EP2046929A1 - Liquid support - Google Patents

Abstract

Disclosed are fluid-containing particles which are obtained by agglomerating support material in the presence of a granulation liquid that has a certain carbohydrate concentration, and then incorporating a liquid, e.g. a perfume oil. Said fluid-containing particles have very good powder properties even when the same are loaded with a large amount of liquid, while securely storing the incorporated liquid also in the presence of aggressive solid matrices. Said fluid-containing particles can be used for fragrancing purposes.

Description

 "Liquid carrier"

The invention relates to fluid-containing particles which can be obtained by agglomeration of carrier material in the presence of a granulation liquid comprising carbohydrates and / or derivatives thereof, followed by the application of a liquid to be incorporated. The invention also relates to detergents or cleaners which comprise such fluid-containing particles, and to the use of the fluid-containing particles for various scenting purposes.

For many applications, there is a need for particulate carriers that are capable of receiving and, depending on the application, storing and returning fluids as needed.

For example, one works in solid detergents or cleaning liquid ingredients such as perfume oils or nonionic surfactants.

The problem with such an incorporation is that the liquid may undesirably leak out, so that sticky products can easily occur. In addition, often only small amounts of liquid can be incorporated into solid agents, so that e.g. the solid matrix can absorb only a maximum of 5 wt .-% or less of liquid. In addition, the mechanical stability of the solid matrix often suffers when it is loaded with liquid, i. the resulting particles become more fragile. This is undesirable because such agents are often used in large containers, e.g. Silos, to be stored. If then the fragility of the particles is too high, the particles can easily be crushed by the pressure of their own weight.

There is therefore still the need for systems which are able to absorb preferably also large amount of liquids, safely store and release only delayed in time. The satisfaction of such need was the object of this invention.

This object is achieved by the subject matter of the invention, which is fluid-containing particles obtainable by agglomeration of carrier material in the presence of a granulation liquid comprising carbohydrates and / or derivatives thereof, followed by the application of a liquid to be incorporated.

Advantageously, these particles may contain larger amounts of liquid, such as perfume oil, but still have a very good flowability and mechanical stability and do not tend to lump. Furthermore, the incorporated in the particle liquid is now protected and can be easily incorporated into other, eg aggressive, solid matrices without there is to be expected with a decomposition of the incorporated liquid. Using the example of the perfume oils as incorporated liquid, this means that improved fragrance properties or improved fragrance stability are achieved.

If the liquid to be incorporated a) fragrances (perfume oils) b) liquid detergents and cleaning agent ingredients, such as preferably surfactants, especially nonionic surfactants, silicone oils, paraffins c) liquid cosmetic ingredients, preferably oils d) liquid non-pharmaceutical additives or active ingredients and / or e ) Mixtures of the aforementioned, so there is a preferred embodiment. In particular, the use of fragrances is advantageous. The perfume-laden particles are characterized by good odor resistance, even when incorporated into aggressive matrices, e.g. in detergent powder to flavor it.

Even if very large amounts of liquid, in particular fragrances are incorporated in the particles, the particles retain their advantageous properties. Thus, according to a preferred embodiment, the particles according to the invention may contain> 5% by weight, preferably> 10% by weight, advantageously> 15% by weight, in particular> 20% by weight or even> 25% by weight of incorporated liquid , preferably fragrances (perfume oils).

The liquid incorporated or to be incorporated into the agglomerate may also contain solids. If the solids content of the liquid to be incorporated is less than 50%, preferably less than 30%, advantageously less than 25%, in particular less than 15%, most preferably less than 10%, based on the liquid to be incorporated, then there is another preferred embodiment. In particular, the liquid to be incorporated is free of solids.

As perfume oils, for example, individual fragrance compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used. Fragrance compounds of the ester type are known e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, ethyl methyl phenyl glycinate,

Allylcyclohexylpropionate, styrallylpropionate and benzylisalicylate. The ethers include, for example, benzyl ethyl ether, to the aldehydes, for example, the linear alkanals with 8 -18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, Hydroxycitronellel, Lilial and Bourgeonal, to the ketones such as the ionone, isomethylionone and methyl cedrylketone to the alcohols anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol, to the Hydrocarbons mainly include the terpenes and balsams. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.

The perfume oils may, of course, also contain natural fragrance mixtures, such as are available from plant or animal sources, e.g. Pine, citrus, jasmine, lily, rose or ylang-ylang oil. Also, lower volatility volatile oils, which are most commonly used as aroma components, are useful as perfume oils, e.g. Sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, galbanum oil and ladanum oil.

According to the invention, in particular fragrances can be used which are selected from fragrances with

(a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 5-methylfurfural, methylbutanal, furfural and / or acetophenone or

(b) apple-like odor, preferably (S) - (+) - ethyl-2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-damascone, heptyl-2-methyl butyrate, methyl 3-methylbutanoate, 2-hexenal-pentyl-methyl butyrate, ethyl methyl butyrate and / or methyl 2-methyl butanoate or

(c) apple peel-like odor, such as preferably ethylhexanoate, hexylbutanoate and / or hexylhexanoate or

(d) apricot-like odor, preferably γ-undecalactone, or

(e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or

(f) bitter almond-like odor such as preferably 4-acetyltoluene or

(g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or

(c) citrus-like odor such as preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cubebene, (Z) limonene oxide, cis-6-ethenyl-tetrahydro-2,2,6- trimethylpyran-3-ol, cis-pyranoidlinalooloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-farnesene, (Z) -cime, (E) -liminene oxide, dihydrotypinyl acetate, (+) -Limonen, (Epoxymethylbutyl) -methylfuran and / or p-cymene or

(i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or

(j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or

(I) flower-like odor such as preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epi-γ-eudesmol , Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -oximes, cetyl alcohol, nerolidol, ethyl (E) -cinnamate, elemicin, pinocarveol, α-bisabolol, ( 2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemicin, methyl 2-methylpropanoate, trimethylphenylbutenone, 2-methylanisole, β-farnesol, ( E) - isoeugenol, nitro-phenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, trimethylphenylbutenone, ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenone or

(m) freshness odor, preferably methylhexanoate, undecanone, (Z) -imimonial oxide, benzyl acetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, β-elemene, α-zingiberene, (E) -lownone oxide, (E) -p-mentha- 2,8-dien-1-ol, menthone, piperitone, (E) -3-hexenol and / or carveol or

(n) fruit odor, such as ethylphenylacetate, geranylvalerate, γ-heptalactone, ethylpropionate, diethylacetal, geranylbutyrate, ethylheptylate, ethyloctanoate, methylhexanoate, dimethylheptenal, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, lobutylacetate, ethoxypropanol, methyl-2-butenal, Methylnonanedione, linalyl acetate, methyl geranate, ammonium oxide, hdrocinnamiccohol, ethylsuccinate, ethylhexanoate, ethylmethylpyrazine, ethyl acetate, cetronellyl butyrate, heyl acetate, nonyl acetate, butylmethyl butyrate, pentenal,

Isopentyldimethylpyrazine, p-menth-1-en-9-ol, hexadecanone, octylacetate, γ-dodecalactone, epoxy-β-ionone, ethyloctenoate, ethylisohexanoate, isobornylpropionate, cedrenol, p-menth-1-en-9-yl acetate, cadinadiene , (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone, 3,5-octadienone, methylcyclohexanecarboxylate, 2-pentylthiophene, α-ocimene, butanediol, ethylvalerate, pentanol, isopiperiton, butyloctanoate, ethyl vanillate, methylbutanoate, 2 Methylbutyl acetate, propylhexanoate, butylhexanoate, isopropylbutanoate, spathulenol, butanol, .delta.-dodecalactone, methylquinoxaline, sesquiphellandrene, 2-hexenol, ethylbenzoate.isopropylbenzoate, ethyllactate and / or citronellylisobutyrate or

(o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadienal, octadienone and / or o-xylene or

(p) grape-like odor such as preferably ethyl decanoate and / or hexanone or

(q) grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenylbicyclo [4.4.0] dec-1-en-3-one and / or p-menthenethiol or

(R) grassy odor such as preferably 2-ethylpyridine, 2,6-dimethylnaphthalene, hexanal and / or (Z) -3-hexenol or

(s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenal, cis Linalool, pyranoxide, nonanol, alpha, v- dimethylallylalcohol, (Z) -2-penten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) -4-decenal, 2-octenal, 2- hepten-1-al, bicyclo mermose, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadienal, fucoserrate, hexenyl acetate, geranylacetone, valencene, β-eudesmol, 1-hexenol, (E) -2-undecenal, artemisia ketone, viridiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadienal, butylisothiocyanate, 2-pentanol, elemole, 2-hexenal, 3-hexenal, (+) - (E) -Limone oxide, cis-isocitral, dimethyloctadienal, bornyl formate, bornyl isovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, (+) - cis-rose oxides, menthone, coumarin, ( Epoxymethylbutyl) -methylfuran, 2-hexenol, (E) -2-hexenol and / or carvylacetate or

(t) Green Tea-like odor, preferably (-) - Cubenol or

(u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides, methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisabolol, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol , 1, 5,9,9-Tetramethyl-12-oxabicyclododeca-4,7-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl Acetate, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, Hydroxypentanone, (Z) -Ocimene, β-Elemene, δ-Cadinol, (E) -β-Ocimene, (Z) -dihydrocarvone, α-Cadinol, Calamenene, (Z) -Piperitol. Lavandulol, β-bourbonene, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) -benzenemethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p-2-menthene 1-ol, α-curcumene, spathulenol, sesquiphellandrene, citronellyl valerate, bornyl isovalerate, 1, 5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or hydroxycalamene or

(v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenones, ethyl (E) cinnamate, 2-phenylethyl alcohol, citronellyl valerates, phenylethyl benzoates and / or eugenol or

(w) Hyacinth-like odor, preferably Hotrienol or

(x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or

(y) lavender-like odor, preferably linalyl valerate and / or linalool or

(z) lemon-like odor, preferably neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1, 8-cineol and / or α-terpinene or

(aa) lily-like odor, preferably dodecanal or

(bb) magnolia-like odor, preferably geranylacetone or

(cc) mandarin-like odor, preferably undecanol or

(dd) melon-like odor, preferably dimethylheptenal or

(ee) minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7-tetrahydro-3,6-dimethylbenzofuran, epoxy-p-menthene, geranial, (methylbutenyl) methylfuran, dihydrocarvylacetate , β-cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (+) - 1-imone, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, isopulegyl acetate, Piperitone, 2,3-dehydro-1, 8-cineole, α-terpineol, DL-carvone and / or α-phellandrene or (ff) Nutty odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or

(gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or

(hh) orange peel-like odor, preferably decanal and / or beta-carene or

(ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or

(jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or

(kk) Pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or

(II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or

(mm) plum-like odor, preferably benzyl butanoate, or

(nn) raspberry-like odor, preferably β-ionone or

(oo) Rose-like odor, preferably β-phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1-) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or

(pp) spearmint-like odor, preferably carvylacetate and / or carveol, or

(qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or

(rr) sweet odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methylhexanoate, linalyl isovalerate, undecanedehyde, caryophyllene oxide, linalyl acetate, safranal, uncinol, phenylethanal, p-anisaldehyde, eudesmol, ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3-pentene-2 -on, nonyl acetate, 10-epi-γ-eudesmol, β-bisabolol, (Z) - 6-dodecene-γ-lactone, β-farnesene, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal , Styrene glycol, methyl furanane, (-) - cis-rose oxide, (E) -β-octenes, dimethylmethoxyfuranone, 1,8-cineols, ethylbenzaldehyde, 2-pentylthiophene, α-farnesene, methionol, 7-methoxycoumarin, (Z) -3 -Hexenyl 2-methylbutanoate, o-aminoacetophenone, viridiflorol, isopiperitones, β-sinensal, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone, sesquiphellandrene, diethyl malate, linalyl butyrate, guaiacol, coumarin , Methyl benzoate, isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or furfural or

(ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or

(tt) watermelon-like odor, preferably 2,4-nonadienal or (uu) woody odor, preferably α-muurolens, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ Eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ-eudesmol, germacrene B, trans-sabin hydrate, dihydrolinalool, isodihydrocarveol, β-farnesene, β-sesquiphellandrene, δ- Elemene, α-calacorene, epoxy-β-ionone, germacrene D, bicyclo mermose, alloaromadendrene, α-thujene, oxo-β-ionone, (-) - γ-elemene. Y-Muurolene, Sabinene, α-Guaienes, α-Copenes, γ-Cadinenes, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinenes, 4,5-Dimethoxy-6- (2-propenyl) -1, 3 benzodioxole, [1 aryl]

(1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro-1, 1, 7-trimethyl-4-methylene-1H-cyclopropyl [e] azulen, α-gurdyen, guaiol, α-farnesene, γ- Selenins, 4- (1-methylethyl) benzene-methanol, perillene, elemole, α-humulenes, β-caryophyllene and / or β-guaiene or

(vv) mixtures of the above.

The liquid incorporated in the agglomerate may preferably contain liquid cosmetic ingredients, such as e.g. Oils included.

Preferred oils may advantageously contain fully synthetic oils such as e.g. Silicone oils, vegetable and / or animal fatty oils (triglycerides of medium or unsaturated fatty acids) and / or essential oils (e.g., from plant parts).

The liquid incorporated or to be incorporated into the agglomerate may preferably contain one or more skin-care and / or skin-protecting active substances. Skin-care active substances are all those active substances which give the skin a sensory and / or cosmetic advantage. Skin-care active substances are preferably selected from the following substances: a) waxes such as, for example, carnauba, spermaceti, beeswax, lanolin and / or derivatives thereof and others. b) Hydrophobic plant extracts c) Hydrocarbons such as squalene and / or squalane d) Higher fatty acids, preferably those having at least 12 carbon atoms, for example lauric acid, stearic acid, behenic acid, myristic acid, palmitic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid and / or multiple times unsaturated fatty acids and others. e) Higher fatty alcohols, preferably those having at least 12 carbon atoms, for example, lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cholesterol and / or 2-hexadecanol and others. f) esters, preferably such as cetyloctanoates, lauryl lactates, myristyl lactates, cetyl lactates, isopropyl myristates, myristyl myristates, isopropyl palmitates, isopropyl adipates, butyl stearates, decyl oleates, cholesterol stearates, glycerol monostearates, glycerol distearates, glycerol tristearates, alkyl lactates, alkyl citrates and / or alkyl tartrates and others. g) lipids such as cholesterol, ceramides and / or sucrose esters and others. h) vitamins such as vitamins A and E, vitamin C esters, including vitamin C.

Alkyl esters and others, i) sunscreens j) phospholipids k) derivatives of alpha-hydroxy acids I) fragrances m) germicides for cosmetic use, both synthetic and, for example, salicylic acid and / or other natural as well as neem oil and / or others, n) silicones and mixtures of any of the aforementioned components.

The liquid to be incorporated in the agglomerate may preferably contain antiseptic oil, preferably essential oil selected in particular from the group of Angelica fine - Angelica archangelica, Anis - Pimpinella anisum, Benzoin siam - Styrax tokinensis, Cabreuva - Myrocarpus fastigiatus , Cajeput - Melaleuca leucadendron, Cistus - Cistrus ladaniferus, Copaiba balm - Copaifera reticulata, Costus root - Saussurea discolor, Edeltann needle - Abies alba, Elemi - Canarium luzonicum, Fennel - Foeniculum dulce Spruce needle - Picea abies, Geranium - Pelargonium graveolens, Ho leaves - Cinnamonum camphora, Immortelle Helichrysum ang., Ginger extra - Zingiber off., St. John's wort - Hypericum perforatum, Jojoba, German chamomile - Matricaria recutita, Chamomile blue fine - Matricaria chamomilla, Chamomile rom. - Anthemis nobilis, Chamomile wild Ormensis multicaulis, carrot - Daucus carota, mountain pine - Pinus mugho, Lavandin - Lavendula hybrida, Litsea Cubeba - (May Chang), Manuka - Leptospermum scoparium, Melissa - Melissa officinalis, Sea pine - Pinus pinaster, Myrrh - Commiphora molmol, Myrtle - Myrtus communis, Neem - Azadirachta, Niaouli - (MQV) Melaleuca quin, viridiflora , Palmarosa - Cymbopogom martini, Patchouli - Pogostemon patchouli, Peru balsam - Myroxylon balsamum var. Pereirae, Raventsara aromatica, Rosewood - Aniba pink odora, Sage - Salvia officinalis Horsetail - Equisetaceae, yarrow extra - Achillea millefolia, plantain lanceolata, Styrax - Liquidambar orientalis, Tagetes (Marigold) Tagetes patula, Tea Tree - Melaleuca alternifolia, Tolu Balsam - Myroxylon Balsamum L., Virginia Cedar - Juniperus virginiana, Frankincense (Olibanum) - Boswellia carteri, Silver Fir - Abies alba.

The liquid incorporated or to be incorporated into the agglomerate may preferably contain skin-protecting active substances, advantageously skin-protecting oil. The skin-protecting substance is advantageously a skin-protecting oil, for example also a carrier oil, in particular selected from the group algae oil Oleum Phaeophyceae, Aloe vera oil Aloe vera brasiliana, apricot kernel oil Prunus armeniaca, arnica Arnica montana, avocado oil Persea americana, Borage oil borago officinalis, calendula oil Calendula officinalis, camellia oil Camellia oleifera, safflower oil Carthamus tinctorius, peanut oil Arachis hypogaea, hemp oil Cannabis sativa, hazelnut oil Corylus avellana /, hypericum perforatum St. John's wort oil, jojoba oil Simondsia chinensis, caraway oil Daucus carota, coconut oil Cocos nucifera, pumpkin seed oil Curcubita pepo, kukui nut oil Aleurites moluccana, macadamia nut oil Macadamia ternifolia, Almond oil Prunus dulcis, olive oil Olea europaea, pear seed oil Prunus persica, rapeseed oil Brassica oleifera, castor oil Ricinus communis, black seed oil Nigella sativa, sesame seed oil Sesamium indicum, sunflower oil Helianthus annus, grape seed oil Vitis vinifera, walnut oil Juglans regia, wheat germ oil Triticum sativum, of which in particular the borage oil Hemp oil and almond oil are beneficial.

