WO2007028480A1 - Particles containing zeolite and perfume having improved fragrance properties - Google Patents

Abstract

The current low stability of perfumed substances in carrier particles generally limit the perfumer in the freedom thereof, in perfuming carrier particles. In particular, in the event of carrier particles containing zeolite, they often form, from perfumes whereby the fragrance is pleasant, decomposition products which can ruin the overall impression of the fragrance. The invention also relates to specific supports which contain zeolite, and which can ensure improved perfume stability.

Description

 Zeolite and perfume containing particles with improved fragrance properties

The present invention relates to zeolite and perfume containing particles containing layered hkat, wherein the ratio of zeolite which is contained in a total amount of more than 20% by weight but less than 70% by weight based on the whole particle, to Schichtsihkat It is further concerned with the use of these particles, processes for their preparation, and agents containing these particles

In textile washing, treatment and aftertreatment, it is customary today to add certain quantities of perfume to the detergents and aftertreatment agents which serve to make the washing or spouting eye itself, but also the textile good treated with the washing or spongy eye, a pleasant one Scenting The scenting of washing or remoing and post-treatment products is, apart from color and appearance, an important aspect of the aesthetic product impression and an important point in the consumer's decision for or against a specific product. For perfuming, the perfume can either be incorporated directly into the compositions or the first way determines a certain product characteristic, the second way the consumer can decide on different scent variants offered about "his" scent individually, comparable to the choice of an eau de toilette or aftershave

Perfume particles and methods for scenting washing and Spullaugen are known as such from a wide state of the art, and usually Tragermatenalien organic or inorganic nature, such as strong, silicic acids, phosphates, zeolites, Alkahsalze of polycarboxylic acids, Cyclodextnne etc be combined with fragrances and other aids

Correspondingly well-known perfume particles either require additional barrier or hull layers to fix the perfume on the carrier, or are not equally suitable for scenting detergents or cleaning agents and for direct use as the sole fragrance, for example for the clear course in a washing machine suitable

An additional problem is exhibited by fragrance particles which contain zeolite as support material. It has been observed that stability problems with respect to the perceptible scent impression often arise in the case of zeolite-containing scent substance particles, so that, for example, the scent character of a perfume particle, in particular after several weeks of storage, it changes markedly adversely, so that, for example, a first fragrant particle then smells rather bad. It is therefore to be assumed that at least individual constituents of a perfume composition, with which a corresponding zeohthhaltige particles is impregnated, during storage of the particles of at least partial Decomposition fall victim, so the originally harmonic odor picture is lost On the other hand, however, in many applications it is desirable that perfume-containing particles also contain zeolite (the zeolites play a particular role in, for example, reducing the hardness of the water together with polycarboxylates as a substitute for phosphates in detergents) Need for improved zeolite and perfume containing particles

The object of the present invention was therefore to provide particles which are distinguished by the fact that, although they contain a larger amount of zeolite, they still provide good odor stability even after several weeks of storage

It has now surprisingly been found that this object is achieved by the subject matter of the present invention, namely a particle which comprises zeolite in a total amount of more than 20% by weight, but less than 70% by weight, based on the total particle, as well as perfume which is preferably absorbed in the particle and / or adsorbed on the particle, wherein the particle according to the invention also contains phyllosilicates, with the proviso that the ratio of zeolite to phyllosilicate based on the total particle is less than 7 1 The applicant could unexpectedly find that corresponding particles that combine zeolite and layered hate in the appropriate proportions, lead to significantly improved Duftstabihtat even with several weeks of storage, whereas otherwise completely comparable particles, but which, for example, no zeolite to layer Hatskat ratio of less than 7 1 have or did not contain any layered hate cat, For example, the corresponding amount of additional zeolite, leading to greater problems with the Duftstabihtat Advantageously, the particles according to the invention also have very good powder properties, even at high parfumbeladung on, so they are good storable and do not clump

The particles according to the invention advantageously lead to a more intensive fragrance experience in the consumer, for example when washing with a detergent formulation containing the particles according to the invention. Thus, a fragrance-enhancing effect is obtained which directly affects the particles and objects in which these particles are be incorporated, for example, detergent formulations, as well as things, such as textiles, which are treated with the objects (here detergent formulation)

A further advantage of the particles according to the invention is advantageously that the scent impression resulting from the particles holds up indirectly and immediately longer. "Immediately" in this context means that the particles according to the invention as such scent over a longer period of time. "Intermediate" in this context means Objects (eg detergent design) containing the particles according to the invention have a long-lasting fragrance, and even when these objects are used (eg detergent for washing textiles) the things treated with them (here washed textile) have a longer odor It is thus advantageously achieved a fragrance-retard effect (ie the temporal extent of the scent impression) both based on the particles, as on the particles containing objects, as on the objects treated with these objects

The phyllosilicate to be used is, according to a preferred embodiment, to

(A) Zweischichtsihkate, such as preferably silicates of the kaolin and / or serpentine group, in particular Kaohnit, Dickit, Halloysit, Antigont, Lizardit and / or Chryosotil

(b) three-layered silicates, such as preferably pyrophyllite, talc, silicates of the mica group such as muscovite, the smectite group such as, in particular, montmorillonite, beidellite, hectorite, nontronite and / or saponite, the hydroghmic group, such as, for example, celadonite and Glauconite, as well as vermiculte and cholπte, such as preferably Clinochlor, Chamosit and / or Donbassit

(c) sheet silicates with alternating support structures, such as preferably the muscovite-montmorillonite mixed layer (also illite-smectite mixed layer)

(D) clay minerals with fiber structure such as preferably sepiolite and / or Palygorskit and / or

(e) non-crystalline silicates such as allophane and imogolite

Phyllosilicates are found, for example, in clay, in which generally sihcatic particles predominate. Such clay minerals, such as, for example, kaohnite, lllht, montmorillonite, inter alia, have been formed by weathering z B of feldspars. Bentonites are certain clays, which smectites, especially montmorillonite, as Bentonites can be used for the invention with advantage, so that the particles according to a preferred embodiment of phyllosilicate in the form of clay, preferably of smectite clay, in particular bentonite

It is known that the properties of the clays, in particular the bentonites, can be modified. It is possible, for example, to increase the swelling capacity of crude bentonite by exchanging the Ca for Na ions (for example activated calcium bentonite) For example, it is possible to increase the specific surface area by treatment with inorganic acids (eg, acid-activated bentonite). It is also possible, for example, to convert organophilicity by reaction of sodium bentonite with quaternary ammonium compounds (eg, organophilic bentonites) Bentone) For the purposes of this invention, the term "layer silicates", the clays of bentonites, montmorillonite, hectoetine, etc. also include the corresponding derivatives or modified substances

According to a preferred embodiment, the particle contains sheet silicate in amounts of more than 5% by weight, preferably more than 10% by weight, advantageously more than 15% by weight, more preferably more than 20% by weight, more preferably more than 25% % By weight, in particular in amounts of at least 30% by weight, based on the total particle, of phyllosilicate may also be present in even greater amounts, for example in amounts of at least 40% by weight or even at least 50% by weight

However, it may also be desirable in the context of another embodiment to limit the content of phyllosilicate more. According to such an embodiment, the particle contains less than 50% by weight, preferably less than 40% by weight, advantageously less than 35% by weight more advantageously less than 30% by weight, more preferably less than 25% by weight, even more advantageously not more than 20% by weight, of phyllosilicate, based on the total particle

Layer silicate amounts of 5 to 20% by weight, preferably of 5 to 10% by weight, based on the total particle, can be very advantageous. This corresponds to a preferred embodiment

The term perfume refers to perfumes, fragrances and fragrances. Perfume oils or fragrances may be selected from individual fragrance compounds, for example the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are, for example, benzyl acetate, Phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzylsalicylate, cyclohexylsalicylate, floramate, melusate and jasmecyclate Benzyl ethyl ether and ambroxan, for example, pay attention to the ethers , to the aldehydes z B the linear alkanals with 8-18 C atoms, citral, citronellal, citronellyloxy-acetaldehyde, cyclamen aldehyde, lilial and bourgeonal, to the ketones z B the ionone, oc-lsomethylιonon and methylcedryl ketone, to the alcohols anethole, Citronellol, eugenol, geraniol, linalool, phenylethyl alcohol hol and terpineol, the hydrocarbons mainly include the terpenes such as limonene and pinene Preferably, however, mixtures of different fragrances are used, which together produce an appealing scent

Such perfume oils may also contain natural fragrance mixtures such as those obtainable from vegetable sources, such as pine, citrus, jasmine, patchouli, rose or ylang-ylang oil. Also suitable are muscatel salvia, chamomile oil, clove oil, mehssenol , Mint oil, cinnamon leaf oil, linden blutenol, juniper berryol, vetiverol, olibanumol, galbanumol and labdanumol, as well as orange blutenol, neroliol, orange peel sol and sandalwood oil

In order to be perceptible, a perfume must be volatile, in addition to the nature of the functional groups and the structure of the chemical compound and the molecular weight plays an important role So most perfumes have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and more represent an exception Due to the different odor of odoriferous substances, the smell of one of several fragrances changes. perfume or fragrance during evaporation, wherein the odor impressions in "top note", "middle note" (middle note or body) and "base note" (end note or dry out) divided as the smell perception to a is largely based on the odor intensity, the top note of a perfume or fragrance is not only from volatile compounds, while the base note for the most part consists of less volatile, ie adherent fragrances

Adhesion-resistant fragrances which can advantageously be used in the context of the present invention are, for example, the essential oils such as angelica root aol, anisol, arnica-bleutenol, basihkumol, bayol, bergamottol, champacablutenol, noble-pine oil, noble-pine cone oil, elemiol, eucalyptus oil, fenchelol, spruce-nel-ol, galbanumol, geraniumol , Gingergrasol, guaiac woodol, gurobjalamol, helichrysumol, Ho oil, ginger oil, iolsol, kajeputol, calmusol, chamomile oil, camphor oil, kanagaol, cardamomenol, kassiaol, pine nadelol, copaivabalsamol, konanderol, spearmint oil, kummelol, kuminol, lavendelol, lemongrasol , Limetteol, mandaπnenol, mehssenol, musk kornerol, myrrh oil, clove oil, Nerohol, Niaouhol, Ohbanumol, orange oil, Oπganumol, palmarosaol, Patschuhol, Perubalsamol, petitgrainol, Pfefferol, peppermint, Pimentol, Pιne oil, rose oil, Rosmannol, Sandelholzol, Selleπeol , Spikol, Star Anisole, Turpentine Oil, Thujaol, Thymeol, Verbenaol, Vetiverol, Juniper Berberol, Werm utol, wintergrunol, ylang-ylang oil, hyssop oil, cinnamon, cinnamon blatterol, citronellol, lemon oil and cypressenol

But also the higher boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or fragrance mixtures, ie fragrances to these compounds pay the compounds listed below and mixtures of these Ambrettohd, α-Amylzιmtaldehyd, anethole, anisaldehyde , Anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, benzoic acid ethyl ester, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valenate, borneol, bomyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl alde-hyd, eugenol, eugenol methyl ether , Eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, hehotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, camphor, Karvakrol , Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone, methyl atranilate methyl ester, p-methylacetophenone, methylchavikol, p-methylcholine, methyl-.beta.-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl-n- naphthyl ketone, Muskon, .beta.-naphtholethyl ether, .beta.-naphthol methyl ether, nerol, nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxyacetophenone, pentadecanohydride, .beta.-phenylethyl alcohol, phenylacetaldehyde dimethylacetal, phenylacetic acid , Pulegone, safrol, salicylic acid isoamyl ester, salicylic acid methyl ester, salicylic acid hexyl ester, salicylic acid cyclohexyl ester, santalol skatole, ter pineol, thymen, thymol, γ-undelactone, vanilin, veratrum aldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester

Among the more readily volatile fragrances which are advantageously usable in the context of the present invention, in particular the lower-boiling fragrances of natural or synthetic origin, which can be used alone or in mixtures. Examples of more readily volatile fragrances are alkyl isothiocyanates (alkylsulfate), butanedione, limonene, Linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal

All of the aforementioned fragrances can be used alone or in a mixture according to the present invention with the advantages already mentioned

The perfume stabilizing effect of the invention relates essentially to the entire fragrance or fragrance collective

The perfume stabilizing effect also relates in particular to those fragrances or fragrances which are generally associated with stabilizing problems of perfume on support materials, in particular Zeohth. Such rather problematic fragrances are known to those skilled in the art from the daily intuition

It is usually the case that such fragrances are not incorporated into particles containing starch because of their instability. Here, the invention opens up to the skilled person an increased freedom in the use of its fragrances

Such rather problematic fragrances relate in particular to allyl alcohol esters, esters of secondary alcohols, esters of tertiary alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof. In particular, these fragrances, insofar as they are incorporated as part of a perfume composition into a long-lasting carrier, lead to significant stability issues and thus deface or even completely ruin the entire odor image

Allyl alcohol esters are the esters of allyl alcohol, which has the following structural feature: C (OH) -C =C Examples of allyl alcohol esters are in particular allylamyl glycolate, allyl anthranilate, allyl benzoate, allyl butyrate, allyl caprate, allyl caproate, allyl cinnamate, allyl cyclohexane acetate, allylcyclohexane butyrate, allyl cyclohexane propionate, allyl heptoate, allyl nonanoate , Allylsalicylat, Amylcinnamyla- acetate, Amylcinnamylformiat, Cinnamylformiate, Cinnamylacetate, cyclogalbanate, geranyl acetate, Geranylacetoacetat, geranyl benzoate, Geranylcinnamat, Methallylbutyrat, Methallylcaproat, Neryla- acetate, Nerylbutyrat, tiglat Amylcinnamylformiat, Alphamethylcinnamylacetat, Methylgeranyl, Merte- acetate, Famesylacetat, fenchyl acetate, Geranylanthranilat, Geranyl butyrate Gerany isobutyrate, geranyl caproate, geranyl caprylate, geranyl ethyl carbonate, geranyl formate, geranyl furoate, geranyl heptoate, geranyl methoxyacetate, geranyl pelargonate, geranyl phenylacetate, geranyl phthalate, geranyl propionate, geranyl isopropoxyacetate, geranyl valerate, geranyl iso-valerate, trans-2-hexenyl acetate, trans-2-hexenyl butyrate, trans-2-hexenyl caproate, trans-2-hexenylphenylacetate , trans-2-hexenylpropionate, trans-2-hexenyltiglate, trans-2-hexenylvalerate, beta-pentenylacetate, alpha-phenylallyl-acetate, prenylacetate, trichloromethylphenylcarbinylacetate and / or mixtures thereof. Allyl alcohols can lead to stability problems in zeolite-containing carriers, which have a negative effect on the odor profile of the entire perfume composition. The compositions according to the invention make it possible to better stabilize perfume compositions comprising allyl alcohol esters. The aforementioned fragrances may preferably be present in the particles according to the invention.

