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WO2006050648A1 - Film hautement oriente d'hydroxydes doubles lamellaires metalliques, et son procede de preparation - Google Patents

Film hautement oriente d'hydroxydes doubles lamellaires metalliques, et son procede de preparation Download PDF

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Publication number
WO2006050648A1
WO2006050648A1 PCT/CN2005/001235 CN2005001235W WO2006050648A1 WO 2006050648 A1 WO2006050648 A1 WO 2006050648A1 CN 2005001235 W CN2005001235 W CN 2005001235W WO 2006050648 A1 WO2006050648 A1 WO 2006050648A1
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WO
WIPO (PCT)
Prior art keywords
film
ldhs
substrate
layered
bishydroxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2005/001235
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English (en)
Chinese (zh)
Inventor
Xue Duan
Xiaodong Lei
Lan Yang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing University of Chemical Technology
Original Assignee
Beijing University of Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing University of Chemical Technology filed Critical Beijing University of Chemical Technology
Publication of WO2006050648A1 publication Critical patent/WO2006050648A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14—Methods for preparing oxides or hydroxides in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/20—Two-dimensional structures
    • C01P2002/22—Two-dimensional structures layered hydroxide-type, e.g. of the hydrotalcite-type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram

Definitions

  • the highly oriented layered hydroxyl composite metal oxide film provided by the present invention is an LDHs film grown on a high molecular material, and the chemical formula of the film LDHs is:
  • A The sulfonated polymer material is pressed into substrates of different shapes and sizes as needed, and immersed in 1-6 angels in a commercially available acid (in general, the concentration is 80%-98%). After washing out, rinse with deionized water and dry at 30-60 °C for use.
  • the surface of the sulfonated polymer material substrate is suspended horizontally in a solution, and after sealing the container, the reaction is carried out at a constant temperature of 50-100 ° C for 3-12 days, and the preferred reaction condition is 60-90 ° C. The temperature is reacted for 5-9 days at a constant temperature; after the solution is cooled, the polymer material substrate is taken out, rinsed with deionized water, and dried, and the film formed on the surface of the polymer material is an LDHs film.
  • e is a curve of nickel aluminum carbonate LDHs powder
  • Fig. 7 is a FESEM photograph of the surface of the magnesium aluminum carbonate LDHs film sample obtained in Example 8. detailed description
  • the styrene-di-glycolylbenzene copolymer was heat-pressed into a sheet and then immersed in a commercially available concentrated acid for 5 days, rinsed with deionized water, and dried at 30 ° C for use.
  • the film formed on the surface of the polystyrene is a nickel-aluminum carbonate LDHs film having a Ni/Al molar ratio of 1.90, and the film surface A1 content is 0. 0151 ⁇ 2ol/m 2 , and the XRD spectrum thereof is shown in the figure. 1 (d), FESEM photos are shown in Figure 4, Figure 5, respectively, it can be seen that the film thickness is about 1. 67 ⁇ , compact, good orientation.
  • the polystyrene was hot pressed into a sheet and immersed in commercially available concentrated sulfuric acid for 3 days, rinsed with deionized water, and dried at 30 Torr for use.
  • the styrene-divinylbenzene copolymer was hot pressed into a sheet and immersed in a commercially available concentrated acid for 5 days, rinsed with deionized water, and dried under 4 (TC).
  • the polystyrene After the polystyrene is hot pressed into a sheet, it is rinsed with deionized water and dried at 40 ° C for use.
  • the FESEM photo of the surface is shown in Fig. 7. It can be seen that the magnesium-aluminum carbonate LDHs film formed on the surface of the polystyrene has poor continuity and the LDHs are disorderly arranged.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)

Abstract

La présente invention concerne des hydroxydes doubles lamellaires métalliques hautement orientés (LDH), et leur procédé de synthèse biomimétique. Le film des LDH est obtenu par croissance sur un substrat de polymère, et sa formule générale est [M2+ 1-xM3+ x(OH)2]x+(CO3 2-)x/2-y H2O. La face cristalline (001) (ou la face cristalline ab) du film des LDH est perpendiculaire à la surface du substrat, et le film est hautement orienté et compact, et l'épaisseur du film est comprise entre 0,5 νm et 5 νm. Le procédé de préparation du film consiste à: mettre horizontalement en suspension le matériau polymérique sulfoné en surface en tant que substrat du film dans la solution contenant de l'urée et des sels métalliques correspondants; contrôler le taux de décomposition de l'urée en réglant la température et la durée de la réaction de façon à contrôler la libération de l'anion; permettre la nucléation des LDH sur le substrat et leur croissance avec orientation. On obtient ainsi le film de l'invention et on règle les problèmes qui faisaient que le film des LDH était déposé uniquement sur un substrat inorganique et que l'orientation du cristal des LDH dans le film était médiocre.
PCT/CN2005/001235 2004-11-15 2005-08-11 Film hautement oriente d'hydroxydes doubles lamellaires metalliques, et son procede de preparation Ceased WO2006050648A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200410090816.4 2004-11-15
CNB2004100908164A CN1333113C (zh) 2004-11-15 2004-11-15 高度定向层状双羟基复合金属氧化物薄膜及其制备方法