The liquid incorporated in the agglomerate may preferably contain moisturizing factors, for example, those selected from the following group: amino acids, chitosan or chitosan salts / derivatives, ethylene glycol, glucosamine, glycerin, diglycerin, triglycerin, uric acid, honey and hardened honey , Creatinine, cleavage products of collagen, lactitol, polyols and polyol derivatives (for example, butylene glycol, erythritol, propylene glycol, 1, 2,6-hexanetriol, polyethylene glycols such as PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18, PEG-20), pyrrolidonecarboxylic acid, sugar and sugar derivatives (for example, fructose, glucose, maltose, maltitol, mannitol, inositol, sorbitol, sorbitylsilanediol, safenose, Trehalose, xylose, xylitol, glucuronic acid and salts thereof), ethoxylated sorbitol (sorbeth-6, sorbeth-20, sorbeth-30, sorbeth-40), hardened starch hydrolysates and mixtures of hardened wheat protein and PEG-20 acetate copolymer, esp other panthenol.

As carriers, in principle, all known carrier materials in question. However, if the carrier material comprises anionic carrier material, advantageously zeolite and / or layered silicate, preferably bentonite, then a preferred embodiment is present.

The presence of inorganic carrier material also offers optical advantages because the resulting particles can thereby obtain a crystalline appearance, especially when solid additives in crystal form, preferably sugar and / or salt (e.g., common salt, sea salt, etc.), e.g. be added before agglomeration.

Thus, if the aggregate prior to agglomeration solid additives in crystal form, preferably sugar and / or salt are added, advantageously in amounts of> 10 wt .-%, more preferably> 20 wt .-%, more preferably> 30 wt .-%, in particular in amounts of 40-55 wt .-% based on the total solids to be agglomerated, so is a preferred embodiment. Fluid-containing particles according to such an embodiment are characterized in that they have a particularly attractive crystal form and yet can contain large amounts of liquid. The crystal form gives the consumer the impression of optically high-quality goods.

Alternatively, the optional addition of sugar and / or salt can also take place only before the application of the liquid to be incorporated. Thus, if solid agglomerated additives in crystal form, preferably sugar and / or salt, are added to the carrier material after agglomeration, advantageously in amounts of> 10% by weight, more preferably> 20% by weight, more preferably> 30% by weight .-%, in particular in amounts of 40-55 wt .-% based on the total solids to be agglomerated, so is a preferred embodiment. The agglomerated carrier material and the sugar and / or the salt are thus mixed with each other in such a case prior to the application of the liquid to be incorporated (mixed).

In the context of the invention, it is generally advantageous, even independently of the addition of solid aggregates in crystal form, if the fluid-containing particles> 30 wt .-%, preferably> 40 wt .-%, advantageously> 50 wt .-%, in particular> 60 wt .-% of zeolite and / or bentonite.

If the carrier material to be used according to the invention comprises spray-dried material, preferably tower powder, a particularly preferred embodiment is present.

The tower powder is obtained in a known way by spray drying. In this case, the material to be dried (liquid solution or suspension, eg an aqueous slurry thermally stable detergent ingredients that neither volatilize nor decompose under the conditions of spray drying such as surfactants, builders, adjusting agents) at the upper end of a wide, cylindrical container through nozzles or sprayed by means of a rapidly rotating atomizer disk to a fine mist. The resulting spray cone, for example hot air (eg with a temperature of 250 to 350 ⁰ C) or an inert gas led from below. The supply of the drying gas can also be carried out in direct current from above, for example in the case of very temperature-sensitive products (eg enzymes, active microorganisms). The dry material falls as more or less fine powder, as granules or in the form of small beads (prills) down and is discharged at the bottom of the dryer.

According to a preferred embodiment of the present invention, the fluid-containing particles according to the invention are characterized in that the carrier material has been agglomerated at high pressure (preferably> 10000 Pa). In particular, a corresponding agglomeration process preferably proceeds under high pressures by means of rolling and then Breaking the slugs off. For this type of agglomeration, preferably pressures above 10000 Pa are needed.

The granulation liquid according to the invention comprises carbohydrates and / or derivatives thereof; modified carbohydrates, e.g. Carboxymethylcellulose (CMC). Preferably, it is an aqueous granulation liquid, advantageously one with a CMC content <8 wt .-%, advantageously <6 wt .-%, in particular from 5.5 wt .-% to 3 wt .-%.

When the granulation liquid according to the invention

(a) cellulose (derivatives) such as carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxypropylmethyl cellulose, methyl cellulose, ethyl cellulose, methyl hydroxyalkyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, ethyl hydroxyethyl cellulose, cationically modified hydroxyethyl cellulose and / or hydroxypropyl cellulose,

(b) Starch (derivatives) such as carboxymethyl starch (starch carboxymethyl ether), hydroxyethyl starches, hydroxypropyl starches, cationic starch (derivatives)

(c) mono-, oligo- and / or polysaccharide (derivatives) e, in particular ribose, xylose and arabinose, glucose, mannose, galactose, fructose, sorbose, fucose, rhamnose, sucrose (cane sugar or beet sugar), maltose (malt sugar ), Lactose (milk sugar), trehalose, cellobiose, gentiobiose, isomaltose, lactulose, melibiose, neohesperidose, neotrehalose, nigerose, palatinose, xanthan, dextran, chitosan and / or alginates

(d) comprises mixtures of the above, there is also a preferred embodiment.

The agglomeration according to the invention is advantageously characterized in that the particles thereby grow (preferably to sizes of 0.2 to 1, 4 mm) that the agglomerated particles are not sealed for the absorption of liquids. Very preferred granulation liquids for this purpose are the aqueous solutions of carboxymethylcelluloses.

If the granulation liquid according to the invention has a solvent content, preferably water content, of greater than 80% by weight, advantageously 90-99% by weight, advantageously of 94-98% by weight, then a further preferred embodiment is present.

If the granulation liquid according to the invention contains a proportion of carbohydrates and / or derivatives of <10% by weight, advantageously <8% by weight, advantageously <6% by weight, in particular from 5.5% by weight to 3% by weight. -%, so is another preferred embodiment. Accordingly, it is possible, for example, to prepare granules according to the invention by intensively mixing spray-dried zeolite powder, for example in a ploughshare mixer, with an aqueous CMC solution, and then removing the water in a fluidized bed. The granules formed can then be impregnated with the liquid components, such as perfume. According to a preferred embodiment, the granules are thus at least partially removed before being exposed to the liquid components, such as perfume. Preferably, in such case, the water content is <25% by weight, preferably <20% by weight, advantageously <15% by weight, more preferably <10% by weight, especially <6% by weight or even <4% by weight .-% adjusted, for example by treatment in a fluidized bed. Water contents of not more than 3% by weight or not more than 2% by weight or not more than 1% by weight are also possible. Not included here in each case was the presence of any existing aluminosilicates such as zeolite water.

By agglomeration of carrier material in the presence of a granulating liquid with Kohlenhy- raadanteil, possibly followed by subsequent water reduction, and then incorporation of a liquid, such. a perfume oil, so you get to fluid-containing particles that have very good powder properties even at high liquid loading and safely store the incorporated liquid even in the presence of aggressive Feststoffmatrices. These fluid-containing particles can be used, for example, for a variety of fragrancing purposes.

As has already been clarified, the fluid-containing particles according to the invention can contain larger amounts of liquid. They also represent a kind of liquid depot. Because the liquid contained, e.g. Perfume, may in use, e.g. Textile laundry, be released again and unfold their effect, e.g. in perfume the fragrance effect. The stored liquid remains safely incorporated into the particles before use.

It is also possible to incorporate ingredients into the particles, which are solid at room temperature but liquid at elevated temperatures, preferably those ingredients whose pour points are in the temperature range from 30 ⁰ C to 260 ⁰ C, such as polyester or carbohydrates such as Disaccharides from the Isomaltitfamilie.

For example, To further improve this storage effect of the particles according to the invention, but also independently, it is possible to coat the fluid-containing particles. Coated fluid-containing particles, which are preferably powdered and / or coated with a film, constitute a preferred embodiment of the invention.

The coating according to the invention may comprise colored substances, dyes, brighteners and / or pigments, advantageously in the nanoscale range or in the micrometer range, which corresponds to a preferred embodiment. According to the invention, fluid-containing particles which are coated with a thermoplastic, such as preferably PEG, PVA, polyacrylates, PVP, carbohydrates, polyesters such as preferably PET, represent a preferred embodiment of the invention.

In view of a possibly desired crystal-like appearance of the particles according to the invention, the use of the aforementioned thermoplastics, such as Medium MW PEGs between 3,000 and 10,000 are very advantageous because these thermoplastics can form crystalline forms upon solidification.

All other coating agents can also be used for the coating according to the invention. Coating agents are e.g. Substances which, for example, give the outer surface of the object to be coated (coating) a shiny appearance and / or form a coating (an envelope) on the outer surface. As coating agent, solid and / or liquid substances may be used, preferably those which prevent or delay moisture penetration or prevent or delay flavor loss.

Suitable coating agents may e.g. water-soluble, water-dispersible and / or water-insoluble (co) polymers. The coating layer as such may e.g. be water-soluble or water-insoluble.

Water-soluble polymers contain a sufficient number of hydrophilic groups for water solubility and are advantageously not crosslinked. The hydrophilic groups may be nonionic, anionic, cationic or zwitterionic, for example, -NH _2, -OH, -SH, - O-, -COOH, - COO ^{"M +,} - ^SO3" M ^+, -PO ₃ ^2- M ^{2 +} , -NH ₃ ⁺ ,

-NH-C-NHa ₁ -NH-C-NH ₂ _ | _etc.

The individual polymers may simultaneously contain different hydrophilic groups, e.g. ionic and nonionic and / or anionic besides cationic groups.

Preferred water-soluble polymers may be e.g. natural polysaccharides and / or polypeptides, e.g. Starch, alginates, pectins, vegetable gums, caseins, gelatin, etc.

Preferred water-soluble polymers may be e.g. semi-synthetic polymers, e.g.

Cellulose ether or starch ether.

Preferred water-soluble polymers may be e.g. biotechnologically produced products, e.g.

Pullulan, curdlan or xanthan be. Preferred water-soluble polymers may be, for example, synthetic polymers, such as, for example, homopolymers and / or copolymers of (meth) acrylic acid and its derivatives, maleic, vinylsulfonic, vinylphosphonic, polyvinylalcohol, polyethylenimine, polyvinylpyrrolidone and the like. Preferred coating compositions contain water-soluble (co) polymer, in particular with a melting ^o ^ ^he softening point ranging from 48 ° C to 300 ⁰ C, advantageously in the range of 48 ° C to 200 ⁰ C, in a further advantageous manner in the range of 48 ⁰ ° C to 200 C. Suitable water-soluble (co) polymer with a suitable melting or softening point can be advantageously selected from the group consisting of polyalkylene glycols, polyethylene terephthalates, polyvinyl alcohols and mixtures thereof.

The optional coating (coating) may comprise, in addition to the actual coating agent or else independently thereof, further constituents, e.g. advantageously textile softening compounds and / or perfume.

It is also possible to coate the particles several times, for example by first coating the particles with a first coating, e.g. comprising a fabric softening compound, and thereafter surrounding the resulting object with another wrapper, e.g. containing water-soluble polymer and perfume.

According to a preferred embodiment, the optional coating contains lipids and / or

Silicone oils.

Preferred lipids are

(a) lipophilic hydrocarbons (such as triacontane, squalene or carotenoids, etc.),

(b) lipophilic alcohols (such as wax alcohols, retinol or cholesterol, etc.),

(c) ether lipids

(d) lipophilic carboxylic acids (fatty acids),

(e) lipophilic esters [such as neutral fats - i. Mono-, Di- u. Triacylglycerols (triglycerides), sterol esters, etc.]

(f) lipophilic amides (such as ceramides, etc.),

(g) waxes

(h) lipids with more than 2 hydrolysis products, e.g. Glycolipids, phospholipids, sphingolipids and / or glycerolipids etc. (i) lipids in the form of higher molecular weight conjugates with more than 2 hydrolysis products, e.g.

Lipoproteins and / or lipopolysaccharides etc., (j) Phosphorus-free glycolipids, such as glycosphingolipids (such as, preferably, cerebrosides,

Gangliosides, sulphatides) or as e.g. Glycoglycerolipids (preferably glycosyl di- and monoglycerides), etc. (k) carbohydrate-free phospholipids, e.g. Sphingophospholipids (as preferably

Sphingomyelin) or as e.g. Glycerophospholipids (such as preferably lecithins, cephalins,

Cardiolipins, phosphatidylinositols and inositol phosphates, etc.) (I) Mixtures of the foregoing.

In a further preferred embodiment, the optional coating comprises colored substances or dyes, brighteners and / or pigments, advantageously in the nanoscale range or in the micrometer range, preferably white pigments, in particular selected from titanium dioxide pigments, in particular anatase pigments and / or rutile Pigments, zinc sulfide pigments, zinc oxide (zinc white), antimony trioxide (antimony white), basic lead carbonate (lead white) 2PbCO ₃ Pb (OH) ₂ , lithopone ZnS + BaSO ₄ . Preferably, white auxiliaries, such as preferably calcium carbonate, talc 3MgO ^■ 4SiO ₂ ^■ H ₂ O and / or barium sulfate may be included.

In another preferred embodiment, the pigments, which may preferably be components of an optional coating, may be

(a) colored pigments (preferably inorganic colored pigments, in particular iron oxide pigments, chromate pigments, iron blue pigments, chromium oxide pigments, ultramarine pigments, mixed oxide phase pigments and / or bismuth vanadate pigments),

(b) black pigments (e.g., aniline black, perylene black, iron oxide pigments, manganese black and / or spinel black),

(c) luster pigments (preferably platelet-shaped effect pigments, metallic effect pigments such as aluminum pigments (silver bronze), copper pigments and copper / zinc pigments (gold bronze) and zinc pigments, pearlescent pigments such as magnesium stearate, zinc stearate, lithium stearate or ethylene glycol distearate or Polyethylene terephthalate, interference pigments such as metal oxide mica pigments) and / or

(d) luminescent pigments such as e.g. Azomethine fluorescence yellow, silver-doped and / or copper-doped zinc sulfide pigments act.

The optional coating may preferably also comprise the following substances:

(a) carbonates, such as preferably chalk, limestone, calcite and / or precipitated calcium carbonate, dolomite and / or barium carbonate

(b) sulphates, such as preferably barite, blanc-fixed and / or calcium sulphates

(c) silicates, such as preferably talc, pyrophyllite, chlorite, hornblende, mica, kaolin (a) wollastonite, slate meal, precipitated Ca, Al, Ca / Al, Na / Al silicates, feldspars and / or minerals

(d) silicas such as, preferably, quartz, fused silica, cristobalite, diatomaceous earth, Neuburg Siliceous Earth, precipitated silica, fumed silica, glass flour, pumice, perlite, Ca-metasilicates and / or fibers from melts of glass, basalt, slags

(E) oxides, in particular aluminum hydroxide and / or magnesium hydroxide

(F) organic fibers, such as in particular textile fibers, cellulose fibers, polyethylene fibers, polypropylene fibers, polyamide fibers, polyacrylonitrile fibers and / or polyester fibers, preferably with lengths in the nanometer or micrometer range and / or

(g) flours, e.g. Starch flours.

The use of such pigments can further enhance a desired crystalline appearance of the particles.

According to a further preferred embodiment, the optional coating of the particles according to the invention is pH and / or temperature and / or ionic strength-sensitive or contains pH and / or temperature and / or ionic strength-sensitive materials.

By the term of pH sensitivity, temperature sensitivity and / or ionic strength sensitivity is meant that the coating or the materials forming the coating with a change in the pH, the temperature and / or the ionic strength in the environment, which is exposed to the coating (eg a wash liquor),

(a) undergoes a change (increase or decrease) in solubility (preferably in water); and or

(b) undergoes a change (increase or decrease) in diffusion density; and or

(c) undergoes a change (acceleration or deceleration) in the solution kinetics; and or

(d) undergoes a change (increase or decrease) in mechanical stability.

In addition to the options (a) to (d) mentioned above, the temperature sensitivity also has the additional option (e) according to which the coating or the materials forming the coating change the physical state from solid to liquid when the temperature changes or vice versa, ie the materials melt or solidify.

If the average particle size of the particles according to the invention is between 0.1 and 2.0 mm, preferably 0.15 and 1.5 mm, in particular 0.2 and 1.2 mm, this is a preferred embodiment of the invention. It is then also a preferred embodiment of the invention, when the fluid-containing particles solids from the group of silicates, phosphates, urea and / or its derivatives, sulfates, carbonates, citrates, citric acid, acetates and / or salts of anionic surfactants.

Preferably, however, solids from the group of silicates, phosphates, urea and / or its derivatives, sulfates, carbonates, citrates, citric acid, acetates and / or salts of anionic surfactants are contained in a particle according to the invention only in a limited amount, e.g. in amounts of <60% by weight, <50% by weight, <40% by weight, <30% by weight, <20% by weight, <10% by weight or <5% by weight , based on the total particle. According to a preferred embodiment, the particles according to the invention can be completely free of solids from the group of silicates, phosphates, urea and / or its derivatives, sulfates, carbonates, citrates, citric acid, acetates and / or salts of anionic surfactants.

