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WO2008093775A1 - 反応性モノマー分散シリカゾル、その製造方法、硬化用組成物及びその硬化体 - Google Patents

反応性モノマー分散シリカゾル、その製造方法、硬化用組成物及びその硬化体 Download PDF

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Publication number
WO2008093775A1
WO2008093775A1 PCT/JP2008/051518 JP2008051518W WO2008093775A1 WO 2008093775 A1 WO2008093775 A1 WO 2008093775A1 JP 2008051518 W JP2008051518 W JP 2008051518W WO 2008093775 A1 WO2008093775 A1 WO 2008093775A1
Authority
WO
WIPO (PCT)
Prior art keywords
silica sol
monomer
reactive
dispersed
curing composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/051518
Other languages
English (en)
French (fr)
Inventor
Naohiko Suemura
Keiko Yoshitake
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Chemical Corp
Original Assignee
Nissan Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Corp filed Critical Nissan Chemical Corp
Priority to KR1020097017406A priority Critical patent/KR101429318B1/ko
Priority to US12/449,328 priority patent/US7999026B2/en
Priority to EP08704265A priority patent/EP2119731A4/en
Priority to CN2008800033934A priority patent/CN101600738B/zh
Priority to JP2008556172A priority patent/JP5376124B2/ja
Publication of WO2008093775A1 publication Critical patent/WO2008093775A1/ja
Anticipated expiration legal-status Critical
Priority to US13/064,293 priority patent/US20110172331A1/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0004—Preparation of sols
    • B01J13/0008—Sols of inorganic materials in water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0004—Preparation of sols
    • B01J13/0026—Preparation of sols containing a liquid organic phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0004—Preparation of sols
    • B01J13/0047—Preparation of sols containing a metal oxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/146—After-treatment of sols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/621—Phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/02—Ingredients treated with inorganic substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicon Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

【課題】 　応性モノマーに分散されたコロイダルシリカ粒子は、その粒子表面の固体酸性の作用により、反応性モノマーの重合や分解等を引き起こし、モノマー分散シリカゾルの製造工程中にモノマーが重合を起こす場合や、安定なシリカゾルが得られない場合がある。また、モノマー分散シリカゾルを硬化させて得た樹脂成形体等のポリマーが、経時的に変質や分解等を引き起こす。よって、反応性モノマー分散シリカゾルに含まれるコロイダルシリカ粒子表面のもつ固体酸性を抑制することにより、安定性の高い反応性モノマー分散シリカゾルとその製造方法、反応性モノマー分散シリカゾルを用いた硬化用組成物及びポリマーの変質や分解等が抑制された硬化体を提供する。 【解決手段】 　アルカリ土類金属イオンが表面に結合したコロイダルシリカ粒子を含む反応性モノマー分散シリカゾルによる。
PCT/JP2008/051518 2007-02-02 2008-01-31 反応性モノマー分散シリカゾル、その製造方法、硬化用組成物及びその硬化体 Ceased WO2008093775A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020097017406A KR101429318B1 (ko) 2007-02-02 2008-01-31 반응성 모노머 분산 실리카 졸, 이의 제조방법, 경화용 조성물 및 이의 경화체
US12/449,328 US7999026B2 (en) 2007-02-02 2008-01-31 Reactive monomer-dispersed silica sol and production method thereof, and curable composition and cured article thereof
EP08704265A EP2119731A4 (en) 2007-02-02 2008-01-31 SILICONE WITH A DISINTERATED REACTIVE MONOMER, METHOD FOR THE PRODUCTION OF THE SILICONE, HARDENING COMPOSITION AND CURED PRODUCTS PRODUCED FROM THE HARDENING COMPOSITION
CN2008800033934A CN101600738B (zh) 2007-02-02 2008-01-31 反应性单体分散硅溶胶、其制备方法、固化用组合物及其固化体
JP2008556172A JP5376124B2 (ja) 2007-02-02 2008-01-31 反応性モノマー分散シリカゾル、その製造方法、硬化用組成物及びその硬化体
US13/064,293 US20110172331A1 (en) 2007-02-02 2011-03-16 Reactive monomer-dispersed silica sol and production method thereof, and curable composition and cured article thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-023740 2007-02-02
JP2007023740 2007-02-02

