WO2007123213A1 - Agent de lutte anti-parasite - Google Patents
Agent de lutte anti-parasite Download PDFInfo
- Publication number
- WO2007123213A1 WO2007123213A1 PCT/JP2007/058664 JP2007058664W WO2007123213A1 WO 2007123213 A1 WO2007123213 A1 WO 2007123213A1 JP 2007058664 W JP2007058664 W JP 2007058664W WO 2007123213 A1 WO2007123213 A1 WO 2007123213A1
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- WIPO (PCT)
- Prior art keywords
- control agent
- pest control
- weight
- salt
- group
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
Definitions
- the present invention relates to a pest control agent used for controlling (controlling and preventing) domestic pests such as termites, ticks, cockroaches, flies (maggots), and mosquitoes.
- Patent Document 1 Japanese Patent No. 2799859
- Patent Document 2 Japanese Patent Laid-Open No. 10-16 7916
- Patent Document 3 Japanese Patent Laid-Open No. 2001-48715.
- Patent Document 4 JP-A-2004-155694.
- Hiba oil also has a strong repellent effect, so termites do not come into contact with Hiba oil, so it is not effective as a termite control agent, and Hiba oil has a strong odor, which makes it uncomfortable when the amount of processing increases. There is also a problem with giving.
- termite control usually requires both soil treatment and xylem treatment, and a control agent suitable for each application site has been selected and used.
- a control agent suitable for each application site has been selected and used.
- a conventional control agent containing the above hinokitiol has been used for xylem treatment!
- an object of the present invention is to solve the above-mentioned problems and to provide a control agent that has a high control effect on house pests, particularly termites, and is safe for the human body.
- the first present invention relates to a pest control agent comprising a trobolone derivative, a chloride of a Group 2 element of the periodic table, and water.
- the second aspect of the present invention is a pest control agent containing chlorides and water of group 2 elements of the periodic table, and as an additive carotenant, a surfactant, an antifungal agent, a sulfate, and an alginate power are selected.
- the present invention relates to a pest control agent containing at least one of the above.
- the third aspect of the present invention relates to a termite control method using the pest control agent according to the first and second aspects of the present invention for soil treatment and Z or xylem treatment.
- a remarkably high control effect can be obtained as a synergistic effect of both.
- various termites including not only termites but also termites It shows a high insecticidal effect against the worm and can effectively prevent the house.
- both active ingredients are highly safe and easily available, it is possible to provide a safe and inexpensive pest control agent.
- the pest control agent according to the present invention can be applied to both soil treatment and xylem treatment, construction on site can be easily and efficiently performed.
- the trobolone derivative is a compound represented by the following general formula (1).
- a 7-membered hydroxyl group or carbonyl group may form a metal complex or a metal salt, or a hydroxyl group may form an ester or ether.
- R 2 and R 3 are each independently hydrogen, an alkyl group, or an alkyl group.
- the alkyl group, alkyl group, and alkyl group of R 2 and R 3 may be either linear or branched, and each preferably has about 1 to 12 carbon atoms.
- the cycloalkyl group preferably has about 1 to 12 carbon atoms, and may further have a substituent such as an alkyl group, or may have an unsaturated bond.
- hinokitiol which is 4 isopropyl trobolone ( ⁇ tsuyapricin).
- Hinokitiol is a natural product contained in the essential oils of Aomori Hiba and Taiwan Hinoki.
- natural extracts may be used, or chemically synthesized products may be used.
- hiba oil obtained by steam distillation of hiba materials (millwood, large sawdust, etc.) such as Aomori hiba
- Hiba oil usually contains about 2% by weight of hinokitiol and various other ingredients. Since these other components than hinokitiol are also considered to contribute to the pest control effect, this is a preferred embodiment.
- a configuration containing hiba oil, salty calcium, and water can be mentioned.
- the amount of the trobolone derivative is extremely low as compared with the conventional one by combining with a chloride of Group 2 element of the periodic table, particularly preferably with calcium chloride and Z or magnesium chloride. can do.
- a chloride of Group 2 element of the periodic table particularly preferably with calcium chloride and Z or magnesium chloride.
- the combination of the trace amount of trobolone derivative provided a synergistic effect with the salt and salt of the Group 2 elements of the periodic table, resulting in a very strong control effect (insecticide). It is a feature of the present invention that an effect and an effect of preventing soil penetration can be obtained.
