WO2008120660A1 - 新規ホスフィンおよびその製造方法と用途 - Google Patents
新規ホスフィンおよびその製造方法と用途 Download PDFInfo
- Publication number
- WO2008120660A1 WO2008120660A1 PCT/JP2008/055855 JP2008055855W WO2008120660A1 WO 2008120660 A1 WO2008120660 A1 WO 2008120660A1 JP 2008055855 W JP2008055855 W JP 2008055855W WO 2008120660 A1 WO2008120660 A1 WO 2008120660A1
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- WO
- WIPO (PCT)
- Prior art keywords
- groups
- substituted
- group
- same
- hydrocarbon
- Prior art date
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title abstract 5
- 229910000073 phosphorus hydride Inorganic materials 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910052731 fluorine Inorganic materials 0.000 abstract 3
- 125000001153 fluoro group Chemical group F* 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000003277 amino group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000002102 aryl alkyloxo group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000004104 aryloxy group Chemical group 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- -1 methacrylate ester Chemical class 0.000 abstract 2
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000003003 phosphines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/58—Pyridine rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
式（１）：
（式中、Ｒ１、Ｒ２、Ｒ３、Ｒ４およびＲ５は、それぞれ独立に、水素原子、ハロゲン原子、若しくはフッ素原子で置換されていてもよい、アルキル基、アラルキル基またはアリール基、炭化水素基で置換されたシリル基、二つの炭化水素基で置換されたアミノ基、アルコキシ基、アラルキルオキシ基およびアリールオキシ基からなる群から選ばれる置換基を表す。Ｒ６、Ｒ７、Ｒ８およびＲ９は、それぞれ独立に、水素原子、ハロゲン原子、アルキル基、アラルキル基、アリール基、炭化水素基で置換されたシリル基、二つの炭化水素基で置換されたアミノ基、アルコキシ基、アラルキルオキシ基およびアリールオキシ基からなる群から選ばれる置換基を表す。但しＲ２、Ｒ３およびＲ４の少なくとも一つはフッ素原子あるいはフッ素原子で置換されたアルキル基であり、Ｒ１、Ｒ２、Ｒ３、Ｒ４、Ｒ５、Ｒ６、Ｒ７、Ｒ８およびＲ９のうち隣接する基は互いに結合して環を形成していてもよい。）
で示されるホスフィン。このホスフィンは、アセチレン化合物と一酸化炭素およびアルコールからメタクリル酸エステルを製造するための触媒成分として有用である。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007087296 | 2007-03-29 | ||
| JP2007-087296 | 2007-03-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008120660A1 true WO2008120660A1 (ja) | 2008-10-09 |
Family
ID=39808242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2008/055855 WO2008120660A1 (ja) | 2007-03-29 | 2008-03-27 | 新規ホスフィンおよびその製造方法と用途 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2008266307A (ja) |
| WO (1) | WO2008120660A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011111806A1 (en) * | 2010-03-09 | 2011-09-15 | Sumitomo Chemical Company, Limited | METHOD FOR PRODUCING α, β-UNSATURATED CARBOXYLATE, AND CATALYST FOR PRODUCING THEREOF |
| WO2012111737A1 (ja) * | 2011-02-17 | 2012-08-23 | 国立大学法人岡山大学 | 新規化合物、新規配位子、新規遷移金属錯体および新規遷移金属錯体からなる触媒 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20100116667A (ko) | 2008-02-18 | 2010-11-01 | 스미또모 가가꾸 가부시키가이샤 | 조성물 및 그것을 이용한 유기 광전 변환 소자 |
| WO2011043483A1 (ja) * | 2009-10-08 | 2011-04-14 | 住友化学株式会社 | 金属錯体、ピリジルホスフィン化合物およびアルキルメタクリレートの製造方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03167196A (ja) * | 1989-10-20 | 1991-07-19 | Shell Internatl Res Maatschappij Bv | リン化合物 |
| JPH0592984A (ja) * | 1991-02-15 | 1993-04-16 | Shell Internatl Res Maatschappij Bv | ジアリールホスフイノピリジンの製造方法 |
| JPH05255362A (ja) * | 1991-12-14 | 1993-10-05 | Hoechst Ag | 第三ホスフアンの製造方法 |
| JPH0820592A (ja) * | 1994-07-04 | 1996-01-23 | Hokko Chem Ind Co Ltd | ２−ジフェニルホスフィノピリジンの製造方法 |
| JPH09188632A (ja) * | 1986-12-05 | 1997-07-22 | Shell Internatl Res Maatschappij Bv | アセチレン系不飽和化合物のカルボニル化方法 |
| JPH11147855A (ja) * | 1997-11-17 | 1999-06-02 | Daicel Chem Ind Ltd | カルボニル化方法 |
| JP2008088153A (ja) * | 2006-04-10 | 2008-04-17 | Okayama Univ | アミド化合物を製造する方法及びその方法に使用される触媒 |
-
2008
- 2008-03-18 JP JP2008068998A patent/JP2008266307A/ja not_active Withdrawn
- 2008-03-27 WO PCT/JP2008/055855 patent/WO2008120660A1/ja active Application Filing
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09188632A (ja) * | 1986-12-05 | 1997-07-22 | Shell Internatl Res Maatschappij Bv | アセチレン系不飽和化合物のカルボニル化方法 |
| JPH03167196A (ja) * | 1989-10-20 | 1991-07-19 | Shell Internatl Res Maatschappij Bv | リン化合物 |
| JPH0592984A (ja) * | 1991-02-15 | 1993-04-16 | Shell Internatl Res Maatschappij Bv | ジアリールホスフイノピリジンの製造方法 |
| JPH05255362A (ja) * | 1991-12-14 | 1993-10-05 | Hoechst Ag | 第三ホスフアンの製造方法 |
| JPH0820592A (ja) * | 1994-07-04 | 1996-01-23 | Hokko Chem Ind Co Ltd | ２−ジフェニルホスフィノピリジンの製造方法 |
| JPH11147855A (ja) * | 1997-11-17 | 1999-06-02 | Daicel Chem Ind Ltd | カルボニル化方法 |
| JP2008088153A (ja) * | 2006-04-10 | 2008-04-17 | Okayama Univ | アミド化合物を製造する方法及びその方法に使用される触媒 |
Non-Patent Citations (1)
| Title |
|---|
| SPENCER L.P. ET AL.: "Pyridine- and Imidazole-Phosphinimine Bidentate Ligand Complexes: Considerations for Ethylene Oligomerization Catalysts", ORGANOMETALLICS, vol. 22, no. 19, 2003, pages 3841 - 3854, XP001174915, DOI: doi:10.1021/om030311t * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011111806A1 (en) * | 2010-03-09 | 2011-09-15 | Sumitomo Chemical Company, Limited | METHOD FOR PRODUCING α, β-UNSATURATED CARBOXYLATE, AND CATALYST FOR PRODUCING THEREOF |
| WO2012111737A1 (ja) * | 2011-02-17 | 2012-08-23 | 国立大学法人岡山大学 | 新規化合物、新規配位子、新規遷移金属錯体および新規遷移金属錯体からなる触媒 |
| US8779133B2 (en) | 2011-02-17 | 2014-07-15 | National University Corporation Okayama University | Compound, novel ligand, novel transition metal complex, and catalyst including novel transition metal complex |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008266307A (ja) | 2008-11-06 |
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