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WO2009001897A1 - 白金族金属の分離試薬及びそれを用いた白金族金属の分離回収方法 - Google Patents

白金族金属の分離試薬及びそれを用いた白金族金属の分離回収方法 Download PDF

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Publication number
WO2009001897A1
WO2009001897A1 PCT/JP2008/061646 JP2008061646W WO2009001897A1 WO 2009001897 A1 WO2009001897 A1 WO 2009001897A1 JP 2008061646 W JP2008061646 W JP 2008061646W WO 2009001897 A1 WO2009001897 A1 WO 2009001897A1
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WO
WIPO (PCT)
Prior art keywords
platinum
group
separation
organic phase
acid solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/061646
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English (en)
French (fr)
Inventor
Hirokazu Narita
Mikiya Tanaka
Kazuko Morisaku
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
National Institute of Advanced Industrial Science and Technology AIST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Institute of Advanced Industrial Science and Technology AIST filed Critical National Institute of Advanced Industrial Science and Technology AIST
Priority to JP2009520636A priority Critical patent/JP5007983B2/ja
Publication of WO2009001897A1 publication Critical patent/WO2009001897A1/ja
Priority to US12/640,077 priority patent/US20100095807A1/en
Anticipated expiration legal-status Critical
Priority to US13/013,490 priority patent/US8609898B2/en
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00Obtaining noble metals
    • C22B11/04Obtaining noble metals by wet processes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/10Hydrochloric acid, other halogenated acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/28Amines
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/40Mixtures
    • C22B3/402Mixtures of acyclic or carbocyclic compounds of different types
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00Obtaining noble metals
    • C22B11/06Chloridising
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

 従来存在しなかった、塩素系酸溶液中のロジウムに対し高抽出率が得られる新規分離試薬及びこれを用いる白金族金属の分離回収方法を提供するものであって、下記の構造式で示されるアミド含有3級アミン分離試薬からなる有機相と白金族金属を含有する酸溶液を接触させ、ロジウム、白金及びパラジウムを前記有機相により抽出し、有機相により抽出した金属を、高濃度塩酸溶液により、ロジウムを選択的に水溶液に逆抽出し、高濃度硝酸溶液によりパラジウム及び白金を逆抽出する。 式(I)(式中、R1、R2及びR3の少なくとも1つが、 式(II)で表されるアミド基を表し、該アミド基以外のR1~R3、及びR4~R6は、炭素数が1~18の分岐してもよい鎖式炭化水素基、炭素数が1~10の脂環式炭化水素基、及び炭素数が1~14の芳香族炭化水素基から選ばれる基を表す。)
PCT/JP2008/061646 2007-06-26 2008-06-26 白金族金属の分離試薬及びそれを用いた白金族金属の分離回収方法 Ceased WO2009001897A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2009520636A JP5007983B2 (ja) 2007-06-26 2008-06-26 白金族金属の分離試薬及びそれを用いた白金族金属の分離回収方法
US12/640,077 US20100095807A1 (en) 2007-06-26 2009-12-17 Separation reagent of platinum group metal, method for separating and recovering platinum group metal, and amide-containing tertiary amine compound
US13/013,490 US8609898B2 (en) 2007-06-26 2011-01-25 Separation reagent of platinum group metal, method for separating and recovering platinum group metal, and amide-containing tertiary amine compound

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-167554 2007-06-26
JP2007167554 2007-06-26

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/640,077 Continuation US20100095807A1 (en) 2007-06-26 2009-12-17 Separation reagent of platinum group metal, method for separating and recovering platinum group metal, and amide-containing tertiary amine compound
US12/640,077 Continuation-In-Part US20100095807A1 (en) 2007-06-26 2009-12-17 Separation reagent of platinum group metal, method for separating and recovering platinum group metal, and amide-containing tertiary amine compound

Publications (1)

Publication Number Publication Date
WO2009001897A1 true WO2009001897A1 (ja) 2008-12-31

Family

ID=40185710

Family Applications (1)

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PCT/JP2008/061646 Ceased WO2009001897A1 (ja) 2007-06-26 2008-06-26 白金族金属の分離試薬及びそれを用いた白金族金属の分離回収方法

Country Status (4)