In general, however, it may be advantageous if the fluid-containing particles according to the invention comprise further ingredients. Contain at least one further, preferably two further or more usually contained in detergents or cleaning agents, preferably a substance from the group of surfactants, builders (inorganic and organic builders), bleaching agents, bleach activators, bleach stabilizers, bleach catalysts, enzymes, special Polymers (for example those with co-builder properties), grayness inhibitors, optical brighteners, UV protectants, soil repellents, electrolytes, colorants, fragrances, fragrances, perfume carriers, pH adjusters, complexing agents, fluorosurfactants, foam inhibitors, Anti-wrinkling agents, antioxidants, quaternary ammonium compounds, anti-static agents, ironing aids, UV absorbers, anti-redeposition agents, germicides, antimicrobial agents, fungicides, viscosity regulators, pearlescers, color transfer inhibitors, anti-shrinkage agents, corrosion inhibitors, preservatives, plasticizers, fabric softeners , Proteinhydroly-sate, repellents and impregnating agents, hydrotropes, silicone oils and swelling and anti-sliding agents, so is a preferred embodiment.

It is also possible to incorporate ingredients into the particles which are solid at room temperature (20 ^° C.) but liquid at elevated temperatures, advantageously selected from the group of fatty alcohols, fatty acids, silicones (silicone oils), paraffins, nonionic surfactants, esterquats , Glycerides of fatty acids (natural oils), waxes, mono-, di- or triglycerides, carbohydrates and / or polyalkylene glycols, preferably those ingredients whose pour points in the temperature range of 25 ° C to 120 ⁰ C.

As carbohydrates, for example, sugars are advantageously used here, for example, alpha-D-glucose monohydrate (melting point in the range 83-86 ° C), alpha-D-galactose monohydrate (melting point in the range of 118-120 ⁰ C) or maltose, for example Monohydrate (melting point in the range 102-103 ° C), to give a few examples. Also suitable are the derivatives, such as, for example, amino sugars, such as D-glucosamine (melting point α-form: 88 ⁰ C), or such as deoxysugar, such as rhamnose monohydrate (melting point 92-94 ° C).

Suitable paraffins may e.g. Octadecane, nonadecane, eicosan, docosan, tricosane, tetracosane, pentacosan, hexacosan, heptacosan, octacosan, nonacosan or triacosane, to name but a few.

Suitable fatty alcohols may be, for example, 1-tridecanol, 1-tetradecanol, 1-pentadecanol, 1-hexadecanol, 1-heptadecanol, 1-octadecanol, 9-trans-octadecen-1-ol, 1-nonadecanol, 1-eicosanol, 1-heneicosanol. 1-docosanol, 13-cis-docosen-1-ol, 3-trans-docosen-1-ol, to name just a few examples. These include the so-called waxy coal, ie fatty alcohols with about 24-36 carbon atoms, such as triacontanol-1 or melissyl alcohol. These include unsaturated fatty alcohols such as Elaidyalkohol, Erucaalkohol or Brassidylalkohol. These include Guerbet alcohols, such as C ₃₂ H ₆₆ O or C ₃₆ H ₇₄ O. These include alkanediols, such as undecanediol-1, 11 or dodecanediol-1, 12th

Suitable nonionic surfactants may be, for example, fatty alcohol polyglycol ethers, such as C ₁₄ H ₂₉ -O- (CH ₂ CH ₂ O) ₂ H, C-i ιoH ₂ "0- (CH ₂ CH ₂ 0) ₈ H, C ₁₂ H ₂₅ -O - (CH ₂ CH ₂ O) ₆ H, C _1-4 H ₂₉ -O- (CH ₂ CH ₂ O) ₄ H, C ₁₆ H ₃₃ - 0 - (CH ₂ CH ₂ O) ₁₂ H, C ₁₈ H ₃₇ -O- (CH ₂ CH ₂ O) ₄ H, to name just a few examples.

Suitable fatty acids may be e.g. its capric, undecanoic, lauric, tridecanoic, tetradecanoic, pentadecanoic, palmitic, margaric, stearic, nonadecanoic, arachidic, behenic, lignoceric, cerotic, crotonic, erucic, elaeostearic or melissic acids, to name but a few.

Also suitable may be the esters of fatty acids, e.g. the methyl or ethyl esters of behenic acid or arachidic acid, for example.

Also suitable are mono-, di- or triglycerides, e.g. the corresponding glycerides of lauric acid, palmitic acid or capric acid, to give a few examples.

Suitable waxes may be natural detergents such as carnauba wax, candelilla wax, esparto wax, guaruma wax, Japan wax, cork wax or montan wax, as well as animal washes such as beeswax, wool wax, shellac wax or spermaceti, as well as synthetic waxes such as polyalkylene waxes or polyethylene glycol waxes, as well as chemically modified waxes Waxes, such as hydrogenated jojoba waxes or montan ester waxes. Another object of the invention are detergents or cleaning compositions containing inventive fluid-containing particles. The term washing or cleaning agents also includes the textile pretreatment agents, aftertreatment agents, treatment agents, conditioners, softeners and fabric softeners.

In the following preferred ingredients of detergents or cleaning agents according to the invention are described in detail. These constituents mentioned below can be present as such both in the fluid-containing particles according to the invention and in the detergents or cleaners according to the invention. In the following, although reference is generally made only to the washing or cleaning agents according to the invention. However, all of the ingredients mentioned below may, at least optionally, also be contained in the fluid-containing particle according to the invention, this being explicitly clarified here.

Anionic surfactants are preferably contained in the detergents or cleaners according to the invention. As anionic surfactants, for example, those of the sulfonate type and sulfates are used. The surfactants of the sulfonate type are preferably C ₉ . _13- Alkylbenzol- sulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as obtained for example from C ₁₂ -i ₈ monoolefins with terminal or internal double bond by sulfonating with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation , considering. Also suitable are alkanesulfonates, which are obtained from Ci ₂ -is-alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Similarly, the esters of α-sulfo fatty acids (ester sulfonates), for example, the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or Taigfettsäuren are suitable.

Further suitable anionic surfactants are sulfated fatty acid glycerol esters. Fatty acid glycerol esters are to be understood as meaning the mono-, di- and triesters and mixtures thereof, as in the preparation by esterification of a monoglycerol with 1 to 3 mol fatty acid or in the transesterification of triglycerides with 0.3 to 2 mol Glycerol can be obtained. Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.

The alkali and especially the sodium salts of the Schwefelsäurehalbester C ₂ -C alk (en) yl sulfates ₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol, or C ₀ -C ₂ o Oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length which are a synthetic, petrochemical-based contain straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. 2,3-Alkyl sulfates can be obtained under the name DAN ^® as commercial products from Shell Oil Company, are suitable anionic surfactants.

Also, the sulfuric acid monoesters of straight-chain or branched C ₇ ethoxylated with 1 to 6 moles of ethylene oxide. ₂ i-alcohols, such as 2-methyl-branched C ₉ n-alcohols having an average of 3.5 moles of ethylene oxide (EO) or C ₁₂ . ₁₈ fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are preferably used only in relatively small amounts, for example in amounts of from 1 to 5% by weight, in detergents in particular. The agents according to the invention may preferably be free of sulfuric acid monoester.

Another class of anionic surfactants is the class of ether carboxylic acids obtainable by the reaction of fatty alcohol ethoxylates with sodium chloroacetate in the presence of basic catalysts. They have the general formula: R ¹⁰ O- (CH ₂ -CH ₂ -O) _P -CH ₂ -COOH with R ¹⁰ = dC- ₁₈ and p = 0.1 to 20. Ethercarboxylic acids are water hardness insensitive and have excellent surfactant properties.

Suitable anionic surfactants are, for example, the partial esters of di- or polyhydroxyalkanes, mono- and disaccharides, polyethylene glycols with the ene-adducts of maleic anhydride to at least monounsaturated carboxylic acids having a chain length of from 10 to 25 carbon atoms with an acid number of from 10 to 140.

In addition to an unbranched or branched, saturated or unsaturated, aliphatic or aromatic, acyclic or cyclic, optionally alkoxylated alkyl radical, preferred anionic surfactants have 4 to 28, preferably 6 to 20, in particular 8 to 18, particularly preferably 10 to 16, most preferably 12 to 14 carbon atoms, two or more anionic, in particular two, acid groups, preferably carboxylate, sulfonate and / or sulfate groups, in particular a carboxylate and a sulfate group on. Examples of these compounds are the sulfo fatty acid salts, the acyl glutamates, the monoglyceride disulfates and the alkyl ethers of glyceryl disulfate, and in particular the monoester sulfosuccinates described below.

Particularly preferred anionic surfactants are the sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and di-esters of Sulfosuccinic acid HOOCCH (SO ₃ H) CH ₂ COOH, while among the sulfosuccinamates the salts of the monoamides of sulfosuccinic acid and of the sulfosuccinamides are the salts of diamides of sulfosuccinic acid.

The salts are preferably alkali metal salts, ammonium salts and mono-, di- or trialkanolammonium salts, for example mono-, di- or triethanolammonium salts, in particular lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts preferably sodium salts.

In the sulfosuccinates, one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified. Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4. The monoesters are preferred in the context of the present invention over the diesters. A particularly preferred sulfosuccinate is sulphonated bernsteinsäurelaurylpolyglykolester-di-sodium salt (lauryl EO sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), the weight, for example as Tego ^® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate 30 .-% is commercially available.

In the sulfosuccinamates or sulfosuccinamides, one or both form carboxyl groups of the sulfosuccinic acid preferably with a primary or secondary amine having one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals having 4 to 22 , preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms carries, a carboxylic acid amide. Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.

Also suitable are, for example, the following sulfosuccinates and sulfosuccinamates designated according to INCI: ammonium dinonyl sulfosuccinates, ammonium lauryl sulfosuccinates, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido-MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 sulfosuccinates, diamyl sodium sulfosuccinates, dicapryl sodium sulfosuccinates, dicyclohexyl sodium sulfosuccinates, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccinate, Disodium Cocamido Glucoside Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate , Disodium Deceth-6 Sulfosuccinate, Disodium Dihydroxyethyl Sulfosuccinyl-undecylenate, Disodium Dimethicone Copolyol Sulfosuccinate, Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamido MEA Sulfosuccinate, Disodium Isostearamido MIPA Sulfosuccinate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramido MEA Sulfosuccinate, Disodium Lauramido PEG-2 Sulfosuccinate, Disodium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauryl Sulfosuc cinate, disodium myristamido MEA sulfosuccinates, disodium nonoxynol-10 sulfosuccinates, disodium oleamido MEA sulfosuccinates, disodium oleamido MIPA sulfosuccinates, disodium oleamido PEG-2 sulfosuccinates, disodium oleth-3 sulfosuccinates, disodium oleyl sulfosuccinates, disodium palmitamido PEG-2 sulfosuccinates, Disodium Palmitoleamido PEG-2 Sulfosuccinate, Disodium PEG-4 Cocamido MIPA Sulfosuccinate, Disodium PEG-5 Lauryl Citrate Sulfosuccinate, Disodium PEG-8 Palm Glycerides Sulfosuccinate, Disodium Ricinoleamido MEA Sulfosuccinate, Disodium Sitostereth-14 Sulfosuccinate, Disodium Stearamido MEA Sulfosuccinate, Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium Tallamido MEA Sulfosuccinate, Disodium Tallowamido MEA Sulfosuccinate, Disodium Tallow Sulfosuccinamate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamido MEA Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA Sulfosuccinate, Disodium Wheat Germamido PEG-2 Sulfosuccinates, di-TEA-Ole-amido PEG-2 Sulfosuccinates, Ditridecyl Sodium Sulfosuccinate, Sodium Bisglycol Ricinosulfosuccinate, Sodium / MEA Laureth-2 Sulfosuccinate and Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate. Yet another suitable sulfosuccinamate is disodium cis-is-alkoxy-propylene sulfosuccinamate.

Anionic surfactants, in particular the aforementioned anionic surfactants, can be present in the fluid-containing particles according to the invention.

The content of the washing or cleaning agent according to the invention to anionic surfactants, preferably to said anionic surfactants, can vary within wide limits, depending on the purpose of the agent in question. Thus, an agent according to the invention can contain very large amounts of anionic surfactant, preferably up to an order of magnitude of up to 40, 50 or 60% by weight or more. Likewise, an agent according to the invention may contain only very small amounts of anionic surfactant, for example less than 15 or 10% by weight or less than 5% by weight or even less. However, anionic surfactants are advantageously contained in the compositions according to the invention in amounts of from 1 to 40% by weight and in particular from 5 to 30% by weight, where Concentrations above 10 wt .-% and even above 15 wt .-% special preference. According to a preferred embodiment, the washing or cleaning agent according to the invention contains anionic surfactants, preferably in amounts of at least 0.1% by weight, based on the total washing or cleaning agent. According to another preferred embodiment, the agent according to the invention is free of anionic surfactant.

In addition to the anionic surfactants mentioned, but also independently of these, soaps may be present in the washing or cleaning compositions according to the invention. Particularly suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, and in particular of natural fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures. The content of the composition of soaps, independently of other anionic surfactants, is preferably not more than 3% by weight and in particular 0.5 to 2.5% by weight, based on the total agent. According to a preferred embodiment, the agent according to the invention is free of soap.

Soaps, in particular the aforementioned soaps, can be present in the fluid-containing particles according to the invention.

The anionic surfactants and soaps may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine. Preferably, they are in the form of their sodium or potassium salts, especially in the form of the sodium salts. Anionic surfactants and soaps may also be prepared in situ by incorporating into the spray-dried composition the anionic surfactant acids and optionally fatty acids which are then neutralized by the alkali carriers in the spray-dried composition.

Advantageously, nonionic surfactants may also be included in the detergents or cleaners according to the invention. For example, their content may be up to 2 or 3 or 5 wt .-%. It may also contain larger amounts of nonionic surfactant, for example up to 5 wt .-% or 10 wt .-% or 15 wt .-% or 20 wt .-%, 30 wt .-%, 40 wt .-%, 50% by weight or even beyond, if appropriate. Useful lower limits may be at values of 0.01, 0.1, 1, 2, 3 or 4 wt .-%.

Preferably, however, the nonionic surfactants are in relatively large amounts, ie up to 50% by weight, advantageously from 0.1 to 40% by weight, particularly preferably from 0.5 to 30 and in particular from 2 to 25% by weight, in each case based on the total agent included. According to a preferred embodiment, the washing or cleaning agent according to the invention comprises nonionic surfactants, preferably in amounts of at least 0.1% by weight, based on the total washing composition. or detergent. According to another preferred embodiment, the agent according to the invention is free of nonionic surfactant.

Advantageously, all known from the prior art nonionic surfactants may be included in the inventive compositions. Preferred nonionic surfactants are presented below.

Nonionic surfactants, in particular the nonionic surfactants mentioned below, can be present in the fluid-containing particles according to the invention.

The washing or cleaning agents according to the invention may preferably also contain cationic surfactants. Suitable cationic surfactants are, for example, surface-active quaternary compounds, in particular having an ammonium, sulfonium, phosphonium, iodonium or arsonium group. Through the use of quaternary surface-active compounds with antimicrobial action, the agent can be designed with an antimicrobial effect or its possibly existing antimicrobial effect due to other ingredients can be improved.

Particularly preferred cationic surfactants are the quaternary, partially antimicrobial ammonium compounds (QAV; / Λ / C / quaternary ammonium compounds) according to the general formula (R ^I ) (R ") (R ¹ ") (R ^IV ) N ⁺ X ^" , in which R ¹ to R ^IV are identical or different C ^ -alkyl 'C ₇ - ₂₈ - aralkyl radicals or heterocyclic radicals, or in the case of an aromatic compound such as pyridine-even three groups together with the nitrogen atom forming the heterocycle, for example a Pyridinium or imidazolinium compound, and X ^"are halide ions, sulfate ions, hydroxide ions or like anions. For optimum antimicrobial activity, preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QACs are prepared by reacting tertiary amines with alkylating agents, e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary amines with a long alkyl radical and two methyl groups is particularly easy, the quaternization of tertiary amines with two long radicals and one methyl group can be carried out with the aid of methyl chloride under mild conditions. Amines which have three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are preferably quaternized with dimethyl sulfate.

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (mp-dichlorobenzyl-dimethyl-C 1-4 -alkylammonium chloride, CAS No. 58390-78-6), benzoxonium chloride (benzyldodecyl bis (2-hydroxyethyl) ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-methylammonium bromide, CAS No. 57-09-0), benzetonium chloride ( N, N-dimethyl-N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides such as di-n-decyldimethylammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammoniumchloric, I-cetylpyridiniumchloride (CAS no. 123-03-5) and thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyldimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

In order to avoid possible incompatibilities of the antimicrobial cationic surfactants with anionic surfactants possibly contained in the washing or cleaning agent according to the invention anionic surfactant compatible and / or optionally cationic surfactant are preferably used or omitted in a particular embodiment of the invention entirely on cationic surfactants.

Further below, in particular in connection with conditioning agents and plasticizers, further cationic surfactants, including quaternary ammonium compounds, are described. These may also be contained in the compositions according to the invention.

Cationic surfactants can be present in the fluid-containing particles according to the invention.

The detergents or cleaners according to the invention may contain one or more cationic surfactants, advantageously in amounts, based on the total composition, of from 0 to 30% by weight, more preferably greater than 0 to 20% by weight, preferably from 0.01 to 10 Wt .-%, in particular 0.1 to 5 wt .-%. Suitable minimum values may also be 0.5, 1, 2 or 3 wt .-%. According to a preferred embodiment, the washing or cleaning agent according to the invention comprises cationic surfactants, preferably in amounts of at least 0.1% by weight, based on the total washing or cleaning agent. According to another preferred embodiment, the agent according to the invention is free of cationic surfactant.

