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WO2008152854A1 - ペースト組成物と太陽電池素子 - Google Patents

ペースト組成物と太陽電池素子 Download PDF

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Publication number
WO2008152854A1
WO2008152854A1 PCT/JP2008/056851 JP2008056851W WO2008152854A1 WO 2008152854 A1 WO2008152854 A1 WO 2008152854A1 JP 2008056851 W JP2008056851 W JP 2008056851W WO 2008152854 A1 WO2008152854 A1 WO 2008152854A1
Authority
WO
WIPO (PCT)
Prior art keywords
paste composition
semiconductor substrate
silicon semiconductor
solar cell
cell element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/056851
Other languages
English (en)
French (fr)
Inventor
Gaochao Lai
Yutaka Ochi
Yoshiteru Miyazawa
Takashi Watsuji
Haruzo Katoh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Aluminum KK
Original Assignee
Toyo Aluminum KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Aluminum KK filed Critical Toyo Aluminum KK
Priority to US12/602,678 priority Critical patent/US20100180948A1/en
Priority to ES08739954T priority patent/ES2426261T3/es
Priority to EP08739954.9A priority patent/EP2157618B1/en
Priority to CN200880019372A priority patent/CN101681942A/zh
Publication of WO2008152854A1 publication Critical patent/WO2008152854A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F10/00Individual photovoltaic cells, e.g. solar cells
    • H10F10/10Individual photovoltaic cells, e.g. solar cells having potential barriers
    • H10F10/14Photovoltaic cells having only PN homojunction potential barriers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C14/00Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
    • C03C14/006Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of microcrystallites, e.g. of optically or electrically active material
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/10Frit compositions, i.e. in a powdered or comminuted form containing lead
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/18Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20Conductive material dispersed in non-conductive organic material
    • H01B1/22Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F10/00Individual photovoltaic cells, e.g. solar cells
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/20Electrodes
    • H10F77/206Electrodes for devices having potential barriers
    • H10F77/211Electrodes for devices having potential barriers for photovoltaic cells
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2214/00Nature of the non-vitreous component
    • C03C2214/08Metals
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2214/00Nature of the non-vitreous component
    • C03C2214/16Microcrystallites, e.g. of optically or electrically active material
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/30Coatings
    • H10F77/306Coatings for devices having potential barriers
    • H10F77/311Coatings for devices having potential barriers for photovoltaic cells
    • H10F77/315Coatings for devices having potential barriers for photovoltaic cells the coatings being antireflective or having enhancing optical properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Photovoltaic Devices (AREA)
  • Conductive Materials (AREA)

Abstract

 厚いシリコン半導体基板に厚い裏面電極層を形成する場合または薄いシリコン半導体基板に薄い裏面電極層を形成する場合のいずれに用いても少なくとも従来と同等以上のBSF効果を十分に達成することができ、薄いシリコン半導体基板に薄い裏面電極層を形成するために用いた場合には従来と同等以上のBSF効果を達成するとともに焼成後のシリコン半導体基板の変形を抑制することが可能なペースト組成物と、それを用いて形成された電極を備えた太陽電池素子を提供する。ペースト組成物は、導電性粉末としてアルミニウム粉末を含むペースト組成物であって、不可避的不純物元素として含まれる鉄とチタンの合計含有量が0.07質量%以下である。太陽電池素子は、上記のペースト組成物をシリコン半導体基板(1)の裏面上に塗布した後、焼成することにより形成した裏面電極(8)を備える。
PCT/JP2008/056851 2007-06-08 2008-04-07 ペースト組成物と太陽電池素子 Ceased WO2008152854A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/602,678 US20100180948A1 (en) 2007-06-08 2008-04-07 Paste composition and solar cell element
ES08739954T ES2426261T3 (es) 2007-06-08 2008-04-07 Composición de pasta y elemento de célula solar
EP08739954.9A EP2157618B1 (en) 2007-06-08 2008-04-07 Paste composition and solar cell element
CN200880019372A CN101681942A (zh) 2007-06-08 2008-04-07 糊组合物及太阳能电池元件

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007152469A JP2008306023A (ja) 2007-06-08 2007-06-08 ペースト組成物と太陽電池素子
JP2007-152469 2007-06-08

Publications (1)

Publication Number Publication Date
WO2008152854A1 true WO2008152854A1 (ja) 2008-12-18

Family

ID=40129467

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/056851 Ceased WO2008152854A1 (ja) 2007-06-08 2008-04-07 ペースト組成物と太陽電池素子