Examples of Esters of Secondary Alcohols (Secondary alcohols are present when two H atoms are substituted by organic radicals (R ¹ and R ² ) on the carbon atom bearing the OH group [general formulas: R ¹ -CH ( OH) -R ² ]) are, in particular, ortho-tert-amylcyclohexyl acetate, isoamylbenzyl acetate, secondary n-amyl butyrate, amylvinylcarbinyl acetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate , Isobornylvalerate, Frutene, 2-methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2-ylacetate, prenylacetate, 4-tert-butylcyclohexylacetate, verdox (2-tert-butyl) butyl cyclohexyl acetate), I vertenex (4-tert-butylcyclohexyl acetate), Violiff (carboxylic acid 4-cycloocten-1-yl methyl ester), ethenyl-iso-amyl carbinyl acetate, fenchyl acetate, fenchyl benzoate, fenchyl n-butyrate, fenchyl isobutyrate, levo-menthyl acetate, dl-menthyl acetate, menthylanethranilate, menthylb enzoate, menthyl isobutyrate, menthyl formate, levo-menthyl phenylacetate, methyl propionate, menthyl salicylate, menthyl iso-valerate, cyclohexyl acetates, cyclohexyl anthranilate, cyclohexyl benzoate, cyclohexyl butyrate, cyclohexyl isobutyrate, cyclohexyl caproate, cyclohexyl cinnamate, cyclohexyl formate, cyclohexylheptoate, cyclohexyl oxalate, cyclohexyl pelargonate, cyclohexyl phenyl acetate, cyclohexyl propionate, cyclohexyl thioglycolate, cyclohexyl valerate, cyclohexyl isovalerate, methyl methyl acetate, methyl benzyl carbinyl acetate, methyl butyl cyclohexanyl acetate, 5-methyl-3-butyl-tetrahydropyran-4-yl acetate, methyl lead, Methyl isophosphate, 2-methylcyclohexyl acetate, 4-methylcyclohexyl acetate, 4-methylcyclohexylmethylcarbinyl acetate, methylethylbenzylcarbinylacetate, 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylformate, methyl-2-methylbutyrate, methylnonylcarbinylacetate , Methylphenylcarbinylacetat, Methylphenylcarbinylanthrani- lat, Methylphenylcarbinylbenzoat, Meth ylphenylcarbinyl-n-butyrate, methylphenylcarbinyl-isobutyrate, methylphenylcarbinylcaproate, methylphenylcarbinylcaprylate, methylphenylcarbinyl cinnamate, methylphenylcarbinylformate, methylphenylcarbinylphenylacetate, methylphenylcarbinylpropionate, methylphenylcarbinylsalicylate, methylphenylcarbinyliso-valerate, 3-nonanylacetate, 3-nonenylacetate, nonanediol 2,3-acetate, nonynol acetate, 2-octanyl acetate, 3-octanyl acetate, n-octyl acetate, sec-octyl isobutyrate, beta-pentenyl acetate. alpha-phenylallyl acetate, phenylethylmethylcarbinyl iso-valerate, phenylethylene glycol diphenylacetate, phenylethylethyl carbinylacetate, phenylglycol diacetate. sec.-phenylglycol monoacetate, phenylglycol monobenzoate, isopropyl caprate, isopropyl caproate, isoporphenyl caprylate, isopropyl cinnamate, para-isopropylcyclohexanyl acetate, propyl glycol diacetate, propylene glycol collyl isobutyrate, propylene glycol dipropionate, isopropyl n-heptoate, isopropyl n-hept-1-yne carbonate, isopropyl pelargonate, isopropyl propionate, isopropyl undecylenate, isopropyl n-valerate, isopropyl n-valerate, isopropyl iso-valerate, Isopropyl sebacinate, isopulegyl acetate, isopuleglyl acetoacetate, isophenylglyhsobutyrate, isopulegylformate, thymylpropionate, alpha-methylcyclohexane-methylacetate, methylcyclohexylacetate, vanillylacetate, vanillylidene diacetate, vanillylvanilate, and / or mixtures of these These esters can lead to stability problems in vehicles containing high molecular weight The odor image of the entire perfume composition has a negative effect. The inventive compositions make it possible to better stabilize perfume compositions comprising esters of secondary alcohols. The aforementioned odoriferous substances can preferably be present in the particles according to the invention

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula R ¹ R ² R ³ C-OH)) are tertiary amyl acetate, caryophyllene acetate, cedrenyl acetate, cedryl acetate, dihydromyrcenyl acetate, dihydroterpinyl acetate, dimethylbenzyl carbamylacetate, dimethylbenzylcarbinylsobutyrate, dimethylheptenyl acetate, dimethylheptenyl formate, dimethylheptylpropionate, dimethylheptenyl isobutyrate, dimethylphenylethylcarbinylacetate, dimethylphenyl ethylcarbιnyl-ιso-butyrate, iso-valerate Dimethylphenylethylcarbmyl-, Dιhydro-nor-dιcyclopentadιenyl- acetate, Dimethylbenzylcarbinylbutyrate, Dimethylbenzylcarbmylformiat, Dimethylbenzylcarbinylpro- propionate, Dιmethylphenylethylcarbιnyl-n-butyrate, Dimethylphenyletylcarbinylformiat, dimethylphenyl ethylcarbinylpropionat, Elemylacetat, Ethinylcyclohexylacetat, Eudesmylacetat, Eugenylcinnamat, Eugenylfo rmiat, iso-eugenyl formate, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, ethyl carbonate Hydroxycitronellyl, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyl losbutyrat, Linallylcarproat, Linallylcaprylat, Lmallylcinnamat, Linallylcitronellat, Linallyl formate, Linallylheptoat, Lιnallyl-N-methyl-lanthranιlat, Linallylmethyltiglat, Linallyl pelargonat, lmallylphenylacetate, lmallylpropionate, linallylpyruvate, linallylsalicylate, vinylallyl-n-valerate, vinylallyvalvalate, methylcyclopentenolone butyrate, methylcyclopentenolonepropionate, methylethylphenylcarbinylacetate, methylheptincarbonate, methylnicotinate, myrcenylacetates, myrcenylformate, myrcenylpropionate, cis - oc- enyl acetate, phenylsahcylate, terpmyl acetate, terpinyl anthranilate, terpinyl benzoate, terpininyl n-butyrate, terphenyl-butyrate, terpinyl cinnamate, terpinyl formate, terpinyl phenylacetate, terpinyl propionate, terphenyl n-valerate, terphenyl-valerate, t-butyl acetyl citrate, and the like d / or mixtures thereof These esters can lead to stability problems in human carriers which negatively affect the odor profile of the entire perfume composition. The inventive compositions make it possible to better stabilize perfume compositions comprising esters of tertiary alcohols. The aforementioned odoriferous substances can preferably be used in the inventive compositions Be contained particles

Some esters with just such Stabihtatsproblematik can be both esters allyhscher and secondary or allyhscher and tertiary alcohols, in particular Amylvinylcarbinylacetat Amyl vinylcarbinylpropionate, hexylvinylcarbinylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, linallylbutyrate, linallyliosbutyrate, linallyl carproate, linallylcaprylate, linallylcinnamate, linallyl citronellate, linallyl formate, linallylheptoate, linallyl-N-methylanthranilate, lithium allylmethyltiglate, Linallyl pelargonate, linaline phenylacetate, linallyl propionate, linallyl pyruvate, linallyl salicylate, linallyl n-valerate, linallyl iso-valerate, myrtenyl acetate, nerolidyl acetates, nerolidyl butyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, and / or mixtures thereof. These esters can also lead to stability problems in zeolite-containing carriers, which have a negative effect on the odor profile of the entire perfume composition. The compositions according to the invention make it possible to better stabilize perfume compositions comprising these esters. The aforementioned fragrances may preferably be present in the particles according to the invention.

Allylic ketones are characterized by the following structural feature, C - C (= O) - C = C. Preferred examples are acetylfuran, allethrolone, allylionone, allylpulegone, amylcyclopentenone, benzylideneacetone, benzylideneacetophenone, alphaisomethylionone, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) 3-buten-2-one, beta damascone (1- (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), damascenone (1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) - 2-buten-1-one), Delta Damascone (1- (2,6,6-trimethyl-3-cyclohexene-1-yl) -2-butene-1-one), alpha-ionone (4- (2,6 , 6-trimethyl-1-cyclohexenyl-1-yl) -3-buten-2-one), beta-ionone (4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-butene-one) 2-one), gamma methyl ionone, (4- (2,6,6-trimethyl-2-cyclohexyl-1-yl) -3-methyl-3-buten-2-one), pulegone and / or mixtures thereof. Allylic ketones can lead to stability problems in zeolite-containing carriers, which negatively affect the odor profile of the entire perfume composition. The compositions according to the invention make it possible to better stabilize perfume compositions comprising allylic ketones. The aforementioned fragrances may preferably be present in the particles according to the invention.

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ). Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso-amyl acetal, acetaldehyde-de-pentanediol acetal, acetaldehyde di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde- phenylethyleneglycol acetal, acetaldehyde phenylethyl-n-propylacetal, cinnamaldehyde dimethylacetal, acetaldehydebenzyl-beta-methoxyethyl acetal, acetaldehyde diiso amylacetal, acetaldehyde diethyl acetal, acetaldehyde di-cis-3-hexenyl acetal, acetaldehyde di pentanediol acetal , Acetaldehyde-di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenyl-ethyleneglycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, acetylvanillin dimethylacetal, alpha-amylcinnamic aldehyde-di-iso-propyl acetal, p-tert-amylphenoxyacetaldehydediethylacetal, anisaldehyde diethyl acetal, anisaldehyde dimethyl acetal, isoapiols, benzaldehyde diethylacetate, benzaldehyde di (ethylene glycol monobutyl ether) acetal, benzaldehyde dimethyl acetal, benzaldehyde ethylene eglycol acetal, benzaldehyde glyceryl acetal, benzaldehyde propylene glycol acetal, cinnamic aldehyde diethyl acetal, citral diethyl acetal, citral dimethyl acetal, citralpropylene glycol acetal, alpha methyl cinnamic aldehyde diethyl acetal, alpha cinnamic aldehyde dimethyl acetal, phenyl acetaldehyde 2,3-butyleneglycol acetal, Phenylacetaldehydcitronellylmethylacetal, Phenylacetaldehyddiallylace- tal, Phenylacetaldehyddiamylacetal, Phenylacetaldehyddibenzylacetal, Phenylacetaldehyddibutyla- CETAL, phenylacetaldehyde, Phenylacetaldehyddigeranylacetal, Phenylacetaldehyddime- thylacetal, Phenylacetaldehydethyleneglycolacetal, Phenylacetaldglycerylacetal, Citronellalcyclo- monoglycolacetal, Citronellaldiethylacetal, Citronellaldimethylacetal, Citronellaldiphenylethylacetal, Geranoxyacetaldehyddiethylacetal and / or mixtures thereof

Acetals can lead to stability problems in human carriers, which have a negative effect on the odor image of the entire perfume composition. The compositions according to the invention make it possible to better stabilize perfume compositions comprising acetals. The aforementioned odoriferous substances can preferably be present in the particles according to the invention

Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ) Preferred examples are acetone diethyl ketal, acetonedimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals can lead to stability problems in human carriers have a negative effect on the odor profile of the entire perfume composition The compositions according to the invention make it possible to better stabilize perfume compositions which comprise ketals. The aforementioned odoriferous substances can preferably be present in the particles according to the invention

Preferred examples of condensation products of amines and aldehydes are anisaldehyde methylanthranilate, aurantiol (hydroxycitronellalmethyl anthranilate), verdantiol (4-tert-butyl-alpha-methyldihydrocmnamaldehyde methyl anthranilate), vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellaleate anthranilate, hydroxycitronellal hydrochloric antranilate, methyl N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenylmethyl-ene) -anthranilate, methylnaphthyl ketone-methyl anthranilate, methyl nonyl acetaldehyde-methyl anthranilate, methyl N- (3,5,5-t-methylhexyl) ) anthranilate, vanillin methylanthranilate and / or mixtures thereof Condensation products of amines and aldehydes can lead to stability problems in human carriers, which have a negative effect on the odor profile of the entire perfume composition. The compositions according to the invention make it possible to include perfume compositions which comprise condensation products of amines and aldehydes to better stabilize the aforementioned smell Substances may preferably be contained in the particles according to the invention