Publications (1)

Publication Number Publication Date
WO2006050648A1 true WO2006050648A1 (fr) 2006-05-18

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Family Applications (1)

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PCT/CN2005/001235 Ceased WO2006050648A1 (fr) 2004-11-15 2005-08-11 Film hautement oriente d'hydroxydes doubles lamellaires metalliques, et son procede de preparation

Country Status (2)

Country Link
CN (1) CN1333113C (fr)
WO (1) WO2006050648A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015098612A1 (fr) 2013-12-27 2015-07-02 日本碍子株式会社 Film orienté d'hydroxyde bicouche et son procédé de fabrication
WO2015098610A1 (fr) 2013-12-27 2015-07-02 日本碍子株式会社 Matériau composite contenant un hydroxyde double lamellaire et son procédé de production
WO2016121168A1 (fr) 2015-01-28 2016-08-04 日本碍子株式会社 Film dense conducteur d'ions hydroxyde et matériau composite
EP3214042A4 (fr) * 2014-10-28 2018-05-02 NGK Insulators, Ltd. Matériau composite contenant un hydroxyde double lamellaire
EP3214043A4 (fr) * 2014-10-28 2018-05-02 NGK Insulators, Ltd. Procédé de formation de membrane dense d'hydroxyde double lamellaire
US10370250B2 (en) 2014-12-17 2019-08-06 Ngk Insulators, Ltd. Layered double hydroxide film and composite material containing layered double hydroxide
EP3560893A4 (fr) * 2016-12-22 2020-08-12 Kyowa Chemical Industry Co., Ltd. Hydrotalcite en forme de plaque à rapport de forme élevé, sa méthode de fabrication et composition de résine

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100430132C (zh) * 2006-09-27 2008-11-05 北京化工大学 一种用于醇氧化反应合成水滑石薄膜催化剂的制备方法
CN102931247B (zh) * 2012-10-23 2014-12-24 北京化工大学 一种聚苯胺与ii-vi族半导体复合光电转换薄膜的制备方法
CN104857927A (zh) * 2015-05-14 2015-08-26 北京化工大学 一种蛭石表面原位生长水滑石材料及其制备方法
CN106057482B (zh) * 2016-06-14 2018-11-02 北京工业大学 一种多级结构LDH@CoS复合电极及制备方法
CN107541718B (zh) * 2017-09-01 2020-01-21 苏州云舒新材料科技有限公司 一种水滑石基磁光薄膜材料的制备方法
CN111118908B (zh) * 2019-12-31 2021-04-27 浙江大学 一种层状双金属氢氧化物-聚苯胺修饰的多孔导电复合材料及其制备方法和应用
CN113451053B (zh) * 2021-06-24 2022-12-02 安徽工程大学 一种PANI/Co-Fe LDHs/NF复合电极材料及其制备方法和应用
CN114853041B (zh) * 2022-02-25 2023-07-21 西北工业大学 一种对苯二甲酸离子插层镁铝层状双氢氧化物的应用
CN115791772B (zh) * 2022-12-08 2024-11-05 北京信息科技大学 一种高机械强度柔性生物传感器的制备及应用

Citations (2)

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US4351814A (en) * 1980-12-18 1982-09-28 Kyowa Chemical Industry Co., Ltd. Hydrotalcites having a hexagonal needle-like crystal structure and process for production thereof
CN1318595A (zh) * 2000-04-17 2001-10-24 北京化工大学 一种新型无机－有机复合的选择性紫外阻隔材料及制备方法

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JPH10283557A (ja) * 1997-04-01 1998-10-23 Kubota Corp 自動販売機の温度検出装置におけるリード線の取付構造
JP4004160B2 (ja) * 1998-09-21 2007-11-07 協和化学工業株式会社 ウラン（ｕ）含量の少ないハイドロタルサイト類化合物およびその製造法

