PPG-450, but also polypropylene glycols with larger chain lengths can be used in the context of this invention. Preferably, the solvent is selected from the group comprising methanol, ethanol, propanol, isopropanol, ethylene glycol, butyl glycol, propylene glycol, polypropylene glycols and mixtures thereof.

Extremely preferred solvents are the C ₂ - ₃ alcohols ethanol, n-propanol and / or iso-propanol, especially ethanol, and the polyalkylene glycols, especially polypropylene glycols, in particular the PPG-400.

As a solubilizer, in particular for perfume and dyes, for example, alkanolamines can be used in addition to the solvents described above.

Due to the solvent content, the flash point of the agent may be 40 ^° C or below; preferred embodiments have flash points of 30 ⁰ C to 35 ° C. Due to the high water content at the same time, however, they represent no danger if the product is used properly.

The agents according to the invention may optionally also contain further than the previously mentioned surfactants.

Optionally suitable are, for example, anionic sulfosuccinic acid surfactants, sulfosuccinates, sulfosuccinamates and sulfosuccinamides, in particular sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and diesters of sulfosuccinic acid HOOCCH (SO ₃ H) CH ₂ COOH, while the sulfosuccinamates are the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid ,

The salts are preferably alkali metal salts, ammonium salts and mono-, di- or trialkanolammonium salts, for example mono-, di- or triethanolammonium salts, in particular lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts , most preferably sodium salts.

In the sulfosuccinates, one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified. Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4. The monoesters are preferred in the context of the present invention over the diesters. A particularly preferred sulfosuccinate is Sulfobemsteinsäurelaurylpolyglykolester-di-sodium salt (EO lauryl sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ^® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.

In the sulfosuccinamates or sulfosuccinamides, one or both carboxyl groups of the sulfosuccinic acid forms preferably with a primary or secondary amine having one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals having 4 to 22 , preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms carries, a carboxylic acid amide. Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.

Also suitable are, for example, the following sulfosuccinates and sulfosuccinamates designated according to INCI: ammonium dinonyl sulfosuccinates, ammonium lauryl sulfosuccinates, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido-MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccinate, Disodium Cocamido MIPA Sulfosuccinate, Disodium Cocamido PEG-3 Sulfosuccinate, Disodium Coco-Glucoside Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosu ccinate, disodium dihydroxyethyl sulfosuccinoundecylenate, disodium dimethicone copolyol sulfosuccinates, disodium hydrogenated cottonseed glycerides sulfosuccinates, disodium isodecyl sulfosuccinates, disodium isostearamido MEA sulfosuccinates, disodium isostearamido MIPA sulfosuccinates, disodium isostearyl sulfosuccinates, disodium laneth-5 sulfosuccinates, disodium lauramido MEA sulfosuccinates , Disodium Lauramido PEG-2 Sulfosuccinate, Disodium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauryl Sulfosuccinate, Disodium Myristamido MEA Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA Sulphosuccinates, Disodium Oleamido MIPA Sulfosuccinates, Disodium Oleamido PEG-2 Sulfosuccinates, Disodium Oleth-3 Sulfosuccinates, Disodium Oleyl Sulfosuccinates, Disodium Palmitamido PEG-2 Sulfosuccinates, Disodium Palmitoleamido PEG-2 Sulfosuccinates, Disodium PEG-4 Cocamido MIPA Sulfo succinate, disodium PEG-5 lauryl citrate sulfosuccinate, disodium PEG-8 palm glycerides sulfosuccinate, disodium ricinoleamido MEA sulfo succinate, disodium sitostereth-14 sulfosuccinate, disodium stearamido MEA sulfosuccinate, disodium stearyl sulfosuccinamate, disodium stearyl sulfosuccinate, disodium tallamido MEA sulfosuccinate, disodium tallowamido MEA sulfosuccinate, disodium tallow sulfosuccinamate, disodium tridecyl sulfosuccinate, disodium undecylenamido MEA sulfosuccinate, disodium undecylenamido PEG -2 Sulfosuccinates, Disodium Wheat Germamido MEA Sulfosuccinates, Disodium Wheat Germamido PEG-2 Sulfosuccinates, Di-TEA-Oleamido PEG-2 Sulfosuccinates, Ditridecyl Sodium Sulfosuccinates, Sodium Bisglycol Ricinosulfosuccinates, Sodium / MEA Laureth-2 Sulfosuccinates and Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate. Yet another suitable sulfosuccinamate is disodium C 1-8 alkoxy-propylene sulfosuccinamate.