But advantageously, the perfume stabilizer can be improved not only in connection with those fragrances, which in zeohthhaltigen carriers a clear Pradisposition to instability or rather unstable (risk group), such as allylamyl glycolate and cyclogalbanate, but the perfume stabilizer can also in connection with Such other fragrances are, without wishing to be limited by the following additional payment, for example, adoxal (2,6-tri-methyl-9-undecene-1-al), amyl acetate, anisaldehyde (4-methoxy) Benzaldehydes), bacdanol (2-ethyl-4- (2,2,3-tri-methyl-3-cyclopenten-1-yl) -2-buten-1-ol), Benzaldehyde, benzophenone, benzyl acetate, Benzylsahcylat, 3-hexene-1-ol, cetalox (dodecahydro-3A, 6,6,9A-tetramethyluap.htho [2.1 B] furan), cιs-3-hexenyl acetates, cιs-3 Hexenyl salicylate, citronellol, coumarin, cyclohexyl salicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde), decyl aldehyde, ethyl vanillin, ethyl 2-methyl butyrate, ethylene brasylate, eucalyptol, eugenol, exaltolide (cyclopentadecanohd), Florhydral (3- (3-isopropylphenyl) butanal), galaxolide (1, 3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma ^ -benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitnl, helional (alpha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), heliotropin, hexyl acetate, hexyl cinnamic aldehyde, hexyl salicylate, hydroxyambrane (2-cyclododecylpropanol), hydroxycitronellal, iso E super (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1, 1, 6,7, tetramethylnaphthalene), isoeugenol, isojasmon, koavon (acetyl di-isoamylene), lauryl aldehyde , Irg 201 (2,4-Di- hydroxy-3,6-dιmethy methyl benzoate), Lyral (4- (4-hydroxy-4-methyl-pentyl) -3-cyclohexene-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol) , Mayor (4- (1-methylethyl) cyclohexanemethanol), methyl anthranilate, methyl beta naphthylketoe, methyl cedrone (methyl cedryl ketone), methyl chavicol (1-methyloxy-4,2-propen-1-yl benzene), methyl dihydro-jasmonate, methyl nonyl acetaldehyde, musk Indanone (4-acetyl-6-tert-butyl-1, 1-dimethylindane), neol, nonalactone (4-hydroxynonanone acid, lactone), norlimbanol (1- (2,2,6-trimethylcyclohexyl) -3- hexanol), PT Bucinal (2-methyl-3 (para tert butylphenyl) propionaldehyde), para hydroxyphenylbutanone, patchouli, phenylacetaldehyde, phenylethylacetate, phenylethylalcohol, phenylethylphenylacetate, phenylhexanol / phenoxanol (3-methyl-5-phenylpentanol), polysantol (3,3-dimethyl-5- (2,2,3-tri-methyl-3-cyclopenten-1-yl) -4-penten-2-ol), rosaphene (2-methyl-5-phenylpentanol), sandalwood, alpha-terpinene, tartalide / musk plus (7-acetyl-1, 1, 3,4,4,6-h examethyltetralin), undecalactone, undecabertol (4-methyl-3-decen-5-ol), undecylaldehyde, undecenealdehydes, vanillin and / or mixtures of these aforementioned fragrances may preferably be present in the particles according to the invention

If the perfume, which is preferably adsorbed in / on the particle, is at least 4, advantageously at least 5, in a further advantageous manner at least 6, more preferably at least 7, even more preferably at least 8, preferably at least 9 , in particular contains at least 10 different fragrances, so hete a preferred embodiment of the invention before

In the context of this invention particularly preferred fragrances which can be used with advantage are, in particular, dihydromyrcenol 4-tert-butylcyclohexyl acetate, tetrahydro-naphthal, methyl palmitate, methylmyπstat, methyl oleate 6-methyl-gammonone, isobornyl acetate, tartalide and / or dihydromethyl-jasmonate but especially dihydromyrcenol and / or 4-tert-butylcyclohexyl acetate. According to a preferred embodiment, preferred particles can therefore comprise at least one of the abovementioned fragrances If desired, the perfume can also be combined with a perfume fixative. It is believed that perfume fixatives can slow the evaporation of high volatile fractions of perfume

According to a further preferred embodiment, the perfume which is adsorbed in / on the carrier material comprises a perfume fixative, preferably in the form of diethyl phthalates, musk (derivatives) and mixtures thereof, the fixative amount preferably being 1 to 55% by weight, advantageously from 2 to 50% by weight, more preferably from 10 to 45% by weight, in particular from 20 to 40% by weight, of the total amount of perfume

According to a further preferred embodiment, the particles contain a viscosity of liquids, in particular perfume-increasing agent, preferably PEG (polyethylene glycol), advantageously having a molecular weight of 400 to 2000, wherein the viscosity-increasing agent in amounts of 0 in a preferred manner , 1 to 20% by weight, advantageously from 0.15 to 10% by weight, more preferably from 0.2 to 5% by weight, in particular from 0.25 to 3% by weight, based on the total particle

It has been found that the viscosity of liquids, especially perfume-increasing agents, further contribute to the stabilization of the perfume in the particle, especially when non-ionic surfactant is present at the same time

The viscosity-increasing agents are preferably polyethylene glycols (PEG for short), which can be described by the following general formula

H- (O-CH ₂ -CHz) _n -OH in the degree of polymerization n of about 5 to> 100 000, corresponding to molecular weights of 200 to 5 000 000 gmol ^"1 , may vary The products with molecular weights below 25 000 gmol ^'1 are referred to as actual polyethylene glycols, while high molecular weight products are often referred to in the literature as polyethylene oxides (PEOX for short) The polyethylene glycols preferably used may have a linear or branched structure, in particular linear polyethylene glycols are preferred, and be endgruppenverschlossen

The particularly preferred polyethylene glycols include those having relative molecular weights between 400 and 2000. Polyethylene glycols which are present in a liquid state at room temperature and a pressure of 1 bar can also be used in particular. Polyethylene glycol having a relative molecular mass of 200 is especially important here , 400 and 600 the speech As already mentioned before, the structure of a perfume composition is classified as "top note", "middle note or body" as well as "base note" (end note or dry out). The top note (Tete, The center note (Bouqet, Corps, Coeur, heart note, body) comprises essentially moderate volatiles fragrances, preferably mostly flowery character and the base note (rear, smell) comprises substantially little volatiles Fragrances, essentially determine the basic character (Leitgeruch) of the perfume So that means that the top note essentially the first phase of the scent process of a perfume or scented with the perfume agent, such as a detergent determines her comes the crucial role in the first impression the smell experience, ie B when opening the detergent pack and when filling the detergent in the Waschmas Essentially, the top note is intended to attract attention and interest in the perfume and thus the perfumed therefrom, which is why it is essentially a mixture of light volatiles, although in some cases notes of the heart and base are already present in the first fragrance phase Role play typical ingredients of the top note are, for example, the Agrumenole, fruit notes, lavender, Dihydomyrcenol or rose oxide. The skilled person knows a variety of other ingredients from the daily view or can refer to the relevant technical literature

The second, middle phase of the perfume process of a perfume or perfume scented agent, such as a detergent, is determined by the heart note. This is preferably formed by a mixture of rounder, more complex notes that give a perfume fullness, character and a particular perfume For example, it can be dominated by floral components such as lily-of-the-valley, jasmine or rose. In addition, many of the spicy components of a perfume such as eugenol (essential carnation fragrance) can be found here. The expert knows a multitude of further components from daily intuition or can take these from the relevant literature

The base note of the perfume (with which, for example, a detergent is perfumed) determines the character of the fragrance. It adheres very well to the fragranced objects and is essentially composed of heavier, warmer notes. For example, you can use a precious wood base with isolated odor carriers from other woods and woods For example, it can also be combined with musk fabrics and / or an animal complex and predestined base notes such as patchouli and vanilla

On the basis of this general purpose fragrance concept, the perfume compositions are generally created with a complex composition of even several hundred individual components. Experience has shown that only a well-balanced mixture of many components (for example at least 15 or 10, in many cases at least 30 or 50) or even more) to perfumistic success, ie to a fragrance On the one hand, it is clear that essentially the degeneration (ie the degeneration, the degradation, the decomposition) of one or at least a few fragrances is sufficient to provide the overall harmonic structure of an entire perfume composition ruinieren Already the odor reduction of only one note, so top note, middle note or base note significantly reduces the odor value of the whole perfume composition or even destroy it completely Against this background, the successful perfuming inexpensive commodity, such as detergent or cleaning agent, a venture, The perfume compositions have to be adapted to the most varied, aggressive media and fundamentals. In the field of detergents, for example, their alkalinity is highly problematic for many perfume compositions, as is the use of long-lasting tablets The present invention now allows the perfumer a whole new spectrum of perfumery possibilities in the scenting of washing or cleaning agents over zeohthhaltige particles as Dufttrager The skilled person can now also use such fragrances, which earlier due to their instability in zeohthhaltigen carriers not in He can now make the top note, middle note and / or base note of a perfume composition even freer and even more individualized. He can now also weight relatively unstable fragrances in the perfume compositions quantitatively higher

According to a preferred embodiment, the notes of the perfume composition contained in the inventive particles differ with regard to their quantitative weighting, wherein preferably

(a) the headnote is weighted higher in terms of quantity than the middle note and the base note, wherein the two lower-weighted notes may be substantially equally weighted to one another or one of the lower-weighted notes is weighted higher than the other, or

(b) the middle note is weighted quantitatively higher than the top note and base note, wherein the two lower weighted notes may be substantially equally weighted to each other or one of the lower weighted notes is weighted higher than the other, or

(c) the base note is weighted quantitatively higher than the top note and middle note, wherein the two lower-weighted notes may be substantially equally weighted to each other or one of the lower-weighted notes is weighted higher than the other

One grade being weighted quantitatively higher than another means that the total mass of fragrances forming the high weighted note is greater than the total mass of fragrances forming the lower weighted note, advantageously at least 10% by weight, preferably at least 20% by weight. , in particular at least 30% by weight, based on the total mass of the total perfume composition According to another preferred embodiment, all notes of the perfume composition are weighted substantially equally.

As has already been emphasized, the present invention allows the person skilled in the art a greater freedom of action in the scenting of zeolite-containing particles, thus making it possible to produce zeolite-containing particles with further refined scent notes. For this purpose, the particle according to the invention according to a preferred embodiment, in particular fragrances with

(a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 5-methylfurfural, methylbutanal, furfural and / or acetophenone or

(b) apple-like odor, such as preferably (S) - (+) - ethyl 2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-da mascone, heptyl-2- methyl butyrate, methyl 3-methyl butanoate, 2-hexenal pentyl methyl butyrate, ethyl methyl butyrate and / or methyl 2-methyl butanoate or

(c) apple peel-like odor, such as preferably ethyl hexanoate, hexyl butanoate and / or hexyl hexanoate or

(d) apricot-like odor, preferably γ-undecalactone, or

(e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or

(f) bitter almond-like odor such as preferably 4-acetyltoluene or

(g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or

(c) citrus-like odor, preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cube level, (Z) -liminene oxide, cis-6-ethenyl-tetrahydro-2,2, 6-trimethylpyran-3-ol, cis-pyranoidlinalooloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-Farneses, (Z) -oximes, (E) -liminene oxide, dihydrotypinyl acetate , (+) - limonene, (epoxymethylbutyl) -methylfuran and / or p-cymene or

(i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or

(j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 ( 3H) -one, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or

(k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or

(I) flower-like odor, preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide. Epoxylmalool, Phytol, 10-epi-γ-Eudesmol. Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone. Hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) - Ocimene, cetyl alcohol, nerohdol, ethyl (E) -cnamein, elemicin, pinocarveol, α-biprodol, (2R, 4R) -tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) isoelemιcιn, methyl 2-methylpropanoat, Tπmethylphenylbutenon, 2-Methylanιsol, ß-Farnesol, (E) isoeugenol, nitro-phe- nylethan, Ethylvanillat, 6-methoxyeugenol, linalool, ß-ionone, Tπmethylphenylbutenon, Ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or

(m) freshness odor, preferably methylhexanoate, undecanone, (Z) -immunoxymet, benzylacetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, .beta.-elemene, .alpha.-zigen-alkenes, (E) -limesonoxide, (E) -p-mentha- 2,8-dien-1-ol, menthone, Pipeπton, (E) -3-hexenol and / or carveol or

(n) Fruit odor, such as ethylphenyl acetate, geranyl valerate, γ-heptalactone, ethyl propionate, diethyl acetal, geranyl butyrate, ethyl heptylate, ethyloctanoate, methylhexanoate, dimethylheptylate, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, lobutylacetate, ethoxypropanol, ethylamine 2-butenal, methylonanedione, linalyl acetate, methyl geranate, ammonium oxide, hdrocinnamic alcohol, ethylsuccinate, ethylhexanoate, ethylmethylpyrazine, β-cbene, nylate, cetronellylbutyrate, heyl acetate, nonyl acetate, butylmethyl butyrate, pentenal, isopentyldimethylpyrazine, p-menth-1-ene 9-ol, hexadecanone, octyl acetate, γ-dodecalactone, epoxy-β-ionone, ethyloctenoate, ethylisohexanoate, isobornylpropionate, cedrenol, p-menth-1-en-9-yl acetate, cadinadiene, (Z) -3-hexenyl - hexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone, 3,5-Octadιenon, methylcyclohexanecarboxylate, 2-pentylthiophene, α-Ocιmene, butanediol ethylvalerate, pentanol, isopipentone, Butyloc- tanoat, Ethylvanillat, methyl butanoate, 2-Mmethylbutylace propylhexanoate, butylhexanoate, isopropylbutanoate, spathulenol, butanol, δ-dodecalactone, methylquinoxalm, sesquipellandans, 2-hexenol, ethylbenzoate.isopropylbenzoate, ethyllactate and / or citronellylisobutyrate or

(o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadιenal, octadienone and / or o-xylene or

(p) grape-like odor such as preferably ethyl decanoate and / or hexanone or

(q) grapefruit-like odor, such as preferably (+) - 5,6-dimethyl-8-isopropenyl-cyclo [4 4 0] dec-1-en-3-one and / or p-menthenethol or

(R) grassy odor such as preferably 2-Ethylpyrιdιn, 2,6-Dmethylnaphthalen, hexanal and / or (Z) -3-hexenol or

(s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenalcis Linalool, pyranoxide, nonanol, alpha, γ-dimenthylallylalcohol, (Z) -2-penten-1-ol, (Z) -3-hexenylbutanoate isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) 4-decenal, 2-octenal, 2-hepten-1-al bicyclo mermose, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadione, fucoserrate hexenyl acetate, Geranylacetone, valencene, β-eudesmol, 1-hexenol, (E) -2-undecenal, artemisia ketone, vindiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadalenal butylisothiocyanate, 2-pentanol, elemole, 2- Hexenal, 3-Hexenal, (+) - (E) -lmonenoxιd, cis-isocitral, Dimethyloctadienal, Bomylformiat boron nylisovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, (+) - cis-rose oxides, menthone, coumarin, (epoxymethylbutyl) -methylfuran, 2-hexenol, (E) - 2-hexenol and / or carvyl acetate or

(t) Green Tea-like odor, preferably (-) - Cubenol or

(u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides ,. Methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisaboil, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol, i. Δ. Θ, θ-tetramethyl- -oxabicyclododeca- y-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1 -ene-9-yl acetate, dehydrocarveol, Artemisia alcohol, γ-muurolene, Hydroxypentanone, (Z) -oximes, β-elemene, δ-cadinol, (E) -β-ocimene, (Z) -dihydrocarvone, α-cadinol, calamine, (Z) -piperitol. Lavandulol, β-bourbonone, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) benzene-ethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p 2-menthen-1-ol, α-curcumene, spathulenol, sesquiphellandrene, citronellyl valerate, bornyl isovalerate, 1, 5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or hydroxycalmenes or

