WO2008131643A1 - Method and apparatus for combined recycling of waste polymer material or joint production with carbon black - Google Patents

Abstract

Method for combined recycling of waste polymer material or joint production with carbon black and integrated equipment thereof. Above said method comprises: breaking or coarsely crushing a part of waste polymer to obtain intermediate product group I comprising waste polymer blocks, powder, or waste polymer powder and mixed fibrous fragments; heat cracking another part of waste polymer or mixed fibrous fragments in intermediate product group I and applying subsequent processing, to obtain product group II comprising heat cracked oil and intermediate product group II comprising heat cracked carbon black dregs and/or tar dregs; mixing the heat cracking carbon black dregs and/or tar dregs in intermediate product group II with the powder of waste polymer in intermediate product group I, superfinely crushing and/or heating desulfurating, plastifying, mixing to obtain product group I comprising mixture of superfine rubber powder and carbon black powder.

Description

 Method and device for recycling waste polymer material combination or carbon black

Technical field

 ~~? Xia Ming proposed a combined regeneration process of waste rubber and plastic polymer materials, or a combination of this process and ordinary carbon black production process, and an integrated device used in the implementation of the method; The technical scope of waste heat utilization in the production process of carbon black.

Background technique

 ~~ The recycling of polymer materials has become an important industrial category in today's society. The main branches are: the recycling of waste rubber such as used tires, the regeneration of waste plastics and so on.

 For the recycling method of waste rubber, the main branching methods are as follows: the use of closed heating and sulfur reduction, plasticizing processing, ie, reclaimed rubber method, to produce reclaimed rubber products; using crushing processing method to produce rubber powder products; using thermal cracking processing method, Production of pyrolysis oil, combustible gas, pyrolysis carbon black (slag) and steel wire products;

 For the recycling and recycling of waste plastics, the main branching methods are: using hot extrusion processing to produce recycled plastic particle products; using pyrolysis processing to obtain pyrolysis oil, combustible gas, tar residue products;

 The existing various recycling methods for recycling waste plastic materials such as waste rubber and plastic have their own disadvantages that are difficult to overcome. Specifically, they mainly include:

 1. Waste tires account for about 80% of the total amount of waste rubber recovered. When using recycled tires as raw materials, when producing recycled rubber and rubber powder products, it will be crushed from waste tires and sieved out to about the weight of used tires. 40% of the shredded fiber skeletons such as steel wire, nylon, cotton, etc., and about 10 to 30% of rubber powder particles are also contained in these chopped fiber materials. For the use of such chopped fiber materials, there are steel wire re-steel steelmaking, steel wire grit steel grit; nylon chopped fiber hot extrusion granulation, nylon chopped fiber filled plastic products, etc.; The composition of the fiber material is too messy, and the separation is often not worth the loss. However, the simple heat treatment will generate a large amount of smoke, and because of its large volume, it will be collected and transported over long distances. Economy, this phenomenon is particularly evident when dealing with semi-steel radial tires, because the composition of the fiber skeleton material is the most complicated.

 2. Using waste rubber such as waste tires as raw material, using the normal temperature pulverization method to produce a finer 40 mesh rubber powder product and its integrated device, there are two types, one is the fine pulverizer in the integrated device used on the drum surface. a unit machine provided with a hard rough working mechanism, that is, a so-called grinding wheel process; and a type of fine pulverizer using a unit machine provided with a rotating flat or taper surface shearing disc mechanism, that is, a so-called shear grinding disc process;

 The characteristics of the grinding wheel process and its integrated device are - a. The finely pulverized rubber can not be 5~30 mesh coarse powder, it must be a large block of 50~800;

 b. The finely pulverized rubber shall not contain a large amount of hard metal impurities such as steel wire;

 c. The chemical modification operation of the rubber powder cannot be carried out simultaneously during the pulverization process;

 d. The type of glue that will become sticky after being rolled up is also applicable;

 e. After fine pulverization, adding powder isolating agent, sieving, etc., can obtain 20~200 mesh rubber powders, wherein the rubber powder is equal to or equal to 100 mesh, and the rubber powder is about 30~40%;

 f. The rubber compound which is finely pulverized cannot be processed into a rubber powder which is finer than 100 mesh;

 g. It can directly process the glue which will be sticky after being rolled into a 20~200 mesh rubber powder which is not adhered; h. Use mechanical sieve method to finely smash 20~200 eye glue The powder is graded, and the efficiency is too low;

 i. The obtained fine rubber powder has poor compatibility with the rubber compound during use, and in the subsequent treatment of the fine rubber powder, no plasticizing treatment process and equipment are provided.

 The characteristics of the shearing disc process and its integrated device are:

 a. The finely pulverized rubber must be 5~30 mesh coarse powder, not bulky;

 b. The finely pulverized rubber shall not contain a large amount of hard metal impurities such as steel wire;

 c Chemical modification of the rubber powder can be carried out simultaneously during the pulverization process;

 d. For the rubber type which will be sticky after being rolled, in the absence of the release agent, the pulverization process cannot be operated normally;

 e. Under the condition of no powder isolating agent, after the fine pulverization, the mixed particle size rubber powder of 40~120. can be obtained, wherein the rubber powder which is finer than 100 mesh is only about 3~5%;

 f. The rubber compound which is finely pulverized can be processed into a rubber powder which is finer than 100 mesh;

 g. Nowadays, the coarse crushing unit machinery matched with the shearing grinding disc process and its integrated device cannot process the rubberized material which is sticky after being rolled into a rubber particle which is finer than 5 mesh and does not adhere, and then finely pulverized. The machine is used to produce sticky rubber pellets;

 h. Using mechanical sieve method to classify 20~200 mesh rubber powder after fine pulverization, the efficiency is too low.

3. Using waste rubber such as used tires as raw material to produce reclaimed rubber products, the materials that are subjected to high temperature plasticization into the tank are always selected to be much thicker than 100 mesh rubber powder, so that the material of the cans must be thinned through the roller. Refining treatment; this reconfirmation Although the raw rubber compound has the advantages of good viscosity, large plasticity and the phase interface of the new rubber compound in the new rubber compound, it is not easy to make the gas in the rubber compound during re-vulcanization. Run out of defects.

 4. Waste tires are used as raw materials, processed by thermal cracking, and oil, carbon black (slag) and steel wire are recovered. This kind of scheme is also insufficient. First of all, the carbon black obtained is a mixture of blocks, granules and powder. It is to be used as a reinforcing agent for elastomers. Now it can only be mechanically coarsely crushed, and then finely pulverized to finer. 500 mesh, and then the process of bagging carbon black powder, this carbon black (slag) treatment scheme makes the thermal cracking treatment of waste rubber and other waste rubber enterprises have serious black dust pollution; When the method is processed, the waste tire is broken into large pieces or is completely loaded into the thermal cracking furnace or the tower or the kettle or the rotary kiln. There are many gaps between the large rubber compounds, which results in the production capacity of the thermal cracking equipment. air.

 5. The plastics are processed by thermal cracking to obtain pyrolysis oil and tar residue products. This method only has a good market for pyrolysis oil, and the current outlet of tar residue is mainly buried, which causes hidden dangers to the environment.

 6. In addition, waste rubber and plastic products are subjected to thermal cracking treatment to obtain fuel oil, combustible gas, carbon black (slag) and steel wire. In these products, if the amount of combustible gas is within an appropriate amount, it can be used as thermal cracking. Fuel, but if the amount of production is more or less, the existing disposal method is venting or external heating energy, the market price of flammable gas is not high, and the existing methods of disposing flammable gas have insufficient use of high value;

 7. It is processed by hot extrusion to produce recycled plastic particle products. This method is only applicable to single clean materials. In summary, the various branching methods used in the recycling and recycling of waste polymer materials in the current market are all shortcomings and advantages, but they are irrelevant to each branch. How to combine and integrate them The topics that have been used together have not been reported in detail, and there are no processes and integrated devices that incorporate the advantages of each branch method.

 Conventional carbon black products are usually soft, ultrafine black powdery materials formed by incomplete combustion or thermal cracking of hydrocarbons under strictly controlled process conditions. There are many varieties of ordinary carbon black. Depending on the raw materials, there are gas black made of natural gas, acetylene black made of acetylene, and lamp (soot) black made of oil (heavy oil, fuel oil, etc.), and a carbon black made of naphthalene or anthracene in coal tar and natural gas or gas; according to the different methods, a groove black made by a groove method, a furnace black made by a furnace method, and a drum black made by a drum method, etc. According to the performance of the product, it is divided into high-strength carbon black, semi-reinforcing carbon black, high wear-resistant carbon black, conductive carbon black and so on.

The production process of the ordinary carbon black is an exothermic process of incomplete combustion. The carbon black furnace tail gas has a low calorific value flammable gas, the exhaust gas contains about 10% of hydrogen, about 10% of carbon monoxide and about 0.25% of formazan. The calorific value in the tail gas of carbon black furnace is in the range of 2700KJ~4600KJ per cubic meter. For the recycling of carbon black tail gas, it is known that 20% is used as a drying heat source for the carbon black production system, and the remaining 80% of the tail gas is purified by the water washing tower, and 30%-35% of the water is removed and sent to the coke. Furnace or waste heat boiler as fuel, China's oil (coal tar: ethylene tar: eucalyptus oil = 20: 50: 30) as the original material of 10,000 tons / year of carbon black standardized design equipment, its carbon black furnace The exhaust gas can be used as a fuel for 11,000 NM ^{3 of} dry-base exhaust per hour. The annual collection is equivalent to 1,500 tons of standard coal.

 The preferred disposal method for carbon black furnace tail gas is to convert the physical and chemical heat of the exhaust gas into high-pressure steam by using a waste heat boiler, and then drive the steam turbine to generate electricity, and then use the electricity for the ordinary carbon black production line device, and the excess electricity is then output to the power plant. Public commercial power grid; After the high-pressure steam is generated by the steam turbine, it becomes low-pressure steam, part of the low-pressure steam is returned to the boiler, and part is used as bath water.

 ordinary. More than 90% of the carbon black production is used in the rubber products industry. In the rubber products industry, the amount of carbon black used in tires accounts for more than 60% of the rubber products industry.

 As mentioned above, the recycling of waste rubber and plastic polymer materials is mainly carried out by thermal cracking, fine or ultrafine pulverization, reclaimed rubber, and hot extrusion granulation.

 Waste tires are mechanically crushed, finely or superfinely pulverized to obtain rubber powder; or heat treated with coarse rubber powder, mechanically kneaded, refined to obtain reclaimed rubber, etc., these recycling methods of used tires, in processing A lot of electricity and heat are needed; the hot extrusion granulation of waste plastics also requires a large amount of electricity.

 In the prior art, the production process of ordinary carbon black is irrelevant to the recycling process of waste rubber and plastic polymer materials. In each individual processing flow, there is no energy of the production system and materials to the environment. The efflux is the excessive consumption of energy and materials from the external environment.

Summary of the invention

 The object of the present invention is as follows: Firstly, a combined regeneration process of waste polymer materials is proposed to eliminate the deficiencies of the existing recycling processes; and second, the regeneration process of waste polymer materials and ordinary carbon black The production process is combined, and they are combined in a total production system to enable the energy and materials between the ordinary carbon black production and the recycling process of the waste polymer materials to communicate with each other, and to reduce the mass transfer between the production system and the environment; Third, an integrated device for implementing the method of the present invention, that is, for achieving the above two purposes, is provided.

In view of the first object of the present invention, the present invention specifically: the raw material competition relationship between the two types of processing methods of thermal cracking and non-thermal cracking of waste polymer materials is a synergistic recycling relationship; Have shattered, The improvement of the method of fine pulverization of waste rubber and plastics, and the complementary advantages of the current room temperature pulverization process or the various temperature pulverization and reclaimed rubber branches;

 In order to achieve the first object of the present invention, the present invention also provides a treatment scheme for recycling waste fibers obtained from waste polymer products such as tires and tapes, and products thereof.

 SUMMARY OF THE INVENTION A first object of the present invention is to provide a method for recycling and recycling a combined waste high molecular material which does not generate waste, waste, and dust pollution. In the process, the waste tar produced by the thermal cracking method can be eliminated, the waste waste fiber generated by the breaking and separating process in the production of the rubber powder and the reclaimed rubber can be eliminated, and the carbon black (slag) generated by the thermal cracking method can be solved, and the carbon black (slag) is not easily utilized, and The problem of dust pollution in production can solve the problem that the shearing disc method can not handle the sticky rubber material, and can solve the problem that the grinding wheel method can not process all the materials into fine powder materials and can not handle the materials with rigid skeleton materials. It can solve the problem of poor compatibility of the fine rubber powder obtained by the grinding wheel method with the rubber compound during use, and can solve the problem that the reclaimed rubber method must use a refining step to cause high energy consumption.

 For the second object of the present invention, the content of the present invention is specifically: The existing ordinary carbon black production process and the recycling process of waste polymer materials are irrelevant, and the energy and materials of each production process cannot be reasonable in each production process. Fully exploiting the defects, providing a joint production method for the recycling of ordinary carbon black and waste polymer materials, so that the energy and materials between the ordinary carbon black production and the recycling process of waste polymer materials can be used interchangeably. .

 The second object of the present invention is to supply the steam recovered from the exhaust heat of the tail gas through the boiler and the electric energy recovered by the steam turbine to the regeneration processing of the waste polymer material, so that the recovered steam and electric energy are obtained commercially. The use of the appreciation of the waste gas; the combustible gas and/or fuel oil obtained by thermal cracking of the waste polymer material for carbon black production as a carbon source and fuel, enabling low-value materials (especially flammable gas) to be commercially available. Appreciation.

 For the third object of the present invention, the integrated device for realizing the foregoing first object in the present invention is specifically: taking advantage of the advantages of the two types of processing integrated devices for thermal cracking and non-thermal cracking of waste polymer materials, After combination, it can eliminate its respective deficiencies; to take advantage of the advantages of each branch of the rubber powder and reclaimed rubber, the combination can make up for their respective deficiencies; this also includes providing a rubber powder with higher classification efficiency than the existing mechanical sieve. Particle size grading combination device;

 The integrated device for realizing the foregoing second object in the present invention is specifically: regenerating an integrated device for producing ordinary carbon black, thermal cracking, pulverization, reclaimed rubber, hot extrusion granulation, etc. of waste rubber and plastic polymer materials. Recombination is achieved using an integrated device of one or more processes of processing.

 Invention concept

 The idea of recycling waste polymer materials or co-production with ordinary carbon black:

 It involves the combination of two major types of processes: thermal cracking and non-thermal cracking of waste rubber and plastic polymer materials.

1. It is easy to treat waste polymer materials with thermal decomposition by thermal cracking, and has the potential of charging space in thermal cracking furnace or tower or kettle or column or rotary kiln. It is treated by thermal cracking method from reclaimed rubber and rubber powder. a chopped fiber skeleton material that is produced during the production process and is difficult to handle;

 2. In the rubber normal temperature pulverization method, the shearing disc process can directly use the fragile rigid material which is finer than 5~200 for the characteristics of the release agent, and the carbon black obtained by the thermal cracking treatment of the waste rubber is only processed to be finer than 5 ~250 mesh, eliminating the need for superfine pulverization or / and superfine powder surface treatment, bagging, etc., using carbon black that can pass through 5~250 mesh screen for the shearing disc process of rubber at room temperature pulverization method, making super a mixture of fine powder and carbon black powder; the ultrafine rubber powder in the mixture product can pass through a 100 mesh screen, and the carbon black powder can pass through a 200 mesh screen; the mixture product can be including but not limited to Particle size fractionation or mixing products in the range of 100-200 mesh;

 3. Using the tar residue with low boiling point fraction in the production of reclaimed rubber to make high-quality softener, and the rubber powder material plasticized in the closed dynamic sulfur-breaking tank is easy to mix with other powders and other materials, and will be thermally cracked. The carbon black or/and tar residue obtained by treating the waste polymer material is matched with the rubber powder, and processed by the reclaimed rubber processing equipment to obtain a reclaimed rubber mixture containing carbon black powder or/and tar;

 4. The products with thermal cracking method and non-thermal cracking method have the best quality and the most benefit, and the waste disposal amount after the combination of each branch method tends to be at least the associated condition, and a relevant proportional interval is obtained. It is now a branching method for disorderly competition of raw materials, which can be a proportional synergistic utilization relationship.

 It involves a combination of room temperature pulverization or room temperature pulverization and reclaimed rubber.

 5. Utilizing the advantages of the grinding wheel and shearing disc process in the rubber normal temperature pulverization method, the two are combined to make the rubber powder suitable for the normal temperature pulverization method more, and the treated materials can reach the ideal 100~200 mesh sieve. The fineness of the net.

 6. Change the current normal temperature fine or super fine pulverization process to set only one shearing disc pulverization treatment, and at least two shearing grinding discs arranged in series are used to make the material difficult to stick in the presence of the release agent. Group, increase the depth of crushing of materials.

 7. In the subsequent treatment of the fine rubber powder obtained by the grading process of the grinding wheel pulverizing process, a section for mixing the plasticizing auxiliaries is set.

8. Using the advantages of the reclaimed rubber and rubber powder process, the two are combined, and at least the ultrafine rubber powder of fineness equal to 100 mesh or the ultrafine rubber powder and the carbon of 200 mesh are obtained by the rubber normal temperature pulverization method. Black powder mixture, which replaces the high-temperature can-processed coarse rubber powder of the current reclaimed rubber process. When combined, the current reclaimed rubber can be reduced or eliminated. The refining process of the process, the obtained materials can also have the advantages of reclaimed rubber and rubber powder.

 The invention relates to a treatment scheme and a product for recycling the waste fiber obtained from waste polymer products such as tires and tapes, and the specific products thereof include:

 • 9. Turn waste fiber into a felt-like or rubber-like, linoleum-like product, and use it as a secondary skeleton material for rubber and plastic products;

 10. Mix the waste fiber with the plasticized rubber, oil, etc., so that the surface of the waste fiber is covered with a layer of interlayer that can be matched with the rubber and plastic materials, so that the waste fiber can be easily redispersed in the rubber. Plastic material, and can be firmly combined with it.

 11. The rubber and oil materials in the coupling layer or the coupling agent should follow the well-known compatibility principle of general rubber, special rubber and plastic.

 It involves a combination of ordinary carbon black and recycled rubber and plastic polymer materials.