Preferred anionic sulfosuccinic are imidosuccinate, mono-Na-sulfosuccinic acid diisobutyl ester (Monawet MB ^® 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawet MO-84 ^® R2W, Rewopol SB ^® DO 75), mono-Na sulfosuccinic acid di-tridecyl (Monawet ^® MT 70), fat alkoholpolyglykolsulfosuccinat-Na-NH ₄ salt (sulfosuccinate S-2), di-Na-sulfosuccinic acid mono- Ci _{2 /} i ₄ 3EO ester (Texapon ^® SB -3), Natruimsulfobernsteinsäurediisooctylester (Texin DOS ^® 75) and di- sodium sulfosuccinic acid mono-Ci _{2 /} i ₈ ester (Texin 128-P ^®), in particular with the inventive ternary surfactant with respect to the drain and / or drying behavior synergistically cooperating mono-Na-sulfosuccinic di-octyl esters.

In a particular embodiment, the inventive composition contains as optional anionic sulfosuccinic acid surfactants one or more sulfosuccinates, sulfosuccinamates and / or sulfosuccinamides, preferably sulfosuccinates and / or sulfosuccinamates, in particular sulfosuccinates, in an amount of usually 0.001 to 5% by weight, preferably 0 , 01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt. -%, relative to the total budget. In another preferred embodiment, no anionic sulfosuccinic acid surfactant is included.

Optional amphoteric surfactants (amphoteric surfactants, zwitterionic surfactants) which may be preferably used include alkylamidoalkylamines, alkyl substituted amino acids, acylated amino acids or biosurfactants.

The alkylamidoalkylamines (INCI alkylamido alkylamines) are amphoteric surfactants of the formula (XVI), R ⁹ -CO-NR ¹⁰ - (CH ₂ ) ₁ -N (R ¹¹ ) - (CH ₂ CH ₂ O) _J - (CH ₂ ) _k - [CH (OH)] _l -CH ₂ ^ Z-OM (XVI) in the R ^{9 is} a saturated or unsaturated C ₆ . ₂₂ alkyl, preferably C ₈ _i ₈ alkyl, in particular a saturated Ci _O -i ₆ alkyl, for example, a saturated C ₁₂ . ₁₄ -alkyl radical, R ^{10 is} a hydrogen atom H or a C 1-4 -alkyl radical, preferably H, i is a number from 1 to 10, preferably 2 to 5, in particular 2 or 3,

R ^{11 is} a hydrogen atom H or CH ₂ COOM (to M su), j is a number from 1 to 4, preferably 1 or 2, in particular 1, k is a number from 0 to 4, preferably 0 or 1,

I 0 or 1, where k = 1, if I = 1,

Z is CO, SO ₂ , OPO (OR ¹² ) or P (O) (OR ¹² ), wherein R ^{12 is} a C 1-4 alkyl radical or M (su), and M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine , eg protonated mono-, di- or triethanolamine.

Preferred representatives satisfy the formulas (XVIa) to (XVId),

R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ -COOM (XVIa)

R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ CH ₂ -COOM (XVIb)

R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹ VCH ₂ CH ₂ O-CH ₂ CH (OH) CH ₂ -SO ₃ M (XVIC)

R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ CH (OH) CH ₂ -OPO ₃ HM (XVId) in which R ¹¹ and M have the same meaning as in formula (XVI).