(v) honey-like odor, preferably ethyl cinnamates, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenones, ethyl (E) cinnamate, 2-phenylethyl alcohol, citronellyl valerates, phenylethyl benzoates and / or eugenol or

(w) Hyacinth-like odor, preferably Hotrienol or

(x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or

(y) lavender-like odor, preferably linalyl valerate and / or linalool or

(z) lemon-like odor, preferably neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1, 8-cineol and / or α-terpinene or

(aa) lily-like odor, preferably dodecanal or

(bb) magnolia-like odor, preferably geranylacetone or

(cc) mandarin-like odor, preferably undecanol or

(dd) melon-like odor, preferably dimethylheptenal or

(ee) minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7a-tetrahydro-3,6-dimethylbenzofuran, epoxy-p-menthene, geranial, (methylbutenyl) -methylfuran , Dihydrocarvyl acetate, β-cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (+) - limonene. Dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, isopulegyl acetate, piperone, 2,3-dehydro-1, 8-cineole, α-terpineol, DL-carvone and / or α-phellandrene or

(ff) Nutty odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrrolidine or

(gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or

(hh) orange peel-like odor, preferably decanal and / or beta-carene or (ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or

(jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or

(kk) Pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or

(II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or

(mm) plum-like odor, preferably benzyl butanoate, or

(nn) raspberry-like odor, preferably β-ionone or

(oo) Rose-like odor, preferably β-phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2- methyl-1-propenyl) -2,5-cis-2H-pyran, isogermanone, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or

(pp) spearmint-like odor, preferably carvylacetate and / or carveol, or

(qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or

(rr) Sweetish odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methyl hexanoate, linalyl isovalerate, undecaned aldehyde, caryophyllene oxide, linalyl acetate, safranal, unlicene, phenylethanal, p-anisaldehyde, eudesmol, ethylmethylpyrazine, citronellyl butyrate, 4-methyl 3-penten-2-one, nonyl acetate, 10-epi-γ-eudesmol, β-metabolol, (Z) -6-dodecen-γ-lactone, β-famesenes, 2-dodecenal, γ-dodecalactone, epoxy-β -ionone, 2-undecenal, styrene glycol, methyl furaneol, (-) - cis-rose oxide, (E) -β-octenes, dimethylmethoxyfuranone, 1,8-cineols, ethylbenzaldehyde, 2-pentylthiophene, α-farnesene, methionol , 7-methoxycoumarin, (Z) -3-hexenyl-2-methylbutanoate, o-aminoacetophenone, vindiflorol, isopiperitones, β-sinensal, ethyl vanillate, methylbutanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone , Sesquiphellandren, diethyl malate, linalyl butyrate, guaiacol, coumarin, methyl benzoate, isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or furfura l or

(ss) Vanilla-like odor, preferably vanillin. Methyl vanillate, acetovanillon and / or ethyl vanillate or

(tt) watermelon-like odor, preferably 2,4-nonadienal or

(uu) woody odor, preferably α-muurolens, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ E-edermol, germacrene B, trans-sabin hydrate, dihydrolinalool, isodihydrocarveol, β-farnesene, β-sesquiphellandrene, δ-elemene, α-calacorene, epoxy-β-ionone, germacrene D, bicyclogermeterrenes, alloaromadendrene, α-thujene , oxo-β-ionone, (-) - γ-elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol. α-cadinol, δ-cadenines, 4,5-dimethoxy-6- (2-propenyl) -1,3-benzodioxole, [1ar- (1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro- 1, 1, 7-trimethyl-4-methylene-1H-cycloprop [e] azulen, α-gurdyen, guaiol, α-farnesene, γ> Selinene, 4- (1-methylethyl) -benzenemethanol, Penllen, Elemol, α-Humulenes, ß-Caryophyllene and / or ß-Guaιene or (vv) mixtures of the aforementioned contain aforementioned Fragrances may preferably be included in the particles according to the invention The perfume stability also be further improved according to the invention in connection with the aforementioned fragrances

An essential constituent of the particles according to the invention is the zeolite, which is present in an amount of more than 20% by weight, but less than 70% by weight, based on the total particle. Within this stated range, certain upper and / or lower limits may be used be used advantageously

In a preferred embodiment, the particle contains certain minimum values of zeolite, namely at least 22% by weight, advantageously at least 25% by weight, in a considerably advantageous manner at least 28% by weight, more preferably at least 31% by weight, more advantageously At least 34% by weight, more preferably at least 36% by weight, very advantageously at least 38% by weight, in a particularly advantageous manner at least 40% by weight, most preferably at least 42% by weight substantially advantageously at least 44% by weight, very advantageously at least 46% by weight, in an extremely advantageous manner at least 48% by weight, most advantageously at least 50% by weight, in an extremely advantageous manner at least 52% by weight, in exceptional preferably at least 54% by weight, in an exceptionally advantageous manner at least 56% by weight, in an extremely advantageous manner at least 58% by weight, in particular e at least 60% by weight of zeolite based on the total particle

The maximum amount of zeolite can also be advantageously adjusted. According to another preferred embodiment, it may therefore be advantageous for the particle not to exceed certain maximum amounts of zeolite, ie less than 68% by weight, advantageously less than 66% by weight, considerably more advantageously Way less than 64% by weight, more preferably less than 62% by weight, more preferably less than 60% by weight, even more advantageously less than 58% by weight, most preferably less than 56% by weight; %, more preferably less than 54% by weight, most preferably less than 52% by weight, considerably less than 50% by weight, and quite advantageously less than 48% by weight, extremely high advantageously less than 46% by weight, most advantageously less than 44% by weight, most advantageously less than 42% by weight, and most advantageously less than 40% by weight, in an exceptionally advantageous manner less than 38% by weight, most advantageously less than 36% by weight, in particular less than 34% by weight of zeolite, based on the total particle Overall, it is advantageous if the amount of zeolite is within the values previously mentioned minimum and maximum amounts, ie, for example, in a range of at least 25% by weight but less than 68% by weight Zeohth or in one region after another possible combination of the above values

In a preferred embodiment, the particle contains certain minimum values of perfume, namely at least 1% by weight, advantageously at least 2% by weight, in an appreciably advantageous manner at least 3% by weight, more preferably at least 4% by weight, more advantageously At least 5% by weight, more preferably at least 6% by weight, very advantageously at least 7% by weight, in a particularly advantageous manner at least 8% by weight, most preferably at least 10% by weight substantially advantageously at least 11% by weight, very advantageously at least 12% by weight, very advantageously at least 13% by weight, most advantageously at least 14% by weight, most advantageously at least 16% by weight, in an exceptionally advantageous manner At least 18% by weight, in an exceptionally advantageous manner at least 20% by weight, in an extraordinarily advantageous manner at least 22% by weight, in particular at least 24% by weight of perfume, based on the total particle

Advantageously, the particles according to the invention are capable of absorbing very large amounts of perfume without impairing the good powder properties such as tackiness. Clumping advantageously does not occur. Surprisingly, the perfume stabilizer in the zeohthhaltigen particle is also at high perfume loading, ie at perfume quantities of at least 5 wt %, at least 10% by weight, at least 15% by weight, at least 20% by weight, etc., based on the total particle, very well ensured

In a preferred embodiment, the particle contains nonionic surfactant, preferably selected from the group of the alkoxylated alcohols, the alkylphenol polyglycol ethers, the alkoxy-hindered fatty acid alkyl esters, the Polyhydroxyfettsaureamide, the alkyl glycosides, the Alkylpolyglucoside, the amine oxides and / or the long-chain alkyl sulfoxide, especially in an amount of at least 0.1% by weight, based on the total particle

The particle is preferably impregnated with the nonionic surfactant, ie the nonionic surfactant is advantageously distributed essentially in the carrier material

If the particles contain nonionic surfactant, then this advantageously leads to an even more intensive fragrance experience for the consumer, for example, when washing with a detergent formulation containing the particles according to the invention. The consumer can therefore advantageously perceive a more intense scent of the washed laundry compared to laundry. those with a conventionally perfumed detergent formulation Even though the absolute amount of the perfume contained was the same, here is a fragrance-enhancing effect which directly affects the particles as well as objects into which these particles are incorporated, for example detergent formulations, as well as things such as textiles treated with the objects (here detergent formulation)

A further advantage of the particles according to the invention, which also contain nonionic surfactant, is surprisingly that the perfume component incorporated in the particle is further stabilized. Perfume decomposition tendencies are thus further suppressed, thus further enhancing the perfume-stabilizing effect of the invention Particles is incorporated into an object, such as in a detergent formulation, which by their object property, such as their alkalinity, rather detrimental to the stability of perfume Again, the additional perfume stabilizing effect further improving

A further advantage of the particles according to the invention, which additionally contain nonionic surfactant, is that, surprisingly, the odor impression resulting from the particles indirectly and directly persists even longer. "Immediately" in this context means that the particles according to the invention smell as such over a relatively long period of time "Indirect" in this context means that objects (eg detergent formulation) containing the particles according to the invention have a longer odor and that even when these objects are used (eg detergent formulation for washing textile) the items treated therewith (here washed textile) long smell

Thus, the fragrance retardation according to the invention is even further enhanced, whereby this fragrance-retard effect (ie the temporal extent of the fragrance impression) relates both to the particles and to the objects containing the particles and to the objects treated with these objects

Surprisingly, another advantage of the particles according to the invention, which also contain nonionic surfactant, is that the addition or presence of nonionic surfactant makes it possible to load the carrier material of the particles with even larger amounts of particles. This is above all else This is surprising because one should assume that the amount of perfume that can be absorbed by the tragermatenal had to decrease if the carrier material additionally had to absorb a certain amount of another substance. However, a further improvement, in particular even a maximization of the perfume absorption capacity of the carrier material, is achieved a perfume loading of the carrier material becomes possible to an even greater extent

The usable amount of nonionic surfactant can be adjusted in an advantageous manner

In a preferred embodiment, the particle according to the invention advantageously contains at least 0.2% by weight, more preferably at least 0.3% by weight, even in a more advantageous manner. at least 0.4% by weight, more preferably at least 0.5% by weight, even more preferably at least 0.6% by weight, very advantageously at least 0.7% by weight, in a particularly advantageous manner at least 0.8% by weight, in a particularly advantageous manner at least 0.9% by weight, in a considerably advantageous manner at least 1.0% by weight, in a very advantageously advantageous manner at least 1.1% by weight, in an extremely advantageous manner at least 1.2% by weight, most advantageously at least 1.3% by weight, very advantageously at least 1.4% by weight, in an exceptionally advantageous manner at least 1.5% by weight, in an exceptionally advantageous manner at least 1.6 % By weight, in an extremely advantageous manner at least 1.7% by weight, in particular at least 1.8% by weight, of nonionic surfactant, based on the total particle

According to another preferred embodiment, however, it may also be advantageous that the particle does not exceed certain maximum amounts of nonionic surfactant, ie less than 30% by weight, advantageously less than 26% by weight, and considerably advantageously less than 24% by weight. , more preferably less than 22% by weight, more preferably less than 20% by weight, even more advantageously less than 18% by weight, most preferably less than 16% by weight, most preferably less less than 12% by weight, in a particularly advantageous manner less than 11% by weight, very advantageously less than 10% by weight, most advantageously less than 9% by weight, %, most advantageously less than 8% by weight, most advantageously less than 7% by weight, most advantageously less than 6% by weight, in exceptionally advantageous Way less than 5% by weight, most advantageously less than 4% by weight, in particular less than 3% by weight of Zeohth, based on the total particle

According to a further preferred embodiment, alkoxylated alcohol is present at least partially as nonionic surfactant, preferably in amounts of at least 40% by weight, advantageously of at least 50% by weight, more preferably of at least 60% by weight, in an extremely advantageous manner of at least 70% by weight, more preferably at least 80% by weight, in particular at least 90% by weight, most advantageously in amounts of 100% by weight, based in each case on the total amount of nonionic surfactant contained in the particle, which are advantageously ethoxy-substituted especially primary alcohols having preferably 8 to 20, in particular 12 to 18 carbon atoms and preferably on average 1 to 12 moles of alkylene oxide, preferably ethylene oxide, per mole of alcohol

According to a further preferred embodiment, the nonionic surfactants are a mixture of at least two different nonionic surfactants, preferably of at least two different alkoxylated, advantageously ethoxylated, in particular primer ren alcohols, wherein the distinguishing feature with respect to the alkoxylated alcohols is preferably in the degree of alkoxylation

If in this mixture of at least two different nonionic surfactants at least one alkoxylated, preferably ethoxylated alcohol having a degree of alkoxylation of less than 7, advantageously not greater than 6, more preferably not greater than 5, in particular not greater than 4.5 and at least one other alkoxylated , Advantageously ethoxylated alcohol having a degree of alkoxylation of at least 7 before, then it is a further preferred embodiment of the invention

In accordance with a further preferred embodiment of the invention, the ratio of lower alkoxylated alcohol to higher alkoxylated alcohol is in the range from 5 to 1, preferably from 4 to 1, advantageously from 3 to 1, in particular from 2 to 1

According to a further preferred embodiment, the Zeohth is preferably Zeohth X, Y, A, P, MAP and / or mixtures thereof. The Zeohth should preferably be less than 25% by weight, advantageously less than 20% by weight, more advantageously Way less than 15% by weight, more preferably less than 8% by weight, in particular less than 5% by weight of desorbable water. Such Zeohth can be obtained, for example, by treating the zeolite at temperatures of 150 ° C. to 350 ° C, if necessary at reduced Drudk (advantageously from about 0.001 to about 20 Torr) activated or dehydrated Then one speaks of activated / dehydrated Zeohth

According to the invention, the ratio of zeolite to phyllosilicate in the particle according to the invention is less than 7. According to a preferred embodiment, the ratio of zeolite to phyllosilicate is less than 6 l, preferably less than 5 l, advantageously less than 4 l, in particular less than 3 l