 12. In the production of carbon black, the steam recovered from the waste heat of the exhaust gas is supplied to the heating required for waste rubber and plastic recycling processing;

13. In the production of carbon black, the electrical energy recovered from the exhaust heat of the exhaust gas is supplied to the mechanical energy used for the recycling of used rubber and plastics;

14. The waste gas and/or fuel oil obtained from waste rubber and plastic pyrolysis are supplied to carbon black for carbon source and fuel. In order to achieve the first object of the present invention, the concept of the above 1 to 10 is proposed, that is, the improvement of the existing pulverized and fine pulverized waste rubber and plastic method, and the fine grinding process of the shear-grinding rubber in the prior pulverization method It can be combined with the grinding wheel rubber fine pulverization process, or the improved pulverization method can be combined with the thermal cracking method or/and the sulfur-removing, plasticizing and mixing methods to combine the advantages of each method. The waste produced by one of the methods can be effectively utilized by another method, and the combined method of the system can eliminate the waste generated by the conventional method independently, for example, the carbon black residue which is independently implemented from the conventional waste rubber and plastic cracking method, The tar residue, the waste fiber obtained from the conventional pulverization method, the excessively thick rubber block, and the fine rubber powder are all recycled in the combined method. In addition, the pre-processing step of the method of the invention can improve the working efficiency of the subsequent processing steps, for example, the combination of the shear grinding disc type rubber fine pulverizing process and the grinding wheel type rubber fine pulverizing process, thereby improving the production of 100-200 mesh fine rubber powder. The rate of the fine grinding process of the shearing disc type rubber, the fine grinding process of the grinding wheel type rubber and the combination of the heating, sulfur breaking, plasticizing and mixing processes, the obtained reclaimed rubber product does not need to be repeatedly masticated, thereby saving energy consumption.

 In order to achieve the second object of the present invention, the above concepts of 11 to 13 are proposed, gp: combining ordinary carbon black production with heat and electric energy discharge with a large amount of energy-consuming waste rubber and plastic recycling processing to make carbon black production and The energy and materials between the recycling process of waste rubber and plastic can be fully utilized.

 The combined regeneration process of the first and second objects of the present invention is realized, that is, a whole component utilization, no waste disposal, a process energy consumption bottom, a large number of appreciation products, a large product use, and a multi-strain market treatment method.

 The idea of an integrated device that can be used to implement the aforementioned methods:

 The combination of thermal cracking and non-thermal cracking of waste rubber and plastic polymer materials is as follows:

 15. An integrated device comprising a thermal decomposition of waste polymer materials and performing fine, ultrafine pulverization, or/and processing of sulfur, plasticization, mixing, and the like.

 16. A sub-assembly device for performing three different treatments on waste polymer materials, namely a sub-assembly device A for performing thermal cracking processing on a polymer material, and a sub-combining device for performing processing such as fine or superfine pulverization B, or / and a sub-combination device C that performs processing such as sulfurization plasticization, mixing, kneading, etc., is recombined to become an integrated device containing a combination of A and B or / and C functions.

 17. The aforementioned sub-assembly device A, (hereinafter referred to as sub-device A or combination device A), includes: a well-known combination device for performing thermal cracking or the like on a high molecular material.

 18. The aforementioned sub-assembly device B, (hereinafter referred to as sub-device B or combination device Β), comprises: a known combination device comprising a roller mill, or/and a known combination device comprising a shear mill fine crusher;

 The sub-device Β includes: The present invention combines the grinding wheel assembly device (honing) used in the normal temperature fine or superfine pulverization process currently performed separately, and the shearing disc assembly device (Β shearing), and then combines them into a joint A combination device (honing, shearing) that performs a fine temperature or ultrafine pulverization process at room temperature.

 19. The aforementioned sub-assembly device C, (hereinafter referred to as sub-device C or combination device C), includes: a well-known combination device for implementing a reclaimed rubber process;

 The sub-device C, including: The present invention eliminates the reintegration device of the refining processing device from the conventionally known combination device for implementing the reclaimed rubber process.

 The combination between the normal temperature pulverization or the room temperature pulverization and the regenerative glue branch integration device, specifically:

 20. The grinding wheel combination device (B-grinding) used in the normal-temperature fine or ultra-fine pulverization process which is currently implemented separately, the shearing disc assembly device (B-cut), and then combined into a grinding machine containing a grinding wheel and a shearing disc unit, The treated materials can be processed into a combination device (B grinding, shearing) which is finer than 100 mesh rubber powder.

21. In the current shearing disc assembly (B-stage shear) used in the fine or superfine pulverization process, only one stage of the shearing disc unit pulverizing machine is provided, and at least a two-stage shearing disc is provided. Unit pulverizing machine in series Combination device B (B secondary shear).

 22. The apparatus for grinding a grinding wheel and a shearing disc unit according to the above concept 19. The processing material can be processed into a combination device (B grinding, shearing) of at least 100 mesh rubber powder and a known reclaimed rubber. The combined device C of the process is combined into an integrated device of (B-grinding, shearing) and C.

 23. After the classifying device in the grinding wheel assembly (B grinding), a machine capable of adding plasticizing aids and mixing is provided.

24. A combination of a combination device B capable of processing the treated material into at least 100 mesh rubber powders and a conventionally known reclaimed rubber process, eliminating the C of the refining treatment device, and combining them into B and C Integrated device.

 25. A classification efficiency is higher between the fine or ultrafine powder pulverizer discharge port and/or the subsequent sieving powder collection bin and the mechanical sieve and the fine powder collection bin. The combination device of the rubber powder size fractionation section of the mechanical sieve, the rubber powder size fractionation assembly device is characterized in that the particle size classification combination device is composed of a gravity-flow particle classifier and a cyclone separator in series.

 The gravity-flow particle classifier described therein has the following effects, specifically:

 Carrying the mixed particle size rubber powder material into the gravity-flow particle classifier in one wind; at least one section of the gravity-flow particle classifier is required to make the air flow of the mixed-size rubber powder material decelerate in the primary air, so that once The coarse-grained powdery material carried in the airflow can be deposited; the secondary airflow and the gravity-carrying flow of the particulate material meet at the primary deceleration section of the primary wind; no material flows from the secondary airflow to the leakage equipment during shutdown After the airflow of the primary particle carrying the mixed-size rubber powder material collides with the secondary airflow, the coarse particles fall vertically, and the fine particles enter the cyclone separator with the tail wind, and the coarse particles enter the tail air flow to be controllable; At present, the section where the particle size of the rubber powder is only used by the swing sieve or the centrifugal sieve is at least doubled.

 Including the combination of common carbon black and integrated equipment used in the recycling of waste rubber and plastic polymer materials, specifically:

26. The integrated device E for producing ordinary carbon black and the integrated device A for performing thermal cracking of waste polymer materials or/and the integrated device B for performing fine and superfine pulverization, or/and performing plasticization, mixing, etc. An integrated device C of the processing sub-assembly device and/or an integrated device D for performing hot extrusion, and then integrated into an integrated device;

 When specifically referring to the production capacity of the combination of common carbon black and integrated equipment used in the recycling of waste rubber and plastic polymer materials, please pay attention to the following parameters:

a. 10,000 tons/year carbon black standardized design equipment using oil (coal tar: ethylene tar: eucalyptus oil = 20: 50: 30), its carbon black furnace exhaust gas can be used for dry base exhaust gas 11000NM ³ , using it as a fuel, the annual collection is equivalent to 1,500 tons of standard coal, and enterprises that use carbon black furnace tail gas to generate electricity will usually lose 50% of the electricity generated to the commercial grid;

 b. The thermal power plant consumes 200~400 grams of standard coal per kilowatt hour, and the standard coal volume per ton can generate steam of 5~7 tons; c "thermal cracking" technology can crack waste tire into 45% fuel oil, 35 % carbon black, 10% steel wire, 10% flammable gas;

 d. The annual rated power of the 10,000-ton waste tire rubber powder is about 960 ;; e. Recycled plastic, the power consumption per ton is in the range of 150-1500 kWh;

 f. Recycling of used tires, the average power consumption of producing 1 ton of reclaimed rubber is 1200 kWh, and the production of 1 ton (40~80 mesh) of rubber powder consumes an average of 600 dry watts of electricity. The power consumption is 200 kWh;

 g. The average power consumption of producing 1 ton of ultra-fine rubber powder equal to 100 mesh is 500-550 dry watt-hours.

 Technical solutions

 A method for co-production of a waste rubber or plastic polymer material combination regeneration or regeneration process and a common carbon black phase combination, in particular, a technical solution realized by the concepts 1 to 11 of the first object of the present invention, characterized in that:

 The combination of the two major types of treatment processes involving thermal cracking and non-thermal cracking of waste polymer materials includes at least a combination of the following three steps, specifically - step I, performing a cutting or cutting of a part of the waste polymer material or The coarse product is processed to obtain the intermediate product group I, and the intermediate product group I includes, but is not limited to: a large rubber block of 50~800x50~800mm waste polymer material, or a waste polymer material particle of 5~200 mesh, or Waste polymer material powder and miscellaneous fiber skeleton;

 Step II, performing heat cracking and subsequent processing on another part of the waste polymer material, or/and the miscellaneous fiber skeleton in the intermediate product group I of the step I, to obtain the product group II and the intermediate product group; the product group II , including: pyrolysis oil or / and its fractionation, distillation products, or metal framework and pyrolysis oil or / and its fractionation, refined product; said intermediate group II, including: thermal cracking carbon black residue or tar Slag

 Step III, mixing the thermally cracked carbon black slag or/and tar residue in the intermediate product group II obtained in the step II with the 5~200 mesh waste polymer material powder in the intermediate product group I obtained in the step I, and implementing the super Finely pulverizing or/and heat-treating, plasticizing, mixing, and obtaining product group I, said product group I, including but not limited to: a mixture of ultrafine rubber powder and carbon black powder, in the mixture The ultrafine rubber powder can pass through the 100 mesh screen, and the carbon black powder can pass through the 200 mesh screen; or the colloidal mixture of the pyrolysis carbon black and the plasticized waste polymer material which is finer than 200 mesh;

That is, after the recycling of the waste polymer material combination, the product group I and the product group II can be obtained; the product group I, including but not limited to: a mixture of the ultrafine rubber powder and the carbon black powder, in the mixture Superfine rubber powder Both 100 mesh screens can be passed through, and the carbon black powder can pass through a 200 mesh screen. The mixture product can be a particle size fractionated or mixed product including, but not limited to, a range of 100-200 mesh; or a thermal cracking carbon black finer than 200 mesh. And a powdered or/and colloidal mixture of the plasticized waste polymer material; said "Product Group 11", which comprises: a pyrolysis oil or/and a fine fractionated product thereof, or a metal skeleton and pyrolysis oil or/and Its fine products.

 The combined recycling method further characterized by:

 Control the 50~800x 50~800mm waste polymer material in the intermediate product group I, or / and the 5~200 mesh waste polymer material powder by controlling the type and quantity of the feed in step I and step II. The ratio of the weight of the thermally cracked carbon black in the intermediate group II is in the range of 100:10 to 900, especially in the range of 100:20 to 60 and 100:400 to 900;

 Control the rubber blocks of 50~500x 50~500 waste polymer materials in the intermediate product group I, or/and the waste polymer materials of 5~200 mesh, by controlling the type and quantity of the feed in step I and step II. The ratio of the weight of the tar residue in the intermediate product group II is in the range of 100: 2 to 100, particularly preferably in the range of 100: 2 to 20.

 The foregoing step II involves the processing of heat cracking of another portion of the waste polymer material together with the chopped fiber skeleton in the intermediate product group I of the step I; and the step III involves the thermal cracking of the carbon in the intermediate product group II obtained in the step II. The black slag or/and the tar residue are mixed with the 5~200 mesh waste polymer material powder in the intermediate product group I obtained in the step I, and subjected to ultrafine pulverization or/and heating to break sulfur, plasticize and mix; These two items can be independently implemented by means of purchasing/selling materials to the market.

 The method for recycling and recycling of waste polymer materials further involves implementing a complementary scheme for each of the current temperature pulverization or room temperature pulverization and reclaimed rubber branches, and the scheme can be independently implemented.

 Wherein the advantages and complementary schemes are implemented between the branches of the normal temperature pulverization process, and the characteristics are: a 50~800x50~800mm bulk waste polymer material which does not contain harmful impurities such as a metal skeleton is placed in the grinding wheel assembly device. In the feeding hopper, after the bulk material is processed by the grinding wheel type rubber fine pulverizer, the bulk waste polymer material is ground into a mixed rubber powder of 20~200 mesh, and then the non-entrained non-mixed rubber powder may be removed. Metal fiber impurities or / and fine rubber powder of 100 mesh sieve, mixed rubber powder or coarse rubber powder not passing through 100 mesh sieve, and then mixed with additives such as powder isolation, and then introduced into a shearing disc type rubber fine pulverizer Re-pulverization, the pulverized material is introduced into the cyclone by a gas flow, and the exhaust gas of the cyclone is evacuated or/re-used by the dust remover, and the pulverized material collected in the cyclone is introduced into a mesh sieve of 100 mesh. Separation, after the coarse material of the 100 mesh net is collected, the raw rubber powder is mixed with the powder and other additives to mix and pulverize the operation, and the material is collected and then introduced into the finished product warehouse; Including but not limited to the details equal to 100, 110, 120, 130, 140, 150, 160, 170, 180, 190, 200 of each hierarchical level or a mixed powder of the finished product, which can be sold as a commodity.

 An advantageous complementary scheme is implemented between the branches of the room temperature pulverizing process, and an improvement scheme of the shearing disc method in the normal temperature pulverizing process, which is characterized in that: it is obtained in a well-known fine grinding process of shearing disc type rubber, It has at least 30% by weight of a mixed particle size rubber powder capable of passing through 200 mesh, and is further pulverized at least once in a shearing disc type rubber fine pulverizer to make it a mixed particle diameter of at least 75% capable of passing 200 mesh. Glue powder material; This improvement scheme is especially suitable for the crushing operation of rigid materials and polymer materials such as thermal cracking carbon black slag with coarse meshes such as 5~20 mesh, because this solution can effectively avoid the ultrafine pulverization of one-pass machine, often There is a disadvantage that the obtained product has a rigid material such as carbon black which is coarser than 200 mesh.

 The invention further comprises a subsequent plasticizing modification scheme of the fine rubber powder obtained by the grinding wheel pulverization method in the normal temperature pulverizing process, which is characterized in that: in the subsequent processing of the fine rubber powder obtained by the grading process of the grinding wheel pulverizing process, the mixing plasticizing aid is set The plasticizing aid is a known material or/and a formulation mixture using a known material, and the fine rubber powder is preferably as small as 100 mesh.

 Wherein the room temperature pulverizing and reclaiming rubber each branch process implements a complementary complementary scheme, which is characterized by: a classified 50~800x50~800mm bulk waste polymer material containing no harmful impurities such as a metal skeleton, placed in a grinding wheel combination In the feeding hopper of the device, after the bulk material is processed by the grinding wheel rubber mill, the large waste polymer material is ground into a mixed rubber powder of 20~200 mesh, and then the mixed rubber powder may be removed. Non-metallic fiber impurities, mixed rubber powder and then mixed with additives such as powder isolation, and then introduced into a shear-grinding rubber fine pulverizer for re-pulverization, and the pulverized material is introduced into a classifier and a cyclone by a gas stream, and the cyclone separator After the exhaust gas is emptied or/re-used by the dust remover, the pulverized material collected in the cyclone separator is introduced into the inter-storage storage silo, and the subsequent processing of the obtained pulverized material is connected with a well-known reclaimed rubber process; Contains at least 80% of the rubber powder that can pass through the 100 mesh screen, and the fine (80-100 mesh) and ultrafine rubber powder (finely equal to 100 mesh) are mixed. The compound replaces the 5~40 mesh coarse powder currently used in the reclaimed rubber process, which can reduce the refining operation in the reclaimed rubber process by at least 50%.

 Wherein the room temperature pulverizing and reclaiming rubber each branch process implements a complementary complementary scheme, which is characterized in that: the rubber powder obtained by pulverizing at room temperature and at least passing through the 100 mesh screen is connected with the well-known reclaimed rubber process, but the well-known The final refining operation in the reclaimed rubber process.

As mentioned above, the polymer material, in terms of material classification, refers to: one or one containing rubber, plastic, plastic. A mixture of the above formulas; or from the classification of products containing rubber, plastics, and plastics, including: but not limited to, conveyor belts, timing belts, sealing strips, woven bags, tires, tapes, hoses, rubber shoes, rubber sheets One or more formula mixture products of fibers, film bags, ropes, pots, and the like.

 The method of the present invention further provides a treatment scheme for recycling waste fibers obtained from waste polymer products such as tires and tapes, and is characterized in that: waste fiber and plasticized rubber material or/and The oily material is mixed at a weight ratio of 100:5 to 100 to obtain a felt-like or rubber-like felt-like mixture; the plasticized rubber material and the oil-based material contain at least one or more of the following materials-

(a) oily plant kernels, fruit materials, (b) vegetable oils, resins and derivatives, (c) oily and decolorizing sludge materials, (d) rubber and plastic softeners, and (e) vulcanized rubber powder Modified, (f) rubber, plastic emulsion;

 ' (a) Oily plant kernels, fruit materials, including but not limited to: Tung tree seed kernels, olive oil kernels, coconut kernels, cotton seed kernels, rapeseed, peanut kernels, soybeans, palm kernels, safflower seeds, sunflower seeds, Tea kernels, linseed, Suziren, rubber kernels, olive oil, black scorpion kernels, wenwan nuts, mountain almonds, wool seeds, medlar, berberine, eucalyptus, walnut, and samara , one or more combinations of immature pine nuts, etc.;

 (b) Vegetable oils, resins and derivatives, including but not limited to: corn germ oil, rice bran oil, cottonseed oil, rapeseed oil, peanut oil, soybean oil, palm oil, sunflower oil, olive oil, tea oil, coconut Kernel oil, tung oil, linseed oil, black scorpion seed oil, sage oil, restaurant oil, rosin, Taikoo oil, hydrogenated rosin, dehydrogenated rosin, rosin glyceride, rosin pentaerythritol ester, xylene rosin resin, rosin ester, One or more combinations of pine resin, metase resin, eucalyptus resin, peach resin, waste peanut pulp, and the like;

 (c) Degreased slag-containing materials, including but not limited to: one or more combinations of oils, oils, fats, fatty acids, or clay slag, which are discarded in the decolorization and purification section of the refinery;

 (d) Common softeners for rubber and plastics, including but not limited to: lubricating oil, engine oil, white oil, halogenated paraffin oil, paraffin oil, third-line oil, six-line oil, transformer oil, polybutene oil, C4~18 fatty acid, petroleum jelly , halogenated paraffin, paraffin, beeswax, animal oil, black grease, white grease, odorless asphalt, emulsified asphalt, epoxidized soybean oil, alkyl phenolic resin, bismuth resin, petroleum resin, octyl phenolic resin, ancient horse Long, styrene resin, low molecular weight polyethylene wax, low molecular weight polypropylene wax, stearic acid, palmitic acid, oleic acid, palmitic acid, polyvinyl alcohol, pentanol, hexanol, heptanol, octanol, sterol , decadiol, tetradecanol, cetyl alcohol, stearyl alcohol, cyclopentanol, cyclohexanol, benzyl alcohol, ethylene glycol, propylene glycol, glycerol, 2-ethylhexanol, 2-octanol, Lauryl alcohol, terpineol, (C7~18) mixed fatty alcohol, pentaerythritol, xylitol, dipropylene glycol, dibutyl phthalate, diisobutyl phthalate, phthalic acid diester Alcohol ester, tributyl phosphate, phosphoric acid Ethyl ester, triphenyl phosphate, tricresyl phosphate, diphenyl-2-ethylhexyl phosphate, dioctyl terephthalate, dioctyl adipate, di-2-ethylhexyl adipate One or more combinations of esters, di-2-ethylhexyl sebacate, and the like;

(e) a modified product of vulcanized rubber powder, including but not limited to: one or one of a sulfurized rubber powder, a sulfurized plastic compound modified with a vulcanized rubber powder, a recycled rubber emulsion, an emulsion of a rubber powder modified asphalt, and the like. Combination of the above;

 (f) Rubber and plastic emulsions, including but not limited to: one or more combinations of rubber emulsion, rubber asphalt emulsion, waste plastic asphalt emulsion, and the like.

