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WO2008016330A2 - Bioformule pour remplacer le carburant diesel - Google Patents

Bioformule pour remplacer le carburant diesel Download PDF

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Publication number
WO2008016330A2
WO2008016330A2 PCT/SG2007/000224 SG2007000224W WO2008016330A2 WO 2008016330 A2 WO2008016330 A2 WO 2008016330A2 SG 2007000224 W SG2007000224 W SG 2007000224W WO 2008016330 A2 WO2008016330 A2 WO 2008016330A2
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WO
WIPO (PCT)
Prior art keywords
reactor
temperature
tank
proceeded
result
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SG2007/000224
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English (en)
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WO2008016330A3 (fr
Inventor
B. F. Prawoto
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2008016330A2 publication Critical patent/WO2008016330A2/fr
Anticipated expiration legal-status Critical
Publication of WO2008016330A3 publication Critical patent/WO2008016330A3/fr
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • bio formula 100 a production process of biofuel further-on called as "bio formula 100", as an alternative material to substitute Diesel Fuel originated from vegetables in the form of palm coconut oil waste.
  • Biofosil subsidy which is being accounted for to the selling Biofosil price, resulted in the high Biofosil price hike, so as to deeply affect almost all public levels, especially the lower level community.
  • Biofosil is one of natural sources that can not be renewed, it is deemed necessary and important to put into consideration to have an alternative as its substitution.
  • Biofosil substitutions such as bricks, coals taken from plantation waste, biogas and others.
  • Biofosii from different raw materials, produced through chemical reaction process, distillation residue, thermal cracking, fractionalization and other processes which have been done to meet the need of alternative fuel.
  • many of them is of high cost, in the supply of raw materials, its additive, supporting materials, its catalyst, instrument, location and so on.
  • most of them have to go through difficult process stages, especially to keep continued process, even though it can be simplified, the result of quality and quantity are not at the maximum, that is, far from adequately anticipated.
  • bio formula 100 an alternative material of biofuel originated from vegetables which is of palm coconut waste.
  • the object of the current invention primarily in regard to the production process of bio formula 100, as an alternative materia! of diesel fuel, essentially covers some stages.
  • R1 Reactor Reactor FFA Treatment Unit
  • R1 Reactor Reactor FFA Treatment Unit
  • the result is proceeded into D1 distillation column to be distilled the top/vapour fraction, in the form of methanol, through the condenser at temperature 20 * C, in liquid condition proceeded to TB1.
  • the bottom/liquid fraction in the form of liquid (water + glycerol + methanol + salt) through the reboiler at temperature 100° C, in liquid condition and proceeded to TB5.
  • R2A and R2B is removed through the bottom part reactor, proceeded into PR2 (Pre Reactor Reserved), further-on it is proceeded into D2 distillation column, the top/vapour fraction D2, in the form of methanol through the condenser at temperature 20 ° C, in liquid condition, proceeded to D1 for continued process in D1 so that D1 input becomes two, that is D2 and E1, and further-on distilled the same way as the initiai D1 stage the bottom/liquid fraction, which is the mixture of Bio Diesel and Glycerine through the reboiier at temperature 100° C, in liquid condition, being recovered/withdrawn through D3 distillation column, reserved in the Reserve Tank Glycerol TB2.
  • PR2 Pre Reactor Reserved
  • the top/vapour fraction in the form of Glycerine through the condenser at temperature 20 * C, in liquid condition, and is proceeded into TB2 the bottom/liquid fraction in the form of (methyl ester/biodiesel) through reboiler at temperature 150'C 1 in liquid condition, is proceeded to R4 Reactor
  • the methyl ester/biodiesel is being neutralized from pH 10 to become pH (5,5 - 6,5) by adding sulphuric acid with 12 Molar concentration, one-hundredth methyl ester volume, from TB3 tank (the sulphuric acid bait tank) and one-fifth methyl ester volume from the TB4 water reserved tank, being processed as the second catalyst, then evaporated in E2, the result of evaporation, top fraction in the form of water + soap + salt are kept in TB5 Dirty Water Reserve Tank, and the bottom fraction which is the Biodiesel 100 (further-
  • the B-100 Biofuel product having physico and chemical characteristics as follows:
  • Figure 1 is a stream diagram of B-100 formula production process as the diesel fuel substitution which is in line with the current invention.
  • the current invention is mainly in regard to the production process of bio formula 100, functioning as the alternative substitution of diesel fuel, essentially covering the following stages:
  • R1 Reactor FFA Treatment Unit Reactor