Likewise, the detergents or cleaners according to the invention may also contain amphoteric surfactants. These are described in more detail below, in particular in connection with conditioning agents and plasticizers.

The washing or cleaning agents according to the invention may contain one or more amphoteric surfactants, advantageously in amounts, based on the total composition, of from 0 to 30% by weight, more preferably from 0 to 20% by weight, preferably from 0.01 to 10% by weight .-%, in particular 0.1 to 5 wt .-%. According to a preferred embodiment, the agent according to the invention is free of amphoteric surfactants.

Amphoteric surfactants may be included in the fluid-containing particles of the invention.

Further ingredients of the washing or cleaning agents according to the invention, such as the fluid-containing particles according to the invention, can be inorganic and organic builders. Inorganic builders include water-insoluble or non-water-soluble ingredients such as aluminosilicates and especially zeolites.

In a preferred embodiment, the inventive washing or

Detergent no phosphate.

It can be advantageously provided that the inventive washing or

Detergent a zeolite content of at least 10 wt .-%, z. B. at least 15 wt .-% or at least 20 wt .-% or at least 30 wt .-% or even beyond, for example at least 50 wt .-%, based on the total washing or

Cleaning supplies.

Soluble builders may preferably contain the inventive detergent or cleaning agent in amounts of 0.1% by weight to 30% by weight, preferably 5% by weight to 25% by weight and particularly preferably 10% by weight to 20% by weight .-%, based on the total weight of the agent, with sodium carbonate is particularly preferred as a soluble builder. However, it can also be advantageously provided that the agent according to the invention contains less than 10% by weight, for example less than 5% by weight, of soluble builder. According to another preferred embodiment, the agent according to the invention is free of soluble builder.

Useful finely crystalline, synthetic and bound water-containing zeolite is preferably zeolite A and / or P. As zeolite P, for example, zeolite MAP ^(R) (commercial product of Crosfield) is particularly preferred. Also suitable however are zeolite X and mixtures of A, X and / or P. Of particular interest is a co-crystallized sodium / potassium aluminum silicate of zeolite A and zeolite X, which as VEGOBOND AX ^® (a product of Condea Augusta SpA) Trade is available.

The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated Ci ₂ - C- ₁₈ fatty alcohols with 2 to 5 ethylene oxide groups, Ci ₂ -Ci ₄ fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have a mean Particle size of preferably less than 10 microns (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of bound water.

Other particularly suitable zeolites are faujasite-type zeolites. Together with the zeolites X and Y, the mineral faujasite belongs to the faujasite types within the zeolite structure group 4, which are characterized by the double-six-membered subunit D6R. In addition to the faujasite types mentioned, the zeolite structural group 4 also includes the minerals chabazite and gmelinite as well as the synthetic zeolites R (chabazite type), S (gmelinite type), L and ZK-5. The latter two synthetic zeolites have no mineral analogs.

Faujasite-type zeolites are composed of β-cages linked by tetrahedral D6R subunits, with the β-cages resembling the carbon atoms in the diamond. The three-dimensional network of the faujasite-type zeolites suitable according to the invention has pores of 2.2 and 7.4 Å, the unit cell also contains 8 cavities with a diameter of approximately 13 A and can be represented by the formula Na ₈₆ [(AlO ₂ ) 86 (SiO 2) io 6] 264 H ₂ O describe. The network of zeolite X contains a void volume of about 50%, based on the dehydrated crystal, which represents the largest void space of all known zeolites (zeolite Y: about 48% void volume, faujasite: about 47% void volume).

In the context of the present invention, the term "faujasite type zeolite" denotes all three zeolites which form the faujasite subgroup of the zeolite structure group 4. In addition to zeolite X, zeolite Y and faujasite and mixtures of these compounds are also suitable according to the invention, with pure zeolite X being preferred.

Mixtures or cocrystallizates of faujasite-type zeolites with other zeolites, which need not necessarily belong to the zeolite structure group 4, are also suitable according to the invention, with preferably at least 50% by weight of the faujasite-type zeolites being suitable.

The suitable aluminum silicates are commercially available and the methods for their preparation are described in standard monographs.

Examples of commercially available X-type zeolites can be described by the following formulas: Na ₈₆ [(AIO ₂ ) 86 (SiO 2) ₁₀ 6] x H ₂ O,

K ₈ 6 [(AIO ₂ ) 86 (SiO 2) ₁ 06] XH ₂ O,

Ca ₄₀ Na ₆ [(AIO ₂ ) ₈₆ (SiO ₂ ) ₁₀ 6] x H ₂ O,

Sr ₂₁ Ba ₂₂ [(AIO ₂ ) ₈₆ (SiO ₂ ) ₁₀ 6] x H ₂ O, in which x can assume values greater than 0 to 276. These zeolites have pore sizes of 8.0 to 8.4 Å.

Also suitable, for example, is zeolite A-LSX, which corresponds to a cocrystal of zeolite X and zeolite A and in its anhydrous form has the formula (M _{2 / n} O + M'2 _{/ n} O) Al ₂ O ₃ zSiO ₂ , wherein M and M 'may be alkali or alkaline earth metals and z is a number from 2.1 to 2.6. Commercially available this product is under the brand name VEGOBOND AX by the company CONDEA Augusta SpA

Y-type zeolites are also commercially available and can be obtained, for example, by the formulas

Na ₅ 6 [(AIO ₂ ) 56 (SiO ₂ ) ₁₃ 6] x H ₂ O, K ₅ 6 [(AIO ₂ ) 56 (SiO ₂ ) ₁₃ 6] x H ₂ O, where x is numbers greater than 0 to 276, describe. These zeolites have pore sizes of 8.0 Å.

The particle sizes of the suitable zeolites are advantageously in the range from 0.1 μm to 100 μm, preferably from 0.5 μm to 50 μm and in particular from 1 μm to 30 μm, in each case measured by standard particle size determination methods. According to another preferred embodiment, the washing or cleaning agent according to the invention is free of zeolite.

In a preferred embodiment of the invention, all of the inorganic constituents contained should preferably be water-soluble. Therefore, builders other than the zeolites mentioned are used in these embodiments.

Further suitable builder substances are polyacetals which can be obtained by reacting dialdehydes with polyolcarboxylic acids which have 5 to 7 C atoms and at least 3 hydroxyl groups. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as gluconic acid and / or glucoheptonic acid.

Further suitable organic builder substances are dextrins, for example oligomers or Polymers of carbohydrates that can be obtained by partial hydrolysis of starches. The hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes. Preferably, it is hydrolysis products having average molecular weights in the range of 400 to 500,000 g / mol. In this case, a polysaccharide with a dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30 is preferred, DE being a common measure of the reducing action of a polysaccharide compared to dextrose, which has a DE of 100 , is. Usable are both maltodextrins with a DE between 3 and 20 and dry glucose syrups with a DE between 20 and 37 and so-called yellow dextrins and white dextrins with higher molecular weights in the range from 2000 to 30,000 g / mol. A preferred dextrin is described in British Patent Application 94 19 091. The oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function.

Oxydisuccinates and other derivatives of disuccinates, preferably ethylenediamine disuccinate, are other suitable co-builders. Ethylenediamine-N, N ^'-di- succinate (EDDS) is preferably used in the form of its sodium or magnesium salts. Also preferred in this context are glycerol disuccinates and glycerol trisuccinates. Suitable amounts are, for example, 3 to 15 wt .-%, based on the total detergent or cleaning agent.

Other useful organic cobuilders are, for example, acetylated hydroxycarboxylic acids or their salts, which may optionally also be present in lactone form and which contain at least 4 carbon atoms and at least one hydroxyl group and a maximum of two acid groups.

Another class of substances with cobuilder properties are the phosphonates. These are, in particular, hydroxyalkane or aminoalkanephosphonates. Among the hydroxyalkane phosphonates, 1-hydroxyethane-1,1-diphosphonate (HEDP) is of particular importance as a co-builder. It is preferably used as the sodium salt, the disodium salt neutral and the tetrasodium salt alkaline (pH 9). Preferred aminoalkane phosphonates are ethylenediamine tetramethylene phosphonate (EDTMP), diethylene triamine pentamethylene phosphonate (DTPMP) and their higher homologs. They are preferably used in the form of the neutral-reacting sodium salts, for example as the hexasodium salt of EDTMP or as the hepta- and octa-sodium salt of DTPMP. The builder used here is preferably HEDP from the class of phosphonates. The aminoalkanephosphonates also have a pronounced heavy metal binding capacity. Accordingly, it may be preferable, especially if the washing or cleaning agents also contain bleach, to use aminoalkanephosphonates, in particular DTPMP, or to use mixtures of the phosphonates mentioned. In cases in which a phosphate content is tolerated, it is also possible to use phosphates, in particular pentasodium triphosphate, if appropriate also pyrophosphates and orthophosphates, which act primarily as precipitants for calcium salts. Phosphates are predominantly used in automatic dishwasher detergents, but in some cases also in detergents.

Alkali metal phosphates is the summary term for the alkali metal (especially sodium and potassium) salts of various phosphoric acids, in which one can distinguish metaphosphoric acids (HPO ₃ ) _n and orthophosphoric H ₃ PO _{4 in} addition to higher molecular weight representatives. The phosphates combine several advantages: they act as alkali carriers, prevent lime deposits on machine parts or lime incrustations in fabrics and also contribute to the cleaning performance.

Sodium dihydrogen phosphate, NaH ₂ PO ₄ , exists as dihydrate (density 1, 91 like ³ , melting point 60 °) and as monohydrate (density 2.04 like ³ ). Both salts are white powders which are very slightly soluble in water and which lose the water of crystallization when heated and at 200 ^° C. into the weak acid diphosphate (disodium hydrogen diphosphate, Na ₂ H ₂ P ₂ O ₇ ), at higher temperature in sodium trimetaphosphate (Na ₃ P ₃ O ₉ ) and Maddrell's salt (see below). NaH ₂ PO _{4 is} acidic; It arises when phosphoric acid is adjusted to a pH of 4.5 with sodium hydroxide solution and the mash is sprayed. Potassium dihydrogen phosphate (potassium phosphate primary or monobasic, potassium bisphosphate, KDP), KH ₂ PO ₄ , is a white salt of density 2.33, like ^'3 , has a melting point of 253 ° [decomposition to form potassium polyphosphate (KPO ₃ ) _X ] and is easily soluble in water.

Disodium hydrogen phosphate (secondary sodium phosphate), Na ₂ HPO ₄ , is a colorless, very slightly water-soluble crystalline salt. It exists anhydrous and with 2 mol. (Density 2.066 like ³ , water loss at 95 °), 7 mol. (Density 1, 68 like ^'3 , melting point 48 ° with loss of 5 H ₂ O) and 12 MoI. Water (density 1, 52 like ^'3 , melting point 35 ° with loss of 5 H ₂ O), becomes anhydrous at 100 ° and on more intense heating in the diphosphate Na ₄ P ₂ O ₇ over. Disodium hydrogen phosphate is prepared by neutralization of phosphoric acid with soda solution using phenolphthalein as an indicator. Dipotassium hydrogen phosphate (secondary or dibasic potassium phosphate), K ₂ HPO ₄ , is an amorphous, white salt that is readily soluble in water.

Trisodium phosphate, sodium tertiary phosphate, Na ₃ PO ₄ , are colorless crystals which, as dodecahydrate, have a density of 1.662 ^', and a melting point of 73-76 ° C (decomposition) Decahydrate (corresponding to 19-20% P ₂ O ₅₎ like to have a melting point of 100 ⁰ C and in anhydrous form (corresponding to 39-40% P ₂ O ₅₎ a density of 2.536 ^"3. Trisodium phosphate is readily soluble in water with an alkaline reaction is prepared by evaporating a solution of exactly 1 mole of disodium phosphate and 1 mole of NaOH.Trical phosphate (tertiary or tribasic potassium phosphate), K ₃ PO ₄ , is a white, deliquescent, granular powder of density 2.56 ^'3 , It has a melting point of 1340 ° and is easily soluble in water with an alkaline reaction, eg when heating Thomas slag with coal and potassium sulphate Despite the higher price, in the detergent industry the more soluble, therefore highly effective potassium phosphates are replaced by the corresponding sodium compounds often preferred.

Tetrasodium diphosphate (sodium pyrophosphate), Na ₄ P ₂ O ₇ , exists in anhydrous form (density 2.534 ^'3 , melting point 988 °, also indicated 880 °) and as decahydrate (density 1, 815-1, 836 like ^"3 , melting point 94 Both substances are colorless crystals which are soluble in water with an alkaline reaction Na ₄ P ₂ O ₇ is formed on heating disodium phosphate to> 200 ° or by reacting phosphoric acid with soda in a stoichiometric ratio and dehydrating the solution by spraying. the decahydrate complexes heavy metal salts and hardness salts and, therefore, reduces the hardness of the water. potassium diphosphate (potassium pyrophosphate), K ₄ P ₂ O _7, exists in the form of the trihydrate and is a colorless, hygroscopic powder with a density of 2.33 represents ^{gcm -3} which is soluble in water, wherein the pH of the 1% solution at 25 ° is 10.4.

Condensation of the NaH ₂ PO ₄ or of the KH ₂ PO ₄ gives rise to relatively high molecular weight sodium and potassium phosphates, in which cyclic representatives, the sodium or potassium metaphosphates and chain-type, the sodium or potassium polyphosphates, can be distinguished. In particular, for the latter are a variety of names in use: hot or cold phosphates, Graham's salt, Kurrolsches and Maddrell's salt. All higher sodium and potassium phosphates are collectively referred to as condensed phosphates.

The technically important pentasodium triphosphate, Na ₅ P ₃ Oi ₀ (sodium tripolyphosphate), is an anhydrous or with 6 H ₂ O crystallizing, non-hygroscopic, white, water-soluble salt of the general formula NaO- [P (O) (ONa) -O] _n -Na with n = 3. In 100 g of water dissolve at room temperature about 17 g, at 60 ° about 20 g, at 100 ° around 32 g of the salt water-free salt; After two hours of heating the solution to 100 ° caused by hydrolysis about 8% orthophosphate and 15% diphosphate. In the preparation of pentasodium triphosphate, phosphoric acid is reacted with soda solution or sodium hydroxide solution in a stoichiometric ratio and the solution is dehydrated by spraying. Similar to Graham's salt and sodium diphosphate, pentasodium triphosphate dissolves many insoluble metal compounds (including lime soaps, etc.). Pentakaliumtriphos-phat, K ₅ P ₃ O ₁₀ (potassium tripolyphosphate), for example in the form of a 50 wt .-% solution (> 23% P ₂ O ₅ , 25% K ₂ O) in the trade. The potassium polyphosphates are widely used in the washing and cleaning industry. There are also sodium potassium tripolyphosphates which can also be used in the context of the present invention. These arise, for example, when hydrolyzed sodium trimetaphosphate with KOH:

(NaPOa) ₃ + 2 KOH ^■ * Na ₃ K ₂ P ₃ O ₁₀ + H ₂ O

These are used according to the invention exactly as sodium tripolyphosphate, potassium tripolyphosphate or mixtures of these two; Mixtures of sodium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of potassium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of sodium tripolyphosphate and potassium tripolyphosphate and sodium potassium tripolyphosphate can also be used according to the invention.

In a preferred embodiment of the invention, in particular carbonates and silicates are used as inorganic builder substances.

Particularly noteworthy here are crystalline, layered sodium silicates of the general

Formula NaMSi _x O _{2x + 1} 7H ₂ O where M is sodium or hydrogen, x is a number from 1.6 to 4, preferably 1.9 to 4.0 and y is a number from 0 to 20 and preferred values for x 2, 3 or 4 are. However, since such crystalline silicates at least partially lose their crystalline structure in a spray-drying process, crystalline silicates are preferably subsequently added to the direct or post-treated spray-drying product. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x are the values

2 or 3. In particular, both .beta.- and δ-sodium Na ₂ Si ₂ O ₅ ^{^} yH ₂ O preferred. Such compounds are commercially available, for example, under the name ^SKS® (from Clariant). So here are mainly SKS-6 ^® is a δ-sodium di-silicate with the

Formula Na ₂ Si ₂ O ₅ ^{^} yH ₂ O, in SKS-7 ^® mainly to the ß-sodium disilicate. Reaction with acids (eg citric acid or carbonic acid) produces kanemite from the δ-sodium disilicate

NaHSi ₂ C-VyI-I ₂ O, commercially under the names SKS-9 ^® and SKS-10 ^® (Clariant). It may also be advantageous to use chemical modifications of these phyllosilicates. For example, the alkalinity of the layered silicates can be suitably influenced. Phyllosilicates doped with phosphate or with carbonate have altered crystal morphologies in comparison with the δ-sodium disilicate, dissolve more rapidly and show increased calcium binding capacity in comparison with δ-sodium disilicate. Thus, phyllosilicates of the general empirical formula x Na ₂ O • y SiO ₂ • z P ₂ O ₅ in which the ratio x to y is a number 0.35 to 0.6, the ratio x to z a number of 1.75 to 1200 and the ratio y to z corresponds to a number from 4 to 2800 known. The solubility of the layered silicates can also be increased by using particularly finely divided layered silicates. Also compounds from the crystalline layer silicates with other ingredients can be used. In particular, compounds with cellulose derivatives which have advantages in the disintegrating action, and compounds with polycarboxylates, for example citric acid, or polymeric polycarboxylates, for example copolymers of acrylic acid, may be mentioned.

The preferred builder substances also include amorphous sodium silicates having a modulus Na ₂ O: SiO _{2 of} from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2, 6, which have secondary washing properties. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred. Such so-called X-ray amorphous silicates, which likewise have a dissolution delay compared with the conventional water glasses, are known. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates. The content of the (X-ray) amorphous silicates in particular zeolite-free compositions is preferably 1 to 10 wt .-%, which corresponds to a preferred embodiment of the invention.

