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WO2007139417A1 - Rail steel - Google Patents

Rail steel Download PDF

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Publication number
WO2007139417A1
WO2007139417A1 PCT/RU2006/000269 RU2006000269W WO2007139417A1 WO 2007139417 A1 WO2007139417 A1 WO 2007139417A1 RU 2006000269 W RU2006000269 W RU 2006000269W WO 2007139417 A1 WO2007139417 A1 WO 2007139417A1
Authority
WO
WIPO (PCT)
Prior art keywords
less
steel
rail steel
chromium
azote
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/RU2006/000269
Other languages
French (fr)
Inventor
Larissa Victorovna Korneeva
Saul Samuilovich Tchernyak
Valeriy Petrovich Dementyev
Nikolay Anatolyevich Kozyryev
Valeriy Alexandrovich Rudenkov
Andrey Pavlovich Khomenko
Mikhail Vladimirovich Klokov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STATE EDUCATIONAL INSTITUTION OF HIGHER PROFESSIONAL TRAINING
Original Assignee
STATE EDUCATIONAL INSTITUTION OF HIGHER PROFESSIONAL TRAINING
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by STATE EDUCATIONAL INSTITUTION OF HIGHER PROFESSIONAL TRAINING filed Critical STATE EDUCATIONAL INSTITUTION OF HIGHER PROFESSIONAL TRAINING
Priority to PCT/RU2006/000269 priority Critical patent/WO2007139417A1/en
Publication of WO2007139417A1 publication Critical patent/WO2007139417A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium

Definitions

  • the invention to be patented refers to ferrous metallurgy and in particular to steel used for making rails.
  • the known kind of rail steel chosen as a prototype [1] contains (weight per
  • This kind of steel essential disadvantage is its low operational stability caused by the poor complex of its physical and mechanical properties.
  • E76F rail steel [2] having (weight per cent, %) carbon 0.71 - 0.82 manganese 0.75 - 1.05 silicon 0.25 - 0.45 vanadium 0.03 - 0.15 chromium not more than 0.15 nickel not more than 0.15 copper not more than 0.15 iron the rest
  • This kind of steel essential disadvantage is the low endurance of rails without thermal treatment as well as the need for steel thermal pretreatment in order to improve its operational characteristics.
  • This steel main disadvantage is its high cost because of the wolfram and lanthanum content as well as its contamination by non-metal inclusions caused by cerium presence, so called cerium edge non-uniformity.
  • the intended technical effect of the invention is improving of the complex of its physical and mechanical characteristics and of its operational strength.
  • the components ratio is the following (weight, per cent %) carbon 0.71 - 0.82
  • the steel can also contain sulphur (less than 0.020%), phosphorus (less than 0.025%), copper (less than 0.15%) as additives.
  • the requested rail steel chemical composition was chosen on the base of the following considerations.
  • the determined amount of chromium addition is supposed to provide high resistance to wear and strength properties of the steel. Decreasing the chromium content to 0.70% does not provide the required track rails durability and if the chromium percentage increases to more than 1.20% the steel cost grows significantly while its strength properties are the same.
  • the aluminium content was calculated, on one hand, after getting of available fine grain and, on the other hand, after the elimination of inadmissible aluminous non-metallic inclusions.
  • the manganese amount in determined limits provides required rails resistance to wear.
  • Azote addition makes it possible to get austenite fine grain to provide increase of the rail steel strength and resistance to fragility.
  • Vanadium presence helps thereby to get required azote solubility in its compounds. If azote content is less than 0.005% grain bucking is impossible and, thereby, required steel hardness cannot be reached. And if azote content is more than 0.020% it causes azote not to be dissolved and inadmissible nipples to appear in steel.
  • the determined azote and vanadium content and ratio ensure required steel impact strength (even at temperature below zero) because of carbonic nitrite setting.
  • Nickel content being more than 0.20% the possibility of getting inadmissible microscopic structures increases.
  • Nickel addition being reduced to less than 0.03% makes the steel impact strength lower.
  • Barium and strontium addition makes it possible to modify such tensions concentrators sources as non-metal inclusions, to prevent creation of so called “dangerous" alumina inclusions, to increase the steel purity from oxide and sulphide ones, to provide globe inclusions formation and to eliminate backstitch aluminates inclusions formation.
  • tensions concentrators sources as non-metal inclusions
  • so called “dangerous" alumina inclusions to increase the steel purity from oxide and sulphide ones
  • to provide globe inclusions formation and to eliminate backstitch aluminates inclusions formation In case of adding more than 0.005% barium and strontium weight per cent to the steel, there is a danger to get barium and strontium non-metal inclusions worsening steel physical properties.
  • Phosphorus, sulphur and copper content limitation causes the improvement of the surface quality of the ready steel rolled and advance in its physical and mechanical properties.
  • a series of tentative smelts was made in arc steel furnaces DSP- 10017.
  • the rail steel chemical composition is shown in the Table 1 (fig. 1).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The rail steel is claimed. The technical result consists in the improving of the complex of its physical and mechanical characteristics and of its operational proof strength. The rail steel contains the following components (weight %) : carbon 0,71-0,82, manganese 0,75-1,10, silicon 0,40-0,60, chromium 0,70-120, aluminium less then 0,005, vanadium 0,05-0,17, calcium 0,0001-0,005, azote 0,005-0,020, nickel 0,03-0,20, barium 0,0001-0,005, strontium 0,0001-0,005, iron -the rest. The rail steel thereby can contain sulphur less then 0,020 wt.%, phosphorus less then 0,025 wt.% and copper less then 0,15 wt.% as additives.