 As mentioned above, the method may further comprise a product of re-circulating waste fiber, which is characterized by: (waste ratio) of waste fiber and plasticized rubber material or/and oil (100%): 5-100 A felt-like or glue-like, linoleum-like mixture obtained by matching.

 The technical solution realized by the concepts 12 to 14 of the second object of the present invention is characterized in that:

 The tail gas generated in the production process with flammable gas and residual heat is recovered by the waste heat boiler, and the steam is converted to supply the heating required for the recycling of the waste rubber and plastic polymer materials;

 Or / and the electric energy generated from the waste gas generated in the production process with flammable gas and residual heat, converted from waste heat boilers and steam turbines, to the mechanical electricity used for the recycling of used rubber and plastic polymer materials;

 The production process of generating combustible gas and residual heat includes, but is not limited to, ordinary carbon black production, coke production, reduction iron making, steel making, and the like.

 Or / and combustible gas and / or fuel oil obtained by thermal cracking of waste rubber and plastic polymer materials to carbon black for carbon source and fuel.

 The conventional carbon black production process refers to the production of carbon black by using a hydrocarbon as a carbon source, incomplete gas phase combustion or thermal cracking, and the production device is accompanied by a carbon black production process in which combustible heat exhaust gas is discharged.

 The waste rubber and plastic polymer materials are reprocessed, including but not limited to the combination of one or more regeneration processes as described below:

Thermal cracking of used tires, thermal cracking of waste rubber, waste plastics, thermal cracking of plastics, recycled rubber from waste tires, recycled rubber from waste rubber, rubber particles from waste tires, powder, rubber particles from waste rubber, powder, waste plastic , plastic particles, powder, waste rubber or / and plastic compound, waste rubber or / and plastic powder; The heating required for the recycling of the waste rubber and plastic polymer materials includes, but is not limited to, one or more processing requirements as described below:

 Promote the steam turbine generator equipped with the waste rubber and plastic polymer material recycling processing production line, the sulfur-reducing heating tank used for heating the recycled rubber, and the mixing tank for heating the rubber powder;

 The mechanical power for recycling waste rubber and plastic polymer materials is characterized in that: the electric energy supply is not directly supplied through a commercial power grid.

 An integrated device for implementing the method of the present invention, in particular, a technical solution realized by the concepts 15 to 26 of the third object of the present invention, characterized in that it involves two major types of integrated devices, thermal cracking and non-thermal cracking. Combined, specifically:

 A sub-assembly A comprising a process of thermally cracking a waste polymer material, or/and a sub-device B processed by fine or ultra-fine pulverization, or/and a sub-device C processed by a process such as sulfurization plasticization, mixing, etc. An integrated device, characterized in that: organic combination of sub-devices 8, B, C is obtained, including by sub-devices A and B or/and C in a well-known configuration, by adding and subtracting their respective sub-setting settings After reintegration.

 The sub-device A described therein refers to: thermal cracking of a polymer material to obtain a pyrolysis oil, thermal cracking carbon black, or thermal cracking of carbon black, metal skeleton, pyrolysis oil, or obtaining pyrolysis oil, tar Thermal cracking of products such as slag and devices for pre- and subsequent processing;

 The sub-device B described therein refers to: finely pulverizing the polymer material to obtain a mixed powder of 40-120 mesh, or super-fine pulverization to obtain pulverization and pre-preparation of products such as powders which are finer than 100 mesh, The device for subsequent processing; wherein the sub-device C refers to: performing processing such as sulfurization, plasticization, mixing, kneading, etc. on the polymer material to obtain plasticization of the plasticized plastic and its pre- and subsequent processing s installation.

 The integrated device, wherein the sub-device A comprises a thermal cracking furnace or a tank or a column or column or a rotary kiln, a "thermal cracking oil" storage silo of "product group I", or a "thermal cracking oil" storage material The warehouse and the "metal skeleton" aggregate mechanism, the "thermal cracking carbon black" storage silo of "intermediate product group I", or the "tar residue" storage silo, pool, etc.;

 The device B includes a normal temperature fine pulverizer, or a normal temperature fine pulverizer and a coarse crusher, and a "5~200 mesh polymer powder granule" storage silo of the "intermediate product group II", "mechanical fiber skeleton" set. Material mechanism, placed in "Product Group II" "thermal cracking carbon black and waste polymer materials are finer than 100 mesh powder" mixture storage bins;

 The apparatus C therein comprises a heat-pressurizable stirred tank or kettle, or a coarse crusher and a heat-pressurizable stirred tank, a kettle, or an internal mixer, or an extruder, and the "intermediate product group" is placed. II ""5~40 mesh polymer powder pellets" storage silo or place, "cocellaneous fiber skeleton" aggregate mechanism, placed "product group II" "fine 200 mesh thermal cracking carbon black and plasticized A colloidal "mixture location of waste polymer materials, etc.

 The integrated device and the improved combination of the sub-devices 8, B, C, further characterized by - wherein the sub-device A comprises a carbon black processing section of a known thermal cracking kit for treating waste tires, etc. To the matching carbon black ultra-fine pulverization or / and ultra-fine carbon black bagging equipment; between the raw material inlet before the cracking furnace or tank or column or column or rotary kiln and the "miscellaneous fiber skeleton" collecting mechanism of sub-device B a mechanism for inputting the chopped fibers; a transport mechanism disposed between each of the grading storage bins and the sub-device B of the "thermal cracking carbon black" powder having a fineness of 5 to 250 mesh; or "thermal cracking at a fineness of 200,500 mesh" The carbon black "fine powder storage silo and the sub-device C are provided with a mechanism for transporting carbon black; wherein the sub-device B includes the fine-grained material of the well-prepared finely pulverized or superfine pulverized equipment for treating the waste tire rubber. A mechanism for inputting carbon black is disposed between the mechanism of the storage bin or the batching section and the sub-assembly A; and a mechanism for conveying the chopped fibers is disposed between the "heterofiber skeleton" collecting mechanism and the sub-assembly A;

 The sub-assembly C therein includes a fine-grained storage of 200-mesh "thermal cracking carbon black" with sub-assembly A before the known dynamic desulfurization tank or kettle or kneading or extrusion equipment for the production of recycled rubber equipment. A mechanism for inputting carbon black is disposed between the silos; and a mechanism for transporting the chopped fibers is disposed between the "heterofiber skeleton" collecting mechanism and the sub-device A.

 The integrated device, the core device in the sub-device A - a thermal cracking furnace or a tank or a column or column or a rotary kiln, and the core device in the sub-device B - a fine pulverizer, or a core in the sub-device C The distance between the device - the sulfur can or the kettle or the kneading or extrusion equipment is preferably no more than 200 meters.

 The mechanism for conveying carbon black and miscellaneous fibers in the integrated device refers to: one or a type of a screw conveyor, a scraper conveyor, a chain bucket conveyor, a pipe chain conveyor, an air conveyor, a conveyor truck, and the like. The combination above.

 The mechanism for conveying tar residue in the aforementioned integrated device means: one or a combination of one or more of a conveying pipe, a tank truck, or a carrier when the material is in a solid state.

 The integrated device further includes:

 An operating machine capable of transferring the thermal cracking carbon black which can be passed through the 180-250 mesh screen obtained in the sub-device A to the sub-device B is provided, and 5 to 30 in the carbon black and the sub-device B are disposed. The objective powdery granular polymer material is superfinely pulverized into an operating machine finer than a 100 mesh mixture;

Or it is provided that the thermal cracking carbon black which is finer than 200 mesh, preferably finer than 500 mesh, obtained in the sub-device A can be added to the sub-device C, and then mixed with the granular polymer material of 5 to 30 mesh. , become a roller to connect Operating machinery for the gum-like mixture;

 Or an operating machine capable of carrying out the mixing of the pyrolysis tar slag obtained in the sub-device A into the pulverizing processing sub-unit B and mixing with the mixture powder which has been pulverized into a 100-mesh sieve;

 Or it is provided that the hot cracked tar residue obtained in the sub-device A can be transported to the sub-device C, and then formulated with 5~30 mesh powdery granular polymer materials, and then subjected to high-temperature mixing treatment to become a roller. An operating machine capable of contiguous compound mixture;

 Or an operating machine capable of performing the thermal cracking treatment of the broken and sieved fibers in the sub-device B or the sub-device C and transporting them to the sub-assembly A for thermal cracking.

 The combined recycling method, wherein the step I is completed in a coarse crushing and screening device disposed in front of the core device in the sub-device B or/and the sub-device C of the integrated device; II is completed in the core of the sub-device A of the integrated device and its subsequent supporting processing; wherein the step III is the core in the sub-device B or/and the sub-device C of the integrated device and its subsequent supporting This is done in a treated apparatus, including fine, ultrafine pulverization, mixing, etc. in B, or / and high temperature tanks, mixers, extruders, etc. in C.

 The integrated device for implementing the method of the present invention further relates to a combination setting of B or B and C between the current room temperature pulverizing or normal temperature pulverizing and regenerating rubber branching integrated devices, and the combined setting can be independently implemented, specifically There are: an integrated complementary solution between the integrated devices B used in each branch of the normal temperature pulverization process, which is characterized in that: the storage rubber powder or rubber powder in the well-known grinding wheel type normal temperature fine pulverizing combination device (B roll) is isolated from the powder. a storage bin of the agent mixture, and a guide mechanism is provided between the feed port of the shearing disc fine pulverizer in the shearing disc type rubber fine pulverizing combination device (B shear), and the original (B shear) is retained in the shearing The grinding disc finely pulverizes the mechanical unit of the core unit, the subsequent mechanical setting, and retains the original mechanical setting of the storage bin of the original (B-roll) in which the rubber powder or the mixture of the rubber powder and the powder release agent is stored;

 An advantageous complementary scheme is implemented between the integrated devices B used in each branch of the room temperature pulverization process, and is characterized by: fine pulverization, wind-driven spiral separation of pulverized materials in a known shear-grinding type rubber fine pulverizing combination device (B-shear) After the exit, at least one set of the mechanism of pulverizing and wind-extracting materials which are mechanically connected in series by the shear-grinding type fine pulverization and the wind-guided spiral separation unit is set, and the conventionally known shear-grinding type rubber fine pulverizing combination device (B- The first-stage fine pulverization in the stage shear is set to at least a fine pulverization setting containing two stages in series, that is, a combined device (B secondary shear);

 In the grinding wheel assembly device (B mill) in the normal temperature pulverization method, a modification scheme for the plasticizing treatment device for the fine rubber powder is added, which is characterized in that: after the classification device in the grinding wheel assembly device (B grinding), the setting can be added. a plasticizing aid, a mixing machine, the machine includes at least a mixing machine, a kneading machine, a mixing screw machine, a material tank for placing a plasticizing agent, and a rubber powder mixture, or the like The above combination,

 The B and C between the room temperature pulverizing and reclaiming rubber sub-devices implement a complementary complementary scheme, which is characterized in that: at least 60% of the storage of the fine pulverizing combination device (rolling roll) or / and (Β shear) at room temperature is over 100%. a material guiding device is arranged between the rubber powder storage bin of the mesh screen and the coarse rubber powder storage bin or/and the high temperature tank or/and the internal mixer or/and the screw machine in the known reclaimed rubber combination device C;

 The guiding mechanism also refers to: one or more combinations of a screw conveyor, a scraper conveyor, a chain bucket conveyor, a pipe chain conveyor, a gas conveyor, and a conveyor carrier.

 A classification efficiency is higher between the fine or superfine pulverizer discharge port and/or the subsequent sieving powder collection bin and the mechanical sieve and the fine powder collection bin than the existing mechanical sieve only. A combination device of a rubber particle size classification section, and a technical solution realized by the concept 25 of the present invention, characterized in that:

 The rubber particle size fractionation assembly device is composed of a cyclone separator 1 and a gravity to air flow particle classifier;

 The gravity-flow particle classifier described therein is preferably characterized in that it is used in the following form, specifically: a primary air inlet duct 2 is provided, and a primary air carrying a mixed particle size rubber powder is introduced into the gravity-flow air particle classification. Set the deceleration section 3 to slow down the primary wind speed to separate and deposit the coarse and heavy rubber particles; set the horizontal or upwardly inclined tail passage 4 to separate from the gravity-flow particle classifier When the fine particles are gone, try not to take the coarse rubber powder; set the secondary air inlet duct 5 inclined or vertically downward to prevent the material from leaking out during the stop; at the perigee of the deceleration section 3, set The intersection of the secondary airflow and the gravity flow of the particulate material collides with the collision point 6, the intersection collision point 6 is at least one set in the gravity-flow particle classifier; the coarse particles separated in the gravity-flow particle classifier are set vertically The falling lane 7 flows out of the gravity ~ airflow particle classifier.

 In the structural features of the gravity-flow particle classifier as described above, the method further includes:

 The collision point between the secondary air flow and the gravity flow of the granular material is 6, and the collision angle of the two flows is preferably less than or equal to 90°, and the departure angle after the collision of the two flows is preferably greater than or equal to 120°;

The flow segment that decelerates the primary wind, specifically, the air passage is set such that the linear velocity of the primary wind is slower than the primary wind before the airflow is set in the air passage, that is, the section is set. The cross-sectional area of the air duct is larger than the cross-sectional area of the air duct of the section. A technical solution achieved by the concept 26 of the third object of the present invention is characterized in that:

 An energy and material conveying mechanism is disposed between the carbon black production unit E and the production equipment A or / and B or / and C or / and D of the secondary rubber and plastic secondary recycling processing;

 The conveying mechanism has characteristics including but not limited to:

 Waste heat recovery steam storage package in carbon black production unit E and production equipment for waste rubber and plastic secondary utilization processing (thermal cracking A or / and rubber powder B or / and reclaimed rubber C or / and extrusion granulation D Between the turbine generator or / and the steam pack, or / and (in the reclaimed rubber B) between the sulfur-reducing heating tank is provided with a pipeline for conveying steam;

 Or / and waste heat recovery in the carbon black production unit E steam storage steam drum or / and steam turbine with waste rubber, plastic secondary processing production equipment (thermal cracking A or / and rubber powder B or / and reclaimed rubber C or / and the steam packet in the extrusion granulation D), or / and (in the reclaimed rubber B) between the sulfur-reducing heating tank is provided with a pipeline for conveying steam;

 Or / and turbine generators that recover electrical energy from steam in carbon black production unit E or / and transformers of the original commercial grid with secondary rubber and plastic secondary processing (thermal cracking A or / and rubber powder B or / And a regenerative glue C or / and extrusion granulation D) between the power supply transformer or / and the motor in the production device, is provided with a cable for transmitting electrical energy;

 Or / and in the thermal cracking furnace in the thermal cracking A production plant of waste rubber and plastic secondary processing or / and the combustion furnace in the gas storage, oil conservator and carbon black production device E or / and gas storage, oil storage Between the cabinets, there are pipes for conveying flammable gas and fuel.

 The integrated device for implementing the method of the present invention is preferably provided with dustproof, muffling, exhaust gas purification, water treatment mechanism, and automatic control mechanism.

 According to the technical solution of the present invention, the industrial department may select one or more combinations according to the needs of the present invention, and of course, the full implementation is the best.

 The positive significance of the invention lies in: combining the independent methods of secondary recycling and recycling of waste rubber and plastic polymer materials in the present market, so that their advantages and disadvantages can make up for each other, and the whole waste rubber and plastic polymer can be made. The material recycling industry has stepped into clean, full-component, high-value utilization channels. On this basis, it has also proposed that the second largest raw material producer in the rubber products industry, carbon black producers, participate in waste rubber and plastic polymer materials. The recycling industry has its own industrial advantages. When the carbon black production equipment is combined with the waste rubber and plastic polymer material recycling equipment, it can also make the waste rubber and plastic polymer materials recycling industry into energy-saving, clean and complete. A better state of use of components and high value.

DRAWINGS

 1 is a schematic diagram of an integrated apparatus of Embodiment 1; FIG. 2 is a schematic diagram of an integrated apparatus of Embodiment 2; FIG. 3 is a schematic diagram of an integrated apparatus of Embodiment 3; FIG. 4 is a schematic diagram of an integrated apparatus of Embodiment 4. FIG. FIG. 6 is a schematic diagram of an integrated apparatus of Embodiment 6; FIG. 7 is a schematic diagram of an integrated apparatus of Embodiment 7; FIG. 8 is a schematic diagram of an integrated apparatus of Embodiment 8; FIG. 10 is a schematic view showing an embodiment of a rubber particle size-grading combination machine according to 24 to 1 in the embodiment 24; FIG. 11 is a schematic view of the embodiment 24; - Figure 2 is a schematic diagram of another gravity-flow classifier in the rubber particle size fractionation combination machine; Figure 12 is another gravity-flow in the rubber particle size fractionation combination machine of 24-3 in Example 24. 13 is a schematic diagram of an integrated device of Embodiment 25; and FIG. 14 is a schematic diagram of an integrated device of Embodiment 26.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The following is a description of the embodiments of the present invention, and is not to be construed as limiting the scope of the invention.

 Example 1.