Exemplary alkylamido alkylamines are the following compounds named according to INCI: coco amphodipropionic Acid, Cocobetainamido amphopropionates, DEA-Cocoamphodipropionate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Cocoamphocarboxyethylhydroxypropylsulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Isostearoamphodi- acetate, Disodium Isostearoamphodipropionate , Disodium Laureth-5 Carboxyamphodiacetate, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium propionate Oleoamphodi-, Disodium PPG-2-lsodeceth-7 Carboxyamphodiacetate, Disodium Stearoamphodiacetate, Disodium Tallowamphodiacetate, Disodium Wheatgermamphodiacetate, Lauroamphodipropionic Acid, Quaternium-85, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate, Sodium Capryloamphoacetate, Sodium Capryloamphohydroxypropylsulfonate, Sodiu m Capryloamphopropionate, Sodium Cocoamphoacetate, Sodium Cocoampho- hydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cornamphopropionate, Sodium iso stearoamphoacetate, sodium Isostearoamphopropionate, Sodium lauroamphoacetate, sodium Lauro- amphohydroxypropylsulfonate, Sodium Lauroampho PG-Acetate Phosphate, Sodium Lauroampho- propionate, Sodium Myristoamphoacetate, Sodium Oleoamphoacetate , Sodium Oleoamphohydroxypropylsulfonate, Sodium Oleoamphopropionate, Sodium Ricinoleoamphoacetate, Sodium Stearo- amphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Tallamphopropionate, Sodium Tallowamphoacetate, Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate, Sodium Wheat Germamphoacetate, and Trisodium Lauroampho PG Acetate Chloride Phosphate.

Preferred alkyl-substituted amino acids (INCI alkyl-substituted amino acids) according to the invention are monoalkyl-substituted amino acids according to formula (XVII),

R ¹³ -NH-CH (R ¹⁴ ) - (CH ₂ ) _U -COOM '(XVII) in the R ^{13 is} a saturated or unsaturated C ₆ . ₂₂ alkyl, preferably C ₈ _i ₈ alkyl, in particular a saturated C ₁₀ _i ₆ alkyl, for example, a saturated C ₁₂ .i ₄ -alkyl radical, R ^{14 is} a hydrogen atom H or a C ^ alkyl, preferably H, u Number from 0 to 4, preferably 0 or 1, in particular 1, and

M 'is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, e.g. protonated mono-, di- or triethanolamine, is alkyl-substituted imino acids according to formula (XVIII),

R ¹⁵ -N - [(CH _{2) V} -COOM '] ₂ (XVIII) where R ^{15 represents} a saturated or unsaturated C _{6 22} alkyl, preferably C ₈ _i ₈ -alkyl radical, preferably a saturated C ₁₀ _i. ₆ - Alkyl radical, for example a saturated C _{12, 14} alkyl radical, v is a number from 1 to 5, preferably 2 or 3, in particular 2, and

M "is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine, where M" in the two carboxy groups may have the same or two different meanings, for example hydrogen and sodium or twice sodium is, and mono- or dialkyl-substituted natural amino acids according to formula (XIX), R ¹⁶ -N (R ¹⁷ ) -CH (R ¹⁸ ) -COOM "'(XIX) in the R ^{16 is} a saturated or unsaturated C ₆ . ₂₂ alkyl, preferably C ₈ _i ₈ alkyl, in particular a saturated Ci _O -i ₆ alkyl, for example, a saturated C _{12. 14} alkyl, R ^{17 is} a hydrogen atom or a C ^ alkyl, optionally hydroxy or amine substituted , for example a methyl, ethyl, hydroxyethyl or aminopropyl radical,

R ^{18 is} the radical of one of the 20 natural α-amino acids H ₂ NCH (R ¹⁸ ) COOH, and M '"is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine. Particularly preferred alkyl-substituted amino acids are the aminopropionates according to formula (XVII a),

R ¹³ -NH-CH ₂ CH ₂ COOM '(XVII a) in which R ¹³ and M' have the same meaning as in formula (IV).

Exemplary alkyl substituted amino acids are the following INCI compounds: Aminopropyl Laurylglutamine, Cocaminobutyric Acid, Cocaminopropionic Acid, DEA Lauroaminopropionate, Disodium Cocaminopropyl Iminodiacetate, Disodium Dicarboxyethyl Cocopropylenediamine, Disodium Lauriminodipropionate, Disodium Steariminodipropionate, Disodium Tallowiminodipropionate, Lauraminopropionic Acid, Lauryl Aminopropylglycine , Lauryl Diethylenediaminoglycine, Myristaminopropionic Acid, Sodium C12-15 Alkoxypropyl Iminodipropionate, Sodium Cocaminopropionate, Sodium Lauraminopropionate, Sodium Lauriminodipropionate, Sodium Lauroyl Methylaminopro- pionate, TEA Lauraminopropionate and TEA Myristaminopropionate.