Description

Rail Steel
The invention to be patented refers to ferrous metallurgy and in particular to steel used for making rails. The known kind of rail steel chosen as a prototype [1] contains (weight per
cent, %)
carbon 0.62 - 0.84
manganese 0.8 - 1.3
silicon 0.2 - 1.0
chromium 0.6 - 1.5
aluminium 0.02 - 0.05
vanadium 0.03 - 0.12
calcium 0.001 - 0.05
iron the rest
This kind of steel essential disadvantage is its low operational stability caused by the poor complex of its physical and mechanical properties.
There is also a known kind of E76F rail steel [2] having (weight per cent, %) carbon 0.71 - 0.82 manganese 0.75 - 1.05 silicon 0.25 - 0.45 vanadium 0.03 - 0.15 chromium not more than 0.15 nickel not more than 0.15 copper not more than 0.15 iron the rest This kind of steel essential disadvantage is the low endurance of rails without thermal treatment as well as the need for steel thermal pretreatment in order to improve its operational characteristics.
There also exists a known kind of rail steel [3] containing carbon, silicon, manganese, chromium, wolfram, cerium and iron which features additional components as aluminium, boron, lanthanum to improve fatigue and short metal strength. The components proportion is the following (weight per cent,
%) carbon 0.6 - 0.8 silicon 0.5 - 1.3 manganese 0.5 - 1.0 chromium 0.5 - 1.0 wolfram 0.5 - 1.0 cerium 0.003 - 0.15 aluminium 0.03 - 0.05 boron 0.002 - 0.007 lanthanum 0.003 - 0.1 iron the rest
This steel main disadvantage is its high cost because of the wolfram and lanthanum content as well as its contamination by non-metal inclusions caused by cerium presence, so called cerium edge non-uniformity.
The intended technical effect of the invention is improving of the complex of its physical and mechanical characteristics and of its operational strength.
To achieve this purpose the rail steel containing carbon, manganese, silicon, chromium, aluminium, vanadium, calcium and iron, contains in addition azote, nickel, barium and strontium. The components ratio is the following (weight, per cent %) carbon 0.71 - 0.82
manganese 0.75 - 1.10
silicon 0.40 - 0.60
chromium 0.70 - 1.20
aluminium less than 0.005
vanadium 0.05 - 0.15
calcium 0.0001 - 0.005
azote 0.005 - 0.020
nickel 0.03 - 0.20
barium 0.0001 - 0.005
strontium 0.0001 - 0.005
iron the rest
And the steel can also contain sulphur (less than 0.020%), phosphorus (less than 0.025%), copper (less than 0.15%) as additives.
The requested rail steel chemical composition was chosen on the base of the following considerations.
Increasing of silicon weight per cent up to 0.60% improves the rail steel yield and strength. At decreasing silicon addition to less than 0.40% dramatic reduction of these parameters is observe*!
The determined amount of chromium addition is supposed to provide high resistance to wear and strength properties of the steel. Decreasing the chromium content to 0.70% does not provide the required track rails durability and if the chromium percentage increases to more than 1.20% the steel cost grows significantly while its strength properties are the same. The aluminium content was calculated, on one hand, after getting of available fine grain and, on the other hand, after the elimination of inadmissible aluminous non-metallic inclusions.
The manganese amount in determined limits provides required rails resistance to wear.
Azote addition makes it possible to get austenite fine grain to provide increase of the rail steel strength and resistance to fragility.
Vanadium presence helps thereby to get required azote solubility in its compounds. If azote content is less than 0.005% grain bucking is impossible and, thereby, required steel hardness cannot be reached. And if azote content is more than 0.020% it causes azote not to be dissolved and inadmissible nipples to appear in steel.
The determined azote and vanadium content and ratio ensure required steel impact strength (even at temperature below zero) because of carbonic nitrite setting.
Nickel content being more than 0.20% the possibility of getting inadmissible microscopic structures increases. Nickel addition being reduced to less than 0.03% makes the steel impact strength lower.
Barium and strontium addition makes it possible to modify such tensions concentrators sources as non-metal inclusions, to prevent creation of so called "dangerous" alumina inclusions, to increase the steel purity from oxide and sulphide ones, to provide globe inclusions formation and to eliminate backstitch aluminates inclusions formation. In case of adding more than 0.005% barium and strontium weight per cent to the steel, there is a danger to get barium and strontium non-metal inclusions worsening steel physical properties.
Phosphorus, sulphur and copper content limitation causes the improvement of the surface quality of the ready steel rolled and advance in its physical and mechanical properties. A series of tentative smelts was made in arc steel furnaces DSP- 10017.
The rail steel chemical composition is shown in the Table 1 (fig. 1).
The steel having been poured at MNLZ the rolling of R65 type rails was made. Having been rolled the rails were not processed with thermal treatment. The tests results of their mechanical properties in hot rolled state in comparison with the prototype steel kind shown in the Table 2 (fig. 2) reflect that the requested rail steel chemical composition provides improvement upon the mechanical properties of the steel. And this improvement, in its turn, increases the operational proof strength of track rails.
References
1. ITaTeHT PΦ JVb 819208, C. 22 C 38/24.
2. FOOT P 51685-2000 "PejiBcti jκejie3Hθ,a;opo)KHE>ie. O6πine TexHHHecKHe ycjioBHa".
3. IIaτeHT PΦ Jfe 522265, C. 22 C 38/22.
Table 1
The Rail Steel Chemical Composition
Figure imgf000007_0001
Figure imgf000007_0002
Table 2
The Mechanical Properties of the Rail Steel
Figure imgf000008_0001