According to a further preferred embodiment, the particle according to the invention contains a polymeric clay flocculating agent, the clay flocculating agent being a polymer or a copolymer which is preferably derived from monomers chosen from ethylene oxide, acrylamide, acrylic acid, dimethylaminoethyl methacrylate, vinyl alcohol, vinylpyrrolidone, ethyleneimm and mixtures thereof, in particular having a weight average molecular weight of 100,000 to 10 million, preferably in the range of 0.005% to 20% by weight, based on the layered silicate contained in the particle

Advantageously, the fabric-softening phyllosilicates are deposited even more efficiently on the fabric during the washing process. The deposition is increased and proceeds evenly more uniformly In a preferred embodiment, the polymeric clay flocculating agent is obtained from monomers selected from ethylene oxide, acrylamide and acrylic acid

In a preferred embodiment, the polymeric clay flocculant has a weight average molecular weight of from 150,000 to 5 million, preferably from 150,000 to 800,000

In a preferred embodiment, the polymeric clay flocculating agent has a molecular weight of 150,000 to 800,000. In another preferred embodiment, the clay flocculating agent has a molecular weight of 800,000 to 5 million

According to a preferred embodiment, the polymeric clay flocculant is present in an amount of 0.005% by weight to 10% by weight, preferably 0.005% by weight to 5% by weight, in particular 0.005% by weight to 2% by weight, based on the layered silicate

Preferably, the particle according to the invention may also contain other ingredients and according to a preferred embodiment the particle contains cationic surfactant, zwitterionic compounds, ampholytes, amphoteric surfactants, betaines, cationic polymers and / or amphoteric polymers. In the presence of such substances, a further improved object scenting can be achieved by using the particles This means that if, for example, textile objects are washed with a detergent which contains such particles according to the invention, then it can be achieved that even more fragrance remains attached to the textile objects and there lingers even longer

According to a preferred embodiment, the particle contains at least one quaternary ammonium compound, preferably an alkylated quaternary ammonium compound, in particular in amounts of from 0.1% by weight to 30% by weight, based on the total particle

According to a preferred embodiment, the particle contains a quaternary ammonium compound of the formula (I),

(I) R ¹ (R ² ) (R ³ ) (R ⁴ ) N ⁺ X, wherein R ¹ , R ² and R ^{3 are} independently selected from C ₁ -C ₄ alkyl, C ₁ -C ₄ hydroxyalkyl , Benzyl and - (C ₂ H ₄ O) _x H, where x is 2 to 5, and wherein R ^{4 is} C ₈ -C ₂₂ alkyl, and where X ^"is an anion, preferably a halide, methosulfate , Methophosphat- or phosphate ion and mixtures thereof

According to a preferred embodiment, the particle contains a quaternary ammonium compound of the formula (II),

(II) R ⁵ R ⁶ _n R ⁷ _{3 n} N ^* X wherein R ^{5 is} a C ₆ -C ₂₄ alkyl or alkenyl wherein each R ^{6 is} independently a - (C _π H _2n O) _x R ⁸ group, where n is 1 to 4 and x is 1 to 14 and wherein R ^{8 is} a methyl, ethyl or preferably a hydrogen, and wherein each R ^{7 is} independently a C ₁ -C ₁₂ alkyl or alkenyl group, with m being 1 to 3, and wherein X- is an anion, preferably a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof In a preferred embodiment, R ^{6 is} a -CH ₂ CH ₂ OH, R ⁷ is independently of one another a C ₁ -C ₄ -alkyl radical, with m is 1 or 2, and wherein R ^{5 is} a linear C ₆ -C ₁₄ alkyl group

According to a preferred embodiment, the particle contains a Cβ-C ₁₆ -alkyl-dι (hydroxyethyl) - methyl ammonium compound, preferably a C ₁₂ -C ₁₄ alkyl-dι (hydroxyethyl) -methyl ammoni- um Verbιndung, and / or a C ₈ -C ₁₆ -alkyl (hydroxyethyl) -dιmethyl ammonium- compound, preferably a Ci ₂ -C ₁₄ alkyl (hydroxyethyl) -dιmethyl ammonium- compound, in particular the respective halides, Methosulfate-, Methophosphate- or phosphates and Mixtures of these

Zwitterionic compounds can also be used with advantage. According to a preferred embodiment, the particle contains a zwitterionic compound of the formula (III)

R ¹⁰ R ⁹ - (COY) _a (CH ₂ ) _b - N ⁺ - (CH ₂ ) _C - X ^" (III)

^.

wherein the R ⁹ stands for a C _{6 28} alkyl or alkenyl group, and wherein R ¹⁰ and R ¹¹ each, independently of one another, C _{1 to 4} alkyl groups, and wherein a represents the number 0 or 1, b and c are each , independently of one another, are selected from integers from 1 to 4, and wherein Y is oxygen or nitrogen, and wherein X is an atom or atomic group having a negative charge. The negative charge is mostly localized to oxygen atoms by donating a proton of Carboxy or sulfo groups, phosphoric acid residues, acidic phenolic or enolic hydroxy groups

According to a preferred embodiment, the particle contains at least one alkylamidoalkylene-dimethylcarboxylic acid betaine of the formula (IV)

CH ₃

R ¹² - CONH (CH ₂ ) _d - N ^* - (CH ₂ J ₆ - COO (IV) i CH ₃ where d and e, independently of one another, are integers from 1-4, preferably d is 2 or 3 and e is 2 or 3 and wherein R ¹² stands for a C1 _{0 18} alkyl chain or mixtures thereof Also cationic nitrile can be used with advantage According to a preferred embodiment, the particle contains at least one cationic nitrile of formula (V)

R ¹³ R ¹ * -N ⁺ - (CH ₂ ) -CN X- (V)

Ä ^» in the R ¹³ for -H, -CH ₃ , a C ₂ . ₂₄ alkyl or alkenyl, a substituted C ₂ . ₂₄ alkyl or alkenyl radical having at least one substituent from the group -Cl, -Br, -OH, -NH ₂ , -CN, an alkyl or Alkenylarylrest with a C _{1 24} alkyl group, or a substituted alkyl or Alkenylarylrest with a Ci. ₂₄ alkyl group and at least one further substituent on the aromatic ring, R ¹⁴ and R ^{15 are} independently selected from -CH ₂ -CN, -CH ₃ , - CH ₂ -CH ₃ , -CH ₂ -CH ₂ -CH ₃ , -CH (CH ₃ ) -CH ₃ , -CH ₂ -OH, -CH ₂ -CH ₂ -OH, -CH (OH) -CH ₃ , -CH ₂ -CH ₂ -CH ₂ -OH, -CH ₂ - CH (OH) -CH ₃ , -CH (OH) -CH ₂ -CH ₃ , - (CH ₂ CH ₂ -O) _n H where n is 1, 2, 3, 4, 5 or 6 and X ^"is an anion In this case, X- in a preferred embodiment is an anion which is selected from the group consisting of chloride, bromide, iodide, hydrogensulfate, methosulfate, lauryl sulfate, dodecylbenzenesulfonate, p-toluenesulfonate (tosylate), cumene sulfonate or xylenesulfonate or mixtures thereof

According to a preferred embodiment, the particle contains at least one cationic nitrile of the formula (VI)

R ¹⁶ R ¹⁷ -N ⁺ - (CH ₂ ) -CN X- (VI)

in which R ¹⁶ , R ¹⁷ and R ^{18 are} independently selected from -CH ₃ , -CH ₂ -CH ₃ , -CH ₂ -CH ₂ -CH ₃ , -CH (CH ₃ ) -CH ₃ , wherein R ¹⁶ additionally also can be -H and X is an anion, preferably R ¹⁷ = R ¹⁸ = -CH ₃ and in particular R ¹⁶ = R ¹⁷ = R ¹⁸ = -CH ₃ and compounds of the formulas (CH ₃ ) ₃ N ⁽⁺⁾ CH ₂ -CN X ^" , (CH ₃ CH ₂ ) ₃ N ⁽⁺⁾ CH ₂ -CN X ^" (CH ₃ CH ₂ CH ₂ ) ₃ N ⁽⁺⁾ CH ₂ -CN X ^" , (CH ₃ CH (CH ₃ )) ₃ N ⁽⁺⁾ CH ₂ -CN X ^" , or (HO-CH ₂ -CH ₂ ) ₃ N ⁽⁺⁾ CH ₂ -CN X are particularly preferred. In one preferred embodiment, X ^'is an anion, which is selected from the group consisting of chloride, bromide, iodide, hydrogensulfate, methosulfate, laurylsulfate, dodecylbenzenesulfonate, p-toluenesulfonate (tosylate), cumene sulfonate or xylenesulfonate or mixtures thereof

Amides can also be used with advantage. According to a preferred embodiment, the particle contains an amide, preferably an amide of the formula R ₁₉ R ₂₀ NCOR ₂₁ , in which R ₁₉ and R ₂₀ independently of one another are C ₁ -C ₂₂ -alkyl, dC ₂₂ alkenyl, C ₁ -C ₂₂ hydroxyalkyl aryl and alkyl aryl groups are selected, R _{21 is} hydrogen or a C ₁ -C ₂₂ -A ^ yI, dC ^ alkenyl, aryl or alkyl Aryl group, or QR ₂₂ in which R _{22 is} a C ₁ -C ₂₂ -alkyl-C ₂₂ alkenyl, an aryl group or alkyl-aryl group, wherein the amide is contained in particular in amounts of 1% to 10%, based on the total particle

Imιdazolιn (derιvate) can be used with advantage According to a preferred embodiment, the particle contains Imιdazolιn (deπvate), preferably Imidazohne the formula 1- (R ₂ 3) Amιdo (R ₂ 4) -2- (R ₂ 5) imidazoline, wherein R ₂₃ , R _{25 are} independently selected from C ₁₂ -C ₂₂ -alkyl and R _{24 is selected} from C ₁ -C ₄ -alkyl, in particular in amounts of 1% by weight to 10% by weight, based on the total particle

Organic humectants may also be used to advantage since they lead to a more efficient deposition of the textile-softening phyllosilicates on the textiles. According to a preferred embodiment, the particle contains organic humectants, in particular glycine, ethylene glycol, propylene glycol, dimers and trimers of glycene and / or mixtures of which is selected, preferably in amounts of from 0.1% by weight to 30% by weight, based on the total particle

Complexing agents may also be used to advantage. According to a preferred embodiment, the particle contains a complexing agent, preferably phosphonate and / or a citrate, in particular in amounts of from 0.1% by weight to 10% by weight, based on the total particle

Pentaerythritol (derivevates) can also be used to advantage since they further improve the washing-softening effect, eg the phyllosilicates. According to a preferred embodiment, the particle contains pentaerythritol (devvate), preferably a C ₂ -C ₂₄ aliphatic acid ester of pentaerythritol, in particular in amounts of from 0.1 to 30% by weight, based on the total particle

Alkahsilicate can also be used with advantage. According to a preferred embodiment, the particle contains alkahsilicate, preferably having a modulus M ₂ O SiO ₂ from the range of 1 1, 9 to 1 3,3, where M is an alkali metal ion According to a preferred embodiment the particle amorphous Natπumsilikat preferably with a modulus Na ₂ O SiO ₂ from the range of 1 2 to 1 2,8

The particles may also contain further support material, preferably selected from

(a) alkali metal carbonate and / or alkali metal bicarbonate and / or

(b) sulfates, preferably alkali metal and alkaline earth metal sulfates, with sodium and magnesium sulfate and in particular sodium sulfate being clearly preferred, and / or

(c) silicic acids, preferably precipitated silicic acids, in particular the silica gels which are advantageously hydrophobic or hydrophilic and / or

(d) carriers from the group of surfactants Surfactant Compounds Citrate Alkali metal phosphates Chitin microspheres, pectin, gums, gelatin resins Strong especially porous starch, modified strong and / or carboxyalkyl-strong di- and / or polysaccharides, cyclodextrins, maltodextrins, (co) polymers, preferably synthetic (co) polymers, in particular water-soluble (co) polymers and / or terpolymers and / or mixtures thereof

The Tragermateπal may therefore at least partially include one or more (co) polymers as a carrier, which are preferably at least partially selected from the following groups

a) homopolymers selected from polyvinyl compounds such as preferably polyvinyl acetates, polyvinyl alcohol and / or polyvinylpyrrolidone, polycarboxylic acids such as preferably polyacrylic acid and / or polymethacrylic acid, polysulfonic acids such as preferably polystyrenesulfonic acids, polyesters such as preferably glycol polyacrylates, polyamides, polyacrylamides, polyurethanes, preferably polyurethanes carry ionic groups, for example carboxy groups, sulfonic acid groups or tertiary amines or polyurethanes, which preferably contain nonionic hydrophilic groups, such as ethylene oxide, polyethylene oxide, polypropylene oxide and polyalkylene glycoldevivative b) polycondensates, such as preferably ethoxylated phenol, formaldehyde resins, preferably sulfonated aromatic formaldehyde resins Urea or melamines, formaldehyde com- pounds, polyamides, polyamines, and epichlorohydrin resins. C) AB copolymers wherein A is a more water-soluble or water-swellable group and B is a less water-soluble one e or less swellable in water, preferably selected from styrene copolymers, in particular styrene-acrylic acid polymers or styrene-ethylene oxide polymers, copolymer of polyvinyl and maleic acid compounds, preferably styrene-maleic acid anhydride polymers or vinyl acetate, maleic acid ester polymers, Polyvinyl-polyalkylene copolymers, such as preferably vinyl acetate-ethylene polymers, ethylene-acrylic acid-acrylic acid ester polymers or ethylene-acrylic acid-acrylonitrile polymers, vinyl copolymers, preferably vinyl acetate polymers, acrylic acid-acrylonitrile polymers, acrylic acid-acrylamide polymers, d) ABA block copolymers where "A" stands for water-soluble or water-swellable groups such as preferably polyethylene oxide, polyvinyl alcohol, polyacrylamide, polyacryic acid, polyvinylpyrrolidone, or polycaprolactone and "B" stands for less water-soluble or sparingly water-soluble groups, such as preferably polypropylene oxide, polyvinyl acetate, polyvinyl butyline e) AB graft (co) polymers, where "A" is water-soluble or water-swelling groups such as, preferably, vinyl alcohol, vinyl acetate, ethylene oxide, propylene oxides, vinyl sulfonates, acrylic acids and vinylamines "B" is preferably selected from vinyl polymer or siloxane. f) Natural polymers such as preferably cellulose derivatives, in particular carboxymethyl cellulose, hydroxypropylmethyl cellulose, methyl cellulose and / or derivatives thereof Particular mention may be made here of polymers which preferably contain, at least partially, monomers selected from isobutyl methacrylate, n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, n-propyl acrylate, isopropyl methacrylate, methyl methacrylate, styrene, decyl (meth) acrylate, Dodecyl (meth) acrylate, tetradecyl (meth) acrylate and / or hexa-decyl (meth) acrylate and mixtures thereof