Particularly preferred inorganic water-soluble builders are alkali metal carbonates and alkali metal bicarbonates, with sodium and potassium carbonate, and especially sodium carbonate, being among the preferred embodiments. The content of alkali metal carbonates in particular zeolite-free compositions can vary within a very broad range and is preferably 1 to 50 wt .-%, advantageously 5 to 40 wt .-%, in particular 8 to 30 wt .-%, wherein usually the content of alkali metal carbonates is higher than on (X-ray) amorphous silicates. According to another preferred embodiment, the washing or cleaning agent according to the invention is free of alkali metal carbonates.

Useful organic builders are, for example, usable in the form of their alkali and especially sodium polycarboxylic acids, such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), if such use is not objectionable for environmental reasons, as well as Mixtures of these. Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof. The acids themselves can also be used. In addition to their builder action, the acids typically also have the property of an acidifying component and thus, for example in the granules according to the invention, also serve to establish a lower and milder pH of detergents or cleaners. In particular, citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any desired mixtures of these can be mentioned here.

Further suitable organic builders are polymeric polycarboxylates, for example the alkali metal salts of polyacrylic acid or of polymethacrylic acid, for example those having a relative molecular mass of 500 to 70,000 g / mol. For the purposes of this document, the molecular weights stated for polymeric polycarboxylates are weight-average molar masses M _{w of} the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard. The molar masses measured against polystyrenesulfonic acids are generally significantly higher than the molecular weights specified in this document.

The detergents or cleaners according to the invention may also contain polymers. Suitable polymers include in particular polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Because of their superior solubility, the short-chain polyacrylates, which have molar masses of from 2000 to 10000 g / mol, and particularly preferably from 3000 to 5000 g / mol, may again be preferred from this group.

Also suitable are copolymeric polycarboxylates, in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven to be particularly suitable. Their relative molecular weight, based on free acids, is generally from 2000 to 70000 g / mol, preferably from 20,000 to 50,000 g / mol and in particular from 30,000 to 40,000 g / mol.

The content of detergents or cleaning agents on organic builders may vary within a wide range. Levels of from 2 to 20% by weight are preferred, with particular contents of not more than 10% by weight finding particular approval. After another preferred Embodiment is the washing or cleaning agent according to the invention free of organic builders.

It should be noted at this point that the statement wt .-%, unless otherwise stated, refers to the entire washing or cleaning agent.

The detergents or cleaners according to the invention may contain components from the classes of the grayness inhibitors (soil carriers), the neutral salts and / or the textile-softening auxiliaries (for example cationic surfactants), which is preferred.

Grayness inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus preventing the dirt from being rebuilt. Water-soluble colloids of mostly organic nature are suitable for this purpose, for example the water-soluble salts of polymeric carboxylic acids, glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids of starch or cellulose or salts of acidic sulfuric acid esters of cellulose or starch. Also, water-soluble polyamides containing acidic groups are suitable for this purpose. Furthermore, soluble starch preparations and other than the above-mentioned starch products can be used, e.g. degraded starch, aldehyde levels, etc. Also polyvinylpyrrolidone is useful. However, preference is given to cellulose ethers, such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, and also polyvinylpyrrolidone, for example in amounts of preferably from 0.1 to 5% by weight. %, based on the detergents or cleaning agents used.

A typical example of a suitable representative of neutral salts is sodium sulfate. It can be used in amounts of, for example, from 0 to 60% by weight, preferably from 2 to 45% by weight.

Suitable plasticizers, which are described in more detail below, are, for example, swellable phyllosilicates of the type of corresponding montmorillonites, for example bentonite, as well as cationic surfactants.

The content of water in the washing or cleaning agent is preferably 0 to less than 30 wt .-% and in particular 0.5 to less than 20 wt .-% by weight, with values of not more than 15 wt .-%, not more than 10 Wt .-%, at most 5 wt .-%, at most 3 wt .-% or at most 2 wt .-% special preference. Not included in this was if necessary existing aluminosilicates such as zeolite adhering water.

According to a preferred embodiment, the washing or cleaning agent according to the invention is substantially solid, preferably in powdery, compressed or granular form.

In the following, nonionic surfactants, which may preferably be contained in the washing or cleaning agent, are described in more detail. These nonionic surfactants may e.g. be applied to the particulate detergent or cleaning agent in a post-treatment step. Of course, all nonionic surfactants may advantageously be contained directly in the washing or cleaning agent according to the invention.

The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture may contain, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, for example of coconut, palm, palm kernel, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred. The preferred ethoxylated alcohols include, for example, C ₁₂ -C ₁₄ -alkyl with 3 EO to 6 EO, C ₉ -C ₁₁ -AlkOhOIe with 7 EO, C ₁₃ -C ₁₅ -alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C ₁₄ -C ₁₅ -alcohols with 4 EO, 5 EO, 7 EO or 9 EO, C ₁₂ -C ₁₈ -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C ₁₂ -C ₁₄ -alcohol with 3 EO and C ₁₂ - C ₁₈ -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.

Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples of these are (TaIg) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

Preferred nonionic surfactants are one or more polyols with ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated, branched or unbranched, saturated or unsaturated C _10-22 alcohols with a degree of alkoxylation up to 30, preferably ethoxylated C ₁₀ - ₁₈ fatty alcohols with a degree of ethoxylation of less than 30, preferably 1 to 20, in particular 1 to 12, more preferably 1 to 8, most preferably 2 to 5, for example C ₁₂ . ₁₄ fatty alcohol ethoxylates with 2, 3 or 4 EO or a mixture of the C ₁₂ . _14- fatty alcohol ethoxylates with 3 and 4 EO in a weight ratio of 1 to 1 or Isotridecylalkoholethoxylat with 5, 8 or 12 EO. In addition, as further nonionic surfactants and alkyl glycosides of the general formula RO (G) _x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glucose unit with 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number from 1 to 10; preferably x is 1, 1 to 1, 4.

Another class of preferred nonionic surfactants which can be used either as the sole nonionic surfactant or in combination with other nonionic surfactants, in particular together with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably with 1 C ₁₂ -C ₁₈ fatty acid methyl esters having an average of 3 to 15 EO, in particular having an average of 5 to 12 EO, are also usable, for example, up to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl esters.

Nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be suitable. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof.

Also suitable are alkoxylated amines, advantageously ethoxylated and / or propoxylated, in particular primary and secondary amines having preferably 1 to 18 carbon atoms per alkyl chain and an average of 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per Mole of amine.

In the case of compositions according to the invention which are particularly suitable for automatic dishwashing, in particular dishwashing compositions in the form of tablet tablets, such as tabs, all surfactants are suitable in principle as surfactants. However, the nonionic surfactants described above and especially the low-foaming nonionic surfactants are particularly preferred for this purpose. Particularly preferred are the alkoxylated alcohols, especially the ethoxylated and / or propoxylated alcohols. The person skilled in the art generally means, under alkoxylated alcohols, the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably in the context of the present invention, the longer-chain alcohols C ₁₀ to C ₁₈ , preferably C ₁₂ to C ₁₆ , such as C ₁₁ -, C ₁₂ - , C ₁₃ -, C ₁₄ -, C ₁₅ -, C ₁₆ -, C ₁₇ - and Ci ₈ -alcohols. As a rule, n moles of ethylene oxide and one mole of Alcohol, depending on the reaction conditions, a complex mixture of addition products of different degrees of ethoxylation. A further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide. Also, if desired, by a final etherification with short-chain alkyl groups, such as preferably the butyl group, the substance class of "closed" alcohol ethoxylates reach, which can also be used in the context of the invention. Very particularly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or mixtures thereof with end-capped fatty alcohol ethoxylates.

Advantageously, the detergents or cleaners according to the invention may also contain foam inhibitors, for example foam-inhibiting paraffin oil or foam-inhibiting silicone oil, for example dimethylpolysiloxane. The use of mixtures of these agents is possible. At room temperature and solid additives, particularly in the above-mentioned foam-inhibiting agents, paraffin waxes, silicas, which may have been rendered hydrophobic in a known manner, and of C ₂ - ₇ -diamines and C-ι _2-22 -carboxylic acids bisamides derived ,

For use, preferably suitable foam-inhibiting paraffin oils, which may also be present in admixture with paraffin waxes, are generally complex mixtures without a sharp melting point. For characterization, the melting range is usually determined by differential thermal analysis (DTA) and / or the solidification point. This is the temperature at which the paraffin passes from the liquid to the solid state by slow cooling. Paraffins with less than 17 carbon atoms are not useful in the invention, their proportion in the paraffin oil mixture should therefore be as low as possible and is preferably below the limit significantly measurable by conventional analytical methods, for example gas chromatography. Preferably, paraffins are used, which solidify in the range of 20 ⁰ C to 70 ⁰ C. It should be noted that even at room temperature appearing paraffin wax mixtures may contain different proportions of liquid paraffin oils. In the case of the paraffin waxes which can be used according to the invention, the liquid fraction at 40 ^° C. is as high as possible, even without being 100% at this temperature. Preferred paraffin wax mixtures have at 40 ⁰ C a liquid fraction of at least 50% by weight, particularly from 55 wt .-% to 80 wt .-%, and at 60 ⁰ C a liquid fraction of at least 90 wt .-% to. This has the consequence that the paraffins are flowable and pumpable at temperatures down to at least 70 ⁰ C, preferably down to at least 60 ⁰ C. It should also be ensured that the paraffins contain as far as possible no volatile components. Preferred paraffin waxes contain less than 1 wt .-%, in particular less than 0.5 wt .-% at 110 ° C and atmospheric pressure vaporizable fractions. Paraffins which can be used according to the invention can be obtained, for example, under the trade names Lunaflex® from Füller and Deawax® of DEA Mineralöl AG.

The paraffin oils may contain at room temperature solid bisamides derived from saturated fatty acids containing 12 to 22, preferably 14 to 18, carbon atoms and alkylenediamines having 2 to 7 carbon atoms. Suitable fatty acids are lauric, myristic, stearic, arachic and behenic acid and mixtures thereof, such as those obtainable from natural fats or hardened oils, such as tallow or hydrogenated palm oil. Examples of suitable diamines are ethylenediamine 1, 3-propylenediamine, tetramethylenediamine, pentamethylenediamine,

Hexamethylenediamine, p-phenylenediamine and toluenediamine. Preferred diamines are ethylenediamine and hexamethylenediamine. Particularly preferred bisamides are bis-myristoyl-ethylenediamine, bispalmitoyl-ethylenediamine, bis-stearoyl-ethylenediamine and mixtures thereof and the corresponding derivatives of hexamethylenediamine.

The washing or cleaning agent may preferably comprise UV absorbers which advantageously are applied to the treated textiles and improve the lightfastness of the fibers and / or the lightfastness of other formulation constituents. Under UV absorber are organic substances (sunscreen) to understand, which are able to absorb ultraviolet rays and the absorbed energy in the form of longer-wave radiation, eg heat to give back. Compounds having these desired properties include, for example, the non-radiative deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid. The biphenyl and especially stilbene derivatives, commercially available as Tinosorb ^® FD or Tinosorb ^® FR available ex Ciba. 3-benzylidene camphor or 3-benzylidene norcamphor and derivatives thereof, for example 3- (4-methylbenzylidene) camphor, may be mentioned as UV-B absorbers; 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 2-octyl 4- (dimethylamino) benzoate and 4- (dimethylamino) benzoic acid ester; Esters of cinnamic acid, preferably 4-methoxycinnamic acid 2-ethylhexyl ester, 4-methoxycinnamic acid propyl ester, 4-methoxycinnamic acid iso-amyl ester, 2-cyano-3,3-phenylcinnamic acid 2-ethylhexyl ester (octocrylene); Esters of salicylic acid, preferably salicylic acid 2-ethylhexyl ester, salicylic acid 4-isopropylbenzyl ester, salicylic acid homomenthyl ester; Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone; Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzmalonate; Triazine derivatives, such as 2,4,6-trianilino (p-carbo-2'-ethyl-1'-hexyloxy) -1, 3,5-triazine and octyl triazone, or dioctyl butamido triazone (Uvasorb® HEB) ; Propane-1,3-diones such as 1- (4-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione; Ketotricyclo (5.2.1.0) decane derivatives. Also suitable are 2-phenylbenzimidazole-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium and glucammonium salts; Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts; Sulfonic acid derivatives of 3-Benzylidencamphers, such as 4- (2-oxo-3-boryl-nylidenme- thyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bomylidene) sulfonic acid and salts thereof.

As a typical UV-A filter, in particular derivatives of benzoylmethane come into question, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1, 3-dione, 4-tert-butyl -4'-methoxydibenzoylmethane (Parsol 1789), 1-phenyl-3- (4'-isopropylphenyl) -propane-1, 3-dione and enamine compounds. Of course, the UV-A and UV-B filters can also be used in mixtures. In addition to the soluble substances mentioned, insoluble photoprotective pigments, namely finely dispersed, preferably nano-metal oxides or salts, are also suitable for this purpose. Examples of suitable metal oxides are in particular zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium and mixtures thereof. As salts silicates (talc), barium sulfate or zinc stearate can be used. The oxides and salts are already used in the form of the pigments for skin-care and skin-protecting emulsions and decorative cosmetics. The particles should have an average diameter of less than 100 nm, preferably from 5 to 50 nm and in particular from 15 to 30 nm. They may have a spherical shape, but it is also possible to use those particles which have an ellipsoidal or otherwise deviating shape from the spherical shape. The pigments can also be surface treated, i. hydro-philic or hy- drophobiert exist. Typical examples are coated titanium dioxides, e.g. Titanium dioxide T 805 (Degussa) or Eusolex® T2000 (Merck). Suitable hydrophobic coating agents are in particular silicones and in particular trialkoxyoctylsilanes or simethicones. Micronized zinc oxide is preferably used. Further suitable UV light protection filters can be found in the relevant prior art.

The UV absorbers can advantageously be present in quantities of from 0.01% by weight to 5% by weight, preferably from 0.03% by weight to 1% by weight, in the washing or cleaning agent. They can also be subsequently added to the washing or cleaning agent, for example together with other substances.

The detergents or cleaners according to the invention may preferably also be in the form of tablets or shaped articles. For the purposes of the present application, "tablet" or "shaped bodies" are dimensionally stable, solid bodies, irrespective of the manner of their preparation. Such bodies can be prepared for example by crystallization, molding, injection molding, reactive or thermal sintering, (co) extrusion, Verprillung, pastillation, or compaction processes such as calendering or tableting. The production of "Tablets" or "shaped bodies" by tabletting is particularly preferred in the context of the present application. The tablet is thus preferably made of compressed, particulate material.

Detergents or cleaning agents according to the invention may preferably contain disintegration aids. Suitable swellable disintegration aids are, for example, bentonites or other swellable silicates. It is also possible to use synthetic polymers, in particular the superabsorbents or cross-linked polyvinylpyrrolidone used in the hygiene sector.

With particular advantage, polymers based on starch and / or cellulose are used as swellable disintegration aids. These base substances can be processed alone or in mixture with other natural and / or synthetic polymers to swellable disintegrating agents. In the simplest case, a cellulosic material or pure cellulose can be converted by pressure transfer into secondary particles by granulation, compaction or other application, which swell on contact with water and thus serve as a disintegrant. Wood pulp which has been made available by thermal or chemical-thermal processes from wood or wood shavings (sawdust, sawmill waste) has proved to be suitable as cellulose-containing material. This cellulosic material from the TMP (thermomechanical pulp) or the CTMP (chemo-thermo mechanical pulp) process can then be compacted by application of pressure, preferably roller compacted and converted into particle form. Of course, pure cellulose can also be used in a completely analogous manner, although it is more expensive from the raw material base. Here, both microcrystalline and amorphous finely divided cellulose and mixtures thereof can be used.

Another way is to granulate the cellulose-containing material with the addition of granulation aids. For example, solutions of synthetic polymers or nonionic surfactants have proven useful as granulating aids. In order to avoid residues on textiles washed with the agents according to the invention, the primary fiber length of the cellulose or cellulose used in the cellulosic material should be less than 200 .mu.m, preference being given to primary fiber lengths of less than 100 .mu.m, in particular less than 50 .mu.m.

The secondary particles ideally have a particle size distribution in which preferably more than 90 wt .-% of the particles have sizes above 200 microns. A certain proportion of dust can contribute to an improved storage stability of the tablets produced therewith. Shares of a fine dust content of less than 0.1 mm up to 10 wt .-%, preferably up to 8 wt .-% may be present, for example. Furthermore, the agents according to the invention can be conditioning agents and contain the appropriate components. For the purposes of this invention, the term conditioning is preferably to be understood as meaning the avivating treatment of textiles, fabrics and fabrics. Conditioning gives the textiles positive properties, such as improved softness, increased gloss and color brilliance, improved fragrance impression, reduction of felting, ironing relief by reducing the sliding properties, reducing the creasing behavior and the static charge and a color transfer inhibition in dyed textiles ,

To improve the softness and the reviving properties, the compositions according to the invention may comprise plasticizer components. Examples of such compounds are quaternary ammonium compounds, cationic polymers and emulsifiers, such as those used in hair care products and also in agents for Textilavivage. These softening compounds, which will also be described in more detail below, can be present in all inventive compositions, but especially in the conditioners or in compositions with the desired softening effect.

Suitable examples are quaternary ammonium compounds of the formulas (III) and (IV),

wherein in (IM) R and R ^{1 is} an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{2 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ^{3 is} either R, R ¹ or R ² or is a aromatic residue stands. X ^~ represents either a halide, methosulfate, methophosphate or phosphate ion and mixtures of these. Examples of cationic compounds of the formula (III) are didecyldimethylammonium chloride,

Ditallow dimethyl ammonium chloride or dihexadecyl ammonium chloride.

