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WO2007002792A3 - SEPARATION OF CARBON DIOXIDE (CO2) FROM GAS MIXTURES BY CALCIUM BASED REACTION SEPARATION ( CaRS-CO2) PROCESS - Google Patents

SEPARATION OF CARBON DIOXIDE (CO2) FROM GAS MIXTURES BY CALCIUM BASED REACTION SEPARATION ( CaRS-CO2) PROCESS Download PDF

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Publication number
WO2007002792A3
WO2007002792A3 PCT/US2006/025266 US2006025266W WO2007002792A3 WO 2007002792 A3 WO2007002792 A3 WO 2007002792A3 US 2006025266 W US2006025266 W US 2006025266W WO 2007002792 A3 WO2007002792 A3 WO 2007002792A3
Authority
WO
WIPO (PCT)
Prior art keywords
separation
cao
calcination
cars
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/025266
Other languages
French (fr)
Other versions
WO2007002792A2 (en
Inventor
Liang-Shih Fan
Himanshu Gupta
Mahesh V Iyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ohio State University
Original Assignee
Ohio State University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/255,099 external-priority patent/US7618606B2/en
Application filed by Ohio State University filed Critical Ohio State University
Priority to CA2613698A priority Critical patent/CA2613698C/en
Priority to EP06774232A priority patent/EP1899049A4/en
Priority to US11/994,316 priority patent/US8226917B2/en
Publication of WO2007002792A2 publication Critical patent/WO2007002792A2/en
Publication of WO2007002792A3 publication Critical patent/WO2007002792A3/en
Anticipated expiration legal-status Critical
Priority to US13/555,054 priority patent/US8501105B2/en
Priority to US13/892,822 priority patent/US20140154162A1/en
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0277—Carbonates of compounds other than those provided for in B01J20/043
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B01J20/3466—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase with steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3491—Regenerating or reactivating by pressure treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/602—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

A reaction-based process has been developed for the selective removal of carbon dioxide (CO2) from a multicomponent gas mixture to provide a gaseous stream depleted in CO2 compared to the inlet CO2 concentration in the stream. The proposed process effects the separation of CO2 from a mixture of gases (such as flue gas/fuel gas) by its reaction with metal oxides (such as calcium oxide). The Calcium based Reaction Separation for CO2 (CaRS-CO2) process consists of contacting a CO2 laden gas with calcium oxide (CaO) in a reactor such that CaO captures the CO2 by the formation of calcium carbonate (CaCOa). Once 'spent', CaCO3 is regenerated by its calcination leading to the formation of fresh CaO sorbent and the evolution of a concentrated stream of CO2. The 'regenerated' CaO is then recycled for the further capture of more CO2. This carbonation-calcination cycle forms the basis of the CaRS-CO2 process. This process also identifies the application of a mesoporous CaCO3 structure, developed by a process detailed elsewhere, that attains >90% conversion over multiple carbonation and calcination cycles. Lastly, thermal regeneration (calcination) under vacuum provided a better sorbent structure that maintained reproducible reactivity levels over multiple cycles.
PCT/US2006/025266 2003-02-06 2006-06-28 SEPARATION OF CARBON DIOXIDE (CO2) FROM GAS MIXTURES BY CALCIUM BASED REACTION SEPARATION ( CaRS-CO2) PROCESS Ceased WO2007002792A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CA2613698A CA2613698C (en) 2005-06-28 2006-06-28 Separation of carbon dioxide (co2) from gas mixtures by calcium based reaction separation (cars-co2) process
EP06774232A EP1899049A4 (en) 2005-06-28 2006-06-28 SEPARATION OF CARBON DIOXIDE (CO2) FROM GAS MIXTURES BY CALCIUM-BASED REACTION SEPARATION METHOD (CARS-CO2)
US11/994,316 US8226917B2 (en) 2003-02-06 2006-06-28 Separation of carbon dioxide from gas mixtures by calcium based reaction separation
US13/555,054 US8501105B2 (en) 2003-02-06 2012-07-20 Separation of carbon dioxide (CO2) from gas mixtures by calcium based reaction separation (CaRS-CO2) process
US13/892,822 US20140154162A1 (en) 2003-02-06 2013-05-13 SEPARATION OF CARBON DIOXIDE (CO2) FROM GAS MIXTURES BY CALCIUM BASED REACTION SEPARATION (CaRS-CO2) PROCESS

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US69459405P 2005-06-28 2005-06-28
US60/694,594 2005-06-28
US11/255,099 US7618606B2 (en) 2003-02-06 2005-10-20 Separation of carbon dioxide (CO2) from gas mixtures
US11/255,099 2005-10-20

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US11/255,099 Continuation US7618606B2 (en) 2003-02-06 2005-10-20 Separation of carbon dioxide (CO2) from gas mixtures

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US11/994,316 A-371-Of-International US8226917B2 (en) 2003-02-06 2006-06-28 Separation of carbon dioxide from gas mixtures by calcium based reaction separation
US13/555,054 Division US8501105B2 (en) 2003-02-06 2012-07-20 Separation of carbon dioxide (CO2) from gas mixtures by calcium based reaction separation (CaRS-CO2) process