 The method for recycling combined regeneration in the present embodiment relates to a combination of thermal cracking and ultrafine pulverized polymer material recycling branch processing, and an integrated device used in the same, and the method has the following three steps: The embodiment is specifically:

 Step I, taking 175 parts by weight of the scrap tire of the car, placing it in the batch pretreatment section of the sub-device B in the integrated device, and first breaking it into about 5 cm X 5 cm by the shear crusher in the sub-assembly device B. The pieces are further crushed, sieved, fiber-captured, and magnetically separated by a groove roller machine and a vibrating screen and a magnetic separator. The intermediate product group I is obtained, in the middle of the example. The product group I comprises: a 20-mesh car waste tire rubber 100 parts by weight and a steel wire, nylon fiber, rubber powder mixture 75 parts by weight;

Step II, taking 70 parts by weight of a 5 cm X 5 cm car scrap tire block and 75 parts by weight of the steel wire, nylon fiber, and rubber powder mixture obtained in the step I, and placing the same in the sub-device in the integrated device In the section, put the crushed rubber block and the mixture of steel wire, fiber and rubber powder into the batching bucket, and then mix the proper amount of the known catalyst into the material (for example: 0.5 part of diatomaceous earth, 0.5 part of silica-alumina molecular sieve, or waste rubber cracked carbon). 1 part of black powder), after stirring, push the material with a screw feeder Into the thermal cracking reactor, the material stays in the gap tank at 300 ~ 400 ° C for about 30 ~ 40mi _n (or about 2 ~ 6min in the continuous tank), turned into charcoal and oil vapor. The oil vapor is discharged through the top of the furnace, and then subjected to alkali absorption, fixed bed, catalytic cracking, condensation, and separation processes to obtain pyrolysis diesel, gasoline, gas, gas, and then used to support the combustion of the pyrolysis furnace, and the heat obtained by condensation separation Pyrolysis of diesel oil and gasoline into the oil storage tank; carbon is discharged through the bottom outlet of the furnace, and after cooling, coarse crushing, magnetic separation, sieving, fine crushing, etc., steel wire and fine carbon with a particle size of 180-250 mesh can be obtained. Black, the steel wire is taken in the steel wire hopper, and the obtained fine carbon black is collected in the fine carbon black collection bin; after the operation of step II, the product group II and the intermediate product group II are obtained, the product group II, This example refers to: 49 parts by weight of steel wire and 45 parts by weight of pyrolysis oil; the intermediate product group II, which is obtained in this example: 30 parts by weight of fine carbon black which can pass through a sieve of 180-250 mesh Step III, taking 30 parts by weight of the pyrolysis fine carbon black in the obtained intermediate product group II and 100 parts by weight of the 20-mesh car waste tire rubber particles in the intermediate product group I obtained in the step I, and placing them in the integrated device Super in sub-device B In the batching section before the fine pulverizer, pour them into the formula material mixer, stir them and then introduce them into the high-level collection bin of the ultra-fine pulverized material. The mixture material is introduced into the elastomer fine pulverizer through the drop tube, and the material is guided by the wind guide. Duct, cyclone separation, sieving treatment, 130 parts by weight of a mixture of thermally cracked carbon black and waste tire rubber powder of 100 mesh sieves, which was collected into a 100 mesh mesh rubber powder and carbon black mixture. In the silo; the carbon black and rubber powder mixture passing through the 100 mesh sieve is much less dusty than the pure carbon black, and it can be used in the rubber product industry to replace the rubber powder, carbon black, zinc oxide or reclaimed rubber, A collection of equal amounts of carbon black and zinc oxide, which is one of the contents included in the product group I of the present invention.

 The method for combined recycling of waste tire polymer materials in the present embodiment, after combining steps I, II, and III, according to the useful products in the product group I - thermal cracking carbon black and waste tire rubber powder (30/100) Proportional requirements, the useful products in product group II - the unlimited amount of steel wire and pyrolysis oil, and the restrictive conditions that do not make the total waste of the product tend to zero.

 The settings of the integrated device used in this embodiment:

 A sub-device A comprising a process for performing thermal cracking on a waste tire, and a sub-device B for performing processing such as normal temperature breaking and pulverization with a waste tire, and an integrated device, characterized in that: a known device A and B are used as sub-devices. Performing an organic combination, based on the well-configured sub-devices A and B, by adding or subtracting the re-integration of their respective sub-sets;

 The sub-device A is obtained by adding and subtracting the original matching settings by the well-known thermal cracking integrated device A. The sub-device A comprises: capable of performing thermal cracking on the waste tire to obtain thermal cracking carbon black and metal. Pyrolysis reactor for skeleton, pyrolysis oil and other products, and its pre-mixing bucket, screw feeder, subsequent supporting alkali absorption device, fixed bed, catalytic cracking unit, condenser, separator, buffer tank, pump, Heat exchange kettle, fractionation tower, diesel condenser, diesel water separator, diesel oil storage, gasoline condenser, gasoline water separator, gasoline storage, and gas storage tank, water sealing tank, crude carbon for processing crude carbon black Black collection bins, coarse crushers, oscillating sieves, magnetic separators, wire hoppers, carbon black crushers, fine anthrax collections, and other warehouses;

 The sub-device Β is obtained by adding and subtracting the original matching settings by using a well-known ultra-fine rubber powder device, and the sub-device Β includes: a formula for stirring 20-piece waste tire rubber particles and fine carbon black. Material mixer, to be ultra-fine pulverized material collection bin, to carry out ultra-fine pulverization to obtain a core device finer than 100 mesh powder product - shear-grinding rubber fine pulverizer, and waste tires set before the core device Crusher, coarse crushing, sieving, magnetic separation crusher, groove stick machine, oscillating screen, magnetic separator, fiber trap, steel wire, nylon fiber aggregate bin, and subsequent support for 100 mesh powder products a treatment device, such as: a cyclone, a dust collector, a centrifugal sieve, and a silo of a mixture of carbon black and rubber powder that has been stored through a 100 mesh sieve;

 The arrangement of the integrated device used in this embodiment further includes: setting a screw conveying mechanism between the fine carbon black collecting bin of the sub-device and the formula mixing machine of the waste tire colloid of the sub-device B; A mechanism for conveying the pulverized fibers is disposed between the steel wire, the smashed fiber hopper, and the batching hopper of the thermal cracking reactor of the sub-assembly A.

 For the setting of the integrated device in this embodiment, refer to the schematic diagram of the integrated device of Embodiment 1. In the schematic diagram:

1 - Sub-device A, including:

 5 - batching bucket, 6 - screw feeder, 7 - thermal cracking reactor, 8 - alkali absorption device, 9 - fixed bed, 10" - catalytic cracking unit, 11 - gas storage cabinet, 12 - Water-sealed tanks, 13 - Diesel condensers, 14 - Gasoline condensers, 15 - Diesel water separators, 16 - Gasoline water separators, 17 - Diesel tanks, 18 - Gasoline tanks, 19 ~ ~ condenser, 20 - separator, 21 - buffer tank, 22 - heating furnace, 23 - pump, 24 - heat exchanger, 25 - fractionation tower, 26 - crude carbon black aggregate Warehouse, 27 - coarse crusher, 28 - shock sieve, 29 - magnetic separator, 30 ^ steel wire hopper, 31 - carbon black crusher, 32 - fine carbon black collection bin;

 2 - sub-device B, which includes -

33——Steel wire, nylon fiber aggregate silo, 34——crusher, 35——groove stick machine, 36——shock screen, 37——fiber trap, 38——magnetic separator, 39-20 Glue collection bin, 40 - formula mixer, 41 - aggregate Warehouse, 42 - shear grinding disc type rubber fine grinder, 43 - cyclone separator, 44 - dust collector, 45 - 100 mesh centrifugal sieve, 46 - carbon black and rubber powder stored in 100 mesh sieve Silo of the mixture;

 3 - a mechanism for conveying the smashed fibers between the wire of the sub-assembly B, the smashed fiber collection bin and the batching hopper of the thermal cracking reactor of the sub-assembly A;

 4 - A screw conveyor is provided between the fine carbon black collection bin of the sub-assembly A and the formulation mixer of the waste tire rubber of the sub-assembly B.

 Example 2.

 The method for recycling and recycling used in the embodiment relates to a combination of thermal cracking, sulfurization, plasticization, and the like, and a combination of the recycling process of waste polymer materials, and an integrated device thereof, and the following three processes are used. The steps are combined, and the embodiment is specifically:

 Step I, taking 175 parts by weight of the car waste tire, and placing it in the dynamic sealed heating tank pre-treatment section of the sub-device C in the integrated device, first breaking it into a compact by the shear crusher in the sub-combination device C 5cm X 5cm pieces, and then use the groove stick machine and the oscillating screen and magnetic separator to further crush, sieving and magnetically separate the 5cm X 5cm rubber block to obtain the intermediate product I. The intermediate product group described in this example I includes: 100~40 parts of scrap car tire rubber particles and 75 parts by weight of steel wire, nylon fiber and rubber powder mixture.

 Step II, taking 70 parts by weight of 5 cm X 5 cm car scrap tire pieces and 75 parts by weight of the steel wire, nylon fiber, rubber powder mixture obtained in the step I, and the waste tire heat in the sub-device A in the integrated device In the feed treatment section before the cracking furnace, put the crushed rubber block and the mixture of steel wire, fiber and rubber powder into the feeding hopper, and then mix the known amount of the catalyst into the material (the same as in the example 1.), stir and use the spiral The feeder pushes the material into the thermal cracking furnace, and the material is retained in the furnace at 300~400 °C for about 30~40min, and becomes charcoal and oil vapor;

 At the same time, another 150 parts by weight of a plastic bag mainly made of waste polyethylene and polypropylene is placed in the feed processing section in front of the waste plastic thermal cracking furnace in the sub-assembly A in the integrated device, and the waste plastic bag is placed. Into the hopper, and then mix the well-known catalyst amount into the material (the same as in Example 1.), stir the sputum and then push the material into the thermal cracking furnace with the screw feeder. The material is in the range of 350~42 (TC stays in the furnace for about 2h). , turned into tar residue and oil vapor;

 The oil vapor in the two furnaces is respectively discharged, condensed and separated by the top of the furnace to obtain pyrolysis oil and gas, and the gas is used to support the combustion of the two thermal cracking furnaces, and the pyrolysis oil obtained by the condensation separation is introduced into the oil storage tank;

 The charcoal in the waste tire thermal cracking furnace is discharged, cooled, coarsely crushed, magnetically selected, sieved, finely pulverized, bagged and dust-collected by the bottom outlet of the furnace, and the steel wire and the ultrafine particle size finer than 500 mesh sieve can be obtained. Carbon black, the steel wire is collected in the steel wire hopper, and the ultra-fine carbon black is collected in the ultra-fine carbon black collection bin;

 The tar residue in the waste plastic thermal cracking furnace is discharged through the bottom outlet of the furnace and collected in the storage tank of the tar residue;

 Through the operation of the step II, the product group II and the intermediate product group II are obtained, and the product group II, the present example refers to: 49 parts by weight of the steel wire and 135 parts by weight of the pyrolysis oil; the intermediate product group II, This example is obtained: 30 parts by weight of ultrafine carbon black having a particle size finer than a 500 mesh sieve, and 10 parts by weight of tar residue.

 Step III, taking 10 parts by weight of the tar residue in the intermediate product group II obtained in the step II and 100 parts by weight of the 20-40 mass car scrap tire rubber particles in the intermediate product group I obtained in the step I, and placing them in the integrated device. In the sub-device C, the batching section in front of the dynamic closed heating tank, pour them into the tank feeding hopper, and then add known ingredients such as: 12 parts by weight of water, etc., push the ingredients into the heating tank, close the tank, stir , heating, the material stays in the tank at 200~220 °C for about 2h, then stop heating, release steam, reduce pressure, cool down, when the gauge pressure in the tank is zero, open the upper feed inlet of the tank, from the feed hopper Adding 30 parts by weight of the ultrafine carbon black in the intermediate product group II obtained in the step II, and then closing the tank for 5 minutes, opening the lower discharge port of the tank, and introducing the carbon black and the plasticized coarse rubber powder mixture into the dense The kneading machine kneads into a dough, and then the micelle is calendered into a film of about 5 mm by a two-roller machine, and the film is refining, rolling, cutting, and lowering the machine by a two-roll refiner to obtain a layered cake-like dosage form. 500-mesh pyrolysis ultrafine carbon black, tar residue and Plasticized waste tire rubber mixture in the rubber products industry it may be used instead of recycled rubber, carbon black, zinc oxide is set equal amounts of material, namely the content of the present invention, one of the products of the group comprising of I.

 The method for combined recycling of waste tires and waste plastic polymer materials in the present embodiment, after combining steps I, II, and III, thermally cracking carbon black/plasticizing according to useful products in product group I. (30/100/10) ratio of rubber powder/tar residue, the useful product of product group II, an unlimited amount of steel wire and pyrolysis oil, and the restrictive conditions for the total discharge of products not to be zero of.

Compared with the prior art, the method of the present embodiment has the advantages of no slag discharge and small pollution, and can convert the waste fibers separated from the waste tire into oil and carbon black, and the obtained carbon black which can be used in the rubber product industry. It is a mixture of carbon black and finer than 100 mesh rubber powder. Of course, this product form can be further processed by mechanical extrusion such as extrusion, which becomes a commercial form of rubber particles, rubber strips, film and glue. Its dust during production and use is much smaller than pure carbon black. The settings of the integrated device used in this embodiment:

 The utility model relates to a sub-device A which performs processing such as thermal cracking on waste plastics and waste tires, and a sub-device C which performs conventional reclaimed rubber processing such as normal temperature breaking pulverization and heating plasticization with waste tires, and a combined integrated device, which is characterized in that: The well-known devices A and C are organically combined, and the re-integration after adding and subtracting their respective sub-sets is performed on the basis of the well-configured sub-devices A and C;

 The sub-device A is obtained by adding and subtracting the original matching settings of the known device A, and the sub-device A comprises: capable of respectively performing thermal cracking on waste plastics and waste tires to obtain tar residue and thermal cracking. a group of thermal cracking furnaces such as oil and other products, such as pyrolysis carbon black, metal skeleton, pyrolysis oil, etc., and a batching bucket, a screw feeder, a post-furnace alkali absorption device, and a fixed set in front of the two groups of furnaces. Bed, catalytic cracking unit, condenser, separator, buffer tank, pump, heat exchange kettle, fractionation column, diesel condenser, diesel water separator, diesel fuel reservoir, gasoline condenser, gasoline water separator, gasoline storage, And gas storage tanks, water-sealed tanks, coarse crushers for processing carbon black, magnetic separators, oscillating screens, fine crushers, wire hoppers, ultra-fine carbon black collection bins that are finer than 500 mesh, pools for collecting tar residues Wait;

 The sub-device C is obtained by adding and subtracting the original matching settings by the known device C, and the sub-device C comprises: performing shearing, coarse crushing, screening, magnetic separation and aggregate on the waste tire. Crusher, groove roller machine, oscillating screen, magnetic separator,

20-40 mesh waste tire rubber pellet storage bin, steel wire silo, nylon fiber aggregate bin; dynamic sealed heating tank, internal mixer, refining for heating, plasticizing, mixing, kneading and refining waste tire rubber pellets Machine, etc.

 The arrangement of the integrated device used in this embodiment further includes: providing a quantitative screw conveying mechanism between the ultrafine carbon black collecting bin of the sub-device A and the feeding hopper of the dynamic sealing heating tank of the sub-device C; Between the fiber collection bin and the pre-furnace batching bucket of the sub-assembly A, a mechanism for conveying the short-cut fibers is provided; between the pool for collecting the tar residue of the sub-assembly A and the feed hopper for the dynamic sealed heating tank of the sub-device C , there is a transport mechanism.

 For the setting of the integrated device described in this embodiment, refer to FIG. 2 of the integrated device of Embodiment 2. In the schematic diagram:

1 - Sub-device A, including:

 6 - batching bucket, 7 - screw feeder, 8 - waste tire thermal cracking furnace, 9 - batching bucket, 10 ^ screw feeder, 11 - waste plastic thermal cracking furnace, 12 - alkali absorption Apparatus, 13 - fixed bed, 14 - catalytic cracking unit, 15 - condenser, 16 - separator, 17 - buffer tank, 18 - pump, 19 - heat exchanger, 20 - fractionation tower ,

21 - diesel condenser, 22 - diesel water separator, 23 - diesel storage, 24 - gasoline condenser, 25 - gasoline water separator, 26 - gasoline storage, 27 - collecting tar residue Pool, 28 - gas storage tank, 29 ~ ~ water sealed tank, 30 ^ coarse carbon black collection silo, 31 - coarse crusher, 32 - Zhen Ping sieve, 33 - magnetic separator, 34 - Fine crusher, 35 a wire hopper, 36 - ultra-fine carbon black collection bin finer than 500 mesh;

 2——Sub-device C, including:

 37——Cut crusher, 38——groove stick machine, 39——shock screen, 40——magnetic separator, 41——20-40 mesh waste tire rubber pellet storage bin, 42——dynamic closed heating tank , 43 - internal mixer, 44 - refiner, 45 - fiber trap, 46 - wire collection bin, 47 - nylon fiber collection bin;

 3 - a mechanism for conveying the smashed fibers between the fiber collection bin of the sub-assembly C and the pre-furnace hopper of the sub-assembly A;

 4 - a screw conveying mechanism is provided between the ultra-fine carbon black collection bin of the sub-assembly A and the feed hopper of the dynamic sealed heating tank of the sub-device C;

 5 - A transport mechanism is provided between the tank for collecting the tar residue of the sub-assembly A and the feed hopper of the dynamic sealed heating tank of the sub-device C.

 Example 3.