Country Status (8)

Country Link
US (1) US20100180948A1 (ja)
EP (1) EP2157618B1 (ja)
JP (1) JP2008306023A (ja)
KR (1) KR20100021616A (ja)
CN (1) CN101681942A (ja)
ES (1) ES2426261T3 (ja)
TW (1) TWI446552B (ja)
WO (1) WO2008152854A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102292820A (zh) * 2009-01-23 2011-12-21 东洋铝株式会社 糊组合物及使用该糊组合物的太阳能电池元件

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010146973A1 (ja) * 2009-06-15 2010-12-23 東洋アルミニウム株式会社 アルミニウム電解コンデンサ用電極材及びその製造方法
JP5815215B2 (ja) * 2009-08-27 2015-11-17 東京応化工業株式会社 拡散剤組成物、および不純物拡散層の形成方法
FR2967811B1 (fr) * 2010-11-24 2014-01-17 Commissariat Energie Atomique Procede de formation d'une couche fibreuse
US9680036B2 (en) * 2011-01-06 2017-06-13 Heraeus Precious Metals North America Conshohocken Llc Organometallic and hydrocarbon additives for use with aluminum back solar cell contacts
US20130160834A1 (en) * 2011-12-27 2013-06-27 E.I. Du Pont De Nemours And Company Back-side electrode of p-type solar cell, and method for forming the same
JP5858025B2 (ja) * 2013-10-30 2016-02-10 信越化学工業株式会社 太陽電池の製造方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0624834A (ja) * 1992-07-01 1994-02-01 Sumitomo Chem Co Ltd ベータアルミナ焼結体製造用組成物
JP2006278071A (ja) * 2005-03-29 2006-10-12 Toyo Aluminium Kk ペースト組成物、電極およびそれを備えた太陽電池素子

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6083426A (en) * 1998-06-12 2000-07-04 Matsushita Electric Industrial Co., Ltd. Conductive paste
JP2001202822A (ja) * 2000-01-21 2001-07-27 Murata Mfg Co Ltd 導電性ペースト
US20030178057A1 (en) * 2001-10-24 2003-09-25 Shuichi Fujii Solar cell, manufacturing method thereof and electrode material
JP3910072B2 (ja) * 2002-01-30 2007-04-25 東洋アルミニウム株式会社 ペースト組成物およびそれを用いた太陽電池
US20040055635A1 (en) * 2002-09-19 2004-03-25 Hiroshi Nagakubo Conductive paste, method for manufacturing solar battery, and solar battery
EP1739690B1 (en) * 2004-07-01 2015-04-01 Toyo Aluminium Kabushiki Kaisha Paste composition and solar cell element employing same
JP2007019069A (ja) * 2005-07-05 2007-01-25 Toyo Aluminium Kk ペースト組成物およびそれを用いた太陽電池素子
JP4843291B2 (ja) * 2005-10-18 2011-12-21 東洋アルミニウム株式会社 アルミニウムペースト組成物およびそれを用いた太陽電池素子
KR101031060B1 (ko) * 2005-10-20 2011-04-25 도요 알루미늄 가부시키가이샤 페이스트 조성물 및 그것을 이용한 태양 전지 소자
CN100446277C (zh) * 2006-06-30 2008-12-24 谭富彬 硅太阳能电池背场铝导电浆料组成及制备方法
JP2009129600A (ja) * 2007-11-21 2009-06-11 Toyo Aluminium Kk ペースト組成物と太陽電池素子

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0624834A (ja) * 1992-07-01 1994-02-01 Sumitomo Chem Co Ltd ベータアルミナ焼結体製造用組成物
JP2006278071A (ja) * 2005-03-29 2006-10-12 Toyo Aluminium Kk ペースト組成物、電極およびそれを備えた太陽電池素子

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2157618A4 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102292820A (zh) * 2009-01-23 2011-12-21 东洋铝株式会社 糊组合物及使用该糊组合物的太阳能电池元件

Also Published As

Publication number Publication date
TW200901487A (en) 2009-01-01
US20100180948A1 (en) 2010-07-22
EP2157618B1 (en) 2013-07-24
EP2157618A4 (en) 2011-09-21
EP2157618A1 (en) 2010-02-24
CN101681942A (zh) 2010-03-24
TWI446552B (zh) 2014-07-21
KR20100021616A (ko) 2010-02-25
JP2008306023A (ja) 2008-12-18
ES2426261T3 (es) 2013-10-22

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