- the compounding amount of the trobolone derivative such as hinokitiol in the pest control agent is preferably 1 ppm (0.0001% by weight) or more, more preferably 5 ppm or more. Further, it is more preferable that it is 10 ppm or more. Even more preferable is 20 ppm or more.
- the upper limit of the blending amount is not particularly limited, but there is no difference in the effect obtained even if blending too much, so that it is preferably about 1000 ppm (0.1% by weight) or less 400 ppm ( 0.04% by weight) or less, more preferably 200ppm (0.02% by weight) or less, and even more preferably about lOOppm or less.
- the amount of Hiba oil is preferably 0.005% by weight or more, more preferably 0.025% by weight or more, and even more preferably 0.05% by weight or more. It is even more preferable that the content is 0.1% by weight or more.
- the upper limit of the blending amount is not particularly limited, but there is no difference in the effect obtained even if blending too much, so it is preferable that the blending amount is about 5.0% by weight or less. It is more preferable that the amount is about 1% by weight or less. More preferably, the amount is about 0. 5% by weight or less. More preferably, the amount is about 5% by weight or less. Since the amount of oil blended can be kept to a minimum and minimum compared to the conventional amount, there is no discomfort after processing.
- salt calcium and Z or salt magnesium can be preferably used, and salt calcium is most preferably used.
- Both calcium chloride and calcium chloride can be used as anhydrous salt or hydrated salt (1-6 hydrate).
- the blending amount may be appropriately set according to the type of pest, but generally it is preferably 10 to 50% by weight, more preferably 15 to 45% by weight, and more preferably 20 to 40% by weight. It is even more preferable that it is 27 to 33% by weight, even more preferably 25 to 35% by weight or more. Even if more than 50% by weight of calcium chloride is added, it becomes a saturated solution, and no further improvement in effect is observed. On the other hand, if it is less than 10% by weight, there is a possibility that a sufficient control effect may not be obtained especially for termites.
- Magnesium chloride can be used either as an anhydrous salt or a hydrated salt (1-6 hydrate).
- the blending amount of salt and magnesium may be appropriately set according to the kind of pest, but generally it is preferably 1 to 35% by weight in the pest control agent in terms of anhydrous salt. More preferably, it is 10 to 25% by weight. Even if more than 35% by weight of magnesium chloride is added, it becomes a saturated solution, and no further improvement in effect is observed. On the other hand, if it is less than 1% by weight, there is a fear that a sufficient control effect cannot be obtained especially for termites.
- the pest control agent is mixed with a chelating agent (complex forming compound) in order to increase the durability of the effect of the trobolone derivative.
- a chelating agent complex forming compound
- the chelating agent is not particularly limited as long as it is a compound having a chelating effect (complex forming ability).
- ethylenediamine amine acetic acid hydroxyethyl ethylenediamine amine acetic acid, dihydroxyethyl ethylenediamine Amine diacetic acid, 1,3-propanediaminetetraacetic acid, cyclohexanediaminetetraacetic acid, diethylenetriaminepentaacetic acid, triethylenetetraminehexaacetic acid, hydroxyethyliminodiacetic acid, utyrolic acid, phosphonic acid, hydroxyethane phosphonic acid, amino Trimethylenephosphonic acid, polyphosphoric acid, polyamino acids (polyglutamic acid, polyaspartic acid, etc.), citrate, darconic acid, succinic acid, ascorbic acid, tartaric acid, acrylic acid-based (co) polymers, and their salts (sodium Salt, potassium salt, amine salt, ammonium salt, etc.) And the like.
- ethylenediamine tetraacetate diisodium salt, tetrasodium salt, etc.
- similar compounds are preferably used. These may be used alone or in combination of two or more.
- the amount of the chelating agent is not particularly limited, but is preferably about 0.1 to 10% by weight in the pest control agent, more preferably about 0.5 to 5% by weight. .
- trobolone derivatives chelate with iron and other metal ions present in soil and xylem, and their effects may not be exerted.
- a pest control agent contains a chelating agent, its chelating agent Since the agent is preferentially complexed with iron, etc., the sustainability of the effect of the trobolone derivative may be maintained.
- the drug transferability into termites such as termites
- a surfactant to the pest control agent.
- the spreadability and adherence of the salty substances of Group 2 elements of the periodic table such as salty calcium and salty magnesium are enhanced, and a higher control effect is obtained.
