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WO2007002792A3 - Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2) - Google Patents

Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2) Download PDF

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Publication number
WO2007002792A3
WO2007002792A3 PCT/US2006/025266 US2006025266W WO2007002792A3 WO 2007002792 A3 WO2007002792 A3 WO 2007002792A3 US 2006025266 W US2006025266 W US 2006025266W WO 2007002792 A3 WO2007002792 A3 WO 2007002792A3
Authority
WO
WIPO (PCT)
Prior art keywords
separation
cao
calcination
cars
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/025266
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English (en)
Other versions
WO2007002792A2 (fr
Inventor
Liang-Shih Fan
Himanshu Gupta
Mahesh V Iyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ohio State University
Original Assignee
Ohio State University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/255,099 external-priority patent/US7618606B2/en
Application filed by Ohio State University filed Critical Ohio State University
Priority to CA2613698A priority Critical patent/CA2613698C/fr
Priority to EP06774232A priority patent/EP1899049A4/fr
Priority to US11/994,316 priority patent/US8226917B2/en
Publication of WO2007002792A2 publication Critical patent/WO2007002792A2/fr
Publication of WO2007002792A3 publication Critical patent/WO2007002792A3/fr
Anticipated expiration legal-status Critical
Priority to US13/555,054 priority patent/US8501105B2/en
Priority to US13/892,822 priority patent/US20140154162A1/en
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0277—Carbonates of compounds other than those provided for in B01J20/043
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B01J20/3466—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase with steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3491—Regenerating or reactivating by pressure treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/602—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

La présente invention concerne un processus à base de réaction qui a été développé de façon à retirer de manière sélective du dioxyde de carbone (CO2) d'un mélange de gaz multicomposant de façon à obtenir un flux gazeux épuisé en CO2 comparé à la concentration de CO2 d'entrée de ce flux. Le processus proposé effectue la séparation du CO2 du mélange de gaz (tel qu'un gaz de combustion/gaz de combustible) par sa réaction avec des oxydes métalliques (tels que l'oxyde de calcium). Cette séparation par réaction à base de calcium du processus de CO2 (CaRS-CO2) consiste à mettre en contact un gaz chargé de CO2 avec un oxyde de calcium (CaO) dans un réacteur de sorte que le CaO capture le CO2 par formation de carbonate de calcium (CaCOa). Une fois consommé, le CaCO3 est régénéré par sa calcination conduisant à la formation de nouveau sorbant CaO et à l'évolution d'un flux concentré de CO2. Le cycle carbonation/calcination forme la base du processus CaRS-CO2. Ce processus identifie aussi l'application d'une structure CaCO3 mésoporeuse élaboré par un processus détaillé ailleurs, qui atteint une conversion supérieure à 90 % sur de multiples cycles de carbonation et de calcination. Enfin, la régénération thermique (calcination) sous vide fournit une meilleure structure de sorbant qui maintient des niveaux de réactivité reproductibles sur de multiples cycles.
PCT/US2006/025266 2003-02-06 2006-06-28 Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2) Ceased WO2007002792A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CA2613698A CA2613698C (fr) 2005-06-28 2006-06-28 Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2)
EP06774232A EP1899049A4 (fr) 2005-06-28 2006-06-28 Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2)
US11/994,316 US8226917B2 (en) 2003-02-06 2006-06-28 Separation of carbon dioxide from gas mixtures by calcium based reaction separation
US13/555,054 US8501105B2 (en) 2003-02-06 2012-07-20 Separation of carbon dioxide (CO2) from gas mixtures by calcium based reaction separation (CaRS-CO2) process
US13/892,822 US20140154162A1 (en) 2003-02-06 2013-05-13 SEPARATION OF CARBON DIOXIDE (CO2) FROM GAS MIXTURES BY CALCIUM BASED REACTION SEPARATION (CaRS-CO2) PROCESS

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US69459405P 2005-06-28 2005-06-28
US60/694,594 2005-06-28
US11/255,099 US7618606B2 (en) 2003-02-06 2005-10-20 Separation of carbon dioxide (CO2) from gas mixtures
US11/255,099 2005-10-20

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US11/255,099 Continuation US7618606B2 (en) 2003-02-06 2005-10-20 Separation of carbon dioxide (CO2) from gas mixtures

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US11/994,316 A-371-Of-International US8226917B2 (en) 2003-02-06 2006-06-28 Separation of carbon dioxide from gas mixtures by calcium based reaction separation
US13/555,054 Division US8501105B2 (en) 2003-02-06 2012-07-20 Separation of carbon dioxide (CO2) from gas mixtures by calcium based reaction separation (CaRS-CO2) process

Publications (2)