According to a preferred embodiment, the particle contains an acidic component, preferably carboxylic acid, advantageously polycarboxylic acids, in particular citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, succinic acids, aminocarboxylic acids, Nitπlo- triessigsaure (NTA), if such an application for environmental reasons not to object is, and / or mixtures thereof, each preferably in the form of their sodium salts

According to a preferred embodiment, the particle contains at least one bleaching agent, preferably selected from the group comprising perborates, in particular Natπumperborattra- hydrat and Natnumperboratmonohydrat, percarbonates, Peroxypyrophosphate, citrate, peracids and peracids, in particular perbenzoates, peroxophthalates, diperazelaic, Phthaloiminopersaure and Diperdodecandisaure

According to a preferred embodiment, the particle contains at least one further substance usually present in detergents or cleaners, preferably a substance from the group of surfactants, builders (inorganic and organic builders), bleaches, bleach activators, bleach stabilizers, bleach catalysts, enzymes, special polymers (e.g. those with cobuilder properties), grayness inhibitors, optical brighteners, UV protectants, soil repellents, electrolytes, colorants, fragrances, fragrances, perfume carriers, pH adjusters, complexing agents, fluorescers, foam inhibitors, crease inhibitors, antioxidants, quaternary ammonium compounds, Antistatic agents, ball aids, UV absorbers, anti redeposition agents, germicides, antimicrobial agents, fungicides, viscosity regulators, pearlescers, color transfer inhibitors, anti-shrinkage agents, corrosion inhibitors, preservatives, plasticizers, softeners, Pr oteinhydrolysates, repellents and impregnating agents, hydro tropics, silicone glycols and swelling and anti-slip agents

According to a preferred embodiment, the particle contains at least one substance selected from the following groups a) waxes such as carnauba, spermaceti, beeswax lanolin and / or corresponding derivatives, b) hydrophobic plant extracts c) hydrocarbons such as squalene and / or squalane, d) higher fatty acids , preferably having at least 12 carbon atoms, in particular Lauπn-, myπstin-, palmitic, stearic behenic, Ol, lmol, linolenic, lanolin, isostearic and polyunsaturated fatty acids, e) higher fatty alcohols, preferably having at least 12 carbon atoms, in particular lauryl, cetyl, stearyl, oleyl, behenyl, cholesterol and 2-hexadecanol alcohol, f) esters, such as cetyl octanoate, lauryl lactate, myristate, cetyl lactate, isopropyl myristate, myriphenylmy - stat, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, cholesterol tosearate, glyceryl monostearate, glycerol distearate, glycerol stearate, alkyl lactate, alkyl citrate and / or alkyl tartrate, g) lipids such as cholesterol, ceramides, sucrose esters and / or pseudo-ceramides h) Vitamins such as vitamins A and E, vitamin alkyl esters such as Vitamin C-alkyl esters, ι) sunscreens such as B or Butylmethoxybenzoylmethan j) phospholipids, k) alpha-hydroxy acids and / or their derivatives

I) germicides, such as synthetic antimicrobials such as 2-phenoxyethanol and / or natural antimicrobials such as grapefruit extract or willow extract, m) mixtures of above-mentioned substances

Advantageously, the aforementioned substances of the skin can be advantageous to their incorporation into the particles according to the invention is particularly advantageous if the inventive particles are the subject of a fabric care component So not only the textile is cared for, but also the skin, because the aforementioned substances In the textile treatment (eg textile wash), they can be applied to the textile fibers and from there to the skin, which then benefits them

According to a preferred embodiment, the particle is at least partly surrounded by a coating

According to a further preferred embodiment of the invention, the support material or the particle is at least partially surrounded by a coating which preferably contains at least one at least partially water-soluble or at least partially water-dispersible component, which is in particular selected from polyols, carbohydrates, starches, modified starches, starch hydrolysates, cellulose and cellulose derivatives, natural and synthetic gum silicates, borates, phosphates, chitin and chitosan, water-soluble polymers, fat components and mixtures thereof. Waxes and / or resins are also suitable, for example beeswax, benzoin, carnauba wax, Candelilla wax, coumarone-indene resin, copels, shellac, mastic, polyethylene wax oxidates or sandarak resin Paraffins or gelatin, in particular cellulose ethers, are likewise suitable

According to another preferred embodiment, the optional coating has polycarboxylates The optional coating of the particles can be carried out in the manners described in the prior art. The coating material preferably completely encloses the particular particle, although it may also be desirable to have a non-coherent coating. Suitable coating materials are, above all, those which are commonly used in connection with detergents or cleaners

Materials which can be used as coating materials in the context of the invention are any inorganic and / or organic substances and / or mixtures of substances, preferably those which are pH, temperature and / or ionic-sensitive, so that they are dependent on a pH value. , Temperature and / or ion-strength change lose their integrity, ie, for example, dissolve completely or partially

Polymers and / or copolymers which have film-forming properties and can preferably be used from aqueous dispersion are particularly preferred as potential coating materials. The decisive factor for the film-forming properties is the glass transition temperature of the film-forming polymer and / or copolymer. Above the glass transition temperature this is Polymer or copolymer elastic, meltable and flowable, while it becomes brittle below the glass transition temperature Only above the glass transition temperature, the polymer can be easily processed, as it is necessary to form a film coating The glass transition temperature can by the addition of low molecular weight substances with softening properties, the In addition to the polymer, it is therefore also possible to use plasticizers in the aqueous dispersion. Suitable plasticizers are all substances which preferably use the glass transition temperature Reducing pH Sensitivity, Polymers and / or Copolymers The polymer can thus be applied at lower temperatures, if appropriate even at room temperature. Particularly preferred plasticizers are citric acid esters (preferably titanium citrate and / or trimethyl citrate), phthalic acid esters (preferably dimethyl phthalate, diethyl phthalate and / or or dibutyl phthalate) esters of organic polyalcohols (preferably glycerol acetate) polyalcohols (preferably glycerol, propylene glycol) and / or polyoxyethylene glycols (preferably polyethylene glycol) The plasticizer is intercalated between the polymer chains, thereby increasing the mobility lowers the interactions and avoids abrasion and by reducing the spasm Cracks in the film

It is particularly advantageous if the optional coating material contains a polyacrylate and / or a derivative thereof and / or a corresponding copolymer based on acrylic acid esters or acrylic acids and other monomers. Copolymers of acrylamide and acrylic acid and / or their derivatives are preferred for the optional coating material advantageous

If the support material or the particle at least partially has a coating which comprises an at least partially water-soluble or at least partially water-dispersible component comprising from 0% to 80% by weight of at least one solid polyol having preferably more than 3 hydroxyl radicals and 20% by weight % to 100% by weight of a liquid diol or polyol in which the perfume is substantially insoluble and in which the solid is Polyol is substantially soluble, wherein said liquid polyol or diol is preferably selected from glycine, ethylene glycol and diglycene or mixtures thereof and wherein the solid polyol is preferably selected from glucose, sorbitol, maltose, glucamine, sucrose, polyvinyl alcohol, starch, Alkylpolyglycoside, sorbitan fat esters, polyhydroxyfatty acid amides whose Fettsaurereste contain 1 to 18 carbon atoms, and mixtures thereof is selected, there is a further preferred embodiment of the invention

According to a preferred embodiment, the particle is colored. The particle can be colored through or its surface can be colored or it can be coated or coated with a colored substance

In a preferred embodiment, the coating has pigments, advantageously in the nanoscale range or in the micrometer range, preferably white pigments, in particular selected from titanium dioxide pigments, in particular anatase pigments and / or rutile pigments. Pigments, zinc sulfide pigments, zinc oxide (zinc white), antimony oxide (antimony white), basic lead carbonate (lead white) 2PbCO ₃ Pb (OH) ₂ , lithopone ZnS + BaSO ₄ White auxiliary substances, preferably calcium carbonate, talc 3MgO 4SiO ₂ H ₂ O and / or barium sulfate may be included

In a further preferred embodiment, the pigments may be um

(a) colored pigments (preferably inorganic colored pigments, in particular iron oxide pigments, chromate pigments, iron blue pigments, chromium oxide pigments, ultramarine pigments, mixed oxide phase pigments and / or bismuth vanadate pigments),

(b) black pigments (eg, anilm black, perylene black, iron oxide pigments, manganese black and / or spinel black),

(c) luster pigments (preferably platelet effect pigments, metal effect pigments such as aluminum pigments (silver bronze), copper pigments and copper / zinc pigments (gold bronze) and zinc pigments, pearlescent pigments such as magnesium stearate, zinc stearate, lithium stearate or Ethylene glycol distearate or polyethylene terephthalate, interference pigments such as metal oxide-mica pigments) and / or

(d) luminescent pigments such as azomethine fluorescent yellow, silver doped and / or copper doped zinc sulfide pigments

If the particle size of the individual particles is substantially between 0.005 and 2.0 mm, this is a further preferred embodiment of the invention. The expression "substantially" here means that at least 40% by weight, advantageously at least 50% by weight, more preferably at least 60% by weight, more preferably at least 70% by weight, preferably at least 80% by weight, in particular 90% by weight, of the particles of this particle size requirement If the particles according to the invention are present in agglomerated form, the agglomerate size preferably being substantially 100-2000 μm, in particular essentially 100-800 μm, then a preferred embodiment of the invention is again. The expression "essentially" here means that at least 40% by weight %, advantageously at least 50% by weight, more preferably at least 60% by weight, even more preferably at least 70% by weight, preferably at least 80% by weight, in particular 90% by weight, of agglomerates of said agglomerate particles Contact with water preferably back into the smaller particle particles from which the agglomerates are composed. In some cases, the agglomerate size may even be in the range of 0.1 to 30 mm, if this is desired in terms of application

The particle of the invention may have any shape. In a most preferred embodiment, however, the particle is spherical (or at least approximately spherical or approximately ellipsoidal in shape). The ellipsoid is similar to the sphere, but the longitudinal axis and transverse axis are different

In other embodiments, the particle is more likely

(a) cubic (cube-shaped) or at least approximately cubic, or

(b) parallelepiped-shaped (z B cuboid) or at least approximately parallelepiped-shaped, or

(c) lamellar (platy and the like) or at least approximately lamellar, or

(d) needle-like or fibrous-shaped or at least approximately needle-like or fibrous-shaped

Another object of the present invention is the use of the particles of the invention as detergents or cleaning agents or as an additive to detergents or cleaners

Another object of the present invention is a process for the preparation of inventive particles, comprising

a) the provision of zeolite and phyllosilicate comprehensive carrier material, preferably based on aqueous suspensions, which advantageously also include nonionic surfactant and optionally other inorganic and organic constituents, wherein the aqueous suspensions are then dried, then b) optionally impregnating the Tragermateπals with at least one nonionic surfactant , such as c) the loading of the carrier material with perfume by mixing perfume and (impregnated) Tragermateπal and / or by spraying perfume on the (impregnated) Tragerma- material, and

optionally the coating of the perfumed carrier material

According to process step a), the carrier material according to the invention is prepared, preferably based on aqueous suspensions of inorganic and organic constituents, which advantageously comprise nonionic surfactant, the aqueous suspensions then being dried. Preferably, a support material is used which contains nonionic surfactant during production

In this case, it is particularly preferable if carbon dioxide is generated during the drying of the aqueous suspension in the drying material

By drying is meant in the broadest sense of any technical drying ability with which you can remove water and / or other solvents from the aqueous suspensions as much, so that at the end of the drying particles, ie particulate solids incurred, which form the desired carrier material These particles must Of course, they may not be completely free of solvent and / or anhydrous, for example they may still contain significant amounts of solvent and / or water, but they preferably have water contents of less than 30% by weight, advantageously less than 25% by weight, in particular less than 20% by weight. in each case based on the solid obtained at the end of the drying. The water content may also be lower, if desired, for example below 15% by weight or below 10% by weight or below 5% by weight, based in each case on the amount obtained at the end of the drying solid fuel

For drying, heat is advantageously added to the material to be dried. Drying may preferably be carried out in cocurrent, countercurrent or cross flow. The type of heat supply differs between contact dryer, convection dryer and radiation dryer. Depending on the pressure prevailing in the dryer, z.sub.B. In the case of convection drying, the heat to the material to be dried is predominantly transferred by means of hot gases (air or inert gas) which is preferred. For example, channel, chamber, belt, shaft and fluidized bed and / or atomizing dryer used, which is preferred In the contact drying, which is also preferred, the heat transfer takes place on heat exchanger surfaces z pay to the contact dryers pay z B the roll, pipe and cabinet dryer floor Teller-, drum and paddle dryer work on both principles of heat

A very preferred drying process according to the invention is spray-drying. Fluidized-bed processes are likewise preferred for drying According to a preferred embodiment of the invention, the inventive aqueous suspension to be dried contains substance (s) which release carbon dioxide at elevated temperatures, preferably selected from bicarbonate compounds, citric acid and / or acetic acid

According to a further preferred embodiment of the invention, the aqueous suspension to be dried according to the invention contains 0 to 40% by weight, preferably 0.1 to 4% by weight, in particular 1 to 3% by weight, of citric acid or 0 to 50% by weight, preferably 0, From 1 to 5% by weight, in particular from 1 to 4% by weight, of bicarbonate compound, or from 0 to 40% by weight, preferably from 0.1 to 10% by weight, and in particular from 5 to 5% by weight of aconitic acid

It may also be advantageous to use mixtures of bicarbonate compounds, citric acid and / or aconitic acid, the total amount of such should not exceed 50% by weight, preferably 40% by weight, advantageously 20% by weight, but in particular 10% by weight, and wherein a minimum total amount of 0 1% by weight should preferably not fall below 1% by weight, in each case based on the total suspension

It has surprisingly been found that in such cases where carbon dioxide is liberated during the drying, particles result, which are distinguished by an even better absorption capacity for fragrances

If the support medium provided does not contain any nonionic surfactant after production, according to a preferred embodiment the impregnating of the inventive support material with at least one nonionic surfactant is followed by loading of the preferably nonionic surfactant-containing carrier material with perfume by mixing or spraying as just described