Compounds of formula (IV) are so-called ester quats. Esterquats are characterized by excellent biodegradability. Here, R ^{4 is} an aliphatic alkyl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds, m, n and p may each independently have the value 1, 2 or 3 have. X ^~ may be either a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these. Preference is given to compounds which contain the group 0 (CO) R ⁷ for R ⁵ and to alkyl radicals having 16 to 18 carbon atoms for R ⁴ and R ⁷ . Particularly preferred Compounds in which R ^{6 is} also OH. Examples of compounds of the formula (IV) are methyl N- (2-hydroxyethyl) -N, N-di (tallow acyl-oxyethyl) ammonium methosulfate, bis (palmitoyl) -ethyl-hydroxyethyl-methyl-ammonium metho sulfate or methyl N, N-bis (acyl-oxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate. If quaternized compounds of the formula (IV) which have unsaturated alkyl chains are used, preference is given to the acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and which have a cis / trans isomer ratio (in wt .-%) of greater than 30: 70, preferably greater than 50: 50 and in particular greater than 70: 30 have. Commercial examples are sold by Stepan under the tradename Stepantex ^® Methylhydroxyalkyldi-alkoyloxyalkylammoniummethosulfate or those known under Dehyquart ^® Cognis products known under or Rewoquat ^® manufactured by Goldschmidt-Witco. Further preferred compounds are the diester quats of the formula (V), which are available under the name Rewoquat® W 222 LM or CR 3099 and, in addition to the softness, also provide stability and color protection.

R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.

In addition to the quaternary compounds described above, it is also possible to use other known compounds, for example quaternary imidazolinium compounds of the formula (VI)

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ independently of one another may each be an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively also be 0 (CO) R ²⁰ where R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^{- is} an anion. q can take integer values between 1 and 4.

Further suitable quaternary compounds are described by formula (VII) R13 H

R 12 - N - (CH ₂ V - C - O (CO) R 15 X ^" (VII);

R14 CH ₂ - 0 (C0) R 16 wherein R ^12, R ¹³ and R ¹⁴ independently represent a d ^ alkyl, alkenyl or hydroxyalkyl group, R ¹⁵ and R ¹⁶ each selected independently a C _8-28 alkyl group and r is a number between 0 and 5.

In addition to the compounds of the formulas (III) and (IV) it is also possible to use short-chain, water-soluble, quaternary ammonium compounds, such as trihydroxyethylmethylammonium methosulfate or the alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride.

Also protonated alkylamine compounds which have plasticizing effect, as well as the non-quaternized, protonated precursors of cationic emulsifiers are suitable.

Further cationic compounds which can be used according to the invention are the quaternized protein hydrolysates.

Suitable cationic polymers include the polyquaternium polymers as referred to in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the Polyquaternium-6, Polyquaternium-7, also referred to as Merquats, Polyquaternium-10 polymers (Ucare Polymer IR 400, Amerchol), polyquaternium-4 copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups attached via allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyltriammonium chloride and similar quaternized guar derivatives (eg Cosmedia guar, manufacturer: Cognis GmbH), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), for example the commercial product Glucquat ^® 100, according to CTFA nomenclature a "lauryl methyl Gluceth-10 hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrolidone, aminosilicone po polymers and copolymers.

Polyquaternized polymers (for example, Luviquat Care by BASF.), And cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer: Cognis) polymer obtainable. Also useful in the present invention are cationic silicone oils such as the commercially available Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimeth-icon), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicones is), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) Abil ^® quat 3270 and 3272 (manufacturer: Goldschmidt-Rewo; di- quaternary polydimethylsiloxanes, quaternium-80), and Silicone quat Rewoquat ^® SQ 1 (Tegopren® ^® 6922, manufacturer: Goldschmidt-Rewo).

It is likewise possible to use compounds of the formula (VIII)

the alkylamidoamines may be in their quaternized or, as shown, their quaternized form. R ¹⁷ can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds, s can assume values between 0 and 5. R ¹⁸ and R ¹⁹ are each independently H, or hydroxyalkyl. Preferred compounds are fatty acid amidoamines, such as under the name Tego Amid ^® S 18 stearylamidopropyldimethylamine available or obtainable under the name Stepantex ^® X 9124 3- tallowamidopropyl trimethylammo-nium methosulfate, which by a good conditioning effect by dye transfer-inhibiting effect and by to distinguish their good biodegradability.

Particularly preferred are alkylated quaternary ammonium compounds, of which at least one alkyl chain is interrupted by an ester group and / or amido group, in particular N-methyl-N (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate.

Suitable nonionic plasticizers are, in particular, polyoxyalkylene glycol alkanoates, polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, alkyl polyglycosides, in particular sorbitan mono-, di- and triester and fatty acid esters of polycarboxylic acids.

In an agent according to the invention, preferably conditioning agents, plasticizers may be used in amounts of from 0.1 to 80% by weight, usually from 0.1 to 70% by weight, preferably from 0.2 to 60% by weight and in particular from 0.5 to 40 Wt .-%, in each case based on the total agent to be included.

Conditioners according to the invention may preferably contain one or more anionic surfactants, in particular those which have already been described above. Conditioners according to the invention may preferably contain one or more nonionic surfactants, in particular those which have already been described above.

Other surfactants for all agents according to the invention, in particular for the conditioning agents, are so-called gemini surfactants. These are generally understood as meaning those compounds which have two hydrophilic groups and two hydrophobic groups per molecule. These groups are usually separated by a so-called "spacer". This spacer is typically a carbon chain that should be long enough for the hydrophilic groups to be spaced sufficiently apart for them to act independently of each other. Such surfactants are generally characterized by an unusually low critical micelle concentration and the ability to greatly reduce the surface tension of the water. In exceptional cases, however, the term gemini surfactants is understood to mean not only dimeric but also trimeric surfactants.

Suitable gemini surfactants are, for example, sulfated hydroxy mixed ethers or dimer alcohol bis- and trimer tris sulfates and ether sulfates. End-capped dimeric and trimeric mixed ethers are characterized in particular by their bi- and multi-functionality. Thus, the end-capped surfactants mentioned have good wetting properties and are low-foaming, so that they are particularly suitable for use in machine washing, care or cleaning processes.

However, it is also possible to use gemini-polyhydroxy fatty acid amides or poly-polyhydroxy fatty acid amides, as described in the relevant prior art.

Further suitable surfactants are polyhydroxy fatty acid amides of the following formula

R ²³

I R-CO-N- [Z] in the RCO for an aliphatic acyl radical having 6 to 22 carbon atoms, R ²³ for hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical with 3 to 10 carbon atoms and 3 to 10 hydroxyl groups. The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.

The group of polyhydroxy fatty acid amides also includes compounds of the following formula R ²⁴ is -OR ²⁵

I R-CO-N- [Z] in the R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{24 is} a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{25 is} a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, where C | _4- alkyl or phenyl radicals are preferred and [Z] is a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated derivatives of this radical.

[Z] is preferably obtained by reductive amination of a reduced sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose. The N-alkoxy- or N-aryloxy-substituted compounds can then be converted into the desired polyhydroxy fatty acid amides, for example, by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.

The detergents or cleaners according to the invention may preferably also contain amphoteric surfactants. In addition to numerous mono- to tri-alkylated amine oxides, the betaines represent an important class.

Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation of aminic compounds. Preferably, the starting materials are condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, wherein one mole of salt is formed per mole of betaine. Furthermore, the addition of unsaturated carboxylic acids, such as acrylic acid is possible. As regards the nomenclature and, in particular, the distinction between betaines and 'true' amphoteric surfactants, reference should be made to the relevant literature. Examples of suitable betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow the formula (IX)

R ²⁷

R ²⁶ -N- (CH ₂ ) _n COOX ¹ (IX)

R ²⁸ in the R ^{26 is} alkyl and / or alkenyl radicals having 6 to 22 carbon atoms, R ^{27 is} hydrogen or alkyl radicals having 1 to 4 carbon atoms, R ^{28 is} alkyl radicals having 1 to 4 carbon atoms, n is from 1 to 6 and X ^{1 is} an alkali and / or alkaline earth metal or ammonium. typical Examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine,

Dodecylethylmethylamine, C _{12 /} i ₄ cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethyl-methylamine, oleyldimethylamine, C _16/18 tallowalkyldimethylamine and technical mixtures thereof.

Also suitable are carboxyalkylation products of amidoamines which follow the formula (X),

R ²⁹ R ³¹ CO-NH- (CH ₂ ) _m -N- (CH ₂ ) _n COOX ² (X)

R ³⁰ in which R ³¹ CO is an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, m is a number from 1 to 3 and R ²⁹ , R ³⁰ , n and X ² are as defined above. Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, namely caproic, caprylic, capric, lauric, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselinic, linoleic, linolenic, elaeostearic, and arachidic acids , Gadoleic acid, behenic acid and erucic acid and technical mixtures thereof, with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and N, N-diethylaminopropylamine, which are condensed with sodium chloroacetate. The use of a condensation product of Csm-coconut fatty acid-N, N-dimethylaminopropylarriide with sodium chloroacetate is preferred.

Furthermore, suitable starting materials for the betaines usable in the context of the invention are imidazolines which follow the formula (XI),

R33

(XI) in which R ^{32 is} an alkyl radical having 5 to 21 carbon atoms, R ^{33 is} a hydroxyl group, an OCOR ³² or NHCOR ³² radical and m is 2 or 3. These substances are also known substances which can be obtained, for example, by cyclizing condensation of 1 or 2 moles of fatty acid with polyhydric amines, such as, for example, aminoethyl-ethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are condensation products of the abovementioned fatty acids with AEEA, preferably imidazolines Based on lauric acid or in turn C _12/14 coconut oil fatty acid, which are subsequently betainized with sodium.

In a preferred embodiment, the washing or cleaning agent according to the invention, in particular the conditioning agent, may optionally contain one or more complexing agents.

Chelating agents (INCI), also called sequestering agents, are ingredients that are capable of complexing and inactivating metal ions, for example, to prevent their adverse effects on the stability or appearance of the agents, for example clouding. On the one hand, it is important to complex the incompatible with numerous ingredients calcium and magnesium ions of water hardness. The complexation of the ions of heavy metals such as iron or copper retards the oxidative decomposition of the finished agents.

For example, the following complexing agents designated according to INCI are suitable: Aminotrimethylene Phosphonic Acid, Beta-Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic Acid, Dipotassium EDTA, Disodium Azacycloheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl Cyclodextrin, Pentapotassium Triphosphate, Pentasodium Aminotrimethylene Phosphonate, Pentasodium Ethylene Diamines Tetramethylene Phosphonates, Pentasodium Pentetates, Pentasodium Triphosphates, Pentetic Acid, Phytic Acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconates, Potassium Polyphosphates, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodiu m Chitosan Methylene Phosphonates, Sodium Citrate, Sodium Diethylenetriamine Pentamethylene Phosphonates, Sodium Dihydroxyethylglycinate, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphate, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, Sodium Polydimethylglycinophenolsulfonate, Sodium Trimetaphosphate , TEA-EDTA, TEA-Polyphos-phate, Tetrahydroxyethyl Ethylenediamine, Tetrahydroxypropyl Ethylenediamine, Tetrapotassium Etidronate, Tetrapotassium Pyrophosphate, Tetrasodium EDTA, Tetrasodium Etidronate, Tetrasodium Pyrophosphate, Tripotassium EDTA, Trisodium Dicarboxymethyl Alaninate, Trisodium EDTA, Trisodium HEDTA, Trisodium NTA and Trisodium Phosphate ,

Preferred complexing agents are tertiary amines, in particular tertiary alkanolamines (amino alcohols). The alkanolamines have both amino and hydroxy and / or ether groups as functional groups. Particularly preferred tertiary alkanolamines are tri-ethanolamine and tetra-2-hydroxypropyl-ethylenediamine (N, N, N ', N'-tetrakis (2-hydroxy-propyl) ethylenediamine). Particularly preferred combinations of tertiary amines with Zinkricinoleat and one or more ethoxylated fatty alcohols as nonionic solubilizers and optionally solvents are described in the prior art.

A particularly preferred complexing agent is etidronic acid (1-hydroxyethylidene-1, 1-diphosphonic acid, 1-hydroxyethyl-1, 1-diphosphonic acid, HEDP, acetophosphonic acid, INCI Etidronic Acid) including their salts. In a preferred embodiment, the washing or cleaning agent according to the invention accordingly contains etidronic acid and / or one or more of its salts as complexing agent.

In a particular embodiment, the washing or cleaning agent according to the invention comprises a complexing agent combination of one or more tertiary amines and one or more further complexing agents, preferably one or more complexing acids or salts thereof, in particular triethanolamine and / or tetra-2-hydroxypropylethylenediamine and etidronic acid and / or or one or more of their salts.

The washing or cleaning agent according to the invention, in particular conditioning agent, advantageously contains complexing agents in an amount of usually 0 to 20 wt .-%, preferably 0.1 to 15 wt .-%, in particular 0.5 to 10 wt .-%, especially preferably 1 to 8 wt .-%, most preferably 1, 5 to 6 wt .-%, based on the total agent.

In a further preferred embodiment, the washing or cleaning agent according to the invention, in particular conditioning agent, optionally contains one or more enzymes.

Particularly suitable enzymes are those from the classes of hydrolases such as the proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of the enzymes mentioned. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying. In addition, cellulases and other glycosyl hydrolases may contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils. Oxireductases can also be used for bleaching or inhibiting color transfer.

Particularly suitable are bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents. Preferably, subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used. These are enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and Cellulase or cellulase and Lipasebzw. lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest. Examples of such lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases. Suitable amylases include in particular α-amylases, iso-amylases, pullulanases and pectinases. As cellulases are preferably cellobiohydrolases, endoglucanases and ß-Glucosi-denen, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by targeted mixtures of the cellulases.

The enzymes may be adsorbed as a shaped body to carriers or embedded coated to protect against premature decomposition. The proportion of enzymes, enzyme mixtures or enzyme granules may be, for example, about 0.1 to 5 wt .-%, preferably 0.12 to about 2 wt .-%, based on the total agent.

The washing or cleaning agents according to the invention (eg conditioning agents) may optionally contain bleaching agents. Among the compounds which serve as bleaches and deliver H ₂ O ₂ in water, sodium percarbonate, sodium perborate tetrahydrate and sodium perborate monohydrate are particularly important. Other useful bleaching agents are, for example, peroxopyrophosphates, citrate perhydrates and H ₂ O ₂ -producing peracidic salts or peracids, such as persulfates or persulfuric acid. Also useful is the urea peroxohydrate percarbamide, represented by the formula H ₂ N-CO-NH _{2 2} O ₂ can be described H. In particular, when using the means for cleaning hard surfaces, for example in automatic dishwashing, they may, if desired, also contain bleaching agents from the group of organic bleaches, although their use is also possible in principle for laundry detergents. Typical organic bleaches are the diacyl peroxides, such as dibenzoyl peroxide. Other typical organic bleaches are the peroxyacids, examples of which include the alkyl peroxyacids and the aryl peroxyacids. Preferred representatives are the peroxybenzoic acid and its ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy-α-naphthoic acid and magnesium monoperphthalate, the aliphatic or substituted aliphatic peroxyacids, such as peroxylauric acid, peroxystearic acid, ε-phthalimidoperoxycaproic acid (phthalimidoperoxyhexanoic acid, PAP), o-carboxybenzamidoperoxycaproic acid, N-nonenylamidoperadipic acid and N-nonylamidoperoperuccinates, and aliphatic and araliphatic peroxydicarboxylic acids, such as 1,12-diperoxycarboxylic acid, 1,9-diperoxyazelaic acid, diperoxysebacic acid, diperoxybrassic acid, the diperoxyphthalic acids, 2-decyl-diperoxybutan-1,4-diacid, N, N-terephthaloyl-di (6-amino-caproic acid) can be used. The bleaching agents may preferably be coated to protect against premature decomposition.

Dyes can be used in the washing or cleaning agent according to the invention, wherein the amount of one or more dyes is to be chosen so small that remain after application of the agent no visible residues. Preferably, the agent according to the invention is free of dyes.

The washing or cleaning agent according to the invention may preferably contain one or more antimicrobial agents or preservatives in an amount of usually 0.0001 to 3 wt .-%, preferably 0.0001 to 2 wt .-%, in particular 0.0002 to 1 wt. %, more preferably 0.0002 to 0.2% by weight, most preferably 0.0003 to 0.1% by weight.

Antimicrobial agents or preservatives are distinguished depending on the antimicrobial spectrum and mechanism of action between bacteriostats and bactericides, fungistats and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenol mercuriacetate. The terms antimicrobial action and antimicrobial agent have the usual meaning within the scope of the teaching according to the invention. Suitable antimicrobial agents are preferably selected from the groups of the alcohols, amines, aldehydes, antimicrobial acids or their salts, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and formals, benzamidines, isothiazolines , Phthalimide derivatives, pyridine derivatives, antimicrobial surface active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1, 2-dibromo-2,4-di-cyanobutane, iodo-2-propyl-butyl-carbamate, iodine, iodophores, peroxo compounds, halogen compounds and any Mixtures of the preceding.

