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WO2007104740A1 - Émulsion lavante sans silicone pour les cheveux - Google Patents

Émulsion lavante sans silicone pour les cheveux Download PDF

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Publication number
WO2007104740A1
WO2007104740A1 PCT/EP2007/052299 EP2007052299W WO2007104740A1 WO 2007104740 A1 WO2007104740 A1 WO 2007104740A1 EP 2007052299 W EP2007052299 W EP 2007052299W WO 2007104740 A1 WO2007104740 A1 WO 2007104740A1
Authority
WO
WIPO (PCT)
Prior art keywords
emulsion according
hair
ethoxylated
emulsifiers
oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2007/052299
Other languages
German (de)
English (en)
Inventor
Harald Albrecht
Horst Argembeaux
Khiet Hien Diec
Birgit Heitmann
Sebastian Otto
Stephan Ruppert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of WO2007104740A1 publication Critical patent/WO2007104740A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/34—Free of silicones

Definitions

  • the present invention relates to silicone-free hair cleansing emulsions, in particular shampoo preparations containing glyceryl esters and ethoxylated fatty acids and fatty alcohols in combination with one or more cationic care components.
  • hair cleansing emulsions have improved combability as well as gloss and sensory properties (hair, foam).
  • the entire human body except the lips, the palms and soles of the feet is hairy, but mostly with scarcely visible woolly hairs. Because of the many nerve endings on the hair root hair is sensitive to external influences such as wind or touch and are therefore a not to be underestimated part of the sense of touch. However, the most important function of the human head hair today should be to shape the appearance of humans in a characteristic way. Similar to the skin, it fulfills a social function because it contributes significantly to interpersonal relationships and self-esteem of the individual through its appearance.
  • the hair consists of the hair shaft, which protrudes freely from the skin - the keratinized (dead) part, which is actually the visible hair - and the hair root stuck in the skin - the living part in which the visible hair is constantly being re-formed.
  • the hair shaft in turn is composed of three layers: a central part - the so-called Haarmark (medulla), which is regressed in humans and often completely absent - also the medulla (cortex) and the outer, up to ten layers strong cuticle (cuticle) that covers the whole hair.
  • Haarmark medulla
  • the human hair is, if there are no pathological changes, practically not to improve in his freshly regrown state.
  • the part of a hair near the scalp accordingly has an almost closed cuticle layer.
  • the cuticle layer as outer shell of the hair, but also the inner area below the cuticle are exposed to special stress due to environmental influences.
  • Significant influences for the loss of quality of a hair during its aging are the influence of sunlight, mechanical stress due to intensive combing or brushing, but also hair treatments such as hair dyeing and in particular bleaching and hair deformations, for example perming procedures.
  • oxidative stress often leads to damage to the hair.
  • Both UV-A and UV-B radiation have a damaging effect on the hair, which manifests itself, for example, in the fact that certain amino acids such as cystine and methionine are broken down or sulfur-sulfur bonds of keratin are split, which in the worst case Destruction of the hair can result.
  • the hair and scalp are parts of the body that are exposed to a significant amount of UV radiation due to their position when they are outdoors.
  • One goal of hair care is to protect the scalp and hair from oxidative influences and preserve the natural state of the newly regrown hair for as long as possible and restore it in the event of loss.
  • Silky sheen, low porosity and a pleasant, smooth feel are considered features of natural, healthy hair.
  • hair care products have been developed specifically. This has resulted in a variety of preparations for both general hair care and hair and scalp anomalies.
  • hair care cosmetics are used, which are either intended to be rinsed out after exposure to the hair, or which should remain on the hair.
  • the latter can be formulated so that they not only serve the care of the individual hair, but also improve the overall appearance of a hairstyle.
  • This kind of well-groomed hair is characterized by a pleasant grip, natural shine, increased fullness, smoothness, good combability and thus good manageability and firmness and thus good fit of the hairstyle.
  • Damaged or damaged hair after shampooing is usually rough, poorly combed and lackluster.