- the type of the surfactant is not particularly limited, and an anionic surfactant, a nonionic surfactant, or the like can be used.
- an anionic surfactant a nonionic surfactant, or the like
- polyoxyethylene alkyl ethers polyoxypropylene alkyl ethers, polyoxyethylene alkylphenyl ethers, polyoxypropylenes that are preferred to be nonionic surfactants from the viewpoints of permeability, emulsification / dispersibility, etc.
- Ether type nonionic surfactants such as alkyl phenyl ethers are particularly preferred.
- biodegradable surfactant for example, a commercially available product such as “SC—Magic Pan” (Infity Co., Ltd.) can be used. This is a surfactant composed of vegetable surfactants, fatty acids and other components.
- the blending amount of the surfactant is not particularly limited, but it is preferably about 1 to 5% by weight in the pest control agent, more preferably about 2 to 4% by weight.
- Rescall W-716 and “Rescall W-880P” manufactured by Toei Kasei Co., Ltd. can be preferably used as commercial products.
- an organic antifungal agent from the viewpoint of improving the drug transferability into the pest body and enhancing the control effect.
- a surfactant type antifungal agent or a surfactant having an antifungal effect.
- a surfactant type antifungal agent or a surfactant having an antifungal effect.
- the repellent effect of alkylamine is added, so that polyoxyethylene alkylamine, dipodium are added.
- Alkylamine antifungal agents such as reoxyethylene alkylamine can be preferably used.
- the effect of the above-mentioned surfactant can also be obtained, so the control effect can be further enhanced.
- fungicides may be used alone or in combination of a plurality of types.
- the blending amount of the fungicide is not particularly limited, but it is 0.1 in the pest control agent. It is preferably about -20% by weight, more preferably 0.2-10% by weight, and even more preferably 0.5-5% by weight.
- a specific auxiliary agent is combined with a salt of a Group 2 element of the periodic table such as salt calcium or salt magnesium, and both of them are combined.
- a salt of a Group 2 element of the periodic table such as salt calcium or salt magnesium
- This particular adjuvant is a sulfate or alginate, and it is preferable to use, for example, calcium sulfate, barium sulfate, or sodium alginate. Two or more of these Use the above compounds together.
- the blending amount is preferably 1 to 20% by weight, more preferably 5 to 15% by weight.
- the pest control agent optionally includes a fungicide, a fungicide, an insect repellent, a stabilizer, a dispersant, a thickener, an antifoaming agent, an organic solvent, a fragrance, and a coloring.
- Agent, PH adjuster, etc. can be added.
- known ones can be used, and the blending amount thereof is not particularly limited as long as it is appropriately set.
- the pest control agent is prepared in the form of an aqueous solution or a dispersion by mixing the trobolone derivative, the salt of the Group 2 element of the periodic table, and water with any of the above-described optional components.
- the pest control agent according to the present invention contains these components and water.
- the control agent containing hinokitiol as an active ingredient was an organic solvent system, whereas the present invention is characterized in that it contains hinokitiol and is prepared in an aqueous system.
- volatile organic substances that cause sick house symptoms and chemical hypersensitivity are not emitted!
- This pest control agent can be used for controlling and preventing pests called house pests such as termites, ticks, cockroaches, flies and mosquitoes. Among them, a high control effect can be obtained against termites (such as termites and termites). In the following, the application method and so on will be described using the case of using it for termite control.
- the pest control agent according to the present invention can be applied to both soil treatment and xylem treatment.
- a chemical is sprayed on the soil surface to form an ant barrier (barrier layer).
- termites which are subterranean insects, dig tunnels from the underfloor soil and invade the underfloor.
- spray a chemical on the underfloor soil surface to form a noria layer spray a chemical on the underfloor soil surface to form a noria layer.
- the “barrier method” is very useful.
- the xylem treatment includes a method of spraying a chemical on the surface of a wood using a sprayer, a method of applying with a brush or the like, and a method of injecting a chemical by perforating wood or a wall. Also Can also apply a pest control agent to the sheet and lay the sheet on the soil surface.
- the pest control agent is preferably used as a liquid type or a spray type. In the case of a liquid type, it can be sprayed using a sprayer. Alternatively, it may be applied by forming a granule containing a liquid pest control agent and spraying it.