Another object of the present invention resides in a detergent composition containing

o (A) particles according to the invention o (B) 0.01 to 95% by weight, preferably 5 to 85% by weight, advantageously 3

% By weight to 30% by weight, in particular 5% by weight to 22% by weight, of additional surfactant (e) o (C) optionally further ingredients of detergents or cleaners

In the context of this invention, the term detergent composition preferably means detergents and / or cleaning agents and / or (textile) care agents and / or softening agents and / or softener compositions

In a preferred embodiment, the detergent composition according to the invention is a multipotent detergent or cleaning agent. These are agents having an effect. These detergents have components with washing or cleaning action and components having a further effect, in particular textile care or softening action and / or skin care action. Skin care action means that the composition contains components which Indirectly serve the skincare, by the fact that they go to the laundry during washing and if necessary, when the textiles are carried, they are then released to the skin. Corresponding substances have already been mentioned above

Accordingly, a 3-in-1 detergent combines components with washing or cleaning action and components with two further effects, in particular textile care or softening action and skin care action

If the additional surfactant comprises anionic surfactant, preferably in a proportion of at least 50% by weight, based on the total amount of additional surfactant, it is a preferred embodiment, wherein it is further preferred that the additional surfactant comprises a mixture of anionic and anionic surfactants nonionic surfactants

A detergent composition according to the invention which comprises at least one surfactant, preferably at least two from the group of alkylbenzenesulfonates, alkyl ester sulfonates, alkyl ethoxylates, alkyl phenol alkoxylates, alkyl polyglucosides, alkyl sulfates, alkyl ethoxy sulfate, secondary alkyl sulfates and / or mixtures thereof, these additional surfactants advantageously being used in amounts of 1 % By weight to 75% by weight, based on the total composition, is a preferred embodiment

In the following, advantageous surfactants will be described which may be included in the detergent composition

The anionic surfactants used are, for example, those of the sulfonate and sulfates type. The surfactants of the sulfonate type are preferably C ₉ . _13- Alkylbenzol-sulfonates, olefinsulfonate, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as for example from C _{12 18} monoolefins with terminal or internal double bond by sulfonating with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of sulfonation products obtained, in consideration also suitable are alkanesulfonates, which are of C _{12-i 8} -Alka- NEN example, by Sulfochloπerung or sulfoxidation and subsequent hydrolysis or neutralization obtained Likewise, the esters of α-Sulfofettsauren (Estersulfona- te), eg the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids are suitable

Further suitable anionic surfactants are sulfonated fatty acid glycyl esters. Fatty acid glycine esters are to be understood as meaning the mono-, di- and tri-esters and mixtures thereof, as in the preparation by esterification of a monoglycerine with 1 to 3 mol fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerine are obtained Preferred sulfated fatty acids Saureglyceπnester are the sulfonation of saturated fatty acids having 6 to 22 carbon atoms, for example, the Capronsaure, Caprylsaure, Capπnsaure, Mynstinsaure, Lauπnsauer, palmitic acid, stearic acid or behenic acid

Alk (en) yl sulfates are the alkali and especially the sodium salts of Schwefelsaurehalb- esters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl nstyl-, cetyl or stearyl alcohol, or C ₀ - C ₂ o-OxoalkQhole and those half-esters of secondary alcohols of these chain lengths are furthermore preferred. Alk (en) ylsulfates of said chain length which contain a synthetic, petrochemical-based straight-chain alkyl radical which has an analogous decomposition behavior to the corresponding compounds on the chain Base of Fatty Chemical Raw Materials From a washing-technical point of view, the C ₁₂ -C ₁₆ -alkyl sulfates and C ₁₂ -C ₁₅ -alkyl sulfates and also C ₁₄ -C ₁₅ -alkyl sulfates are preferred. Also 2,3-alkylsulfates which are, for example, according to US Pat. Nos. 3,234,258 or 5,075,041 are manufactured and can be obtained as commercial products from Shell Oil Company under the name DAN ^®, are suitable e anionic surfactants

Also the sulfuric acid monoesters of the straight-chain or branched C _7-21 -alcohols ethoxylated with 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11 -alcohol with on average 3.5 mol of ethylene oxide (EO) or C ₁₂ .i ₈ They are suitable in detergents due to their high foaming behavior only in relatively small amounts, for example in amounts of 1 to 5 wt -%, used

Further suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or sulfosuccinic acid esters and the monoesters and / or diesters of sulfosubstituted with alcohols, preferably fatty alcohols and in particular e-thoxyherten fatty alcohols Preferred sulfosuccinates contain C _8- i ₈ -Fettalkoholreste or mixtures of these particularly preferred sulfosuccinates contain a fatty alcohol radical which is derived from ethoxylated fatty alcohols, which in themselves constitute nonionic surfactants. In turn, sulfosuccinates whose fatty alcohol radicals are derived from ethoxylated fatty alcohols with a narrow homolog distribution are particularly preferred also possible to use alk (en) ylbernstic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof

Suitable further anionic surfactants are, in particular, soaps. Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, and in particular soap mixtures derived from natural fatty acids, for example coconut, palm kernel or tallow fatty acids

The anionic surfactants including the soaps may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases such as mono-, di- or Tπethanolamin, are preferably the anionic surfactants in the form of their sodium or potassium salts, in particular in the form of Sodium salts The nonionic surfactants (additional surfactants) used are preferably alkoxylated, preferably ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol in which the alcohol radical is linear or preferably 2- However, however, alcohol ethoxylates having linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, such as coconut, palm, tallow fat, are especially methyl-branched or linear and methyl-branched radicals may be present in the mixture The preferred ethoxylated alcohols include, for example, C ₁₂ -i ₄ -alcohols with 3 EO or 4 EO, C ₉ "-alcohol with 7 EO C ₁₃ . ₁₅ alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C _{12 18} alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C ₁₂ -i ₄ -alcohol with 3 EO and C _{12 18} -alcohol with 5 EO The stated ethoxy heritages are statistical mean values which may be a whole number or a fractional number for a specific product. Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE) in addition to Fatty alcohols with more than 12 EO can also be used for these nonionic surfactants. Examples of these are tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO

In addition, other nonionic surfactants (additional surfactants) and alkyl glycosides of the general formula RO (G) _x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 C. And G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10, preferably x at 1, 2 to 1, 4

Another class of preferred nonionic surfactants (additional surfactants) used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain , in particular fatty acid methyl esters, as described for example in Japanese Patent Application JP 58/217598 or which are preferably prepared according to the method described in International Patent Application WO-A-90/13533

Nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowkyl-N-N-hydroxyethylaminoamide, and the fatty acid alkanolamides may also be suitable as additional surfactants. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated surfactants Fatty alcohols, in particular not more than half of them

Further suitable additional surfactants are polyhydroxy fatty acid amides of the formula R ²

I

R-CO-N- [Z] in the RCO for an aliphatic acyl radical having 6 to 22 carbon atoms, R ² for hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical having 3 to The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride

The group of polyhydroxy fatty acid amides also includes compounds of the formula

R ³ -OR ⁴

I

R-CO-N- [Z] in the R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{3 is} a linear, branched or cyan alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{4 is} a linear, branched or cyan alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, with C _1-4 alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups or alkoxylated, preferably ethoxylated or propoxylated derivatives of this group

[Z] is preferably obtained by reductive amination of a reduced sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose. The N-alkoxy- or N-aryloxy-substituted compounds can then be prepared, for example, according to the teaching of the international application WO-A A-95/07331 can be converted into the desired polyhydroxy fatty acid amides by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst. The detergent compositions according to the invention, such as cleaning agents, care agents and detergents, may optionally also contain cationic surfactants. Suitable cationic surfactants are, for example, also surface-active quaternary compounds. in particular with an ammonium, sulfomum, phosphomum, iodonium or arsonium group, as described, for example, in the prior art as antimicrobial agents. The use of quaternary surface-active compounds with antimicrobial action may be the means be designed with an anti-microbial effect or its possibly existing antimicrobial effect can be improved due to other ingredients

Particularly preferred cationic surfactants are the quaternary, z T antimicrobial ammonium compounds (QAV, INCI Quaternary Ammonium Compounds) according to the general Formula (R ^I ) (R ^II ) (R ^I ") (R ^IV ) N ⁺ X ^" , in which R ¹ to R ^ιv identical or different C ^ -alkyl radicals, C _7-28 - Aralkylreste or heterocyclic radicals, where two or in the case of an aromatic inclusion as in Pyndin, even three radicals together with the nitrogen atom form the heterocycle, for example a Pyπdinium- or Imidazoliniumverbmdung, and X ^"are halide ions, sulfate ions, hydroxide ions or similar anions For optimum antimicrobial activity preferably at least one of the radicals has a chain length of 8 to 18, ιnsbesondere12 to 16, carbon atoms

QACs can be prepared by reaction of tertiary amines with alkylating agents, such as methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide. The alkylation of tertiary amines with a long alkyl radical and two methyl groups is particularly easy, also the quaternization of tertiary amines with two long radicals and one methyl group can be carried out under mild conditions with the aid of methyl chloride. Amines which have three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are preferably quaternized with dimethyl sulfate

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylamine monomer, CAS No. 8001-54-5), benzalkone B (mp-dichlorobenzyl-dimethyl-C 1 -alkylammonium chloride, CAS No. 58390 -78-6), benzoxonium chloride (benzyldodecyl-bis (2-hydroxyethyl) -ammonium chloride), cetmonium bromide (N-hexadecyl-N, N-trimethylammonium bromide, CAS No 57-09-0), benzetonium chloride ( N, N-dimethyl-N- [2- [2- [p- (1, 1, 3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No 121-54-0), Dialkyldimethylammoniumchloπde as Dι-n-decyl-dιme- thyl-ammonium-chlond (CAS No 7173-51-5-5), Didecyldimethylammoniumbromid (CAS No 2390-68-3), dioctyl-dimethyl-ammoniumchloπc, 1-Cetylpyπdιnιumchlorιd (CAS No 123-03-5) and Thiazohnjodid (CAS No 15764-48-1) and mixtures thereof Preferred are the quaternary ammonium compounds benzalkonium koniumchlonde with C ₈ -C ₈ alkyl radicals, in particular C ^ Cn-Aklyl-benzyl-dimethylammo-niumchlo- A particularly preferred QAV is coco-pentaethoxymethylammonium methoxy. sulfate (INCI PEG-5 Cocomonium Methosulfate, Rewoquat CPEM ^®)

In order to avoid possible incompatibilities of the antimicrobial cationic surfactants with anionic surfactants contained in the detergent composition according to the invention anionic surfactant and / or cationic surfactant are preferably used or omitted in a particular embodiment of the invention entirely on antimicrobial cationic surfactants

Parabens, benzoic acid and / or benzoate, lactic acid, salicylic acid and / or lactates can be used instead as antimicrobial substances. Particular preference is given to benzoic acid and / or lactic acid

The detergent compositions according to the invention, such as cleansing and care compositions, may contain one or more cationic surfactants in amounts, based on the total composition of the compositions. Setting, from 0 to 5% by weight, large 0 to 5% by weight, preferably 0.01 to 3% by weight, in particular 0.1 to 1% by weight

Likewise, the inventive detergent compositions, such as cleaning, care and detergent, may also contain amphoteric surfactants Suitable amphoteric surfactants are, for example, betaines of the formula (R ¹ ) (R ² ) (R ³ ) N ⁺ CH ₂ CO ^~ , in the R ¹ an optionally interrupted by heteroatoms or heteroatom groups alkyl radical having 8 to 25, preferably 10 to 21 carbon atoms and R ² and R ^{3 are} identical or different alkyl radicals having 1 to 3 carbon atoms, in particular Ci ₀ -C ₂₂ Alkyldιmethylcarboxymethylbetaιn and Cn-C ^ Furthermore, the use of alkylamidoalkylamines, alkyl-substituted amino acids, acylated amino acids or biosurfactants as amphoteric surfactants in the compositions according to the invention, such as cleaning agents, care agents and detergents, is conceivable. The detergent compositions according to the invention, such as cleaning, care and cleaning agents. and detergents, one or more amphoteric surfactants in amounts, bezoge n to the total composition, from 0 to 5% by weight, from 0 to 5% by weight, preferably from 0.01 to 3% by weight, in particular from 0.1 to 1% by weight

In addition to the washing-active substances, scaffolds are the most important ingredients of detergents or cleaners, especially zeolites, silicates, carbonates, organic co-builders and-where there are no ecological prejudices against their use-also the phosphates. The detergent compositions may accordingly also be preferred in addition to the scaffolds present in the particles according to the invention If the detergent composition furthermore comprises at least 1% by weight of an additional laundry detergent, then another preferred embodiment of the invention is present, and it is likewise preferred to additionally contain conventional additives for washing or cleaning agents

As an additional Geruststoffe are, for example and in particular the above-mentioned advantageous suitable are preferably crystalline, or amorphous schichtformige Natπumsilikate Natnum- silicates Zeohth preferably zeolite A and / or P is also advantageous as zeolite P is Zeohth MAP ^® (a product of Crosfield) However, zeolite X and mixtures of A, X and / or P are also suitable. Commercially available and preferably usable in the context of the present invention is, for example, a co-catalyst of zeolite X and zeolite A (about 80% by weight of zeolite X). which is marketed by CONDEA Augusta S p A under the brand name VEGOBOND AX ^® and by the formula

nNa ₂ O (1-n) K ₂ O Al ₂ O ₃ (2 - 2.5) SιO ₂ (3.5-5 5) H ₂ O can be described. The zeolite can be used both as a further skeleton and as well be used to powder the particles suitable zeolites have preferred has an average particle size of less than 10 μm (volume distribution, Coulter Counter method) and preferably contains 18 to 22% by weight, in particular 20 to 22% by weight, of bound water

Of course, the use of other conventional additional Geruststoffe advantageous, for example, the well-known phosphates as builders in the detergent composition possible, if such use should not be avoided for environmental reasons Particularly suitable are the sodium salts of orthophosphates of pyrophosphates and in particular the Tπpolyphosphate

Useful organic framework substances are, for example, the polycarboxylic acids which can be used in the form of their sodium salts, such as citric acid, adipic acid, glutaric acid, tartaric acid, succinic acids, aminocarboxylic acids, nitroglioacetic acid (NTA), provided such use is not objectionable for environmental reasons and mixtures of these preferred salts the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof

In addition to the constituents already mentioned, other ingredients customary in detergents or cleaners, in particular from the group of bleach bleach activators, enzymes, enzyme stabilizers, fluorescers, dyes, foam inhibitors, silicone oils, antiredeposition agents, optical brighteners, grayness inhibitors, dye transfer inhibitors and corrosion inhibitors Further optional ingredients preferably originate from the group of oligomeric and polymeric polycarboxylates, pH regulators, fluorescence infeed inhibitors, wetting enhancers, antimicrobial agents germicides, fungicides, antioxidants, antistatic agents, bleaching aids. tel, repellents and impregnating agents, swelling and anti-slip agents, chelating agents, fabric softeners and UV absorbers

Among the compounds used as bleaching agent, _{H 2} O ₂ in water, H compounds, the Natπ- have umperborattetrahydrat and Natπumperboratmonohydrat particular importance Other useful bleaching agents are, for example Natπumpercarbonat Peroxypyro-phosphate, hydrate Citratper- and H ₂ O ₂ -liberating peracid salts or peracids, such as perbenzoates, Peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid

In order to achieve an improved bleaching effect at temperatures of 60 ^° C. and below, bleach activators can be incorporated. As bleach activators, it is possible to use compounds which under perhydrolysis conditions contain aliphatic peroxocarboxylic acids having preferably 1 to 10 carbon atoms, in particular 2 to 4 carbon atoms and / or Substances which may be used are unsubstituted or substituted perbenzoic acid. Suitable substances are the O- and / or N-acyl groups The above-mentioned C atom number and / or optionally substituted benzoyl groups are preferred. Acylated alkylenediamines are preferred, in particular tetraacetylethylenediamine (TAED), acylated Tπazinderivate, in particular 1, 5-Dιacetyl-2,4-dιoxohexahydro-1, 3,5-tπazιn DADHT), acylated glycol oils, in particular tetraacetylglycol (TAGU), N-acylimides, in particular N-nonanoyl succmimide (NOSI), acylated phenolsulphonates, in particular n-nonanoyl or isononanoyloxybenzenesulphonate (n- or iso-NOBS), carboxylic acid anhydrides in particular Phthalsaureanhydπd, acyherte polyhydric alcohols, in particular Tπacetin, ethylene glycol diacetate and 2,5-Dιacetoxy- 2,5-diphohydrofuran

In addition to or in place of the conventional bleach activators, it is also possible to incorporate so-called bleach catalysts. These substances are pale-bleaching transition metal salts or transition metal complexes such as, for example, Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with N-containing Tπpod ligands and Co, Fe, Cu and Ru amine complexes can be used as bleach catalysts

Suitable enzymes are those from the class of the proteases, lipases, amylases, cellulases or mixtures thereof Particularly suitable are from Baktπenstammen or fungi, such as Bacillus subtihs, Bacillus hcheniformis and Streptomyces gπseus derived enzymatic agents Preferably proteases of Subtιlιsιn type and in particular Enzyme mixtures, for example from protease and amylase or protease and lipase or protease and cellulase or from cellulase and lipase or from protease, amylase and lipase or protease, lipase and cellulase, in particular, however, cellulase and protease, which are obtained from Bacillus lentus. Containing mixtures of particular interest Peroxidases or oxidases have also proved to be suitable in some cases. The enzymes can be adsorbed on carriers and / or embedded in hull substances to protect them from premature decomposition. The proportion of enzymes, enzyme mixtures or enzyme granules in which he By way of example, compositions may be about 0.1 to 5% by weight, preferably 0.1 to about 2% by weight

In addition, the compositions may also contain components which positively affect the oil and Fettauswaschbarkeit from textiles (so-called repellents) This effect is particularly clear when a textile is dirty, which previously several times with a detergent according to the invention that these oil and fatless For example, nonionic cellulose ethers such as methylcellulose and methylhydroxy-propylcellulose having a methoxy group content of 15 to 30% by weight and hydroxypropoxyl groups of 1 to 15% by weight belong to the preferred oil and grease components. %, in each case based on the nonionic cellulose ether, and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionically modified derivatives of these. Particularly preferred of these are the sulfonated derivatives of phthalic acid and terephthalic acid polymers

The compositions may contain, as optical brighteners, derivatives of diaminostilbenedisulfonic acid or its alkali metal salts. Suitable salts are, for example, salts of 4,4'-bis (2-anilino-4-morpholino-1, 3,5-triazolinyl-6-amino). 2,2'-Dysulfonic acid or similarly structured compounds which carry a diethanolamino group, a methylamino group, an anilino group or a 2-methoxyethylamino group in place of the morpholino group Furthermore, brighteners of the type of substituted diphenylstyrene may be present, for example the alkali metal salts of 4,4 '-Bιs (2-sulfostyryl) -dι- phenyls, 4,4'-Bιs (4-chloro-3-sulfostyryl) -diphenyls, or 4- (4-chlorostyryl) -4' - (2-sulfostyryl) -diphenyls Mixtures of the aforementioned brightener can be used

In order to improve the aesthetic impression of the agents according to the invention, they may be colored, preferably in part, with suitable dyes. Preferred dyes whose selection does not present any difficulty to the skilled person possess a high storage stability and insensitivity to the other ingredients of the compositions and to light as well as no pronounced substantivity to textile fibers in order not to stain them

When the detergent composition according to the invention is in the form of agglomerates, it is likewise a preferred embodiment of the invention

If the detergent composition according to the invention has a density of advantageously at least 300 g / l, advantageously 400 g / l, more preferably 500 g / l, preferably at least 600 g / l and especially at least 650 g / l, then this is likewise a preferred embodiment the invention

If the detergent composition according to the invention also comprises a second perfume which is sprayed onto the surface of the detergent particles contained, then again a preferred embodiment of the invention is provided

A further preferred embodiment is a detergent composition according to the invention in the form of a laundry detergent composition, preferably in tablet form

For example, the particles according to the invention which are contained in the detergent stucco can also contain decomposition accelerators, for example substances which have a high adsorption capacity for water (for example strong cellulose derivatives alginates, dextranes, crosslinked polyvinylpyrrolidone, casein derivatives, etc.). and / or in particular gas-evolving substances (for example sodium bicarbonate, citric or tartaric acid, etc.) so that a showering effect or effervescent effect occurs Another preferred embodiment is a detergent composition according to the invention which is filled into pouches, bags or sacs

The pouches, bags or sacs are preferably designed so that they allow a penetration of the detergent composition in the course of the washing process So you are either permeable to water or they dissolve in water, if necessary under adjustable conditions (temperature, pH, ionic strength)

Another object of the present invention is a process for laundering textiles comprising the step of contacting the fabrics with an aqueous medium containing an effective amount of a detergent composition comprising particles of the invention

A further subject of the present invention resides in a detergent or cleaning agent additive which comprises particles according to the invention, this additive being in the form of a pouch, the quantity measured in the pouch being sized to be normal Washing load of an automatic washing machine is sufficient

Another object of the invention is a plasticizer composition which is added to the winding process of an automatic washing machine, comprising particles according to the invention

example

The particles according to V1 and E1-E4 were each prepared in a standard spray-drying process

The particles each contained greater amounts of perfume (> 15% by weight in each case, which means that 100 g of the particles had a weight of> 115 g after perfuming). The particles according to the invention retained their good powder properties, ie remained good non-selfish and showed no clumping

Fragrance stability The fragrance stock was evaluated by a six-headed panel of perfumery laypersons. They judged the fragrance of the particles according to V1 and E1 -E4 about 24 hours after the loading of the particles with 18% by weight of a fragrance composition " ^* * (Parfumol)

In addition, they assessed the scent of these particles after four weeks of storage. It was found that the scent of the particles changed significantly after V1 storage after four weeks of storage. The scent contained unpleasant notes that were not present before storage. The original scent was after this Storage time significantly impaired By contrast, the scent of the particles according to E1-E4 was still good after four weeks of storage, the fragrance was always preserved or only changed gradually. Therefore, the six-headed panel evaluated the fragrance ratio after 4 weeks of storage Particles according to V1 with "bad", the corresponding fragrance ratio of the particles according to E1 -E4, however, could be assessed as "good"

The composition of the fragrance used contained, among other components, 15% by weight of allylamyl glycolate and 15% by weight of cyclogalbanate, based in each case on the total fragrance composition

Claims

Claims Particles containing Zeolite, in a total amount of more than 20% by weight, but less than 70% by weight, based on the total particle, and perfume, characterized in that the particle also contains layered silicate, the ratio of zeolite to layered hematite being less than 7 1 is Particles according to claim 1, characterized in that the layered hiqate is (A) Zweischichtsihkate, such as preferably silicates of the kaolin and / or serpentene group, in particular Kaohnit, Dickit, Halloysit Antigoπt, Lizardite and / or Chryosotil (b) three-layer silicates, such as preferably pyrophyllite, talc, silicates of the mica group such as muscovite, the smectite group such as, in particular, montmorillonite, beidellite, hectont, nontronite and / or saponite, the hydrogels group, such as, for example, celadonite and Glauconite and Vermiculite and Chloπte, such as preferably Chnochlor Chamosit and / or Don bassit (c) Layered shkates with alternating support structures, such as preferably the muscovite-montmorillonite mixed layer (also Ilht-smectite mixed layer) (d) clay minerals with fibrous structure such as preferably Sepiohth and / or Palygorskit and / or (e) non-crystalline silicates such as allophane and imogolite Particles according to one of claims 1 or 2, characterized in that layered hate is contained in the form of clay, preferably of smectite-rich clay, in particular bentonite Particles according to one of claims 1 to 3, characterized in that it contains nonionic surfactant, preferably selected from the group of alkoxy-alcohols, Alkylphe- nolpolyglykolether, the alkoxyherten Fettsaurealkylester of Polyhydroxyfettsaureamide, the alkyl glycosides, the Alkylpolyglucoside, the amine oxides and / or long-chain alkyl sulfoxides, in particular in an amount of at least 0.1% by weight, based on the total particle Particles according to any one of Claims 1 to 4, characterized in that they contain a polymeric clay flocculating agent, the clay flocculating agent being a polymer or a copolymer which is preferably derived from monomers obtained from ethylene oxide, acrylamide, acrylic acid, dimethylaminoethyl methacrylate, vinyl alcohol, Vinylpyrrolidone, ethyleneimine, and mixtures thereof, more preferably having a weight average molecular weight of 100,000 to 10 million, and is preferably contained in the particle in the range of 0.005% to 20% by weight of the clay Particles according to one of claims 1 to 5, characterized in that it contains cationic surfactants, zwitterionic compounds, ampholytes, amphoteric surfactants, betaines, cationic polymers and / or amphoteric polymers Particles according to one of claims 1 to 6, characterized in that it contains at least one quaternary ammonium compound, preferably an alkylated quaternary ammonium compound, in particular in amounts of 0.1% by weight to 30% by weight, based on the total particle Particles according to one of claims 1 to 7, characterized in that it contains 0 1% by weight to 30% by weight of an organic humectant which is selected in particular from glycerol, ethylene glycol, propylene glycol, dimers and trimers of glycerol and / or mixtures thereof Particles according to one of claims 1 to 8, characterized in that it contains a complexing agent, preferably phosphonate and / or a citrate, in particular in amounts of from 0.1% by weight to 10% by weight, based on the total particle Particles according to one of claims 1 to 9, characterized in that it contains Pentae- rythrιt (derιvate), such as preferably a C ₂ -C ₂₄ aliphatic acid ester of Pentae- rythπt, in particular in amounts of 0.1 to 30 wt -% Particles according to any one of claims 1 to 10, characterized in that it contains an alkali metal hydroxide, preferably with a modulus M ₂ O SiO ₂ from the range of 1 1, 9 to 1 3,3, wherein M stands for an alkali metal ion Particles according to one of claims 1 to 11, characterized in that it contains an acidic component, preferably carboxylic acid, advantageously polycarboxylic acids, in particular citric acid Particles according to one of claims 1 to 12, characterized in that it contains at least one further substance usually contained in detergents or cleaners, preferably a substance from the group of surfactants, builders (inorganic and organic builders), bleaches, bleach activators bleach stabilizers, bleach catalysts , Enzymes, special polymers (for example those with cobuilder properties), inhibitors of glazing, optical brighteners UV protection substances target repellents, electrolytes, colorants, fragrances fragrances, perfume carriers, pH adjusters, complexing agents, fluorescers, foam inhibitors, anti-wrinkling agents antioxidants quaternary ammonium compounds anti-static agents, polishing aids, UV absorbers Anti-redeposition agents Germicides, antimicrobial agents Fungicides Viscosity regulators, pearlescers Color transfer inhibitors enema, anti-shrinkage agents, corrosion inhibitors, preservatives, plasticizers, fabric softeners, protein hydrolysates, repellents and impregnating agents, hydrotropes, Sihkonole and swelling and anti-sliding agents Particles according to one of claims 1 to 13, characterized in that it is at least partly surrounded by a coating Particles according to any one of claims 1 to 14, characterized in that it is colored Use of a particle according to any one of the preceding claims 1-15 as a washing or cleaning agent or detergent or cleaning agent additive A process for producing a particle according to any one of claims 1 to 15, comprising a) the zeolite and layered silicate Tragermateπals, preferably based on wassπgen suspensions, which advantageously also include nonionic surfactant and optionally further inorganic and organic components, wherein the aqueous suspensions then dried b) optionally impregnating the Tragermateπals with at least one nonionic surfactant, and c) loading the Tragermateπals with perfume by mixing perfume and (impregnated) Tragermateπal and / or by spraying perfume on the (impregnated) carrier material, and optionally the coating of perfumed Tragermateπals A detergent composition containing o (A) particles according to any one of claims 1 to 15 o (B) 0, 01 wt% to 95 wt%, preferably 5 wt% to 85 wt%, advantageously 3 wt% to 30 wt %, in particular 5% to 22% by weight of additional surfactant (s) A method of laundering textiles, comprising the step of contacting the fabrics with a wet medium containing an effective amount of a detergent composition according to claim 18 A detergent or irritant additive comprising particles according to any one of claims 1 to 15 which is in the form of a sachet A softening composition to be added in the case of spooling, comprising particles according to any one of claims 1 to 15