  • FFA Treatment Unit Reactor being the mixing tank reactor
  • temperature (60 - 70) 'C? the kind ⁇ ype of continued reactor in operation condition
  • temperature (60 - 70) 'C? the kind ⁇ ype of continued reactor in operation condition
  • temperature (60 - 70) 'C? the kind ⁇ ype of continued reactor in operation condition
  • temperature (60 - 70) 'C? the kind ⁇ ype of continued reactor in operation condition
  • temperature (60 - 70) 'C? atmospheric pressure
  • the fractions (bottom) of the distillation result being the methyl ester, having a temperature of 70 * C.
  • the top/vapor fraction, methanol, through the condenser at temperature 20 * C, in liquid condition is proceeded to TB1.
  • the bottom/liquid fraction which is a mixture of (water + glycerol + soap) through the reboiler at temperature 70° C, in liquid form and proceeded to TB5.
  • WVO is proceeded (being the bait in the form of oil waste of fruits/palm coconut) which has been evaporated in E1 evaporator and retained in PR1 (Pre Reactor Reserved) for 30 minutes, meant for homogeneity, mixed and put into R2A and R2B reactors (which is the main reactor being the mixing tank for continued process/ the CSTR Main Reactor through M1 together with the mixture result of R3 i.e. NaMethanol. This is done in order to obtain Methyl Ester result.
  • D2 distillation column having column packing specification, in operation condition (temperature 65 * C, pressure - (20 - 60) mmHg, condenser/reboiler on the distillation container is in the form of Shell and Tube and the reboiler is the Reboiler Kettle, the top/vapour fraction, in the form of methanol through the condenser at temperature 20 'C, in liquid condition proceeded into D1 for continued process in D1 so that D1 input becomes two i.e.
  • top/vapour fraction in the form of Glycerol through condenser at temperature 20 * C, in liquid condition, proceeded to TB2
  • bottom/liquid fraction in the form of (methyl ester/biodiesel) through the reboiler at temperature 65 * C, in liquid condition proceeded to R4 reactor.
  • Biodiesel B-100 the substitution of diesel fuel reserved in the Biodiesel B-100 Product Tank.
  • Biodiesel B-100 product has a physico and chemical characteristics as the following: Physico state is in the form of yellow-brownish liquid The chemical characteristics of 6 maximum acid number The above-mentioned characteristics have fully met the criteria as alternative material for diesel fuel substitution.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un procédé de production de bioformule 100 en tant que matière alternative pour remplacer le carburant diesel, qui comprend essentiellement les étapes de distillation suivantes : - raffinage de déchets d'huile provenant de noix de coco de palmier par distillation, - on fait passer le produit final dans un réacteur R1 tout en ajoutant du méthanol et de l'acide sulfurique, - le produit résultant est placé dans un évaporateur E1, - on fait ensuite passer le produit résultant dans une colonne de distillation D1 pour être distillé, - le produit résultant de la distillation de méthanol est retenu dans un réservoir de repos TB1 et on le fait passer dans un réservoir R3, en même temps qu'on ajoute NaOH/KOH, - pour faire ensuite WVO s'écouler dans les (déchets d'huile de fruits/noix de coco de palmier) qui ont été évaporés dans E1 et retenus dans PR1 (Pré-réacteur de Retenue), mélangés et placés dans le R2A et R2B (Réacteur Principal CSTR) par M1 conjointement avec le produit résultant de mélange de R3, - le produit résultant de R2A et P2B est ensuite amené dans PR2 (Pré-Réacteur de Retenue), - et est ensuite amené dans une colonne de distillation D2 pour poursuivre le procédé dans D1 de telle sorte que l'entrée de D1 devient le double, à savoir D2 et E1, et par la suite le produit est distillé comme dans le stade initial D1, - la fraction de pied/liquide, sous la forme de (glycérol + savon + ester méthylique) à travers le rebouilleur, à l'état liquide, est récupérée/soutirée par une colonne de distillation D3, retenue dans un réservoir de retenue de glycérol TB2, - dans la colonne de distillation D3, la fraction de tête/vapeur, sous la forme de méthanol, à travers le condenseur, à l'état liquide, est amenée à TB2, l'ester méthylique/biodiesel est amené dans le réacteur R4, - dans le réacteur de neutralisation R4 l'ester méthylique/biodiesel est neutralisé par ajout d'acide sulfurique provenant du réservoir TB3 (le réservoir de repos d'acide sulfurique) et d'eau provenant du réservoir de retenue d'eau TB4, traitée en tant que second catalyseur, qui est ensuite évaporée dans E2, - le produit résultant de l'évaporation, la fraction de tête consistant en eau + savon + sel est retenue dans un Réservoir de Retenue d'Eau Sale TB5, et la fraction de pied sous la forme de biodiesel 100 (ci-après appelée Biodiesel B-100 qui est le produit de remplacement du carburant diesel) est retenue dans le Réservoir de Produit Biodiesel B-100.
PCT/SG2007/000224 2006-08-01 2007-07-30 Bioformule pour remplacer le carburant diesel Ceased WO2008016330A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
INP00200600449 2006-08-01
ID20060449 2006-08-01