- Granules include a granular carrier such as a porous body impregnated with a pest control agent, a granular carrier coated with a pest control agent, a form in which a filler and a pest control agent are kneaded and granulated, capsule It may be out of place, such as a form that contains a pest control agent inside.
- the amount of treatment with the pest control agent is not particularly limited, and may be set as appropriate depending on the concentration of the active ingredient and the application site.
- LO l Z m 2 about the amount can be sprayed 3-7 liters Zm 2 about a it is in preferred instrument 4-6 l Zm 2 about More preferably it is.
- Calcium chloride as the weight of the chloride of the periodic table Group 2 element such as magnesium chloride (anhydrous salt basis), preferably be treated to be sprayed amount of 0. L ⁇ 3kgZm 2 fixture 0. more preferred be treated such that the application rates of 2 ⁇ 2kgZm 2,.
- sulfate or alginate preferably calcium sulfate, barium sulfate, or sodium alginate is used as an auxiliary agent in advance (with a pest control agent). It is preferable to spray or apply simultaneously (before the treatment with the pest control agent) or after the treatment (after the treatment with the pest control agent) before the treatment. A remarkably high control effect can be obtained by spraying or applying these adjuvants. This is presumably because a physical layer is formed by the adjuvant, and a synergistic effect is obtained by increasing the contact time between the termites and the salt of the group 2 element of the periodic table.
- the treatment with such an auxiliary agent is particularly preferable when the pest control agent to be used does not contain these auxiliary agents.
- the auxiliary agent When the auxiliary agent is sprayed in advance, the auxiliary agent can be sprayed in the form of powder.
- the adjuvant in the case of post spraying, it is preferable to spray the adjuvant as an aqueous solution or a suspension with water.
- the throughput of calcium sulfate, barium sulfate, or sodium alginate is particularly limited It may be set as appropriate depending on the concentration of the active ingredient and the application location.
- concentration of the active ingredient in the case of pre-sprayed in powder form, in the case of post-sprayed with preferred tool solutions or suspensions be used 0. l ⁇ lkgZm 2 about adjuvants, 0. 1 ⁇ : LkgZm as about two auxiliary agent is diffused, it is preferable to adjust the concentration and their application rates (approximately 2 typically l ⁇ 5LZm).
- the second aspect of the present invention provides at least one additive selected from the group power of the periodic table group 2 element chloride, which is a specific additive, that is, a surfactant, an antifungal agent, a sulfate, and an alginate force. It is an invention used in combination with a caloric agent, and can provide a control effect that is much better than the use of a salt of a Group 2 element of the periodic table alone.
- salt calcium is used as a salt of the Group 2 element of the periodic table, and by combining a salt calcium with a surfactant and an antifungal agent, the spread of the salt calcium is enhanced and high. It is possible to obtain a pest control agent that has a control effect and does not have a problem of metal corrosiveness to metal members under the floor.
- a synergistic effect can be obtained by increasing the contact time between the pest and the salted calcium salt, which is notable.
- a high control effect can be obtained.
- it shows a high insecticidal effect against various termites including not only termites but also termites, and can effectively prevent houses.
- this pest control agent can be applied to both soil treatment and xylem treatment, construction at the site can be performed easily and efficiently.
- Sand loam was packed to a height of lcm in a polyethylene container 5cm in diameter and 3cm in height.
- the central portion of the sandy loam making a clear acrylic cylinder having an inner diameter of 1. 5 cm, packed with sandy loam height 4c m therein, impregnated upper force throughput 5LZm 2 of test solution.
- After air drying add 2.5 ml of water to the transparent acrylic cylindrical sand loam, and lml of water to the sandy loam in the polyethylene container to moisten it.
- Cellulose was packed to a height of 1 cm and the upper end was sealed with a wrap film.
- 50 polyethylene termite ants were placed in a polyethylene container, and the state of soil penetration up to 21 days later was examined.
- a predetermined amount (100, 200, 300gZm 2 equivalent) of test solution was applied to a cedar sapwood piece (2 X 2 X lcm) with a brush and left in the room for a week.
- the treated piece of wood is placed in an insect release container (cylindrical container made of acrylic resin with a diameter of 7 cm and a plaster on the bottom), and Yeshiroari (150 professional ants and 50 soldier ants) is released. Insects. This was left for 3 weeks with hydration, and the amount of damage (weight reduction rate) and the number of dead termites were examined after 3 weeks.
