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WO2008153002A1 - 硬化性含フッ素ポリマー組成物 - Google Patents

硬化性含フッ素ポリマー組成物 Download PDF

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Publication number
WO2008153002A1
WO2008153002A1 PCT/JP2008/060555 JP2008060555W WO2008153002A1 WO 2008153002 A1 WO2008153002 A1 WO 2008153002A1 JP 2008060555 W JP2008060555 W JP 2008060555W WO 2008153002 A1 WO2008153002 A1 WO 2008153002A1
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WO
WIPO (PCT)
Prior art keywords
containing polymer
fluorine
polymer composition
ethylenical
stain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/060555
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English (en)
French (fr)
Inventor
Masayuki Hayashi
Eiji Kitaura
Peter Cheshire Hupfield
Katsuhiko Imoto
Masaru Nagato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daikin Industries Ltd
DuPont Toray Specialty Materials KK
Dow Silicones Corp
Original Assignee
Daikin Industries Ltd
Dow Corning Toray Co Ltd
Dow Corning Corp
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Filing date
Publication date
Application filed by Daikin Industries Ltd, Dow Corning Toray Co Ltd, Dow Corning Corp filed Critical Daikin Industries Ltd
Priority to CN200880018353A priority Critical patent/CN101743281A/zh
Priority to US12/664,535 priority patent/US9018306B2/en
Priority to JP2009519248A priority patent/JP5307004B2/ja
Priority to EP08765345A priority patent/EP2159261B1/en
Priority to BRPI0812540A priority patent/BRPI0812540A2/pt
Publication of WO2008153002A1 publication Critical patent/WO2008153002A1/ja
Priority to IL201941A priority patent/IL201941A0/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1675—Polyorganosiloxane-containing compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6275—Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6279—Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/837—Chemically modified polymers by silicon containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16—Homopolymers or copolymers of vinylidene fluoride
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    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/10—Block or graft copolymers containing polysiloxane sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
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    • C08F214/28—Hexyfluoropropene
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    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C08F216/1416—Monomers containing oxygen in addition to the ether oxygen, e.g. allyl glycidyl ether
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    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
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    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
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    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/10—Block- or graft-copolymers containing polysiloxane sequences

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

　ヒドロシリル化反応により比較的低温で迅速に硬化し、高硬度で、可撓性を有すると共に、被膜表面を撥水撥油性にすることにより長期間にわたって防汚効果、特に汚れの除去性、拭き取り性を保つことができる被膜を形成する硬化性含フッ素ポリマー組成物を提供する。フッ化エチレン性単量体単位と非フッ化エチレン性単量体単位を含み、前記非フッ化エチレン性単量体単位の一部ないし全てが式： ［式中、Ｒ1は水素、メチル基；Ｒ2はエチレン性Ｃ＝Ｃを有する炭化水素基；Ｘは－Ｃ(Ｏ)ＮＨ－、－Ｃ(Ｏ)－；Ｒ3は－Ｏ－、－Ｏ[ＣＨ(Ｒ4)]mＯ－、－(ＣＨ2)mＯ－、－ＯＣ(Ｏ)－(ＣＨ2)nＯ－、－(ＣＨ2)mＯＣ(Ｏ)－(ＣＨ2)nＯ－｛式中、Ｒ4は－Ｈ、－ＯＨ、－ＣＨ2ＯＨ、－Ｏ－Ｘ－Ｒ2｝]の単位である含フッ素ポリマー、ケイ素原子結合水素原子を有するシロキサン系化合物、ヒドロシリル化反応用触媒、およびケイ素原子結合水素原子を含有しないシロキサン系化合物を含む硬化性含フッ素ポリマー組成物。
PCT/JP2008/060555 2007-06-15 2008-06-09 硬化性含フッ素ポリマー組成物 Ceased WO2008153002A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN200880018353A CN101743281A (zh) 2007-06-15 2008-06-09 固化性含氟聚合物组合物
US12/664,535 US9018306B2 (en) 2007-06-15 2008-06-09 Curable fluorine-containing polymer composition
JP2009519248A JP5307004B2 (ja) 2007-06-15 2008-06-09 硬化性含フッ素ポリマー組成物
EP08765345A EP2159261B1 (en) 2007-06-15 2008-06-09 Curable fluorine-containing polymer composition
BRPI0812540A BRPI0812540A2 (pt) 2007-06-15 2008-06-09 composição polimérica contendo flúor curável, e composição de revestimento
IL201941A IL201941A0 (en) 2007-06-15 2009-11-05 Curable fluorine-containing polymer composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007159335 2007-06-15
JP2007-159335 2007-06-15

Publications (1)

Publication Number Publication Date
WO2008153002A1 true WO2008153002A1 (ja) 2008-12-18

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ID=40129607

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PCT/JP2008/060555 Ceased WO2008153002A1 (ja) 2007-06-15 2008-06-09 硬化性含フッ素ポリマー組成物

Country Status (9)

