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WO2008108181A1 - 金合金被膜、金合金被膜被覆積層体及び金合金被膜被覆部材 - Google Patents

金合金被膜、金合金被膜被覆積層体及び金合金被膜被覆部材 Download PDF

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Publication number
WO2008108181A1
WO2008108181A1 PCT/JP2008/052988 JP2008052988W WO2008108181A1 WO 2008108181 A1 WO2008108181 A1 WO 2008108181A1 JP 2008052988 W JP2008052988 W JP 2008052988W WO 2008108181 A1 WO2008108181 A1 WO 2008108181A1
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Prior art keywords
alloy coating
gold alloy
gold
colored
providing
Prior art date
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Ceased
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PCT/JP2008/052988
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English (en)
French (fr)
Inventor
Kenya Karuishi
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Citizen Tohoku Co Ltd
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Citizen Tohoku Co Ltd
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Priority to JP2009502512A priority Critical patent/JPWO2008108181A1/ja
Priority to EP08711771A priority patent/EP2135972A4/en
Publication of WO2008108181A1 publication Critical patent/WO2008108181A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/018—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of a noble metal or a noble metal alloy
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C14/00—Alloys based on titanium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C5/00—Alloys based on noble metals
    • C22C5/02—Alloys based on gold
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0015—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterized by the colour of the layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/021—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/341—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one carbide layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/347—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with layers adapted for cutting tools or wear applications
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/80—After-treatment
    • G—PHYSICS
    • G04—HOROLOGY
    • G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B19/00—Indicating the time by visual means
    • G04B19/04—Hands; Discs with a single mark or the like
    • G04B19/042—Construction and manufacture of the hands; arrangements for increasing reading accuracy
    • G—PHYSICS
    • G04—HOROLOGY
    • G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B37/00—Cases
    • G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Physical Vapour Deposition (AREA)
  • Laminated Bodies (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

　機能性とコストパフォーマンスに優れた、赤味を帯びた金色ないしはピンク色系の金色を呈する金合金被膜を、乾式メッキ法によって提供する。金合金被膜は、乾式メッキ法によって成膜され、金合金被膜中の全成分の合計を１００重量％としたとき、金（Ａｕ）を７０～８５重量％、銅（Ｃｕ）を１５～２８重量％、パラジウム（Ｐｄ）を０．５～２．０重量％含んだ組成からなる。また、基材（２）に、硬質の下地メッキ被膜（３）と、その上面にこの金合金被膜（４）を成膜することによって、耐摩耗性、耐傷性を始めとする高い機能性を持つ金合金被膜部材を提供できる。
PCT/JP2008/052988 2007-03-02 2008-02-21 金合金被膜、金合金被膜被覆積層体及び金合金被膜被覆部材 Ceased WO2008108181A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2009502512A JPWO2008108181A1 (ja) 2007-03-02 2008-02-21 金合金被膜、金合金被膜被覆積層体及び金合金被膜被覆部材
EP08711771A EP2135972A4 (en) 2007-03-02 2008-02-21 GOLD ALLOY COATING, GOLD ALLOY COATING SHEATH LAMINATE AND GOLD ALLOY COATING SHEATH ELEMENT.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-053005 2007-03-02
JP2007053005 2007-03-02

Publications (1)

Publication Number Publication Date
WO2008108181A1 true WO2008108181A1 (ja) 2008-09-12

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Application Number Title Priority Date Filing Date
PCT/JP2008/052988 Ceased WO2008108181A1 (ja) 2007-03-02 2008-02-21 金合金被膜、金合金被膜被覆積層体及び金合金被膜被覆部材

Country Status (4)

Country Link
EP (1) EP2135972A4 (ja)
JP (1) JPWO2008108181A1 (ja)
TW (1) TW200846480A (ja)
WO (1) WO2008108181A1 (ja)

Cited By (8)

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US20100227156A1 (en) * 2007-09-19 2010-09-09 Junji Satoh Decorative part
JP2011112462A (ja) * 2009-11-25 2011-06-09 Seiko Epson Corp 装飾品の製造方法、装飾品および時計
JP2014530962A (ja) * 2011-11-08 2014-11-20 ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド 金製の時計又は宝飾品
US20150378311A1 (en) * 2013-02-06 2015-12-31 Rolex Sa Timepiece made from rose gold alloy
JP2017167138A (ja) * 2016-03-16 2017-09-21 ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド 計時器用部品を装飾する方法
WO2017170324A1 (ja) * 2016-03-31 2017-10-05 シチズン時計株式会社 さくらピンク色の装飾部材およびその製造方法
JP2017181084A (ja) * 2016-03-28 2017-10-05 セイコーエプソン株式会社 装飾品、装飾品の製造方法および時計
US20190376175A1 (en) * 2018-06-11 2019-12-12 Citizen Watch Co., Ltd. Hard decorative member and method for manufacturing the same