Publication Number Publication Date
WO2007002792A2 WO2007002792A2 (fr) 2007-01-04
WO2007002792A3 true WO2007002792A3 (fr) 2007-03-29

Family

ID=37596032

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/025266 Ceased WO2007002792A2 (fr) 2003-02-06 2006-06-28 Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2)

Country Status (3)

Country Link
EP (1) EP1899049A4 (fr)
CA (1) CA2613698C (fr)
WO (1) WO2007002792A2 (fr)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7618606B2 (en) * 2003-02-06 2009-11-17 The Ohio State University Separation of carbon dioxide (CO2) from gas mixtures
US7678351B2 (en) 2005-03-17 2010-03-16 The Ohio State University High temperature CO2 capture using engineered eggshells: a route to carbon management
WO2008039783A2 (fr) 2006-09-25 2008-04-03 The Ohio State University Procédé de mise en boucle de calcium pour une production d'hydrogène haute pureté
US8632626B2 (en) 2008-05-15 2014-01-21 Calix Limited System and method for processing flue gas
WO2009148334A1 (fr) 2008-06-05 2009-12-10 Industrial Research Limited Procédé de séparation de gaz
DE102008050816B4 (de) * 2008-10-08 2013-09-05 Alstom Technology Ltd. Verfahren und Anordnung zur Abscheidung von CO2 aus Verbrennungsabgas
US8496909B2 (en) 2008-10-13 2013-07-30 The Ohio State University Research Foundation Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides
WO2011082448A1 (fr) * 2010-01-08 2011-07-14 The University Of Queensland Régénération de sorbant
US11180860B2 (en) 2018-05-18 2021-11-23 California Institute Of Technology Process to convert reduced sulfur species and water into hydrogen and sulfuric acid
CN114555539A (zh) 2019-08-13 2022-05-27 加州理工学院 由含钙岩石和矿物生产氧化钙或普通波特兰水泥的工艺
CN111085101B (zh) * 2019-12-25 2021-03-09 华北电力大学 一种二氧化碳矿化封存及固化飞灰中重金属的系统及方法
EP3862067B1 (fr) * 2020-02-10 2025-05-14 Clariant Catalysts (Japan) K.K. Procédé d'élimination de co2 et o2
US11858819B2 (en) 2021-03-04 2024-01-02 Energy And Environmental Research Center Foundation Methods of producing a syngas composition
US11717802B2 (en) 2021-03-04 2023-08-08 Energy And Environmental Research Center Foundation Methods of treating metal carbonate salts
FR3125817B1 (fr) * 2021-07-30 2024-06-21 Welya Procédé de formation d’un produit final à partir de carbonate de calcium et d’une autre espèce
CN115282922B (zh) * 2022-08-01 2024-01-09 合肥工业大学 一种垃圾焚烧飞灰改性处理方法及其在二氧化碳高温吸附中的应用
TWI890195B (zh) * 2023-11-14 2025-07-11 財團法人工業技術研究院 捕獲二氧化碳的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4748010A (en) * 1985-03-11 1988-05-31 Chemstar, Inc. Energy conserving limestone calcining system
US5520894A (en) * 1992-07-02 1996-05-28 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Process for removing carbon dioxide regeneratively from gas streams
US20030113239A1 (en) * 2001-08-01 2003-06-19 Pahlman John E. Systems and processes for removal of pollutants from a gas stream
EP1332783A1 (fr) * 2002-01-16 2003-08-06 Hamilton Sundstrand Corporation Dispositif de lavage pour le dioxide de carbon provenant des émissions de gaz et de carburant

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2192994B1 (es) * 2002-03-22 2005-02-16 Consejo Superior Investig. Cientificas Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.
US6942719B2 (en) * 2003-06-30 2005-09-13 The Boeing Company Methods and systems for pressure swing regeneration for hydrogen generation
US7879139B2 (en) * 2003-11-14 2011-02-01 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Reactivation of lime-based sorbents by CO2 shocking

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4748010A (en) * 1985-03-11 1988-05-31 Chemstar, Inc. Energy conserving limestone calcining system
US5520894A (en) * 1992-07-02 1996-05-28 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Process for removing carbon dioxide regeneratively from gas streams
US20030113239A1 (en) * 2001-08-01 2003-06-19 Pahlman John E. Systems and processes for removal of pollutants from a gas stream
EP1332783A1 (fr) * 2002-01-16 2003-08-06 Hamilton Sundstrand Corporation Dispositif de lavage pour le dioxide de carbon provenant des émissions de gaz et de carburant

Also Published As

Publication number Publication date
CA2613698C (fr) 2013-02-05
EP1899049A2 (fr) 2008-03-19
WO2007002792A2 (fr) 2007-01-04
CA2613698A1 (fr) 2007-01-04
EP1899049A4 (fr) 2010-12-08

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