The antimicrobial agent may be selected from ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycerol, undecylenic acid, benzoic acid, salicylic acid, dihydracetic acid, o-phenylphenol, N-propanol. Methylmorpholine-acetonitrile (MMA), 2-benzyl-4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 4,4'-di-chloro-2'-hydroxydiphenyl ether ( Dichlosan), 2,4,4'-trichloro-2'-hydroxydiphenylether (trichlosan), chlorhexidine, N- (4-chlorophenyl) - N- (3,4-dichlorophenyl) -urea, N, N '- (1, 10-decanediyldi-1-pyridinyl-4-ylidene) bis- (1-octanamine) dihydrochloride, N, N'-bis (4-chlorophenyl) -3,12-diimino-2,4,1 1 , 13-tetraaza-tetradecandiimidamide, glucoprotamines, antimicrobial quaternary surface active compounds, guanidines including the bi- and polyguanidine, such as 1, 6-bis (2-ethylhexyl-biguanido-hexane) - dihydrochloride, 1, 6-di - (N _1, N i '-phenyldiguanido-Ns.Ns ^ -hexane tetrahydrochloride, 1, 6-di- (N _{1 11} N' - phenyl-Ni.Ni-methyldiguan ido-Ns.Ns ^ -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ '-o-chloro) phenyldiguanido-N ₅ , N ₅ ') -hexane-dihydrochloride, i-thiol-di-Ni, N-i'-1, 3-dichloro-phenyldiguanido-

N ₅ , N ₅ ') hexane dihydrochloride, 1,6-di- [N ₁ , N ₁ ' -beta (p-methoxyphenyl) diguanido-N ₅ , N ₅ '] -hexane dihydrochloride, 1, 6-di- (N ₁ , N ₁ '-alpha-methyl-.beta.-phenyldiguanido-N ₅ , N ₅ ') -hexane-dihydro-chloro-Nd, 1,6-di- (N ₁ , N ₁ '- p-nitrophenyldiguanido-N ₅ , N ₅ ') hexane dihydrochloride, omega: omega-di (N ₁₁ N ₁ ' - phenyldiguanido-N ₅ , N ₅ ') di-n-propyl ether dihydrochloride, omega: omega' Di- (N ₁ , N ₁ '-p-chlorophenyldiguanido-N ₅ , N ₅ ') di-n-propyl ether tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-2,4 -dichlorophenyldiguanido- N ₅ , N ₅ ') hexane-tetrahydrochloride, 1,6-di- (N ₁ , N-i'-p-methylphenyl-nigiguanido- N ₅ , N ₅ ') hexanedihydrochloride, 1, 6- Di- (N ₁ , N ₁ , N, ₃ -trichlorophenyl-guanido-N, N, N-hexan-tetrahydrochloride, 1,6-di- [N ₁ , N-1'-alpha- (p-chlorophenyl) -ethyl-diguanido-N ₅ , N ₅ '] hexane-dihydrochloride, omega: omega-di- (N ₁ , N ₁ ' -p-chlorophenyl-nigiguanido-N ₅ , N ₅ '), m-xylenedihydrochloride, 1,12-di- (N ₁ , N ₁ ^ p- chlorophenyldiguanido-N _5, N ₅ ') dodecane-dihydro-chloride, 1, 10 -Di- (N ₁ , N -i'-phenyldiguanido- N ₅ , N ₅ ') - decane tetrahydrochloride, 1, 12-di (N ₁ , N-i'-phenyldiguanido- N ₅ , N ₅ ') dodecane-tetrahydrochloride, 1,6-di- (N ₁ , N-i'-o-chlorophenyldi-guanido-Ns, N ₅ ') hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ¹ O-) chlorophenyldiguanido- N ₅ , N ₅ ') hexane-tetrahydrochloride, ethylene-bis (1-tolyl biguanide), ethylene-bis (p-tolyl biguanide), ethylene-bis- (3,5-dimethylphenylbiguanide), ethylene-bis - (p-tert-amylphenylbiguanide), ethylene-bis- (nonylphenylbiguanide), ethylene-bis- (phenylbi-guanide), ethylene-bis- (N-butylphenylbioguanide), ethylene-bis (2,5-diethoxyphenylbiguanide), Ethylene bis (2,4-dimethylphenyl biguanide), ethylene bis (o-diphenylbiguanide), ethylene bis (mixed amyl naphthyl biguanide), N-butyl ethylene bis (phenylbiguanide), trimethylene bis (o-tolyl biguanide ), N-butyl-trimethyl-bis- (phenyl biguanide) and the corresponding salts such as acetates, gluconates, hydrochlorides, hydrobromides, citrates, bisulfites, fluorides, polymaleates, N-cocoalkyl sarcosinates , Phosphites, hypophosphites, perfluorooctanoates, silicates, sorbates, salicylates, maleates, tartrates, fumarates, ethylenediaminetetraacetates, iminodiacetates, cinnamates, thiocyanates, arginates, pyromellitates, tetracarboxybutyrates, benzoates, glutarates, monofluorophosphates, perfluoropropionates and any mixtures thereof. Also suitable are halogenated xylene and cresol derivatives, such as p-chlorometacresol or p-chloro-meta-xylene, and natural antimicrobial agents of plant origin (eg from spices or herbs), of animal and microbial origin. Preferably, antimicrobial surface-active quaternary compounds, a natural antimicrobial agent of plant origin and / or a natural antimicrobial agent of animal origin, most preferably at least one natural antimicrobial agent of plant origin from the group comprising caffeine, theobromine and theophylline and essential oils such as eugenol, thymol and geraniol, and / or at least one natural antimicrobial agent of animal origin from the group, comprising enzymes such as protein from milk, lysozyme and lactoperoxidase, and / or at least one antimicrobial surface-active quaternary compound with an ammonium, sulfonium, phosphonium, iodonium - or Arsoniumgruppe, peroxo compounds and chlorine compounds are used. Also substances of microbial origin, so-called bacteriocins, can be used. Glycine, glycine derivatives, formaldehyde, compounds which readily split off formaldehyde, formic acid and peroxides are preferably used. The suitable as antimicrobial agents quaternary ammonium compounds (QAV) have been described above. Is particularly suitable, for example, benzalkonium chloride, etc. Benzalkonium halides and / or substituted benzalkonium halides are for example commercially available as Barquat ^® ex Lonza, Marquat® ^® ex Mason, Variquat ^® ex Witco / Sherex and Hyamine ^® ex Lonza and as Bardac ^® ex Lonza. Other commercially obtainable antimicrobial agents are N- (3-chloroallyl) hexaminium chloride such as Dowicide and Dowicil ^{® ®} ex Dow, benzethonium chloride such as Hyamine ^® 1622 ex Rohm & Haas, methylbenzethonium as Hyamine ^® 10X ex Rohm & Haas, cetylpyridinium chloride such as Cepacol ex Merrell Labs ,

Furthermore, the washing or cleaning agents according to the invention, optionally ironing aids for improving the water absorbency, the rewettability of the treated textiles and to ease the Bügeins the treated textiles. For example, silicone derivatives can be used in the formulations. These additionally improve the rinsing out of the wash-active formulations by their foam-inhibiting properties. Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated. Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds. The viscosities of the preferred silicones are in the range between 100 and 100,000 mPas at 25 ° C., wherein the silicones can be used in amounts of between 0.2 and 5% by weight, based on the total agent.

It should be pointed out once again that all ingredients mentioned hereinbefore in connection with the detergents or cleaners according to the invention can be contained in the fluid-containing particles according to the invention.

A powdered (full) detergent according to the invention may preferably be e.g. Contain components which include i.a. are selected from the following:

Anionic surfactants, e.g. Alkylbenzenesulfonate, alkyl sulfate, in amounts of advantageously 5-30 wt .-%, preferably 8-15 wt .-%, in particular 15-20 wt .-%,

Nonionic surfactants, e.g. Fatty alcohol polyglycol ethers, alkyl polyglucoside, fatty acid glucamide, advantageously in amounts of 0.1-20% by weight, preferably 2-15% by weight, in particular 6-11% by weight,

Builders, e.g. Zeolite, polycarboxylate, sodium citrate, for example in amounts of 5-60% by weight, preferably in amounts of 10-55% by weight, in particular 15-40% by weight,

Alkalis, for example sodium carbonate, advantageously in amounts of from 1 to 30% by weight, preferably from 2 to 25% by weight, in particular from 5 to 20% by weight, Bleaching agents, such as, for example, sodium perborate, sodium percarbonate, advantageously in amounts of 5-25% by weight, preferably 10-20% by weight,

Corrosion inhibitors, e.g. Sodium silicate, advantageously in amounts of 1-6 wt .-%, preferably 2-5 wt .-%, in particular 3-4 wt .-%,

Stabilizers, e.g. Phosphonates, advantageously in amounts of 0-1% by weight,

Foam inhibitor, e.g. Soap, silicone oils, paraffins advantageously in amounts of 0.1-4% by weight, preferably 0.2-2% by weight, in particular 1-3% by weight,

Enzymes, e.g. Proteases, amylases, cellulases, lipases, advantageously in amounts of 0.1-2% by weight, preferably 0.2-1% by weight, in particular 0.3-0.8% by weight,

- grayness inhibitor, e.g. Carboxymethylcellulose, advantageously in amounts of 0-1% by weight,

Discoloration inhibitor, e.g. Polyvinylpyrrolidone derivatives, advantageously in amounts of 0-2% by weight,

- Adjustment means, such as Sodium sulfate, advantageously in amounts of 0-20% by weight,

Optical brighteners, e.g. Stilbene derivative, biphenyl derivative, advantageously in amounts of 0.1-0.4 wt .-%, in particular 0.1-0.3 wt .-%,

- perfumes

- Water

- Soap

- bleach activators

- Cellulosic derivatives

- Dirt deflector

The detergents or cleaners according to the invention may preferably also be perfumed with perfume oil (fragrances, perfumes).

Adhesive-resistant fragrances which can advantageously be used in the context of the present invention are, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, Champacablütenöl, Edeltannenöl, Edeltannenzapfenöl, Elemiöl, eucalyptus oil, fennel oil, spruce needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil , Gurijar balm oil, helichrysum oil, ho oil, ginger oil, iris oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanaga oil, cardamom oil, cassia oil, pine needle oil, copaϊva balsam oil, coriander oil, spearmint oil, caraway oil, cumin oil, lemongrass oil, musk kernel oil, myrrh oil, clove oil, neroli oil, niaouli oil , Olibanum oil, Origanum oil, Palmarosa oil, Patchouli oil, Peru balsam oil, Petitgrain oil, Pepper oil, Peppermint oil, Pimento oil, Pine oil, Rose oil, Rosemary oil, Sandalwood oil, Celery oil, Star aniseed oil, Thuja oil, Thyme oil, Verbena oil, Vetiver oil, Juniper berry oil, Vermouth oil, Wintergreen oil, Ylang-ylang - oil, Hyssop oil, cinnamon oil, cinnamon leaf oil and cypress oil.

But the higher-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or Fragrance mixtures are used in the perfume oils. These compounds include the following compounds and mixtures thereof: ambrettolide, α-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, borneol, bornyl acetate, α-bromostyrene, n -Decylaldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone di-methyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, Iran, isoeugenol, isoeugenol methyl ether, isosaferol , Jasmon, camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone, methyl anthranilate, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-.beta.-naphthyl ketone, methyln-nonylacetaldehyde, methyl n-nonyl ketone, Muskon, β-naphthol ethyl ether, β-naphthol methyl ether, nerol, nitrob enol, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxyacetophenone, pentadecanolide, β-phenylethyl alcohol, phenylacetaldehyde dimethyl acetal, phenylacetic acid, pulegone, safrole, salicylic acid isoamyl ester, salicylic acid methyl ester, salicylic acid hexyl ester, cyclohexyl salicylate, santalol, skatole, terpineol, Thymen, thymol, γ-undelactone, vanilin, veratrum aldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester.

Among the more volatile fragrances, which are advantageously used in the perfume oil in the present invention include, in particular, the lower-boiling fragrances natural or synthetic origin, which can be used alone or in mixtures. Examples of more readily volatile fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

All of the aforementioned fragrances can be used alone or in a mixture according to the present invention with the advantages already mentioned.

In particular, fragrances from the group of allyl alcohol esters, esters of secondary alcohols, esters of tertiary alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof may be included in the perfume oil.

Allyl alcohol esters are the esters of allyl alcohol, which has the following structural feature, C (OH) -C = C. Examples of Allylalkohlester are in particular allyl amyl glycolate, Allylanthranilat, allyl benzoate, allyl butyrate, Allylcaprat, allyl caproate, allyl cinnamate, Allylcyclohexanacetat, Allylcyclohexanbutyrat, Allylcyclohexanpropionat, allyl heptoate, Allylnonanoat, Allylsalicylat, Amylcinnamylacetat, Amylcinnamylformiat, Cinnamylformiate, Cinnamylacetate, cyclogalbanate, geranyl acetate, Geranylacetoacetat, geranyl benzoate, Geranylcinnamat, Methallylbutyrat , Methallyl caproate, neryl acetate, neryl butyrate, amyl cinnamyl formate, alpha methyl cinnamyl acetate, Methyl geranyl tiglate, mertenyl acetate, farnesyl acetate, fenchyl acetate, geranyl anthranilate, geranyl butyrate, geranyl isobutyrate, geranyl caproate, geranyl caprylate, geranyl ethyl carbonate, geranyl formate, geranyl furoate, geranyl heptoate, geranyl methoxyacetate, geranyl pelargonate, geranyl phenylacetate, geranyl phthalate, geranyl propionate, geranyl iso-propoxyacetate, geranyl valerate, geranyl iso valerate, trans-2-hexenylacetate, trans-2-hexenylbutyrate, trans-2-hexenylcaproate, trans-2-hexenylphenylacetate, trans-2-hexenylpropionate, trans-2-hexenyltiglate, trans-2-hexenylvalerate, beta-pentenylacetate, alpha -Phenylallylacetat, prenyl acetate, Trichloromethylphenylcarbinylacetat and / or mixtures thereof. Allyl alcohol esters may preferably be contained in the perfume oil according to the invention.

Examples of Esters of Secondary Alcohols (Secondary alcohols are present when two H atoms are substituted by organic radicals (R ¹ and R ² ) on the carbon atom bearing the OH group [general formulas: R ¹ -CH ( OH) -R ² ]) are, in particular, ortho-tert-amylcyclohexyl acetate, isoamylbenzylacetate, secondary n-amylbutyrate, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate, isobornylvalerate, Frutene , 2-methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2-yl acetate, prenylacetate, 4-tert-butylcyclohexylacetate, 2-tert-butylcyclohexylacetate, Vertenex (I) 4-tert-butylcyclohexyl acetate), Violiff (carboxylic acid 4-cycloocten-1-yl methyl ester), ethenyliso-amyl carbinyl acetate, fenchyl acetate, fenchyl benzoate, fenchyl n-butyrate, fenchyl isobutyrate, levo-methyl acetate, dl-menthyl acetate , Menthylanthranilate, menthylbenz ethylenediamine, menthyl isobutyrate, menthylformate, laevo-menthylphenylacetate, menthylpropionate, menthylsalicylate, menthyl isovalerate, cyclohexylacetates, cyclohexylanthranilate, cyclohexyl benzoate, cyclohexylbutyrate, cyclohexylisobutyrate, cyclohexylcaproate, cyclohexylcinnamate, cyclohexyl formate, cyclohexylheptoate, cyclohexyl oxalate, Cyclohexyl pelargonate, cyclohexylphenyl acetate, cyclohexyl propionate, cyclohexyl thioglycolate, cyclohexyl valerate, cyclohexyl iso-valerate, methyl amyl acetate, methyl benzyl carbinyl acetate, methyl butyl cyclohexanyl acetate, 5-methyl-3-butyl-tetrahydropyran-4-yl acetate, methyl lead, methyl isophosphate, 2-methylcyclohexyl acetate, 4 Methylcyclohexylacetate, 4-methylcyclohexylmethylcarbinylacetate, methylethylbenzylcarbinylacetate, 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylformiate, methyl-2-methylbutyrate, methylnonylcarbinylacetate, methylphenylcarbinylacetate,

Methylphenylcarbinyl anthranilate, methylphenylcarbinylbenzoate, methylphenylcarbinyl-n-butyrate, methylphenylcarbinylisobutyrate, methylphenylcarbinyl; Caproate, methylphenylcarbinylcaprylate, methylphenylcarbinyl cinnamate, methylphenylcarbinylformate, methylphenylcarbinylphenylacetate, methylphenylcarbinylpropionate, methylphenylcarbinylsalicylate, methylphenylcarbinyliso-valerate, 3-nonanylacetate, 3-nonenylacetate, nonanediol-2,3-acetate, nonynolacetate, 2-octanylacetate, 3-octanylacetate, n-octyl acetate, sec-octyl-iso-butyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, phenylethylmethylcarbinyl-iso-valerate, phenylethylene glycol diphenylacetate, phenylethylcarbinylacetate, phenylglycoldiacetate, sec-phenylglycol monoacetate, phenylglycolmonobenzoate, Isopropyl caprate, isopropyl caproate, isoporpyl caprylate, isopropyl cinnamate, para-

Isopropylcyclohexanyl acetate, propyl glycol diacetate, propylene glycol di-isobutyrate,

Propylene glycol dipropionate, isopropyl-n-heptoate, isopropyl-n-hept-1-yne carbonate,

Isopropyl pelargonate, isopropyl propionate, isopropyl undecylenate, isopropyl n-valerate, isopropyl n-valerate, isopropyl iso-valerate, isopropyl sebacate, isopulegyl acetate, isopuleglyceoacetoacetate, isopulperyl isobutyrate, isopulegylformate, thymylpropionate, alpha-2,4-trimethylcyclohexanemethylacetate, trimethylcyclohexylacetate , Vanillin triacetate, vanillylidene diacetate, vanillyl vanillate, and / or mixtures thereof. These esters may preferably be contained in the perfume oil according to the invention.