 The method for recycling and recycling used in the embodiment relates to a combination of thermal cracking and ultrafine pulverization, a combination of waste polymer materials recycling process such as sulfurization and plasticization, and an integrated device used in the embodiment thereof, and a processing method thereof There are three steps combined as follows, and the embodiment is specifically:

 Step I, taking 175 parts by weight of the waste semi-steel radial tire, placing the treatment section of the sub-device B in the integrated device before the batching, first breaking it into about 5 cm by the shear crusher in the sub-combination device B The 5 cm pieces were further crushed, sieved and magnetically separated by a groove roller machine and a vibrating screen and a magnetic separator to obtain an intermediate product I. The intermediate product group I described in this example includes : 20~30 mesh waste semi-steel radial tire rubber 100 parts by weight and 75 parts by weight of steel wire, nylon fiber and rubber powder mixture;

Step II, taking 70 parts by weight of the half-cut waste semi-steel radial tire chunks and 75 parts by weight of the steel wire, nylon fiber, and rubber powder mixture obtained in the step I, and placing the waste tire heat in the sub-device A in the integrated device In the feed treatment section before the cracking furnace, the crushed rubber block and the mixture of steel wire, fiber and rubber powder are placed in the feed hopper, and the known catalyst is stirred into the material. Appropriate amount (same as in Example 1.), stir the material into the thermal cracking furnace with a screw feeder, and the material is retained in the furnace at 300~400 °C for about 30~40min, which becomes carbon and oil vapor;

 At the same time, another 150 parts by weight of a plastic bag mainly made of waste polyethylene and polypropylene is placed in the feed processing section in front of the waste plastic thermal cracking furnace in the sub-assembly A in the integrated device, and the waste plastic bag is placed. Into the hopper, and then mix the known amount of catalyst into the material (the same as in the example 1.), stir the material into the thermal cracking furnace with a screw feeder, and the material is retained in the furnace at 350~420 °C for about 2 hours. Turned into tar residue and oil vapor;

 The oil vapor in the two furnaces is separately discharged through the top of the furnace, and then passed through alkali absorption, fixed bed, catalytic cracking, condensation, separation, etc., to obtain pyrolysis diesel, gasoline, gas, gas through the gas storage cabinet. After collection, it is used to support the combustion of two thermal cracking furnaces, and the pyrolysis diesel oil and gasoline imported by condensation are introduced into diesel oil and gasoline storage;

 The carbon in the waste tire thermal cracking furnace is discharged, cooled, coarsely crushed, magnetically selected, sieved, finely pulverized, finely pulverized, and dust collected in the bag, and the steel wire and the particle size are respectively finer than 180-250. The fine carbon black and ultrafine carbon black are finer than the 500 mesh sieve. The steel wire is collected in the steel wire hopper. The fine carbon black and the ultrafine carbon black are respectively collected in the fine carbon black collection bin and the ultrafine carbon black aggregate. Warehouse

 The tar residue in the waste plastic thermal cracking furnace is discharged through the bottom outlet of the furnace and collected in the storage tank of the tar residue;

 After the step Π operation, the product group II and the intermediate product group II are obtained, and the product group II, the present example refers to: 49 parts by weight of the steel wire and 135 parts by weight of the pyrolysis oil, the intermediate product group II, This example is obtained: 25 parts by weight of fine carbon black having a fine particle size of 180 to 250 mesh, 5 parts by weight of ultrafine carbon black finer than 500 mesh sieve, and 10 parts by weight of tar residue.

 Step III, taking 10 parts by weight of the tar residue in the intermediate product group II obtained in the step II and the sub-device in the integrated device of the 20-30 mass waste semi-steel radial tire rubber particles 50 in the intermediate product group I obtained in the step I Dynamically close the batching section in front of the heating tank in C, pour them into the tank feeding hopper, add the known ingredients such as: 6 parts by weight of water, etc., push the ingredients into the heating tank, close the tank, stir, heat The material is retained in the tank at 200~220 °C for about 2h, then the heating is stopped, the steam is released, the pressure is reduced, and the temperature is lowered. When the gauge pressure in the tank is zero, the upper feed inlet of the tank is opened, and the feed tank is added. 5 parts by weight of the ultrafine carbon black in the intermediate product group II obtained in the step II, and then closed in a can for 5 minutes, the lower discharge port of the can is opened, and the carbon black and the plasticized coarse rubber powder mixture are introduced into the internal mixer. After kneading into a dough, the micelles are calendered into a film of about 5 mm by a two-roller machine, and the film is refining, rolling, cutting, and lowering the machine by a two-roll refiner to obtain a layered cake-like dosage form containing 500 mesh. Thermal cracking of ultrafine carbon black, tar residue and plasticized Tires gum mixture, it may be used in place of rubber products reclaimed rubber, carbon black, zinc oxide is set equal amounts of material, namely, one of the products of the present invention, Group I included content;

 Taking 25 parts by weight of the pyrolysis fine carbon black in the intermediate product group II obtained in the step II and the 20-30 mass waste semi-steel radial tire rubber particles 50 in the intermediate product group I obtained in the step I, the sub-devices disposed in the integrated device In the batching section before the ultra-fine pulverizer in B, pour them into the powder mixer, stir them and then introduce them into the high-level storage bin of the superfine pulverized material. The mixture material is introduced into the elastomer fine pulverizer through the drop pipe, and the material is discharged. Wind-guided duct, cyclone separation, sieving treatment, 75 parts by weight of a mixture of pyrolysis carbon black and waste tire rubber powder of 100 mesh mesh, dust dusting of 100-mesh carbon black and rubber powder mixture It is far less than pure carbon black, and it can be used in the rubber product industry to replace the equal amount of material of rubber powder, carbon black and zinc oxide, which is also one of the contents included in the product group I of the present invention.

 The method for combined recycling of waste tires and waste plastic polymer materials in the present embodiment, after combining steps I, II, and III, thermally cracking carbon black/plasticizing according to useful products in product group I. (5/50/10) ratio of rubber powder/tar residue and (25/50) ratio of cracked carbon black/rubber powder, useful products in product group II - unlimited amount of steel wire and pyrolysis oil, and no product The restrictive conditions for total rejects tending to zero are coordinated to achieve the completion.

 Compared with the prior art, the invention has the advantages of no slag discharge and small pollution compared with the prior art, and can convert the miscellaneous fibers separated from the polymer products such as waste tires into oil and carbon black, and refine the waste plastics. The obtained tar residue, the carbon black obtained by refining the waste tire, and the rubber powder or/and the plasticized rubber powder are mixed into a mixture of the rubber powder and the carbon black or/and tar residue.

 The settings of the integrated device used in this embodiment:

 A device comprising a sub-device A for performing thermal cracking processing on a polymer material, a sub-device B processed by fine or ultra-fine pulverization, and a sub-device C processed by desulfurization, plasticization, mixing, etc., and characterized Yes - organic combination with sub-devices 8, B, C, to obtain re-integration including the sub-devices A and B and C in the well-known configuration, after adding and subtracting their respective sub-sets;

The sub-device A is obtained by adding and subtracting the original matching settings of the known device A, and the sub-device A comprises: capable of respectively performing thermal cracking on waste plastics and waste rubber to obtain tar residue and thermal cracking. a group of thermal cracking furnaces such as oil and other products, such as pyrolysis carbon black, metal skeleton, pyrolysis oil, etc., and a batching bucket, a screw feeder, and an alkali absorption device installed in the furnace, fixed in front of each furnace. Bed, catalytic cracking unit, condenser, separator, buffer tank, Pumps, heat exchangers, and fractionation towers, diesel condensers, diesel water separators, diesel fuel tanks, gasoline condensers, gasoline water separators, gasoline storage tanks, gas storage tanks, water seal tanks, pools for collecting tar residues, Collecting the collection bin of coarse carbon black, processing the coarse crusher of carbon black, oscillating sieve, crusher, magnetic separator, collecting hopper of steel wire, collecting the collection bin of 180~250 mesh carbon black, collecting fine Ultra-fine carbon black collection bin of 500 mesh carbon black;

 The sub-device B is obtained by adding or subtracting the original matching settings by the known device B, and the sub-device B includes: a crushing machine for cutting large rubber parts such as scrap tires and the like with a metal skeleton. , a coarse-grained groove roller machine for a small rubber member having a skeleton such as a metal, a sieving sieve for sieving the rubber particles having different particle sizes, and a magnetic separator for magnetically selecting the rubber particles containing the magnetic metal , collection bins for each crude product, such as: 20~40 mesh waste rubber coarse aggregate bin, steel wire bin, nylon fiber aggregate bin; compounding machine for formulating coarse rubber pellets, Superfine pulverized material collection bin, superfine pulverization to obtain a pulverizer that is finer than 100 mesh powder products, and a subsequent processing device for 100 mesh powder products, such as: cyclone separator, sieving machine, bag filter Wait;

 The sub-device C is obtained by adding and subtracting the original matching setting by the known device C, and the sub-device C comprises: a dynamic sealing heating tank for heating plasticizing and mixing the waste rubber particles, a two-roll refiner that performs refining on a rubber compound, or a two-roller or extruder;

 The arrangement of the integrated device used in this embodiment further includes: providing a screw conveying mechanism between the ultrafine carbon black collecting bin of the sub-device A and the feeding hopper of the dynamic sealing heating tank of the sub-device C; Between the collection bin of 180~250 mesh carbon black and the formula rubber mixer of the waste rubber pellet of sub-device B, a quantitative screw conveying mechanism is set; in the fiber collection bin of the sub-device B and the pre-furnace batching bucket of the sub-device A Between, the mechanism for conveying the chopped fibers is set.

 The integrated device according to the embodiment further includes: a dust-proof bag filter is disposed at each of the exhaust outlets of each cyclone; and a pipe and a mechanical device are provided in each operation. There are sound-absorbing shells, hoods and walls; in the outlets with high-temperature exhaust gas, such as: flue gas exhaust outlet heated by oil furnace, water spray purifiers of heating tanks are equipped with water spray purifiers; In the operating water circulation system, a water treatment tank is connected in series; an automatic control system is set for the entire integrated device.

 For the setting of the integrated device described in this embodiment, refer to FIG. 3 of the integrated device of Embodiment 3. In the schematic diagram:

1 - Sub-device A, including:

 7 - batching bucket, 8 - screw feeder, 9 - waste tire thermal cracking furnace, 10 - batching bucket, 11 - screw feeder, 12 - waste plastic thermal cracking furnace, 13 - alkali Absorption device, 14 - fixed bed, 15 - catalytic cracking unit, 16 - condenser, 17 - separator, 18 - buffer tank, 19 - pump, 20 - heat exchanger, 21 - fractionation Tower, 22 - diesel condenser, 23 - diesel water separator, 24 - diesel storage, 25 - gasoline condenser, 26 - gasoline water separator, 27 - gasoline storage, 28 - storage Gas cabinet, 29 - water sealing tank, 30 - pool for collecting tar residue, 31 - crude carbon black collection bin, 32 - coarse crusher, 33 - shock sieve, 34 - fine crusher, 33 - magnetic separator, 36 - wire hopper, 37 - 180-250 mesh carbon black collection bin, 38 - ultra-fine carbon black collection bin finer than 500 mesh;

 2 - Sub-device B, which includes:

 39 ~~ Crusher, 40 - Ditch stick machine, 41 - Shock screen, 42 - Magnetic separator, 43 - 20-40 mesh waste tire rubber pellet bin, 44 - Wire hopper, 45- - fiber trap, 46 - mixing machine, 50 ^ superfine pulverized material collection bin, 51 - superfine pulverizer, 52 - sieving machine, 53 - cyclone separator, 54 - bag dust removal , 55 - a silo of a mixture of rubber powder and carbon black over a 100 mesh screen, 56 - a nylon fiber collection bin;

 3——Sub-device C, including:

 47——dynamic closed heating tank, 48——mixer or two-roller or extruder, 49^two-roll refiner;

 4 - a mechanism for conveying the smashed fibers between the nylon fiber collecting bin of the sub-assembly B and the batching hopper before the waste tire thermal cracking furnace of the sub-assembly A;

 5 - a quantitative screw conveying mechanism is provided between the collection bin of the 180-250 mesh carbon black of the sub-device A and the formula rubber mixer of the waste rubber pellet of the sub-device B;

 6 - a transport mechanism disposed between the pool for collecting tar residue in the sub-assembly A and the feed hopper of the dynamic sealed heating tank of the sub-device C;

 57 - A screw conveying mechanism is provided between the ultrafine carbon black collection bin of the sub-assembly A and the feed hopper of the dynamic sealed heating can of the sub-device C.

 Example 4.

The method for recycling and recycling in the embodiment relates to an advantageous complementary scheme between the branches of the current room temperature pulverization process, and an integrated device used in the embodiment thereof. The embodiment of the process method is specifically: Take 100 parts by weight of waste butyl water tire or waste bias tire, cut it into large pieces of 50~500X50~500, and place it in the feeding hopper of the grinding wheel type rubber fine pulverizer in the grinding wheel combination device. In the middle, after the bulk material is processed by the grinding wheel rubber fine pulverizer, the bulk scrap rubber is ground into a mixed granular rubber powder of 20~200 mesh waste butyl water tire or waste bias tire, if it is treated waste The bias tire, the oscillating sieve and the fiber separation machine can be used to remove the nylon fiber from the division, and the mixed rubber powder obtained by finely pulverizing the grinding wheel is put into the collection bin, and the butyl hydrotalel obtained at this time or The offset tire mix powder is less than 100% of the rubber powder of about 100%; and the mixed rubber powder is introduced into the formula mixer of the shearing disc type rubber fine pulverizing combination device by using the guiding mechanism, and It is mixed with additives such as carbon black powder in a ratio of 100:30, and then introduced into a storage bin, and then introduced into a shearing disc type rubber fine pulverizer for re-pulverization. The pulverized material is introduced into the cyclone by a gas flow, and the exhaust of the cyclone separator Drain or/and reuse after passing through the dust collector, The pulverized material collected in the cyclone separator is introduced into a mesh sieve with a coarseness of 100 mesh, and the crude material which has not passed through the 100 mesh net is collected, and then introduced into the mixing process of the pre-adhesive powder and the powder isolation and the like, and then mixed and pulverized. After the material is collected, it is imported into the finished product warehouse; the obtained fine powder is equal to 100 parts of the finished product of 130 mesh (Note: After multiple feedings, the coarse return material that is screened out each time is added to the next batch of feed, so the feed can be They are considered to be lossless) and they can be sold as commodities.

 The arrangement of the integrated device used in this embodiment involves the complementary arrangement of the integrated devices used in each branch of the normal temperature pulverization process, and the embodiment is specifically:

 The mixing chamber of the rubber powder mixture in the known grinding wheel type normal temperature fine pulverizing assembly device (honing), and the mixing before the shearing disc fine pulverizing machine in the shearing disc type rubber fine pulverizing combination device (Β-shearing) A guiding mechanism is arranged between the feed inlets of the feeder, and the original (Β-shear) is pre-machined in its shearing disc, and the mechanical arrangement of the core unit is followed, and the original mechanical setting is retained, and the original (honing) is stored in the rubber powder. Or the front mechanical setting of the storage bin of the mixture of rubber powder and powder release agent.

 The combined device (honing) includes: a large rubber block cutting machine, a grinding wheel type rubber fine pulverizer, a vibrating screen, a fiber separator, a fiber collection silo, a rubber powder and a powder auxiliary mixer, a mixed glue Powder collection silo, etc.;

 The combined device includes: large rubber block cutting machine, coarse crushing machine, oscillating sieve, magnetic separator, steel wire, iron filing bin, fiber trap, cyclone separator, fiber aggregate Warehouse, colloidal silo, formula mixer, storage silo, shear-grinding rubber fine grinder, as well as centrifugal sieves, dust collectors, and carbon black and rubber powder mixtures that store at least 100 mesh sieves! Wait.

 The integrated device used in the embodiment can not only make 20-30 mesh rubber particles separated from the waste radial tire into carbon black and rubber powder mixture which is at least 100 mesh sieve, but also can be used for halogenated butyl group. The types of waste rubber that will be adhered by rolling are also processed into a mixture of carbon black and rubber powder which is at least 100 mesh sieve, and this result is an equipment problem that the rubber powder industry has not solved so far.

 For the arrangement of the integrated device described in this embodiment, refer to the embodiment 4. FIG. 4, in which:

 B-grinding - grinding wheel type normal temperature fine pulverizing combination device for producing rubber powder, including:

 1——large rubber block cutting machine, 2——grinding rubber fine pulverizer, 3——oscillation sieve, 4——fiber separator, 5——fiber collection bin, 6——mixed rubber aggregate Warehouse

 B-shear - a shear-grinding rubber fine pulverizing combination device for producing rubber powder, including:

 7——large rubber block cutting machine, 8——coarse crusher, 9——oscillating sieve, 10×magnetic separator, 11——wire collecting bin, 12——formulation mixer, 13——stock Warehouse, 14 - shear grinding disc type rubber fine pulverizer, 15 - cyclone separator, 16 - centrifugal sieve, 17 - storage silo of at least 100 mesh sieve carbon black and rubber powder mixture, 18 - - fiber trap, 19 - cyclone separator, 20 - fiber collection bin, 21 ^ ^ wire, iron filing bin, 22 - dust collector;

 23——The guiding mechanism between B and B.

 Example 5.

 The method for recycling and recycling in this embodiment involves implementing an advantageous complementary scheme between the branches of the current room temperature pulverizing process, and an integrated device used in the embodiment thereof. The embodiment of the method is specifically:

 Taking the powder of the waste radial tire or the bias tire rubber powder which has at least 30% of the 200 mesh screen which is obtained by one-time pulverization in the well-known shearing disc type rubber fine pulverization process: the ratio of the powder such as carbon black is 100:30 130 parts of the rubber powder material, which was further pulverized by a shearing disc type rubber fine pulverizer to obtain 130 parts of a rubber powder material containing 75% of a 200 mesh screen.

The arrangement of the integrated device used in this embodiment relates to the improvement of the arrangement in the integrated device B used in the normal temperature pulverization process, and the embodiment is specifically: - Fine pulverization in a known shear-grinding type rubber fine pulverizing assembly (B-shear) After the outlet of the pulverized material separated by the wind guide spiral, a set of pulverization of a series of mechanically connected series of finely pulverized and air-guided spiral separation is performed. The mechanism for extracting the wind, the first-stage fine pulverization in the conventionally known shear-grinding type rubber fine pulverizing combination device (B-shear) is set to a two-stage series-type shear-grinding type rubber fine pulverizing combination device (B shearing, shearing) ).

 For the arrangement of the integrated device described in this embodiment, refer to Embodiment 5. FIG. 5, in which:

 (B-shearing, shearing)—The production of rubber powder, which consists of two-stage fine pulverizers arranged in series, and a shear-grinding rubber fine pulverizing combination device, including:

 1——Magnetic separator, 2—— 20-30 mesh colloid collection bin, 3——mixer, 4——reservoir bin, 5-steel bin, 6——shear grinding disc rubber fine crushing Machine, 7 - cyclone separator, 8 - storage bin, 9 - shear grinding disc type rubber fine grinder, 10 ^ dust collector, 11 - cyclone separator, 12 - centrifugal sieve, 13 - dust removal , 14 - collection bin, 15 - cyclone separator.

 Example 6.