Acylated amino acids are amino acids, in particular the 20 natural α-amino acids which carry on the amino nitrogen atom the acyl radical R ¹⁹ CO of a saturated or unsaturated fatty acid R ¹⁹ COOH, where R ^{19 is} a saturated or unsaturated C ₆ . ₂₂ alkyl, preferably C ₈ . ₁₈ alkyl, in particular a saturated Ci _O -i ₆ alkyl, for example a saturated C ₁₂ . ₁₄ alkyl. The acylated amino acids can also be used as the alkali metal salt, alkaline earth metal salt or alkanolammonium salt, for example mono-, di- or triethanolammonium salt. Exemplary acylated amino acids are the acyl derivatives summarized in accordance with INCI under Amino Acids, for example sodium cocoyl glutamate, lauroyl glutamic acid, capryloyl glycine or myristoyl methylalanine.

The composition according to the invention may optionally additionally contain one or more cationic surfactants (cation surfactants, INCI quaternary ammonium compounds), usually in an amount of 0.001 to 5% by weight, preferably 0.01 to 4% by weight, in particular 0, 1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt .-%, based on the total agent.

Preferred cationic surfactants are the known quaternary surface-active compounds, in particular having an ammonium, sulfonium, phosphonium, iodonium or arsonium group. Through the use of quaternary surface-active compounds with antimicrobial action, the agent can be designed with an antimicrobial effect or its possibly existing antimicrobial effect due to other ingredients can be improved. Particularly preferred cationic surfactants are the quaternary ammonium compounds (QAV, INCI quaternary ammonium compounds) according to the general formula (R ') (R ") (R'") (R ^IV ) N ⁺ X ^" , in which R ¹ to R ^ιv same represent or different C. _{1 22} alkyl, C _{7. 28,} aralkyl radicals, or heterocyclic radicals, or in the case of an aromatic compound such as pyridine-even three groups together with the nitrogen atom forming the heterocycle, for example a pyridinium or imidazolinium compound, and X ^"are halide ions, sulfate ions, hydroxide ions or like anions. For optimum antimicrobial activity, preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QACs are prepared by reacting tertiary amines with alkylating agents, e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary amines with a long alkyl radical and two methyl groups succeeds particularly easily, and the quaternization of tertiary amines with two long radicals and one methyl group can be carried out with the aid of methyl chloride under mild conditions. Amines having three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are preferably quaternized with dimethyl sulfate.

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (mp-dichlorobenzyl-dimethyl-C 1-4 -alkylammonium chloride, CAS No. 58390-78 -6), benzoxonium chloride (benzyldodecyl-bis- (2-hydroxyethyl) -ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-trimethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N , N-dimethyl-N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides as described in U.S. Pat Di-n-decyldimethylammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammonium chloride, 1-cetylpyridinium chloride (CAS No 123-03-5) and thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C 1 -C -alkyl-alkylbenzyldimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

To avoid possible incompatibilities of the optionally present cationic surfactants with anionic surfactants optionally present anionic surfactant and / or as little as cationic surfactant are preferably used or omitted in a particular embodiment of the invention entirely on cationic surfactants.

To further improve the running and / or drying behavior, the agent according to the invention may optionally contain one or more additives from the group of surfactants, polymers and builders. Substances (builders), usually in an amount of 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt. -%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt .-%, based on the total agent.

Surfactants suitable as optional additives are certain of the amphoteric surfactants already described above, further anionic surfactants, nonionic surfactants and cationic surfactants, which are repeated at this point. The content of surface-active additives is preferably to be selected such that the total surfactant content is in the quantitative ranges set out above.

Some of the optional additives listed below have one or more trade names in brackets, among which the respective one is commercially available.

