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WO2008125567A3 - Method for making a metallised graphitic felt member homogenously coated on its entire volume with a conducting organic polymer - Google Patents

Method for making a metallised graphitic felt member homogenously coated on its entire volume with a conducting organic polymer Download PDF

Info

Publication number
WO2008125567A3
WO2008125567A3 PCT/EP2008/054293 EP2008054293W WO2008125567A3 WO 2008125567 A3 WO2008125567 A3 WO 2008125567A3 EP 2008054293 W EP2008054293 W EP 2008054293W WO 2008125567 A3 WO2008125567 A3 WO 2008125567A3
Authority
WO
WIPO (PCT)
Prior art keywords
metallised
organic polymer
felt member
making
entire volume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/054293
Other languages
French (fr)
Other versions
WO2008125567A2 (en
Inventor
Olivier Lavastre
Didier Floner
Florence Geneste
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite de Rennes 1
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite de Rennes 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite de Rennes 1 filed Critical Centre National de la Recherche Scientifique CNRS
Publication of WO2008125567A2 publication Critical patent/WO2008125567A2/en
Publication of WO2008125567A3 publication Critical patent/WO2008125567A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00—Electrophoretic coating characterised by the process
    • C25D13/18—Electrophoretic coating characterised by the process using modulated, pulsed, or reversing current
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4476—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications comprising polymerisation in situ
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/24—Electrodes for alkaline accumulators
    • H01M4/26—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/8807—Gas diffusion layers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8817—Treatment of supports before application of the catalytic active composition
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9008—Organic or organo-metallic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Composite Materials (AREA)
  • Molecular Biology (AREA)
  • Wood Science & Technology (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Fuel Cell (AREA)

Abstract

The invention relates to a method for making a metallised graphitic felt member homogenously coated on its entire volume with a conducting organic polymer, said method comprising the steps of: inserting into an electropolymerisation device a solution containing from 10-3 M to 1 M of a monomer in at least one organic solvent containing at least one carrier electrolyte, the device comprising a working electrode and a counter-electrode that comprises two holders between which the metallised graphitic felt member is held, at least one of said holders including electric current conducting means; starting the electropolymerisation of the monomer on the metallised felt by successive cycles, each cycle including a phase for applying a current with an intensity between 100 mA and 500 mA for 15 to 30 seconds and a rest phase of one to two minutes; and extraction from the electropolymerisation device the metallised graphitic felt member homogenously coated on its entire volume with said conducting organic polymer. The product thus obtained can be used for making accumulator reversible electrodes or for accumulators of the metal/hydride type or for fuel cells of the O2/ H2 type.
PCT/EP2008/054293 2007-04-10 2008-04-09 Method for making a metallised graphitic felt member homogenously coated on its entire volume with a conducting organic polymer Ceased WO2008125567A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0702623A FR2914931B1 (en) 2007-04-10 2007-04-10 METHOD FOR MANUFACTURING A HOMOGENEOUSLY COATED METALLIC GRAPHIC FELT ELEMENT IN ALL ITS VOLUME OF A CONDUCTIVE ORGANIC POLYMER
FR0702623 2007-04-10

Publications (2)

Publication Number Publication Date
WO2008125567A2 WO2008125567A2 (en) 2008-10-23
WO2008125567A3 true WO2008125567A3 (en) 2009-09-03

Family

ID=38669765

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/054293 Ceased WO2008125567A2 (en) 2007-04-10 2008-04-09 Method for making a metallised graphitic felt member homogenously coated on its entire volume with a conducting organic polymer

Country Status (2)

Country Link
FR (1) FR2914931B1 (en)
WO (1) WO2008125567A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2989225A1 (en) * 2012-04-10 2013-10-11 Univ Rennes CIRCULATING ELECTROLYTE FUEL CELL DEVICE PERCOLATING THROUGH ELECTRODES WITH A THREE DIMENSIONAL POROUS STRUCTURE
US9771483B2 (en) 2013-04-19 2017-09-26 The Boeing Company Systems, compositions, and methods for corrosion inhibition
FR3028264A1 (en) 2014-11-07 2016-05-13 Univ Rennes USE OF AN ELECTROCHEMICAL REACTOR COMPRISING AT LEAST ONE POROUS ELECTRODE, AND METHOD FOR IMPLEMENTING THE SAME
CN117174923B (en) * 2023-11-03 2024-02-06 杭州德海艾科能源科技有限公司 Graphite felt for enhancing solid-liquid interface interaction and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6345389A (en) * 1986-08-13 1988-02-26 Agency Of Ind Science & Technol Metal oxide supporting graphite electrode
US5085743A (en) * 1990-05-02 1992-02-04 Physical Sciences, Inc. Electrode for current-limited cell, cell including the electrode method for using the cell and a method of making the electrode
EP0930663A1 (en) * 1998-01-15 1999-07-21 Alcatel Non-sintered nickel electrode
FR2846012A1 (en) * 2002-10-18 2004-04-23 Univ Rennes DEVICE FOR METALLIZING A GRAPHIC FELT, METHOD IMPLEMENTED THROUGH THIS DEVICE, CORRESPONDING METALLIC GRAPHIC FELT AND USE OF SUCH A METALLIC GRAPHIC FELT

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6345389A (en) * 1986-08-13 1988-02-26 Agency Of Ind Science & Technol Metal oxide supporting graphite electrode
US5085743A (en) * 1990-05-02 1992-02-04 Physical Sciences, Inc. Electrode for current-limited cell, cell including the electrode method for using the cell and a method of making the electrode
EP0930663A1 (en) * 1998-01-15 1999-07-21 Alcatel Non-sintered nickel electrode
FR2846012A1 (en) * 2002-10-18 2004-04-23 Univ Rennes DEVICE FOR METALLIZING A GRAPHIC FELT, METHOD IMPLEMENTED THROUGH THIS DEVICE, CORRESPONDING METALLIC GRAPHIC FELT AND USE OF SUCH A METALLIC GRAPHIC FELT

Also Published As

Publication number Publication date
FR2914931A1 (en) 2008-10-17
FR2914931B1 (en) 2012-06-15
WO2008125567A2 (en) 2008-10-23

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