 The method for recycling and recycling in the embodiment relates to an advantageous complementary scheme for implementing the complementary process between the current temperature pulverization and reclaimed rubber branches, and the integrated device used in the embodiment. The embodiment of the process is specifically:

 Take 100 parts by weight of commercially available 20~30 mesh rubber pellets for waste bias tires or waste radial tires. If there are metal impurities in the material, remove them with a magnetic separator and store the rubber particles in the storage bin. Mix well-known compounding agent such as rubber particles and carbon black powder in a powder mixer according to the weight: 100/25~50, mix the materials and send them to the storage bin, and then continuously introduce the mixed materials. The first fine pulverization is carried out in the shearing disc type rubber fine pulverizer, and the pulverized material is exported by airflow, separated by cyclone and sent to another working storage silo, and the material which has been finely pulverized is transferred from the work space. The warehouse is slowly exported, and it is continuously introduced into another shearing disc type rubber fine pulverizer for the second fine pulverization. The pulverized material is discharged by airflow, separated by cyclone and sent to the centrifugal sieve for separation, and the centrifugal sieve separation operation can be transformed. Different meshes of meshes are obtained, and powder materials of different particle sizes are obtained. In the centrifugal sieve separation operation, the coarsest selection is generally 100 mesh mesh operation, and 125 to 150 parts of the sieve are vortexed. The separator is introduced into the storage bin, and the coarse powder is returned to the storage bin of the material to be crushed before the first stage or/and the second stage fine crusher;

 Then, the mixed rubber powder which is at least 100 mesh sieve is introduced into the dynamic closed heating tank by using the guiding mechanism, and then added with the mixed rubber powder according to the varieties and proportions of the known reclaimed rubber compounding agent, and the operation of dynamically sealing the heating tank is carried out. According to the common public technology, the material of the can is only required to be rolled once by the open mill, and the reclaimed rubber product can be obtained.

 The obtained reclaimed rubber product not only has the advantages of the easy-adhesive roller of the reclaimed rubber of the present market, but also has a three-dimensional network structure due to the strong rolling treatment of the rubber powder particles without the refiner. The rubber powder is then used in the new rubber compound. It will have a new and old rubber interface with the new rubber compound. Due to the existence of this interface, the new rubber compound is easily vulcanized during molding, and the heated expansion gas in the rubber compound is easy. Run out from this interface, thereby increasing the yield of new rubber products; and because the rubber hydrocarbon chain in the rubber powder still maintains a three-dimensional network structure, it can absorb into the rubbery hydrocarbon chain has become linear More hot melt compounding agent of the reclaimed rubber, the hot melt compounding agent may be an oil softening agent such as a tackifying resin or an engine oil, and the wear resistance of the new rubber product to which the rubber powder is added is utilized. It will be better than the addition of reclaimed rubber. The oil on the surface of the product will be less than that of the reclaimed rubber. 'This is because the hot melt compounding agent has penetrated the rubber powder in the process of thermal vulcanization. ) in the three-dimensional net pocket, and in the rubber compound ( The concentration of the tackifying resin, engine oil, etc. in the phase is reduced; the rubber powder has a strong space barrier to solid compounding agents such as carbon black, and this feature is used in the preparation of conductive and antistatic rubber products. It can save 50%~95% of conductive carbon black, acetylene black, graphite and other dusty high-flying expensive materials; the new rubber compound prepared with this rubber powder material, its tensile strength is not lower than that of recycled rubber. Its compressive strength is more due to reclaimed rubber.

 The mixed rubber powder obtained by the secondary shearing disc type rubber fine pulverizer and processed by at least 100 mesh mesh screen can replace the 5~40 mesh coarse rubber powder currently used in the reclaimed rubber process, and the refining in the reclaimed rubber process can be omitted. operating.

 The arrangement of the integrated device used in this embodiment relates to the complementary arrangement of the B and C between the branching integrated devices of the room temperature pulverizing and reclaiming rubber, and the embodiment is specifically - a well-known normal temperature shearing disc type rubber fine pulverizing assembly device ( In the B-cut), a normal-temperature shear-grinding rubber fine pulverizing unit is added in series to make it (B shearing, shearing), and the storage in (B shearing, shearing) is at least 100 mesh mesh rubber powder. a guiding mechanism is arranged between the storage bin and the high temperature tank in the known reclaimed rubber combination device C;

 For the arrangement of the integrated device described in this embodiment, refer to the embodiment 6. FIG.

 (B-shear, shear)—Combination device for producing rubber powder containing two series of normal temperature shear-grinding rubber fine pulverizers, including:

1——Magnetic separator, 2——Storage bin, 3——Mixer, 4——Storage bin, 5——Shearing disc type rubber fine grinder, 6——Cyclone separator, 7——Dust removal , 8 - storage silo, 9 - shear grinding disc type rubber fine grinder, 10 ^ cyclone separator, 11 - centrifugal sieve, 12 - storage to carbon black and glue that is 100 mesh mesh Silo of the powder mixture, 13 - cyclone separator, 14 - dust collector, 15 - wire collection bin, 16 - dust collector; C - a combination of reclaimed rubber, including -

17——dynamic closed heating tank, 18——opening machine;

 19—(B shear, shear) and the guiding mechanism between C and C.

 Example 7.

 The method for recycling and recycling in the embodiment relates to an advantageous complementary scheme for implementing the complementary process between the current temperature pulverization and reclaimed rubber branches, and the integrated device used in the embodiment. The embodiment of the process is specifically:

 Take 167 parts by weight of waste bias tires or waste rubber or miscellaneous rubber products waste or waste butyl water tires, cut into

50~800X50~800mm large-size rubber compound, placed in the feeding hopper of the grinding wheel type rubber fine pulverizer in the combined device. After the bulk material is processed by the grinding wheel type rubber fine pulverizer, the large piece of scrap rubber is directly It is ground into a mixed rubber powder of 20~200 mesh, and then the non-metallic fiber impurities that may be entrained in the mixed rubber powder are removed to obtain a mixed rubber powder of 20~200 mesh.

100~167 parts, the mixed particle size storage silo storage bin is exported, and then mixed with carbon black powder isolation aid according to the ratio of 100:27, and then introduced into the shearing disc type rubber fine pulverizer for further The pulverized material is introduced into the cyclone by a gas flow, and the exhaust gas of the cyclone is vented or/or utilized by the precipitator, and the pulverized material collected in the cyclone is introduced into the centrifugal sieve, and the powder passing through the 200 mesh sieve is introduced. The storage silo in the work space, the coarse powder of the unscreened screen is guided back to the storage bin or the mixer before the fine pulverizer, and the subsequent processing of the obtained pulverized material is connected with the well-known reclaimed rubber process; Finely pulverized material, which contains at least 80% of the rubber powder which can pass through the 150 mesh screen before the sieving, and the mixed rubber powder obtained by the method replaces the 5~40 mesh crude rubber currently used in the reclaimed rubber process. Powder, can eliminate the refining in the reclaimed rubber process.

 The arrangement of the integrated device used in the embodiment relates to the complementary arrangement of the B and C between the branching integrated devices of the normal temperature pulverizing and reclaiming rubber, and the embodiment is specifically - the fine pulverizing combination device (B grinding) and the (B shearing) at room temperature At least 80% of the storage is a material guiding device between the rubber powder storage bin capable of passing through the 150 mesh screen and the high temperature tank in the known reclaimed rubber combination device C;

 For the arrangement of the integrated device described in this embodiment, refer to the embodiment 7. FIG.

 B-grinding - grinding wheel type normal temperature fine pulverizing combination device for producing rubber powder, including -

1——grinding wheel type rubber fine pulverizer, 2——oscillation screen, 3——fiber trap, 4——storage bin, 5——cyclone, 6——fiber collection bin;

 B-shear - a shear-grinding rubber fine pulverizing combination device for producing rubber powder, including -

7——Mixer, 8——Storage bin, 9~~Shearing disc type rubber fine grinder, 10——Cyclone separator, 11——Dust collector, 12——Dust collector, 13——Cyclone separator , 14 - Centrifugal sieve, 15 - (slightly thicker than 200 mesh without sieving) Carbon black and rubber powder storage silo, 16 - (stored 200 mesh sieve) Carbon black and rubber powder mixture Storage bin

 C——Combination device for producing reclaimed rubber, including:

 17——dynamic closed heating tank, 18——opening machine;

 19——B guide mechanism between B-grinding and B-shear and C.

 Example 8.

 The method for recycling and recycling in the embodiment relates to an advantageous complementary scheme for implementing the complementary process between the current temperature pulverization and reclaimed rubber branches, and the integrated device used in the embodiment. The embodiment of the process is specifically:

 1. Referring to Examples 1 to 7, a large-scale waste rubber or waste rubber product side leather or waste butyl water tire material of 50 to 500 χ 50 to 500 is pulverized into a grinding wheel type rubber fine pulverizing machine B. 20~200 mesh mixed particle size rubber powder;

 2. Referring to Examples 1 to 7, a pre-precision machine for fine pulverization in a shear-grinding rubber fine pulverizing assembly B (shearing and shearing) is used to apply a 30-cm χ 30-50 rubber-like waste rubber or The waste rubber product side leather material or waste radial tire material is pulverized into a mixed particle size rubber powder of 20-30 mesh;

 3. Referring to Examples 1 to 7, a mixed particle size rubber powder of 20 to 200 mesh or a mixed particle size rubber powder of 20 to 30 mesh is separately mixed with a powder additive such as carbon black, and a rubber plate for shearing is used. Two fine pulverizations in the fine pulverizing assembly Β (shearing and shearing), which gives a mixture of nearly 100% carbon black and rubber powder which can pass 100 sieves; it is worth mentioning that two fine pulverization methods are used, even It is a powder additive used in the mixing operation. It is mixed with 10~100 mesh coarse materials. After being crushed by two passes, the rigid materials such as carbon black have been pulverized to finer than 200. The purpose of the powder, using this feature, the choice of powder additives can be properly thick;

4. Referring to the foregoing embodiment, a mixture of a powder such as carbon black having a thickness of 100 mesh and a rubber powder is introduced into a dynamic sealed heating tank in a combination device C for producing reclaimed rubber, and a known reclaimed rubber compounding agent is added, and is carried out by a known technique. Heating place According to the kneading process of the can material and the internal mixer or the extruder, the regenerated rubber products corresponding to the various materials obtained by the feeding can be obtained.

 The arrangement of the integrated device used in this embodiment relates to the complementary arrangement of the B and C between the branching integrated devices of the normal temperature pulverizing and reclaiming glue, and the embodiment is specifically:

 Combination between a normal temperature fine pulverizing combination device (B grinding) and (B shearing, shearing) and a known reclaimed rubber combination device C

 For the arrangement of the integrated device described in this embodiment, refer to the embodiment 8. FIG.

 B-grinding - grinding wheel type normal temperature fine pulverizing combination device for producing rubber powder, including:

 1——grinding rubber fine pulverizer, 2——oscillating sieve, 3——storage bin, 4——fiber trap, 5——cyclone, 6——fiber collection bin;

 B shearing, shearing - a combination of two series of normal temperature shearing disc type rubber fine pulverizers for the production of rubber powder, including:

 7——groove roller machine, 8——oscillation screen, 9~~fiber trap, 10^ cyclone separator, 11——fiber collection silo, 12——colloidal aggregate silo, 13——magnetic separator , 14 - steel wire, iron filings bin, 15 - mixer, 16 - one bin, 17 - shearing disc type rubber fine grinder, 18 - cyclone, 19 ^ storage silo, 20~ a shearing disc type rubber fine pulverizer, 21 - cyclone separator, 22 - storage bin;

 C——Combination device for producing reclaimed rubber, including:

 23——opening machine, 18——dynamic closed heating tank;

 25—— Guide mechanism between B-grinding and B-shearing and shearing C.

 Example 9.

 The embodiment relates to a subsequent plasticizing modification scheme of the fine rubber powder obtained by the grinding wheel pulverization method in the current room temperature pulverizing process, and specifically: as shown in FIG. 9, the fine rubber originally obtained directly from the mechanical sieve grading process The process of packaging the powder is changed to a new process route in which the plasticizing agent is added to the fine rubber powder, and then mixed, and then packaged.

 The plasticizing aid to be added is a known rubber softener-like material or/and a formulation mixture using such a known material, and the fine rubber powder is preferably finer than 100 mesh, plasticizing aid and fine rubber powder. The mixing ratio is preferably 3~15: 97~85.

 By implementing this plasticizing modification scheme, the improvement scheme on the apparatus can be set as shown in FIG. 9 after the fine rubber powder silo 7 in the grinding wheel assembly device (B mill) can be added with plasticizing aid and mixing. Mechanically, the machine comprises at least one or a combination of a mixer, a kneader, a mixing screw machine, a tank for placing a plasticizing aid, and a rubber powder mixture.

 The fine rubber powder plasticized by this example, when it is mixed with the new rubber compound and vulcanized, has a fast feeding material, and the rubber powder knife can not see the rubber powder and other rubber powder and the new rubber compound has good compatibility. Obvious features.

 Example 10.

 Take 100 parts by weight of 20-mesh waste EPDM rubber pellets, or 20-200 mesh waste butyl rubber pellets and 25 to 30 parts by weight of 5 mesh waste polyethylene or waste polypropylene plastic film coarsely pulverized pellets and 25~ 50 parts by weight of 5~100 mesh or 200 mesh waste rubber thermal cracking carbon black, using the B shearing, shearing and shearing type rubber fine pulverizing combination device in the foregoing embodiment, performing mixing, two fine pulverization, sieving treatment, At least: Ethylene-propylene propylene rubber and polyethylene plastic, or EPDM and polypropylene plastic, or butyl rubber and polyethylene plastic, or butyl rubber and polypropylene plastic four rubber, plastic combination The waste rubber thermally cracks a powder mixture of carbon black, and the rubber and plastic in the powder mixture have a particle diameter of 100 mesh, wherein the thermally cracked carbon black has a particle size of 200 mesh.

 Example 11.

 Take 100 parts by weight of 20-mesh waste tire rubber particles, or 20-200 mesh waste neoprene rubber particles, and 25 to 30 parts by weight of 5 mesh waste polymethyl methacrylate or waste polycarbonate plastic coarsely pulverized pellets. And 25~50 parts by weight of 5~100 mesh or 200 mesh waste rubber thermal cracking carbon black, using the B shearing, shearing and shearing type rubber fine pulverizing combination device in the foregoing embodiment, performing mixing, two fine pulverization, Screening treatment, at least: tire rubber and polymethyl methacrylate plastic, or tire rubber and polymethyl methacrylate plastic, or neoprene and polycarbonate plastic, or neoprene and polycarbonate plastic The powder mixture of the four rubber and plastic combinations and the waste rubber thermal cracking carbon black, the rubber and plastic in the powder mixture has a particle diameter of 100 mesh, wherein the thermal cracking carbon black has a particle diameter of 200 mesh.

 Example 12.

Take 100 parts by weight of 20-mesh waste rubber rubber product produced by the production of the side rubber pellets, or 20 to 200 mesh waste polyurethane rubber pellets, and 25 to 30 parts by weight of the 5 mesh waste plastic buttons coarsely pulverized pellets, and 20 ~50 parts by weight of 5~100 mesh or 200 mesh waste rubber thermal cracking carbon black, using the B shearing, shearing and shearing disc type rubber fine pulverizing combination in the foregoing embodiment Set, carry out mixing, two fine smashing, sieving treatment, at least: miscellaneous waste rubber and waste button plastic, or polyurethane rubber and waste button plastic two kinds of rubber, plastic, plastic combination and waste rubber thermal cracking carbon black The powder mixture, the rubber, plastic, plastic in the powder mixture has a particle size of 100 mesh, wherein the thermal cracking carbon black has a particle size of 200 mesh.

 Example 13

 Take 100 parts by weight of 20~40 mesh waste rubber shoes coarsely crushed rubber particles, or 20~200 mesh waste butyl tire inner rubber rubber particles, and 15~50 parts by weight of 5 mesh waste polyvinyl chloride plastic coarse crushed pellets, And 15~50 or 800 parts by weight of 5~100 mesh or 200 mesh waste rubber thermal cracking carbon black, using the B shearing, shearing and shearing type rubber fine pulverizing combination device in the foregoing embodiment, performing mixing and two fine pulverization , Screening treatment, at least: powder mixture of rubber rubber and plastic PVC, or combination of rubber, plastic and plastic of waste butyl rubber and waste polyvinyl chloride plastic and thermal cracking carbon black of waste rubber The rubber, plastic, and plastic in the powder mixture have a particle diameter of 100 mesh, wherein the thermal cracking carbon black has a particle diameter of 200 mesh.

 Example 14

 This example relates to the selection of materials such as plasticized rubber materials or/and oils used as a coupling agent for wetting the surface of waste fibers. The materials are as described in Table 1: (This example is suitable for formulating into natural materials.) , waste fiber materials used in general-purpose rubbers such as butylbenzene and cis-butyl) (Table 1)

 Take the first to fifth, eighth, and seventh items of the table, a total of 101 parts by weight of the material, placed in a heating kettle, the kettle is heated, stirred, and the temperature in the kettle is raised to 120 ° C, at this time the oily plant kernels in the material The oil in the fruit material has been blown out, the oil residue has been carbonized, and then under the condition of heat preservation and stirring, 19 parts of the remaining materials of the remaining 6, 7, 10, and 11 items in the table are slowly added to the kettle. After stirring evenly, the material can be used as a coupling agent for wetting the surface of the waste fiber. It is preferably mixed with the waste fiber by a weight ratio of 5 to 100:100.