As additives suitable amphoteric surfactants are, in particular Natriumcarboxyethylkokosphospho- ethylimidazoline (Phosphoteric ^® TC-6), C _{8 /} i ₀ -Amidopropylbetain (INCI caprylic / Capramidopropyl Betaine, Betaine Tego ^® 810), N-2-hydroxyethyl-N-carboxymethyl-fettsäureamido- ethylamine Na (Rewoteric ^® AMV) and N-caprylic / capric amidoethyl-N-ethyl-propionate-Na (Rewoteric AMVSF ^®) and the betaine 3- (3-cocoamido-propyl) dimethylammonium-2-hydroxypropane (INCI sultaines ; Rewoteric AM CAS ^®) and the Alkylamidoalkylamin N- [N '(N "-2-hydroxyethyl-N" -carboxyethylamino- ethyl) -essigsäureamido] -N, N-dimethyl-N-coco-ammonium betaine (Rewoteric QAM ^® 50) ,

Further suitable anionic surfactants which are suitable as additives are, in particular, anionic gemini surfactants having a diphenyloxide basic structure, 2 sulfonate groups and one alkyl radical on one or both benzene rings of the formula O ₃ S (C ₆ H ₃ R) O (C ₆ H ₃ R ') SO ₃ ^' , in which R is an alkyl radical having, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ^® Dry hydrotropes Powder with C ₁₆ alkyl radical (s); INCI Sodium Hexyldiphenyl ether sulfonates, Disodium decyl phenyl ether Di - sulfonate, Disodium lauryl phenyl ether disulfonates, Disodium Cetyl phenyl ether disulfonates) and the fluorinated anionic surfactants ammonium Cg _/ ^ -Perfluoroalkylsulfonat (Fluorad ^® FC 120), perfluorooctane sulfonic acid potassium salt (Fluorad ^® FC 95), and sulfosuccinic acid imido succinate, mono-Na-sulfosuccinic acid diisobutyl ester (Monawet MB ^® 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawet MO ^® 84 R2W, Rewopol SB ^® DO 75), mono-Na-sulfosuccinic acid di - tr idecylester (Monawet ^® MT 70) Fettalkoholpolyglykolsulfosuccinat-Na-NH ₄ salt (sulfosuccinate S-2), di-Na-sulfosuccinic acid mono-Ci _{2 /} i ₄ 3EO ester (Texapon ^® SB-3), Natruimsulfobernsteinsäurediiso- octyl (Texin DOS 75 ^®) and di-Na-sulfosuccinic mono-Ci _{2 /} i ₈ ester (Texin ^® 128 P).

As additives suitable nonionic surfactants are in particular C ₁₀ dimethyl amine oxide (Ammonyx ^® DO), C _{10 /} i ₄ fatty alcohol + 1, + 2PO 6,4EO (Dehydol ^® 980), C _{12 /} i ₄ fatty alcohol + 6 EO (Dehydol ^® LS6), C ₈ - fatty alcohol + 1, 2PO + 9EO (Dehydol ^® O10), C _16/2 o -guerbet alcohol + 8EO, n-butyl-capped (Dehypon ^® G2084), mixture of several n-butyl-closed nonionic surfactants and C _{8 /} io APG-(Dehypon ^® Ke 2555) C _8/10 fatty alcohol + 1 PO + 22EO- (2-hydroxydecyl) ether (Dehypon Ke ^® 3447), C _12/14 alcohol + 5EO + 4PO -Fett- (Dehypon LS ^® 54 G), C _{12 /} i ₄ fatty alcohol + 5EO + 3PO, methyl closed (Dehypon LS 531 ^®), C _{12 /} i ₄ fatty alcohol + 10EO, n-butyl closed (Dehypon LS ^® 104 L), Cn-oxo-alcohol + 8EO (Genapol ^® UD 088), C ₁₃ oxo alcohol + 8EO (Genapol ^® X 089), C _13/15 fatty alcohol-EO adduct, n-butyl closed (Plurafac LF ^® 221), and alkoxylated fatty alcohol (Tegotens ^® EC-11). Preferably, however, the agents according to the invention are free of the aforementioned additives.

As additives suitable cationic surfactants are particularly compatible with anionic surfactants, cationic surfactants such as quaternary ammonium compounds, for example Kokospentaethoxymethyl- methosulfate (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

Polymers suitable as additives maleic acid-acrylic acid copolymer Na salt are, in particular (Sokalan ^® CP 5), modified polyacrylic acid Na salt (Sokalan ^® CP 10), modified polycarboxylate Na salt (Sokalan ^® HP 25) or polyalkylene suitable ,

As additives suitable builders are, in particular polyaspartic acid-Na-salt, ethylene diamintriacetatkokosalkylacetamid (Rewopol ^® CHT 12), methylglycine-Tri-Na-salt (Trilon ES ^® 9964) and acetophosphonic (Turpinal SL ^®).