Publications (2)

Publication Number Publication Date
WO2007002792A2 WO2007002792A2 (en) 2007-01-04
WO2007002792A3 true WO2007002792A3 (en) 2007-03-29

Family

ID=37596032

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/025266 Ceased WO2007002792A2 (en) 2003-02-06 2006-06-28 SEPARATION OF CARBON DIOXIDE (CO2) FROM GAS MIXTURES BY CALCIUM BASED REACTION SEPARATION ( CaRS-CO2) PROCESS

Country Status (3)

Country Link
EP (1) EP1899049A4 (en)
CA (1) CA2613698C (en)
WO (1) WO2007002792A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7618606B2 (en) * 2003-02-06 2009-11-17 The Ohio State University Separation of carbon dioxide (CO2) from gas mixtures
US7678351B2 (en) 2005-03-17 2010-03-16 The Ohio State University High temperature CO2 capture using engineered eggshells: a route to carbon management
WO2008039783A2 (en) 2006-09-25 2008-04-03 The Ohio State University Calcium looping process for high purity hydrogen production
US8632626B2 (en) 2008-05-15 2014-01-21 Calix Limited System and method for processing flue gas
WO2009148334A1 (en) 2008-06-05 2009-12-10 Industrial Research Limited Gas separation process
DE102008050816B4 (en) * 2008-10-08 2013-09-05 Alstom Technology Ltd. Method and arrangement for separating CO2 from combustion exhaust gas
US8496909B2 (en) 2008-10-13 2013-07-30 The Ohio State University Research Foundation Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides
WO2011082448A1 (en) * 2010-01-08 2011-07-14 The University Of Queensland Sorbent regeneration
US11180860B2 (en) 2018-05-18 2021-11-23 California Institute Of Technology Process to convert reduced sulfur species and water into hydrogen and sulfuric acid
CN114555539A (en) 2019-08-13 2022-05-27 加州理工学院 Process for producing calcium oxide or ordinary portland cement from calcium-containing rocks and minerals
CN111085101B (en) * 2019-12-25 2021-03-09 华北电力大学 A system and method for carbon dioxide mineralization, sequestration and solidification of heavy metals in fly ash
EP3862067B1 (en) * 2020-02-10 2025-05-14 Clariant Catalysts (Japan) K.K. Method for removing co2 and o2
US11858819B2 (en) 2021-03-04 2024-01-02 Energy And Environmental Research Center Foundation Methods of producing a syngas composition
US11717802B2 (en) 2021-03-04 2023-08-08 Energy And Environmental Research Center Foundation Methods of treating metal carbonate salts
FR3125817B1 (en) * 2021-07-30 2024-06-21 Welya Process for forming a final product from calcium carbonate and another species
CN115282922B (en) * 2022-08-01 2024-01-09 合肥工业大学 A method for modifying waste incineration fly ash and its application in high-temperature carbon dioxide adsorption
TWI890195B (en) * 2023-11-14 2025-07-11 財團法人工業技術研究院 Method of capturing carbon dioxide

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4748010A (en) * 1985-03-11 1988-05-31 Chemstar, Inc. Energy conserving limestone calcining system
US5520894A (en) * 1992-07-02 1996-05-28 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Process for removing carbon dioxide regeneratively from gas streams
US20030113239A1 (en) * 2001-08-01 2003-06-19 Pahlman John E. Systems and processes for removal of pollutants from a gas stream
EP1332783A1 (en) * 2002-01-16 2003-08-06 Hamilton Sundstrand Corporation Carbon dioxide scrubber for fuel and gas emissions

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2192994B1 (en) * 2002-03-22 2005-02-16 Consejo Superior Investig. Cientificas COMBUSTION PROCEDURE WITH INTEGRATED CO2 SEPARATION BY CARBONATION.
US6942719B2 (en) * 2003-06-30 2005-09-13 The Boeing Company Methods and systems for pressure swing regeneration for hydrogen generation
US7879139B2 (en) * 2003-11-14 2011-02-01 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Reactivation of lime-based sorbents by CO2 shocking

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4748010A (en) * 1985-03-11 1988-05-31 Chemstar, Inc. Energy conserving limestone calcining system
US5520894A (en) * 1992-07-02 1996-05-28 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Process for removing carbon dioxide regeneratively from gas streams
US20030113239A1 (en) * 2001-08-01 2003-06-19 Pahlman John E. Systems and processes for removal of pollutants from a gas stream
EP1332783A1 (en) * 2002-01-16 2003-08-06 Hamilton Sundstrand Corporation Carbon dioxide scrubber for fuel and gas emissions

Also Published As

Publication number Publication date
CA2613698C (en) 2013-02-05
EP1899049A2 (en) 2008-03-19
WO2007002792A2 (en) 2007-01-04
CA2613698A1 (en) 2007-01-04
EP1899049A4 (en) 2010-12-08

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