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/064,293 Continuation US20110172331A1 (en) 2007-02-02 2011-03-16 Reactive monomer-dispersed silica sol and production method thereof, and curable composition and cured article thereof

Publications (1)

Publication Number Publication Date
WO2008093775A1 true WO2008093775A1 (ja) 2008-08-07

Family

ID=39674081

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/051518 Ceased WO2008093775A1 (ja) 2007-02-02 2008-01-31 反応性モノマー分散シリカゾル、その製造方法、硬化用組成物及びその硬化体

Country Status (7)

Country Link
US (2) US7999026B2 (ja)
EP (1) EP2119731A4 (ja)
JP (1) JP5376124B2 (ja)
KR (1) KR101429318B1 (ja)
CN (1) CN101600738B (ja)
TW (1) TWI464116B (ja)
WO (1) WO2008093775A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010254548A (ja) * 2009-03-31 2010-11-11 Admatechs Co Ltd コロイダルシリカ及びその製造方法
US20110281974A1 (en) * 2008-11-18 2011-11-17 Nissan Chemical Industries, Ltd. Process for producing composition of polymerizable organic compound containing silica particles
JP2013155245A (ja) * 2012-01-27 2013-08-15 Tamura Seisakusho Co Ltd 紫外線硬化性透明樹脂組成物

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2832690A1 (de) * 2013-08-02 2015-02-04 EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt Verfahren zur Herstellung eines Aerogelmaterials
US10160884B2 (en) 2015-03-23 2018-12-25 Versum Materials Us, Llc Metal compound chemically anchored colloidal particles and methods of production and use thereof
EP3480828A4 (en) * 2016-07-01 2020-03-04 Nissan Chemical Corporation METHOD FOR PREVENTING THE ARRANGEMENT OF A RAMPANT ELECTRIC SHOCK
CN108854871B (zh) * 2017-05-11 2021-06-25 中国科学院化学研究所 一种环状胶体及其制备方法
CN113247910A (zh) * 2021-06-02 2021-08-13 厦门宜宏盛硅胶制品有限公司 一种耐水耐老化型硅胶按键及制备工艺
KR102871087B1 (ko) * 2023-11-29 2025-10-14 닛산 가가쿠 가부시키가이샤 유기산을 포함하는 질소 함유 유기 용매에 분산된 실리카졸 및 절연성 수지 조성물

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57196717A (en) 1981-05-25 1982-12-02 Shokubai Kasei Kogyo Kk Powdered silica dispersible homogeneously in organic solvent and its manufacture
JPS58145614A (ja) 1982-02-23 1983-08-30 Shokubai Kasei Kogyo Kk 有機溶剤に均質に分散可能な粉末状シリカとその製造法
JPS6295130A (ja) * 1985-10-18 1987-05-01 Sumitomo Chem Co Ltd 反応性モノマ−を分散媒とする酸化物ゾル
JPH01317115A (ja) * 1988-03-16 1989-12-21 Nissan Chem Ind Ltd 細長い形状のシリカゾル及びその製造法
JPH03187913A (ja) 1989-12-15 1991-08-15 Shin Etsu Chem Co Ltd シリカ粉末の製造方法
JPH1143319A (ja) 1997-05-26 1999-02-16 Nissan Chem Ind Ltd 疎水性オルガノシリカゾルの製造方法
WO2000015552A1 (en) * 1998-09-10 2000-03-23 Nissan Chemical Industries, Ltd. Moniliform silica sol, process for producing the same, and ink-jet recording medium
WO2006035709A1 (ja) * 2004-09-27 2006-04-06 Nippon Kayaku Kabushiki Kaisha エポキシ樹脂組成物および物品
JP2007063117A (ja) * 2005-08-02 2007-03-15 Nissan Chem Ind Ltd 有機溶媒分散シリカゾル及びその製造方法