In a particular embodiment of the invention, however, the additives mentioned are completely dispensed with.

The viscosity which is favorable for the composition according to the invention, if it is liquid, is 20 ^° C. and a shear rate of 30 min ^-1 - measured with a Brookfield LV DV II viscometer and spindle 31, preferably in the range from 5 to 1500 mPa.sup.-1. s, preferably 10 to 1200 mPa · s, in particular 20 to 800 mPa · s Viscosities> 1500 mPa · s are also possible, but generally less preferred.

The viscosity of the agent according to the invention can be adjusted, in particular at a high surfactant content of the agent, e.g. be reduced by the water-soluble salts and / or solvents and / or hydro tropics contained.

To stabilize the present invention means, in particular at high surfactant content, one or more dicarboxylic acids and / or salts thereof may optionally be added, in particular a composition of Na salts of adipic, succinic and glutaric acid, for example, under the trade name Sokalan ^® DSC is available. The use is advantageously carried out in amounts of 0.1 to 8 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1, 3 to 6 wt .-% and particularly preferably 2 to 4 wt .-%, based on the total mean. A change in the dicarboxylic acid (salt) content can - especially in amounts above 2 wt .-% - contribute to a clear solution of the ingredients. Also, within certain limits, influencing the viscosity of the mixture by this means is possible. Furthermore, this component influences the solubility of the mixture. This component is particularly preferably used at high surfactant contents, in particular at surfactant contents above 30 wt .-%.

However, if it is possible to dispense with their use, the agent according to the invention is preferably free from dicarboxylic acid (salts).

In addition, can optionally contain one or more further - especially in hand dishwashing detergents and cleaning agents for hard surfaces - conventional auxiliaries, active ingredients and additives, in particular UV stabilizers, perfumes, pearlescent agents (INCI opacifying agents, for example glycol distearate, for example Cutina ^® AGS Fa. Cognis, or mixtures comprising, for example, the Euperlane ^® from. Cognis), dyes, corrosion inhibitors, preservatives (for example, the technical also known as Bronopol 2-bromo-2-nitropropane-1, 3-diol (CAS 52-51- 7) which is commercially available is), organic salts, disinfectants, enzymes, pH-adjusting agents and skin feel-improving or caring additives (eg dermatologically effective substances, such as vitamin A, vitamin example, as Myacide ^® BT or as Boots Bronopol BT from Boots B2, Vitamin B12, Vitamin C, Vitamin E, D-Panthenol, Sericerin, Collagen Partial Hydrolyzate, Various Vegetable Protein Partial Hydrolyzates, Pr oteinhydrolyzate-fatty acid condensates, liposomes, cholesterol, vegetable and animal oils such as lecithin, soybean oil, etc., plant extracts such as aloe vera, azulene, witch hazel extracts, algae extracts, etc., allantoin, AHA complexes or even cationic polymers, For example, the known as Polyquaternium polymeric quaternary ammonium compounds), in amounts of usually not more than 5 wt .-% may be included.

The pH of the composition according to the invention can be adjusted by means of customary pH regulators, for example acids such as mineral acids or citric acid and / or alkalis such as sodium or potassium hydroxide, wherein - in particular with the desired hand compatibility - a range from 4 to 9, preferably 5 to 8, in particular 5.5 to 7.5, is preferred.

For adjusting and / or stabilizing the pH, the agent according to the invention may contain one or more buffer substances (INCI Buffering Agents), usually in amounts of 0.001 to 5 wt .-%, preferably 0.005 to 3 wt .-%, in particular 0 , 01 to 2 wt .-%, particularly preferably 0.05 to 1 wt .-%, most preferably 0.1 to 0.5 wt .-%, for example, 0.2 wt .-%, based on the total agent. Preference is given to buffer substances which are at the same time complexing agents or even chelating agents (INCI chelating agents). Particularly preferred buffer substances are citric acid or citrates, in particular the sodium and Kaliumeitrate, for example, tri- sodium citrate 2H ₂ O and tripotassium-H ₂ 0th

Another object of the present invention is the use of a washing or cleaning agent according to the invention, as described above, as hand dishwashing detergents.