Country Link
US (1) US9018306B2 (ja)
EP (1) EP2159261B1 (ja)
JP (1) JP5307004B2 (ja)
KR (1) KR20100049022A (ja)
CN (1) CN101743281A (ja)
BR (1) BRPI0812540A2 (ja)
IL (1) IL201941A0 (ja)
TW (1) TW200911905A (ja)
WO (1) WO2008153002A1 (ja)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011065155A1 (ja) * 2009-11-24 2011-06-03 ダイキン工業株式会社 硬化性樹脂組成物
WO2011065154A1 (ja) * 2009-11-24 2011-06-03 ダイキン工業株式会社 硬化性樹脂組成物
CN102911314A (zh) * 2011-08-02 2013-02-06 厦门名大科技有限公司 一种防污耐磨透明氟硅高分子材料及其制备方法
WO2013051669A1 (ja) * 2011-10-05 2013-04-11 旭硝子株式会社 含フッ素オレフィン／ビニルアルコール共重合体とアルコキシシラン化合物とを含有する組成物、該組成物から形成する硬化物および該硬化物からなるフィルム
WO2013115267A1 (ja) * 2012-01-31 2013-08-08 ダイキン工業株式会社 含フッ素重合体及びその製造方法
WO2013118784A1 (ja) * 2012-02-09 2013-08-15 ダイキン工業株式会社 含フッ素重合体及びその製造方法
JP2017165958A (ja) * 2016-03-10 2017-09-21 ダイキン工業株式会社 重合体、組成物、塗膜、積層体、バックシート及び太陽電池モジュール
CN114716913A (zh) * 2022-03-17 2022-07-08 中国船舶重工集团公司第七二五研究所 一种双亲性防污活性剂及其制备方法

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KR20120130782A (ko) * 2010-03-16 2012-12-03 다이킨 고교 가부시키가이샤 경화성 수지 조성물, 경화물 및 불소 함유 중합체
CN102496642B (zh) * 2011-12-22 2013-07-17 云南云天化股份有限公司 太阳能电池背板及其制备方法
JP5936184B2 (ja) 2012-02-14 2016-06-15 国立大学法人福井大学 ヒドロキシル基含有ビニルエーテルのホモポリマー又はランダム共重合体の製造方法
CN103509422B (zh) 2012-06-29 2018-07-31 3M创新有限公司 一种疏水和疏油的涂层组合物
CN103193919B (zh) * 2013-03-14 2015-04-15 北京化工大学 端硅烷基液体氟聚合物的制备方法及固化方法
CN103602094A (zh) * 2013-11-21 2014-02-26 董绍品 一种自洁自阻燃自发光材料及其制备方法
CN105330867B (zh) * 2015-12-07 2017-11-17 浙江汉邦化工有限公司 一种有机氟硅表面处理剂及其制备方法
CN109689773B (zh) * 2016-07-01 2021-09-03 浙江新安化工集团股份有限公司 包覆型氟聚合物颗粒及包含其的聚合物共混物和聚合物组合物
TWI801443B (zh) * 2017-10-27 2023-05-11 美商陶氏有機矽公司 可固化聚有機矽氧烷組成物、藉由固化該等組成物獲得之固化體、及包含其之電子裝置
US10190234B1 (en) * 2017-10-30 2019-01-29 Wisconsin Alumni Research Foundation Continuous system for fabricating multilayer heterostructures via hydride vapor phase epitaxy
EP3998297A4 (en) * 2019-08-06 2023-12-06 Daikin Industries, Ltd. FLUORINE-CONTAINING POLYMER FOR METAL-COVERED LAMINATED FILM, COMPOSITION FOR METAL-COVERED LAMINATED FILM, CURABLE COMPOSITION, METAL-COVERED LAMINATED FILM AND PRINTED SUBSTRATE

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JP5418602B2 (ja) * 2009-11-24 2014-02-19 ダイキン工業株式会社 硬化性樹脂組成物
WO2011065154A1 (ja) * 2009-11-24 2011-06-03 ダイキン工業株式会社 硬化性樹脂組成物
WO2011065155A1 (ja) * 2009-11-24 2011-06-03 ダイキン工業株式会社 硬化性樹脂組成物
JP5494671B2 (ja) * 2009-11-24 2014-05-21 ダイキン工業株式会社 硬化性樹脂組成物
CN102911314A (zh) * 2011-08-02 2013-02-06 厦门名大科技有限公司 一种防污耐磨透明氟硅高分子材料及其制备方法
WO2013051669A1 (ja) * 2011-10-05 2013-04-11 旭硝子株式会社 含フッ素オレフィン／ビニルアルコール共重合体とアルコキシシラン化合物とを含有する組成物、該組成物から形成する硬化物および該硬化物からなるフィルム
JP2013177570A (ja) * 2012-01-31 2013-09-09 Daikin Industries Ltd 含フッ素重合体及びその製造方法
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WO2013115267A1 (ja) * 2012-01-31 2013-08-08 ダイキン工業株式会社 含フッ素重合体及びその製造方法
JP2013177585A (ja) * 2012-02-09 2013-09-09 Daikin Industries Ltd 含フッ素重合体及びその製造方法
WO2013118784A1 (ja) * 2012-02-09 2013-08-15 ダイキン工業株式会社 含フッ素重合体及びその製造方法
JP2017165958A (ja) * 2016-03-10 2017-09-21 ダイキン工業株式会社 重合体、組成物、塗膜、積層体、バックシート及び太陽電池モジュール
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CN114716913A (zh) * 2022-03-17 2022-07-08 中国船舶重工集团公司第七二五研究所 一种双亲性防污活性剂及其制备方法
CN114716913B (zh) * 2022-03-17 2023-03-03 中国船舶重工集团公司第七二五研究所 一种双亲性防污活性剂及其制备方法

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JP5307004B2 (ja) 2013-10-02
KR20100049022A (ko) 2010-05-11
JPWO2008153002A1 (ja) 2010-08-26
BRPI0812540A2 (pt) 2016-07-05
US20100210769A1 (en) 2010-08-19
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CN101743281A (zh) 2010-06-16
TW200911905A (en) 2009-03-16

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