- test solution 25 ml of the test solution was put in a glass bottle with a 50 ml lid, and an iron test piece (SS-400, 40 mm X 20 mm X 2 mm) was immersed, sealed, and left in a thermostatic oven at 40 ° C for 30 days. Thereafter, the test piece was taken out and the degree of wrinkles was observed.
- an iron test piece (SS-400, 40 mm X 20 mm X 2 mm) was immersed, sealed, and left in a thermostatic oven at 40 ° C for 30 days. Thereafter, the test piece was taken out and the degree of wrinkles was observed.
- the degree of iron corrosion was judged according to the following criteria. 5: Extremely severe corrosion, 4: Extreme corrosion, 3: Corrosion, 2: Slight corrosion, 1: Almost no corrosion.
- Test solutions of Example A and Comparative Example A shown in Table 1 were prepared. Of the test solution shown in Table 1.
- the compounding components are as follows.
- Hiba Oil Kisei Tech's “Kisei PROSOL ⁇ N” containing Hiba oil (Hinokithiol content: 0.5% by weight; isoparaffinic hydrocarbons containing natural essential oils such as Hiba Oil, Hinoki Oil, etc.) Reagent (CaCl) manufactured by Iki Kosei Co., Ltd.
- Tables 2-5 The results obtained are shown in Tables 2-5.
- Tables 2 and 3 are the results of soil penetration test 1.
- Example A Composition of test solution
- Example IV the test solution of Example IV in which two kinds of active ingredients (trobolone derivative and a chloride of Group 2 element of the periodic table) were combined obtained a very high control effect.
- active ingredients robotlone derivative and a chloride of Group 2 element of the periodic table
- Test solutions of Example B and Comparative Example B shown in Table 6 were prepared.
- the components of the test solution shown in Table 6 are as follows.
- Salt Calcium Reagent (CaCl) manufactured by Iki Seisei Co., Ltd.
- Antifungal agent Polyoxyethylene alkylamine (Miyoshi Oil & Fat Co., Ltd. “Muron”)
- Auxiliary agent A Calcium sulfate: Reagent (CaSO) manufactured by Wako Pure Chemical Industries, Ltd.
- Auxiliary agent B Barium sulfate: Wako Pure Chemical Industries, Ltd. Reagent (BaSO)
- Auxiliary agent c Sodium alginate: Reagent manufactured by Wako Pure Chemical Industries, Ltd.
- Tables 7-9 show the results of soil penetration test 1.
- Example B As seen from the above results, the test solution of Example B provided a very high control effect. For termites, the usefulness of these test solutions is clear because they cannot withstand practical use unless the mortality rate is 100%. Due to the action of the physical layer of the adjuvant, a synergistic effect can be obtained by increasing the contact time between the termites and the salt of the Group 2 element (salt calcium). It was found that a control effect can be obtained.
- Test solutions of Example C and Reference Example C shown in Table 10 were prepared. As a control, soil was also tested without treatment with the test solution. There were 3 test zones each.
- the pre-spreading of the auxiliary agent was carried out in powder form, and an auxiliary agent in an amount of 0.5 kgZm 2 was sprayed on the sand loam soil, and then the test solution was soaked.
- the supplement was prepared as an aqueous suspension, the test solution was soaked in sandy loam, and then added to the sandy loam so that 0.5 kgZm 2 of supplement was sprayed. .
- Magnesium chloride Reagent (MgCl) manufactured by Wako Pure Chemical Industries, Ltd.
- Antifungal agent Polyoxyethylene alkylamine (Miyoshi Oil and Fat Co., Ltd. “Muron”)
- Hiba oil Contains Hiba oil (Yes)
- Adjuvant A Calcium sulfate: Reagent (CaSO) manufactured by Wako Pure Chemical Industries, Ltd.
- Auxiliary agent B Barium sulfate: Wako Pure Chemical Industries, Ltd.
- Adjuvant c Sodium alginate: Reagent made by Wako Pure Chemical Industries, Ltd.
- Table 11 shows the results of soil penetration test 2.
- test solution of Example C provided a very high control effect.
- test solution of Reference Example C did not provide a sufficient control effect against termites.
- Test solutions for each Example D and Comparative Example D shown in Table 13 were prepared. As a control, soil was also tested without treatment with the test solution. There were 3 test zones each.