 Example 15

 This example relates to the selection of materials such as plasticized rubber material or/and oil used as a coupling agent for wetting the surface of waste fibers. The selection of the material selection formula is further described in Table 2: (In this case, the coupling agent) Suitable for the production of waste fibers used in general rubber such as natural, styrene-butadiene and cis-butene [Table 2)

 Select material classification Select material type Select the weight of the material Use material number Oily plant kernel, fruit Cotton seed kernel or / and colza 10 1 Material Oil olive meat 10 2

 Vegetable oil, resin Tung oil or / and olive oil - 10 3

 And derivative materials Peanut oil or / and soybean oil 10 4

 Xylene rosin resin / / and bismuth resin 10 5

Metasequoia resin or / and rosin glyceride 10 6 Common softeners for rubber and plastics, petroleum resin or / and styrene resin 1 7

 Odorless asphalt or / and white grease 50 8 Modified rubber vulcanized rubber powder Emulsion of rubber powder modified asphalt 2 9 Surfactant Flat plus 1 10

 Example 16

 This example relates to the selection of materials such as plasticized rubber material or/and oil used as a coupling agent for wetting the surface of waste fiber. The selection of the material is as follows: (Table 3) Suitable for formulating natural, styrene-butadiene, cis-butyl and other general rubber

 Example 18

 This example relates to the selection of materials such as plasticized rubber material or/and oil used as a coupling agent for wetting the surface of the waste fiber. The material selection formula is further introduced, as described in Table 5: (In this case, the coupling agent) Suitable for the preparation of waste fiber materials used in general rubber such as natural, butylbenzene and cis-butyl) ( 3⁄4 5 )

 Select material classification Select material type Select the weight of the material Select the material number Tea seed 10 1

 Oily plant kernels, fruit materials Palm kernel kernel 10 2

 Black scorpion kernel oil 10 3

 Corn germ oil 10 4

 Vegetable oils, resins and derivatives Hydrogenated rosin 10 5

 Rice bran oil 10 6

 Common softeners for rubber and plastics Petroleum resins 1 7

Odorless asphalt 50 8 Rubber, plastic emulsion rubber asphalt emulsion 2 9

 Example 19

 This example relates to the selection of materials such as plasticized rubber material or/and oil used as a coupling agent for wetting the surface of waste fibers. The selection of the material selection formula is further described in Table 6: (In this case, the coupling agent) Suitable for the preparation of waste fiber materials used in general rubber such as natural, styrene-butadiene and cis-butyl) (3⁄4 6)

 Example 20

 This example relates to the selection of materials such as plasticized rubber material or/and oil used as a coupling agent for wetting the surface of waste fiber. The material selection formula is further introduced, as described in Table 7: (This example is a coupling agent) Suitable for the preparation of waste fiber materials used in special rubber such as ethylene propylene, butyl, butyronitrile) (3⁄4 7)

 The proper amount of water added in the examples means that the addition of water to the coupler material is not too viscous to facilitate wetting mixing between the coupler material and the spent waste fibers.

 Example 21

 In this embodiment, a pre-formulated coupler for wetting the surface of the waste fiber is used, specifically:

Take 100 parts by weight of the waste fiber separated from the bias tire or / and the semi-steel radial tire or / and the conveyor belt, and place it in a dynamic closed heating tank, at a tank temperature of 60 ~ 120 ° C, add 30~50 parts by weight of the rubber powder modified asphalt emulsion as a wetting coupling agent (the emulsion is formulated as in Example 18), and the mixture is evenly stirred, and the stirring time is generally controlled within 20 to 30 minutes. Then, the material is discharged from the tank, and the material is flattened on a plastic film such as polyethylene by heat. The initial thickness of the material flattening can be controlled at 20~30mm, and the flattened material is cooled to a non-sticky hand, and will be thick. The loose flattening material roll is compacted to a felt-like or asphalt-like felt shape, and then the waste waste felt-like mixture is rolled together with a plastic film into a roll package of about 10 to 30 kg in a roll, which is obtained by the present invention. A waste fiber that is recycled again. This product can be used at least for formula rubber and plastic materials to increase the physical properties such as the strength of the rubber and plastic materials. This embodiment also employs a pre-formulated coupler for wetting the surface of the waste fiber, specifically:

 Taking 100 parts by weight of the waste fiber separated from the bias tire, placing it in a dynamic closed heating tank, and adding 30 parts by weight of an emulsion of the rubber powder modified asphalt at room temperature (the emulsification In the liquid: the solid content is 40%; the formulation is as in the case of Example 16), can be stirred under non-sealed conditions for 10 to 30 minutes, then the material is discharged from the tank, and the material is flattened on a plastic film such as polyethylene. The initial thickness of the material flattening can be controlled at 20~30mm. Sprinkle a little waste fiber powder with no latex on the flattening material as anti-adhesive release agent. After not sticking the hand, thick loose flattening material roll The compacted fiber felt-like mixture is rolled up into a roll package of about 10 to 30 kg-volume together with a plastic film to obtain a non-dark black waste fiber recyclable product. This product can be used in the formulation of light-colored rubber and plastic materials.

 Example 23

 In this embodiment, the intercalating agent for the surface of the wetted waste fiber is temporarily prepared, specifically, 100 parts by weight of the waste fiber (including not less than 15% of the steel fiber) separated from the semi-steel radial tire. Containing not less than 10% of the rubber powder), placed in a dynamic closed heating tank, at a tank temperature of 100 ~ 120 ° C, adding 20 parts by weight of bitumen, 20 parts by weight of oil, 0.5 ~ 3 parts by weight Flattened, 10 parts by weight of water, sealed and heated to 120~180 °C for 40 minutes to 2 hours, then the material is discharged from the tank, the material is cooled to below 50 °C, and the material is placed in plastic weaving by heat. In the bag, the loading amount of each bag can be controlled at 5~25 kg. It is also possible to combine several plastic woven bags that have been loaded together and compress them with a baler to form a product package with a weight of 50~500 kg. Such product packaging facilitates transportation efficiency and is also easy to unpack.

 Example 24

 The embodiment relates to an efficient rubber particle size grading combination machine, specifically:

 23-1 rubber powder size fractionation combination machine, as shown in FIG. 9, is an embodiment of the rubber powder particle size classification combined machine of the present invention, which is a gravity-flow particle classification in front of the cyclone separator 1 The gravity-flowing air classifier is a decelerating flow section 3 that decelerates the primary air that carries the material by the air inlet 2 that carries the primary air of the mixed particle size rubber powder, and promotes the variable flow rotation thereof. The tail air passage 4 carrying the fine particles is horizontally arranged, and the secondary air inlet duct 5 is disposed downwardly inclined. At the periphery of the deceleration flow section 3, a collision point 6 of the intersection of the secondary air flow and the gravity flow of the particulate material is set, The coarse particle falling track 7 is arranged vertically downward.

 As shown in FIG. 9, in the gravity-flow particle classifier, the primary air is introduced into the gravity-flow particle classifier, and in the deceleration section 3, since the cross-sectional area of the flow section 3 is larger than that of the inlet duct 2 The cross-sectional area, so the primary wind entering is decelerated in this flow segment, and because the flow segment 3 is cylindrical, the primary wind flows in along the circular cutting edge, so the decelerated primary wind becomes a rotating flow, where the rotating flow In the middle, the coarse particles are separated by rotation to the rounded edge, and then guided downward, and the fine powder flows out from the horizontally disposed tailing passage 4 in the middle of the deceleration flow section 3, and the coarse-grained material stream carrying a part of the fine powder is rotated to the perigee Vertically falling, when hitting the collision point 6, two collisions with the secondary air, the first time is shown in 6 (top) with the collision angle of its two flows is equal to 90° and the departure angle is equal to 120°. The second time is shown in Figure 6 (bottom) with its collision angle of two flows equal to 45° and the departure angle approximately equal to 120°. The coarse granules carrying a part of the fine powder flow through the collision with the secondary air, wherein the fine powder carried by the fine powder is lifted out and then recirculated, so that the fine powder content in the falling coarse granule stream is further reduced.

 As shown in FIG. 9, in order to control the size of the damper at the inlet of the secondary air inlet duct 5, the particle size of the fine powder flowing out of the exhaust passage 4 can meet the technical requirements, but the coarse particles from the falling lane 7 are also There will be a small amount of fine powder, and then the coarse particles which are only 30~10% of the original powder to be classified are introduced into the mechanical sieve for further screening; the tail wind from the exhaust passage 4 is passed through the cyclone separator. 1 Cyclone collects fine particles that meet the product requirements. It is taken into the fine powder collection bin; the exhaust gas from the cyclone separator is drained or reused after entering the filter bag dust collector.

 23-2. The gravity-flow particle classifier in the rubber particle size fractionation combination machine of the present invention can also be as shown in Fig. 10, which is also a primary air inlet duct 2 carrying a mixed particle size rubber powder. The deceleration flow section 3 in which the primary wind is decelerated is provided with a tail air passage 4 carrying fine particles obliquely upward, a secondary air inlet duct 5 which is disposed downwardly inclined, and a secondary air flow is provided at a periphery of the deceleration flow section 3 Convergence point 6 with the gravity flow of the granular material, and a coarse particle falling path 7 arranged vertically downward.

 23-3 The gravity-flow particle classifier in the particle size fractionation combination machine of the present invention can also be as shown in FIG. 11, which is also the inlet air duct 2 carrying the primary air of the mixed particle size rubber powder, The deceleration flow section 3 for carrying out the deceleration of the primary air carrying the material is arranged to be inclined to set the tail air passage 4 carrying the fine particles, and the secondary air inlet duct 5 disposed vertically downward, at the perigee of the deceleration flow section 3, is set The intersection of the secondary airflow and the gravity flow of the particulate material collides with the collision point 6, and the coarse particle falling lane 7 disposed vertically downward.

The gravity-flow particle classifier in the particle size-grading combination machine of the rubber powder according to 23-2 or / and 23-3, the inlet air channel 2 can also be connected in series with the gravity in the rubber particle size-grading combination machine of 23-1 ~ The coarse particles of the gas flow particle classifier fall below the channel 7 to further reduce the fines content in the coarse stream. 23-2, 23-3 Gravity ~ airflow particle classifier, its mechanism of action is similar to 23-1. The use of the rubber powder particle size fractionation combined mechanical energy according to the present invention is only using a rocking sieve, The efficiency of the section of the centrifugal sieve grading rubber powder is at least doubled.

 Example 25

 This embodiment relates to a combination of a conventional carbon black producing apparatus E and a thermal cracking A or / and ultrafine rubber powder B or / and a reclaimed rubber C production apparatus, specifically:

 As shown in Fig. 13, a conventional carbon black producing apparatus E is known to be combined with a pyrolysis A or / and ultrafine rubber powder B or / and a regrind C production apparatus;

 The E described therein specifically includes unit equipment: raw material oil dehydration tank 1, oil guiding pump 2, raw material oil tank 3, fuel oil tank 4, fuel oil filter 5, fuel pump 6, fuel oil preheater 7, spray mist Chemical unit 8, main air supply fan 9, air preheater 10, carbon black reaction furnace combustion section 11, feedstock oil filter 12, feedstock oil pump 13, feedstock oil preheater 14, feedstock oil nozzle 15, waste heat boiler 16, Main bag filter 17, reverse blower 18, exhaust gas pressurizing fan 19, exhaust gas burning furnace 20, micro-pulverizer 21, air blower 22, cyclone 23, bag filter hopper 24, return fan 25, main feed conveyor 26 , wet granulator 27, hopper 28, additive nozzle 29, metering pump 30, binder storage tank 31, dryer 32, exhaust gas furnace blower 33, screening machine 34, reject product tank 35, finished product Conveyor 36, magnetic separator 37, product conveyor 38, storage hoist 39, product storage tank 40, packaging machine 41, exhaust gas pressure fan 42, exhaust gas bag filter 43, steam package 44, waste heat boiler 45, steam package 46 , steam turbine 47, Compressed air 48, a pump 49, a pump 50 and the like;

 The A includes the unit equipment: oil tank, gas tank, power transformer, etc.; wherein the B includes unit equipment: power transformer, etc.; wherein the C includes unit equipment: power transformer , steam packs, etc.;

 As shown in Figure 13 of the present example, the features of the present invention are included:

 In the carbon black production unit E and the waste rubber and plastic secondary recycling production equipment A or / and B or / and C are provided with energy and material conveying mechanism, specifically:

 A power supply circuit is provided between the unit equipment steam turbine 47 in the conventional carbon black producing apparatus E and the unit equipment power supply transformer in the thermal cracking A or / and ultrafine rubber powder B or / and the reclaimed rubber C production apparatus;

 A steam supply line is provided between the steam turbine 47 of the E or/and the steam supply steam drum of the steam packs 44 and C; the fuel oil dehydration tank 1 in the oil tank or/and the combustible gas tank and the E in the spray A pipeline for supplying oil and gas is disposed between the atomizers 8.

 Example 26

 This embodiment relates to a combination of a conventional carbon black producing apparatus E and a thermal cracking A or/and a plastic pelletizing apparatus D, specifically - as shown in Fig. 14, by a known conventional carbon black producing apparatus E and thermal cracking A or / combined with plastic hot extrusion production unit D;

 The E includes the same unit device as the embodiment 24; wherein the A includes a unit device - an oil tank, a gas canister, a power supply transformer, a cracking furnace, etc.; wherein the D includes a unit Equipment: power transformers, etc.;

 As shown in Figure 14 of the present example, the features of the present invention are included:

 In the carbon black production unit E and the waste rubber and plastic secondary recycling production equipment A or / and D, there is a transport mechanism for energy and materials, specifically:

 A power supply circuit is provided between the unit equipment steam turbine 47 in the conventional carbon black production unit E and the unit equipment power supply transformer in the thermal cracking A or/and the plastic hot extrusion production unit D;

 A pipeline for supplying oil and gas is disposed between the oil tank of A or / and the fuel oil tank of E and the feed water dehydration tank of E;

 A conveying mechanism is disposed between the cracking furnace of A and the waste plastic storage yard of D which is not suitable for granulation.

The inventors of the present invention have been clarified by the above description, and it will be apparent to those skilled in the art that the waste polymer materials, especially the pulverized fibers removed from the used tires, can be utilized by thermal cracking; the thermal cracking of the waste polymer materials is obtained. Thermal cracking carbon black (slag) and tar residue can be used to prepare rubber powder and reclaimed rubber; it can process the waste rubber of waste polymer materials, especially used tires, at room temperature, which can be applied to large blocks or Applicable to powdered granules; The normal temperature pulverization process can be applied not only to viscous, non-viscous waste rubber varieties, but also to the treatment of materials to be processed into a graded or mixed particle size of 100-200 mesh screen. Fine rubber powder; The normal temperature pulverized fine rubber powder obtained by the grinding wheel method can be plasticized and treated on the production line to make the compatibility of the rubber powder and the rubber compound better; 100~200 mesh grade or mixed particle size ultrafine rubber powder After the heat treatment of the reclaimed rubber process, the plasticized ultra-fine rubber powder can no longer be refined by the reclaimed rubber process in the current market. The obtained ultra-fine rubber powder plasticized material can combine the anti-cracking property and the space barrier property of the rubber powder. with Recycled rubber has the advantages of contiguous adhesion. The present inventors have improved and optimized the combination of various waste polymer materials recycling methods independently implemented in the prior art, and proposed that the production process of ordinary carbon blacks is also combined, and further better effects are obtained.

 For the combination of the two types of processes, such as thermal cracking and non-thermal cracking, those skilled in the art can refer to the embodiments 1 to 3 according to the concept and technical solution of the present invention, and the operation only needs to control the foregoing steps I and II. The type and quantity of the feed can control the ratio of the 5~200 mesh waste polymer material particles in the intermediate group I to the weight of the thermal cracking carbon black in the intermediate group II in the range of 100: 10-900. Or / and control the ratio of the weight of the 5~200 mesh waste polymer material particles in the intermediate product group I to the weight of the tar residue in the intermediate product group II in the range of 100: 2-100; Including (required) thermal cracking A and (at least one of them) finely pulverized B, organic combination of thermoplastic C device, plus the core (referring to thermal cracking furnace, fine or superfine pulverization) Machine, closed heating tank) The A, B, C peripheral setting of the device can be coordinated as an auxiliary condition; those skilled in the art can reach the present invention when processing waste polymer materials, especially waste tires The effects of the said book.

 Regarding the implementation of the complementary solution between the normal temperature pulverization or the room temperature pulverization and the reclaimed rubber each branch process of the present market, as long as according to the concept and technical solution of the present invention, referring to the embodiments 4 to 13, the person skilled in the art is using the waste high In the case of molecular materials, the effects described in the present specification can also be achieved. Referring to the concept and technical solution of the present invention, referring to the embodiments 14 to 23, it is possible to obtain a strict separation without disregarding the waste fibers in the present market, and the production process is non-polluting. And a heterogeneous fiber felt-like mixture product with extensive market demand. For a high-efficiency rubber powder size-grading combination machine for fractionating the current rubber powder, as long as according to the concept and technical solution of the present invention, referring to the embodiment 24, only the swing sieve and the centrifugal sieve classification rubber powder can be used. The granularity of the work section is at least doubled. In combination with the conventional carbon black production device and the waste polymer material recycling method production device, the regeneration and new production process can be further received according to the concept and technical solution of the present invention, with reference to the embodiments 25-26. Better results in harmonious symbiosis in a full-component, green, energy-saving, high-value use atmosphere.

 According to the concept and technical solution of the present invention, the industrial department can perform the combined implementation according to the needs of the embodiment and select one or more required ones, and the desired technical effect can be obtained without creative labor.