Country Link
US (2) US20100095807A1 (ja)
JP (1) JP5007983B2 (ja)
WO (1) WO2009001897A1 (ja)
ZA (1) ZA200909145B (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010180430A (ja) * 2009-02-03 2010-08-19 Univ Of Miyazaki 金属イオンの抽出剤、及び抽出方法
JP2011041918A (ja) * 2009-08-21 2011-03-03 Tosoh Corp 白金族金属吸着剤、及びそれを用いた白金族金属の分離回収方法
JP2011125840A (ja) * 2009-12-17 2011-06-30 National Institute Of Advanced Industrial Science & Technology アミド含有3級アミン化合物及びそれを用いた白金族金属分離回収
CN106574322A (zh) * 2014-06-18 2017-04-19 庄信万丰股份有限公司 金属的互相分离

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021183340A1 (en) 2020-03-10 2021-09-16 Sirrus, Inc. Radiation cured copolymers of dicarbonyl substituted-l-alkenes and electron rich comonomers
WO2021231288A1 (en) 2020-05-15 2021-11-18 Nippon Shokubai Co., Ltd. Improved dicarbonyl substituted-1-alkene compositions
CN113462900B (zh) * 2021-07-04 2022-06-21 贵研资源(易门)有限公司 一种从废铑派克催化剂中回收铑的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4927401A (ja) * 1972-07-10 1974-03-11
JPS5316368A (en) * 1976-06-21 1978-02-15 Nat I Fuoa Metaraajii Method of separating and refining platinum and*or palladium
JPH04143231A (ja) * 1990-10-05 1992-05-18 Tanaka Kikinzoku Kogyo Kk ロジウムの回収方法
WO2005083131A1 (ja) * 2004-02-27 2005-09-09 National Institute Of Advanced Industrial Science And Technology パラジウムの抽出剤及びパラジウムの分離回収方法

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US2411662A (en) * 1943-05-13 1946-11-26 Geigy Ag J R Imino-di-fatty acid amide
ZA72308B (en) * 1972-01-18 1973-09-26 Nat Inst Metallurg Improved process for the separation and purification of platinum group metals and gold
ZA79175B (en) * 1978-01-17 1980-01-30 Matthey Rustenburg Refines Solvent extraction
ZA815735B (en) * 1980-09-05 1982-08-25 Inco Ltd Process for the extraction of presious metals from solutions thereof
JPS6430896A (en) 1987-07-27 1989-02-01 Honda Motor Co Ltd Motorcycle
JP3733598B2 (ja) 1994-05-13 2006-01-11 住友金属鉱山株式会社 白金族元素の回収方法
JPH08158088A (ja) 1994-12-05 1996-06-18 Nissan Motor Co Ltd 白金族金属の回収方法
JP3493778B2 (ja) 1995-01-13 2004-02-03 住友金属鉱山株式会社 ロジウムの精製及び回収方法
JPH09279264A (ja) 1996-04-10 1997-10-28 Mitsubishi Materials Corp 貴金属の連続抽出方法および回収方法
JP3229218B2 (ja) 1996-09-27 2001-11-19 日鉱金属株式会社 白金の精製方法
JP4116490B2 (ja) 2003-05-07 2008-07-09 日鉱金属株式会社 高純度の白金族の回収方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4927401A (ja) * 1972-07-10 1974-03-11
JPS5316368A (en) * 1976-06-21 1978-02-15 Nat I Fuoa Metaraajii Method of separating and refining platinum and*or palladium
JPH04143231A (ja) * 1990-10-05 1992-05-18 Tanaka Kikinzoku Kogyo Kk ロジウムの回収方法
WO2005083131A1 (ja) * 2004-02-27 2005-09-09 National Institute Of Advanced Industrial Science And Technology パラジウムの抽出剤及びパラジウムの分離回収方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010180430A (ja) * 2009-02-03 2010-08-19 Univ Of Miyazaki 金属イオンの抽出剤、及び抽出方法
JP2011041918A (ja) * 2009-08-21 2011-03-03 Tosoh Corp 白金族金属吸着剤、及びそれを用いた白金族金属の分離回収方法
JP2011125840A (ja) * 2009-12-17 2011-06-30 National Institute Of Advanced Industrial Science & Technology アミド含有3級アミン化合物及びそれを用いた白金族金属分離回収
CN106574322A (zh) * 2014-06-18 2017-04-19 庄信万丰股份有限公司 金属的互相分离
JP2017519905A (ja) * 2014-06-18 2017-07-20 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company 金属の相互分離
CN106574322B (zh) * 2014-06-18 2021-09-28 庄信万丰股份有限公司 金属的互相分离

Also Published As

Publication number Publication date
JP5007983B2 (ja) 2012-08-22
JPWO2009001897A1 (ja) 2010-08-26
US20100095807A1 (en) 2010-04-22
ZA200909145B (en) 2010-08-25
US20110113927A1 (en) 2011-05-19
US8609898B2 (en) 2013-12-17

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