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US4351814A (en) * 1980-12-18 1982-09-28 Kyowa Chemical Industry Co., Ltd. Hydrotalcites having a hexagonal needle-like crystal structure and process for production thereof
CN1318595A (zh) * 2000-04-17 2001-10-24 北京化工大学 一种新型无机－有机复合的选择性紫外阻隔材料及制备方法

Non-Patent Citations (3)

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Title
GARDNER ELIZABETH.: "Direct synthesis of alkoxide-intercalated derivatives of hydrotalcite-like layered double hydroxides: precursors for the formation of colloidal layered double hydroxide suspension and transparent thin films.", ADVANCED MATERIALS., vol. 13, no. 16, 2001, pages 1263 - 1266 *
SHU BING MAO ET AL: "IN SITU SYNTHESIS OF NI-AL-CO3 LDHs ON THE SURFACE OF GAMMA-AL2 O3.", CHINESE JOURNAL OF INORGANIC CHEMISTRY., vol. 20, no. 5, May 2004 (2004-05-01), pages 596 - 602 *
XIANG JUN HE ET AL: "Preparation of hybrid films of an anionic Ru(II) cyanide polypyridyl complex with layered double hydroxides by the Langmuir-Blodgett method and their use as electrode modifiers.", THIN SOLID FILMS., vol. 397, no. 1,2, 2001, pages 255 - 265 *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9793529B2 (en) 2013-12-27 2017-10-17 Ngk Insulators, Ltd. Layered-double-hydroxide-oriented film and method for producing same
US10020480B2 (en) 2013-12-27 2018-07-10 Ngk Insulators, Ltd. Layered-double-hydroxide-containing composite material and method for producing same
KR20150088291A (ko) 2013-12-27 2015-07-31 엔지케이 인슐레이터 엘티디 층형 복수산화물 배향막 및 그 제조 방법
KR20150144814A (ko) 2013-12-27 2015-12-28 엔지케이 인슐레이터 엘티디 층형 복수산화물 함유 복합 재료 및 그 제조 방법
EP2942327A4 (fr) * 2013-12-27 2016-01-27 Ngk Insulators Ltd Film orienté d'hydroxyde bicouche et son procédé de fabrication
US11152668B2 (en) 2013-12-27 2021-10-19 Ngk Insulators, Ltd. Layered-double-hydroxide-containing composite material and method for producing same
EP3015430A4 (fr) * 2013-12-27 2017-01-25 NGK Insulators, Ltd. Matériau composite contenant un hydroxyde double lamellaire et son procédé de production
JPWO2015098612A1 (ja) * 2013-12-27 2017-03-23 日本碍子株式会社 層状複水酸化物配向膜及びその製造方法
WO2015098610A1 (fr) 2013-12-27 2015-07-02 日本碍子株式会社 Matériau composite contenant un hydroxyde double lamellaire et son procédé de production
WO2015098612A1 (fr) 2013-12-27 2015-07-02 日本碍子株式会社 Film orienté d'hydroxyde bicouche et son procédé de fabrication
US10199624B2 (en) 2014-10-28 2019-02-05 Ngk Insulators, Ltd. Layered double hydroxide-containing composite material
EP3214042A4 (fr) * 2014-10-28 2018-05-02 NGK Insulators, Ltd. Matériau composite contenant un hydroxyde double lamellaire
EP3214043A4 (fr) * 2014-10-28 2018-05-02 NGK Insulators, Ltd. Procédé de formation de membrane dense d'hydroxyde double lamellaire
US10370250B2 (en) 2014-12-17 2019-08-06 Ngk Insulators, Ltd. Layered double hydroxide film and composite material containing layered double hydroxide
US10193118B2 (en) 2015-01-28 2019-01-29 Ngk Insulators, Ltd. Hydroxide-ion-conductive dense membrane and composite material
WO2016121168A1 (fr) 2015-01-28 2016-08-04 日本碍子株式会社 Film dense conducteur d'ions hydroxyde et matériau composite
EP3560893A4 (fr) * 2016-12-22 2020-08-12 Kyowa Chemical Industry Co., Ltd. Hydrotalcite en forme de plaque à rapport de forme élevé, sa méthode de fabrication et composition de résine
US11078087B2 (en) 2016-12-22 2021-08-03 Kyowa Chemical Industry Co., Ltd. Plate-shaped hydrotalcite with high aspect ratio, method for manufacturing same and resin composition

Also Published As

Publication number Publication date
CN1776030A (zh) 2006-05-24
CN1333113C (zh) 2007-08-22

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