Claims

Rights request A method of regenerating waste polymer materials or co-produced with carbon black, characterized in that it comprises at least one or more of the following combinations:  1-a. The combination of the thermal treatment and non-thermal cracking of the waste polymer materials includes at least a combination of the following three steps, specifically:  Step I, performing a cutting or coarse crushing process on a part of the waste polymer material to obtain an intermediate product group I, wherein the intermediate product group I includes but is not limited to: a large rubber block of waste polymer materials of 50 to 800×50 to 800 mm, Or 5~200 mesh waste polymer material powder, or waste polymer material powder and miscellaneous fiber skeleton;  Step II, performing heat cracking and subsequent processing on another portion of the waste polymer material, or/and the miscellaneous fiber skeleton in the intermediate product group I of the step I, to obtain the product group II and the intermediate product group II; , including: pyrolysis oil or / and its fractionation, distillation products, or metal framework and pyrolysis oil or / and its fractionation, distillation products; said intermediate group II, including: thermal cracking carbon black residue or tar Slag  Step III, mixing the thermally cracked carbon black slag or/and tar residue in the intermediate product group II obtained in the step II with the 5~200 mesh waste polymer material powder in the intermediate product group I obtained in the step I, and implementing the super Finely pulverizing or/and heat-treating, plasticizing, mixing, and obtaining product group I, said product group I, including but not limited to: a mixture of ultrafine rubber powder and carbon black powder, in the mixture The ultrafine rubber powder can pass through the 100 mesh screen, and the carbon black powder can pass through the 200 mesh screen; or the colloidal mixture of the pyrolysis carbon black and the plasticized waste polymer material which is finer than 200 mesh;  That is, after the recycling of the waste polymer material combination, the product group I and the product group II can be obtained; the product group I, including but not limited to: a mixture of the ultrafine rubber powder and the carbon black powder, in the mixture The ultrafine rubber powder can pass through a 100 mesh screen, and the carbon black powder can pass through a 200 mesh screen. The mixture product can be a particle size fractionation or mixing product including but not limited to the range of 100-200 mesh; or finer than 200. A powdery or/and a gelatinous mixture of thermally cracked carbon black and a plasticized waste polymer material; said "Product Group 11" comprising: a pyrolysis oil or/and a fine fractionated product thereof, or a metal skeleton and Pyrolysis oil or/and its rectified product;  L--b. Involving the complementary combination of the normal temperature grinding wheel and the normal temperature shearing disc crushing process in the current non-thermal cracking method:  A 50~800X50~800mm large piece of waste polymer material containing no harmful impurities such as a metal skeleton is placed in a feeding hopper in a grinding wheel assembly device, and the bulk material is processed by a grinding wheel type rubber fine pulverizer The large waste polymer material is ground into a mixed rubber powder of 20~200 mesh, and then the non-metallic fiber impurities or/and the fine rubber powder of 100 mesh sieve which may be entrained in the mixed rubber powder are removed, and the rubber powder is mixed. The raw rubber powder or the coarse rubber powder which has not passed through the 100 mesh sieve is mixed with the auxiliary agent such as powder isolation and then introduced into a shearing disc type rubber fine pulverizer for re-pulverization. The pulverized material is introduced into the cyclone by the gas flow, and the exhaust gas of the cyclone separator After being drained or/re-used by the dust collector, the pulverized material collected in the cyclone separator is introduced into a mesh sieve of 100 mesh for classification and separation, and the coarse material collected after 100 mesh is collected and then introduced into the front rubber powder and The mixing process of powder isolation and the like is carried out by mixing and pulverizing operations, and the material after the net material is collected and introduced into the finished product warehouse; the obtained at least includes but is not limited to fineness equal to 100, 110, 120, 130, 140, 150, 160, 170, 180, 190, 200 graded or mixed grade rubber powder products, which can be sold as commodities;  1--C. Involved in the improvement of the normal temperature pulverizing shearing disc process in the current non-thermal cracking method:  It will be obtained in a known fine grinding process of a shear-grinding type rubber, which has at least 30% by weight of a mixed-particle rubber powder capable of passing through 200 mesh, and is pulverized at least in a shear-grinding rubber fine pulverizer. Once, make it into a mixed particle size rubber material containing at least 75% of the energy of 200 mesh; ' L--d. Involving the subsequent plasticization modification scheme of the fine rubber powder obtained by the grinding wheel pulverization method in the normal temperature pulverization process: in the subsequent treatment of the fine rubber powder obtained by the grading process of the grinding wheel pulverization process, setting the mixing plasticization The plasticizing aid is a known rubber softener-like material or/and a formulation mixture using the known material, and the fine rubber powder is preferably as small as 100 mesh, and plasticizing aid The mixing ratio of the agent and the fine rubber powder is preferably from 3 to 15: 97 to 85. L--e. Involved in the combination of room temperature pulverization and reclaimed rubber in the non-thermal cracking method of the current market: a classified 50~800X50~800mm bulk waste polymer containing no harmful impurities such as metal skeleton The material is placed in the feeding hopper in the grinding wheel assembly device. After the bulk material is processed by the grinding wheel rubber mill, the large waste polymer material is ground into a mixed rubber powder of 20~200 mesh, and then the mixing is removed. Non-metallic fiber impurities that may be entrained in the rubber powder. The mixed rubber powder is mixed with additives such as powder insulation and then introduced into a shear-grinding rubber fine pulverizer for re-pulverization. The pulverized material is introduced into the classifier by airflow and separated by cyclone. In the device, the exhaust gas of the cyclone separator is evacuated or/re-used by the dust remover, and the pulverized material collected in the cyclone separator is introduced into the work storage silo, and the subsequent processing of the obtained pulverized material is connected with the well-known reclaimed rubber process. The obtained finely pulverized material contains at least 80% of a rubber powder which can pass through a 100 mesh screen, and the obtained fine-80-100 mesh-and ultrafine rubber powder-finely equal to 100 mesh-mixture Instead of regeneration Processes presently used 5 to 40 mesh coarse powder, plastic can reduce the regeneration process in refining operations is at least 50%. 2. The method of claim 1 wherein:  The combination of the three steps described in l--a. also includes:  Control the 50~800X 50~800mm waste polymer material in the intermediate product group I, or / and the 5~200 mesh waste polymer material powder by controlling the type and quantity of the feed in step I and step II. The ratio of the weight of the thermally cracked carbon black in the intermediate group II is in the range of 100:10 to 900, especially in the range of 100:20 to 60 and 100:400 to 900;  Control the rubber blocks of 50~500X 50~500 waste polymer materials in the intermediate product group I, or / and the waste polymer materials of 5~200 mesh, by controlling the type and quantity of the feed in step I and step II. The ratio of the weight of the tar residue in the intermediate product group II is in the range of 100: 2 to 100, particularly preferably in the range of 100: 2 to 20. 3. The method of claim 1 wherein:  \→The method is applied to the pulverization operation of rigid materials and high-molecular materials such as thermal cracking carbon black slag with coarse meshes such as 5~20 mesh, which effectively avoids the use of ultrafine pulverization in one pass, which often leads to coarseness in the obtained product. The disadvantages of rigid materials such as carbon black in 200 mesh. 4. The method of claim 1 wherein:  (2.-a) The use of commercially available/self-made 50~800X50~800mm waste polymer materials, or / and commercially available/self-made miscellaneous fiber skeletons, to perform heat cracking processing; Or / and (2.-b) using commercially available / self-made thermal cracking carbon black or / and tar residue and commercially available / self-made 5 ~ 200 mesh waste polymer material powder, superfine pulverization or / and Heating, sulfurization, plasticization, mixing processing. 5. The method according to claim 1, characterized by: specifically comprising: improving the non-thermal cracking process, and further providing a recycling of the waste fiber obtained from the waste polymer products such as tires and tapes. The treatment scheme _: mixing the waste fiber with the plasticized rubber material or/and the oil material by weight ratio of 100: 5-100 to obtain a felt-like or rubber-like mixture; the plasticized rubber Materials, oil materials, including at least one or more of the following materials - (a) oily plant kernels, fruit materials, (b) vegetable oils, resins and derivatives, (c) oily and decolorized sludge materials, (d) rubber and plastic softeners, and (e) vulcanized rubber powder Modified, (f) rubber, plastic emulsion; (a) Oily plant kernels and fruit materials, including but not limited to: Tung oil tree kernels, olive kernels, coconut kernels, cotton kernels, rapeseed, peanut kernels, soybeans, palm kernels, safflower seeds, sunflower seeds, tea Ziren, Linseed, Suziren, Rubber Seeds, Olive Oil, Blackberry Seed, Wenguan Nut, Mountain Almond, Maozizi, Gardenia, Pistacia, Eucalyptus, Walnut, Samara Oil, One or more combinations of immature pine nuts, etc.; (b) Vegetable oils, resins and derivatives, including but not limited to: corn germ oil, rice bran oil, cottonseed oil, rapeseed oil, peanut oil, soybean oil, palm oil, sunflower oil, olive oil, tea oil, coconut Kernel oil, tung oil, linseed oil, black scorpion seed oil, sage oil, restaurant oil, rosin, Taikoo oil, hydrogenated rosin, dehydrogenated rosin, rosin glyceride, rosin pentaerythritol ester, xylene rosin resin, rosin ester, One or more combinations of pine resin, metase resin, eucalyptus resin, peach resin, waste peanut pulp, and the like;  (C) Desiccant-containing materials containing oil and fat, including but not limited to: one or more combinations of oil, oil, fat, fatty acid activated carbon or clay slag which are discarded in the decolorization and purification section of the refinery;  (d) Common softeners for rubber and plastics, including but not limited to: lubricating oil, engine oil, white oil, halogenated paraffin oil, paraffin oil, third-line oil, six-line oil, transformer oil, polybutene oil, C4~18 fatty acid, petroleum jelly , halogenated paraffin, paraffin, beeswax, animal oil, black grease, white grease, odorless asphalt, emulsified asphalt, epoxidized soybean oil, nonyl phenolic resin, bismuth resin, petroleum resin, octyl phenolic resin, ancient horse Long, styrene resin, low molecular weight polyethylene wax, low molecular weight polypropylene wax, stearic acid, palmitic acid, oleic acid, palmitic acid, polyvinyl alcohol, pentanol, hexanol, heptanol, octanol, sterol , decadiol, tetradecanol, cetyl alcohol, stearyl alcohol, cyclopentanol, cyclohexanol, benzyl alcohol, ethylene glycol, propylene glycol, glycerol, 2-ethylhexanol, 2-octanol, Lauryl alcohol, terpineol, (C7~18) mixed fatty alcohol, pentaerythritol, xylitol, dipropylene glycol, dibutyl phthalate, diisobutyl phthalate, phthalic acid diester Alcohol ester, tributyl phosphate, phosphoric acid Ester, triphenyl phosphate, tricresyl phosphate, diphenyl-2-ethylhexyl phosphate, dioctyl terephthalate, dioctyl adipate, di-2-ethylhexyl adipate One or a combination of one or more of di-2-ethylhexyl sebacate; (e) A modified product of vulcanized rubber powder, including but not limited to: one or one of a sulfurized rubber powder, a sulfurized plastic compound modified with a vulcanized rubber powder, a recycled rubber emulsion, an emulsion of a rubber powder modified asphalt, and the like. Combination of the above;  (f) one or more combinations of rubber and plastic emulsions, including but not limited to: rubber emulsion, rubber asphalt emulsion, waste plastic asphalt emulsion;  The resulting felt-like or gel-like, linoleum-like mixture can be made into a separate re-cycled product. 6. The method according to claim 1, comprising combining a waste rubber and plastic polymer material regeneration process with a common carbon black production process, characterized by: comprising at least one or more of the following combinations:  6~a. It will be derived from the tail gas generated in the ordinary carbon black production process, recovered by the waste heat boiler, and converted into steam for the heating required for the recycling of waste rubber and plastic polymer materials;  6-b. The electric energy derived from the exhaust gas produced in the ordinary carbon black production process and converted by the waste heat boiler and steam turbine is supplied to the mechanical electricity used for the recycling of used rubber and plastic polymer materials;  6--C. The combustible gas and/or fuel oil obtained by thermal cracking of waste rubber and plastic polymer materials will be supplied to carbon black for carbon source and fuel. 7. An integrated device for implementing the method of claim 1 comprising a combination of two major types of integrated devices, thermal cracking and non-thermal cracking, characterized by:  A sub-assembly A comprising a process of thermally cracking a waste polymer material, or/and a sub-device B processed by fine or ultra-fine pulverization, or/and a sub-device C processed by a process such as sulfurization plasticization, mixing, etc. An integrated device; wherein, the organic combination of the sub-devices A, B, and C is obtained, including the sub-devices A and B or/and C in the well-known configuration, after adding and subtracting their respective sub-sets. Reintegration. 8. The integrated device according to claim 7, further comprising: The sub-assembly A includes the carbon black treatment section of the known thermal cracking equipment for processing rubber such as waste tires, minus the matching carbon black ultra-fine pulverization or/and ultra-fine carbon black bagging equipment; Or a raw material inlet before the tank or column or column or rotary kiln and a mechanism of inputting the pulverized fiber between the "heterofiber skeleton" collecting mechanism of the sub-device B; in the "thermal cracking carbon black" powder which is finer than 5~250 mesh a transport mechanism is disposed between each of the graded storage bins and the sub-device B; or Finer than 200~500 mesh "thermal cracking carbon black" fine powder storage silo and sub-device C are provided with a mechanism for transporting carbon black; wherein the sub-device B, including the well-known finely pulverized or super-processed waste tire rubber A mechanism for inputting carbon black is disposed between the mechanism of the finely shredded equipment storage bin or the batching section and the sub-assembly A; and the conveying of the miscellaneous fibers is disposed between the "heavy fiber skeleton" collecting mechanism and the sub-assembly A. Institution  The sub-assembly C therein includes a fine-grained storage of 200-mesh "thermal cracking carbon black" with sub-assembly A before the known dynamic desulfurization tank or kettle or kneading or extrusion equipment for the production of recycled rubber equipment. A mechanism for inputting carbon black is disposed between the silos; a mechanism for transporting the chopped fibers is disposed between the "heterofiber skeleton" collecting mechanism and the sub-device A; and the mechanism for transporting carbon black and miscellaneous fibers in the integrated device refers to: One or a combination of a screw conveyor, a scraper conveyor, a bucket conveyor, a pipe chain conveyor, an air conveyor, a conveyor carrier, and the like;  The mechanism for conveying tar residue in the aforementioned integrated device means: one or a combination of one or more of a conveying pipe, a tank truck, or a carrier when the material is in a solid state. 9. An integrated device for implementing the method of claim 1, further comprising a solution for improving or complementing B or B and C between the current room temperature pulverizing or room temperature pulverizing and regenerating rubber branching integrated devices, said combination The setting includes at least one or more combinations as follows:  9 a. The complementary device is implemented between the integrated devices B used in each branch of the normal temperature pulverization process, and is characterized in that the rubber powder or the rubber powder is stored in a known grinding wheel type normal temperature fine pulverizing combination device (B roll). a storage compartment of the powder separator mixture, and a guide mechanism is provided between the feed port of the shearing disc fine pulverizer in the shear-grinding rubber fine pulverizing combination device (B shear), and the original (B shear) is retained. The shearing grinding disc finely pulverizes the mechanical unit of the core unit, the subsequent mechanical setting, and retains the original mechanical setting of the storage bin of the original (B-rolling) in which the rubber powder or the mixture of the rubber powder and the powder release agent is stored;  9-b. A complementary solution is implemented between the integrated devices B used in each branch of the room temperature pulverization process, which is characterized by: fine pulverization, wind-guided spiral in a known shear-grinding type rubber fine pulverizing combination device (B-shear) After the separated pulverized material outlet, at least one set of pulverizing and air-extracting materials mechanically connected in series by the shear grinding disc type fine pulverization and the wind guiding spiral separation unit is provided, and the conventionally known shearing disc type rubber fine pulverizing combination is changed. The first-stage fine pulverization in the device (B-stage shear) is set to at least a fine pulverization setting comprising two stages in series, that is, a combined device (B secondary shear);  9-C. A modification of the plasticizing treatment device for fine rubber powder is added to the grinding wheel assembly device (B mill) in the normal temperature pulverization method, which is characterized by: after the classification device in the grinding wheel assembly device (B grinding) a machine capable of adding a plasticizing aid and a mixing machine, the machine comprising at least one of a mixing machine, a kneading machine, a mixing screw machine, a material tank (a plasticizing agent, and a rubber powder mixture) Or a combination of more than one;  9-d. B and C between the branching integrated devices of room temperature pulverizing and reclaimed rubber implement complementary complementary schemes, which are characterized by: at least 60% storage at room temperature fine pulverizing assembly (B roll) or / and (B shear) The above is a guide between a rubber powder storage bin capable of passing through a 100 mesh screen and a coarse rubber powder storage bin or/and a high temperature tank or/and an internal mixer or/and a screw machine in a known reclaimed rubber combination device C. Material institution  The guiding mechanism also refers to: one or more combinations of a screw conveyor, a scraper conveyor, a chain bucket conveyor, a pipe chain conveyor, a gas conveyor, and a conveyor carrier. 10. An integrated device for carrying out the method according to claim 1, further comprising a mechanical fines and a fine powder collection bin for the current fine or superfine pulverizer discharge port or/and the subsequent powder collection bin after the sieve A combination device having a higher classification efficiency than the prior art rubber particle size classification section using only the mechanical sieve is characterized in that the set of the rubber particle size fractionation device is a well-known cyclone separator 1 and a gravity to air flow. The particle classifiers are formed in series;  The gravity-flow particle classifier described therein, the structure of which: Set the primary air inlet duct 2, and introduce the primary air carrying the mixed particle size rubber powder into the gravity-flow air particle classifier; Set the deceleration section 3, which slows down the wind speed, to separate and deposit the coarse and heavy rubber particles. Set the horizontal or upwardly inclined tail passage 4 to make the fine separation from the gravity-flow particle classifier. When the particles leave, try not to take the coarse rubber powder; set the secondary air inlet duct 5 inclined or vertically downward to prevent the material from leaking out during the stop; at the perigee of the deceleration section 3, set the second time. The intersection of the wind flow and the gravity flow of the particulate material collides with the collision point 6, the intersection collision point 6 is at least one set in the gravity ~ air flow particle classifier; the coarse particles separated in the gravity ~ air flow particle classifier are vertically set Road 7 flows out of the weight; ^ ~ airflow particle classifier;  In the configuration of the gravity-flow particle classifier as described above, the method further includes: The collision angle between the secondary air flow and the gravity flow of the granular material is 6 , and the collision angle of the two flows is preferably less than or equal to 90°, and the departure angle after the collision of the two flows is preferably greater than or equal to 120 ^Q ;  The flow segment that decelerates the primary wind, specifically, the air passage is set such that the linear velocity of the primary wind is slower than the primary wind before the airflow is set in the air passage, that is, the section is set. The cross-sectional area of the air duct is larger than the cross-sectional area of the air passage of the section;  The gravity-flow particle classifier or a combination thereof in series with a known cyclone can be used as an independent mechanical product. 11. An integrated device for implementing the method of claim 1, comprising a combination of a carbon black production device and a production device for recycling secondary processing of waste rubber and plastic polymer materials, characterized in that - in the carbon black production device E a heat transfer A or / and a normal temperature pulverization B or / and reclaimed rubber C or / and plastic granulation D production device is provided with energy, material transport mechanism;  The conveying mechanism includes, but is not limited to, one or more combinations as described below:  Ll--a. Waste heat recovery steam storage package in carbon black production unit E and production equipment for waste rubber and plastic secondary utilization processing (thermal cracking A or / and rubber powder B or / and reclaimed rubber C or / and Extrusion granulation D) between the turbine generator or / and the steam 'package, or / and (in the reclaimed rubber B) between the sulfur-reducing heating tank is provided with a pipeline for conveying steam;  Ll--b. Waste heat recovery steam storage steam or steam turbine in carbon black production unit E and waste steel and plastic secondary production processing equipment (thermal cracking A or / and rubber powder B or / and reclaimed rubber A line for transporting steam is provided between the steam pack in C or / and extrusion granulation D), or / and (in reclaimed rubber B) between the sulfur-breaking heating tanks:  11--C. Turbine generators that recover electrical energy from steam in carbon black production unit E or/and transformers of the original commercial grid and secondary processing of waste rubber and plastic (thermal cracking A or / and rubber powder B Or / and reclaimed rubber C or / and extrusion granulation D) between the power supply transformer or / and the motor in the production device, is provided with a cable circuit for delivering electrical energy;  11-d. Thermal cracking furnace or/and gas storage, oil storage tank and combustion furnace in carbon black production unit E in the thermal cracking A production plant of waste rubber and plastic secondary processing, and/or gas storage and storage Between the oil tanks, there are pipes for conveying flammable gas and fuel.