Claims

The Summary of the Invention
The rail steel containing carbon, manganese, silicon, chromium, aluminium, vanadium, calcium and iron, differs in additions of azote, nickel, barium and strontium. The components proportion is the following (weight per cent, %) carbon 0.71 - 0.82
manganese 0.75 - 1.10
silicon 0.40 - 0.60
chromium 0.70 - 1.20
aluminium less than 0.005
vanadium 0.05 - 0.15
calcium 0.0001 - 0.005
azote 0.005 - 0.020
nickel 0.03 - 0.20
barium 0.0001 - 0.005
strontium 0.0001 - 0.005
iron the rest
The rail steel thereby can contain sulphur (less than 0.020%), phosphorus (less than 0.025%), copper (less than 0.15%) as additives.
PCT/RU2006/000269 2006-05-26 2006-05-26 Rail steel Ceased WO2007139417A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/RU2006/000269 WO2007139417A1 (en) 2006-05-26 2006-05-26 Rail steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/RU2006/000269 WO2007139417A1 (en) 2006-05-26 2006-05-26 Rail steel

Publications (1)

Publication Number Publication Date
WO2007139417A1 true WO2007139417A1 (en) 2007-12-06

Family

ID=38778850

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2006/000269 Ceased WO2007139417A1 (en) 2006-05-26 2006-05-26 Rail steel

Country Status (1)

Country Link
WO (1) WO2007139417A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017199079A1 (en) * 2016-05-19 2017-11-23 Rail 1520 Ip Ltd Steel for producing railway wheels
CN109972052A (en) * 2018-06-08 2019-07-05 中南大学 A kind of strontium modified hard alloy and its casting and heat treatment method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2100471C1 (en) * 1996-06-14 1997-12-27 Акционерное общество "Кузнецкий металлургический комбинат" Rail steel
RU2161210C1 (en) * 1999-06-01 2000-12-27 Открытое акционерное общество "Кузнецкий металлургический комбинат" Rail steel
RU2197539C2 (en) * 1999-06-01 2003-01-27 Открытое акционерное общество "Кузнецкий металлургический комбинат" Method of making rail steel in electric arc furnaces
JP2004043963A (en) * 2002-05-20 2004-02-12 Nippon Steel Corp Perlite rail excellent in toughness and ductility and method for producing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2100471C1 (en) * 1996-06-14 1997-12-27 Акционерное общество "Кузнецкий металлургический комбинат" Rail steel
RU2161210C1 (en) * 1999-06-01 2000-12-27 Открытое акционерное общество "Кузнецкий металлургический комбинат" Rail steel
RU2197539C2 (en) * 1999-06-01 2003-01-27 Открытое акционерное общество "Кузнецкий металлургический комбинат" Method of making rail steel in electric arc furnaces
JP2004043963A (en) * 2002-05-20 2004-02-12 Nippon Steel Corp Perlite rail excellent in toughness and ductility and method for producing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017199079A1 (en) * 2016-05-19 2017-11-23 Rail 1520 Ip Ltd Steel for producing railway wheels
CN109972052A (en) * 2018-06-08 2019-07-05 中南大学 A kind of strontium modified hard alloy and its casting and heat treatment method

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