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WO2008143325A1 - 繊維用集束剤 - Google Patents

繊維用集束剤 Download PDF

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Publication number
WO2008143325A1
WO2008143325A1 PCT/JP2008/059478 JP2008059478W WO2008143325A1 WO 2008143325 A1 WO2008143325 A1 WO 2008143325A1 JP 2008059478 W JP2008059478 W JP 2008059478W WO 2008143325 A1 WO2008143325 A1 WO 2008143325A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyester resin
weight
sizing agent
diol
fiber sizing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/059478
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English (en)
French (fr)
Inventor
Masahito Inoue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Chemical Industries Ltd
Original Assignee
Sanyo Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Chemical Industries Ltd filed Critical Sanyo Chemical Industries Ltd
Priority to US12/601,001 priority Critical patent/US20100159243A1/en
Priority to CN200880016469A priority patent/CN101755089A/zh
Priority to EP08764539.6A priority patent/EP2149637B1/en
Publication of WO2008143325A1 publication Critical patent/WO2008143325A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/285—Acrylic resins
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/323—Polyesters, e.g. alkyd resins
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/326—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/36—Epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/248—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using pre-treated fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/50—Aqueous dispersion, e.g. containing polymers with a glass transition temperature (Tg) above 20°C
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2938—Coating on discrete and individual rods, strands or filaments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

　マトリックス樹脂との接着性を保持したままで、乳化安定性及び集束性が改善されたポリエステル樹脂含有繊維用集束剤を提供する。当該繊維用集束剤は、下記（ｉ）～（ｉｖ）の全てを満たすポリエステル樹脂（Ａ）及び水性媒体を含有してなる水性溶液状若しくは水性エマルジョン状の繊維用集束剤である。（ｉ）ポリエステル樹脂（Ａ）がジカルボン酸若しくはその無水物（ａ）及びジオール（ｂ）から製造される。（ｉｉ）前記ジオール（ｂ）のうちの少なくとも１種が、平均４．５～６０個の連続したオキシエチレン基を有するジオール（ｂ１）である。（ｉｉｉ）ポリエステル樹脂（Ａ）中における前記平均４．５～６０個の連続したオキシエチレン基の重量割合が２５～５０重量％である。（ｉｖ）ポリエステル樹脂（Ａ）１０重量部及び水９０重量部の混合物が、２５°Cで均一透明溶液若しくは均一エマルジョンを形成する。
PCT/JP2008/059478 2007-05-22 2008-05-22 繊維用集束剤 Ceased WO2008143325A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/601,001 US20100159243A1 (en) 2007-05-22 2008-05-22 Sizing agent for fibers
CN200880016469A CN101755089A (zh) 2007-05-22 2008-05-22 纤维用集束剂
EP08764539.6A EP2149637B1 (en) 2007-05-22 2008-05-22 Fiber sizing agent

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007135858 2007-05-22
JP2007-135858 2007-05-22
JP2008089479A JP4887323B2 (ja) 2007-05-22 2008-03-31 繊維用集束剤
JP2008-089479 2008-03-31

Publications (1)

Publication Number Publication Date
WO2008143325A1 true WO2008143325A1 (ja) 2008-11-27

Family

ID=40032018

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/059478 Ceased WO2008143325A1 (ja) 2007-05-22 2008-05-22 繊維用集束剤

Country Status (5)

Country Link
US (1) US20100159243A1 (ja)
EP (1) EP2149637B1 (ja)
JP (1) JP4887323B2 (ja)
CN (1) CN101755089A (ja)
WO (1) WO2008143325A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016043043A1 (ja) * 2014-09-19 2016-03-24 三洋化成工業株式会社 繊維用集束剤組成物、繊維用集束剤分散体、繊維用集束剤溶液、繊維束の製造方法、複合中間体及び繊維強化複合材料
CN106283639A (zh) * 2016-08-08 2017-01-04 苏州莱奥生物技术有限公司 一种环保型集束剂
JP2018131511A (ja) * 2017-02-14 2018-08-23 帝人株式会社 樹脂組成物
CN110937825A (zh) * 2019-12-24 2020-03-31 陕西华特新材料股份有限公司 用于高硅氧玻璃纤维的无蜡型浸润剂及其制备方法
CN112679717A (zh) * 2020-12-04 2021-04-20 吉林乾仁新材料有限公司 一种多用途自乳化阴离子型不饱和聚酯碳纤维上浆剂的制备方法及其产品和应用
JP7385327B1 (ja) 2023-06-09 2023-11-22 竹本油脂株式会社 強化繊維用サイジング剤および強化繊維
WO2025094726A1 (ja) * 2023-10-30 2025-05-08 松本油脂製薬株式会社 繊維用集束剤及びその用途