It has been found that especially in the removal of oily and greasy soil, e.g. concerning oils, such as sunflower oil or rapeseed oil, fats, such as butter or lard, very good cleaning results could be achieved from dishes. Very outstanding results were achieved in particular when a surfactant combination of APG and FAS, preferably in a ratio of 3: 1 to 1: 3, advantageously 2: 1 to 1: 2 and especially 1, 5: 1 to 1: 1, 5 was used.

The use of a washing or cleaning agent according to the invention as a hand dishwashing detergent for removing oily and / or greasy soil from dishes therefore also corresponds to a preferred embodiment of the invention.

Another object of the invention is the use of a surfactant system, which

(a) less than 10% by weight of petrochemical-based surfactants, which in particular comprise alkanesulfonates (SAS), alkylbenzenesulfonates, betaines and / or alkoxylated surfactants, such as preferably fatty alcohol ethoxylates, fatty acid ethoxylates, fatty amine ethoxylates, fatty alcohol ethers,

(b) more than 90% by weight of surfactants based on renewable raw materials, which in particular a. Sugar surfactants, preferably alkyl polyglucosides (APG), sugar esters, in particular sucrose esters and / or Zuckeram ide, in particular glucamides, b. Soaps, c. Fatty acid sarcosinates, d. Estersulfonates, e. Fatty alcohol sulfates (FAS), f. Alkanolamides, g. Protein-fatty acid condensates and / or h. Fatty amines, in a hand dishwashing detergent, wherein the indication wt .-% in each case on the entire contained

Amount of surfactant is related. In this case, it corresponds to a preferred embodiment of the invention if in the aforementioned use a surfactant combination of APG and FAS, preferably in a ratio of 3: 1 to 1: 3, advantageously 2: 1 to 1: 2 and especially 1, 5: 1 to 1: 1, 5 is used.

When the described use serves to remove oily and greasy debris from dishes, again a preferred embodiment of the invention is provided.

embodiment

Three hand dishwashing detergents E1 to E3 were prepared by stirring together the ingredients listed in the table below. The formulation E1 corresponds to a conventional hand dishwashing detergent, while the formulations E2 and E3 contain only surfactants based on renewable raw materials. The total amount of surfactant was the same in each case.

E1 E2 E3

Secondary-C13-17- 3.00 - ~

Alkanesulfonate sodium salt

Cocoamidopropyl betaine 3.00 - ~

Sodium lauryl ether sulfate (2 EO) 14.00 - ~

Ethanol 4.00 4.00 4.00

C12-16 fatty alcohol 1.4 ~ 20.00 10.00 polyglucoside

Sodium dodecyl sulfate ~ 10,00 the in. Water ad 100 ad 100 ad 100

All amounts are given in% by weight of active ingredient, based on the agent.

The formulations E2 and E3 contained as ethanol those produced from biomass

(Bioethanol).

The hand dishwashing detergents obtained all had a good overall cleaning performance during manual dishwashing.

In the cleaning performance with respect to oily and greasy stains on dishes, however, surprisingly, the recipe E3, with a combination of APG and fatty alcohol sulfate, even slightly superior to the conventional hand dishwashing E1, whereas the recipe E2 not reach the cleaning performance of the conventional hand dishwashing Rinse E1 at these soiling could.