  • the consumer has the need for additional care.
  • shampoos for this type of hair additionally contain conditioning components; the cationic polymers are widespread. These improve the care properties such as combability and grip in both dry and wet hair and shine.
  • Cationic polymers are the basis-care raw materials for shampoo formulations, but they do not give the consumer adequate care.
  • foamable surfactant-containing emulsions containing from 0 to 0.001% by weight of silicone compounds containing at least one ethoxylated and / or propoxylated fatty acid or at least one ethoxylated and / or propoxylated fatty alcohol or its derivative, at least one glyceryl ester, one or more lipids and at least one cationic care component and, if desired, further cosmetic active substances, auxiliaries and additives.
  • Glyceryl esters and ethoxylated fatty acids or alcohols in combination with cationic conditioning agents provide a synergistic effect on care and shine.
  • the emulsion is of the oil-in-water type.
  • optically creamy or pearlescent surface-active emulsions according to the invention are based on emulsions of the oil-in-water type, comprising a fatty phase and a water phase.
  • Emulsions are two-phase systems of two immiscible liquid phases, in the simplest case a droplet-shaped inner disperse phase being surrounded by a continuous outer phase.
  • emulsifiers which reduce the interfacial tension.
  • HLB system it is possible to calculate, taking into account the oil phase, which emulsifier or which emulsifier combination can be used.
  • An ideal emulsifier or ideal emulsifier mixture has, inter alia, the following properties: high interfacial activity, lowering of the interfacial tension, stabilization by an "emulsifier pellicle", rapid spreading capacity at the interface, high surface viscosity and elasticity of the emulsifier film for delaying the coalescence also a described emulsion which comprises an oil phase and a water phase containing:
  • One or more polyethoxylated O / W emulsifiers and / or polypropoxylated O / W emulsifiers are provided.
  • One or more surfactants are provided.
  • such an emulsion is optically creamy or pearlescent in color.
  • the emulsifier content is 0.01 to 20% by weight, particularly preferably 0.01 to 10% by weight.
  • the glyceryl ester is glyceryl stearate or its derivative, and the ratio of glyceryl ester to fatty acid ethoxylate and / or its derivatives in the preparations according to the invention is 1: 10 to 10: 1, more preferably 1: 5 to 5: 1.
  • the ethoxylated and / or propoxylated fatty acid or alcohol has an alkoxylation degree of from 0 to 150, more preferably from 20 to 60. It is particularly preferred if the surfactant content is between 1 and 70% by weight, more preferably between 1 and 50% by weight.
  • ethoxylated and sulfated fatty alcohols with 12 to 14 and / or alkylamidopropylbetaine are used as anionic, amphoteric and / or nonionic surfactants. It is also particularly preferred if the lipid or lipids are selected from the group of ester oils, the carbonates, hydrocarbon-based oils, vegetable oils.
  • the content of the cationic care component is from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, very preferably from 0.01 to 2% by weight. It is preferred if the emulsion as further constituents opacifiers and / or Verdi contains cker and / or additional surfactants and / or cosmetic or dermatological auxiliaries, additives and / or active ingredients are included. Particularly preferred emulsions are characterized in that the viscosity is between 1000 and 10000 Pa s, measured with the Haake Viscotester VT 2 at 20 ° C. The invention also encompasses the use of one of the emulsions described for improving the gloss, combability and sensory properties of the hair and a cosmetic preparation comprising emulsions according to the invention which are suitable for hair and for the body.
  • the cosmetic cleaning compositions containing the care combinations according to the invention are topical preparations. These may additionally contain conventional active ingredients, ingredients, additives and / or adjuvants and are used for the treatment and care of the skin, scalp and / or hair.
  • the preparations of the invention are applied in the usual manner for cosmetics and hair cleansers on the scalp and hair in sufficient quantity.
  • preparations in the sense of the present invention can be present as emulsions or solutions.
  • compositions according to the invention may for example consist of squeeze bottles or preparations which can be metered by a pumping or spraying device, but also agents which can be applied in normal bottles and containers.