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ITFI20120103A1 (it) * 2012-06-01 2013-12-02 Bluclad Srl Bagni galvanici per l'ottenimento di una lega di oro a bassa caratura e processo galvanico che utilizza detti bagni.
CH712210B1 (fr) * 2016-03-14 2020-02-14 Nivarox Sa Procédé de fabrication d'un composant d'affichage d'horlogerie.
EP3339983B1 (fr) * 2016-12-23 2020-07-01 The Swatch Group Research and Development Ltd Substrat en nacre revêtu d'une couche jaune
CN106977233B (zh) * 2017-03-01 2020-07-10 清华大学 一种用于工艺陶瓷的玫瑰金描金方法
IT201800003593A1 (it) * 2018-03-15 2019-09-15 Argor Heraeus Sa Lega d’oro resistente alla decolorazione e metodo di produzione della medesima
CN108893712A (zh) * 2018-07-06 2018-11-27 深圳市联合蓝海科技开发有限公司 表面带有镀层的贵金属制品及其制备方法
CN108570641A (zh) * 2018-07-06 2018-09-25 深圳市联合蓝海科技开发有限公司 表面带有镀层的贵金属制品及其制备方法
CN108914059A (zh) * 2018-07-06 2018-11-30 深圳市联合蓝海科技开发有限公司 表面带有镀层的贵金属制品及其制备方法
CN109097736B (zh) * 2018-09-06 2023-11-07 深圳市联合蓝海科技开发有限公司 表面带有镀层的贵金属制品及其制备方法
CN109136844A (zh) * 2018-10-12 2019-01-04 佛山科学技术学院 一种玫瑰金镀层及其制备工艺

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JPS61127863A (ja) 1984-11-22 1986-06-16 Seiko Instr & Electronics Ltd 外装部品
JPH10245646A (ja) 1997-03-07 1998-09-14 Seiko Epson Corp 金合金、装飾部材、携帯時計及び装飾部材の製造方法
JPH11335755A (ja) * 1998-05-27 1999-12-07 Ijima Kingin Kogyo Kk メガネ用合金
JP2002285359A (ja) * 2001-03-26 2002-10-03 Citizen Watch Co Ltd 硬化層を有する装飾部材及びその製造方法

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US9212408B2 (en) * 2007-09-19 2015-12-15 Citizen Holdings Co., Ltd. Decorative part with substrate and multi-layer hardening laminate
US20100227156A1 (en) * 2007-09-19 2010-09-09 Junji Satoh Decorative part
JP2011112462A (ja) * 2009-11-25 2011-06-09 Seiko Epson Corp 装飾品の製造方法、装飾品および時計
JP2014530962A (ja) * 2011-11-08 2014-11-20 ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド 金製の時計又は宝飾品
JP2016033263A (ja) * 2011-11-08 2016-03-10 ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド 金合金製の時計又は宝飾品
US10514661B2 (en) 2013-02-06 2019-12-24 Rolex Sa Timepiece made from rose gold alloy
US20150378311A1 (en) * 2013-02-06 2015-12-31 Rolex Sa Timepiece made from rose gold alloy
JP2016513175A (ja) * 2013-02-06 2016-05-12 ロレックス・ソシエテ・アノニムＲｏｌｅｘ Ｓａ ローズゴールド合金から作成される時計
JP2016514201A (ja) * 2013-02-06 2016-05-19 ロレックス・ソシエテ・アノニムＲｏｌｅｘ Ｓａ ローズゴールド合金から作成される時計
JP2017167138A (ja) * 2016-03-16 2017-09-21 ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド 計時器用部品を装飾する方法
JP2017181084A (ja) * 2016-03-28 2017-10-05 セイコーエプソン株式会社 装飾品、装飾品の製造方法および時計
JPWO2017170324A1 (ja) * 2016-03-31 2019-02-28 シチズン時計株式会社 装飾部材およびその製造方法
WO2017170324A1 (ja) * 2016-03-31 2017-10-05 シチズン時計株式会社 さくらピンク色の装飾部材およびその製造方法
JP2020116392A (ja) * 2016-03-31 2020-08-06 シチズン時計株式会社 装飾部材およびその製造方法
US11408066B2 (en) 2016-03-31 2022-08-09 Citizen Watch Co., Ltd. Decorative member and method for producing the same
US20190376175A1 (en) * 2018-06-11 2019-12-12 Citizen Watch Co., Ltd. Hard decorative member and method for manufacturing the same
JP2019214785A (ja) * 2018-06-11 2019-12-19 シチズン時計株式会社 硬質装飾部材及びその製造方法
US11015240B2 (en) 2018-06-11 2021-05-25 Citizen Watch Co., Ltd. Hard decorative member and method for manufacturing the same
JP7198726B2 (ja) 2018-06-11 2023-01-04 シチズン時計株式会社 硬質装飾部材及びその製造方法

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TW200846480A (en) 2008-12-01

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