Publications (2)

Publication Number Publication Date
WO2008016330A2 true WO2008016330A2 (fr) 2008-02-07
WO2008016330A3 WO2008016330A3 (fr) 2009-06-11

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SG2007/000224 Ceased WO2008016330A2 (fr) 2006-08-01 2007-07-30 Bioformule pour remplacer le carburant diesel

Country Status (2)

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US (1) US20080047194A1 (fr)
WO (1) WO2008016330A2 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2742793C (fr) * 2008-11-26 2016-05-10 Elevance Renewable Sciences, Inc. Procedes de fabrication de carbureacteur a partir de matieres premieres huiles naturelles par des reactions de clivage par l'oxygene
BRPI0921222A2 (pt) * 2008-11-26 2018-10-23 Elevance Renewable Sciences processos de produção de combustível de jato a partir de estoques de alimentação de óleo natural atrave´s de reações de metatese.
US9382502B2 (en) 2009-10-12 2016-07-05 Elevance Renewable Sciences, Inc. Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks
CN104479882A (zh) 2009-10-12 2015-04-01 艾勒旺斯可再生科学公司 从天然油原料中提炼燃料的方法
US8735640B2 (en) 2009-10-12 2014-05-27 Elevance Renewable Sciences, Inc. Methods of refining and producing fuel and specialty chemicals from natural oil feedstocks
US9175231B2 (en) 2009-10-12 2015-11-03 Elevance Renewable Sciences, Inc. Methods of refining natural oils and methods of producing fuel compositions
US9000246B2 (en) 2009-10-12 2015-04-07 Elevance Renewable Sciences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
US9365487B2 (en) 2009-10-12 2016-06-14 Elevance Renewable Sciences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
US9222056B2 (en) 2009-10-12 2015-12-29 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US9051519B2 (en) 2009-10-12 2015-06-09 Elevance Renewable Sciences, Inc. Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters
US9169447B2 (en) 2009-10-12 2015-10-27 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US9139493B2 (en) 2011-12-22 2015-09-22 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9169174B2 (en) 2011-12-22 2015-10-27 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9133416B2 (en) 2011-12-22 2015-09-15 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9388098B2 (en) 2012-10-09 2016-07-12 Elevance Renewable Sciences, Inc. Methods of making high-weight esters, acids, and derivatives thereof

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DE3444893A1 (de) * 1984-12-08 1986-06-12 Henkel KGaA, 4000 Düsseldorf Verfahren zur herstellung von fettsaeuremethylestern
FR2696185B1 (fr) * 1992-09-25 1994-12-02 Inst Francais Du Petrole Procédé amélioré de fabrication d'esters à partir de corps gras d'origine naturelle.
US5525136A (en) * 1994-09-06 1996-06-11 Rosen; Richard M. Gasketed multi-media air cleaner
US6965044B1 (en) * 2001-07-06 2005-11-15 Iowa State University Research Foundation Method of converting free fatty acids to fatty acid methyl esters with small excess of methanol
US20040074760A1 (en) * 2002-10-17 2004-04-22 Carnegie Mellon University Production of biofuels
MY150129A (en) * 2004-04-09 2013-11-29 Archer Daniels Midland Co Method of preparing fatty acid alkyl esters from waste or recycled fatty acid stock
JP2005350632A (ja) * 2004-06-14 2005-12-22 Electric Power Dev Co Ltd バイオディーゼル燃料の製造方法
SG139562A1 (en) * 2006-07-11 2008-02-29 W J E Invest Ltd Biofuel(s)

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Publication number Publication date
US20080047194A1 (en) 2008-02-28
WO2008016330A3 (fr) 2009-06-11

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