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula: R ¹ R ² R ³ C-OH)) are tertiary amyl acetate, Caryophylleneacetat, Cedrenylacetat, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, dimethylbenzyl carbinyl acetate, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenyl formate, Dimethylheptenylpropionat, Dimethylheptenyl-iso-butyrate,

Dimethylphenylethylcarbinylacetat, Dimethylphenylethylcarbinyl-iso-butyrate, Dimethylphenylethylcarbinyl-iso-valerate, dihydro-nor-dicyclopentadienylacetat, Dimethylbenzylcarbinylbutyrate, Dimethylbenzylcarbinylformiat, Dimethylbenzylcarbinylpropionat, Dimethylphenylethylcarbinyl-n-butyrate, Dimethylphenyletylcarbinylformiat, Dimethylphenylethylcarbinylpropionat, Elemylacetat, Ethinylcyclohexylacetat, Eudesmylacetat, Eugenylcinnamat, eugenyl formate, iso- eugenyl formate, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, Hydroxycitronellyl ethyl carbonate, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyl iosbutyrat, Linallylcarproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallyl formate, methyl anthranilate Linallylheptoat, Linallyl-N-, Linallylmethyltiglat, Linallyl pelargonate, Linallylphenylacetat, Linallylpropionat , Linallyl pyruvate, linallyl salicylate, linallyl n-valerate, linallyl iso-valerate,

Methylcyclopentenolonebutyrat, methyl cyclopentenolonpropionat, acetate Methylethylphenylcarbinyl-, Methylheptincarbonat, methyl nicotinate, Myrcenylacetate, Myrcenylformiat, Myrcenylpropionat, cis-ocimenylacetat, phenyl salicylate, terpinyl acetate, Terpinylanthranilat, Terpinylbenzoat, Terpinyl-n-butyrate, Terpinyl-iso-butyrate, Terpinylcinnamat, Terpinylformat, Terpinylphenylacetat, terpinyl propionate , Terpinyl n-valerate, terpinyl iso-valerate, tributyl acetyl citrate, and / or mixtures thereof. These esters may preferably be contained in the perfume oil according to the invention.

Some fragrance esters may be esters of allylic and secondary or allylic and tertiary alcohols, in particular amylvinylcarbinylacetate, amylvinylcarbinylpropionate, hexylvinylcarbinylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, linallylbutyrate, linallylisobutyrate, linallyl carproate, Linallyl caprylate, linallyl cinnamate, linallyl citronellate, linallyl formate, linallylheptoate, linallyl-N-methylanthranilate, linallylmethyltiglate, linallyl pelargonate, linalinal phenylacetate, linallyl propionate, linallyl pyruvate, linallyl salicylate, linallyl n-valerate, linallyl iso-valerate, myrtenyl acetate, nerolidyl acetates, nerolidyl butyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, and / or mixtures thereof. These esters may also preferably be present in the perfume oil according to the invention.

Allylic ketones are characterized by the following structural feature, C - C (= O) - C = C. Preferred examples are acetylfuran, allethrolone, allylionone, allylpulegone, amylcyclopentenone, benzylideneacetone, benzylideneacetophenone, alphaisomethylionone, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) 3-buten-2-one, beta damascon (1 - (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), damascenone (1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) -2- butene-1-one), delta damascone (1- (2,6,6-trimethyl-3-cyclohexen-1-yl) -2-buten-1-one), alpha-ionone (4- (2,6, 6-trimethyl-1-cyclohexenyl-1-yl) -3-buten-2-one), beta-ionone (4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one one), gamma methyl ionone, (4- (2,6,6-trimethyl-2-cyclohexyl-1-yl) -3-methyl-3-buten-2-one), pulegone and / or mixtures thereof. Allylic ketones may preferably be present in the perfume oil according to the invention.

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ). Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso-amyl acetal, acetaldehyde-di-pentanediol acetal, acetaldehyde-di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal , Acetaldehyde phenylethyl-n-propyl acetal,

Cinnamicaldehyde dimethyl acetal, acetaldehyde benzyl-beta-methoxyethyl acetal, acetaldehyde diiso amyl acetal, acetaldehyde diethyl acetal, acetaldehyde-di-cis-3-hexenyl acetal, acetaldehyde dipentanediol acetal, acetaldehyde di-n-propyl acetal, acetaldehyde-ethyl trans 3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, acetylvinyl dimethyl acetal, alpha-amyl cinnamic aldehyde-di-iso-propyl acetal, p-tert-amyl phenoxy acetaldehyde diethyl acetal, anisaldehyde diethyl acetal, anisaldehyde dimethyl acetal, isoapiols, Benzaldehyde diethyl acetal, benzaldehyde di (ethylene glycol monobutyl ether) acetal, benzaldehyde dimethyl acetal, benzaldehyde ethylene glycol acetal, benzaldehyde glyceryl acetal, benzaldehyde propylene glycol acetal, cinnamic aldehyde diethyl acetal, citral diethyl acetal, citral dimethyl acetal, citralpropylene glycol acetal, alpha methyl cinnamic aldehyde diethyl acetal, alpha

Cinnamic aldehyde dimethyl acetal, phenyl acetaldehyde 2,3-butylene glycol acetal,

Phenylacetaldehyde citronellylmethyl acetal, phenyl acetaldehyde diallyl acetal,

Phenylacetaldehyde diamyl acetal, phenyl acetaldehyde dibenzyl acetal,

Phenylacetaldehyde dibutyl acetal, phenyl acetaldehyde diethyl acetal,

Phenylacetaldehydedigeranylacetal, phenylacetaldehyde dimethylacetal,

Phenylacetaldehyde ethylene glycol acetal, phenylacetaldeglyceryl acetal,

Citronellal cyclomonoglycol acetal, citronellaldiethyl acetal, citronellaldimethyl acetal,

Citronellaldiphenylethylacetal, Geranoxyacetaldehyddiethylacetal and / or mixtures thereof. Acetals may preferably be contained in the perfume oil according to the invention. Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ). Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be present in the perfume oil according to the invention.

Preferred examples of condensation products of amines and aldehydes are Anisaldehydemethylanthranilat, Aurantiol (Hydroxycitronellalmethylanthranilat), Verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehydmethylanthranilat), Vertosin (2,4-dimethyl-3-cyclohexencarbaldehyde), Hydroxycitronellalethylanthranilat, Hydroxycitronellal linallylanthranilat, methyl-N - (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenyl-methylidene) - anthranilate, methylnaphthyl ketone methylanthranilate, methyl nonyl acetaldehyde methyl anthranilate, methyl N- (3,5,5-trimethylhexylidene) anthranilate, vanillin methyl anthranilate and / or their mixtures. Condensation products of amines and aldehydes may preferably be present in the perfume oil according to the invention.

In particular, it is advantageous if fragrances such as e.g. Adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, anisaldehyde (4-methoxy-benzaldehydes), bacdanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopentene 1-yl) -2-buten-1-ol), benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, cetalox (dodecahydro-3A, 6,6,9A-tetramethyl-naphtho [2,1 B] -furan), cis-3-hexenylacetate, cis-3-hexenylsalicylate, citronellol, coumarin, cyclohexylsalicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde), decylaldehyde, ethylvanillin, ethyl-2-methylbutyrate, ethylene brasylate, Eucalyptol, eugenol, exaltolide (cyclopentadecanolide), florhydral (3- (3-isopropylphenyl) butanal), galaxolide (1, 3,4, 6, 7,8-hexahydro-4, 6,6,7, 8,8-hexamethyl cyclopenta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitrile, helional (alpha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), heliotropin, hexylacetate, hexylcinnamaldehyde, hexylsalicylate, hydroxyambran (2- Cyclododecyl-propanol), hydroxycitronellal, iso E super (7-acetyl-1, 2,3,4, 5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene), isoeugenol, isojasmon, koavon (acetyldi-isoamylene), laurylaldehyde, Irg 201 (2,4-dihydroxy-3,6-dimethyl methyl benzoate), Lyral (4- (4-hydroxy-4-methylpentyl) 3-cyclohexene-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), Mayor ( 4- (1-methylethyl) cyclohexanemethanol), methyl anthranilate, methyl beta naphthylketoe, methyl cedrone (methyl cedryl ketone), methyl chavicol (1-methyloxy-4,2-propen-1-yl benzene),

Methyl dihydrojasmonate, methylnonylacetaldehyde, musk indanone (4-acetyl-6-tert-butyl-1,1-dimethyl indan), nerol, nonalactone (4-hydroxynonanoic acid, lactone), norlimbanol (1- (2,2,6-) Trimethylcyclohexyl) -3-hexanol), PT Bucinal (2-methyl-3 (para tert-butylphenyl) propionaldehyde), para-hydroxyphenylbutanone, patchouli, phenylacetaldehyde, phenylethylacetate, phenylethylalcohol, phenylethylphenylacetate, phenylhexanol / phenoxanol (3-methyl-5-phenylpentanol ), Polysantol (3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), rosaphene (2-methyl-5-phenylpentanol) , Sandalwood, alpha-terpinene, tonalid / musk plus (7-acetyl-1, 1, 3,4,4,6-hexamethyl- tetralin), undecalactone, undecabertol (4-methyl-3-decen-5-ol), undecylaldehyde or undecenealdehydes, vanillin and / or mixtures are contained in the perfume oil according to the invention.

In a preferred embodiment, the washing or cleaning agent according to the invention contains certain minimum values of perfume oil, namely at least 0.01% by weight, advantageously at least 0.1% by weight, in a considerably advantageous manner at least 0.15% by weight more preferably at least 0.2 wt.%, more preferably at least 0.25 wt.%, even more advantageously at least 0.3 wt.%, most preferably at least 0.35 wt.% , in a particularly advantageous manner at least 0.4 wt .-%, in a particularly advantageous manner at least 0.45 wt .-%, in a significantly advantageous manner at least 0.5 wt .-%, in a very advantageous manner, at least 0.55 Wt .-%, in an extremely advantageous manner at least 0.6 wt .-%, most advantageously at least 0.65 wt .-%, most advantageously at least 0.7 wt .-%, in an exceptionally advantageous manner at least 0.75 Wt .-%, in an exceptionally advantageous manner at least 0.8 wt .-%, in the outside erordentlich advantageously at least 0.85 wt .-%, in particular at least 0.9 wt .-% of perfume oil, based on the total washing or cleaning agent.

In a preferred embodiment, the perfume oils contain less than 8, advantageously less than 7, more preferably less than 6, more preferably less than 5, more preferably less than 4, even more preferably less than 3, preferably less than 2, especially no fragrances from the list Amylcinnamal, Amylcinnamylalkohol, Benzylalcohol, Benzylsalicylat, Cinnamylalkohol, Cinnamal, Citral, Cumarin, Eugenol, Geraniol, Hydroxycitronellal, Hydroxymethylpentylcyclohexencarboxaldehyde, Isoeugenol, Anisylalkohol, Benzylbenzoat, Benzylcinnamat, Citronellol, Farnesol, Hexylcinnamaldehyd, Lilial, d-Limonen, Linalool , Methylheptincarbonate, 3-methyl-4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one, oak moss extract, tree moss extract.

Another object of the invention is the use of the fluid-containing particles according to the invention for room, vehicle or cabinet scenting, in particular in the form of fragrance bags.

Another object of the invention is the use of fluid-containing particles for scenting articles, preferably detergents, washing and cleaning machines, dry laundry and packaging.

Another object of the invention is the use of fluid-containing particles for scenting textiles during the, preferably mechanical, washing or drying process. Another object of the invention is the use of fluid-containing particles to protect the contained fluid, in particular perfume, against an aggressive medium, in particular a detergent matrix.

Examples

Composition A

A zeolite-containing tower powder was granulated with a 4.6% by weight aqueous carboxymethylcellulose (CMC) solution. The resulting agglomerate after drying had 94.98% by weight of tower powder, 0.19% by weight of CMC and 4.83% by weight of water.

This agglomerate was then treated with perfumes. The resulting particles contained 20% by weight perfumes and 80% by weight of the original agglomerate.

The particles showed even several weeks of storage at elevated temperatures (40 ⁰ C) excellent powder and fragrance properties.

Comparative Composition B

The same zeolite-containing tower powder as in the first example was granulated with PEG 400. After drying, the resulting granules had 94.98% by weight of tower powder, 2.2% by weight of PEG 400 and 2.82% by weight of water.

This agglomerate was then treated with perfumes. The resulting particles contained 20% by weight perfumes and 80% by weight of the original agglomerate.

The particles showed poor powder properties after preparation and were not flowable.

Claims

claims:

1. Fluid-containing particles obtainable by agglomeration of carrier material in the presence of a granulating liquid comprising carbohydrates and / or their derivatives, followed by the application of a liquid to be incorporated.

2. Fluid-containing particles according to claim 1, characterized in that the fluid to be incorporated a) fragrances (perfume oils) b) liquid detergents and cleaning agent ingredients, such as preferably surfactants, especially nonionic surfactants, silicone oils, paraffins c) liquid cosmetic ingredients, such as preferably oils d) liquid non-pharmaceutical additives or active ingredients and / or e) mixtures of the aforementioned.

3. fluid-containing particles according to claim 1 or 2, characterized in that they> 5 wt .-%, preferably> 10 wt .-%, advantageously> 15 wt .-%, in particular> 20 wt .-%, fragrances (perfume oils) contain.

4. Fluid-containing particles according to any one of claims 1-3, characterized in that the carrier material comprises anionic carrier material, advantageously zeolite and / or layered silicate, preferably bentonite.

5. Fluid-containing particles according to any one of claims 1-4, characterized in that they> 30 wt .-%, preferably> 40 wt .-%, advantageously> 50 wt .-%, in particular> 60 wt .-% of zeolite and or contain bentonite.

6. fluid-containing particles according to any one of claims 1-5, characterized in that the carrier material before the agglomeration solid additives in crystal form, preferably sugar and / or salt, are added, advantageously in amounts of> 10 wt .-%, in a more advantageous manner > 20 wt .-%, more preferably> 30 wt .-%, in particular in amounts of 40-55 wt .-% based on the total solids to be agglomerated.

7. Fluid-containing particles according to any one of claims 1-6, characterized in that the carrier material spray-dried material, preferably tower powder comprises.

8. Fluid-containing particles according to any one of claims 1-7, characterized in that the carrier material with high pressure, preferably> 10 000 Pa, agglomerated.

9. fluid-containing particles according to any one of claims 1-8, characterized in that the granulation liquid

(a) cellulose (derivatives) such as carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxypropylmethyl cellulose, methyl cellulose, ethyl cellulose, methyl hydroxyalkyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, ethyl hydroxyethyl cellulose, cationically modified hydroxyethyl cellulose and / or hydroxypropyl cellulose,

(b) Starch (derivatives) such as carboxymethyl starch (starch carboxymethyl ether), hydroxyethyl starches, hydroxypropyl starches, cationic starch (derivatives)

(c) mono-, oligo- and / or polysaccharide (derivatives) e, in particular ribose, xylose and arabinose, glucose, mannose, galactose, fructose, sorbose, fucose, rhamnose, sucrose (cane sugar or beet sugar), maltose (malt sugar ), Lactose (milk sugar), trehalose, cellobiose, gentiobiose, isomaltose, lactulose, melibiose, neohesperidose, neotrehalose, nigerose, palatinose, xanthan, dextran, chitosan and / or alginates

(d) mixtures of the aforementioned.

10. Fluid-containing particles according to any one of claims 1-9, characterized in that the granulation liquid has a solvent content, preferably water content of greater than 80 wt .-%, advantageously 90-99 wt .-%, advantageously of 95-98 wt .-% ,

1 1. Fluid-containing particles according to any one of claims 1-10, characterized in that they are coated, preferably powdered and / or are coated with a film.

12. Fluid-containing particles according to claim 11, characterized in that the coating comprises colored substances, dyes, brighteners and / or pigments, advantageously in the nanoscale range or in the micrometer range.

13. Fluid-containing particles according to any one of claims 1-12, characterized in that they are coated with a thermoplastic, such as preferably PEG, PVA, polyacrylates, PVP, carbohydrates, polyesters such as preferably PET.

14. Fluid-containing particles according to any one of claims 1-13, characterized in that the average particle size of the particles between 0.1 and 2.0 mm, preferably 0.15 and 1, 5 mm, in particular 0.2 and 1, 2 mm lies.

15. Fluid-containing particles according to any one of claims 1-14, characterized in that they contain solids from the group of silicates, phosphates, urea and / or its derivatives, sulfates, carbonates, citrates, citric acid, acetates and / or salts of anionic surfactants.

16. Fluid-containing particles according to one of claims 1 to 15, characterized in that they contain at least one further, preferably two further or more usually contained in detergents or cleaning agents, preferably a substance from the group of surfactants, builders (inorganic and organic Builders), bleaching agents, bleach activators, bleach stabilizers, bleach catalysts, enzymes, special polymers (for example those with cobuilder properties), grayness inhibitors, optical brighteners, UV protectants, soil repellents, electrolytes, colorants, fragrances, fragrances, Perfume carriers, pH adjusters, chelating agents, fluorescers, foam inhibitors, anti-crease agents, antioxidants, quaternary ammonium compounds, antistats, ironing aids, UV absorbers, anti redeposition agents, germicides, antimicrobial agents, fungicides, viscosity regulators, pearlescers, dye transfer inhibitors, Ein anti-clogging agents, corrosion inhibitors, preservatives, plasticizers, fabric softeners, protein hydrolysates, repellents and impregnating agents, hydrotropes, silicone oils and swelling and anti-slipping agents.

17. Washing, cleaning or conditioning agent containing fluid-containing particles according to one of the preceding claims.

18. Use of the fluid-containing particles according to one of claims 1 to 16 for room, vehicle or cabinet scenting, in particular in the form of fragrance bags.

19. Use of the fluid-containing particles according to one of claims 1 to 16 for the scenting of articles, preferably of detergents, washing and cleaning machines, dry laundry and packaging.

20. Use of the fluid-containing particles according to one of claims 1 to 16 for the scenting of textiles during the, preferably mechanical, washing or drying process.

21. Use of the fluid-containing particles according to any one of claims 1 to 16 for the protection of the contained fluid, in particular perfume, against an aggressive medium, in particular a detergent matrix.