- the pre-spreading of the auxiliary agent was carried out in powder form, and an auxiliary agent in an amount of 0.5 kgZm 2 was sprayed on the sand loam soil, and then the test solution was soaked.
- the supplement was prepared as an aqueous suspension, the test solution was soaked in sandy loam, and then added to the sandy loam so that 0.5 kgZm 2 of supplement was sprayed. .
- Surfactant Polyoxyethylene alkyl ether ("Pelesoft NSC” manufactured by Miyoshi Oil & Fats Co., Ltd.)
- Antifungal agent Polyoxyethylene alkylamine (Miyoshi Oil & Fat Co., Ltd. “Muron”)
- Auxiliary agent A Calcium sulfate: Reagent (CaSO) manufactured by Wako Pure Chemical Industries, Ltd.
- Auxiliary agent c Sodium alginate: Reagent manufactured by Wako Pure Chemical Industries, Ltd.
- Table 14 shows the results of soil penetration test 2.
- Example D As seen from the above results, the test solution of Example D provided a very high control effect. On the other hand, the test solution of Comparative Example D was not able to obtain a sufficient control effect.
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2007241835A AU2007241835B2 (en) | 2006-04-20 | 2007-04-20 | Pest control agent |
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006116985A JP2007290966A (ja) | 2006-04-20 | 2006-04-20 | 害虫防除剤 |
| JP2006-116985 | 2006-04-20 | ||
| JP2006-128373 | 2006-05-02 | ||
| JP2006128373A JP4387375B2 (ja) | 2006-05-02 | 2006-05-02 | シロアリ防除剤 |
| JP2006-193408 | 2006-07-13 | ||
| JP2006193408A JP2008019217A (ja) | 2006-07-13 | 2006-07-13 | 害虫防除剤 |
| JP2006-193409 | 2006-07-13 | ||
| JP2006193409A JP4767113B2 (ja) | 2006-07-13 | 2006-07-13 | シロアリ防除剤 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2007123213A1 true WO2007123213A1 (fr) | 2007-11-01 |
Family
ID=38625112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2007/058664 Ceased WO2007123213A1 (fr) | 2006-04-20 | 2007-04-20 | Agent de lutte anti-parasite |
Country Status (2)
| Country | Link |
|---|---|
| AU (1) | AU2007241835B2 (fr) |
| WO (1) | WO2007123213A1 (fr) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0733608A (ja) * | 1993-07-22 | 1995-02-03 | Japan Tobacco Inc | 界面活性剤を利用した殺虫剤及び殺虫方法 |
| JPH10245293A (ja) * | 1997-03-06 | 1998-09-14 | Sumitomo Chem Co Ltd | 害虫防除用農薬含有肥料組成物及びそれを用いる害虫防除方法 |
| JP2000247819A (ja) * | 1999-03-01 | 2000-09-12 | Etsuo Kobayashi | 有機活性農薬及びその製造方法 |
| JP2004043327A (ja) * | 2002-07-09 | 2004-02-12 | Asahi Kasei Chemicals Corp | 木材処理剤 |
| JP3868992B1 (ja) * | 2006-02-27 | 2007-01-17 | 株式会社アムテック | シロアリ防除剤 |
-
2007
- 2007-04-20 WO PCT/JP2007/058664 patent/WO2007123213A1/fr not_active Ceased
- 2007-04-20 AU AU2007241835A patent/AU2007241835B2/en not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0733608A (ja) * | 1993-07-22 | 1995-02-03 | Japan Tobacco Inc | 界面活性剤を利用した殺虫剤及び殺虫方法 |
| JPH10245293A (ja) * | 1997-03-06 | 1998-09-14 | Sumitomo Chem Co Ltd | 害虫防除用農薬含有肥料組成物及びそれを用いる害虫防除方法 |
| JP2000247819A (ja) * | 1999-03-01 | 2000-09-12 | Etsuo Kobayashi | 有機活性農薬及びその製造方法 |
| JP2004043327A (ja) * | 2002-07-09 | 2004-02-12 | Asahi Kasei Chemicals Corp | 木材処理剤 |
| JP3868992B1 (ja) * | 2006-02-27 | 2007-01-17 | 株式会社アムテック | シロアリ防除剤 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2007241835A1 (en) | 2007-11-01 |
| AU2007241835B2 (en) | 2010-10-14 |
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