  • polyethoxylated or polypropylated O / W emulsifiers are advantageously selected from the group:
  • the fatty acid ethoxylates of the general formula R-COO - (- CH 2 -CH 2 -O-) n -H where R is a branched or unbranched alkyl or alkenyl radical having 5 to 30 C atoms and n is a number from 10 to 100, preferably represent 20 to 60.
  • R is a branched or unbranched alkyl or alkenyl radical having 5 to 30 C atoms and n is a number from 10 to 100, preferably represent 20 to 60.
  • They are, for example, advantageously selected from polyethylene glycol (40) stearate, polyethylene glycol (30) stearate, polyethylene glycol (40) isostearate or polyethylene glycol (25) oleate.
  • R is a branched or unbranched alkyl or alkenyl radical having 5 to 30 C atoms and n is a number from 10 to 80, preferably 10 to 30 represent.
  • They are, for example, selected from polyethylene glycol (20) stearyl ether (steareth-20), polyethylene glycol (20) isostearyl ether (isosteareth-20), polyethylene glycol (15) cetyl ether (ceteth-15) or polyethylene glycol (30) cetyl stearyl ether (ceteareth-30),
  • the polyethoxylated or polypropoxylated O / W emulsifiers used are selected particularly advantageously from the group of substances with HLB values of 8-17, very particularly advantageously with HLB values of 10-16, provided that the O / W Emulsifiers have saturated radicals R and R '. If the O / W emulsifiers have unsaturated radicals R and / or R ', or if isoalkyl derivatives are present, the preferred HLB value of such emulsifiers may also be lower or higher.
  • the w / o emulsifiers advantageous according to the invention can be used: fatty alcohols having 8 to 30 carbon atoms, monoglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular 12-18 carbon atoms, monoglycerol ethers saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 8 to 24, in particular 12-18 C-atoms, and sorbitan esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular 12 - 18 C atoms.
  • W / O emulsifiers are glyceryl monostearate, glyceryl monoisostearate, sorbitan monoisostearate, cetyl alcohol, stearyl alcohol, polyethylene glycol (2) stearyl ether (steareth-2), glyceryl monolaurate, glyceryl monocaprinate, glyceryl monocaprylate.
  • one or more oil components are advantageously present in a concentration of 0.001 to 10% by weight, preferably in a concentration of 0.01 to 5% by weight and most preferably in a concentration of 0.01 to 3% by weight, respectively based on the total weight of the preparation use.
  • the oil phase of the invention is advantageously selected from the group of esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms.
  • ester oils can be then advantageously selected from the group dicapryl carbonates, isopropyl myristate, isopropyl, with isopropyl, Isononylisononanoat, Isotridecylisononanoat, 2-Ethylhexylisostea- rat, Dicaprylylether and synthetic, semi-synthetic and natural mixtures of such esters, eg. B. jojoba oil.
  • the oil component can be advantageously selected from the group of branched and unbranched hydrocarbons and waxes, the group of saturated or unsaturated, branched or unbranched alcohols, and the fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkane - Carboxylic acids of a chain length of 8 to 24, in particular 12 to 18 carbon atoms. They are z. Dicaprylyl ethers, paraffin oil and waxes, e.g. Cetyl palmitate.
  • the fatty acid triglycerides can be selected, for example, advantageously from the group of synthetic, semi-synthetic and natural oils, for. As olive oil, sunflower oil, soybean oil, almond oil, palm kernel oil and the like.
  • the oil component is also advantageously selected from the group of phospholipids.
  • the phosphatidylcholines are, for example, the lecithins.
  • the cationic polymers are used in a concentration of 0.01 to 10% by weight, preferably in a concentration of 0.01 to 5% by weight and very particularly preferably in a concentration of 0.01 to 1% by weight. %, in each case based on the total weight of the preparation.
  • cationic polymers are: cationic cellulose derivatives synthesized based on hydroxycellulose with a trimethylammonium substituted epoxide known as
  • Polyquaternium-10 cationic polysaccharides, especially modified guar derivatives
  • Copolymers of vinylpyrrolidone and vinylmethylimidazolium salt such as Polyquaternium-44 or Polyquaternium-16.
  • Formulations according to the invention which are hair cosmetic cleansing preparations for the hair or the scalp can be present in liquid or solid form. They preferably contain at least one anionic, nonionic or amphoteric surface active substance or mixtures thereof, if appropriate an electrolyte and auxiliaries, as customarily used for this purpose.