Claims

claims 1. Surfactant-containing washing or cleaning agent, characterized in that it (a) less than 10% by weight of petrochemical-based surfactants, which in particular comprise alkanesulfonates (SAS), alkylbenzenesulfonates, betaines and / or alkoxylated surfactants, such as preferably fatty alcohol ethoxylates, fatty acid ethoxylates, fatty amine ethoxylates, fatty alcohol ether sulfates, (b) more than 90% by weight of surfactants based on renewable raw materials, which in particular a. Sugar surfactants, preferably alkyl polyglucosides (APG), sugar esters, in particular sucrose esters and / or Zuckeram ide, in particular glucamides, b. Soaps, c. Fatty acid sarcosinates, d. Estersulfonates, e. Fatty alcohol sulfates (FAS), f. Alkanolamides, g. Protein-fatty acid condensates and / or h. Fatty amines include, wt .-% in each case based on the total amount of surfactant contained. 2. Composition according to claim 1, characterized in that it contains more than 95 wt .-%, preferably more than 99 wt .-%, in particular 100 wt .-% surfactants based on renewable raw materials, wt .-% based on the total contained surfactant. 3. Composition according to one of claims 1 or 2, characterized in that it contains a total amount of 5-50 wt .-%, preferably 10 -35 wt .-%, in particular 15-30 wt .-% of surfactants, based on the entire remedy. 4. Composition according to one of claims 1 to 3, characterized in that it contains a mixture of at least 2 surfactants based on renewable raw materials, preferably selected from sugar surfactants, preferably alkylpolyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular glucamides , Soaps, fatty acid sarcosinates, ester sulfonates, fatty alcohol sulfates (FAS), alkanolamides, protein-fatty acid condensates and / or fatty amines. 5. Composition according to one of claims 1 to 4, characterized in that it contains a mixture of APG and FAS, preferably in a ratio of 3: 1 to 1: 3, advantageously 2: 1 to 1: 2 and in particular 1, 5: 1 to 1: 1, 5. 6. Composition according to one of claims 1 to 5, characterized in that the fatty alcohol _sulfate contained is a C ₈ -C _2O - alcohol sulfate, preferably a C ₁₀ -C ₁₈ -alcohol sulfate, in particular a C ₁₂ -C ₁₄ - alcohol sulfate. 7. Composition according to one of claims 1 to 6, characterized in that the agent contains 3-30 wt .-%, preferably 5-20 wt .-%, in particular 8-15 wt .-% fatty alcohol sulfate, based on the total agent , 8. Composition according to one of claims 1 to 7, characterized in that the agent contains 3-30 wt .-%, preferably 5-20 wt .-%, in particular 8-15 wt .-% APG, based on the total agent. 9. Composition according to one of claims 1 to 8, characterized in that it additionally contains components selected from the following, but preferably all the following components: (a) pH adjusting agent, preferably citric acid and / or alkali citrate, (b) hydrotrope, preferably aromatic sulfonate, in particular cumene sulfonate, advantageously in amounts of 0-5% by weight, more preferably 0.5-2.5% by weight (c) refatting agents, preferably fatty acid amides, (d) care components, preferably plant extracts, (e) fragrances, (f) dyes (g) antibacterial agents, preferably sodium benzoate or sodium salicylate (h) preservative (i) auxiliaries for adjusting the viscosity, preferably water-soluble salt, in particular sodium chloride, advantageously in amounts of 0-10% by weight, more preferably 0.1-7% by weight, particularly preferably 0.5% to 5% by weight (i) alcohol, preferably bioalcohol, advantageously in amounts of from 0 to 15% by weight, preferably from 1 to 12% by weight, in particular from 3 to 8% by weight, in each case based on the total agent. 10. Composition according to one of claims 1 to 9, characterized in that it is in liquid form and> 50 wt .-%, preferably> 60 wt .-%, advantageously> 70 wt .-% and in particular> 80 wt .-% Contains water, based on the total agent. 11. Use of a composition according to any one of claims 1-1 O as hand dishwashing detergent. 12. Use according to claim 11 for removing oily and / or greasy soil, in particular comprising oils, such as sunflower oil or rapeseed oil, fats, such as butter or lard, of crockery. 13. Use of a surfactant system which (a) less than 10% by weight of petrochemical-based surfactants, which in particular comprise alkanesulfonates (SAS), alkylbenzenesulfonates, betaines and / or alkoxylated surfactants, such as preferably fatty alcohol ethoxylates, fatty acid ethoxylates, fatty amine ethoxylates, fatty alcohol ethers, (b) more than 90% by weight of surfactants based on renewable raw materials, which in particular a. Sugar surfactants, preferably alkyl polyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular glucamides, b. Soaps, c. Fatty acid sarcosinates, d. Estersulfonates, e. Fatty alcohol sulfates (FAS), f. Alkanolamides, g. Protein-fatty acid condensates and / or h. Fatty amines, in a hand dishwashing detergent, wherein the indication wt .-% in each case on the entire contained Amount of surfactant is related. 14. Use according to claim 13, wherein a surfactant combination of APG and FAS, preferably in a ratio of 3: 1 to 1: 3, advantageously 2: 1 to 1: 2 and in particular 1, 5: 1 to 1: 1, 5 is used , 15. Use according to claim 13 or 14 for the removal of oily and / or greasy soil, in particular comprising oils, such as sunflower oil or rapeseed oil, fats, such as butter or lard, of crockery.