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US3328339A (en) * 1963-08-28 1967-06-27 Monsanto Co Reinforced plastics containing base treated, calcined particulate fillers and organosilane coupling agents
NO300125B1 (no) * 1988-03-16 1997-04-14 Nissan Chemical Ind Ltd Stabil væskeformig silikasol, samt fremgangsmåte ved fremstilling derav
US5221497A (en) 1988-03-16 1993-06-22 Nissan Chemical Industries, Ltd. Elongated-shaped silica sol and method for preparing the same
JPH0735407A (ja) * 1993-07-22 1995-02-07 Janome Sewing Mach Co Ltd 浴湯の保温清浄化装置
JP4228578B2 (ja) 2002-02-14 2009-02-25 Ｄｉｃ株式会社 液晶表示素子用原材料の精製方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57196717A (en) 1981-05-25 1982-12-02 Shokubai Kasei Kogyo Kk Powdered silica dispersible homogeneously in organic solvent and its manufacture
JPS58145614A (ja) 1982-02-23 1983-08-30 Shokubai Kasei Kogyo Kk 有機溶剤に均質に分散可能な粉末状シリカとその製造法
JPS6295130A (ja) * 1985-10-18 1987-05-01 Sumitomo Chem Co Ltd 反応性モノマ−を分散媒とする酸化物ゾル
JPH0735407B2 (ja) 1985-10-18 1995-04-19 住友化学工業株式会社 反応性モノマ−を分散媒とする酸化物ゾル
JPH01317115A (ja) * 1988-03-16 1989-12-21 Nissan Chem Ind Ltd 細長い形状のシリカゾル及びその製造法
JPH03187913A (ja) 1989-12-15 1991-08-15 Shin Etsu Chem Co Ltd シリカ粉末の製造方法
JPH1143319A (ja) 1997-05-26 1999-02-16 Nissan Chem Ind Ltd 疎水性オルガノシリカゾルの製造方法
WO2000015552A1 (en) * 1998-09-10 2000-03-23 Nissan Chemical Industries, Ltd. Moniliform silica sol, process for producing the same, and ink-jet recording medium
WO2006035709A1 (ja) * 2004-09-27 2006-04-06 Nippon Kayaku Kabushiki Kaisha エポキシ樹脂組成物および物品
JP2007063117A (ja) * 2005-08-02 2007-03-15 Nissan Chem Ind Ltd 有機溶媒分散シリカゾル及びその製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2119731A4 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110281974A1 (en) * 2008-11-18 2011-11-17 Nissan Chemical Industries, Ltd. Process for producing composition of polymerizable organic compound containing silica particles
JP2010254548A (ja) * 2009-03-31 2010-11-11 Admatechs Co Ltd コロイダルシリカ及びその製造方法
JP2013155245A (ja) * 2012-01-27 2013-08-15 Tamura Seisakusho Co Ltd 紫外線硬化性透明樹脂組成物

Also Published As

Publication number Publication date
US20110172331A1 (en) 2011-07-14
JPWO2008093775A1 (ja) 2010-05-20
EP2119731A1 (en) 2009-11-18
KR20090116752A (ko) 2009-11-11
JP5376124B2 (ja) 2013-12-25
CN101600738B (zh) 2012-11-14
CN101600738A (zh) 2009-12-09
TWI464116B (zh) 2014-12-11
US20100029845A1 (en) 2010-02-04
TW200904751A (en) 2009-02-01
US7999026B2 (en) 2011-08-16
KR101429318B1 (ko) 2014-08-11
EP2119731A4 (en) 2010-03-10

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