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WO2012080385A1 (en) * 2010-12-16 2012-06-21 Dsm Ip Assets B.V. Oil in water emulsion
TW201323681A (zh) * 2011-09-22 2013-06-16 Sanyo Chemical Ind Ltd 纖維用上漿劑組成物、纖維用上漿劑水性液、纖維束的製造方法、纖維束、複合中間物及纖維強化複合材料
CN103890261B (zh) 2011-10-21 2016-08-24 松本油脂制药株式会社 碳纤维用上浆剂、碳纤维丝束及纤维强化复合材料
RU2014131002A (ru) * 2011-12-27 2016-02-20 Торэй Индастриз, Инк. Углеродные волокна, покрытые проклеивающим веществом, способ получения углеродных волокон, покрытых проклеивающим веществом, препрег и композитный материал, армированный углеродными волокнами
US9765194B2 (en) * 2012-07-25 2017-09-19 Toray Industries, Inc. Prepreg and carbon fiber-reinforced composite material
CN104704151B (zh) 2012-08-15 2016-11-09 3M创新有限公司 上胶的短氧化铝基无机氧化物纤维、制备该纤维的方法和包括该纤维的组合物
WO2014061336A1 (ja) * 2012-10-18 2014-04-24 東レ株式会社 炭素繊維強化樹脂組成物、炭素繊維強化樹脂組成物の製造方法、成形材料、成形材料の製造方法および炭素繊維強化樹脂成形品
JP6154127B2 (ja) * 2012-12-20 2017-06-28 帝人株式会社 補強用炭素繊維束の製造方法およびそれを用いた炭素繊維複合材料の製造方法
CN103114434B (zh) * 2013-03-04 2015-04-08 北京师范大学 纳米Fe3O4-V2O5-Au掺杂聚萘胺膜修饰活性炭纤维电极的制备工艺
JP6456048B2 (ja) * 2013-06-13 2019-01-23 旭化成株式会社 ガラス繊維強化ポリアミド樹脂組成物及び成形体
JP6116503B2 (ja) * 2014-03-03 2017-04-19 松本油脂製薬株式会社 炭素繊維用サイジング剤及びその用途
JP5553464B1 (ja) * 2014-03-27 2014-07-16 竹本油脂株式会社 炭素繊維用サイジング剤及び炭素繊維ストランド
JP6478093B2 (ja) * 2014-10-09 2019-03-06 Dic株式会社 繊維集束剤
US20170342654A1 (en) * 2015-01-19 2017-11-30 Teijin Limited Fiber material for cement reinforcement
JP6524882B2 (ja) * 2015-10-16 2019-06-05 日本電気硝子株式会社 ガラスストランド、ガラスロービング及びその製造方法
CN105271830B (zh) * 2015-10-20 2018-08-21 江门市新会区美亚化工有限公司 一种纳米改性的玄武岩连续纤维专用浸润剂及其制备方法
JP2017110064A (ja) * 2015-12-15 2017-06-22 三菱エンジニアリングプラスチックス株式会社 樹脂被覆金属長繊維ペレットの製造方法及び成形品の製造方法
JP6626875B2 (ja) * 2016-12-19 2019-12-25 三洋化成工業株式会社 繊維用集束剤組成物
CN108484891B (zh) * 2018-03-12 2020-05-08 吉林乾仁新材料有限公司 自组装自乳化自稳定聚酯型高性能纤维界面改性助剂的制备及产品和应用
JP7325976B2 (ja) * 2018-03-20 2023-08-15 三洋化成工業株式会社 繊維用集束剤組成物、繊維束及び繊維製品
US12241200B2 (en) * 2018-08-02 2025-03-04 Sanyo Chemical Industries, Ltd. Sizing agent composition for fibers, fiber bundle, fiber product and composite material
JP7389668B2 (ja) * 2019-02-20 2023-11-30 三洋化成工業株式会社 繊維用集束剤
CN110512427A (zh) * 2019-09-17 2019-11-29 广东石油化工学院 一种纤维集束剂
CN113278321B (zh) * 2020-02-19 2022-02-11 湖南惠同新材料股份有限公司 一种不锈钢纤维防静电地坪漆涂层及其制备方法
JP7248763B2 (ja) * 2021-04-27 2023-03-29 三洋化成工業株式会社 繊維用集束剤組成物、繊維用集束剤溶液、繊維束、繊維製品及び複合材料
CN115140953A (zh) * 2022-07-08 2022-10-04 海南电网有限责任公司电力科学研究院 一种以双酚a型环氧树脂乳液为成膜剂的玄武岩纤维浸润剂及其制备方法

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JPWO2025094726A1 (ja) * 2023-10-30 2025-05-08

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EP2149637A4 (en) 2014-03-26
EP2149637B1 (en) 2016-11-23
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