  • the surface-active substance may be concentrated in a concentrated ration between 1 and 70% by weight in the cleaning preparations, based on the total weight of the preparations, but in particular between 1 and 50% by weight.
  • Anionic surfactants are preferably used in concentrations of between 5 and 30% by weight, based in each case on the total weight of the preparation.
  • Other anionic surfactants are acylamino acids and their salts such. As acylglutamates and / or their derivatives, sarcosinates and / or derivatives thereof, taurates and / or derivatives thereof and carboxylic acids and their derivatives and phosphoric acid esters and salts thereof.
  • Nonionic surfactants are preferably used in concentrations of 1 to 10% by weight.
  • Examples are decyl glucosides as offered under the name Oramix NS 10 by the company Seppic or polysorbates 80 as it is offered under the name Tween 80 by the company Uniqema / ICI.
  • Amphoteric tendides are preferably used at a concentration of 1 to 10% by weight.
  • Examples are cocamidopropyl betaine as it is offered as Tego betaine by the company Goidschmidt or sodium cocoamphoacetate as it is offered under the name Miranol Ultra by the company Rhone Poulene.
  • the preparations according to the invention may contain cosmetic adjuvants such as are conventionally used in such preparations, eg. As preservatives, perfumes, foam stabilizers, dyes, pigments, which have a coloring effect, thickeners, surface-active substances, lubricating agents, alcohols, polyols and their toxicologically acceptable ethers and esters, branched and / or unbranched hydrocarbons, other antioxidants, stabilizers, pH Regulators, bodying agents, bactericides, deodorants, antimicrobials, antistatic agents, UV absorbers (UV-A and UV-B filters), common antioxidants, complexing agents and sequestering agents, pearlescing agents, polymers, electrolytes, organic compounds Solvents, plant extracts, vitamins and / or other active ingredients or other common components of a cosmic or dermatological formulations.
  • cosmetic adjuvants such as are conventionally used in such preparations, eg.
  • perfumes perfumes, foam stabilizers, dyes, pigments, which have
  • the total amount of the excipients is for example 0.001 to 15% by weight, preferably 0.01 to 10% by weight, in each case based on the total weight of the preparation.
  • the water content of the preparation is for example 40 to 95 wt .-%, preferably 50 to 90 wt .-%, each based on the total weight of the preparation.
  • the pH of the preparations can be adjusted in a known manner by addition of acids or bases, preferably by addition of buffer mixtures, eg. B. based on citric acid / citrate or phosphoric phosphate buffergemsichen.
  • buffer mixtures eg. B. based on citric acid / citrate or phosphoric phosphate buffergemsichen.
  • the pH is below 10, e.g. in the range of 4 to 8, in particular in the range 5 to 7.
  • the preparation of the invention may, for. B. are manufactured as follows:
  • the components of the fat phase are weighed and melted homogeneously at about 75 ° C.
  • the components of the water phase are weighed and heated to about 75 ° C.
  • the water phase is then added in portions to the fat phase with stirring. Subsequently, the mixture is homogenized.
  • the surfactant phase is added to the emulsion after the homogenization step. If desired, further auxiliaries, additives and / or active ingredients are dissolved and added to the mixture.
  • the formed preparation is then cooled to room temperature. This is preferably done with stirring.
  • hair cosmetic conditioning shampoos examples include:
  • the pH of the shampoos is adjusted to 5-6 and the viscosity between 1000 - 10000 mPa s (Haake viscometer, VT02).
  • Homogenizer 920G Mixture of Stearyl Alcohol + Cetyl Alcohol + Ceteareth-25 + Ceteareth-15 + Myristyl Alcohol + Myreth-4.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des émulsions moussantes contenant des tensioactifs et présentant une teneur en composés siliconés de 0 à 0,001 % en poids, lesquelles émulsions contiennent au moins un acide gras éthoxylé et/ou propoxylé ou au moins un alcool gras éthoxylé et/ou propoxylé ou leur/son dérivé, au moins un ester glycérique, un ou plusieurs lipides et au moins un composant de soin cationique et éventuellement d'autres agents actifs, auxiliaires et additifs cosmétiques.
PCT/EP2007/052299 2006-03-13 2007-03-12 Émulsion lavante sans silicone pour les cheveux Ceased WO2007104740A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006011884A DE102006011884A1 (de) 2006-03-13 2006-03-13 Silikonfreie Haarreinigungsemulsion
DE102006011884.7 2006-03-13

Publications (1)

Publication Number Publication Date
WO2007104740A1 true WO2007104740A1 (fr) 2007-09-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/052299 Ceased WO2007104740A1 (fr) 2006-03-13 2007-03-12 Émulsion lavante sans silicone pour les cheveux

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DE (1) DE102006011884A1 (fr)
WO (1) WO2007104740A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1880712A3 (fr) * 2006-06-28 2008-07-30 Beiersdorf Aktiengesellschaft Composition de nettoyage et de soin des cheveux à technique sensorielle particulière
EP1872771A3 (fr) * 2006-06-28 2008-07-30 Beiersdorf AG Composition de nettoyage de soins capillaires dotée d'une technologie particulière de capteur de cheveux secs
WO2018152718A1 (fr) * 2017-02-23 2018-08-30 Beiersdorf Daily Chemical (Wuhan) Co. Ltd. Composition de shampooing sans silicone
CN108685734A (zh) * 2018-08-09 2018-10-23 广州荣创优品科技有限公司 一种无硫酸盐无硅低刺激温和植物养发香波
WO2020052913A1 (fr) 2018-09-10 2020-03-19 Beiersdorf Ag Préparation nettoyante moussante à base d'une émulsion
WO2020052914A1 (fr) 2018-09-10 2020-03-19 Beiersdorf Ag Préparation nettoyante moussante sans sulfate à base d'une émulsion

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009046869A1 (de) * 2009-11-19 2011-05-26 Henkel Ag & Co. Kgaa Haarkur ohne Silikone
TWI740604B (zh) * 2020-08-12 2021-09-21 財團法人食品工業發展研究所 油性成分微膠囊製備方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4033928A1 (de) * 1990-10-25 1992-04-30 Henkel Kgaa Oel-in-wasser-emulsionen
EP0825200A1 (fr) * 1996-08-16 1998-02-25 National Starch and Chemical Investment Holding Corporation Modificateurs rhéologiques polymériques
US20040131645A1 (en) * 2000-06-16 2004-07-08 Peter Williams Polysaccharide based gel

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DD221922A1 (de) * 1983-10-27 1985-05-08 Miltitz Chem Werk Verfahren zur herstellung von co-emulgatoren bei der emulsionsherstellung
DE4009617A1 (de) * 1990-03-26 1991-10-02 Henkel Kgaa Haarregenerierende zubereitungen
DE29902452U1 (de) * 1999-02-11 2000-06-29 Goldwell GmbH, 64297 Darmstadt Voremulsion zur Herstellung eines Haarfärbemittels
ATE272388T1 (de) * 2001-04-30 2004-08-15 Cognis Iberia Sl Verwendung von kationischen zubereitungen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4033928A1 (de) * 1990-10-25 1992-04-30 Henkel Kgaa Oel-in-wasser-emulsionen
EP0554292A1 (fr) * 1990-10-25 1993-08-11 Henkel Kgaa Emulsions d'huile dans l'eau.
EP0825200A1 (fr) * 1996-08-16 1998-02-25 National Starch and Chemical Investment Holding Corporation Modificateurs rhéologiques polymériques
US20040131645A1 (en) * 2000-06-16 2004-07-08 Peter Williams Polysaccharide based gel

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1880712A3 (fr) * 2006-06-28 2008-07-30 Beiersdorf Aktiengesellschaft Composition de nettoyage et de soin des cheveux à technique sensorielle particulière
EP1872771A3 (fr) * 2006-06-28 2008-07-30 Beiersdorf AG Composition de nettoyage de soins capillaires dotée d'une technologie particulière de capteur de cheveux secs
WO2018152718A1 (fr) * 2017-02-23 2018-08-30 Beiersdorf Daily Chemical (Wuhan) Co. Ltd. Composition de shampooing sans silicone
CN108685734A (zh) * 2018-08-09 2018-10-23 广州荣创优品科技有限公司 一种无硫酸盐无硅低刺激温和植物养发香波
WO2020052913A1 (fr) 2018-09-10 2020-03-19 Beiersdorf Ag Préparation nettoyante moussante à base d'une émulsion
WO2020052914A1 (fr) 2018-09-10 2020-03-19 Beiersdorf Ag Préparation nettoyante moussante sans sulfate à base d'une émulsion

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